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    Mechanical activation of fullerene containing soot during extraction of higher and endohedral metallofullerenes / V. I. Elesina, G. N. Churilov, N. G. Vnukova [et al.] // Fuller. Nanotub. Carbon Nanostruct. - 2022. - Vol. 30, Is. 5. - P. 553-558, DOI 10.1080/1536383X.2021.1966421. - Cited References: 33 . - ISSN 1536-383X
   Перевод заглавия: Механоактивация фуллеренсодержащей сажи при экстракции высших и эндоэдральных металлофуллеренов
Кл.слова (ненормированные):
Fullerenes -- endohedral metallofullerenes -- extraction -- enrichment -- titanium chloride
Аннотация: For extraction of higher fullerenes and endohedral metallofullerenes (EMF) with yttrium from fullerene-containing carbon soot (soot) obtained by combined spraying of graphite and yttrium oxide powders in an arc plasma, we developed a device (Extractor*) that provides mechanical activation effects on agents combined with filtration. It has been shown that the soot recovery percentage of a mixture of higher fullerenes and EMF with different solvents (carbon disulfide, o-xylene, pyridine) and the EMF mass fraction in the mixture is significantly higher than in the extraction with a Soxhlet apparatus traditionally used for these purposes. The time spent on the extraction process is reduced significantly. Due to a known reaction with titanium chloride (TiCl4) and removal of a solution of empty fullerenes, subsequent bonding of EMF with yttrium into an insoluble complex directly in the extractor allows the product to be significantly enriched with EMF. In general, we were able to significantly reduce both the duration of extraction of the fullerenes mixture and EMF and the production of EMF separately.

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Держатели документа:
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics FRC KSC SB RAS, FSBSI "Federal Research Center "Krasnoyarsk Science Center SB RAS",, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Elesina, V. I.; Елесина, Виктория Игоревна; Churilov, G. N.; Чурилов, Григорий Николаевич; Vnukova, N. G.; Внукова, Наталья Григорьевна; Nikolaev, N. S.; Николаев, Никита Сергеевич; Glushenko, G. A.; Глущенко, Гарий Анатольевич; Isakova, V. G.; Исакова, Виктория Гавриловна
}
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    Cu-doped TiNxOy thin film resistors DC/RF performance and reliability / L. V. Shanidze, A. S. Tarasov, M. V. Rautskiy [et al.] // Appl. Sci. - 2021. - Vol. 11, Is. 16. - Ст. 7498, DOI 10.3390/app11167498. - Cited References: 13. - This research was funded by RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, project code 20-42-240013 and by Grant of the Government of the Russian Federation for Creation ofWorld Tier Laboratories (contract No. 075-15-2019-1886) . - ISSN 2076-3417
   Перевод заглавия: Производительность и надежность тонкопленочных резисторов TiNxOy, легированных медью

РУБ Chemistry, Multidisciplinary + Engineering, Multidisciplinary + Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
GROWTH
Кл.слова (ненормированные):
high-frequency passive components -- high power density -- thin film -- copper doped titanium oxynitride -- non-linear -- resistors -- heterogeneous integration
Аннотация: We fabricated Cu-doped TiNxOy thin film resistors by using atomic layer deposition, optical lithography, dry etching, Ti/Cu/Ti/Au e-beam evaporation and lift-off processes. The results of the measurements of the resistance temperature dependence, non-linearity, S-parameters at 0.01–26 GHz and details of the breakdown mechanism under high-voltage stress are reported. The devices’ sheet resistance is 220 ± 8 Ω/□ (480 ± 20 µΩ*cm); intrinsic resistance temperature coefficient (TCR) is ~400 ppm/°C in the T-range of 10–300 K; and S-parameters versus frequency are flat up to 2 GHz with maximum variation of 10% at 26 GHz. The resistors can sustain power and current densities up to ~5 kW*cm−2 and ~2 MA*cm−2, above which they switch to high-resistance state with the sheet resistance equal to ~200 kΩ/□ (~0.4 Ω*cm) caused by nitrogen and copper desorption from TiNxOy film. The Cu/Ti/TiNxOy contact is prone to ageing due to gradual titanium oxidation while the TiNxOy resistor body is stable. The resistors have strong potential for applications in high-frequency integrated and hybrid circuits that require small-footprint, medium-range resistors of 0.05–10 kΩ, with small TCR and high-power handling capability.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Dept Radio Elect, Krasnoyarsk 660041, Russia.
Reshetnev Siberian State Univ Sci & Technol, Inst Space Technol, Krasnoyarsk 660037, Russia.

