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KRUSTALEV, B. P.
EXCHANGE INTERACTIONS IN SUPERPARAMAGNETIC NANOCLUSTER FILMS FE-SIO / B. P. KRUSTALEV, A. D. BALAEV, V. M. SOSNIN // Solid State Commun. - 1995. - Vol. 95, Is. 5. - P. 271-275, DOI 10.1016/0038-1098(95)00264-2. - Cited References: 9 . - ISSN 0038-1098

РУБ Physics, Condensed Matter

Кл.слова (ненормированные):
NANOSTRUCTURES -- THIN FILMS -- EXCHANGE AND SUPEREXCHANGE
Аннотация: The magnetic properties of superparamagnetic films Fe-SiO have been investigated. It has been shown that a proper consideration of intra- and intercluster interactions describes well the magnetic behavior of the films. Their main parameters have been determined. On the basis of a proposed cluster model, the decrease of the effective magnetic moment per one iron atom is explained.

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Доп.точки доступа:
BALAEV, A. D.; Балаев, Александр Дмитриевич; SOSNIN, V. M.; Соснин, Виктор Михайлович
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Superparamagnetic and ferrimagnetic nanoparticles in glass matrix / I. S. Edelman [et al.] // Physica B. - 2001. - Vol. 301, Is. 3-4. - P. 203-211, DOI 10.1016/S0921-4526(01)00274-5. - Cited References: 9 . - ISSN 0921-4526

РУБ Physics, Condensed Matter
Рубрики:
MAGNETIC-PROPERTIES
PARTICLES
FILMS
Кл.слова (ненормированные):
magnetic nanoparticles -- Faraday rotation -- Faraday rotation -- Magnetic nanoparticles -- Crystal structure -- Faraday effect -- Ferrimagnetic materials -- Glass -- Particle size analysis -- Superparamagnetism -- X ray diffraction analysis -- Amorphous glass matrices -- Faraday rotations -- Nanostructured materials
Аннотация: Faraday rotation (FR) spectral, field, and temperature dependencies in oxide glasses with small additions of paramagnetic elements are investigated. Formation of ferrite nanoparticles in amorphous glass matrices is revealed by X-ray diffraction. Particles have crystal structure similar to spinel structure, their dimensions are about 10-24 nm. The FR field dependencies are typical for ferrimagnetic or superparamagnetic substances depending on particle size. Strong FR increase at the samples cooling (more than twice for some samples) in the temperature interval 105-273 K is observed. (C) 2001 Elsevier Science B.V. All rights reserved.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
SI Vavilov State Opt Inst, St Petersburg 193117, Russia
ИФ СО РАН
L.V. Kirensky Institute of Physics, Russian Academy of Sciences-SB, Krasnoyarsk 660036, Russian Federation
S.I. Vavilov Optical State Institute, St. Peterburg 193117, Russian Federation

Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Ivantsov, R.; Vasiliev, A.; Stepanov, S.; Kornilova, E.; Zarubina, T.
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Magnetic interaction between superparamagnetic particles in nanogranular cobalt films / R. S. Iskhakov [et al.] // Tech. Phys. Lett. - 2004. - Vol. 30, Is. 8. - P. 687-689, DOI 10.1134/1.1792314. - Cited References: 12 . - ISSN 1063-7850

РУБ Physics, Applied
Рубрики:
SINGLE-DOMAIN PARTICLES
BEHAVIOR
Аннотация: A system of cobalt nanoparticles exhibits a transition from the superparamagnetic state into the state with cooperative magnetic ordering caused by the magnetic interaction between Co particles. It is shown that this transition can be used for obtaining nanogranular materials possessing soft magnetic properties at a large electric resistivity. (C) 2004 MAIK "Nauka/Interperiodica".

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Держатели документа:
Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Iskhakov, R. S.; Исхаков, Рауф Садыкович; Frolov, G. I.; Фролов, Георгий Иванович; Zhigalov, V. S.; Жигалов, Виктор Степанович; Prokof'ev, D. E.
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From superparamagnetic to magnetically ordered state in Co-Sm-О nanocrystalline films [Text] / R. S. Iskhakov, G. I. FrolovZhigalov V.S. [et al.] // Physics of Metals and Metallogra phy. - 2006. - Vol. 102, Suppl. 1. - P. S61-S63DOI 10.1134/S0031918X06140158. - Библиогр.: 11
Аннотация: Transition of the system of Co nanoparticles from a superparamagnetic state into the region of cooperative magnetic ordering caused by effects of magnetic interaction between particles has been analyzed. The possibility of the preparation of materials with soft magnetic properties and higher electrical resistivity was shown.

