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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Kazak N. V., Gokhfeld Yu. S., Belskaya N. A., Molokeev M. S., Gudim I. A., Eremin E. V., Knyazev Yu. V., Velikanov D. A., Ovchinnikov S. G.
Заглавие : Structural disorder, heat capacity, and magnetic transitions in Cu2FeBO5
Коллективы : Samarkand International Symposium on Magnetism, Samarkand State University
Место публикации : Book of abstacts of Samarkand International Symposium on Magnetism (SISM-2023)/ int. adv. com. S. G. Ovchinnikov [et al.]. - 2023. - Ст.3PO-L9-7. - P.208. - ISBN 978-5-00202-320-2
Примечания : Cited References: 3. - РФФИ № 21-52-12033
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Беляев, Борис Афанасьевич, Тюрнев, Владимир Вениаминович
Заглавие : Формулы электродинамики для сред с отрицательной диэлектрической проницаемостью
Колич.характеристики :13 с
Место публикации : Ural Radio Eng. J. - 2023. - Vol. 7, Is. 4. - P.457-469. - ISSN 25880454 (ISSN), DOI 10.15826/urej.2023.7.4.006. - ISSN 25880462 (eISSN)
Примечания : Cited References: 15
Аннотация: Формулы электродинамики, широко используемые при описании объектов, содержащих диэлектрические среды, дают противоречащие физике результаты в случае, когда диэлектрическая проницаемость среды принимает отрицательное значение. Проблему снимают уточненные формулы, позволяющие рассчитывать электрические потенциалы точечного заряда и точечного дипольного момента, емкость конденсатора, а также плотность энергии электромагнитного поля и добротность материала. Формулы справедливы для любых сред, как с положительной, так и с отрицательной действительной частью комплексной диэлектрической проницаемости.Electrodynamic formulas widely used in the description of objects containing dielectric media give results contrary to physics in the case when the permittivity of the medium takes a negative value. The problem is solved by refined formulas that allow calculating the electric potentials of the point charge and the point dipole moment, the capacitance of the capacitor, as well as the energy density of the electromagnetic field and the quality factor of the material. The formulas are valid for any media, both with positive and negative real part of the complex permittivity.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Tsyganova S. I., Yu. Fetisova O., Velikanov D. A., Taran O. P.
Заглавие : Structural, magnetic and electrochemical characteristics of Ni/C composites fabricated from modified hydrolytic lignin
Колич.характеристики :3 с
Место публикации : Mater. Lett. - 2023. - Vol. 352. - Ст.135120. - ISSN 0167577X (ISSN), DOI 10.1016/j.matlet.2023.135120. - ISSN 18734979 (eISSN)
Примечания : Cited References: 11. - The present work was supported by the Russian Foundation for Basic Research , the Government of the Krasnoyarsk Territory and carried out as part of the budget project ( 0287-2021-0017 ) of the Institute of Chemistry and Chemical Technology SB RAS
Аннотация: The synthesis of metal–carbon materials based on hydrolytic lignin by its modification with subsequent carbonation is studied. It is shown the modification of hydrolysis lignin with ZnCl2 and NiCl2 leads to a significant increase of specific surface area up to 716 m2/g and the apparent specific capacity up to 350F/g of carbonized composite. It was found out that fabricated Ni/C composites are characterized by a coercive force of 80–105 Oe, a saturation magnetization of 4–11 Gs•cm3/g, and a residual magnetization of 0.28–0.45 Gs•cm3/g. This indicates the prospects of their use as a magnetically soft material.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bogdanov E. V., Pogoreltsev E. I., Gorev M. V., Mel'nikova S. V., Molokeev M. S., Laptash N. M., Flerov I. N.