Доп.точки доступа:
Shanidze, L. V.; Шанидзе, Лев Викторович; Tarasov, A. S.; Тарасов, Антон Сергеевич; Rautskiy, M. V.; Рауцкий, Михаил Владимирович; Zelenov, F. V.; Konovalov, S. O.; Nemtsev, I. V.; Немцев, Иван Васильевич; Voloshin, A. S.; Волошин, Александр Сергеевич; Tarasov, I. A.; Тарасов, Иван Анатольевич; Baron, F. A.; Барон, Филипп Алексеевич; Volkov, N. V.; Волков, Никита Валентинович; RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science [20-42-240013]; Government of the Russian Federation for Creation ofWorld Tier Laboratories [075-15-2019-1886]
}
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    Влияние охлаждения на возникновение намагниченности в никелиде титана / А. В. Достовалов, Ф. М. Носков, В. С. Жигалов, А. В. Нявро // Изв. Алт. гос. ун-та. - 2021. - № 1 (117). - С. 17-20, DOI 10.14258/izvasu(2021)1-02. - Библиогр.: 15 . - ISSN 1561-9443. - ISSN 1561-9451
   Перевод заглавия: Effect of cooling on the occurrence of magnetization in titanium nickelide
Кл.слова (ненормированные):
никелид титана -- ферромагнетизм -- микродеформации -- магнитометрия -- структура и свойства -- Ni-Ti alloy -- ferromagnetism -- microstrains -- magnetometry -- structure and properties
Аннотация: Вопрос возникновения намагниченности в сплавах системы никель-титан до сих пор изучен недостаточно. Наши ранние работы показали возможность возникновения намагниченности при многократных циклах прямых и обратных мартенситных переходах в сплаве Ni51Ti49, а также после деформации этого сплава растяжением до разрыва. Представленная работа посвящена выявлению эффекта намагниченности в образцах сплава Ni51Ti49 в результате их однократного охлаждения в жидком азоте, а также исчезновению намагниченности при нагревании образцов до комнатной температуры. С помощью индукционного петлескопа выявлено, что непосредственно после охлаждения образец имел высокую намагниченность. По мере нагревания образца петли гистерезиса изменяются, приобретая меньший наклон к горизонтальной оси, что свидетельствует об уменьшении магнитной индукции практически до нуля с повышением температуры до комнатной. Причину появления и исчезновения намагниченности можно связать с микродеформационными процессами, проходящими при охлаждении и нагревании образцов, связанными с прямым и обратным мартенситными переходами.
The occurrence of magnetization in alloys of the nickel-titanium system is still studied insufficiently. Our early work showed the possibility of magnetization arising during multiple cycles of forward and reverse martensitic transitions in the Ni51Ti49 alloy, as well as after deformation of this alloy by tensile stress to rupture. The purpose of this paper is devoted to revealing the effect of magnetization in samples of the Ni51Ti49 alloy as a result of their single cooling in liquid nitrogen, as well as the disappearance of magnetization when the samples are heated to room temperature. Using an induction hysteresigraph it is found out that the sample has a high magnetization immediately after cooling. As the sample is heated, the hysteresis loops change, acquiring a smaller inclination to the horizontal axis. It indicates a decrease in the magnetic induction to almost zero as the temperature rises to room temperature. The reason for the occurrence and disappearance of magnetization can be associated with micro-deformation processes related to forward and reverse martensitic transitions during cooling and heating of the samples.

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Держатели документа:
Сибирский федеральный университет (Красноярск, Россия)
Институт физики им. Л.В. Киренского (Красноярск, Россия)
Национальный исследовательский Томский государственный университет (Томск, Россия)

Доп.точки доступа:
Достовалов, А. В.; Носков, Ф. М.; Жигалов, Виктор Степанович; Zhigalov, V. S.; Нявро, А. В.
}
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Structural, optical, and electronic properties of Cu-doped TiNxOy grown by ammonothermal atomic layer deposition / F. A. Baron, Y. L. Mikhlin, M. S. Molokeev [et al.] // ACS Appl. Mater. Interfaces. - 2021. - Vol. 13, Is. 27. - P. 32531-32541, DOI 10.1021/acsami.1c08036. - Cited References: 69. - This research was funded by the RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science (project code 20-42-240013) and by the grant of the Government of the Russian Federation for Creation of World Tier Laboratories (contract no. 075-15-2019-1886) . - ISSN 1944-8244. - ISSN 1944-8252

РУБ Nanoscience & Nanotechnology + Materials Science, Multidisciplinary
Рубрики:
OXYNITRIDE THIN-FILMS
TITANIUM-NITRIDE
CONFORMAL TIN
Кл.слова (ненормированные):
atomic layer deposition -- titanium oxynitride -- copper doping -- surface segregation -- thin film
Аннотация: Copper-doped titanium oxynitride (TiNxOy) thin films were grown by atomic layer deposition (ALD) using the TiCl4 precursor, NH3, and O2 at 420 °C. Forming gas was used to reduce the background oxygen concentration and to transfer the copper atoms in an ALD chamber prior to the growth initiation of Cu-doped TiNxOy. Such forming gas-mediated Cu-doping of TiNxOy films had a pronounced effect on their resistivity, which dropped from 484 ± 8 to 202 ± 4 μΩ cm, and also on the resistance temperature coefficient (TCR), which decreased from 1000 to 150 ppm °C–1. We explored physical mechanisms causing this reduction by performing comparative analysis of atomic force microscopy, X-ray photoemission spectroscopy, X-ray diffraction, optical spectra, low-temperature transport, and Hall measurement data for the samples grown with and without forming gas doping. The difference in the oxygen concentration between the films did not exceed 6%. Copper segregated to the TiNxOy surface where its concentration reached 0.72%, but its penetration depth was less than 10 nm. Pronounced effects of the copper doping by forming gas included the TiNxOy film crystallite average size decrease from 57–59 to 32–34 nm, considerably finer surface granularity, electron concentration increase from 2.2(3) × 1022 to 3.5(1) × 1022 cm–3, and the electron mobility improvement from 0.56(4) to 0.92(2) cm2 V–1 s–1. The DC resistivity versus temperature R(T) measurements from 4.2 to 300 K showed a Cu-induced phase transition from a disordered to semimetallic state. The resistivity of Cu-doped TiNxOy films decreased with the temperature increase at low temperatures and reached the minimum near T = 50 K revealing signatures of the quantum interference effects similar to 2D Cu thin films, and then, semimetallic behavior was observed at higher temperatures. In TiNxOy films grown without forming gas, the resistivity decreased with the temperature increase as R(T) = – 1.88T0.6 + 604 μΩ cm with no semimetallic behavior observed. The medium range resistivity and low TCR of Cu-doped TiNxOy make this material an attractive choice for improved matching resistors in RF analog circuits and Si complementary metal–oxide–semiconductor integrated circuits.

