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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Udod L. V., Sitnikov M. N., Velikanov D. A., Gorev M. V., Molokeev M. S., Galyas A. I., Yanushkevich K. I.
Заглавие : Magnetic and electrical properties of bismuth cobaltite Bi24(CoBi)O40 with charge ordering
Место публикации : Phys. Solid State. - 2012. - Vol. 54, Is. 10. - P.2005-2014. - ISSN 1063-7834, DOI 10.1134/S106378341210006X
Примечания : Cited References: 22. - This study was supported by the Russian Foundation for Basic Research (project nos. 09-02-92001-NNS_a, 12-02-00125-a, and 11-02-98004-r_sibir'_a)
Предметные рубрики: Thermoelectric-power
Co3O4
Conductivity
Transition
Аннотация: The compound Bi24(CoBi)O40 has been synthesized using the solid-phase reaction method. The temperature and field dependences of the magnetic moment in the temperature range 4 K T 300 K and the temperature dependences of the EPR line width and g-factor at temperatures 80 K T 300 K have been investigated. The electrical resistivity and thermoelectric power have been measured in the temperature range 100 K T 1000 K. The activation energy has been determined and the crossover of the thermoelectric power from the phonon mechanism to the electron mechanism with variations in the temperature has been observed. The thermal expansion coefficient of the samples has been measured in the temperature range 300 K T 1000 K and the qualitative agreement with the temperature behavior of the electrical resistivity has been achieved. The electrical and structural properties of the compound have been explained in the framework of the model of the electronic-structure transition with inclusion of the exchange and Coulomb interactions between electrons and the electron-phonon interaction.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Cherepakhin A. V., Zaitsev A. I., Aleksandrovsky A. S., Zamkov A. V.
Заглавие : Optical and nonlinear optical properties of orthorhombic BiB3O6
Место публикации : Opt. Mater.: Elsevier Science BV, 2012. - Vol. 34, Is. 5. - P.790-792. - ISSN 0925-3467, DOI 10.1016/j.optmat.2011.11.004
Примечания : Cited References: 13. - The work was supported by Ministry of Education and Science of Russian Federation (Contract 16.740.11.0150), Grant of President of Russian Federation for support of leading scientific schools No. SS-4645.2010.2, Grant No. RNP.2.1.1.3455, Project 3.9.1 of PSB RAS, and Projects No. 27.1 and No. 5 of SB RAS.
Предметные рубрики: BISMUTH BORATE BIB3O6
CRYSTAL
LASER
GENERATION
GROWTH
BIBO
Ключевые слова (''Своб.индексиров.''): orthorhombic bismuth triborate delta-bibo--refractive indices--nonlinear optical coefficients--nonlinear optical materials--phase matching
Аннотация: Dispersion of refraction coefficients of orthorhombic BiB3O6 in the wavelength range between 435.8 and 1060 nm is studied, nonlinear optical coefficients are determined, and phase matching angles, angular and spectral bandwidths for second harmonic generation processes are calculated. delta-BiBO may be suitable for doubling of lasers with a wavelength in the 1.3 mu m region as well as the matrix for self-doubling lasing media. (C) 2011 Elsevier B.V. All rights reserved.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vasiliev A. D., Golovnev N. N.
Заглавие : Crystal structure of hexakis(thiourea)-bis((μ-perchlorato-O,O')- (perchlorato-O)-bismuth) diperchlorate
Место публикации : Russ. J. Coordin. Chem. - 2013. - Vol. 39, Is. 2. - P.161-164. - ISSN 1070-3284, DOI 10.1134/S1070328413020097
Ключевые слова (''Своб.индексиров.''): crystallographic data--hydrogen atoms--hydrogen bond networks--ir and raman spectroscopy--space groups--sulfur atoms--atoms--complex networks--hydrogen bonds--raman spectroscopy--single crystals--x ray diffraction--thioureas
Аннотация: The complex[Bi2(Tu)6(ClO4) 4](ClO4)2 (I) (Tu is thiourea) was synthesized and studied by X-ray diffraction. The crystallographic data of I are: a = 14.205(1) A, b = 13.083(1) A, c = 22.078(2) A, ? = 96.182(1), V = 4079.1(7) A3, space group C2/c, Z = 4. The molecule is located on a twofold axis and consists of the binuclear cation [Bi2(Tu)6(ClO4)4]2+ and two outer-sphere anions Cl 4 -. The Bi-S bond lengths are 2.61-2.62 A. For each terminal and bridging ClO 4 - ion, one Bi-O distance varies from 2.744 to 3.048 3.269 structure contains a hydrogen bond network involving all hydrogen atoms. The IR and Raman spectroscopy data confirm the thiourea coordination by the sulfur atom. В© 2013 Pleiades Publishing, Ltd.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Patrin K. G., Yakovchuk V.Yu., Patrin G. S., Yarikov S. A.
