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1.


   
    Anisotropy of piezocaloric effect at ferroelectric phase transitions in ammonium hydrogen sulphate / E. A. Mikhaleva, M. V. Gorev, M. S. Molokeev [et al.] // J. Alloys Compd. - 2020. - Vol. 839. - Ст. 155085, DOI 10.1016/j.jallcom.2020.155085. - Cited References: 31. - The reported study was supported by the Russian Science Foundation (project no. 19-72-00023 ). X-ray and dilatometric data were obtained using the equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS" . - ISSN 0925-8388
Кл.слова (ненормированные):
Piezocaloric effect -- Phase transition -- Ferroelectrics -- Thermal expansion -- High-pressure -- Entropy
Аннотация: The role of anisotropy of the thermal expansion in formation of piezocaloric effect (PCE) near ferroelectric phase transitions in NH4HSO4 was studied. Strong difference in linear baric coefficients and as a result in intensive and extensive PCE associated with the different crystallographic axes was found. PCE giving the main contribution to the barocaloric effect were determined at both phase transitions. Rather strong effect of the lattice dilatation on the tuning of PCE was observed. Comparative analysis of PCE at the phase transitions in different materials showed that NH4HSO4 can be considered as a promising solid-state refrigerant. A hypothetical cooling cycle based on alternate using uniaxial pressure along two axes was considered.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, 660074, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation
Astafijev Krasnoyarsk State Pedagogical University, Krasnoyarsk, 660049, Russian Federation

Доп.точки доступа:
Mikhaleva, E. A.; Михалева, Екатерина Андреевна; Gorev, M. V.; Горев, Михаил Васильевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Kartashev, A. V.; Карташев, Андрей Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич
}
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2.


   
    Prediction of orientation relationships and interface structures between α-, β-, γ-FeSi2 and Si phases / M. A. Visotin, I. A. Tarasov, A. S. Fedorov [et al.] // Acta Crystallogr. B. - 2020. - Vol. 76. - P. 469-482, DOI 10.1107/S2052520620005727. - Cited References: 85. - The following funding is acknowledged: Russian Science Foundation (grant No. 16-13-00060-Pi). . - ISSN 2052-5206
РУБ Chemistry, Multidisciplinary + Crystallography
Рубрики:
THERMAL-EXPANSION
   BETA-FESI2 FILMS

   GROWTH

   SILICON

   DIFFRACTION

Кл.слова (ненормированные):
interface structure -- structure prediction -- orientation relationship -- near-coincidence site -- edge-to-edge matching -- iron silicide -- DFT calculations -- thermal expansion
Аннотация: A pure crystallogeometrical approach is proposed for predicting orientation relationships, habit planes and atomic structures of the interfaces between phases, which is applicable to systems of low-symmetry phases and epitaxial thin film growth. The suggested models are verified with the example of epitaxial growth of α-, γ- and β-FeSi2 silicide thin films on silicon substrates. The density of near-coincidence sites is shown to have a decisive role in the determination of epitaxial thin film orientation and explains the superior quality of β-FeSi2 thin grown on Si(111) over Si(001) substrates despite larger lattice misfits. Ideal conjunctions for interfaces between the silicide phases are predicted and this allows for utilization of a thin buffer α-FeSi2 layer for oriented growth of β-FeSi2 nanostructures on Si(001). The thermal expansion coefficients are obtained within quasi-harmonic approximation from the DFT calculations to study the influence of temperature on the lattice strains in the derived interfaces. Faster decrease of misfits at the α-FeSi2(001)||Si(001) interface compared to γ-FeSi2(001)||Si(001) elucidates the origins of temperature-driven change of the phase growing on silicon substrates. The proposed approach guides from bulk phase unit cells to the construction of the interface atomic structures and appears to be a powerful tool for the prediction of interfaces between arbitrary phases for subsequent theoretical investigation and epitaxial film synthesis.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Visotin, M. A.; Высотин, Максим Александрович; Tarasov, I. A.; Тарасов, Иван Анатольевич; Fedorov, A. S.; Федоров, Александр Семенович; Varnakov, S. N.; Варнаков, Сергей Николаевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Russian Science FoundationRussian Science Foundation (RSF) [16-13-00060-Pi]
}
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3.


   
    Calorimetric, dilatometric and DTA under pressure studies of the phase transitions in elpasolite (NH4)2KZrF7 / M. V. Gorev, A. V. Kartashev, E. V. Bogdanov [et al.] // J. Fluor. Chem. - 2020. - Vol. 235. - Ст. 109523, DOI 10.1016/j.jfluchem.2020.109523. - Cited References: 45. - The reported study was funded by RFBR according to the research project No. 18-02-00269 a. X-ray and dilatometric data were obtained using the equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS" . - ISSN 0022-1139
Кл.слова (ненормированные):
Phase transition -- Fluorides -- Heat capacity -- Entropy -- Thermal expansion -- High pressure
Аннотация: Heat capacity, thermal expansion, and sensitivity to the hydrostatic pressure of (NH4)2KZrF7 elpasolite are studied in a wide temperature range. The changes in deformation and entropy during successive phase transitions are determined: Δ(ΔV/V) = 3·10−4; ΔS = 8 J/mol K The temperatures and entropies of phase transitions turned out to be slightly sensitive to pressure changes. An analysis of the entropy of phase transformations was performed in the framework of the model of the cubic phase structure Fm-3 m. In the low temperature phase, an anomalous behavior of thermodynamic properties, which is not characteristic of phase transitions, was observed, accompanied by a significant change in the crystal lattice entropy.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, 660074, Russian Federation
Astafijev Krasnoyarsk State Pedagogical University, Krasnoyarsk, 660049, Russian Federation
Institute of Engineering Systems and Energy, Krasnoyarsk State Agrarian University, Krasnoyarsk, 660049, Russian Federation
Institute of Chemistry, Far Eastern Department of RAS, Vladivostok, 690022, Russian Federation

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Kartashev, A. V.; Карташев, Андрей Васильевич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Flerov, I. N.; Флёров, Игорь Николаевич; Laptash, N. M.
}
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4.