Заглавие : Effect of the size of the central atom on the stability of crystalline phases in solid solutions (NH4)3TixSn1-xF7
Колич.характеристики :8 с
Место публикации : J. Solid State Chem. - 2023. - Vol. 328. - Ст.124373. - ISSN 00224596 (ISSN), DOI 10.1016/j.jssc.2023.124373. - ISSN 1095726X (eISSN)
Примечания : Cited References: 20. - The study was supported by a grant from the Russian Science Foundation № 23-22-00115, https://rscf.ru/project/23-22-00115/X-ray and dilatometric data and SEM images were obtained using the equipment of the Krasnoyarsk Regional Center for Collective Use of the Federal Research Center — Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences. We are grateful to Dr. A.V. Shabanov for examination of the SEM images
Аннотация: The effect of a change in internal pressure as a result of partial substitution of the central atom on the realization and stability of the initial and distorted crystalline phases in (NH4)3TixSn1-xF7 solid solutions has been studied. It was found that at a Ti concentration in the range of x = 0.15–0.40, the reconstructive transition Pm-3m ↔ Pa-3 is transformed into a sequence of phase transitions Pm-3m ↔ P4/mbm ↔ P4/mnc ↔ Pa-3. In the (NH4)3Ti0.15Sn0.85F7 solid solution, the first-order phase transition between two cubic phases at T0 = 352 K is characterized by a significant volume jump δ(ΔV/V0) ≈ 1 %, comparable with that in (NH4)3SnF7. An increase of the Ti concentration leads to a strong decrease in the stability of the Pm-3m cubic phase: the first tetragonal P4/mbm phase appears in (NH4)3Ti0.4Sn0.6F7 at T0 = 400 K, which proves the existence of the predicted high-temperature cubic phase in (NH4)3TiF7. In solid solutions, a decrease in birefringence and entropy of phase transitions was observed in comparison with the initial compounds with Sn and Ti as central atoms. The role of critical parameters (unit cell volume, temperature, external pressure) in the formation of cubic and distorted phases is discussed.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Денисова Л. Т., Молокеев, Максим Сергеевич, Голубева Е. О., Галиахметова Н. А.
Заглавие : Синтез, кристаллическая структура и термодинамические свойства апатитоподобных ванадато-германатов свинца гадолиния
Коллективы : Siberian Federal University [FSRZ-2020-0013]
Место публикации : Журн. СФУ. Химия. - 2022. - Т. 15, № 1. - Ст.128-136. - ISSN 1998-2836, DOI 10.17516/1998-2836-0277; J. Sib. Fed. Univ. Chem. - 2022. - ISSN 2313-6049(eISSN)
Примечания : Библиогр.: 25. - Авторы выражают благодарность Красноярскому региональному центру коллективного пользования ФИЦ КНЦ СО РАН. Работа выполнена при частичной финансовой поддержке в рамках государственного задания на науку ФГАОУ ВО «Сибирский федеральный университет», номер проекта FSRZ‑2020–0013
Аннотация: Методом твердофазных реакций обжигом на воздухе стехиометрических смесей PbO, Gd2O3, GeO2 и V2O5 в интервале температур 773–1073 K синтезированы апатиты Pb10-xGdx(GeO4)2+x(VO4)4-x (x = 0.5, 1.0). С использованием рентгеноструктурного анализа определена их кристаллическая структура. Методом дифференциальной сканирующей калориметрии измерена высокотемпературная теплоемкость (350–1000 K). По экспериментальным данным Cp = f(T) рассчитаны термодинамические свойства апатитов.The Pb10-xGdx(GeO4)2+x(VO4)4-x (x = 0.5, 1.0) apatites were synthesized by the solid-phase synthesis by roasting stoichiometric mixtures of PbO, Gd2O3, GeO2, and V2O5 in air at temperatures of 773–1073 K. Their crystal structure was determined using X‑ray diffraction analysis. The high-temperature heat capacity (350–1000 K) was measured by differential scanning calorimetry. The experimental data Cp = f (T) were used to calculate the thermodynamic properties of apatites.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Ivanova O. S., Edelman I. S., Sokolov A. Е., Svetlitsky E. S., Lin C.-R., Chen Y. -Z., Tseng Y.-T.
