Библиотека института физики им. Л.В. Киренского СО РАН

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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Coondoo I., Panwar N., Krylova S. N., Krylov A. S., Alikin D., Jakka S. K., Turygin A., Shur V. Y., Kholkin A. L.
Заглавие : Temperature-dependent Raman spectroscopy, domain morphology and photoluminescence studies in lead-free BCZT ceramic
Место публикации : Ceram. Int. - 2021. - Vol. 47, Is. 2. - P.2828-2838. - ISSN 02728842 (ISSN), DOI 10.1016/j.ceramint.2020.09.137
Примечания : Cited References: 65. - I.C. would like to thank financial assistance by national funds (OE), through FCT – Fundação para a Ciência e a Tecnologia, I.P., in the scope of the framework contract foreseen in the numbers 4, 5 and 6 of the article 23, of the Decree-Law 57/2016, of August 29, changed by Law 57/2017, of July 19. This work was developed within the scope of the project CICECO-Aveiro Institute of Materials, UIDB/50011/2020 & UIDP/50011/2020, financed by national funds through the Portuguese Foundation for Science and Technology / MCTES . The authors would also like to acknowledge the Ural Center for Shared Use “Modern nanotechnology”, Ural Federal University, Russia and the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS”. The authors would like to thank Dr. E. Venkata Ramana, Department of Physics, University of Aveiro for the dielectric measurements. The work was supported by Government of the Russian Federation (Act 211, 440 Agreement 02.A03.21.0006)
Аннотация: Present work focuses on detailed temperature-dependent X-ray diffraction, Raman scattering, domain configuration, and photoluminescence (PL) studies in the (Ba0·85Ca0.15) (Zr0·10Ti0.90)O3 (BCZT) ceramics. The comprehensive Raman spectroscopy analysis in the present work not only validates the presence of the intermediate orthorhombic phase in BCZT, but also provides evidence of another transition: rhombohedral R3c phase to R3m at low temperature. Temperature behaviour of the lowest frequency transverse optical mode (soft E (TO) phonon) and hard modes was studied. Temperature dependence of peak positions, intensities, and linewidths of Raman phonon modes signalled the presence of phase transitions near −50 ± 5 °C, 0±5 °C, 35±5 °C and 110 ± 10 °C. Evolution of domain morphology occurring at phase transitions above room temperature was studied by piezoresponse force microscopy technique. Analysis of PL spectra revealed disorder/heterogeneity in the sample and indicated the existence of self-trapped excitons. PL spectra are composed of four distinct colour components (~2.55eV:blue, ~2.32eV:green, ~2.08eV:orange and ~1.78eV:red).
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bikbaev R. G., Vetrov S. Ya., Timofeev I. V.
Заглавие : Hybrid Tamm and surface plasmon polaritons in resonant photonic structure
Место публикации : J. Quant. Spectrosc. Radiat. Transf. - 2020. - Vol. 253. - Ст.107156. - ISSN 00224073 (ISSN), DOI 10.1016/j.jqsrt.2020.107156
Примечания : Cited References: 58. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project No. 19-42-240004 and by a joint project of the Russian Foundation for Basic Research, project No. 19-52-52006, and the Taiwan Ministry of Science and Technology, project No. 108-2923E-009-003-MY3
Аннотация: Hybrid modes originating from the coupling of the Tamm and surface plasmon polaritons excited in a one-dimensional resonant photonic structure are demonstrated. The structure represents a photonic crystal bounded by a nanocomposite film consisting of a transparent matrix and silver nanoparticles uniformly distributed over its volume. In comparison with structures on planar metal films the volume concentration and shape of nanoparticles are of great help in configuring the hybrid mode properties, including their wavelength and splitting. Also the radiation incidence angle variation opens the possibility of fine-tuning the energy spectra of the structure. We demonstrate the high-sensitivity of optical sensors based on the resonant photonic structure.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Крылов, Александр Сергеевич, Мошкина, Евгения Михайловна, Гудим, Ирина Анатольевна, Крылова, Светлана Николаевна, Втюрин, Александр Николаевич
Заглавие : Фазовые переходы в кристаллах мультиферроиков со структурой хантита, содержащих ионы редкоземельных элементов - исследования методом комбинационного рассеяния света
Коллективы : Исследование сегнетоэлектрических материалов российскими учеными. Столетие открытия сегнетоэлектричества, международная онлайн-конференция, Уральский Федеральный университет им. Первого Президента России Б.Н. Ельцина
Место публикации : Втюрин, Александр Николаевич Исследование сегнетоэлектрических материалов российскими учеными. Столетие открытия сегнетоэлектричества, международная онлайн-конференция (2020 ; 14-19 сент. ; Екатеринбург). Международная онлайн-конференция "Исследование сегнетоэлектрических материалов российскими учеными. Столетие открытия сегнетоэлектричества" (СЭ-100): сб. тезисов/ Александр Николаевич Втюрин ; чл. прогр. ком. А. Н. Втюрин. - 2020. - Ст.П17. - С. 26-27. - ISBN 978-5-9500624-3-8
Примечания : Cited References: 7
Аннотация: Изучены эффекты, связанные с параметрами структурного порядка и магнитного упорядочения при фазовых переходах в спектрах комбинационного рассеяния света монокристаллов и твердых растворов кристаллов (Hо-Nd)Fe3(BO3)4, (Sm-La)Fe3(BO3)4, Hо(Fe-Ga)3(BO3)4, Tb(Fe-Ga)3(BO3)4 и Nb(Fe-Ga)3(BO3)4.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Крылов, Александр Сергеевич, Senkovska I., Ehrling S., Maliuta M., Крылова, Светлана Николаевна, Слюсарева, Евгения Алексеевна, Втюрин, Александр Николаевич, Kaskel S.