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Держатели документа:
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036 Russia

Доп.точки доступа:
Iskhakov, R. S.; Исхаков, Рауф Садыкович; Frolov, G. I.; Фролов, Георгий Иванович; Zhigalov, V. S.; Жигалов, Виктор Степанович; Prokof'ev, D. E.; Burkova, L. V.; Буркова, Людмила Викторовна
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Formation and evolution of magnetic nanoparticles in borate glass simultaneously doped with Fe and Mn oxides / J. . Kliava [et al.] // J. Appl. Phys. - 2008. - Vol. 104, Is. 10. - Ст. 103917, DOI 10.1063/1.3021289. - Cited References: 37. - A financial support from the Russian Foundation for Basic Research (RFBR)-CNRS (Grant No. 07-02-92174) is highly appreciated. R. Ivantsov is grateful to the Russian Science Support Foundation. Y. Yeshurun acknowledges the support of the Israel Scienc Foundation (ISF). . - ISSN 0021-8979

РУБ Physics, Applied
Рубрики:
COBALT FERRITE PARTICLES
   SUPERPARAMAGNETIC RESONANCE
   GAMMA-FE2O3 NANOPARTICLES
   MATRIX
   SIZE
   SYSTEMS
Кл.слова (ненормированные):
aluminium compounds -- borate glasses -- coercive force -- Faraday effect -- heat treatment -- iron compounds -- magnetic hysteresis -- magnetic particles -- magnetic susceptibility -- manganese compounds -- Mossbauer effect -- nanoparticles -- paramagnetic materials -- potassium compounds -- remanence -- superparamagnetism -- transmission electron microscopy -- X-ray chemical analysis -- Atomic spectroscopy -- Auger electron spectroscopy -- Crystal structure -- Electric relays -- Electronic medical equipment -- Ferrite -- Ferrites -- Glass -- Heat treatment -- Hysteresis -- Hysteresis loops -- Magnetic properties -- Magnetic resonance measurement -- Magnetic susceptibility -- Magnetism -- Manganese -- Manganese compounds -- Molybdenum -- Nanoparticles -- Optical properties -- Ozone water treatment -- Polydispersity -- Superparamagnetism -- Borate glasses -- Concentration ratios -- Electron magnetic resonances -- Emr spectrums -- Experimental techniques -- Faraday rotations -- Glass compositions -- Glass matrixes -- Glass preparations -- Magnetic measurements -- Magnetic nano particles -- Magnetic orders -- Magnetically ordered systems -- Magneto-optical properties -- Manganese ferrites -- Mean diameters -- Mn oxides -- Phase states -- Polydisperse nanoparticles -- Remnant magnetizations -- Ssbauer spectroscopies -- Superparamagnetic -- Superparamagnetic states -- Thermal treatments -- Variable temperatures -- Magnetic materials
Аннотация: Evolution of the phase state of paramagnetic additions at various stages of synthesis and subsequent thermal treatment of glasses of the system Al(2)O(3)-K(2)O-B(2)O(3) simultaneously doped with Fe(2)O(3) and MnO is studied by means of a combination of experimental techniques: Faraday rotation (FR), electron magnetic resonance (EMR), transmission electron microscopy (TEM), Mossbauer spectroscopy, and magnetic measurements. Both FR and EMR show that magnetically ordered clusters occur already at the first stage of the glass preparation. In particular, for the ratio of the Fe and Mn oxides in the charge close to 3:2, fine magnetic nanoparticles are formed with characteristics similar to those of manganese ferrite. By computer simulating the EMR spectra at variable temperatures, a superparamagnetic nature of these nanoparticles is confirmed and their mean diameter is estimated as approximately 3.2 nm. In the thermally treated glasses larger magnetic nanoparticles are formed, giving rise to FR spectra, characteristic of magnetically ordered systems, and the EMR spectra different from those in as-prepared glasses but also showing superparamagnetic narrowing. The Mossbauer spectroscopy corroborates the manganese ferrite structure of the nanoparticles and indicates their coexistence in the ferrimagnetic and superparamagnetic states. The TEM shows the presence of polydisperse nanoparticles on the background of the glass matrix, and electron diffraction of a selected region containing larger particles indicates a crystal structure close to that of MnFe(2)O(4). Energy-dispersive atomic x-ray spectra confirm that the major part of Fe and Mn introduced to the glass composition is gathered in the particles, with the concentration ratio close to 2:1, characteristic of bulk MnFe(2)O(4). Magnetic hysteresis loops of samples subjected to an additional thermal treatment demonstrate a strong increase in the coercive force, remnant magnetization, and high-field magnetic susceptibility with temperature decrease. The consistent results obtained using various techniques demonstrate that the formation of nanoparticles with characteristics close to those of MnFe(2)O(4) confers to these glasses magnetic and magneto-optical properties typical of substances possessing magnetic order.

