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1.
Kikoin, K. A.
A novel explanation of the phase-transition with the valence change in
cation
-substituted samarium monochalcogenides / K. A. Kikoin, E. G. Goryachev, V. A. Gavrichkov> // Solid State Commun. - 1986. -
Vol. 60
,
Is. 8
. - P. 663-667,
DOI
10.1016/0038-1098(86)90264-4. - Cited References: 21 . - ISSN 0038-1098
РУБ
Physics, Condensed Matter
WOS
,
Scopus
Держатели документа:
LV KIRENSKII PHYS INST,KRASNOYARSK 660036,USSR
ИФ СО РАН
Доп.точки доступа:
Goryachev, E. G.; Горячев, Евгений Геннадьевич; Gavrichkov, V. A.; Гавричков, Владимир Александрович
}
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2.
Bayukov, O. A.
The prognostication possibility of some magnetic-properties for dielectrics on the basis of covalency parameters of ligand
cation
bonds / O. A. Bayukov, A. F. Savitskii> // Phys. Status Solidi B. - 1989. -
Vol. 155
,
Is. 1
. - P. 249-255,
DOI
10.1002/pssb.2221550125. - Cited References: 27 . - ISSN 0370-1972
РУБ
Physics, Condensed Matter
WOS
Доп.точки доступа:
Savitskii, A. F.; Баюков, Олег Артемьевич
}
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3.
On the two-phase
magnetic state in a CuxZn1-xCr2Se4
cation
-substituted chalcogenide spinel / A. D. Balaev [et al.]> // Phys. Solid State. - 2001. -
Vol. 43
,
Is. 6
. - P. 1089-1092,
DOI
10.1134/1.1378149. - Cited References: 8 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Аннотация:
The region of the concentration magnetic phase transition in a CuxZn1-xCr2Se4 chalcogenide spinel in which the substituted ion concentration x smoothly varies from 0.1 to 0.2 with a step of 0.02 is thoroughly investigated. An anomalous behavior of the Curie temperature is observed. This anomaly is associated with the nucleation of ferromagnetically ordered microregions in the vicinity of Cr ions with an intermediate valence and subsequent long-range magnetic ordering at a critical Cu concentration in the range 0.12 x(c) 0.14. The possible coexistence of ferro- and antiferromagnetism in the same temperature range is revealed. (C) 2001 MAIK "Nauka/Interperiodica".
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
Доп.точки доступа:
Balaev, A. D.; Балаев, Александр Дмитриевич; Zhukov, E. G.; Ivanova, N. B.; Иванова, Наталья Борисовна; Kazak, N. V.; Казак, Наталья Валерьевна; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Popel, E. P.
}
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4.
Beznosikov, B. V.
Prediction of pra-phases of layered perovskite-like structures with
cation
vacancies / B. V. Beznosikov, K. S. Aleksandrov> // J. Struct. Chem. - 2002. -
Vol. 43
,
Is. 1
. - P. 172-175,
DOI
10.1023/A:1016098521933 . - ISSN 0022-4766
Scopus
,
РИНЦ
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Публикация на русском языке
Безносиков, Борис Валерьевич. Прогноз прафаз слоистых перовскитоподобных структур с катионными вакансиями [Текст] / Б. В. Безносиков, К. С. Александров // Журн. структ. химии. - Новосибирск : Изд-во СО РАН, 2002. - Т. 43 № 1. - С. 184-187
Доп.точки доступа:
Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Безносиков, Борис Валерьевич
}
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5.
Zinenko, V. I.