Заглавие : Фазовый переход в каркасной металло-органической структуре DUT-8(Ni) под давлением – исследование методом комбинационного рассеяния
Коллективы : Исследование сегнетоэлектрических материалов российскими учеными. Столетие открытия сегнетоэлектричества, международная онлайн-конференция, Уральский Федеральный университет им. Первого Президента России Б.Н. Ельцина
Место публикации : Втюрин, Александр Николаевич Исследование сегнетоэлектрических материалов российскими учеными. Столетие открытия сегнетоэлектричества, международная онлайн-конференция (2020 ; 14-19 сент. ; Екатеринбург). Международная онлайн конференция "Исследование сегнетоэлектрических материалов российскими учеными. Столетие открытия сегнетоэлектричества" (СЭ-100): сб. тез. конф./ Александр Николаевич Втюрин ; чл. прогр. ком. А. Н. Втюрин. - 2020. - Ст.П3. - С. 7. - ISBN 978-5-9500624-3-8
Примечания : Cited References: 3
Аннотация: Методом комбинационного рассеяния исследована гибкая каркасная структура DUT-8(Ni) под давлением. Установлено, что индуцированная давлением трансформация открытой структуры в закрытую происходит, как фазовый переход первого рода. В некотором интервале давлений сосуществуют домены открытой и закрытой фаз.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Grishina, Svetlana, Kodera, Peter, Goryainov, Sergey, Oreshonkov A. S., Seryotkin, Yurii, Simko, Frantisek, Polozov, Alexander G.
Заглавие : Application of Raman spectroscopy for identification of rinneite (K3NaFeCl6) in inclusions in minerals
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-05-00682]; European Regional Development FundEuropean Union (EU) [ITMS 26240220086]; Vedecka Grantova Agentura MSVVaS SR a SAV [1/0313/20]
Место публикации : J. Raman Spectrosc. - 2020. - Vol. 51, Is. 12. - P.2505-2516. - ISSN 0377-0486, DOI 10.1002/jrs.6005. - ISSN 1097-4555(eISSN)
Примечания : Cited References: 55. - Russian Foundation for Basic Research, Grant/Award Numbers: 18-05-00682, 18-05-00682; European Regional Development Fund, Grant/Award Number: ITMS 26240220086; Vedecka Grantova Agentura MSVVaS SR a SAV, Grant/Award Number: 1/0313/20
Предметные рубрики: SALT MELT
IRON
DEPOSIT
FLUIDS
TRANSFORMATIONS
FERRIHYDRITE
Аннотация: Solid daughter phases in fluid and salt melt inclusions in minerals provide important clues to characterization of mineral‐forming processes. The analysis of the fluid inclusions often requires the exposure of the daughter minerals. Rinneite (K3NaFeCl6), which is a hygroscopic mineral, decomposes in air and cannot thus be identified by conventional methods. A combined approach has been applied for investigation of synthetic and natural rinneite to acquire its diagnostic Raman spectrum for a nondestructive identification. We used natural rinneite inclusions in halite, suitable for applying a complex of methods, to clear up the reference spectrum. Improved high‐resolution X‐ray diffraction (XRD) data obtained from natural rinneite inclusion are comparable with that of previously published, with similar unit cell dimensions. Polarized Raman spectra of natural inclusions were obtained using different geometries and polarization of the incident and scattered light. Interpretation of experimental Raman spectra was performed within the framework of lattice dynamics simulations and group analysis. Individual spectral bands are interpreted in terms of Raman‐active vibrational modes of K3NaFeCl6 structural units. Raman spectrum of synthetic rinneite with main peaks at 75, 91, 103, 143, 167, 171, 187, and 239 cm−1 agrees well with the spectra of rinneite inclusions in halite from the Nepa potash deposit and rinneite daughter minerals in salt melt inclusions hosted by quartz veinlets from the porphyry gold systems in the Central Slovakia Volcanic Field. This provides a firm basis for any future identification of this mineral worldwide, using nondestructive Raman spectroscopy.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Saykova, Diana, Saikova, Svetlana, Mikhlin, Yuri, Panteleeva, Marina, Ivantsov R. D., Belova E.