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Держатели документа:
[Kliava, J.] Univ Bordeaux 1, CNRS, UMR 5798, CPMOH, F-33405 Talence, France
[Edelman, I.
Ivanova, O.
Ivantsov, R.
Bayukov, O.
Petrakovskaja, E.
Stepanov, S.] RAS, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Zaikovskiy, V.] RAS, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
[Bruckental, I.
Yeshurun, Y.] Bar Ilan Univ, Dept Phys, IL-52900 Ramat Gan, Israel
[Stepanov, S.] SI Vavilov State Opt Inst, St Petersburg 199034, Russia
ИФ СО РАН
CPMOH, Universit? Bordeaux, 1-CNRS UMR 5798, 33405 Talence Cedex, France
Kirensky Institute of Physics, Siberian Branch of RAS, 660036 Krasnoyarsk, Russian Federation
Boreskov Institute of Catalysis, Siberian Branch, RAS, 630090 Novosibirsk, Russian Federation
Department of Physics, Bar-Ilan University, Ramat-Gan 52900, Israel
S. I. Vavilov State Optical Institute, St. Petersburg 199034, Russian Federation

Доп.точки доступа:
Kliava, J.; Edelman, I. S.; Эдельман, Ирина Самсоновна; Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Bayukov, O. A.; Баюков, Олег Артемьевич; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна; Zaikovskiy, V.; Bruckental, I.; Yeshurun, Y.; Stepanov, S.
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Investigation of ferromagnetic and superparamagnetic particles of ball milled cobalt-copper alloys / Iskhakov R.S., Denisova E.A., Kuzovnikova L.A., Komogortsev S.V. // Moscow Int. Symp. on Magnet. (MISM-2008) : June 20-25, 2008, Moscow : book of abstract. - 2008. - Ст. 25PO-13-29. - p. 769. - This work was supported by the RFBR and KRSF, project no.07-03-96808 and National Science Fund (2008, PhD RAS)

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Доп.точки доступа:
Iskhakov, R. S.; Исхаков, Рауф Садыкович; Denisova, E. A.; Денисова, Елена, Александровна; Kuzovnikova, L. A.; Кузовникова, Людмила, Александровна; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Moscow International Symposium on Magnetism(4 ; 2008 ; Jun. ; Moscow); Московский государственный университет им. М.В. Ломоносова; Российский фонд фундаментальных исследований
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Edelman, I.
Oxide glasses with magnetic nanoparticles: transparent magnets (Faraday rotation and electron magnetic resonance studies) / I. . Edelman, J. . Kliava // Phys. Status Solidi B. - 2009. - Vol. 246, Is. 10. - P. 2216-2231, DOI 10.1002/pssb.200945169. - Cited References: 87. - This work is supported in part by RFBR-CNRS joint project, grant No 07-02-92174. We are grateful to E. Petrakovskaja and O. Ivanova for measuring and discussing, respectively, the EMR spectra in thermally treated samples and the FR spectral and magnetic field dependences. . - ISSN 0370-1972

РУБ Physics, Condensed Matter
Рубрики:
SPIN-HAMILTONIAN PARAMETERS
   SINGLE-DOMAIN PARTICLES
   SUPERPARAMAGNETIC RESONANCE
   CRYSTALLIZATION BEHAVIOR
   FERRIMAGNETIC RESONANCE
   PARAMAGNETIC-RESONANCE
   TEMPERATURE-DEPENDENCE
   COMPUTER-SIMULATIONS
   FINE PARTICLES
   BORATE GLASSES
Аннотация: In the first part of this paper we outline the state of the art in the field of magnetic nanoparticles in oxide glasses. We describe the theoretical background of two complementary techniques used for the studies of the state of paramagnetic ions, clusters and magnetic particles in a diamagnetic matrix, viz., magnetooptical Faraday rotation (FR) and electron magnetic resonance (EMIR) and we overview previous results obtained with these techniques for several glass systems. In the second part, we highlight the case of potassium-alumina-borate glasses - a glassy system where doping with paramagnetic oxides results in formation of magnetic particles at very low contents of paramagnetic additions: Fe(2)O(3) and MnO. In the special case when the ratio of the iron and manganese oxides in the charge is 3/2, magnetic nanoparticles with characteristics close to those of manganese ferrite are formed already at the first stage of the glass preparation. After thermal treatment all glasses show FR and EMR spectra attesting to the presence of superparamagnetic nanoparticles, characterized by relatively broad size and shape distributions. The formation of magnetic nanoparticles confers to these glasses magnetic and magnetooptical properties typical of magnetically ordered substances. At the same time, the glasses remain transparent in a part of the visible and near infrared spectral range and display a high FR value. Such properties make them particularly interesting for use as new media for various magneto-optical devices. (C) 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

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Держатели документа:
[Edelman, Irina] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Kliava, Janis] Univ Bordeaux 1, Ctr Phys Mol Opt & Hertzienne, CNRS, UMR 5798, F-33405 Talence, France
ИФ СО РАН
L.V. Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 38, 660036 Krasnoyarsk, Russian Federation
Centre de Physique Moleculaire Optique et Hertzienne, Universite Bordeaux1-CNRS, UMR 5798, 351 cours de la Liberation, 33405 Talence cedex, France