   
    Structure analysis, tuning photoluminescence and enhancing thermal stability on Mn4+-doped La2-xYxMgTiO6 red phosphor for agricultural lighting / S. Gai, H. Zhu, P. Gao [et al.] // Ceram. Int. - 2020. - Vol. 46, Is. 12. - P. 20173-20182, DOI 10.1016/j.ceramint.2020.05.095. - Cited References: 40. - The authors would like to gratefully acknowledge funds from the National Natural Science Foundation of China (Grant No. 21706060 , 51703061 , 51974123 ), the Hunan Graduate Research and Innovation Project (Grant No. CX2018B396 ), the Hunan provincial Engineering Technology Research Center for Optical Agriculture (Grant No. 2018TP2003 ), the Scientific Research Fund of Hunan Provincial Education Department (15K058, 19C0903), the Natural Sciences Foundation of Hunan agricultural university, China (Grant No. 19QN11), the Science and Technology project of Changsha (KH1801219) and the Huxiang high level talent gathering project (2019RS1077) . - ISSN 0272-8842
   Перевод заглавия: Анализ структуры, управление фотолюминесценцией и улучшенная термостойкость легированного Mn4+ красного люминофора La2-xYxMgTiO6 для сельскохозяйственного освещения
Кл.слова (ненормированные):
La2-xYxMgTiO6:Mn4+ -- Cation substitution -- Tunable photoluminescence -- Thermal stability -- Plant growth LED lighting
Аннотация: Currently, phosphor-converted LEDs (pc-LEDs) are revolutionizing the industry of plant growth lighting. To meet the requirements of this technology, phosphors with tunable photoluminescence, high thermal stability and luminous intensity are required. Herein, we found that the simple substitution of yttrium for lanthanum in La2MgTiO6:Mn4+ (LMT:Mn4+) system could satisfy above three criteria simultaneously. The photoluminescence properties can be regulated by continuously controlling the chemical composition of La2-xYxMgTiO6:Mn4+ solid solution. The La sites are occupied by Y ions, causing a significant blue shift in the emission spectra which owing to the change of local crystal field strengthen. Meanwhile, the thermal stability and decay lifetimes are also varied due to the variation of local structure and band gap energy. The thermal stability of the material reaches 83.5% at 150 °C, which is better than the reported La2MgTiO6:Mn4+ and Y2MgTiO6:Mn4+ phosphors. The electronic luminescence (EL) of pc-LED devices using La2-xYxMgTiO6:Mn4+ red phosphor is evaluated, which matching the absorption regions of plant pigments well, reflecting the superiority of the studied phosphors in plant growth lighting areas.

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Держатели документа:
School of Chemistry and Materials Science, Hunan Agricultural University, Changsha, 410128, China
Hunan Optical Agriculture Engineering Technology Research Center, Changsha, 410128, China
College of Agronomy, Hunan Agricultural University, Changsha, 410128, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
School of Architecture and Art, Central South University, Changsha, 410083, China

Доп.точки доступа:
Gai, S.; Zhu, H.; Gao, P.; Zhou, C.; Kong, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Qi, Z.; Zhou, Z.; Xia, M.
}
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5.


   
    Experimental study of the thermal conductivity of single-walled carbon nanotube-based thin films / I. A. Tambasov, A. S. Voronin, N. P. Evsevskaya [et al.] // Phys. Solid State. - 2020. - Vol. 62, Is. 6. - P. 1090-1094, DOI 10.1134/S1063783420060311. - Cited References: 21. - This study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory, and the Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activity, project Study of the Thermal Conductivity and Structural Features in Nanostructured Oxide Thin Films Promising for Thermoelectric Applications no. 18-42-243010 and the Scholarships of the President of the Russian Federation (SP-2235.2019.1). . - ISSN 1063-7834. - ISSN 1090-6460
РУБ Physics, Condensed Matter
Рубрики:
THERMOELECTRIC PROPERTIES
   TRANSPORT-PROPERTIES

Кл.слова (ненормированные):
single-walled carbon nanotubes -- vacuum filtration -- thin films -- thermal conductivity
Аннотация: The single-walled carbon nanotube-based thin films with a thickness from 11 ± 3 to 157 ± 18 nm have been formed using vacuum filtration. The thermal conductivity of the thin films as a function of thickness and temperature up to 450 K has been studied by the 3ω technique. It has been found that, in the region of 49 nm, the supplied heat from a gold strip started propagating with the high efficiency to the thin film plane. The thermal conductivity of the thin films with a thickness of 49 ± 8 nm was measured using the 3ω technique for bulk samples. It has been found that the thermal conductivity of the single-walled carbon nanotube-based thin films strongly depends on their thickness and temperature. The thermal conductivity sharply (by a factor of ~60) increases with an increase in thickness from 11 ± 3 to 65 ± 4 nm. In addition, it has been observed that the thermal conductivity of the thin film with a thickness of 157 ± 18 nm rapidly decreases from 211 ± 11 to 27.5 ± 1.4 W m–1 K–1 at 300 and 450 K, respectively.

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Публикация на русском языке Экспериментальное исследование коэффициента теплопроводности в тонких пленках на основе одностенных углеродных нанотрубок [Текст] / И. А. Тамбасов, А. С. Воронин, Н. П. Евсевская [и др.] // Физ. тверд. тела. - 2020. - Т. 62 Вып. 6. - С. 960-964

Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Krasnoyarsk Sci Ctr, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Krasnoyarsk Sci Ctr, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Inst Chem & Chem Technol, Krasnoyarsk Sci Ctr, Siberian Branch, Krasnoyarsk 660036, Russia.
Nizhnii Novgorod State Univ, Res Inst Phys & Technol, Nizhnii Novgorod 603950, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Siberian State Univ Sci & Technol, Krasnoyarsk 660014, Russia.

Доп.точки доступа:
Tambasov, I. A.; Тамбасов, Игорь Анатольевич; Voronin, A. S.; Evsevskaya, N. P.; Kuznetsov, Yu M.; Luk'yanenko, A. V.; Лукьяненко, Анна Витальевна; Tambasova, E. V.; Gornakov, M. O.; Горнаков, М. О.; Dorokhin, M., V; Loginov, Yu Yu; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of the Krasnoyarsk Territory; Krasnoyarsk Territorial Foundation for Support of Scientific and RD Activity [18-42-243010]; Russian FederationRussian Federation [SP-2235.2019.1]
}
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6.