Заглавие : Synthesis and characterization of core-shell magnetic nanoparticles NiFe2O4@Au
Место публикации : Metals. - 2020. - Vol. 10, Is. 8. - Ст.1075. - ISSN 2075-4701(eISSN), DOI 10.3390/met10081075
Примечания : Cited References: 45
Предметные рубрики: NICKEL FERRITE NANOPARTICLES
GOLD NANOPARTICLES
OXIDATION
REDUCTION
Аннотация: In this study, NiFe2O4@Au core–shell nanoparticles were prepared by the direct reduction of gold on the magnetic surface using amino acid methionine as a reducer and a stabilizing agent simultaneously. The obtained nanoparticles after three steps of gold deposition had an average size of about 120 nm. The analysis of particles was performed by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and UV-Vis spectroscopy techniques. The results indicate successful synthesis of core–shell particles with the magnetic core, which consists of a few agglomerated nickel ferrite crystals with an average size 25.2 ± 2.0 nm, and the thick gold shell consists of fused Au0 nanoparticles (NPs). Magnetic properties of the obtained nanoparticles were examined with magnetic circular dichroism. It was shown that the magnetic behavior of NiFe2O4@Au NPs is typical for superparamagnetic NPs and corresponds to that for NiFe2O4 NPs without a gold shell. The results indicate the successful synthesis of core–shell particles with the magnetic nickel ferrite core and thick gold shell, and open the potential for the application of the investigated hybrid nanoparticles in hyperthermia, targeted drug delivery, magnetic resonance imaging, or cell separation. The developed synthesis strategy can be extended to other metal ferrites and iron oxides.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gerasimova Yu. V., Krylov A. S., Vtyurin A. N., Laptash N. M., Krylova S. N.
Заглавие : Ferroelastic phase transition in the family of double fluoride crystals by Raman spectroscopy
Коллективы : European Meeting on Ferroelectricity
Место публикации : Ferroelectrics. - 2020. - Vol. 568, Is. 1. - P.185-190. - DOI 10.1080/00150193.2020.1713348
Примечания : Cited References: 14. - This research is supported by Russian Foundation for Basic Research under Grant No. 17-02-00920
Аннотация: In order to clarify ordering mechanisms of ferroic phase transitions in double fluoride salts (NH4)3SnF7, (NH4)3GeF7 and (NH4)3TiF7, their Raman scattering spectra have been studied in wide ranges of frequencies (20–3400 cm−1) and temperatures (8–410 K). Substitution of the central ion in the octahedron groups was found to change not only the phase transition types and sequences, but to modify the types of structural disorder as well, which is a special feature of these high-symmetry fluoride crystals.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krylov A. S.
Заглавие : Raman spectroscopy of crystals
Место публикации : Crystals. - 2020. - Vol. 10, Is. 11. - Ст.981. - P.1-4. - ISSN 20734352 (ISSN), DOI 10.3390/cryst10110981
Примечания : Cited References: 10
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ruseikina A. V., Molokeev M. S., Chernyshev V. А., Aleksandrovsky A. S., Krylov A. S., Krylova S. N., Velikanov D. A., Grigoriev M. V., Maximov N. G., Shestakov N. P., Garmonov A. A., Matigorov A. V., Tarasov A. S., Rautskii M. V., Khritokhin N. А., Melnikova L. V., Tretyakov N. Y.