Заглавие : Magnetism and magnetoresistance in NiFe/Bi/NiFe films
Коллективы : Moscow International Symposium on Magnetism
Место публикации : Diffusion and Defect Data Pt.B: Solid State Phenomena. - 2012. - Vol. 190. - P.439-442. - ISBN 1012-0394, DOI 10.4028/www.scientific.net/SSP.190.439. - ISBN 9783037854365
Ключевые слова (''Своб.индексиров.''): antiferromagnetic interaction--bi spacer--hysteresis loop--interlayer coupling--magnetization--magnetoresistance--permalloy--trilayer films--antiferro-magnetic interactions--giant magnetoresistive--interlayer coupling--interlayer interactions--permalloy--spacer thickness--squid magnetometry--trilayer film--trilayers--antiferromagnetism--bismuth--giant magnetoresistance--hysteresis loops--magnetic materials--magnetic resonance--magnetization--magnetoresistance--electric resistance
Аннотация: Interlayer interactions in FeNi/Bi/FeNi trilayers have been experimentally studied. Based on the data of SQUID magnetometry and magnetic resonance investigations, it is shown that the interlayer interaction is determined by a bismuth spacer thickness and temperature. The giant magnetoresistive effect in the trilayer films has been discovered. В© (2012) Trans Tech Publications.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ikonnikov D. A., Malakhovskii A. V., Sukhachev A. L., Zaitsev A. I., Aleksandrovsky A. S., Jubera V.
Заглавие : Spectroscopic properties of Nd3+ in orthorhombic δ-BiB3O6 crystal
Место публикации : Opt. Mater.: ELSEVIER SCIENCE BV, 2012. - Vol. 34, Is. 11. - P.1839-1842. - ISSN 0925-3467, DOI 10.1016/j.optmat.2012.05.016
Примечания : Cited References: 23. - The work was supported by Ministry of Education and Science of Russian Federation (Contract 16.740.11.0150), by Russian Foundation for Basic Researches Grant 12-02-00026, Grant of President of Russian Federation for support of leading scientific schools No. SS-4828.2012.2, Grant No. SFU.F12, and Projects No. 28, 43 and No. 101 of SB RAS.
Предметные рубрики: SPECTRAL-LINE INTENSITIES
RARE-EARTH IONS
LASER CRYSTAL
NdAl3(BO3)(4) NAB
OPTICAL-SPECTRA
BiB3O6
SYSTEMS
GROWTH
Er3+
Tm3+
Ключевые слова (''Своб.индексиров.''): neodymium--orthorhombic bismuth triborate--absorption--judd-ofelt analysis
Аннотация: Absorption spectra of the Nd3+ ions in an orthorhombic δ-BiB3O6 single crystal were measured in the spectral range 11,000-20,500 cm-1. The f-f transition intensities were analyzed in terms of the Judd-Ofelt theory, and the following parameters of the theory were obtained: Ω2 = 6.35 × 10-20 cm2, Ω4 = 4.86 × 10-20 cm 2, and Ω6 = 11.233 × 10-20 cm 2. The strengths, spontaneous emission probabilities, branching ratios, spectroscopic quality factor and excited state radiative lifetime were calculated for laser transitions from the 4F3/2 state to 4IJ manifold. Spectroscopic properties of Nd 3+:δ-BiB3O6 crystal favor lasing at 1.3 μm, where this crystal possesses near non-critical phase matching for second harmonic generation. © 2012 Elsevier B.V. All rights reserved.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Melnikova S. V., Isaenko L. I.