   
    Improving thermal stability of novel single-component white-light emitting phosphor Ca8MgLu(PO4)7:Tm3+, Dy3+ by back-energy-transfer / F. Xie, D. Xu, Z. Wu [et al.] // J. Lumines. - 2020. - Vol. 227. - Ст. 117516, DOI 10.1016/j.jlumin.2020.117516. - Cited References: 54. - This work was financially supported by grants from the National Natural Science Foundation of China (No. 21771195 and 51972347), the Natural Science Foundation of Guangdong Province (No. 2016A030313118), the Science and Technology program of Huizhou City (No. 2016X0421036), the Department of Education of Guangdong Province (No. 2018KQNCX249), and the Professorial and Doctoral Scientific Research Foundation of Huizhou University (No. 2018JB012) . - ISSN 0022-2313
   Перевод заглавия: Повышение термостойкости нового однокомпонентного люминофора, излучающего белый свет, Ca8MgLu(PO4)7:Tm3+,Dy3+ за счет обратной передачи энергии
Кл.слова (ненормированные):
Single-phase white-light emitting phosphor -- Ca8MgLu(PO4)7:Tm3+,Dy3+ -- Back-energy-transfer -- Highly thermal stability
Аннотация: The light degradation of WLED devices after long-time use has been proved to be mainly caused by thermal quenching of phosphors, therefore, the design of single-component white-light emitting phosphors with high thermal stability remains a huge challenge. A novel single-phase white light-emitting phosphor Ca8MgLu(PO4)7:Tm3+,Dy3+ was designed and prepared in this work. The photoluminescent results show that white light emission from the phosphor can be achieved by controlling the ratio of Tm3+ and Dy3+ to adjust the relative intensity of the emission at 451 nm of Tm3+ and the emissions at 488, 571 and 660 nm of Dy3+. The luminescence decay results reveal that there is energy transfer from Tm3+ to Dy3+ in Ca8MgLu(PO4)7:Tm3+,Dy3+ and the efficiency of energy transfer between the two dopants reaches as much as 55%. Temperature-dependent luminescent analyses suggest the highly stable emission of Ca8MgLu0.76(PO4)7:0.12Tm3+,0.12Dy3+ as the integrated emission intensity of the phosphor at 475 K reduces only about 13% of that at room temperature, which is due to the back-energy-transfer from highly doped Dy3+ to Tm3+ that compensates the luminescence energy. This single-phase white-light emitting phosphor exhibits superior color and luminescence stability and thus may find a potential application in WLEDs.

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Держатели документа:
School of Chemistry and Materials Engineering, Huizhou University, Huizhou, 516007, China
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, China
College of Chemistry and Molecular Engineering, Qingdao University of Science &Technology, Qingdao, 266042, China
Kirensky Institute of Physics, SB RAS, Krasnoyarsk, RU 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Xie, F.; Xu, D.; Wu, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Milicevic, B.; Li, H.; Shi, J.
}
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7.


   
    Hydrates of lanthanide(III) 2-thiobarbiturates: synthesis, structure, and thermal decomposition / N. N. Golovnev, M. S. Molokeev, M. K. Lesnikov, A. S. Samoilo // Russ. J. Inorg. Chem. - 2020. - Vol. 65, Is. 7. - P. 999-1005, DOI 10.1134/S0036023620070098. - Cited References: 22. - This study was financially supported by the Russian Foundation for Basic Research within scientific project no. 19-52-80003 . - ISSN 0036-0236
Кл.слова (ненормированные):
lanthanides(III) -- thiobarbiturates -- hydrates -- structure -- stability
Аннотация: The hydrates Ln(Htba)3 ∙ 3H2O (Ln = Yb (I), Er (II), Ho (III); Н2tba = 2-thiobarbituric acid), Ln(Htba)3 ∙ 2H2O and Ln(Htba)3 ∙ 8H2O were crystallized from aqueous solutions. According to single-crystal X-ray diffraction analysis data, the structure of monoclinic crystals of isostructural complexes I–III was [Ln2(H2O)6(μ2-Htba-О,O')4(Htba-О)2]n. The formation of isostructural Ln(Htba) ∙ 2H2O (Ln = La, Ce, Eu, Yb, Lu), Ln(Htba)3 ∙ 8H2O (Ln = Eu, Tb, Ho, Yb) and Y(Htba)3 ∙ nH2O (n = 2, 8) was confirmed by the comparison of X-ray diffraction patterns, and their composition was determined by elemental and thermal analyses. The stability of crystal hydrates under heating in an air atmosphere and in contact with their saturated solutions was studied.

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Публикация на русском языке Гидраты 2-тиобарбитуратов лантаноидов(III): синтез, структура и термическое разложение [Текст] / Н. Н. Головнев, М. С. Молокеев, М. К. Лесников, А. С. Самойло // Журн. неорг. химии. - 2020. - Т. 65 № 7. - С. 915-921

Держатели документа:
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Kirenskii Institute of Physics, Federal Research Center “Krasnoyarsk Scientific Center,” Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation

Доп.точки доступа:
Golovnev, N. N.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Lesnikov, M. K.; Samoilo, A. S.
}
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8.


   
    Two new Cu(II) and Ni(II) 1,10-phenanthroline complexes with anions of barbituric acids in the outer sphere: Synthesis, structure, spectroscopic, magnetic and thermal properties / N. N. Golovnev, M. S. Molokeev, I. V. Sterkhova [et al.] // J. Mol. Struct. - 2020. - Vol. 1219. - Ст. 128526, DOI 10.1016/j.molstruc.2020.128526. - Cited References: 40. - The study was funded by RFBR according to the research project № 19-52-80003 . X-ray data from single crystals were obtained with use the analytical equipment of Baikal Center of collective use of SB RAS and powder pattern were obtained with use the analytical equipment of Krasnoyarsk Center of collective use of SB RAS . - ISSN 0022-2860
   Перевод заглавия: Два новых комплекса 1,10-фенантролина Cu (II) и Ni (II) с анионами барбитуровой кислоты во внешней сфере: синтез, структура, спектроскопические, магнитные и термические свойства
Кл.слова (ненормированные):
Barbituric acids -- Phenanthroline complexes -- X-ray diffraction -- Thermal -- Spectroscopic and magnetic properties
Аннотация: Two new complexes [Cu(Phen)2(H2O)](Hba)2∙3H2O (1) and [Ni(Phen)3](Htba)2]∙Phen∙2H2O (2) (Phen = 1,10-phenanthroline, Hba− = barbiturate ion, Htba− = thiobarbiturate ion) have been synthesized and characterized by elemental analysis, single-crystal and powder XRD, magnetic measurements, TG-DSC, FT-IR, and Vis absorption spectra. Complex 1 shows a distorted square pyramidal geometry around the copper (II) metal center. The coordination around the Ni atom is a distorted octahedron NiN6. The 3D and 2D supramolecular structures of 1 and 2 are formed respectively by intermolecular H-bonds. Two N–H⋯O hydrogen bonds in 1, and N–H⋯O, N–H⋯S hydrogen bonds in 2 form infinite chains. As a result of π–π interactions, similar 4-membered zigzag chains in structures 1 and 2 respectively are formed.