Statistical mechanics of
cation
ordering and lattice dynamics of PbZrxTi1-xO3 solid solutions / V. I. Zinenko, S. N. Sofronova> // Phys. Solid State. - 2004. -
Vol. 46
,
Is. 7
. - P. 1291-1300,
DOI
10.1134/1.1778455. - Cited References: 18 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
PEROVSKITE
Аннотация:
An effective Hamiltonian for Zr-Ti
cation
ordering in PbZrxTi1 - xO3 solid solutions is written out. To determine the parameters of the effective Hamiltonian, a nonempirical calculation is performed within an ionic-crystal model taking into account the deformation and dipole and quadrupole polarizabilities of ions. The thermodynamic properties of
cation
ordering are studied using the Monte Carlo method. The calculated phase transition temperatures (180 and 250 K for the concentrations x = 1/3 and 1/2, respectively) are much lower than the melting temperature of the compound under study. At such temperatures, the ordering kinetics is frozen and, in reality, the phase transition to the ordered phase does not occur, in agreement with experimental observations. Within the same ionic-crystal model, we calculated the high-frequency permittivity, Born dynamic charges, and the lattice vibration spectrum for a completely disordered phase and certain ordered phases. It is shown that soft vibration modes, including ferroelectric ones, exist in the lattice vibration spectrum of both the completely disordered and the ordered phases. (C) 2004 MAIK "Nauka / Interperiodica".
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Доп.точки доступа:
Sofronova, S. N.; Софронова, Светлана Николаевна; Зиненко, Виктор Иванович
}
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6.
Zinenko, V. I.
The nonempirical calculation of the
cation
ordering and lattice dynamics in the solid solutions of PbSc1/2Nb1/2O3 and PbSc1/2Ta1/2O3 / V. I. Zinenko, S. N. Sofronova ; ed.: A Kaplyanskii, A Akimov, Akimov,> // 11th International Conference on Phonon Scattering in Condensed Matter (PHONONS 2004) (JUL 25-30, 2004, St Petersburg, RUSSIA) : WILEY-V C H VERLAG GMBH, 2004. - P. 3047-3051,
DOI
10.1002/pssc.200405286. - Cited References: 10 . - ISBN 3-527-40588-7
РУБ
Physics, Condensed Matter
Аннотация:
An effective Hamiltonian for the study of Sc-Nb(Ta)
cation
ordering in PbSc1/2Nb(Ta)(1/2)O-3 solid solutions is written out. To determine the parameters of the effective Hamiltonian, a nonempirical calculation is performed within an ionic-crystal model taking into account the deformation, dipole and quadrupole polarizabilities of ions. The phase transition temperatures are calculated by mean field, cluster approximations and Monte-Carlo method. Within the same ionic-crystal model, we calculated the high-frequency permittivity, Born dynamic charges, and the phonon spectrum for a completely disordered and ordered phases. (C) 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Krasnoyarsk 660036, Akademgorokok, Russia
ИФ СО РАН
Доп.точки доступа:
Sofronova, S. N.; Софронова, Светлана Николаевна; Зиненко, Виктор Иванович
}
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7.
Zinenko, V. I.
Statistical mechanics of
cation
ordering in PbSc1/2Ta1/2O3 and PbSc1/2Nb1/2O3 solid solutions / V. I. Zinenko, S. N. Sofronova> // Phys. Solid State. - 2005. -
Vol. 47
,
Is. 12
. - P. 2309-2314,
DOI
10.1134/1.2142896. - Cited References: 17 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
PHASE-TRANSITION
PEROVSKITE
DISORDER
FERROELECTRICS
CRYSTALS
MODEL
Аннотация:
A model Hamiltonian for B
cation
ordering (Sc-Nb(Ta)) in PbSc1/2Nb1/2O3 and PbSc1/2Ta1/2O3 solid solutions is constructed. The parameters of the model Hamiltonian are determined from the ab initio calculation within the ionic crystal model with allowance made for the deformability and the dipole and quadrupole polarizabilities of the ions. The temperatures of the phase transition due to the ordering of the B cations are calculated by the Monte Carlo method in the mean-field and cluster approximations. The phase transition temperatures calculated by the Monte Carlo method (1920 K for PbSc1/2Ta1/2O3 and 1810 K for PbSc1/2Nb1/2O3) are consistent with the experimental data (1770 and 1450 K, respectively). The thermodynamic properties of the
cation
ordering are investigated using the Monte Carlo method. (c) 2005 Pleiades Publishing, Inc.
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Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Доп.точки доступа:
Sofronova, S. N.; Софронова, Светлана Николаевна; Зиненко, Виктор Иванович
}
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8.
Zinenko, V. I.