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Держатели документа:
KSC SB RAS, Inst Chem & Chem Technol, Fed Res Ctr, Krasnoyarsk 660036, Russia.
KSC SB RAS, Kirensky Inst Phys, Fed Res Ctr, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Reshetnev Siberian State Univ Sci & Technol, Krasnoyarsk 660037, Russia.

Доп.точки доступа:
Baron, F. A.; Барон, Филипп Алексеевич; Mikhlin, Yurii L.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Rautskiy, M. V.; Рауцкий, Михаил Владимирович; Tarasov, I. A.; Тарасов, Иван Анатольевич; Volochaev, M. N.; Волочаев, Михаил Николаевич; Shanidze, L. V.; Шанидзе, Лев Викторович; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Smolyarova, T. E.; Смолярова, Татьяна Евгеньевна; Konovalov, Stepan O.; Zelenov, Fyodor, V; Tarasov, A. S.; Тарасов, Антон Сергеевич; Volkov, N. V.; Волков, Никита Валентинович; RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science [20-42-240013]; Government of the Russian Federation for Creation of World Tier Laboratories [075-15-2019-1886]
}
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Using titanium additives to produce high porous tiNi-based alloys with martensitic transformations / S. G. Anikeev, N. V. Artyukhova, M. I. Kaftaranova [et al.] // AIP Conf. Proc. - 2020. - Vol. 2310. - Ст. 020018DOI 10.1063/5.0034809. - Cited References: 13. - The study is funded by the Russian Science Foundation (project No. 19-79-10045)
Аннотация: Structural features of porous TiNi-based materials with Ti additives produced by diffusion sintering have been studied. TiNi powder fraction with a size of 100–160 µm used for sintering provides highly porous material. It is found that increased concentrations of Ti additives decrease the porosity coefficient of the material and increase the volumetric content of the secondary Ti2Ni and Ti4Ni2 (0, N, C) phases. It is shown that Ti powder additives can be used to improve the atomic composition of the TiNi compound.

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Держатели документа:
National Research Tomsk State University, Tomsk, 634050, Russian Federation
Kirensky Institute of Physics, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Anikeev, S. G.; Artyukhova, N. V.; Kaftaranova, M. I.; Khodorenko, V. N.; Monogenov, A. N.; Volochaev, M. N.; Волочаев, Михаил Николаевич; Garin, A. S.; Mamazakirov, O. R.; International Conference on Physical Mesomechanics. Materials with Multilevel Hierarchical Structure and Intelligent Manufacturing Technology 2020(5 - 9 October 2020 ; Tomsk, Russian Federation)
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Emergence of ferromagnetism in nanoparticles of BeTiO3 ceramic with the perovskite structure / A. V. Pavlov, L. I. Kveglis, D. N. Saprykin [et al.] // Inorg. Mater.: Appl. Res. - 2021. - Vol. 12, Is. 1. - P. 88-93, DOI 10.1134/S2075113321010330. - Cited References: 21. - The part of the work involving calculations was supported by the Russian Science Foundation (grant no. 18-19-00268) . - ISSN 2075-1133
Кл.слова (ненормированные):
titanium dioxide nanopowder -- rutile structure -- beryllium ceramic -- magnetic hysteresis -- electrical resistance -- electronic structure -- icosahedral clusters
Аннотация: Emergence of ferromagnetism and an increase in the electrical conductance of BeTiO3 beryllium ceramic with the perovskite structure were discovered experimentally. To explain the reason for appearance of the metallic properties, models are proposed, and calculations of the electronic structure of nanoclusters with different short-range order are performed.

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Публикация на русском языке Появление ферромагнетизма в наночастицах керамики со структурой перовскита BeTiO3 [Текст] / А. В. Павлов, Л. И. Квеглис, Д. Н. Сапрыкин [и др.] // Материаловедение. - 2020. - № 5. - С. 15-20

Держатели документа:
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Sarsen Amanzholov East Kazakhstan State University, Ust’-Kamenogorsk, 070000, Kazakhstan
Tomsk State University, Tomsk, 634050, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Pavlov, A. V.; Kveglis, L. I.; Saprykin, D. N.; Nasibullin, R. T.; Kalitova, A. A.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Nemtsev, I. V.; Немцев, Иван Васильевич; Kantai, N.
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Magnetic properties of nickel-titanium alloy during martensitic transformations under plastic and elastic deformation / L. I. Kveglis, F. M. Noskov, M. N. Volochaev [et al.] // Symmetry. - 2021. - Vol. 13, Is. 4. - Ст. 665, DOI 10.3390/sym13040665. - Cited References: 61 . - ISSN 2073-8994

РУБ Multidisciplinary Sciences
Рубрики:
NITI SHAPE-MEMORY
   CRYSTAL-STRUCTURE
   WAVE MECHANICS
   TRANSITIONS
Кл.слова (ненормированные):
titanium nickelide -- deformation -- martensitic transformation -- electron diffraction -- ferromagnetism -- clusters
Аннотация: This paper focuses on the processes of the occurrence of magnetization during structure formation in samples of Ni51Ti49 alloy under deformation conditions. The possibility of the existence of a phase with an FCC (face-centered cubic) lattice in titanium nickelide has been demonstrated by electron microscopy and electron diffraction. It has been discovered that the interplanar distances of BCC110 (body-centered cubic), FCC111, and HCP002 (hexagonal close packed) in the alloy under study have similar values, which indicates the possibility of their mutual polymorphic transformation. Based on the modular self-organization, a scheme of martensitic transformations in titanium nickelide from the B2 structure (BCC lattice) to the B19' structure (HCP lattice) through an intermediate phase with an FCC lattice is proposed. It is shown that lenticular crystals appear in the Ni51Ti49 alloy under tensile deformation until rupture, which is accompanied by the onset of ferromagnetism. The effect of magnetization in Ni51Ti49 samples when immersed in liquid nitrogen has been also discovered. In this case, the reason for the appearance and disappearance of magnetization can be associated with microdeformation processes caused by direct and reverse martensitic transitions that occur during cooling and heating of the samples.