Заглавие : Selective adsorption capacity of Fe3O4@C nanoparticles with respect to organic cationic dyes
Коллективы : Asian School-Conference on Physics and Technology of Nanostructured Materials, Азиатская школа-конференция по физике и технологии наноструктурированных материалов
Место публикации : The Sixth Asian school-conference on physics and technology of nanostructured materials: Proceedings. - VLadivostok, 2022. - Ст.IV.p.14. - P.231-232. - ISBN 987-5-8044-1716-2
Примечания : Cited References: 3
Предметные рубрики:
Аннотация: The Fe3O4 and core-shell Fe3O4@C magnetic nanoparticles (NPs) with an average size of 15 ± 2 nm were synthesized and characterized. Comparative study of two types of NPs revealed their different sorption capacity of cationic and anionic dyes. The leading role of electrostaticinteractions in the dyes adsorption by Fe3O4@C NPs has been revealed.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova L. T., Molokeev M. S., Kargin Y. F., Galiakhmetova N. A., Beletskii V. V., Denisov V. M.
Заглавие : High-temperature heat capacity and thermodynamic properties of the CaY2Ge3O10 and CaY2Ge4O12 germanates
Место публикации : Inorg. Mater. - 2022. - Vol. 58, Is. 4. - P.414-419. - ISSN 00201685 (ISSN), DOI 10.1134/S0020168522040033
Примечания : Cited References: 31. - This work was supported in part by the Russian Federation Ministry of Science and Higher Education as part of the state research target for the Siberian Federal University federal state autonomous educational institution of higher education, project no. FSRZ-2020-0013
Аннотация: The CaY2Ge3O10 and CaY2Ge4O12 germanates have been synthesized by a standard ceramic processing route using CaCO3, Y2O3, and GeO2 as starting materials, and their crystal structure has been refined by X-ray diffraction. The high-temperature (350–1000 K) experimental heat capacity data obtained for the germanates by differential scanning calorimetry have been used to calculate their principal thermodynamic functions.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Churilov G. N., Nikolaev N. S., Elesina V. I., Glushenko G. A., Isakova V. G., Tomashevich Y. V.
Заглавие : Obtaining particles with the structure Mg@C and (Mg@C)@Pd, their properties and stability in the hydrogenation/dehydrogenation processes
Место публикации : Int. J. Hydrogen Energy. - 2022. - Vol. 47. Is. 11. - P.7299-7309. - ISSN 03603199 (ISSN), DOI 10.1016/j.ijhydene.2021.03.042
Примечания : Cited References: 46
Аннотация: In this work, we studied the change in the properties of powders with a core (magnesium) – shell structure (carbon and carbon/palladium) in the process of hydrogenation/dehydrogenation with hydrogen (99.995 wt%). Magnesium powders were obtained by plasma chemical synthesis in an atmosphere of argon containing a small amount of hydrogen (2–3 at.%) and nitrogen (8–9 at.%), when performing a low-frequency arc discharge between a tungsten electrode and a magnesium melt. The shell (carbon and carbon/palladium) was deposited in a plasma generator with vortex and magnetic stabilization. For all samples, a decrease in the sorption capacity of hydrogen was observed as a result of successive cycles of sorption and desorption reactions. It was found that the reason for this fall is associated with the formation of the MgO and Mg(OH)2 phase, which prevents the diffusion of hydrogen. The carbon shell provides a more complete hydrogenation of the magnesium particles, and an additional palladium shell increases the resistance to cyclic hydrogenation/dehydrogenation and reduces the temperature of these processes. According to the data obtained, powders with particles (Mg@C)@Pd can absorb the largest amount of hydrogen (6.9 wt%) for the duration of 5 cycles, after which the protective shell of the particles begins to collapse and a loss of sorption capacity is observed.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Eremin E. V., Andryushin N. D., Gudim I. A., Pavlovskii M. S., Titova V. R.