Заглавие : Linear optical properties of γ-modification of bismuth borate BiB3O6
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 54, Is. 10. - P.1966-1969. - ISSN 1063-7834, DOI 10.1134/S1063783412100228
Примечания : Cited References: 9. - This study was supported by the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation (grant no. NSh-4828.2012.2) and the Siberian Branch of the Russian Academy of Science (integration project no. 28).
Предметные рубрики: GROWTH
Аннотация: The refractive index dispersion of the γ-BiB3O6 crystal in the wavelength range 0.43–0.81 μm has been measured. It has been shown that the principal refractive indices n 1, n 2, and n 3 are on average higher than those of α-BiB3O6, but are slightly lower than those of δ-BiB3O6. The temperature dependences of the rotation angle φ(T) of the optical indicatrix and birefringence Δn 2(T) = (n 1 − n 3)(T) have been studied in the temperature range 100–963 K. It has been shown that the γ-BiB3O6 crystal is stable in this temperature region.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Patrin G. S., Yakovchuk V.Yu., Velikanov D. A., Patrin K. G., Yarikov S. A.
Заглавие : Interlayer interactions in FeNi/Bi/FeNi trilayers
Место публикации : Bull. Russ. Acad. Sci.: Phys.: Allerton Press, 2012. - Vol. 76, Is. 2. - P.177-179. - ISSN 1062-8738
Примечания : Cited References: 5. - This study was supported by the Russian Foundation for Basic Research, project no. 110200675a.
Ключевые слова (''Своб.индексиров.''): giant magnetoresistance effect--interlayer interactions--spacer thickness--squid magnetometry--trilayers--magnetic resonance--bismuth
Аннотация: Interlayer interactions in FeNi/Bi/FeNi films are studied experimentally. It is established by SQUID magnetometry and magnetic resonance investigations that the interlayer interaction in these films is determined by the bismuth spacer thickness and temperature. A giant magnetoresistance effect is observed in the investigated trilayers. © 2012 Allerton Press, Inc.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vasil'ev A. D., Golovnev N. N., Leshok A. A.
Заглавие : Crystal structure of hexakis-(N-methylthiourea) bismuth(III) triperchlorate
Место публикации : Russ. J. Inorg. Chem.: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 57, Is. 4. - P.525-527. - ISSN 0036-0236, DOI 10.1134/S0036023612040250
Примечания : Cited References: 12
Предметные рубрики: THIOUREAS
Аннотация: A bismuth(III) complex of N-methylthiourea (Mtu, C2H6N2S) [Bi(C2H6N2S)6](ClO4)3 has been synthesized, and its crystal structure has been determined. The structure is built of octahedral Bi(Mtu) 6 3+ cations and ClO 4 − anions. Sulfur atoms are coordinated to bismuth(III) (at axis 2) at octahedron vertices (Bi-S, 2.7670(8), 2.8142(8), and 2.8315(8) Å); angles SBiS vary from 82.26(3)° to 96.13(2)°. The presence of amino groups and oxygen atoms in the structure results in the emergence of numerous hydrogen bonds (HBs). All H atoms of amino groups are involved in HBs; one of them is bound to the sulfur atom. One of the oxygen atoms of ClO 4 − anions does not participate in HBs.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Gokhfeld D. M., Popkov S. I., Shaikhutdinov K. A., Klinkova L. A., Zherikhina L. N., Tsvokhrebov A. M.
Заглавие : Increase in the magnetization loop width in the Ba0.6K0.4BiO3 superconductor: Possible manifestation of phase separation
Место публикации : J. Exp. Theor. Phys.: MAIK Nauka-Interperiodica / Springer, 2014. - Vol. 118, Is. 1. - P.104-110. - ISSN 1063-7761, DOI 10.1134/S1063776114010038. - ISSN 1090-6509
Примечания : Cited References: 39
Предметные рубрики: (K,BA)BIO3 SINGLE-CRYSTALS
II SUPERCONDUCTORS
BISMUTH-OXIDE
PEAK
DENSITY
TC
Аннотация: The magnetization of Ba0.6K0.4BiO3 samples in fields up to 90 kOe in the temperature range from 2 to 30 K is investigated. It is shown that the observed increase in the width of the magnetization loop can be explained by a decrease in the phase nonuniformity upon an increase in the magnetic field. The asymmetric hysteretic dependence of magnetization with the secondary peak was successfully described by the extended critical state model taking into account the phase separation in the superconductor.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Udod L. V., Aplesnin S. S., Sitnikov M. N., Molokeev M. S.