The nonempirical calculations of the
cation
ordering and lattice dynamics in the solid solution of PbSc1/2Nb1/2O3 and PbSc1/2Ta1/2O3 [Text] / V. I. Zinenko, S. N. Sofronova> // Sol. St. Phen. - 2006. -
Vol. 115
. - P. 305-310
DOI
10.4028/3-908451-24-8.305
РИНЦ
,
РИНЦ
Держатели документа:
L.V. Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, Akademgorodok, 660036
Доп.точки доступа:
Sofronova, S. N.; Софронова, Светлана Николаевна; Зиненко, Виктор Иванович
}
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9.
Effect of central
cation
substitutionon the properties and phase transitions in (NH4)3Me(O2)2F4 oxyfluorides / V. D. Fokina, I. N. Flerov, M. S. Molokeev [et al.]> // The 6th International Seminar on Ferroelastic Physics : abstract book. - Voronezh, 2009. - P. 5
Материалы конференции
Доп.точки доступа:
Fokina, V. D.; Фокина, Валентина Дмитриевна; Flerov, I. N.; Флёров, Игорь Николаевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Pogoreltsev, E. I.; Погорельцев, Евгений Ильич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Laptev, Y. V.; Воронежский государственный технический университет; Российская академия наук; International Seminar on ferroelastic physics (6 ; 2009 ; Sept. 22-25 ; Voronezh); Международный семинар по физике сегнетоэластиков (6(11) ; 2009 ; 22-25 сент. ; Воронеж)
}
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10.
Magnetic and electrical
properties of
cation
-substituted sulfides Me (x) Mn1-x S (Me = Co, Gd) / S. S. Aplesnin [et al.]> // Phys. Solid State. - 2009. -
Vol. 51
,
Is. 4
. - P. 698-701,
DOI
10.1134/S1063783409040076. - Cited References: 17. - This study was supported by the Russian Foundation for Basic Research RFFI-BRFFI (project no. 0802-90031) and FFIRB (project no. F08R-037). . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
ALPHA-MNS
MAGNETORESISTANCE
TRANSPORT
Аннотация:
The temperature dependences of the specific magnetization sigma and the electrical resistivity rho of Me (x) Mn1 - x S single crystals (Me= Co, Gd; x= 0.05) have been studied in the temperature range 80 K T 1000 K. The samples under study have revealed the presence of a spontaneous magnetic moment below the N,el temperature (T (N)) and ferromagnetic clusters in Gd0.05Mn0.95S in the temperature range 146 K T 680 K. Substitution of gadolinium for manganese initiates a transition from p-type to n-type conduction. The change in the conduction type is accompanied by an increase in the electrical resistivity at 300 K by approximately one order of magnitude and, accordingly, by a decrease in the activation energy. The magnetic and electrical properties of the crystals under study have been interpreted in terms of the cluster model with temperature-dependent ferromagnetic exchange and an electron localized in this cluster.
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Держатели документа:
[Aplesnin, S. S.
Ryabinkina, L. I.
Romanova, O. B.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Reshetnev Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
[Sokolov, V. V.
Pichugin, A. Yu.] Russian Acad Sci, Siberian Branch, Inst Inorgan Chem, Novosibirsk 630090, Russia
[Galyas, A. I.
Demidenko, O. F.
Makovetskii, G. I.
Yanushkevich, K. I.] Natl Acad Sci Belarus, Sci Pract Mat Res Ctr, Minsk 220072, Byelarus
ИФ СО РАН
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation
Reshetnev Siberian State Aerospace University, pr. im. Gazety Krasnoyarski rabochi 31, Krasnoyarsk 660014, Russian Federation
Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Akademika Lavrent'eva 3, Novosibirsk 630090, Russian Federation
Scientific-Practical Materials Research Centre, National Academy of Sciences of Belarus, ul. P. Brovki 19, Minsk 220072, Belarus
Доп.точки доступа:
Aplesnin, S. S.; Аплеснин, Сергей Степанович; Ryabinkina, L. I.; Рябинкина, Людмила Ивановна; Romanova, O. B.; Романова, Оксана Борисовна; Sokolov, V. V.; Pichugin, A. Y.; Galyas, A. I.; Demidenko, O. F.; Makovetskii, G. I.; Yanushkevich, K. I.; Russian Foundation for Basic Research RFFI-BRFFI [0802-90031]; FFIRB [F08R-037]
}
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11.