Доп.точки доступа:
Kliava, J.; RFBR-CNRS [07-02-92174]
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Transport properties of FeSi with cobalt impurities / G. Y. Yurkin [et al.] // TRENDS IN MAGNETISM. - 2011. - Vol. 168-169. - P493-496, DOI 10.4028/www.scientific.net/SSP.168-169.493 . - ISSN 1012-0394
Кл.слова (ненормированные):
iron monosilicide -- kondo effect -- magnetization -- resistivity -- spindependent scattering -- superparamagnetic cluster -- cobalt -- crystals -- electric resistance -- electron energy loss spectroscopy -- kondo effect -- magnetic field effects -- magnetic properties -- magnetization -- magnetoresistance -- scattering -- superparamagnetism -- transport properties -- cobalt -- electric conductivity -- electron scattering -- impurities -- kondo effect -- magnetism -- magnetization -- experimental investigations -- kondo models -- magnetoresistance properties -- resistivity -- si crystals -- spin dependent scattering -- superparamagnetic clusters -- crystal impurities -- crystal impurities
Аннотация: The results of experimental investigations of Fe1-xCo xSi crystals in the impurity limit are presented in this article. We made an attempt to study changes of magnetic properties and conductivity in mixed Fe1-xCoxSi crystals in the impurity limit. Magnetoresistance properties are well described in the framework of Kondo model. The presence of Co-subsystem leads to the occurrence of spin-dependent channel in electron scattering conduction.

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Держатели документа:
Kirensky Institute of Physics, SB, RAS, 660036, Krasnoyarsk, Russian Federation
Siberian Federal University, 660041, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Yurkin, G. Yu.; Юркин, Глеб Юрьевич; Patrin, G. S.; Патрин, Геннадий Семёнович; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Beletsky, V. V.
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Magnetic nanoparticles formed in glasses co-doped with iron and larger radius elements / I. S. Edelman [et al.] // J. Appl. Phys. - 2012. - Vol. 112, Is. 8. - Ст. 84331. - P. , DOI 10.1063/1.4759244. - Cited References: 65. - This work was partly supported by the Russian Foundation for Basic Research, Grant Nos. 07-02-92174 RFBR-CNRS and 11-02-00972, and President of Russia Federation Grant No NSh 1044.2012.2. A. Artemenko acknowledges financial support from the Marie Curie International Incoming Fellowship within the 7th European Community Framework Programme (EPREXINA, GA 255662). The synchrotron measurements were supported via the Russian federal Contract No. 16.552.11.7003. The authors thank K. P. Polyakova for the preparation of thin films. . - ISSN 0021-8979

РУБ Physics, Applied
Рубрики:
SUPERPARAMAGNETIC RESONANCE
   FERROMAGNETIC-RESONANCE
   TEMPERATURE-DEPENDENCE
   FERRITE NANOPARTICLES
   OXIDE NANOPARTICLES
   FARADAY-ROTATION
   CERAMICS
   ANISOTROPY
   PARTICLES
   SPECTRA
Аннотация: A new type of nanoparticle-containing glasses based on borate glasses co-doped with low contents of iron and larger radius elements, Dy, Tb, Gd, Ho, Er, Y, and Bi, is studied. Heat treatment of these glasses results in formation of magnetic nanoparticles, radically changing their physical properties. Transmission electron microscopy and synchrotron radiation-based techniques: x-ray diffraction, extended x-ray absorption fine structure, x-ray absorption near-edge structure, and small-angle x-ray scattering, show a broad distribution of nanoparticle sizes with characteristics depending on the treatment regime; a crystalline structure of these nanoparticles is detected in heat treated samples. Magnetic circular dichroism (MCD) studies of samples subjected to heat treatment as well as of maghemite, magnetite, and iron garnet allow to unambiguously assign the nanoparticle structure to maghemite, independently of co-dopant nature and of heat treatment regime used. Different features observed in the MCD spectra are related to different electron transitions in Fe3+ ions gathered in the nanoparticles. The static magnetization in heat treated samples has non-linear dependence on the magnetizing field with hysteresis. Zero-field cooled magnetization curves show that at higher temperatures the nanoparticles occur in superparamagnetic state with blocking temperatures above 100 K. Below ca. 20 K, a considerable contribution to both zero field-cooled and field-cooled magnetizations occurs from diluted paramagnetic ions. Variable-temperature electron magnetic resonance (EMR) studies unambiguously show that in as-prepared glasses paramagnetic ions are in diluted state and confirm the formation of magnetic nanoparticles already at earlier stages of heat treatment. Computer simulations of the EMR spectra corroborate the broad distribution of nanoparticle sizes found by "direct" techniques as well as superparamagnetic nanoparticle behaviour demonstrated in the magnetization studies. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4759244]

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Держатели документа:
[Edelman, I.
Ivanova, O.
Ivantsov, R.
Velikanov, D.
Zabluda, V.] LV Kirensky Inst Phys SB RAS, Krasnoyarsk 660036, Russia
[Zubavichus, Y.
Veligzhanin, A.] NRC Kurchatov Inst, Moscow 123182, Russia
[Zaikovskiy, V.] Siberian Branch RAS, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
[Stepanov, S.] SI Vavilov State Opt Inst, St Petersburg, Russia
[Artemenko, A.] CNRS, ICMCB, UPR 9048, F-33608 Pessac, France
[Curely, J.
Kliava, J.] Univ Bordeaux 1, CNRS, UMR 5798, LOMA, F-33405 Talence, France

Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Ivanova, O. S.; Иванова, Оксана Станиславовна; Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Zabluda, V. N.; Заблуда, Владимир Николаевич; Zubavichus, Y.; Veligzhanin, A. A.; Zaikovskiy, V. I.; Stepanov, S.; Artemenko, A.; Curely, J.; Kliava, J.
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10.