Заглавие : Synthesis, structure, and properties of EuScCuS3 and SrScCuS3
Место публикации : J. Solid State Chem. - 2021. - Vol. 296. - Ст.121926. - ISSN 00224596 (ISSN), DOI 10.1016/j.jssc.2020.121926
Примечания : Cited References: 72. - The work was supported by the Ministry of Science and Higher Education of the Russian Federation under Project No. FEUZ-2020-0054; by RFBR Grant 18-02-00754 ; by the “UMNIK” program research project № 14977GY/2019; by the Ministry of Science and Higher Education of the Russian Federation (contract no. 05.594.21.0019 , unique identification number RFMEFI59420X0019). Maxim S. Molokeev, Anton S. Tarasov and Mikhail V. Rautskii acknowledge additional funding from Research Grant No. 075-15-2019-1886 from the Government of the Russian Federation. The subset research was performed in Research Resource Center “Natural Resource Management and Physico-Chemical Research.” The use of equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center « Krasnoyarsk Science Center SB RAS» is acknowledged
Аннотация: The crystal structures of the first-synthesized compound EuScCuS3 and previously known SrScCuS3 are refined by Rietveld analysis of X-ray powder diffraction data. The structures are found to belong to orthorhombic crystal system, space group Cmcm, structural type KZrCuS3, with a = 3.83413(3) Å, b = 12.8625(1) Å, c = 9.72654(8) Å (SrScCuS3) and a = 3.83066(8) Å, b = 12.7721(3) Å, c = 9.7297(2) Å (EuScCuS3). The temperatures and enthalpies of incongruent melting are the following: Тm = 1524.5 К, ΔHm = 21.6 kJ•mol−1 (SrScCuS3), and Тm = 1531.6 К, ΔHm = 26.1 kJ•mol−1 (EuScCuS3). Ab initio calculations of the crystal structure and phonon spectrum of the compounds were performed. The types and wavenumbers of fundamental modes were determined and the involvement of ions participating in the IR and Raman modes was assessed. The experimental IR and Raman spectra were interpreted. EuScCuS3 manifests a ferromagnetic transition at 6.4 K. The SrScCuS3 compound is diamagnetic. The optical band gaps were found to be 1.63 eV (EuScCuS3) and 2.24 eV (SrScCuS3) from the diffuse reflectance spectra. The latter value is in good agreement with that calculated by the DFT method. The narrower band gap of EuScCuS3 is explained by the presence of 4f-5d transition in Eu2+ ion that indicates a possibility to control the band gap of the chalcogenides by the inclusion of Eu. The activation energy of crystal structure defects, being the source of additional absorption in the NIR spectral range, was found to be 0.29 eV.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Peschanskii A. V., Glamazda, A. Yu., Gudim I. A.
Заглавие : Spectroscopic study of the TbAl3(BO3)4 single crystal: Raman and luminescence spectroscopy
Место публикации : Физ. низких температур. - 2020. - Т. 46, Вып. 12. - С.1437-1445. - ISSN 0132-6414. - ISSN 1816-0328(eISSN)
Примечания : Cited References: 20
Предметные рубрики: SCATTERING
GENERATION
ND
Аннотация: The vibrational and luminescence properties of the TbAl3(BO3)4 single crystal were studied in the temperature range of 5–300 K. Raman spectra of the single crystal revealed 5 of 7 A1 and all E phonon modes predicted by the group-theory analysis. The splitting energy between the LO and TO components of polar E phonons is determined. A group of intense bands associated with the 5D4 → 7F0 electronic transition was observed in the energy range of 14520–14680 cm−1 of the luminescence spectra. The intensity of these bands decreases upon heating. At the same time, the bands which can be assigned with 5D4 → 7F6, 5D4 → 7F5, and 5D4 → 7F4 transitions were revealed in luminescence spectra at room temperature. The intensity of these bands is comparable to the intensity of the Raman spectrum of TbAl3(BO3)4. The observation of luminescence from the 5D4 multiplet (20600–20750 cm−1) upon excitation at λexc = 632.8 nm (15803 cm−1) and λexc = 532 nm (18797 cm−1) indicates strong nonlinear properties of the studied crystal. The structure of the main 7F6 multiplet of Tb+3 in the TbAl3(BO3)4 single crystal has been studied at 5 K by Raman spectroscopy. The energies of the electronic levels of 7F6 and 5D4 multiplets were determined from the luminescence spectra measured at 300 K.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Немцев И. В., Шабанова О. В., Тамбасов, Игорь Анатольевич, Иваненко, Александр Анатольевич, Зырянов, Виктор Яковлевич
Заглавие : Опалоподобные структуры на основе субмикросфер полиметилметакрилата
Место публикации : Ученые зап. физ. фак-та МГУ. - 2020. - № 5. - Ст.2050101. - ISSN 2307-9665 (eISSN)
Примечания : Библиогр.: 18