Заглавие : Heat capacity of scandoborate NdSc3(BO3)4
Место публикации : Phys. Solid State. - 2022. - Vol. 64, Is. 14. - P.2435-2438. - ISSN 10637834 (ISSN), DOI 10.21883/PSS.2022.14.54353.188. - ISSN 10906460 (eISSN)
Примечания : Cited References: 21. - The study was done with financial support from the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory and the Krasnoyarsk Regional Fund of Science within the scientific project ”Development of solution-melt technologies of growing the new monocrystals of NdSc3−xGax(BO3)4 with huntite structure and study of interaction of their magnetic, electric and elastic subsystems“ (No. 20-42-240009)
Аннотация: Single crystals of trigonal neodymium scandoborate NdSc3(BO3)4 were grown by the group method from a solution-melt based on bismuth trimolybdate. The molar heat capacity C(T) was studied in the temperature range 2-300 K and magnetic fields up to 9 T. The experimental curve was approximated by the combined Debye-Einstein model. The lattice contribution was determined from ab-initio calculations. Schottky anomaly was observed in the low-temperature region C(T) with the applied magnetic field.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova L. T., Molokeev M. S., Golubeva E. O., Belousova N. V., Denisov V. M.
Заглавие : Synthesis, crystal structure and high-temperature heat capacity of substituted apatites Pb9R(GeO4)3(VO4)3 (R=Tb, Dy, Ho)
Место публикации : Phys. Solid State. - 2022. - Vol. 64, Is. 11. - P.1621-1625. - ISSN 10637834 (ISSN), DOI 10.21883/PSS.2022.11.54182.353. - ISSN 10906460 (eISSN)
Примечания : Cited References: 38. - The work has been partially funded within the framework of the state science assignment of Federal State Independent Institution for Higher Education Siberian Federal University, project number FSRZ-2020-0013
Аннотация: Pb9R(GeO4)3(VO4)3 (R=Tb, Dy, Ho) apatites were obtained by solid-phase synthesis from the initial oxides of PbO, Tb2O3 (Dy2O3, Ho2O3), GeO2 and V2O5 by sequential annealing (at a temperature of 773-1073 K) in an air atmosphere. Their crystal structure has been determined by X-ray diffraction analysis. The high-temperature heat capacity was measured by differential scanning calorimetry. Based on the experimental dependence of the heat capacity on the temperature, the thermodynamic properties are calculated.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova L. T., Molokeev M. S., Galiakhmetova N. A., Denisov V. M., Belousova N. V.
Заглавие : Heat capacity and thermodynamic properties of germanates CaR2Ge3O10 (R = Pr, Nd) in the region of 320–1000 K
Место публикации : Russ. J. Phys. Chem. A. - 2022. - Vol. 96, Is. 5. - P.913-917. - ISSN 00360244 (ISSN), DOI 10.1134/S0036024422050077
Примечания : Cited References: 30. - The authors are grateful to the Krasnoyarsk Regional Shared Resource Center of the Krasnoyarsk Science Center. This work was performed as part of a State Task for Siberian Federal University, project no. FSRZ-2020-0013
Аннотация: Sequential annealing of stoichiometric mixtures of CaCO3, Pr6O11(Nd2O3), and GeO2 in air at 1423–1473 K yields germanates CaPr2Ge3O10 and CaNd2Ge3O10. Their crystal structure is refined via X-ray diffraction. The high-temperature heat capacity (320–1000 K) is measured by means of differential scanning calorimetry. The thermodynamic properties of germanates are calculated using experimental dependences Cp = f(T).
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova L. T., Molokeev M. S., Golubeva E. O., Belousova N. V., Denisov V. M.