Гуревич, Юрий Леонидович.
Самосборка суперпарамагнитных наночастиц ферригидрита / Ю. Л. Гуревич, Ю. И. Маньков, Р. Г. Хлебопрос // Доклады Академии наук. - 2013. - Т. 453, № 3. - С. 268-271DOI 10.7868/S0869565213330098

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Переводная версия Self-assembly of superparamagnetic ferrihydrite nanoparticles. - [Б. м. : б. и.]

Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Маньков, Юрий Иннокентьевич; Man'kov, Yu.I.; Хлебопрос, Рэм Григорьевич; Khlebopros, R. G.
}
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11.

Gurevich, Y. L.
Self-assembly of superparamagnetic ferrihydrite nanoparticles / Y. L. Gurevich, Yu. I. Mankov, R. G. Khlebopros // Dokl. Phys. - 2013. - Vol. 58, Is. 11. - P. 478-481, DOI 10.1134/S1028335813110104. - Cited References: 15. - This work was supported by the Russian Foundation for Basic Research, project nos. 08-08-00427_a and 10-08-00278_a, and by the Siberian Branch, Russian Academy of Sciences, Integration project no. 21. . - ISSN 1028-3358

РУБ Mechanics + Physics, Multidisciplinary
Рубрики:
CHAINS
CLUSTERS
Аннотация: A study was conducted to estimate the possibility of formation of chains of superparamagnetic nanoparticles of iron oxyhydroxides synthesized in a bacteria culture. The self-assembly of biogenic nanoparticles distinguished by low values of magnetization and small sizes is assumed to proceed due to the forces of magnetic dipole dipole interaction as an initial mechanism of aggregation and exchange-interaction forces, which provide the stability of chains. The microphotographs demonstrate the self-assembly of anisotropic cobalt-doped ferrihydrite nanoparticles in aggregates of ellipsoidal shape with sizes of about 550 × 300 nm and a platelike shape of 50-100 nm thick. The aggregates, in turn, are combined from blocks, which include a restricted number of nanoparticles of about 5 nm in diameter and have the shape of rods of 50-100 × 12 nm in size. The energy of degaussing fields of chains is reasonably high, which forces them to form two and three dimensional structures in which the compensation of such fields is provided.

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Публикация на русском языке Самосборка суперпарамагнитных наночастиц ферригидрита. - [S. l. : s. n.]

Держатели документа:
Russian Acad Sci, Siberian Branch, Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia
Russian Acad Sci, Kirenskii Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia;

Доп.точки доступа:
Mankov, Yu.I.; Маньков, Юрий Иннокентьевич; Khlebopros, R. G.; Хлебопрос, Рэм Григорьевич; Russian Foundation for Basic Research [08-08-00427_a, 10-08-00278_a]; Siberian Branch, Russian Academy of Sciences, Integration project [21]
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12.

Structural and magnetic resonance investigations of CuCr2S4 nanoclusters and nanocrystals / A. I. Pankrats [et al.] // J. Appl. Phys. - 2014. - Vol. 116, Is. 5. - Ст. 54302, DOI 10.1063/1.4891993. - Cited References: 26. - The work was supported by a Grant CRDF-SB RAS "New Nano-size and Layered Cu-containing Sulphides for Electronics" RUP1-7054-KR-11, N 16854. S.M.Z. acknowledges support from the Ministry of education and science of the Russian Federation (in the framework of the state assignment for SFU for 2014). . - ISSN 0021-8979. - ISSN 1089-7550

РУБ Physics, Applied
Рубрики:
SUPERPARAMAGNETIC RESONANCE
   NANOPARTICLES
   GLASS
   BIOMEDICINE
   PARTICLES
   SPINELS
Аннотация: Nanoclusters and nanocrystals of the room temperature magnetic spinel CuCr2S4 synthesized using a facile solution-based method have been examined by transmission electron microscopy, magnetic measurements, and magnetic resonance over a wide frequency range 9.6–80 GHz and at temperatures down to 4.2 K. Decreasing of the resonance field and broadening of the resonance lines below 50 K for both samples are due to the freezing of magnetic moments of nanocubes and nanocrystalline particles constituting nanoclusters. The effective fields of averaged magnetic anisotropy (HA)≌2.4 kOe are similar for both nanopowder samples as estimated from resonance measurements at T = 4.2 K. An additional blocking temperature T b ≅ 300 K appears in nanoclusters due to freezing of the magnetic moment of the entire cluster as a whole. Below this blocking temperature, the magnetic dipolar field acting in boundary areas of interacting constituent nanocrystals is responsible for the additional low-field resonance line observed in the resonance spectra of nanoclusters at X-band.