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Держатели документа:
Siberian Federal University, 79 Svobodny Ave., Krasnoyarsk, 660041, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Bld. 38 Akademgorodok 50, Krasnoyarsk, 660036, Russian Federation
Department of Physics, Far Eastern State Transport University, 47 Seryshev Str., Khabarovsk, 680021, Russian Federation
Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky, Irkutsk, 664033, Russian Federation
Laboratory of Magnetic Dynamics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Bld. 38 Akademgorodok 50, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Golovnev, N. N.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Sterkhova, I. V.; Lesnikov, M. K.; Demina, A. V.; Patrin, G. S.; Патрин, Геннадий Семёнович
}
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9.


   
    Thermodynamic properties of vanadium oxypentafluoride (IV) (NH4)3VOF5 / E. V. Bogdanov, E. I. Pogoreltsev, A. V. Kartashev [et al.] // Phys. Solid State. - 2020. - Vol. 62, Is. 7. - P. 1271-1279, DOI 10.1134/S1063783420070057. - Cited References: 17. - This study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory, and the Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activity, project no. 18-42-243003 “Effect of Deuteration on Orientational Ordering and Phase Transitions in Ammonium Fluorine-Oxygen Vanadates” . - ISSN 1063-7834
Кл.слова (ненормированные):
oxyfluorides -- phase transitions -- specific heat -- birefringence -- thermal expansion -- pressure susceptibility
Аннотация: The (NH4)3VOF5 crystals have been synthesized and their homogeneity and single-phase structure has been established by the X-ray diffraction, energy dispersive spectroscopy, and X-ray photoelectron spectroscopy studies. The investigations of the temperature dependences of specific heat, entropy, strain, and pressure susceptibility show the occurrence of three phase transitions caused by the structural transformations in the (NH4)3VOF5 crystals. The T–p phase diagram shows the temperature limits of stability of the crystalline phases implemented in (NH4)3VOF5. The optical and dielectric studies disclose the ferroelastic nature of the phase transitions. An analysis of the experimental data together with the data on the isostructural (NH4)3VO2F4 crystal makes it possible to distinguish the physical properties of oxyfluorides containing vanadium of different valences (IV and V).

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Публикация на русском языке Термодинамические свойства оксипентафторида ванадия (IV), (NH4)3VOF5 [Текст] / Е. В. Богданов, Е. И. Погорельцев, А. В. Карташев [и др.] // Физ. тверд. тела. - 2020. - Т. 62 Вып. 7. - С. 1123-1131

Держатели документа:
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Krasnoyarsk State Agrarian University, Institute of Engineering Systems and Power, Krasnoyarsk, 660049, Russian Federation
Siberian Federal University, Institute of Engineering Physics and Radio Electronics, Krasnoyarsk, 660041, Russian Federation
Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, Vladivostok, 690022, Russian Federation

Доп.точки доступа:
Bogdanov, E. V.; Богданов, Евгений Витальевич; Pogoreltsev, E. I.; Погорельцев, Евгений Ильич; Kartashev, A. V.; Карташев, Андрей Васильевич; Gorev, M. V.; Горев, Михаил Васильевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Mel'nikova, S. V.; Мельникова, Светлана Владимировна; Flerov, I. N.; Флёров, Игорь Николаевич; Laptash, N. M.
}
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10.


   
    Synthesis of samarium oxysulfate Sm2O2SO4 in the high-temperature oxidation reaction and its structural, thermal and luminescent properties / Y. G. Denisenko, E. I. Sal'nikova, S. A. Basova [et al.] // Molecules. - 2020. - Vol. 25, Is. 6. - Ст. 1330, DOI 10.3390/molecules25061330. - Cited References: 56. - This research was funded by the Russian Foundation for Basic Research (Grants 18-02-00754, 18-32-20011) and Russian Science Foundation (project 19-42-02003). . - ISSN 1420-3049
   Перевод заглавия: Синтез оксисульфата самария Sm2O2SO4 в реакции высокотемпературного окисления и его структурные, термические и люминесцентные свойства
РУБ Biochemistry & Molecular Biology + Chemistry, Multidisciplinary
Рубрики:
RARE-EARTH SULFATES
   SPECTROSCOPIC PROPERTIES

   OXYGEN-STORAGE

   LN

   LA

Кл.слова (ненормированные):
samarium -- oxysulfate -- structure -- luminescence -- thermochemistry
Аннотация: The oxidation process of samariumoxysulfide was studied in the temperature range of 500–1000 °C. Our DTA investigation allowed for establishing the main thermodynamic (∆Hºexp = −654.6 kJ/mol) and kinetic characteristics of the process (Ea = 244 kJ/mol, A = 2 × 1010). The enthalpy value of samarium oxysulfate (ΔHºf (Sm2O2SO4(monocl)) = −2294.0 kJ/mol) formation was calculated. The calculated process enthalpy value coincides with the value determined in the experiment. It was established that samarium oxysulfate crystallizes in the monoclinic symmetry class and its crystal structure belongs to space group C2/c with unit cell parameters a = 13.7442 (2), b = 4.20178 (4) and c = 8.16711 (8)Å, β = 107.224 (1)°, V = 450.498 (9)Å3, Z = 4. The main elements of the crystalline structure are obtained and the cation coordination environment is analyzed in detail. Vibrational spectroscopy methods confirmed the structural model adequacy. The Sm2O2SO4 luminescence spectra exhibit three main bands easily assignable to the transitions from 4G5/2 state to 6H5/2, 6H7/2, and 6H9/2 multiplets.