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Держатели документа:
Siberian Fed Univ, Polytech Inst, Svobodny Ave 79, Krasnoyarsk 660041, Russia.
Amanjolov East Kazakhstan Univ, Phys Dept, 30th Guards Div Str 34, Ust Kamenogorsk 070002, Kazakhstan.
Russian Acad Sci, Kirensky Inst Phys, Siberian Div, Akad Gorodok 50, Akademgorodok 660036, Russia.
Tomsk State Univ, Natl Res, Lenin Ave 36, Tomsk 634050, Russia.
Univ Wroclaw, Fac Chem, 14 F Joliot Curie Str, PL-50383 Wroclaw, Poland.
Ind Univ Tyumen, Ctr Adv Res & Innovat, Volodarsky Str 38, Tyumen 625000, Russia.

Доп.точки доступа:
Kveglis, Ludmila I.; Noskov, Fedor M.; Volochaev, M. N.; Волочаев, Михаил Николаевич; Nyavro, Alexander V.; Filarowski, Aleksander
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Titanium oxynitride thin films wide temperature range sensors / F. A. Baron, L. V. Shanidze, M. V. Rautskiy [et al.] // Tech. Phys. Lett. - 2022. - Vol. 48, Is. 10. - P. 74-77, DOI 10.21883/TPL.2022.10.54805.19292. - Cited References: 14. - This study was supported financially by the Russian Foundation for Basic Research, the Government of Krasnoyarsk Krai, and the Krasnoyarsk Krai Foundation of Science as part of scientific project No. 20-42-240013. The Rutherford backscattering study of samples was performed at Research and Education Center ” Functional Nanomaterials“ of the Baltic Federal University with financial support from the Ministry of Science and Higher Education of the Russian Federation (project FZWN-2020-0008) . - ISSN 1063-7850. - ISSN 1090-6533
Кл.слова (ненормированные):
titanium oxide-nitride -- temperature sensors -- thin films -- atomic layer deposition -- integrated circuit components
Аннотация: The temperature dependence of the resistivity of titanium oxynitride TiNxOy thin films with different oxygen and nitrogen content obtained by atomic layer deposition was investigated. We found that the resistance of all films monotonically decreased with increasing temperature and varied within a wide range depending on the chemical composition and thickness of the film. The technology for obtaining a compact temperature sensor of wide range from helium to room temperature based on 40 nm thick TiN0.87O0.97 is presented.

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Публикация на русском языке Тонкие пленки оксинитрида титана для сенсоров широкого диапазона температур [Текст] / Ф. А. Барон, Л. В. Шанидзе, М. В. Рауцкий [и др.] // Письма в Журн. техн. физ. - 2022. - Т. 48 Вып. 20. - С. 39-42

Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
Institute of Chemistry and Chemical Technology, Federal Research Center KSC SB RAS, Russian Academy of Sciences, Krasnoyarsk, Russia
Reshetnev Siberian State Aerospace University, Krasnoyarsk, Russia
Research and Education Center “Functional Nanomaterials”, Immanuel Kant Baltic Federal University, Kaliningrad, Russia

Доп.точки доступа:
Baron, F. A.; Барон, Филипп Алексеевич; Shanidze, L. V.; Шанидзе, Лев Викторович; Rautskiy, M. V.; Рауцкий, Михаил Владимирович; Mikhlin, Yu. L.; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Konovalov, S. O.; Zelenov, F. V.; Shvets, P. V.; Goikhman, A. Yu.; Volkov, N. V.; Волков, Никита Валентинович; Tarasov, A. S.; Тарасов, Антон Сергеевич
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    Semi-artificial photosynthetic system based on TiO2/Chlorophyll composite and microalgae for N2 fixation / X. Pan, W. Li, Yu. Fang [et al.] // Chem. Eng. J. - 2023. - Vol. 475. - Ст. 146179, DOI 10.1016/j.cej.2023.146179. - Cited References: 45. - The work was supported by the National Natural Science Foundations of China (No. 12274144), the Ministry of Science and Technology of China (No. G2021030022L), the Guangdong Provincial Special Fund for Modern Agriculture Industry Technology Innovation Teams (No. 2022KJ122, 2023KJ122), the Key Realm R&D Program of Guangdong Province (No. 2021B0707010003), the Guangzhou Science & Technology Project (No. 202103000059), the Guangdong Provincial Science and Technology Project (No. 2021A0505050006), and the Project of GDUPS (2018) for Prof. Bingfu LEI . - ISSN 1385-8947. - ISSN 1873-3212
   Перевод заглавия: Полуискусственная фотосинтетическая система на основе композита TiO2/Хлорофилл и микроводорослей для фиксации N2
Кл.слова (ненормированные):
Microalgae -- Titanium -- Ubiquinone-0 -- Ammonia
Аннотация: Significant process has been made on the development of semi-artificial photosynthesis catering to the production of H2– and CO2– derived value-added products. But there are little reports on the application of semi-artificial photosynthetic system to nitrogen fixation areas. In this study we report the successful and highly efficient N2 fixation in one step at room temperature and ambient pressure by constructing new semi-artificial photosynthetic systems based on material-cell hybrids and microbial photo-electrolysis cells (MPECs). Improved TiO2/Chlorophyll composite that annealed at 400 °C was selected as electron donator to replenish additional electrons to Nostoc commune Vauch microalgae cell for N2 fixation. Ubiquinone-0 (2,3-dimethoxy-5-methyl-1,4-benzoquinone, Q0) was selected as electron relay that guarantees efficient transmission of electrons from abiotic material to microalgae cells. Determined by an ammonia assay kit, at constant concentration of microalgae, the constructed material-cell hybrid system photosynthetically synthesized 40.67 μM/h ammonia, while H-shape MPECs synthesized 132.70 μM/h, 19.23 times higher than that produced by pure microalgae. Using 15N2 as the reduction gas, the constructed H-shape MPECs photosynthetically synthesized 28.37 μM/h 15NH4+, 2.80 time higher than that of the MPECs without Q0 as electron relay.