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Держатели документа:
SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Univ Alabama, MINT Ctr, Tuscaloosa, AL 35487 USA

Доп.точки доступа:
Pankrats, A. I.; Панкрац, Анатолий Иванович; Vorotynov, A. M.; Воротынов, Александр Михайлович; Tugarinov, V. I.; Тугаринов, Василий Иванович; Zharkov, S. M.; Жарков, Сергей Михайлович; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Abramova, G. M.; Абрамова, Галина Михайловна; Zeer, G. M.; Ramasamy, K.; Gupta, A.; Grant CRDF-SB RAS "New Nano-size and Layered Cu-containing Sulphides for Electronics" [RUP1-7054-KR-11, 16854]; Ministry of education and science of the Russian Federation
}
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13.

Magnetic nanoparticles in borate glasses: Identification and sizing / I. S. Edelman [et al.] // International Conference on Optimization of Electrical and Electronic Equipment (OPTIM 2014) : IEEE Computer Society, 2014. - P. 95-104, DOI 10.1109/OPTIM.2014.6850939. - Cited References: 60 . - ISBN 978-1-4799-5183-3
Рубрики:
Engineering, Electrical and Electronic
Кл.слова (ненормированные):
SUPERPARAMAGNETIC RESONANCE -- FERROMAGNETIC-RESONANCE -- FERRITE NANOPARTICLES -- OXIDE NANOPARTICLES -- FARADAY-ROTATION -- CERAMICS -- IRON -- CRYSTALLIZATION -- ANISOTROPY -- PARTICLES
Аннотация: Heat treatment of borate glasses co-doped with low contents of iron and larger radius elements: Dy, Tb, Gd, Ho, Er, Y and Bi results in formation of magnetic nanoparticles, radically changing their physical properties. Transmission electron microscopy and synchrotron radiation-based techniques: XRD, EXAFS, XANES and SAXS, show a broad distribution of nanoparticle sizes with characteristic depending on the treatment regime; a crystalline structure of these nanoparticles is detected in heat treated samples. Magnetic circular dichroism (MCD) studies of samples subjected to heat treatment as well as of maghemite, magnetite and iron garnet allow to unambiguously assigning the nanoparticle structure to maghemite. Different features observed in the MCD spectra are related to different electron transitions in Fe3+ ions gathered in the nanoparticles. Variable-temperature electron magnetic resonance (EMR) studies confirm the formation of magnetic nanoparticles and the identification of their nature. Computer simulations of the EMR spectra corroborate the broad distribution of nanoparticle sizes found by 'direct' techniques. © 2014 IEEE.

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Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Ivanova, O. S.; Иванова, Оксана Станиславовна; Zubavichus, Y.; Trofimova, N. N.; Zaikovskiy, V. I.; Artemenko, A.; Curely, J.; Kliava, J.; Russian Foundation for Basic Research; Russian Foundation for Basic Research; International Conference on Optimization of Electrical and Electronic Equipmen (22 May - 24 May 2014 ; Bran, Romania)
}
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14.

Formation, characterization and magnetic properties of maghemite γ-Fe2O3 nanoparticles in borate glasses / I. S. Edelman [et al.] // J. Alloys Compd. - 2015. - Vol. 624. - P. 60-67, DOI 10.1016/j.jallcom.2014.11.059. - Cited References: 25. - This work was supported partly by the Russian Foundation for Basic Research - Russia, Grant No. 14-02-01211-a and by the President of Russia Grant No. NSh-2886.2014.2. This work was performed using the equipment of Unique Scientific Facility "Kurchatov Synchrotron Radiation Source'' supported by the Russian Ministry of Science and Education (project code RFMEFI61914X0002). . - ISSN 0925-8388

РУБ Chemistry, Physical + Materials Science, Multidisciplinary + Metallurgy & Metallurgical Engineering
Рубрики:
SUPERPARAMAGNETIC RESONANCE
   HYSTERESIS LOOPS
   EXCHANGE BIAS
   IONS
   MATRIX
Кл.слова (ненормированные):
Nanostructures -- Crystal structure and symmetry -- Magnetic measurements
Аннотация: A new type of nanocomposite materials based on maghemite, γ-Fe2O3, nanoparticles dispersed in borate glasses co-doped with low contents of iron together with the larger radius element combinations: Y and Bi, or Sm and Pb, or Y and Pb is studied. Nanoparticles arise as a result of heat treatment of the glasses which gives them properties characteristic of magnetically ordered substances. Transmission electron microscopy and XRD show that only one magnetic phase, namely γ-Fe2O3 nanoparticles, occurs in glasses subjected to the thermal treatment at 540 °C during 24 h independently on the doping element nature. At the same time doping element and their concentrations ratio in every combination affect the particles average size and glass magnetic properties, such as magnetization temperature dependences, Faraday rotation value and electron magnetic resonance spectrum characteristics.