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Ind Univ Tyumen, Dept Gen & Special Chem, Tyumen 625000, Russia.
Tyumen State Univ, Inst Chem, Tyumen 625003, Russia.
Northen Trans Ural Agr Univ, Dept Gen Chem, Tyumen 625003, Russia.
RAS, Fed Res Ctr, Kirensky Inst Phys, KSC,SB,Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Sch Engn Phys & Radioelect, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
RAS, Kirensky Inst Phys, Fed Res Ctr, KSC,SB,Lab Mol Spect, Krasnoyarsk 660036, Russia.
RAS, Kirensky Inst Phys, Fed Res Ctr, KSC,SB,Lab Coherent Opt, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Inst Nanotechnol Spect & Quantum Chem, Krasnoyarsk 660041, Russia.
Siberian Fed Univ, Sch Engn & Construct, Krasnoyarsk 660041, Russia.
RAS, Inst Semicond Phys, Lab Opt Mat & Struct, SB, Novosibirsk 630090, Russia.
Novosibirsk State Univ, Lab Semicond & Dielectr Mat, Novosibirsk 630090, Russia.
Kemerovo State Univ, Res & Dev Dept, Kemerovo 650000, Russia.
Tyumen State Univ, Res Resource Ctr, Nat Resource Management & Physicochem Res, Tyumen 625003, Russia.
RAS, Inst Solid State Chem, Lab Chem Rare Earth Cpds, UB, Ekaterinburg 620137, Russia.

Доп.точки доступа:
Denisenko, Yu. G.; Sal'nikova, E. I.; Basova, S. A.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Krylov, A. S.; Крылов, Александр Сергеевич; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Atuchin, V. V.; Volkova, S. S.; Khritokhin, N. A.; Andreev, O. V.; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-02-00754, 18-32-20011]; Russian Science FoundationRussian Science Foundation (RSF) [19-42-02003]
}
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11.


   
    Structure and Electrical Properties of (ZnO/SiO2)25 Thin Films / M. N. Volochaev [et al.] // Semiconductors. - 2019. - Vol. 53, Is. 11. - P. 1465-1471, DOI 10.1134/S106378261911023X. - Cited References: 16. - This study was carried out in the framework of the state assignment of the Ministry of Science and Higher Education of the Russian Federation, project no. 3.1867.2017/4.6. . - ISSN 1063-7826. - ISSN 1090-6479
РУБ Physics, Condensed Matter
Рубрики:
HETEROSTRUCTURES
Кл.слова (ненормированные):
thin films -- multilayers -- oxide semiconductors -- hopping conductivity -- thermal stability
Аннотация: (ZnO/SiO2)25 thin-film multilayers consisting of nanocrystalline ZnO layers and amorphous SiO2 spacers with a bilayer thickness from 6 to 10 nm are synthesized in a single deposition process. An analysis of the temperature dependences of the electrical resistivity of (ZnO/SiO2)25 thin films shows that, in the temperature range of 77–300 K, the dominant conductivity mechanism successively changes from hopping conductivity with a variable hopping length in a narrow energy band near the Fermi level at temperatures of 77–250 K to thermally activated impurity conductivity around room temperature. Using the obtained temperature dependences of the electrical resistivity, the effective density of localized states at the Fermi level and the activation energy of impurity levels are estimated. The effect of heat treatment on the structure and electrical properties of the synthesized films is examined. It is established that in (ZnO/SiO2)25 thin-film systems at temperatures of 580–600°C, the ZnO and SiO2 layers chemically interact, which is accompanied by destruction of the multilayer structure and formation of the Zn2SiO4 compound with a tetragonal structure (sp. gr. I-42d).

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Публикация на русском языке

Держатели документа:
Russian Acad Sci, Krasnoyarsk Sci Ctr, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk, Russia.
Voronezh State Tech Univ, Voronezh 394026, Russia.

Доп.точки доступа:
Volochaev, M. N.; Волочаев, Михаил Николаевич; Kalinin, Yu E.; Kashirin, M. A.; Makagonov, V. A.; Pankov, S. Yu; Bassarab, V. V.; Ministry of Science and Higher Education of the Russian Federation [3.1867.2017/4.6]
}
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12.


   
    Thermal, mechanical and biodegradation studies of biofiller based poly-3-hydroxybutyrate biocomposites / S. Thomas [et al.] // Int. J. Biolog. Macromol. - 2020. - Vol. 155. - P. 1373-1384, DOI 10.1016/j.ijbiomac.2019.11.112. - This study was financially supported by Project “Agropreparations of the new generation: a strategy of construction and realization” (Agreement No 074-02-2018-328) in accordance with Resolution No 220 of the Government of the Russian Federation of April 9, 2010, “On measures designed to attract leading scientists to the Russian institutions of higher learning”. . - ISSN 1879-0003
   Перевод заглавия: Термические, механические и биодеградационные исследования биокомпозитов на основе бионаполнителей на основе поли-3-гидроксибутирата
Кл.слова (ненормированные):
Poly-3-hydroxybutyrate -- Biocomposite -- Physical properties -- Environmental degradation
Аннотация: Biodegradable poly-3-hydroxybutyrate [P(3HB)] and natural fillers - clay, peat, and birch wood flour – were used to prepare powdered composites to form pellets and granules. Pellets were produced by cold pressing of polymer and filler powder whereas granules were produced from the powders wetted with ethanol. Characterization techniques like IR spectroscopy, differential scanning calorimetry, X-ray analysis, mechanical analysis and electron microscopy were employed to study the properties of the initial P(3HB) and fillers and the composites. Analysis of the IR spectra of the composites showed the absence of chemical bonds between the components, i.e. the composites were physical mixtures. Young's moduli of the pellets prepared from initial materials varied considerably, and the highest value was obtained for P(3HB) pellets (350 MPa). Studies of biodegradation of composite pellets and granules in the soil for 35 days showed that the residual mass of the pellets had decreased to 68% for P(3HB); 56.4% for P(3HB)/peat; 67% for P(3HB)/wood flour, and 64% for P(3HB)/clay; granules exhibited a similar mass loss, residual mass of the granules of P(3HB) was 68.4%, P(3HB)/peat 46.4%; P(3HB)/wood flour 77%, and P(3HB)/clay 74%. This shows the significance of the material as an eco-friendly composite without sacrificing its mechanical properties.

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Держатели документа:
Siberian Federal University, 79 Svobodnyi Av., Krasnoyarsk 660041, Russia
International and Interuniversity Centre for Nano Science and Nano technology, Kottayam, Kerala, India
Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/50 Akademgorodok, Krasnoyarsk 660036, Russia
L.V. Kirensky Institute of Physics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 43/50 Akademgorodok, Krasnoyarsk 660036, Russia
Federal Research Center Krasnoyarsk Scientific Center of the Siberian Branch of Russian, Academy of Sciences, 50 Akademgorodok, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Thomas, S.; Shumilova, A. A.; Kiselev, E. G.; Baranovsky, S. V.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Nemtsev, I. V.; Kuzmin, A. P.; Sukovatyi, A. G.; Avinash, R. P.; Volova, T. G.
}
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13.