Zamkova, N. G.
Effect of
cation
substitution on the lattice dynamics and ferroelectric instability of cubic BaTiO3 and BaZrO3 doped with Bi and La ions / N. G. Zamkova, V. I. Zinenko> // Phys. Solid State. - 2009. -
Vol. 51
,
Is. 5
. - P. 973-981,
DOI
10.1134/S1063783409050151. - Cited References: 11. - This work was supported by the Russian Foundation for Basic Research, project no. 07-02-00069. . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
CERAMICS
Аннотация:
The spectra of lattice vibration frequencies of solid solutions Ba1 - x Bi(2x/3)a-- Ti-x/3(Zr)O-3 and Ba1 - x La (x) Ti(Zr)(1 - x/4)a-- O-x/4(3) are calculated in terms of a generalized Gordon-Kim model with inclusion of the dipole and quadrupole polarizabilities. Over the entire concentration range, the calculated phonon spectra contain a ferroelectric soft mode. The effect of various interactions on the ferroelectric instability of these solid solutions is studied. It is shown that the character of ferroelectric instability is largely determined by the mechanism of charge compensation.
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Держатели документа:
[Zamkova, N. G.
Zinenko, V. I.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation
Доп.точки доступа:
Zinenko, V. I.; Зиненко, Виктор Иванович; Замкова, Наталья Геннадьевна; Russian Foundation for Basic Research [07-02-00069]
}
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12.
Dielectric properties of
a mixed-valence Pb3Mn7O15 manganese oxide / N. V. Volkov [et al.]> // J. Phys.: Condens. Matter. - 2010. -
Vol. 22
,
Is. 37
. - Ст. 375901,
DOI
10.1088/0953-8984/22/37/375901. - Cited References: 14. - This study was supported by the Russian Foundation for Basic Research 'Siberia', project No. 09-02-98003, and the Siberian Branch of the Russian Academy of Sciences, integration project No. 101. . - ISSN 0953-8984
РУБ
Physics, Condensed Matter
Кл.слова (ненормированные):
cation
--
lead
--
manganese derivative
--
oxide
--
article
--
chemical model
--
chemistry
--
crystallization
--
electric conductivity
--
electronics
--
methodology
--
temperature
--
Cations
--
Crystallization
--
Electric Conductivity
--
Electronics
--
Lead
--
Manganese Compounds
--
Models, Chemical
--
Oxides
--
Temperature
--
AC electric field
--
Analysis of resistivity
--
Carrier hopping
--
Charge ordering
--
Complex dielectric constant
--
Crystal site
--
Debye models
--
Dielectric constants
--
Dielectric spectra
--
Frequency windows
--
Lattice sites
--
Low frequency
--
Manganese ions
--
Mixed valence
--
Mixed valence state
--
Relaxation behaviors
--
Temperature range
--
Electric fields
--
Manganese
--
Manganese oxide
--
Permittivity
--
Single crystals
--
Crystal symmetry
Аннотация:
We investigated the low-frequency dielectric properties of a Pb3Mn7O15 single crystal with manganese ions in the mixed-valence state (Mn3+/Mn4+). Dielectric relaxation was found in the frequency window from 20 to 100 kHz in the temperature range 110-180 K. The dielectric spectra of the crystal were analyzed using a Debye model. Estimations made within the model and analysis of resistivity data suggest that the relaxation behavior of the dielectric constant is related to polaronic charge carrier hopping. Around 250 K, charge ordering occurs in the crystal when the Mn3+ and Mn4+ ions are arranged in a specific order among the crystal sites. With a decrease in temperature, an ac electric field can induce a charge hop between the equivalent lattice sites available, related to crystal symmetry. This hopping is equivalent to the reorientation of an electric dipole that yields Debye-type behavior of the complex dielectric constant. The observed anisotropy in the behavior of the dielectric properties and resistivity can be attributed to a pronounced two-dimensional character of the crystal structure.