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Держатели документа:
RAS, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660036, Russia
NRC Kurchatov Inst, Moscow 123182, Russia
RAS, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
Novosibirsk State Univ, Novosibirsk 630090, Russia

Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Ivanova, O. S.; Иванова, Оксана Станиславовна; Petrakovskaja, E. A.; Петраковская, Элеонора Анатольевна; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Tarasov, I. A.; Тарасов, Иван Анатольевич; Zubavichus, Y. V.; Trofimova, N. N.; Zaikovskii, V. I.; Russian Foundation for Basic Research - Russia [14-02-01211-a]; President of Russia [NSh-2886.2014.2]; Russian Ministry of Science and Education [RFMEFI61914X0002]
}
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15.

    Magnetic resonance in CuCr2S4 nanoclusters and nanocrystals / A. I. Pankrats [et al.] // Solid State Phenom. : Selected, peer reviewed papers. - 2015. - Vol. 233-234: Achievements in Magnetism. - P. 542-545, DOI 10.4028/www.scientific.net/SSP.233-234.542. - Cited References: 6 . - ISSN 1662-9779. - ISSN 978-3-038
   Перевод заглавия: Магнитный резонанс в нанокластерах и нанокристаллах CuCr2S4
Рубрики:
Achievements in magnetism
Кл.слова (ненормированные):
magnetic resonance -- nanocrystal -- superparamagnetic particles
Аннотация: Nanoclusters and nanocrystals of the room temperature magnetic spinel CuCr2S4 synthesized using a facile solution-based method were examined by magnetic resonance in a wide frequency range 9.6÷80 GHz and at temperatures down to 4.2 K. Decreasing of the resonance field and broadening of the resonance lines are found below ∼ 50 K for both the nanocluster and nanocube samples due to the freezing of magnetic moments of nanocubes and nanocrystalline particles constituting nanoclusters. Additional blocking temperature Tb≅300 K appears in nanoclusters due to the freezing of the magnetic moment of the entire cluster as a whole. Below this temperature, an additional low-field resonance line is found in the resonance spectra of nanoclusters at X-band.

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Доп.точки доступа:
Perov, N. \ed.\; Semisalova, A. \ed.\; Pankrats, A. I.; Панкрац, Анатолий Иванович; Vorotynov, A. M.; Воротынов, Александр Михайлович; Tugarinov, V. I.; Тугаринов, Василий Иванович; Zharkov, S. M.; Жарков, Сергей Михайлович; Abramova, G. M.; Абрамова, Галина Михайловна; Zeer, G. M.; Зеер Г. М.; Ramasamy, Karthik; Gupta, Arunava; Moscow International Symposium on Magnetism(6 ; 2014 ; June-July ; Moscow)
}
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16.

Magnetic structure and size-effects in the system of epsilon-Fe2O3/SiO2 nanoparticles / S. S. Yakushkin [et al.] // VI Euro-Asian Symposium "Trends in MAGnetism" (EASTMAG-2016) : abstracts / ed.: O. A. Maksimova, R. D. Ivantsov. - Krasnoyarsk : KIP RAS SB, 2016. - Ст. O9.5. - P. 383. - References: 6 . - ISBN 978-5-904603-06-9
Кл.слова (ненормированные):
ε-Fe2O3 nanoparticles -- superparamagnetic nanoparticles -- size effect -- FMR

Доп.точки доступа:
Yakushkin, S. S.; Якушкин С. С.; Balaev, D. A.; Балаев, Дмитрий Александрович; Shaikhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Dubrovsky, A. A.; Дубровский, Андрей Александрович; Bukhtiyarova, G. A.; Martyanov, O. N.; Euro-Asian Symposium "Trends in MAGnetism"(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); "Trends in MAGnetism", Euro-Asian Symposium(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); Институт физики им. Л.В. Киренского Сибирского отделения РАН

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17.

Remagnetization of ε-Fe2O3 nanoparticles in a pulse field / A. A. Krasikov [et al.] // VI Euro-Asian Symposium "Trends in MAGnetism" (EASTMAG-2016) : abstracts / ed.: O. A. Maksimova, R. D. Ivantsov. - Krasnoyarsk : KIP RAS SB, 2016. - Ст. P9.4. - P. 390. - References: 4 . - ISBN 978-5-904603-06-9
Кл.слова (ненормированные):
ε-Fe2O3 -- nanoparticles -- coercivity -- remagnetization -- superparamagnetic relaxation

Доп.точки доступа:
Krasikov, A. A.; Красиков, Александр Александрович; Balaev, D. A.; Балаев, Дмитрий Александрович; Shaikhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Popkov, S. I.; Попков, Сергей Иванович; Balaev, A. D.; Балаев, Александр Дмитриевич; Yakushkin, S. S.; Якушкин С. С.; Bukhtiyarova, G. A.; Бухтиярова Г. А.; Martyanov, O. N.; Мартьянов О.Н.; Poperechny, I. S.; Поперечный И. С.; Raikher, Yu.L.; Euro-Asian Symposium "Trends in MAGnetism"(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); "Trends in MAGnetism", Euro-Asian Symposium(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); Институт физики им. Л.В. Киренского Сибирского отделения РАН

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18.