    Kiselev, E. G.
    Thermal and Mechanical Studies of Biofiller/Poly-3-Hydroxybutyrate Biocomposites / E. G. Kiselev, A. P. Kuzmin, I. V. Nemtsev // J. Sib. Fed. Univ. Biol. - 2019. - Vol. 12, Is. 3. - P. 302-310 ; Журнал СФУ. Биология, DOI 10.17516/1997-1389-0304. - Cited References: 8. - The study was performed using equipment from the Shared Instrument Facility of Federal Research Center “Krasnoyarsk Science Center SB RAS”, 43/50 Akademgorodok, Krasnoyarsk, 660036, Russia. . - ISSN 1997-1389. - ISSN 2313-5530
   Перевод заглавия: Тепловые и механические свойства биокомпозита на основе поли-3-гидроксибутирата и бионаполнителя
Кл.слова (ненормированные):
P(3HB) -- wood flour -- fillers -- polymer blends -- physicochemical properties -- P(3HB) -- древесные опилки -- филлер -- полимерные смеси -- физико-химические и механические свойства
Аннотация: Biodegradable poly-3-hydroxybutyrate [P(3HB)] and birch wood flour (as filler) were used to prepare powdered blends and then pellets and granules. Pellets were produced by cold pressing of polymer and filler powders; granules were produced from the powders wetted with ethanol. The properties of the initial P(3HB) and filler and the blends thereof were studied using IR spectroscopy, differential scanning calorimetry, X-ray analysis, and electron microscopy. No chemical bonds between the components were revealed; the blends were physical mixtures. The degree of crystallinity of the blends was lower than that of the initial polymer, suggesting different crystallization kinetics of the blends. The introduction of increasing amounts of filler into the polymer progressively decreased the mechanical strength of the pellets, as confirmed by a decrease in Young’s modulus. The resulting composite, based on biodegradable polymers and wood flour, is a promising nontoxic material for the production of wood-based panels for the construction industry and the manufacture of furniture in place of materials produced using toxic polyester resins.
Биоразлагаемый поли-3-гидроксибутират [P(3HB)] и березовые опилки (в качестве наполнителя) использованы для приготовления порошкообразных смесей с целью получения форм в виде гранул и таблеток. Таблетки получены прямым холодным прессованием порошков полимера и наполнителя, гранулы - техникой гранулирования из пасты смеси полимера с опилками, увлажненной этанолом. Свойства исходного полимера, наполнителя и полученных смесей изучены с помощью ИК-спектроскопии, дифференциальной сканирующей калориметрии, рентгенографии и электронной микроскопии. Химических связей между компонентами обнаружено не было, следовательно, эти смеси представляют собой физические смеси. Степень кристалличности смесей была ниже, чем у исходного полимера, что свидетельствует о различной кинетике кристаллизации смесей. Увеличение содержания наполнителя в полимере снижало механическую прочность. Полученный на основе биоразлагаемого полимера и опилок композит имеет перспективу в качестве нетоксичного материала для производства древесных плит для стройиндустрии и мебельной промышленности вместо материалов, изготовленных с использованием токсичных полиэфирных смол.

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Держатели документа:
Siberian Federal University 79 Svobodny, Krasnoyarsk, 660041, Russia
Federal Research Center “Krasnoyarsk Science Center SB RAS” 43/50 Akademgorodok, Krasnoyarsk, 660036, Russia

Доп.точки доступа:
Kuzmin, A. P.; Nemtsev, I. V.; Немцев, Иван Васильевич

}
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14.


   
    Thermal conductivity and magnetic phase diagram of CuB2O4 / T. Kawamata [et al.] // J. Phys. Soc. Jpn. - 2019. - Vol. 88, Is. 11. - Ст. 114708, DOI 10.7566/JPSJ.88.114708. - Cited References: 42. - This work was supported by a Grant-in-Aid for Scientific Research of the Ministry of Education, Culture Sports, Science and Technology, Japan, (Grant Number 17038002) and also by CREST of Japan Science and Technology Corporation. . - ISSN 0031-9015. - ISSN 1347-4073
Аннотация: We have measured temperature and magnetic field dependences of the thermal conductivity along the c-axis, κc, and that along the [110] direction, κ110, of CuB2O4 single crystals in zero field and magnetic fields along the c-axis and along the [110] direction. It has been found that the thermal conductivity is nearly isotropic and very large in zero field and that the thermal conductivity due to phonons is dominant in CuB2O4. The temperature and field dependences of κc and κ110 have markedly changed at phase boundaries in the magnetic phase diagram, which has been understood to be due to the change of the mean free path of phonons caused by the change of the phonon-spin scattering rate at the phase boundaries. It has been concluded that thermal conductivity measurements are very effective for detecting magnetic phase boundaries.

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Держатели документа:
Department of Applied Physics, Tohoku University, Sendai 980-8579, Japan
Department of Engineering and Applied Sciences, Sophia University, Chiyoda, Tokyo 102-8554, Japan
Research Institute for Interdisciplinary Science, Okayama University, Okayama 700-8530, Japan
Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan
Research Center for Development of Far-Infrared Region, University of Fukui, Fukui 910-8507, Japan
Department of Applied Physics, Faculty of Engineering, University of Fukui, Fukui 910-8507, Japan
Institute of Physics, Siberian Branch of the Russian Academy of Science, 660036 Krasnoyarsk, Russia

Доп.точки доступа:
Kawamata, T.; Sugawara, N.; Haidar, S. M.; Adachi, T.; Noji, T.; Kudo, K.; Kobayashi, N.; Fujii, Yu.; Kikuchi, H.; Chiba, M.; Petrakovskii, G. A.; Петраковский, Герман Антонович; Popov, M. A.; Попов, Михаил Александрович; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Koike, Yo.
}
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15.