Аннотация: В данной работе методом самосборки из частиц полиметилметакрилата субмикронного размера с полидисперсностью менее 5% изготовлены двумерные и трехмерные метаматериалы - коллоидные кристаллы. Морфологические особенности полученных образцов исследованы на сканирующем электронном микроскопе сверхвысокого разрешения FE-SEM Hitachi S-5500. Три различные области поверхности трехмерного опала исследованы с помощью спектроскопии отраженного света с угловым разрешением. Измерения спектров проводились в диапазоне 400-1250 нм. Вышеуказанными методами обнаружена высокоупорядоченная структура. Выявлено узкое гранулометрическое распределение частиц. Определены средний диаметр частиц, плотность упаковки, добротность и отражательная способность образцов. На основе экспериментальных спектров отражения выполнена аппроксимация зависимости максимальной длины волны отражательной способности от угла, используя модифицированный закон Брэгга-Снеллиуса. На основании данной зависимости определены длина волны максимума отражения при нормальном падении, диаметр частиц и плотность упаковки. Рассчитана длина волны центра фотонной запрещенной зоны для высокоупорядоченной поверхности при нормальном падении. Экспериментально измеренная полная ширина пика на полувысоте для наилучшего образца составила 70 нм, а добротность - 12.4. Рассчитанный коэффициент заполнения для высокоупорядоченного опала составил 87 %. Средний диаметр частиц, полученный при помощи аппроксимации спектров отражения, отлично согласуется со значениями, полученными с помощью электронной микроскопии. Наиболее интересный результат заключается в том, что отражающая способность поверхности при нормальном падении света может достигать 98 %, и эта величина зависит от коэффициента заполнения - плотности упаковки.In this paper, 2D and 3D metamaterials based on colloidal crystals are made from submicron-sized polymethylmethacrylate particles with a polydispersity of less than 5%. Morphological features of the obtained samples were studied using an ultra-highresolution FE-SEM Hitachi S-5500 scanning electron microscope. Three different surface areas of a three-dimensional opal was investigated using spectroscopy of the reflected light with the angular resolution. The spectra were measured in the range of 400- 1250 nm. The above methods revealed a highly ordered structure. A narrow particle size distribution was revealed. The average particle diameter, packing density, q-factor, and reflectivity of the samples were determined. Based on the experimental reflection spectra, the dependence of the maximum reflectivity wavelength on the angle is approximated using the modified Bragg-Snell law. Based on this dependence, the wavelength of the maximum reflection at normal incidence, the particle diameter, and the packing density are determined. The wavelength of the center of the photonic band gap is calculated for a highly ordered surface at normal incidence. The experimentally measured full width of the peak at half-height for the best sample was 70 nm, and the q factor was 12.4. The calculated filling factor for the highly ordered opal was 87%. The average particle diameter obtained by approximating the reflection spectra is in perfect agreement with the values obtained by electron microscopy. The most interesting result is that the reflectivity of the surface at normal light incidence can reach 98%, and this value depends on the filling factor the density of the package.
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12.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Samoshkina Yu. E., Edel'man I. S., Petrov D. A., Chou, Hsiung, Ovchinnikov S. G.
Заглавие : Visible MCD spectroscopy and nature of room temperature ferromagnetism in hydrogenated Сo - and (Co+Al) - doped ZnO films
Коллективы : Japanese-Mediterranean Workshop on Applied Electromagnetic Engineering for Magnetic, Superconducting, Multifunctional and Nanomaterials
Место публикации : Book of abstracts of The Eleventh Japanese-Mediterranean Workshop on Applied Electromagnetic Engineering for Magnetic, Superconducting, Multifunctional and Nanomaterials (JAPMED’11). - 2019. - P.121-122
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shetty P. P., Babu M., Maksimov D. N., Bingi J.
Заглавие : Thermo-optic refraction in MoS2 medium for “Normally on” all optical switch
Место публикации : Opt. Mater. - 2021. - Vol. 112. - Ст.110777. - ISSN 09253467 (ISSN), DOI 10.1016/j.optmat.2020.110777
Примечания : Cited References: 25. - Authors acknowledge the funding support from DST India under INT/RUS/RFBR/P-262
Аннотация: Two dimensional (2D) nanomaterials like Molybdenum disulfide (MoS2) have been drawing a lot of interest due to their excellent nonlinear optical response. In this research we study thermal lens formation in MoS2 nanoflakes dispersion using mode mismatched pump probe configuration. Observation of the pump and probe beam intensity patterns gave visual insights on time evolution of photothermal lens formation. Effect of MoS2 nanoflakes concentration on thermo-optic properties of dispersions were studied using thermal lens spectroscopy technique. Further, a thermo-optic refraction based technique to measure thermal lens size is proposed. Thermal lens region size increased with increase in pump power. The observed thermal lens modulation is applied to demonstrate ‘normally on’ all optical switch which showed excellent modulation of output beam signal by pump beam.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Korzhneva K. E., Bekenev V. L., Khyzhun O. Y., Goloshumova A. A., Tarasova A. Y., Molokeev M. S., Isaenko L. I., Kurus A. F.