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Держатели документа:
Key Laboratory for Biobased Materials and Energy of Ministry of Education, Guangdong Provincial Engineering Technology Research Center for Optical Agriculture, College of Materials and Energy, College of Materials and Energy, South China Agricultural University, Guangzhou 510642, China
Kirensky Institute of Physics, Federal Research Center, Krasnoyarsk Scientific Center, Siberian Branch of Russian Academy of Science, Academgorodolk 50 bld.38, 660036, Russia
WA School of Mines: Minerals, Energy and Chemical Engineering, Curtin University, Perth, Western Australia 6102, Australia
Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory, Foshan 528216, China

Доп.точки доступа:
Pan, Xiaoqin; Li, Wei; Fang, Yueping; Zhang, Haoran; Xiao, Yong; Molokeev, M. S.; Молокеев, Максим Сергеевич; Ping Jiang, San; Liu, Yingliang; Lei, Bingfu
}
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10.

Temperature Raman study of Li4Ti5O12 and ambiguity in the number of its bands / A. A. Nikiforov, A. S. Krylov, S. N. Krylova [et al.] // J. Raman Spectrosc. - 2024. - Vol. 55, Is. 3. - P. 406-415, DOI 10.1002/jrs.6641. - Cited References: 51. - The research was funded by the Russian Science Foundation (project No 22-22-00350, https://rscf.ru/project/22-22-00350) . - ISSN 0377-0486. - ISSN 1097-4555
Кл.слова (ненормированные):
defects -- distortions -- lithium titanate -- lithium titanium oxide -- spinel structure
Аннотация: The two primary physical methods for identifying lithium titanate, a negative electrode material used commercially, are X-Ray diffraction and Raman spectroscopy. Although there are many publications on this topic, they are focused mainly on chemistry, so there are still some points that require clarification from a physical and methodological point of view. Difference of experimentally observed and theoretically predicted Raman spectra was explained through a combination of experiments and computations. The work comprises experiments and computations to explain why there are different numbers of predicted and observed Raman-active bands. Our low-temperature study and the analysis of thermal shifts during heating led us to conclude that the approach with surplus bands is advantageous and we recommend using major F2g band shifts to estimate the sample heating.

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Institute of Natural Sciences and Mathematics, Ural Federal University, Ekaterinburg, Russia
L.V. Kirensky Institute of Physics SB RAS, Krasnoyarsk, Russia
Independent Researcher, Ekaterinburg, Russia

Доп.точки доступа:
Nikiforov, A. A.; Krylov, A. S.; Крылов, Александр Сергеевич; Krylova, S. N.; Крылова, Светлана Николаевна; Gorshkov, V. S.; Pelegov, D. V.
}
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11.

Tamm plasmons in TiO2 nanotube photonic crystals / M. V. Pyatnov, R. G. Bikbaev, I. V. Timofeev [et al.] // Photonics. - 2023. - Vol. 10, Is. 1. - Ст. 64, DOI 10.3390/photonics10010064. - Cited References: 40. - This research was funded by Russian Science Foundation and Krasnoyarsk Regional Fund of Science, project № 22-22-20078, https://rscf.ru/project/22-22-20078/ (accessed on 01 January 2023) . - ISSN 2304-6732
Кл.слова (ненормированные):
photonic crystals -- titanium dioxide -- absorbers -- anodization
Аннотация: The anodic TiO2 photonic crystals evoke great interest for application as photocatalytic media due to high absorption of light resuling from their specific structure. In this work, the optical properties of the photonic crystal based on a bamboo-type TiO2 nanotube with a metallic coating are analyzed theoretically by the finite-difference time-domain method. The occurrence of Tamm plasmons that appears as a peak in the absorption spectrum is predicted. A Tamm plasmon polariton is a localized state of light excited at the boundary of two highly reflective media, a metal and a Bragg reflector. The integral absorption of the gold-, titanium-, and titanium nitride-coated photonic crystals in the wavelength range of 450–600 nm is calculated. It is established that the titanium nitride-coated structure exhibits the maximum integral absorption.

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Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, 660036 Krasnoyarsk, Russia
Siberian Federal University, 660041 Krasnoyarsk, Russia
Institute of Computational Modelling, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, 660036 Krasnoyarsk, Russia

Доп.точки доступа:
Pyatnov, M. V.; Пятнов, Максим Владимирович; Bikbaev, R. G.; Бикбаев, Рашид Гельмединович; Timofeev, I. V.; Тимофеев, Иван Владимирович; Ryzhkov, Ilya I.; Vetrov, S. Ya.; Ветров, Степан Яковлевич; Shabanov, V. F.; Шабанов, Василий Филиппович
}
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12.