Заглавие : Dielectric and electrical properties of polymorphic bismuth pyrostannate Bi2Sn2O7
Коллективы : Russian Foundation for Basic Research [09-02-00125-a, 14-02-92003 NNS_a, 14-02-90010_Bel_a, 14-12-00124]
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2014. - Vol. 56, Is. 7. - P.1315-1319. - ISSN 1063-7834, DOI 10.1134/S1063783414070336. - ISSN 1090-6460
Примечания : Cited References: 20. - This study was supported by the Russian Foundation for Basic Research (project nos. 09-02-00125-a, 14-02-92003 NNS_a, 14-02-90010_Bel_a, and 14-12-00124).
Предметные рубрики: STRONG MAGNETIC-FIELD
DOPED MANGANITES
MAGNETORESISTANCE
Bi2O3
Аннотация: The Bi2Sn2O7 compound existing simultaneously in two polymorphic modifications, namely, orthorhombic and cubic, has been synthesized for the first time by solid-phase synthesis. The dielectric and electrical properties of the compound have been studied in the temperature range 100 K ˂ T ˂ 500 K. Anomalies in the temperature dependences of the electrical resistivity and the permittivity (imaginary and real parts) have been found at both low and high temperatures. These features are explained in terms of the model of martensitic phase transitions.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Melnikova S. V., Shabanova L. A., Zaitsev A. I., Parshikov S. A., Ageev O. A., Aleksandrov K. S.
Заглавие : Ferroelastic phase transition in Cs3Bi2I9 crystal
Место публикации : Ferroelectrics, Letters Section. - 1996. - Vol. 20, Is. 5-6. - P.163-167. - ISSN 0731-5171
Ключевые слова (''Своб.индексиров.''): birefringence--cesium compounds--crystal symmetry--crystals--differential scanning calorimetry--elasticity--ferroelectricity--permittivity--stiffness--twinning--cesium bismuth iodide--elastic constant--elastic stiffness--ferroelastic phase transition--phase transitions
Аннотация: Phase transition (PT) was found in Cs3Bi2I9 single crystal at T0=223 K. Optical birefringence, dielectric and elastic constants and differential scanning calorimetry have been studied. It was found that birefringence ?nc and twinning picture appeared on (001) - and (100) - plates below T0, as well as softening of elastic stiffness C44 above T0. It allows to classify the PT as proper ferroelastic one with symmetry change 6/mmm - 2/m. В© 1996 OPA (Overseas Publishers Association) Amsterdam B.V. Published in The Netherlands under license by Gordon and Breach Science Publishers SA.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Pavlovskii M. S., Shinkorenko A. S., Zinenko V. I.
Заглавие : Calculation of lattice dynamics, elastic and dielectric properties of γ-BiB3O6 and δ-BiB3O6
Коллективы : Council on Grants from the President of the Russian Federation for Support of the "Leading Scientific Schools" [NSh-924.2014.2]
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2015. - Vol. 57, Is. 4. - P.675-682. - ISSN 1063, DOI 10.1134/S1063783415040241. - ISSN 10906460(eISSN)
Примечания : Cited References:14. - This study was supported by the Council on Grants from the President of the Russian Federation for Support of the "Leading Scientific Schools" (grant no. NSh-924.2014.2).
Предметные рубрики: BISMUTH BORATE BiB3O6
OPTICAL-PROPERTIES
CRYSTAL
RAMAN
Аннотация: The crystal lattice vibration frequencies, densities of phonon states, elastic moduli, and high-frequency permittivities have been calculated in terms of the density functional theory method for two polymorphs γ-BiB3O6 and δ-BiB3O6. Based on the calculated densities of phonon states, the temperature dependences of the free energies of two considered bismuth triborate modifications have been constructed, and the temperature of the phase transition between these modifications has been determined (1100 K). The structure of a possible nonpolar praphase of δ-BiB3O6 has been proposed. The polarization of δ-BiB3O6 has been estimated as 131 μC/cm2.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Savina A. A., Atuchin V. V., Solodovnikov S. F., Solodovnikova Z. A., Krylov A. S., Maximovsky E. A., Molokeev M. S., Oreshonkov A. S., Pugachev A. M., Khaikina E. G.