   
    Aliovalent substitution toward reinforced structural rigidity in Ce3+-doped garnet phosphors featuring improved performance / T. Hu [et al.] // J. Mater. Chem. C. - 2019. - Vol. 7, Is. 46. - P. 14594-14600, DOI 10.1039/c9tc05354a. - Cited References: 38. - This work was supported by the National Natural Science Foundation of China (No. 51722202 and 51972118), the Guangdong Provincial Science & Technology Project (2018A050506004) and the Fundamental Research Funds for the Central Universities (D2190980). . - ISSN 2050-7534
   Перевод заглавия: Алиовалентное замещение с целью усиления структурной жесткости в люминофорных гранатах, легированных Ce3 + и имеющих улучшенные характеристики
Кл.слова (ненормированные):
Color -- Deterioration -- Efficiency -- Gallium alloys -- Garnets -- III-V semiconductors -- Indium alloys -- Photoluminescence -- Reinforcement -- Rigidity -- Semiconductor alloys -- Thermal Engineering -- Thermodynamic stability
Аннотация: Highly efficient phosphors with thermal stability and color-tunable emission are required for the fabrication of phosphor-converted white light-emitting diodes (pc-WLEDs). Currently developed engineering strategies are generally successful in photoluminescence tuning but, unfortunately, suffer severe deterioration in emission intensity/efficiency and/or thermal stability. Herein, an efficient aliovalent substitution strategy toward reinforced structural rigidity is proposed and demonstrated experimentally. By incorporating Be2+ ion into the garnet-type Lu2SrAl4SiO12:Ce3+ phosphor, the phosphor shows enhanced internal/external quantum efficiency, from 79.2%/26.7% to 84.5%/32.9%, photoluminescence tuning from green (peaking at ∼512 nm) to yellow (peaking at ∼552 nm), and zero thermal quenching, even up to 200 °C. The Be2+ substitution at the Al2/Si2 site enables stable and rigid local surroundings around the Ce3+ activator, which is responsible for the unprecedented performance. In addition, high-quality warm WLED devices with a luminous efficiency of 158.1 lm W-1, correlated color temperature of 3858 K and high color rendering index of 81.7, are obtained by combining Lu2SrAl4SiO12:Ce3+,Be2+ as the yellow emitter, CaAlSiN3:Eu2+ as the red emitter and a blue-emitting InGaN chip. These findings highlight a new strategy for performance optimization of LED phosphors by selecting rigid covalent compounds with further reinforced structural rigidity via aliovalent substitution.

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Держатели документа:
State Key Laboratory of Luminescent Materials and Devices, Institute of Optical Communication Materials, South China University of Technology, Guangzhou, 510641, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation

Доп.точки доступа:
Hu, T.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Xia, Z.; Zhang, Q.
}
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16.


   
    Enhanced green emission and thermal stability of Ba3Si6O12N2:Eu2+ by Ce3+/P5+-doping: Unity energy transfer, charge compensation and lattice strain release / J. Hao, M. Tao, Z. Gao [et al.] // J. Lumines. - 2020. - Vol. 220. - Ст. 116995, DOI 10.1016/j.jlumin.2019.116995. - Cited References: 66. - This work is financially supported by the National Natural Science Foundation of China (NSFC No. 51672259 , 51601131 ) and the Fundamental Research Fund for National Universities , China University of Geosciences (Wuhan) . - ISSN 0022-2313
   Перевод заглавия: Улучшенное зеленое излучение и термическая стабильность Ba3Si6O12N2:Eu2 + путем легирования Ce3+/P5+: передача энергии, компенсация заряда и снятие деформации решетки
Кл.слова (ненормированные):
Oxonitridosilicate -- Green phosphor -- Unity energy transfer -- Charge compensation -- Thermal stability improvement
Аннотация: To optimize luminescence properties of oxonitridosilicate phosphors are extremely necessary for improving lighting quality of white light-emitting diodes (WLEDs). Herein, we designed Ce3+, Eu2+ codoping and P5+-Si4+ substitution in the presentative Ba3Si6O12N2:Eu2+ green phosphor to realize an enhancement of luminescence efficiency and thermal stability. Rietveld refinement results of Ce3+, Eu2+, P5+-doped Ba3Si6O12N2 (BSON) confirmed the formation of pure trigonal phase (P-3) of Ba3Si6O12N2 and the successful doping of Ce3+, Eu2+, P5+ ions. Ce3+ and Eu2+ ions randomly occupy two Ba crystallographic sites. Interestingly, a near unity energy transfer (ET, ~100%) from Ce3+ ions to Eu2+ ions is observed. Meanwhile, the doping of P5+ ions into BSON also helps improving the luminescence efficiency and thermal stability, which should be attributed to the charge compensation and the relax of lattice strain. In addition, the white light emitting diodes (WLEDs) fabricated by employing P5+-doped BSON: Eu2+ present a better electroluminescence performance than BSON: Eu2+. This study could serve as a guide in developing optimized oxonitridosilicates phosphors with improved luminescence performances based on complete energy transfer and lattice variations in local coordination environments through cation substitutions, and the as-prepared Ce3+/P5+-codoped Ba3Si6O12N2:Eu2+ could be an excellent green-emitting phosphor for UV-to-Visible LED chips pumped WLEDs.

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Engineering Research Center of Nano-Geomaterials of Ministry of Education, Faculty of Materials Science and Chemistry, China University of Geosciences, 388 Lumo Road, Wuhan, 430074, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, 660036, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Hao, J.; Tao, M.; Gao, Z.; Chen, S.; Liu, Y.; Wang, H.; Wei, Y.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Li, G.
}
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17.


   
    Infrared lattice dynamics in negative thermal expansion material in single-crystal ScF3 / S. U. Handunkanda, E. B. Curry, V. Voronov, J. N. Hancock // J. Phys.: Condens. Matter. - 2020. - Vol. 32, Is. 3. - Ст. 035403, DOI 10.1088/1361-648X/ab4955. - Cited References: 49. - Work at the University of Connecticut is supported by National Science Foundation Award No. DMR-1506825 . - ISSN 0953-8984. - ISSN 1361-648X
РУБ Physics, Condensed Matter
Рубрики:
LONGITUDINAL-OPTIC MODES
   TEMPERATURE-DEPENDENCE

   ABSORPTION

Кл.слова (ненормированные):
phonons -- infrared reflectivity -- negative thermal expansion -- optical properties
Аннотация: Simple cubic 'open' perovskite ScF3 stands out among trifluoride materials in its large, isotropic negative thermal expansion (NTE), but also its proximity of its zero-temperature state to a structural phase transition. Here we report a temperature- and frequency-dependent lattice dynamical study of Brillouin zone center lattice excitations of single crystals of ScF3 using infrared reflectivity measurements. In addition to quantifying the mode strengths and energies in single crystals of this interesting material, we also find strong evidence for multiphonon absorption processes which excite the zone-edge incipient soft modes associated with NTE and the structural quantum phase transition. In this way, we identify an optically-allowed pathway to excite soft modes provides a means to athermally populate modes associated with NTE in ScF3.

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Держатели документа:
Univ Connecticut, Dept Phys, Storrs, CT 06269 USA.
Univ Connecticut, Inst Mat Sci, Storrs, CT 06269 USA.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 66006, Russia.