Synthesis and structural, magnetic, and thermal properties of the titanium-doped Pb3Mn7O15 compound / S. N. Sofronova, E. V. Eremin, M. S. Molokeev [et al.] // Phys. Solid State. - 2021. - Vol. 63, Is. 4. - P. 654-659, DOI 10.1134/S1063783421040223. - Cited References: 10. - This study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk krai, and the Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project no. 18-42-240007 . - ISSN 1063-7834. - ISSN 1090-6460

РУБ Physics, Condensed Matter

Кл.слова (ненормированные):
manganites -- magnetic phase transition -- indirect exchange coupling
Аннотация: The Pb3Mn7O15 crystals doped with titanium ions have been synthesized. The study of the structural properties has shown that titanium ions occupy positions in the interplane columns, which weakens the exchange coupling between the planes. Two anomalies in the temperature dependences of magnetization and heat capacity at 62 and 35 K have been found. It has been supposed that, at 62 K, the long-range magnetic order arises and, at 35 K, a spin-reorientation transition, as in the Pb3Mn7O15 compound, occurs.

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Публикация на русском языке Синтез, структурные, магнитные и теплофизические свойства Pb3Mn7O15, допированного ионами титана [Текст] / С. Н. Софронова, Е. В. Еремин, М. С. Молокеев [и др.] // Физ. тверд. тела. - 2021. - Т. 63 Вып. 4. - С. 545-549

Держатели документа:
Russian Acad Sci, Krasnoyarsk Sci Ctr, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Sofronova, S. N.; Софронова, Светлана Николаевна; Eremin, E. V.; Еремин, Евгений Владимирович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Mikhashenok, N. V.; Михашенок, Наталья Владимировна; Kartashev, A. V.; Карташев, Андрей Васильевич; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of the Krasnoyarsk krai; Krasnoyarsk Territorial Foundation for Support of Scientific and RD Activities [18-42-240007]
}
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13.

Why the magnetite-gold core-shell nanoparticles are not quite good and how to improve them / A. E. Sokolov, O. S. Ivanova, A. S. Fedorov [et al.] // Phys. Solid State. - 2021. - Vol. 63, Is. 10. - P. 1536-1540, DOI 10.1134/S1063783421090365. - Cited References: 35. - This study was supported by the Russian Foundation for Basic Research, project no. 19-52-52002, and the Ministry of Science and Technology of Taiwan, projects MOST nos. 109-2112-M-153-003 and 108-2923-M-153-001-MY3 . - ISSN 1063-7834. - ISSN 1090-6460

РУБ Physics, Condensed Matter
Рубрики:
IRON-OXIDE NANOPARTICLES
   TOTAL-ENERGY CALCULATIONS
   STABILITY
   DESIGN
Кл.слова (ненормированные):
core-shell magnetic nanoparticles -- magnetite-gold interface -- magnetite-titanium-gold trilayer
Аннотация: The nature of the formation of a chemical bond at the magnetite-gold interface has been studied. The geometric structure and the electronic and magnetic properties of plane layers consisting of magnetite Fe3O4 and gold have been investigated using the DFT-GGA calculation. It has been found that the specific energy and the wetting parameter of the magnetite-gold interface are negative, which leads to the island growth of small Au particles on the Fe3O4 surface. The role of an intermediate thin titanium layer between magnetite and gold has been discussed. The specific energy and wetting parameter of the magnetite-titanium (for thin Ti layers) and magnetite-titanium-gold interfaces are positive. It has been suggested that an intermediate thin titanium layer at the interface between the magnetite nanoparticle surface and the gold layer will make it possible to obtain magnetite nanoparticles with a continuous gold coating.

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Публикация на русском языке Почему наночастицы магнетит/золото со структурой ядро-оболочка недостаточно хороши и как их улучшить [Текст] / А. Э. Соколов, О. С. Иванова, А. С. Федоров [и др.] // Физ. тверд. тела. - 2021. - Т. 63 Вып. 9. - С. 1367-1371

Держатели документа:
Russian Acad Sci, Krasnoyarsk Sci Ctr, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Tomsk State Univ, Tomsk 634050, Russia.
Natl Pingtung Univ, Pingtung 90003, Pingtung County, Taiwan.

Доп.точки доступа:
Sokolov, A. Е.; Соколов, Алексей Эдуардович; Ivanova, O. S.; Иванова, Оксана Станиславовна; Fedorov, A. S.; Федоров, Александр Семенович; Kovaleva, E. A.; Vysotin, M. A.; Высотин, Максим Александрович; Lin, C-R; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [19-52-52002]; Ministry of Science and Technology of TaiwanMinistry of Science and Technology, Taiwan [109-2112-M-153-003, 108-2923-M-153-001-MY3]
}
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14.

    Узкие резонансы в периодических структурах на основе термостойкого нитрида титана / В. И. Закомирный, В. С. Герасимов [и др.] // Решетневские чтения : [Электронный ресурс] : материалы XXI Междунар. науч.-практич. конф., посвящ. памяти ген. конструктора ракет.-космич. систем акад. М. Ф. Решетнева : в 2-х ч. : электронное издание. - Красноярск : СибГУим. М. Ф. Решетнева, 2017. - Ч. 1. - С. 609-611. - Библиогр.: 6
   Перевод заглавия: Narrow resonances in periodic structures based on refractory titanium nitride
Аннотация: Исследованы возможности применения нитрида титана (TiN) для получения высокодобротного поверхностного резонанса на периодической структуре сферических наночастиц. Полученные данные открывают перспективы для использования 2D массивовиз TiN наночастиц в качестве элементов оптических интегральных микросхем нового поколения.

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Держатели документа:
Сибирский федеральный университет 660041 Красноярск, проспект Свободный, 79
Институт вычислительного моделирования СО РАН
Королевский технологический институт, Швеция
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Закомирный, Вадим Игоревич; Герасимов, Валерий Сергеевич; Gerasimov, V. S.; Ершов, Александр Евгеньевич; Ershov, A. E.; Карпов, Сергей Васильевич; Karpov, S.V.; "Решетневские чтения", международная научно-практическая конференция(21 ; 2017 ; нояб. ; 8-11 ; Красноярск); Сибирский государственный университет науки и технологий им. акад. М. Ф. Решетнева; Информационные спутниковые системы им. академика М. Ф. Решетнева, АО; Красноярский машиностроительный завод, ОАО
}
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15.