Заглавие : Single crystal growth and the electronic structure of Rb2Na(NO3)3: Experiment and theory
Место публикации : J. Solid State Chem. - 2021. - Vol. 294. - Ст.121910. - ISSN 00224596 (ISSN), DOI 10.1016/j.jssc.2020.121910
Примечания : Cited References: 54. - This work was done on state assignment of IGM SB RAS, Ministry of Science and Higher Education of the Russian Federation; NSU BCH-2020-0036-4 (10988) (XRD analysis), and was supported by Russian Foundation for Basic Research (grants Nos. 18-32-00359 , 19-42-540012)
Аннотация: Rb2Na(NO3)3 crystals demonstrate nonlinear optical properties and can be used as a converter of laser radiation in the shortwave region. The crystals were grown in the present work by the Bridgman–Stockbarger method in a ratio of 75 wt%(RbNO3) and 25 wt%(NaNO3). After the growth, a transparent centimeter size single crystal (6 cm long) was obtained for the first time that is very important for its practical application. The unit cell volume of double Rb2Na(NO3)3 nitrate is intermediate between the cell volumes of simple rubidium and sodium nitrates, RbNO3 and NaNO3. Electronic structure of Rb2Na(NO3)3 was studied in the present work from both experimental and theoretical viewpoints. In particular, employing X-ray photoelectron spectroscopy, we have measured binding energies of core electrons and energy distribution of the electronic states within the valence band region of the Rb2Na(NO3)3 crystal and established rather big binding energies for N 1s and O 1s core-level electrons. The bombardment of middle-energy Ar+ ions induces transformation of some nitrogen atoms of the analyzing topmost layers of the Rb2Na(NO3)3 crystal surface from the NO3– group to the NO2– group. To explore in detail the filling of the valence band of Rb2Na(NO3)3 by electronic states associated with constituting atoms, we use first-principles calculations within a density functional theory (DFT) framework. The DFT calculations reveal that O 2p states are the principal contributors to the valence band bringing the main input in its upper portion. The theoretical finding is supported experimentally by fitting the X-ray photoelectron valence band spectrum and the X-ray emission O Kα band on the total energy scale. The conduction band bottom of Rb2Na(NO3)3 is composed by unoccupied O 2p and N 2p states in almost equal proportion.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Peschanskii A. V., Glamazda, A. Yu., Gudim I. A.
Заглавие : Spectroscopic study of the TbAl3(BO3)4 single crystal: Raman and luminescence spectroscopy
Место публикации : Low Temp. Phys. - 2020. - Vol. 46, Is. 12. - P.1223-1230. - ISSN 1063-777X, DOI 10.1063/10.0002478. - ISSN 1090-6517(eISSN)
Примечания : Cited References: 20
Предметные рубрики: SCATTERING
GENERATION
ND
Аннотация: The vibrational and luminescence properties of the TbAl3(BO3)4 single crystal were studied in the temperature range of 5–300 K. Raman spectra of the single crystal revealed 5 of 7 A1 and all E phonon modes predicted by the group-theory analysis. The splitting energy between the LO and TO components of polar E phonons is determined. A group of intense bands associated with the 5D4 → 7F0 electronic transition was observed in the energy range of 14520–14680 cm−1 of the luminescence spectra. The intensity of these bands decreases upon heating. At the same time, the bands which can be assigned with 5D4 → 7F6, 5D4 → 7F5, and 5D4 → 7F4 transitions were revealed in luminescence spectra at room temperature. The intensity of these bands is comparable to the intensity of the Raman spectrum of TbAl3(BO3)4. The observation of luminescence from the 5D4 multiplet (20600–20750 cm−1) upon excitation at λexc = 632.8 nm (15803 cm−1) and λexc = 532 nm (18797 cm−1) indicates strong nonlinear properties of the studied crystal. The structure of the main 7F6 multiplet of Tb+3 in the TbAl3(BO3)4 single crystal has been studied at 5 K by Raman spectroscopy. The energies of the electronic levels of 7F6 and 5D4 multiplets were determined from the luminescence spectra measured at 300 K.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Romanova O. B., Aplesnin S. S., Udod L. V.