Заглавие : Synthesis, crystal structure and thermodynamic properties of apatite Pb3Bi2(GeO4)3
Место публикации : Phys. Solid State. - 2022. - Vol. 64, Is. 7. - P.889-893. - ISSN 10637834 (ISSN), DOI 10.21883/PSS.2022.07.54599.312. - ISSN 10906460 (eISSN)
Примечания : Cited References: 30. - This work was partially supported within the scope of the state assignment for science of FSAEI HE ”Siberian Federal University“, project number FSRZ-2020-0013
Аннотация: Apatite Pb3Bi2(GeO4)3 was obtained by the solid-phase method from the initial oxides of PbO, Bi2O3 and GeO2 by sequential firing in air at temperatures of 773–1003 K. Its crystal structure has been refined by X-ray diffraction. The high-temperature heat capacity (350–1000 K) of this compound was measured by differential scanning calorimetry. Based on these data, the main thermodynamic functions are calculated.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova L. T., Molokeev M. S., Kargin Y. F., Golubeva E. O., Belousova N. V., Denisov V. M.
Заглавие : Synthesis, crystal structure, and high-temperature heat capacity of Pb10 – xSmx(GeO4)2 + x(VO4)4 – x (x = 0.2, 0.5, 0.7, 1.0) apatites from 350 to 1000 K
Место публикации : Inorg. Mater. - 2022. - Vol. 58, Is. 8. - P.831-837. - ISSN 00201685 (ISSN), DOI 10.1134/S0020168522070081
Примечания : Cited References: 24. - This work was supported in part by the Russian Federation Ministry of Science and Higher Education as part of the state research target for the Siberian Federal University federal state autonomous educational institution of higher education, project no. FSRZ-2020-0013
Аннотация: Pb10 – xSmx(GeO4)2 + x(VO4)4 – x (x = 0.2, 0.5, 0.7, 1.0) compounds with the apatite structure have been synthesized by firing appropriate mixtures of the PbO, Sm2O3, GeO2, and V2O5 oxides in air at temperatures from 773 to 1073 K. Their crystal structure has been studied using X-ray diffraction, and their high-temperature heat capacity (350–1000 K) has been determined by differential scanning calorimetry. The data have been used to evaluate their thermodynamic properties.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mikhaleva E. A., Gorev M. V., Bondarev V. S., Molokeev M. S., Zaitsev A. I., Nemtsev I. V., Fokin A. V., Flerov I. N.
Заглавие : Heat capacity and thermal expansion of nanosized ferroelectric (NH4)2SO4 embedded in borosilicate glasses
Место публикации : J. Non-Cryst. Solids. - 2022. - Vol. 597. - Ст.121935. - ISSN 00223093 (ISSN), DOI 10.1016/j.jnoncrysol.2022.121935
Примечания : Cited References: 29. - The authors are grateful to Dr. Ewa Rysiakiewicz-Pasek (Wroclaw University of Science and Technology, Poland) for the preparation and characterization of borosilicate glasses. X-ray and dilatometric data were obtained using the equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS”
Аннотация: The thermal properties of nanocomposites obtained by incorporating a ferroelectric (NH4)2SO4 (AS) into porous glasses (PG) was studied for the first time. X-ray diffraction studies showed a strong increase in the ratio of the size of nanocrystallites grown in glass matrices to pore size, dcryst/ dpore = 0.47→1.50→5.00, with a decrease in dpore = 320→46→7 nm. Calorimetric and dilatometric measurements showed a change from a first-order phase transition in AS single crystal to a second-order transformation in AS nanocrystallites. A restricted geometry also led to a significant decrease in the anomalous entropy in AS+PG samples compared to AS (J/mol∙K): 17.7 (AS)→12.4 (AS+PG320)→10.4 (AS+PG46)→8.1 (AS+PG7). A discussion of the nontrivial behavior of the phase transition temperature in embedded AS was carried out using the degree of PG filling, the ratio dcryst/dpore, texture, and the volumetric and linear baric coefficients for the bulk AS.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Fedorov A. S., Teplinskaia A. S.