Magnetic properties of plastically deformed nickel-titanium alloy / L. I. Kveglis [et al.] // VI Euro-Asian Symposium "Trends in MAGnetism" (EASTMAG-2016) : abstracts / ed.: O. A. Maksimova, R. D. Ivantsov. - Krasnoyarsk : KIP RAS SB, 2016. - Ст. P9.30. - P. 421. - References: 3 . - ISBN 978-5-904603-06-9
Кл.слова (ненормированные):
martensite transformation -- ferromagnetic phase -- lenticular nanocrystals

Доп.точки доступа:
Kveglis, L. I.; Квеглис, Людмила Иосифовна; Volochaev, M. N.; Волочаев, Михаил Николаевич; Dzhes, A. V.; Джес, Алексей Владимирович; Noskov, F. M.; Носков, Федор Михайлович; Euro-Asian Symposium "Trends in MAGnetism"(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); "Trends in MAGnetism", Euro-Asian Symposium(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); Институт физики им. Л.В. Киренского Сибирского отделения РАН

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16.

Titanium nitride as light trapping plasmonic material in silicon solar cell / N. Venugopal [et al.] // Opt. Mater. - 2017. - Vol. 72. - P. 397-402, DOI 10.1016/j.optmat.2017.06.035. - Cited References: 56 . - ISSN 0925-3467
Кл.слова (ненормированные):
Photovoltaics -- Plasmonics -- Titanium nitride
Аннотация: Light trapping is a crucial prominence to improve the efficiency in thin film solar cells. However, last few years, plasmonic based thin film solar cells shows potential structure to improve efficiency in photovoltaics. In order to achieve the high efficiency in plasmonic based thin film solar cells, traditionally noble metals like Silver (Ag) and Gold (Au) are extensively used due to their ability to localize the light in nanoscale structures. In this paper, we numerically demonstrated the absorption enhancement due to the incorporation of novel plasmonic TiN nanoparticles on thin film Silicon Solar cells. Absorption enhancement significantly affected by TiN plasmonic nanoparticles on thin film silicon was studied using Finite-Difference-Time-Domain Method (FDTD). The optimal absorption enhancement 1.2 was achieved for TiN nanoparticles with the diameter of 100 nm. The results show that the plasmonic effect significantly dominant to achieve maximum absorption enhancement g(λ) at longer wavelengths (red and near infrared) and as comparable with Au nanoparticle on thin film Silicon. The absorption enhancement can be tuned to the desired position of solar spectrum by adjusting the size of TiN nanoparticles. Effect of nanoparticle diameters on the absorption enhancement was also thoroughly analyzed. The numerically simulated results show that TiN can play the similar role as gold nanoparticles on thin film silicon solar cells. Furthermore, TiN plasmonic material is cheap, abundant and more Complementary Metal Oxide Semiconductor (CMOS) compatible material than traditional plasmonic metals like Ag and Au, which can be easy integration with other optoelectronic devices.

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Держатели документа:
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, Russian Federation
Institute of Computational Modeling, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
L.V. Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Venugopal, N.; Gerasimov, V. S.; Герасимов, Валерий Сергеевич; Ershov, A. E.; Ершов, Александр Евгеньевич; Karpov, S. V.; Карпов, Сергей Васильевич; Polyutov, S. P.
}
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17.

    Structure and magnetic properties of titanium nickelide nanoparticles synthesized by pulsed laser ablation method / A. K. Drozdova [et al.] // J. Phys. Conf. Ser. - 2017. - Vol. 857, Is. 1. - Ст. 012007, DOI 10.1088/1742-6596/857/1/012007. - Cited References: 9 . - ISSN 1742-6588
   Перевод заглавия: Структура и магнитные свойства наночастиц никелида титана, синтезированных методом импульсной лазерной абляции
Кл.слова (ненормированные):
Ablation -- Coatings -- High resolution transmission electron microscopy -- Laser ablation -- Nanomagnetics -- Nanoparticles -- Synthesis (chemical) -- Titanium -- Transmission electron microscopy -- Equiatomic composition -- Magnetization values -- Ti atoms -- Titanium nickelide -- Pulsed lasers
Аннотация: We have successfully synthesized magnetic titanium nickelide nanoparticles with equiatomic composition by pulsed laser ablation method. Using transmission electron microscopy and microanalysis was revealed that particles represent the homogeneous conglomerates containing identical amount of Ni and Ti atoms. The magnetization value of nanoparticles was estimated.

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Доп.точки доступа:
Drozdova, A. K.; Cherepanov, V. N.; Svetlichny, V. A.; Kveglis, L. I.; Volochaev, M. N.; Волочаев, Михаил Николаевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; International Conference on Films and Coatings(13 ; 18-20 April 2017 ; St. Petersburg)
}
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18.