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Держатели документа:
[Volkov, N. V.
Eremin, E. V.
Sablina, K. A.
Sapronova, N. V.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
L V Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk, Russia.
L V Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk 660036, Russian Federation
Доп.точки доступа:
Volkov, N. V.; Волков, Никита Валентинович; Eremin, E. V.; Еремин, Евгений Владимирович; Sablina, K. A.; Саблина, Клара Александровна; Sapronova, N. V.
}
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13.
Electrical and thermoelectric
properties of
cation
– substituted GdXMn1-XS sulphides [Text] / O. F. Demidenko, A. I. Galyas [et al.]> //
IV Euro-Asian Symposium "Trends in MAGnetism" Nanospintronics (EASTMAG-2010). School for young scientist "Spintronics" : June 28 - Lule 2, 2010"Book of abstracts. - Ekaterinburg, 2010. - P. 72
РИНЦ
Доп.точки доступа:
Demidenko, O.F.; Galyas, A.I.; Makovetskii, G.I.; Romanova, O.B.; Ryabinkina, L.I.; Yanushkevich, K.I.; Euro-Asian Symposium "Trends in MAGnetism"(4 ; 2010 ; Jun.-Jul. ; Ekaterinburg); "Trends in MAGnetism", Euro-Asian Symposium(4 ; 2010 ; Jun.-Jul. ; Ekaterinburg); Уральское отделение РАН
}
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14.
Effect of
cation
substitution in fluorine-oxygen molybdates (NH4)(2-x) A (x) MoO2F4 / E. V. Bogdanov [et al.]> // Phys. Solid State. - 2011. -
Vol. 53
,
Is. 2
. - P. 303-308,
DOI
10.1134/S1063783411020065. - Cited References: 11. - This study was supported by the Russian Foundation for Basic Research (project no. 09-02-00062) and the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation (project no. NSh-1011.2008.2). . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
PHASE-TRANSITIONS
CRYSTALS
(NH4)(2)WO2F4
DIFFRACTION
OXYFLUORIDE
MECHANISM
DISORDER
Аннотация:
Thermophysical and structural studies of (NH4)(2 - x) A (x) MoO2F4 (A = Cs, Rb, K) solid solutions of oxyfluorides have been performed. The character of the influence of
cation
substitutions on the stability of the initial phase (space group Cmcm) and on the mechanism of phase transitions has been elucidated.
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Держатели документа:
[Bogdanov, E. V.
Vasil'ev, A. D.
Flerov, I. N.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Vasil'ev, A. D.
Flerov, I. N.] Siberian Fed Univ, Inst Engn Phys & Radioelect, Krasnoyarsk 660074, Russia
[Laptash, N. M.] Russian Acad Sci, Inst Chem, Far Eastern Branch, Vladivostok 690022, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, ul. Kirenskogo 28, Krasnoyarsk 660074, Russian Federation
Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok 690022, Russian Federation
Доп.точки доступа:
Bogdanov, E. V.; Богданов, Евгений Витальевич; Vasil'ev, A. D.; Васильев, Александр Дмитриевич; Flerov, I. N.; Флёров, Игорь Николаевич; Laptash, N. M.
}
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15.