Заглавие : Thermal properties of porous silicon nanomaterials
Место публикации : Materials. - 2022. - Vol. 15, Is. 23. - Ст.8678. - ISSN 19961944 (ISSN), DOI 10.3390/ma15238678
Примечания : Cited References: 50. - This study was funded by the Ministry of Science and High Education of Russian Federation, project no. FSRZ-2020-0008
Аннотация: The thermal properties, including the heat capacity, thermal conductivity, effusivity, diffusivity, and phonon density of states of silicon-based nanomaterials are analyzed using a molecular dynamics calculation. These quantities are calculated in more detail for bulk silicon, porous silicon, and a silicon aerocrystal (aerogel), including the passivation of the porous internal surfaces with hydrogen, hydroxide, and oxygen ions. It is found that the heat capacity of these materials increases monotonically by up to 30% with an increase in the area of the porous inner surface and upon its passivation with these ions. This phenomenon is explained by a shift of the phonon density of states of the materials under study to the low-frequency region. In addition, it is shown that the thermal conductivity of the investigated materials depends on the degree of their porosity and can be changed significantly upon the passivation of their inner surface with different ions. It is demonstrated that, in the various simulated types of porous silicon, the thermal conductivity changes by 1–2 orders of magnitude compared with the value for bulk silicon. At the same time, it is found that the nature of the passivation of the internal nanosilicon surfaces affects the thermal conductivity. For example, the passivation of the surfaces with hydrogen does not significantly change this parameter, whereas a passivation with oxygen ions reduces it by a factor of two on average, and passivation with hydroxyl ions increases the thermal conductivity by a factor of 2–3. Similar trends are observed for the thermal effusivities and diffusivities of all the types of nanoporous silicon under passivation, but, in that case, the changes are weaker (by a factor of 1.5–2). The ways of tuning the thermal properties of the new nanostructured materials are outlined, which is important for their application.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bogdanov E. V., Bondarev V. S., Gorev M. V., Molokeev M. S., Flerov I. N.
Заглавие : Effect of deuteration on phase transitions in (NH4)3VOF5
Место публикации : Phys. Solid State. - 2022. - Vol. 64, Is. 3. - P.394-399. - ISSN 10637834 (ISSN), DOI 10.21883/PSS.2022.03.53195.237. - ISSN 10906460 (eISSN)
Примечания : Библиогр.: 26
Аннотация: The (ND4)3VOF5 crystal was grown with a high degree of deuteration (D≈92%). Structural and thermophysical studies have been carried out, the parameters of phase transitions have been determined. It was found that the deuteration of the ammonium cation in (NH4)3VOF5 led to a change in the chemical pressure, which was accompanied by an increase in the unit cell volume and an increase in the phase transition temperatures. The baric coefficients dTi/dp were determined and the phase T−p diagram (ND4)3VOF5 was constructed. A decrease in the temperature stability of the initial cubic phase Fm3¯m in (ND4)3VOF5, as well as a wedging out of the intermediate monoclinic phase at a lower pressure as compared to (NH4)3VOF5, was found.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gorev M. V., Molokeev M. S., Kartashev A. V., Pogoreltsev E. I., Mel'nikova S. V., Laptash N. M., Flerov I. N.
Заглавие : Investigation of thermal properties and structure of complex fluoride K3ZrF7
Место публикации : J. Fluor. Chem. - 2021. - Vol. 241. - Ст.109677. - ISSN 00221139 (ISSN), DOI 10.1016/j.jfluchem.2020.109677
Примечания : Cited References: 44. - The reported study was funded by RFBR according to the research project No. 18-02-00269 a. X-ray and dilatometric data were obtained using the equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS"
Аннотация: X-ray, calorimetric and dilatometric studies of K3ZrF7 revealed the existence of the phase transition Fm-3m ↔ R-3m at T0 = 320 K. The structural model assumes a disorder of a pentagonal bipyramid ZrF7 with the following ratio of equivalent orientation positions in the initial and distorted phases: 12 to 6. A good agreement was found between the experimental and model-calculated changes in strain and entropy during the phase transition. A comparative analysis of entropy and structural parameters of related fluorides K3ZrF7 - (NH4)2KZrF7 - (NH4)3ZrF7 was performed. The anomalous behavior of thermodynamic properties in the range 140−230 K is not typical for phase transitions and is accompanied by a significant change in the entropy of the crystal lattice.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova L. T., Molokeev M. S., Chumilina L. G., Ryabov V. V., Denisov V. M.