Заглавие : Synthesis, structural and spectroscopic properties of acentric triple molybdate Cs2NaBi(MoO4)3
Коллективы : Russian Foundation for Basic Research [4828.2012.2, 12-02-31205]; Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" [8379]
Место публикации : J. Solid State Chem. - 2015. - Vol. 225. - P.53–58. - ISSN 0022-4596, DOI 10.1016/j.jssc.2014.11.023. - ISSN 1095-726X
Примечания : Cited References: 66. - The authors are grateful to Dr. K.M. Khal'baeva and Dr. Irina A. Gudkova for their assistance in preparing the compound and taking X-ray single-crystal diffraction data. This study is partly supported by the Russian Foundation for Basic Research (Grants 13-03-01020 and 14-03-00298). V.V.A., A.S.K. and A.S.O. gratefully acknowledge the Ministry of Education and Science of the Russian Federation for a partial financial support.
Предметные рубрики: CRYSTAL-STRUCTURE
SINGLE-CRYSTALS
VIBRATIONAL PROPERTIES
RAMAN-SPECTROSCOPY
HYDROTHERMAL SYNTHESIS
DIELECTRIC-PROPERTIES
SELECTIVE OXIDATION;
BISMUTH MOLYBDATES
IONIC-CONDUCTIVITY
OPTICAL-PROPERTIES
Ключевые слова (''Своб.индексиров.''): triple molybdate--sodium--cesium--bismuth--crystal structure--raman spectroscopy--crystal-structure--single-crystals--vibrational properties--raman-spectroscopy--hydrothermal synthesis--dielectric-properties--selective oxidation;--bismuth molybdates--ionic-conductivity--optical-properties
Аннотация: New ternary molybdate Cs2NaBi(MoO4)3 is synthesized in the system Na2MoO4–Cs2MoO4–Bi2(MoO4)3. The structure of Cs2NaBi(MoO4)3 of a new type is determined in noncentrosymmetric space group R3c, a=10.6435(2), c=40.9524(7) Å, V=4017.71(13) Å3, Z=12 in anisotropic approximation for all atoms taking into account racemic twinning. The structure is completely ordered, Mo atoms are tetrahedrally coordinated, Bi(1) and Bi(2) atoms are in octahedra, and Na(1) and Na(2) atoms have a distorted trigonal prismatic coordination. The Cs(1) and Cs(2) atoms are in the framework cavities with coordination numbers 12 and 10, respectively. No phase transitions were found in Cs2NaBi(MoO4)3 up to the melting point at 826 K. The compound shows an SHG signal, I2w/I2w(SiO2)=5 estimated by the powder method. The vibrational properties are evaluated by Raman spectroscopy, and 26 narrow lines are measured.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Аплеснин, Сергей Степанович, Udod L. V., Sitnikov M. N., Eremin E. V., Molokeev M. S., Tarasova L. S., Yanushkevich K. I., Galyas A. I.
Заглавие : Correlation of the magnetic and transport properties with polymorphic transitions in bismuth pyrostannate Bi2(Sn1 − xCr x)2O7
Коллективы : Russian Foundation for Basic Research [15-02-01445-a], Ministry of Education and Science of the Russian Federation [114090470016]
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2015. - Vol. 57, Is. 8. - P.1627-1632. - ISSN 1063-7834, DOI 10.1134/S1063783415080028
Примечания : Cited References: 17. - This study was supported by the Russian Foundation for Basic Research (project no. 15-02-01445-a) and the Ministry of Education and Science of the Russian Federation (state task no. 114090470016).
Предметные рубрики: GAS SENSORS
Bi2Sn2O7
CRYSTAL
Аннотация: The correlation of the electrical, magnetic, and structural properties of Bi2(Sn1 − xCrx)2O7 solid solutions has been investigated for two compositions with x = 0.05 and 0.1. The temperatures of structural phase transitions and anomalies of the electrical resistance in the vicinity of these transitions at temperatures in the range 300 K ˂ T ˂ 1000 K have been determined using differential scanning calorimetry. It has been found that the thermoelectric power changes sign upon the polymorphic transition. The paramagnetic Curie temperature and the chromium-ion spin have been found from the temperature dependence of the magnetic susceptibility in the range 4 K ˂ T ˂ 1000 K and from the field dependence of the magnetic moment in magnetic fields of up to 6 T.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Babitsky N. A., Leshok D. Y., Mikhaleva N. S., Kuzubov A. A., Zhereb V. P., Kirik S. D.