The superexchange interactions
in mixed Co-Fe ludwigite / N. V. Kazak [et al.]> // J. Magn. Magn. Mater. - 2011. -
Vol. 323
,
Is. 5
. - P. 521-527,
DOI
10.1016/j.jmmm.2010.09.057. - Cited Reference Count: 15. - Гранты: This study was supported by the Russian Foundation for Basic Research (Project no. 09-02-00171-a), the Federal Agency for Science and Innovation (Rosnauka) (Project no. MK-5632. 2010.2), Physical Division of the Russian Academy of Science, the program "Strongly Correlated Electrons", project 2.3.1.; The financial support of Spanish MINCYT, MAT08/1077 and Aragonese E-34 project are also acknowledged. - Финансирующая организация: Russian Foundation for Basic Research [09-02-00171-a]; Federal Agency for Science and Innovation (Rosnauka) [MK-5632. 2010.2]; Physical Division of the Russian Academy of Science; "Strongly Correlated Electrons" [2.3.1]; Spanish MINCYT [MAT08/1077]; Aragonese E-34 project . - MAR. - ISSN 0304-8853
Рубрики:
TRANSPORT-PROPERTIES
SPECTRA
Кл.слова (ненормированные):
ludwigite structure
--
magnetic susceptibility
--
magnetic frustration
--
mott conductivity
--
ludwigite structure
--
magnetic frustration
--
magnetic susceptibility
--
mott conductivity
--
ac susceptibility
--
cation
distributions
--
crystal data
--
crystallographic sites
--
electrical resistivity
--
iron atoms
--
low temperatures
--
ludwigite structure
--
magnetic behavior
--
magnetic frustrations
--
magnetic system
--
magnetic transitions
--
mossbauer
--
mossbauer effects
--
mott conductivity
--
mott hopping
--
superexchange energy
--
superexchange interaction
--
temperature regions
--
trivalent iron
--
variable range
--
cobalt
--
electric conductivity
--
magnetic susceptibility
--
magnetism
--
mossbauer spectroscopy
--
x ray diffraction
--
crystal structure
Аннотация:
The crystal structure,
cation
distribution and exchange interactions in the Co2.25Fe0.75O2BO3 ludwigite have been explored through X-ray diffraction, electrical resistivity, ac-susceptibility and Mossbauer effect measurements. The crystal data have shown that iron atoms occupy the most symmetric crystallographic sites Fe4 and Fe2. The complex magnetic behavior with two magnetic transitions near 70 and 115 K at low temperatures was found. The Mossbauer data have displayed the trivalent iron states only. The values of superexchange energies have been estimated for Co3O2BO3 and Co2.25Fe0.75O2BO3 yielding a significant role of frustrations in the ludwigite magnetic system. Variable range Mott hopping conductivity law was proved to be valid in the wide temperature region, pointing out a localized character of charge carriers rather than collective. (C) 2010 Elsevier B.V. All rights reserved.
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Держатели документа:
RAS, LV Kirensky Phys Inst, SB, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660074, Russia
Krasnoyarsk State Agr Univ, Krasnoyarsk 660049, Russia
Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Abd Dept Fis Mat Condensada, E-50009 Zaragoza, Spain
Univ Zaragoza, Area Medidas Fis, Serv Instrumentac Cient, E-50009 Zaragoza, Spain
Доп.точки доступа:
Kazak, N. V.; Казак, Наталья Валерьевна; Bayukov, O. A.; Баюков, Олег Артемьевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Rudenko, V. V.; Руденко, Валерий Васильевич; Ivanova, N. B.; Иванова, Наталья Борисовна; Knyazev, Yu. V.; Князев, Юрий Владимирович; Bartolom, J.; Arauzo, A.
}
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16.
Crystal structure of
enrofloxacinium tetrabromidodichloridostannate(IV) monohydrate / N. N. Golovnev [et al.]> // J. Struct. Chem. - 2013. -
Vol. 54
,
Is. 2
. - P. 377-382,
DOI
10.1134/S0022476613020157. - Cited References: 17. - The work was supported by the grant of the President of the Russian Federation for the support of leading scientific schools of the Russian Federation (NSh-4828.2012.2) and the Federal Targeted Program "Scientific and Scientific Pedagogical Personnel of Innovative Russia, 2009-2013" (State contracts Nos. 02.740.11.0269 and 02.740.11.0629). . - ISSN 0022-4766
РУБ
Chemistry, Inorganic & Nuclear + Chemistry, Physical
Рубрики:
COMPLEX
Кл.слова (ненормированные):
crystal structure
--
enrofloxacinium
cation
--
tetrabromidodichloridostannate(IV) anion
--
hydrogen bonds
Аннотация:
A new compound EnrH(3)[SnBr3.46Cl2.54]center dot H2O, where EnrH (3) (2+) is the enrofloxacinium
cation
(C19H24FN3O (3) (2+) ), is synthesized and its crystal and molecular structure is determined. Crystallographic data for enrofloxacinium tetrabromidodichloridostannate(IV) monohydrate are as follows: a = 17.1262(19) , b = 10.3435(11) , c = 17.2582(19) , beta = 119.203(1)A degrees, V = 2640.5(4) (3), space group P2(1)/c, Z = 4. Hydrogen bonds form a branched three-dimensional network linking EnrH (3) (2+) , [SnBr3.46Cl2.54](2-), and water molecules. The structure is also stabilized by the pi-pi interaction of EnrH (3) (2+) aromatic rings.