Особенности формирования линзовидных кристаллов при мартенситных превращениях в никелиде титана / А. С. Джес [и др.] // Фундамент. проблемы совр. материаловед. - 2016. - Т. 13, № 1. - С. 96-104 . - ISSN 1811-1416
Кл.слова (ненормированные):
titanium nickelide -- plastic deformation -- martensitic transformation -- Lenticular crystals -- bending extinction contours -- method of magnetic torques -- никелид титана -- пластическая деформация -- мартенситное превращение -- линзовидные кристаллы -- изгибные экстинкционные контуры -- метод магнитных крутящих моментов
Аннотация: В работе рассматриваются процессы структурообразования в массивных образцах сплава Ni51Ti49 подвергнутых растягивающей нагрузке. Методами электронной микроскопии обнаружены линзовидные кристаллы, имеющие химический состав и структуру, отличающийся от состава матричного сплава. С помощью анализа изгибных экстинкционных контуров на электронно-микроскопических изображениях линзовидных кристаллов сделаны оценки внутренних напряжений в зонах локализации деформации. Показано, что образцы сплава Ni51Ti49 испытавшие множественные циклы прямых и обратных мартенситных переходов обладают ненулевой намагниченностью, вызванной ростом новой ферромагнитной фазы.
The paper deals with the processes of structure formation in massive Ni51Ti49 alloy samples subjected to tensile loading. Electron microscopy revealed lenticular crystals having a chemical composition and structure, wherein the composition of the matrix alloy. By analyzing bending extinction contours on electron microscopic images of lenticular crystals made assessment of internal stresses in the areas of localization of deformation. It is shown that the alloy samples Ni51Ti49 experienced multiple cycles of direct and reverse martensitic transformations have a non-zero magnetization caused by the growth of new ferromagnetic phase.

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Держатели документа:
Восточно-Казахстанский государственный технический университет
Восточно-Казахстанский государственный университет
Институт физики СО РАН
Сибирский федеральный университет

Доп.точки доступа:
Джес, Алексей Владимирович; Носков, Федор Михайлович; Квеглис, Людмила Иосифовна; Волочаев, Михаил Николаевич; Volochaev, M. N.; Тажибаева, Гаухар Баранбаевна
}
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19.

Krasnov, P. O.
Interaction of Scandium and Titanium Atoms with a Carbon Surface Containing Five- and Seven-Membered Rings / P. O. Krasnov, N. S. Eliseeva, A. A. Kuzubov // J. Exp. Theor. Phys. - 2012. - Vol. 114, Is. 1. - P. 80-84, DOI 10.1134/S1063776111160059. - Cited References: 25. - We are grateful to the Joint Supercomputer Center, Russian Academy of Sciences, for the possibility of using the computer cluster for our quantum-chemical calculations. This work was supported by the Ministry of Education and Science of the Russian Federation (federal program "Human Capital for Science and Education in Innovative Russia" for 2009-2013). . - ISSN 1063-7761. - ISSN 1090-6509

РУБ Physics, Multidisciplinary
Рубрики:
MOLECULAR-HYDROGEN COMPLEXES
   STORAGE
   NANOTUBES
   TRANSITION
   ENERGY
   TEMPERATURE
   EXCHANGE
   DYNAMICS
   METALS
   C60
Аннотация: The use of carbon nanotubes coated by atoms of transition metals to store molecular hydrogen is associated with the problem of the aggregation of these atoms, which leads to the formation of metal clusters. The quantum-chemical simulation of cluster models of the carbon surface of a graphene type with scandium and titanium atoms has been performed. It has been shown that the presence of five- and seven-membered rings, in addition to six-membered rings, in these structures makes it possible to strongly suppress the processes of the migration of metal atoms over the surface, preventing their clustering.

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Публикация на русском языке Краснов, Павел Олегович. Взаимодействие атомов скандия и титана с углеродной поверхностью, содержащей пятичленные и семичленные кольца [Текст] / П. О. Краснов, Н. С. Елисеева, А. А. Кузубов // Журн. эксперим. и теор. физ. : Наука, 2012. - Т. 141 Вып. 1. - С. 90-95

Держатели документа:
[Krasnov, P. O.
Kuzubov, A. A.] Siberian State Technol Univ, Krasnoyarsk 660049, Russia
[Krasnov, P. O.
Kuzubov, A. A.] Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
[Eliseeva, N. S.
Kuzubov, A. A.] Siberian Fed Univ, Krasnoyarsk 660041, Russia

Доп.точки доступа:
Eliseeva, N. S.; Kuzubov, A. A.; Кузубов, Александр Александрович; Краснов, Павел Олегович; Ministry of Education and Science of the Russian Federation
}
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20.

Calculation of the energy of binding of titanium and scandium complexes to the surface of carbon nanotubes / A. A. Kuzubov [et al.] // Russ. J. Phys. Chem. B. - 2009. - Vol. 3, Is. 4. - P. 679-683, DOI 10.1134/S1990793109040289. - Cited References: 27. - This work was supported by the analytical departmental program "Development of Higher Education Potential (2009-2100)" (grant 2.1.1/2584) and by the Russian Foundation for Basic Research, project no. 09-02-00324-a. . - ISSN 1990-7931

РУБ Physics, Atomic, Molecular & Chemical
Рубрики:
MOLECULAR-HYDROGEN COMPLEXES
   STORAGE
   TEMPERATURE
   TRANSITION
   DYNAMICS
   METALS
Аннотация: Complexes of zigzag-type carbon nanotubes (CNTs) with transition metal atoms, scandium and titanium, were studied. It was demonstrated that the energy of binding of both atoms with a carbon surface decreases whereas the rate of diffusion along the surface increases with increasing nanotube diameter. The rate constant of migration of scandium atoms over a CNT surface are several orders of magnitude higher than that for titanium atoms, because the CNT surface-Sc atom binding energy is substantially lower.

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Держатели документа:
Institute of Natural and Humanitarian Sciences, Siberian Federal University, Krasnoyarsk 660041, Russian Federation
Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Siberian State Technological University, Krasnoyarsk 660049, Russian Federation

Доп.точки доступа:
Kuzubov, A. A.; Кузубов, Александр Александрович; Krasnov, P. O.; Краснов, Павел Олегович; Kozhevnikov, T. A.; Popov, M. A.; Analytical departmental program "Development of Higher Education Potential" [2.1.1/2584]; Russian Foundation for Basic Research [09-02-00324-a]
}
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