Заглавие : Heat capacity and thermodynamic functions of GdGaTi2O7 in the temperature range of 320-1000 K
Место публикации : Phys. Solid State. - 2021. - Vol. 63, Is. 4. - P.534-537. - ISSN 1063-7834, DOI 10.1134/S1063783421040065. - ISSN 1090-6460(eISSN)
Примечания : Cited References: 17
Аннотация: Titanate GdGaTi2O7 has been obtained from the initial oxides Gd2O3, Ga2O3, and TiO2 by the solid-state synthesis via annealing in air at temperatures of 1273 and 1573 K. The crystal structure of the titanate has been refined by X-ray diffraction. The high-temperature (320–1000 K) heat capacity of the compound has been measured by differential scanning calorimetry. Based on the experimental dependence Cp = f(T), the main thermodynamic functions of the titanate have been calculated.
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19.

Вид документа : Статья из журнала
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Автор(ы) : Denisova L. T., Molokeev M. S., Kargin, Yu F., Ryabov V. V., Chumilina L. G., Belousova, N., V, Denisov V. M.
Заглавие : Structure and thermodynamic properties of the DyGaTi2O7 and EuGaTi2O7 titanates
Коллективы : Russian Federation Ministry of Science and Higher Education [FSRZ-2020-0013]
Место публикации : Inorg. Mater. - 2021. - Vol. 57, Is. 7. - P.733-740. - ISSN 0020-1685, DOI 10.1134/S0020168521070050. - ISSN 1608-3172(eISSN)
Примечания : Cited References: 26. - This work was supported by the Russian Federation Ministry of Science and Higher Education as part of the state research target for the Siberian Federal University federal state autonomous educational institution of higher education, project no. FSRZ-2020-0013
Предметные рубрики: CRYSTAL-STRUCTURE
MAGNETIC-PROPERTIES
STATE
Аннотация: The DyGaTi2O7 and EuGaTi2O7 titanates have been prepared by solid-state reactions in a starting mixture of Dy2O3 (Eu2O3), Ga2O3, and TiO2 via firing in air at temperatures of 1273 and 1573 K, and their crystal structure has been studied by X-ray diffraction. Their high-temperature heat capacity (350-1000 K) has been determined by differential scanning calorimetry. The Cp(T) experimental data have been used to calculate the thermodynamic functions of the titanates.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova L. T., Molokeev M. S., Kargin, Yu F., Irtyugo L. A., Belousova, N., V, Denisov V. M.
Заглавие : Synthesis, crystal structure, and thermodynamic properties of CuSm2Ge2O8
Коллективы : Siberian Federal University [FSRZ2020-0013]
Место публикации : Russ. J. Inorg. Chem. - 2021. - Vol. 66, Is. 12. - P.1817-1821. - ISSN 0036-0236, DOI 10.1134/S0036023621120020. - ISSN 1531-8613(eISSN)
Примечания : Cited References: 30. - This work was carried out with partial financial support within the framework of the State assignment for science of the Siberian Federal University, project number FSRZ2020-0013
Предметные рубрики: TEMPERATURE HEAT-CAPACITY
CU-O
PREDICTION
GERMANATES
GROWTH
Аннотация: Copper samarium germanate CuSm2Ge2O8 have been synthesized by the ceramic method from CuO, Sm2O3, and GeO2 in air at the final calcination temperature 1273 K (200 h), and its crystal structure has been determined (space group Cm; a = 9.7592(2) Å, b = 15.2608(4) Å, c = 8.2502(2) Å, β = 148.2566(8)°, V = 646.46(3) Å3). The temperature dependence of the molar heat capacity Cp = f(T) measured in the temperature range 350–1000 K shows a maximum at Tmax = 498.5 K caused by the phase transition. Thermodynamic properties have been calculated from experimental data.
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