Exchange bias in nano-ferrihydrite / D. A. Balaev [et al.] // J. Appl. Phys. - 2016. - Vol. 120, Is. 18. - Ст. 183903, DOI 10.1063/1.4967912. - Cited References: 43. - The authors are grateful to M. Volochaev for measurements and O. A. Bayukov for Mössbauer study. - This work was supported in part by the Ministry of Education and Science of the Russian Federation. . - ISSN 0021-8979
Кл.слова (ненормированные):
Anisotropy -- Cooling systems -- Hysteresis -- Magnetic fields -- Magnetic materials -- Magnetism -- Nanomagnetics -- Nanoparticles -- Particle size -- Characteristic value -- Exchange bias -- Exchange bias effects -- External magnetic field -- Field cooling -- High anisotropy -- Minor hysteresis loop -- Superparamagnetic blocking -- Hysteresis loops
Аннотация: We report the results of investigations of the effect of cooling in an external magnetic field starting from the temperature over superparamagnetic blocking temperature TB on the shift of magnetic hysteresis loops in systems of ferrihydrite nanoparticles from ∼2.5 to ∼5 nm in size with different TB values. In virtue of high anisotropy fields of ferrihydrite nanoparticles and open hysteresis loops in the range of experimentally attainable magnetic fields, the shape of hysteresis loops of such objects in the field-cooling mode is influenced by the minor hysteresis loop effect. A technique is proposed for distinguishing the exchange bias effect among the effects related to the minor hysteresis loops caused by high anisotropy fields of ferrihydrite particles. The exchange bias in ferrihydrite is stably observed for particles not less than 3 nm in size or with TB over 40 K, and its characteristic value increases with the particle size. © 2016 Author(s).

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Держатели документа:
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Presidium of Krasnoyarsk Scientific Center, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Popkov, S. I.; Попков, Сергей Иванович; Stolyar, S. V.; Столяр, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ladygina, V. P.; Yaroslavtsev, R. N.
}
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19.

Superparamagnetic blocking of an ensemble of magnetite nanoparticles upon interparticle interactions / D. A. Balaev [et al.] // J. Magn. Magn. Mater. - 2017. - Vol. 440. - P. 199-202, DOI 10.1016/j.jmmm.2016.12.046. - Cited References: 27. - Authors thanks to O.A. Bayukov and A.D. Balaev for fruitful discussions. The work was supported partially by Russian Foundation for Basic Research Grant No. 16-32-50156. . - ISSN 0304-8853
Кл.слова (ненормированные):
Fe3O4 nanoparticles -- Superparamagnetic nanoparticles -- Size effect -- Blocking temperature
Аннотация: We report on the effect of interparticle magnetic interactions in an ensemble of superparamagnetic magnetite particles with an average size of ~8.4 nm dispersed in the diamagnetic matrix on the blocking of this ensemble in external magnetic field. The two limit cases are investigated: the case of strongly interacting particles, when the value of magnetic dipole-dipole interaction between particles is comparable with the energy of other interactions in the ensemble (the interparticle distance is similar to the nanoparticle diameter) and the case of almost noninteracting particles distant from each other by about ten particle diameters. We demonstrate that the experimental dependence of the blocking temperature on external field is described well within the model [1], in which the density of particles in a nonmagnetic medium is taken into account and the correlation value depends on external magnetic field. The model for describing the magnetic properties of a disperse nanoparticle ensemble is proposed, which makes corrections related to the particle size and mean dipole-dipole interaction energy for the anisotropy constant. The surface magnetic anisotropy of Fe3O4 particles and parameters of the interparticle coupling are estimated. © 2017 Elsevier B.V.

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Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Yakushkin, S. S.; Kirillov, V. L.; Martyanov, O. N.; Euro-Asian Symposium "Trends in MAGnetism"(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); "Trends in MAGnetism", Euro-Asian Symposium(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); Институт физики им. Л.В. Киренского Сибирского отделения РАН
}
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20.

Superparamagnetic behavior of titanium nickelide nanoparticles obtained by laser ablation / A. K. Drozdova [и др.] // Moscow Int. Symp. on Magnet. (MISM-2017) : 1-7 July 2017 : book of abstracts. - 2017. - Ст. 2PO-J-33. - P. 286. - Cited References: 2

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Доп.точки доступа:
Drozdova, A. K.; Cherepanov, V. N.; Svetlichny, V. A.; Kveglis, L. I.; Volochaev, M. N.; Волочаев, Михаил Николаевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Moscow International Symposium on Magnetism(7 ; 2017 ; Jul. ; Moscow); Московский государственный университет им. М.В. Ломоносова; Российский фонд фундаментальных исследований
}
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