Заглавие : Electronic Structure Change at Cationic Substitition of Manganese Sulfide by Elements with Variable Valence
Место публикации : Sib. J. Sci. Technol. - 2020. - Vol. 21, Is. 3. - P.441-450. - ISSN 2587-6066, DOI 10.31772/2587-6066-2020-21-3-441-450; \b Сибирский журнал науки и технологий
Примечания : Cited References: 27. - The reported study was funded by RFBR and BRFBR, project number 20-00005 Bel_a
Аннотация: Cation-substituted solid solutions YbxMn1-xS were prepared by the melt method from polycristalline sulfide powders. The synthesized samples are antiferromagnetic semiconductors and, according to the results of X-ray structural analysis, have an FCC structure of the NaCl type. Structural, electrical, optical, and acoustic properties of the chalcogenide system YbxMn1-xS were studied in the temperature range 80 - 500 K. The effect of variable valence elements on the electronic structure of cationic substitution of manganese sulfide has been studied. The change in the electronic structure in the YbxMn1-xS system occurs due to the electron-phonon interaction. Samples with variable valence have anomalous compressibility, which is confirmed by the data on the thermal expansion coefficient and the change in the attenuation coefficient. As a result of inelastic interaction with d- electrons, the density of states at the Fermi level changes, this is reflected in the temperature dependence of the conductivity. The positions of the f-level and two electronic transitions were determined from the IR spectra. A zone of temperatures and concentrations was found, where a correlation of structural, electrical, optical and acoustic properties is observed. To explain the experimantal results, the electronic structure of the semiconductor is considered and a model is proposed that qualitatively describes the experiment.Методом расплава из поликристаллических порошков сульфидов приготовлены катион замещенные твердые растворы YbxMn1-xS. Синтезированные образцы являются антиферромагнитными полупроводниками и согласно результатам рентгеноструктурного анализа имеют ГЦК структуру типа NaCl. Проведены исследования структурных, электрических, оптических и акустических свойств халькогенидной системы YbxMn1-xS в интервале температур 80 - 500 К. Исследовано влияние на электронную структуру элементов переменной валентности при катионном замещении сульфида марганца. Изменение электронной структуры в системе YbxMn1-xS происходит за счет электрон-фононного взаимодействия. Образцы с переменной валентностью обладают аномальной сжимаемостью, что подтверждается данными коэффициента теплового расширения и изменением коэффициента затухания. В результате неупругого взаимодействия с d-электронами меняется плотность состояний на уровне Ферми, что отражается на температурной зависимости проводимости. Из ИК спектров определены положения f-уровня и два электронных перехода. Обнаружена область температур и концентраций, где наблюдается корреляция структурных, электрических, оптических и акустических свойств. Для объяснения экспериментальных результатов рассмотрена электронная структура полупроводника и предложена модель, качественно описывающая эксперимент.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Popova M. N., Chukalina E. P., Erofeev D. S., Jablunovskis A., Gudim I. A., Malkin B. Z.
Заглавие : High-resolution optical spectroscopy and modeling of spectral and magnetic properties of multiferroic ErFe3(BO3)4
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [19-12-00413]
Место публикации : Phys. Rev. B. - 2020. - Vol. 101, Is. 20. - Ст.205108. - ISSN 2469-9950, DOI 10.1103/PhysRevB.101.205108. - ISSN 2469-9969(eISSN)
Примечания : Cited References: 38. - Financial support of the Russian Science Foundation under Grant No. 19-12-00413 is acknowledged.
Предметные рубрики: F-F TRANSITIONS
ENERGY-LEVELS
ER3+ IONS
GROWTH
Аннотация: We carried out the high-resolution broadband temperature-dependent polarized optical spectroscopy and theoretical studies of ErFe3(BO3)4 single crystals in the paramagnetic and antiferromagnetic (T˂TN=39K) phases. On the basis of the experimentally determined 45 crystal-field (CF) levels of Er3+ ions at sites with the C2 point symmetry, CF calculations were performed, a set of physically grounded CF parameters was obtained and used to model the temperature dependences of the Er magnetic moments measured in neutron-scattering experiments, as well as the magnetic susceptibility and magnetization of the compound; the contributions of the quasi-one-dimensional iron magnetic subsystem were calculated in the frame of the previously developed self-consistent four-particle cluster model. The modeling strongly supports an easy-plane collinear structure of iron magnetic moments and excludes earlier proposed additional magnetic phase.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Loiko V. A., Konkolovich A. V., Miskevich A. A., Krakhalev M. N., Prishchepa O. O., Zyryanov V. Ya.
Заглавие : Small-angle scattering and radiation polarization by a stretched polymer film with nematic liquid crystal droplets having a single-domain structure
Коллективы : Belarusian Republican Foundation for Fundamental Research [F18RA-003]; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of Krasnoyarsk krai; Krasnoyarsk Krai Foundation of Science [18-42-243006]
Место публикации : Opt. Spectrosc. - 2020. - Vol. 128, Is. 3. - P.331-338. - ISSN 0030-400X, DOI 10.1134/S0030400X20030121. - ISSN 1562-6911(eISSN)
Примечания : Cited References: 24. - This work was carried out within the framework of the agreement on interacademic collaboration between the National Academy of Sciences of Belarus and Siberian Branch of the Russian Academy of Sciences. It was supported by the Belarusian Republican Foundation for Fundamental Research (project no. F18RA-003). M.N. Krakhalev acknowledges the support of the Russian Foundation for Basic Research, the Government of Krasnoyarsk krai, and Krasnoyarsk Krai Foundation of Science (grant no. 18-42-243006).