Заглавие : New bismuth borophosphate Bi4BPO10: Synthesis, crystal structure, optical and band structure analysis
Место публикации : Mater. Chem. Phys.: Elsevier, 2015. - Vol. 163. - P.286-292. - ISSN 0254-0584, DOI 10.1016/j.matchemphys.2015.07.042
Примечания : Cited References: 32. - The study was performed with the financial support of the Ministry of Science and Education of the Russian Federation, Projects 3049, 3098, item 1025, "Fund for Assistance to Small Innovative Enterprises in Science and Technology" (Grant program "UMNIK" 2013 II half GU1/2014), ICDD Grant-in-Aid, #93-10
Предметные рубрики: INITIO MOLECULAR-DYNAMICS
AUGMENTED-WAVE METHOD
POWDER DATA
SYSTEM
PHASES
Ключевые слова (''Своб.индексиров.''): inorganic compounds--crystal growth--crystal structure--band-structure
Аннотация: New bismuth borophosphate Bi4BPO10 was obtained by spontaneous crystallization from the melt of correspondent composition at 804 °C. Crystal structure with orthorhombic lattice parameters: a = 22.5731(3) Å, b = 14.0523(2) Å, c = 5.5149(1) Å, V = 1749.34(4), Z = 8, SG Pcab was determined by X-ray powder diffraction technique. The [Bi2O2]2+ -layers, which are typical for bismuth oxide compounds, transform into cationic endless strips of 4 bismuth atoms width directed along the c-axis in Bi4BPO10. The strips combining stacks are separated by flat triangle [BO3]3- -anions within stacks. Neighboring stacks are separated by tetrahedral [PO4]3--anions and shifted relatively to each other. Bismuth atoms are placed in 5-7 vertex oxygen irregular polyhedra. Bi4BPO10 is stable up to 812 °C, then melts according to the peritectic law. The absorption spectrum in the range 350-700 nm was obtained and the width of the forbidden band was estimated as 3.46 eV. The band electronic structure of Bi4BPO10 was modeled using DFT approach. The calculated band gap (3.56 eV) is in good agreement with the experimentally obtained data. © 2015 Elsevier B.V. All rights reserved.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Udod L. V., Sitnikov M. N., Shestakov N. P.
Заглавие : Bi2(Sn0.95Cr0.05)2O7: Structure, IR spectra, and dielectric properties
Место публикации : Ceram. Int.: Elsevier, 2016. - Vol. 42, Is. 4. - P.5177-5183. - ISSN 02728842 (ISSN), DOI 10.1016/j.ceramint.2015.12.040
Примечания : Cited References: 45. - This work was supported by the Russian Foundation for Basic Research Projects no. 15-42-04099 r_siberia_a, Siberian Branch of Science and NAS of Belarus “Electronic and magnetic phase transitions in materials with magnetoelectric affect” and government work no. 114090470016.
Предметные рубрики: BISMUTH PYROSTANNATE
PYROCHLORE STRUCTURE
MAGNETIC-PROPERTIES
PARTIAL OXIDATION
HIGH-TEMPERATURE
X-RAY
Bi2Sn2O7
SUBSTITUTION
CATALYSTS
DIFFRACTION
Ключевые слова (''Своб.индексиров.''): bismuth pyrostannate--infrared absorption spectra--structural transition--permittivity--debye model
Аннотация: Infrared absorption spectra of the bismuth pyrostannate Bi2(Sn0.95Cr0.05)2O7 were investigated in the frequency range 350-1100 cm-1 at temperatures of 110-525 K. Four frequency regions with split absorption lines are distinguished. Softening of frequencies at the structural transitions was observed. The maxima of permittivity measured in the frequency range 1-200 kHz at temperatures 100-400 K were determined. It was found that the magnetic susceptibility changes its sign in the low-temperature region. The correlation between anomalies in the magnetic susceptibility, permittivity, and absorption line intensity was established. Softening of frequencies is explained by the variation in the coefficient of thermal expansion of the lattice. The temperature behavior of permittivity is described using the Debye model. © 2015 Elsevier Ltd and Techna Group S.r.l.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vasil'ev A. D., Golovnev N. N., Lesnikov M. K.