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Публикация на русском языке
Кристаллическая структура моногидрата тетрабромидодихлоридостанната(IV) энрофлоксациния // Журнал структурной химии. - 2013. - Т. 54, № 2. - С. 325-330
Держатели документа:
Siberian Fed Univ, Krasnoyarsk, Russia
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk, Russia
Доп.точки доступа:
Golovnev, N. N.; Головнёв, Николай Николаевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Golovneva, I. I.; Головнева И.И.; Glushchenko, G. A.; Глущенко, Гарий Анатольевич
}
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17.
Zamkova, N. G.
First-principles calculations of ferroelectric properties in AA`BB`O6 double perovskites with different types of
cation
ordering / N. G. Zamkova, V. S. Zhandun, V. I. Zinenko> // Phys. status solidi B. - 2013. -
Vol. 250
,
Is. 9
. - P. 1888-1897,
DOI
10.1002/pssb.201349084 . - ISSN 0370-1972
Перевод заглавия:
Первопринципные расчеты сегнетоэлектрических свойств двойных перовскитов AA'BB'O6
Кл.слова (ненормированные):
Density functional theory
--
Double perovskites
--
Ferroelectrics
--
Polarization
Аннотация:
First-principles calculations of lattice dynamics and polarization properties have been performed for double perovskite ABiBNbO6 (A - alkali metal Na, Rb, and B - trivalent metal Sc, Lu). Three possible types of A- and B-site
cation
ordering are studied: layer and columnar ordering of A-site cations with rocksalt ordering of B-site cations, and layer ordering of both cations. The ground state of all compounds is polar with a large value of polarization for all types of
cation
ordering. For some compounds we obtain spontaneous polarization of 0.7-1.0Cm-2 that is twice the BaTiO3 value. For RbBiScNbO6 the lowest-energy state has layer ordering of both A- and B-site cations, which is rare for compounds with double-perovskite structure.
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Доп.точки доступа:
Zhandun, V. S.; Жандун, Вячеслав Сергеевич; Zinenko, V. I.; Зиненко, Виктор Иванович; Замкова, Наталья Геннадьевна
}
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18.
Cation
substitution dependent
bimodal photoluminescence in whitlockite structural Ca3-xSrx(PO4)2:Eu2+ (0 ≤ x ≤ 2) solid solution phosphors / H. P. Ji [et al.]> // Inorg. Chem. - 2014. -
Vol. 53
,
Is. 20
. - P. 11119-11124,
DOI
10.1021/ic501679f. - Cited References: 37. - This work was supported by the National Natural Science Foundations of China (Grant Nos. 51032007, 51002146, 51272242), the Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20130022110006), the Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), and Beijing Youth Excellent Talent Program (YETP0635). V.V.A. acknowledges the Ministry of Education and Science of the Russian Federation for financial support. . - ISSN 0020-1669. - ISSN 1520-510X
Перевод заглавия:
Катион зависимая бимодальная люминесценция в твердом растворе Ca3-xSrx(PO4)2:Eu2+ (0 ˂ x ˂ 2) со структурой витлокита
РУБ
Chemistry, Inorganic & Nuclear
Рубрики:
LIGHT-EMITTING-DIODES
EFFICIENT ENERGY-TRANSFER
EMISSION-TUNABLE PHOSPHOR
EXCITED WHITE LEDS
CRYSTAL-STRUCTURE
LUMINESCENCE PROPERTIES
Mn2+ PHOSPHOR
COLOR TONE
PHASE
Eu2+
Аннотация:
Cation
substitution dependent tunable bimodal photoluminescence behavior was observed in the Ca3-xSrx(PO4)2:Eu2+ (0 ≤ x ≤ 2) solid solution phosphors. The Rietveld refinements verified the phase purity and whitlockite type crystal structure of the solid solutions. The tunable photoluminescence evolution was studied as a function of strontium content, over the composition range 0.1 ≤ x ≤ 2. In addition to the emission band peak at 416 nm in Ca3(PO4)2:Eu2+, the substitution of Ca2+ by Sr2+ induced the emerging broad-band peak at 493-532 nm. A dramatic red shift of the emission peak located in the green-yellow region was observed on an increase of x in the samples with 0.75 ≤ x ≤ 2.00. The two emission bands could be related to the EuOn-Ca9 and EuOn-Ca9-xSrx emitting blocks, respectively. The values for the two kinds of emitting blocks in the solid solutions can be fitted well with the observed intensity evolution of the two emission peaks.