Предметные рубрики: IONIC MODIFICATION
LIGHT
Аннотация: The coefficient of directed transmittance of a stretched polymer-dispersed liquid crystal film with a defect-free single-domain liquid crystal droplet structure formed by a stretched surfactant-doped film and the polarization degree of forward-transmitted light in the visible and near-infrared spectrum ranges are studied. Results are presented for the 5CB, E7, and E44 nematic liquid crystals. Dependences of the transmission coefficient and polarizing ability of the film on the photodetector field of view are studied. Relationships allowing one to determine film parameters at which the transmission coefficient and polarizing ability of the films simultaneously reach values close to limit ones (0.5 and ±1.0, respectively) are obtained in the Foldy–Twersky and anomalous diffraction approximations.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Plotnikova A. A., Bragin V. I., Knyazev Yu. V.
Заглавие : Structural Characteristics and Processability of Sphalerite in Lead-Zinc Ore of the Gorevka Deposit
Место публикации : J. Min. Sci. - 2019. - Vol. 55, Is. 6. - P.995-1006. - ISSN 1062-7391, DOI 10.1134/S1062739119066381. - ISSN 1573-8736(eISSN)
Примечания : Cited References: 33
Аннотация: The theoretical and experimental substantiation of the behavior of ferrous sphalerite in magnetic separation is given in terms of the Gorevka deposit ore. In sphalerite of this deposit, the content of isomorphous iron ranges as 4-9%. The Mossbauer spectroscopy showed the singlet and two doublet lines of iron, demonstrating separate arrays of iron atoms in sphalerite lattice, with formation of Fe-Fe pairs and clusters of three or more iron atoms. It is found that distribution of iron in sphalerite into three forms coincides for magnetic and nonmagnetic products of zinc concentrate separation. It is determined that magnetic separation undivides sphalerite grains by the isomorphous iron content but is governed by the genetic features of the deposit formation-association of sphalerite with magnetic minerals (pyrrhotine and siderite) and the absence of such associations in galena.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kremneva A. M., Fedorov A. V., Bulavchenko O. A., Knyazev Yu. V., Saraev A. A., Yakovlev V. A., Kaichev V. V.
Заглавие : Effect of calcination temperature on activity of Fe2O3-Al2O3 nanocomposite catalysts in CO oxidation
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [17-73-20157]; National center of investigation of catalysts" at Boreskov Institute of Catalysis
Место публикации : Catal. Lett. - 2020. - Vol. 150. - P.3377-3385. - ISSN 1011-372X, DOI 10.1007/s10562-020-03250-8. - ISSN 1572-879X(eISSN)
Примечания : Cited References: 31. - This work was supported by the Russian Science Foundation (Grant No. 17-73-20157). The experiments were performed using facilities of the shared research center "National center of investigation of catalysts" at Boreskov Institute of Catalysis. The authors thank A.Yu. Gladky for the TPR measurements and Z.S. Vinokurov for the XRD measurements.
Предметные рубрики: MOSSBAUER
SPECTROSCOPY
CHEMISTRY
IRON
XPS
ADSORPTION
OXYGEN
FE
Аннотация: Nanocomposite Fe–Al oxide catalysts were prepared by the melting of iron and aluminum nitrates with the subsequent calcination in air at different temperatures. It was found that the catalysts calcined at 450 °C are more active in the oxidation of CO than the catalysts calcined at 700 °C. X-ray diffraction and X-ray photoelectron spectroscopy showed that all the catalysts consist of hematite, α-Fe2O3 nanoparticles, and Al2O3 in an amorphous state. Iron oxide is the active component, which provides the oxidation of CO, while alumina is a texture promoter. The increase in the calcination temperature leads to a minor increase in the average size of hematite nanoparticles and an insignificant decrease in the specific surface area. Kinetic measurements showed that the oxidation of CO over the Fe–Al catalysts calcined at 450 and 700 °C proceeds with the activation energy of 61–69 and 91 kJ/mol, respectively. This means that the low-temperature and high-temperature catalysts contain different active species. Temperature-programmed reduction with CO indicated that the decrease in the calcination temperature improves the reducibility of the Fe-Al nanocomposites. According to 57Fe Mössbauer spectroscopy, the low-temperature catalysts contain hydrated iron oxides (acagenite and ferrihydrite) and a significant amount of highly defective hematite, which is absent in the high-temperature catalyst. These species can provide the enhanced activity of the low-temperature catalysts in the oxidation of CO.
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