Доп.точки доступа:
Handunkanda, Sahan U.; Curry, Erin B.; Voronov, V. N.; Воронов, Владимир Николаевич; Hancock, Jason N.
}
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18.


   
    Synthesis and transport properties of FET based on Heusler alloy thin films formed by rapid thermal annealing / A. V. Lukyanenko [et al.] // J. Phys.: Conf. Ser. - 2019. - Vol. 1410. - Ст. 012017, DOI 10.1088/1742-6596/1410/1/012017. - Cited References: 10. - This study was supported by the Russian Foundation for Basic Research, project no. 17-02-00302 and supported in part by the Ministry of Education and Science of the Russian Federation and the Siberian Branch of the Russian Academy of Sciences, project II.8.70, and the Presidium of the Russian Academy of Sciences, Fundamental Research Program no. 32 «Nanostructures: Physics, Chemistry, Biology, Basics of Technologies». . - ISSN 1742-6588. - ISSN 1742-6596
РУБ Crystal growth and structural properties of semiconductor materials and nanostructures

Аннотация: In this work we show a preparation technique of Co2FeSi full-Heusler alloy thin films on silicon-on-insulator (SOI) substrates, employing rapid thermal annealing (RTA). The films of the Co2FeSi alloy were formed by a silicidation reaction, caused by RTA, between the ultrathin SOI (001) layer and the Fe/Co layers deposited on it. It is assumed that this technology is compatible with the process of formation of a half-metal source-drain in an advanced CMOS and SOI technology and will be applicable for the manufacture of a source-drain of a field-effect transistor. Schottky barrier field-effect transistors (FET) with a back-gate, based on silicon nanowires with source and drain of a Co2FeSi film, synthesized on an SOI substrate, were manufactured. The transport properties of the device were investigated.

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Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk 660041, Russia
Reshetnev Siberian State University of Science and Technology, Krasnoyarsk 660037, Russia

Доп.точки доступа:
Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Tarasov, A. S.; Тарасов, Антон Сергеевич; Shanidze, L. V.; Шанидзе, Лев Викторович; Yakovlev, I. A.; Яковлев, Иван Александрович; Zelenov, F. V.; Зеленов, Ф. В.; Masugin, A. N.; Масюгин, Альберт Николаевич; Ivanov, A. B.; Иванов, А. Б.; Baron, F. A.; Барон, Филипп Алексеевич; Volkov, N. V.; Волков, Никита Валентинович; International School and Conference on optoelectronics, photonics, engineering and nanostructures(6 ; 2019 ; 22-25 April ; Saint Petersburg)
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19.


    Flerov, I. N.
    Conversial and inversial barocaloric effects around triple points in ferroelastics (NH4)3NbOF6 and (NH4)3TiOF5 / I. N. Flerov, M. V. Gorev, E. V. Bogdanov // 2nd Journale of Thermal analysis and calorimetry conference : book of abstracts. - 2019. - P. 489-490. - Cited References:. - The reported study was funded by RFBR according to the research project No 18-02-00269 . - ISBN 978-963-454-416-6

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk
Institute of Engineering Systems and Energy, Krasnoyarsk State Agrarian University, Krasnoyarsk

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Флёров, Игорь Николаевич; Journale of Thermal Analysis and Calorimetry Conference(2 ; 2019 ; June. ; 18-21 ; Budapest, Hungary); Joint Czech-Hungarian-Polish-Slovakian) Thermoanalytical Conference(7 ; 2019 ; June. ; 18-21 ; Budapest, Hungary)
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20.


   
    Manipulation of Cl/Br transmutation in zero-dimensional Mn2+-based metal halides toward tunable photoluminescence and thermal quenching behaviors / G. J. Zhou, Z. Y. Liu, M. S. Molokeev [et al.] // J. Mater. Chem. C. - 2021. - Vol. 9, Is. 6. - P. 2047-2053, DOI 10.1039/d0tc05137c. - Cited References: 56. - The present work was financially supported by the Natural Science Foundation of China (21871167), and 1331 Project of Shanxi Province and the Postgraduate Innovation Project of Shanxi Normal University (2019XBY018), and funded by RFBR according to the research project no. 19-52-80003 . - ISSN 2050-7526. - ISSN 2050-7534
   Перевод заглавия: Манипуляции перестановок Cl/Br в нульмерных галогенидах металлов на основе Mn2+ для настраиваемой фотолюминесценции и ослабления термического тушения
РУБ Materials Science, Multidisciplinary + Physics, Applied

Аннотация: Low-dimensional-networked metal halides are attractive for the screening of emitters applied in solid-state lighting and displays, but the lead toxicity and poor stability are obstacles that must be overcome in industrial applications. Herein, we aim at the discovery of bright and stable photoluminescence in zero-dimensional (0D) Mn2+-based metal halides. By manipulation of Cl/Br transmutation, the nature of the halogen can be confirmed as a pivotal factor to tune the PL behaviors, and the optimum Mn2+ emission with a high PLQY of 99.8% and a short lifetime of 0.372 ms can be achieved in (C24H20P)2MnBr4. The thermal quenching behaviors have been discussed in depth, indicating that the synergistic effect of good chemical stability of organic groups, a long Mn⋯Mn distance of 10.447 Å and a relatively large activation energy (ΔE = 0.277 eV) provides a platform for achieving excellent thermal stability in (C24H20P)2MnBr4. Moreover, the as-fabricated white LED device with a high luminous efficacy of 118.9 lm W−1 and a wide color gamut of 105.3% National Television System Committee (NTSC) shows that (C24H20P)2MnBr4 can be employed as a desirable narrow-band green emitter for LED displays. This work provides a new understanding of fine tailoring halogens, and proposes a feasible approach to achieving high thermal stability emitters toward the targeted practical applications.

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Держатели документа:
Shanxi Normal Univ, Sch Chemist & Mat Sci, Key Lab Magnet Mol & Magnet Informat Mat, Minist Educ, Linfen 041004, Shanxi, Peoples R China.
Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Wuhan 430074, Peoples R China.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
South China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510641, Peoples R China.
South China Univ Technol, Inst Opt Commun Mat, Guangzhou 510641, Peoples R China.

Доп.точки доступа:
Zhou, Guojun; Liu, Zhiyang; Molokeev, M. S.; Молокеев, Максим Сергеевич; Xiao, Zewen; Xia, Zhiguo; Zhang, Xian-Ming
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