Заглавие : Crystal structure of [Bi(N-ethylthiourea)4(ClO4)2]ClO4
Место публикации : Russ. J. Inorg. Chem.: MAIK Nauka-Interperiodica / Springer, 2016. - Vol. 61, Is. 6. - P.704-707. - ISSN 00360236 (ISSN), DOI 10.1134/S003602361606022X
Примечания : Cited References: 21
Ключевые слова (''Своб.индексиров.''): hydrogen bonds--bismuth complexes--mutual repulsion--octahedral cation--thiocarbonyl--crystal structure
Аннотация: The structure of the bismuth(III) complex with N-ethylthiourea (Ettu) has been determined for the first time. We found that the crystal structure of [Bi(Ettu)4(ClO4)2]ClO4 is built of distorted octahedral cations [Bi(Ettu–S)4(ClO4)2]ClO4]+ and anions ClO4 -. The deviation of one of the two independent Ettu molecules from the plane structure is explained by the mutual repulsion of the ligands and the formation features of hydrogen bonds. The C2H5(Ettu) group is in the cis position relative to the thiocarbonyl group. © 2016, Pleiades Publishing, Ltd.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Popkov S. I., Semenov S. V., Bykov A. A., Sabitova E. I., Dubrovskiy A. A., Shaikhutdinov K. A., Petrov M. I.
Заглавие : Contributions from Inter-grain Boundaries to the Magneto-resistive Effect in Polycrystalline High-T (C) Superconductors. The Underlying Reason of Different Behavior for YBCO and BSCCO Systems
Разночтения заглавия :авие SCOPUS: Contributions from inter-grain boundaries to the magneto-resistive effect in polycrystalline high-TC superconductors. the underlying reason of different behavior for YBCO and BSCCO systems
Место публикации : J. Supercond. Nov. Magn: SPRINGER, 2011. - Vol. 24, Is. 7. - P2129-2136. - ISSN 1557-1939, DOI 10.1007/s10948-011-1166-9
Примечания : Cited References: 30. - This work is supported by program N5 of RAS, project N7.
Предметные рубрики: HIGH-TEMPERATURE SUPERCONDUCTORS
PHASE-SLIP
TRANSPORT-PROPERTIES
TRANSITION
FIELD
COMPOSITES
BULK
TAPES
YBA2CU3O7-DELTA
DISSIPATION
Ключевые слова (''Своб.индексиров.''): bscco--ybco--intergrain boundaries--magnetoresistance--bscco--intergrain boundaries--magnetoresistance--ybco--bscco--bscco system--comparative studies--high tc superconductors--high-field--inter-grain--irreversibility lines--magneto-resistive effect--polycrystalline--resistive transition--standard measurements--weak pinning--ybco--bismuth--electric resistance--grain boundaries--high temperature superconductors--lead--magnetic fields--magnetoelectronics--magnetoresistance--magnetos--superconductivity--yttrium barium copper oxides--semiconductor metal boundaries
Аннотация: In order to clarify the mechanisms in charge of broadening of resistive transition R(T) in magnetic fields of bismuth-based polycrystalline high-T (C) superconductor (HTSC), a comparative study of Bi1.8Pb0.3Sr1.9Ca2Cu3O (x) (BSCCO) and YBa2Cu3O7-delta (YBCO) have been performed. Magnetoresistive effects and irreversibility line obtained from magnetic measurements have been studied. It was established that (1) for YBCO, the smooth part of R(T) dependence unambiguously corresponds to dissipation in the intergrain boundaries for arbitrary magnetic fields; (2) for polycrystalline BSCCO, the smooth part of R(T) dependences correspond to dissipation within intergrain boundary subsystem in the field range H 10(2) Oe only, while standard measurements of R(T) dependences in magnetic field range H 10(2) Oe reflect the dissipation processes occurring both in intergrain boundary and HTSC grain subsystems; (3) for the high-field range, the contribution from intergrain boundaries of BSCCO can be distinguished from magnetoresistance R(H) dependences obtained at high enough current density on textured samples. It is proposed that various magneto-resistive properties of these classical HTSC systems are due comparatively weak pinning in BSCCO.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Bykov A. A., Semenov S. V., Popkov S. I., Dubrovskii A. A., Shaikhutdinov K. A., Petrov M. I.
Заглавие : General regularities of magnetoresistive effects in the polycrystalline yttrium and bismuth high-temperature superconductor systems
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2011. - Vol. 53, Is. 5. - P922-932. - ISSN 1063-7834, DOI 10.1134/S1063783411050052
Примечания : Cited References: 52. - This study was supported by the Russian Academy of Sciences within the program no. 5 (project no. 7).
Предметные рубрики: HIGH MAGNETIC-FIELDS
PHASE-SLIP
RESISTIVE TRANSITION
CU-O
TRANSPORT-PROPERTIES
JOSEPHSON MEDIUM
MIXED-STATE
FLUX-CREEP
T-C
DISSIPATION
Аннотация: The influence of thermomagnetic prehistory on the behavior of a resistive transition R(T) in external magnetic fields of polycrystalline YBa(2)Cu(3)O(7) and Bi(1.8)Pb(0.3)Sr(1.9)Ca(2)Cu(3)O (x) high-temperature supercon-ductors and the Bi(1.8)Pb(0.3)Sr(1.9)Ca(2)Cu(3)O (x) + Ag texture has been investigated. It has been found that, for YBa(2)Cu(3)O(7), the thermomagnetic prehistory exerts a substantial influence on the dissipation in the subsystem of grain boundaries in magnetic fields up to similar to 10(3) Oe, and this effect becomes insignificant in fields higher than similar to 10(4) Oe. This behavior has been explained by the influence of magnetic moments of high-temperature superconductor grains on the effective magnetic field in the intergranular medium. For bismuth high-temperature superconductors, no influence of thermomagnetic prehistory on the resistive transition has been observed; however, this effect manifests itself in current-voltage characteristics at high transport current densities. There is also a radical difference in the behavior of isotherms of the magnetoresistance R(H) for the yttrium and bismuth systems. For YBa(2)Cu(3)O(7), there is a clear separation between the dissipation regimes in the intergranular medium and in grains, which manifests itself even at low transport current densities as a change of sign in the curvature of the dependence R(H). For a texture based on the bismuth high-temperature superconductor, this feature has been observed only at high current densities (comparable to the critical current density at H = 0). This difference in the behavior of magnetoresistive properties of the classical high-temperature superconductor systems under investigation has been explained by relatively low irreversibility fields of the bismuth high-temperature superconductors. In these materials, simultaneous processes of dissipation can occur in an external magnetic field both in the subsystem of grain boundaries between crystallites and in the crystallites themselves.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Petrov M. I., Balaev D. A., Belozerova I. L., Vasil'ev A. D., Gokhfel'd D. M., Mart'yanov O. N., Popkov S. I., Shaihutdinov K. A.
Заглавие : Highly textured bismuth-containing high-temperature superconductor ceramics obtained by uniaxial pressing in liquid medium: Fabrication and properties
Место публикации : Tech. Phys. Lett.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007. - Vol. 33, Is. 9. - P740-743. - ISSN 1063-7850, DOI 10.1134/S1063785007090088
Примечания : Cited References: 12
Предметные рубрики: MICROSTRUCTURE
MAGNETIZATION
Аннотация: A new method of fabricating textured ceramics with a composition of Bi1.8Pb0.3Sr1.9Ca2Cu3Ox is described, according to which the initial low-density ceramics is subjected to uniaxial pressing in a liquid medium followed by drying and annealing. Analysis of the X-ray diffraction and scanning electron microscopy data show evidence for a high degree of texture in high-temperature superconductor ceramics fabricated using the proposed method. The results of magnetic measurements indicate that the obtained material possesses anisotropy of the magnetic moment for the magnetic field H oriented parallel and perpendicular to the direction of uniaxial pressing. The textured ceramics also show high diamagnetic response for H parallel to the c axis of grains, which makes these ceramics promising materials for practical applications.
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