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Держатели документа:
China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
SB RAS, LV Kirensky Phys Inst, Lab Crystal Phys, Krasnoyarsk 660036, Russia
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia
Univ Auckland, Dept Chem & Mat Engn, Auckland 1142, New Zealand
Доп.точки доступа:
Ji, H. P.; Huang, Z. H.; Xia, Zhiguo; Molokeev, M. S.; Молокеев, Максим Сергеевич; Atuchin, V. V.; Атучин, Виктор Валерьевич; Huang, S. F.
}
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19.
Blue-shift of Eu2+
emission in (Ba,Sr)3Lu(PO4)3:Eu2+ eulytite solid-solution phosphors resulting from release of neighbouring-
cation
-induced stress / Z. Y. Wang [et al.]> // Dalton Trans. - 2014. -
Vol. 43
,
Is. 44
. - P. 16800-16804,
DOI
10.1039/c4dt02319f. - Cited References: 16. - The present work was supported by the National Natural Science Foundations of China (grant no. 51002146, no. 51272242), Natural Science Foundations of Beijing (2132050), the Program for New Century Excellent Talents in the University of the Ministry of Education of China (NCET-12-0950), Beijing Nova Program (Z131103000413047), Beijing Youth Excellent Talent Program (YETP0635) and the Funds of the State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University (KF201306). V.V.A. is partly supported by the Ministry of Education and Science of the Russian Federation. . - ISSN 1477-9226. - ISSN 1477-9234
Перевод заглавия:
Синее смещение излучения Eu2+ в твердых растворах (Ba,Sr)3Lu(PO4)3:Eu2 со структурой эулита, вызванное снятием напряжения, индуцированного соседними катионами
РУБ
Chemistry, Inorganic & Nuclear
Рубрики:
TUNABLE COLOR TONE
EXCITED WHITE LEDS
CRYSTAL-STRUCTURE
TEMPERATURE
IONS
Аннотация:
A series of iso-structural eulytite-type (Ba,Sr)(3)Lu(PO4)(3):Eu2+ solid-solution phosphors with different Sr/Ba ratios were synthesized by a solid-state reaction. Crystal structures of (Ba,Sr)(3)Lu(PO4)(3):Eu2+ were resolved by the Rietveld method, which shows an eulytite-type cubic Bi-4(SiO4)(3) structure with cations disordered in a single C-3 site while the oxygen atoms were distributed over two partially occupied sites. The emission peaks of Ba(3-x)SrxLu(PO4)(3):Eu2+ (0
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Держатели документа:
China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia
Доп.точки доступа:
Wang, Z. Y.; Xia, Zhiguo; Molokeev, M. S.; Молокеев, Максим Сергеевич; Atuchin, V. V.; Атучин, Виктор Валерьевич; Liu, Q. L.
}
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20.
Ryabinkina, L. I.
Magnetotranport properties of
cation
-substituted sulphides VXMn1-XS / L. I. Ryabinkina, O. B. Romanova, N. I. Kisilev> //
Moscow Int. Symp. on Magnet. (MISM-2014) : Book of abstracts. - 2014. - Ст. 1PO-K-11. - P. 544 . - ISBN 978-5-91978-025-0
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Доп.точки доступа:
Romanova, O. B.; Романова, Оксана Борисовна; Kisilev, N. I.; Рябинкина, Людмила Ивановна; Moscow International Symposium on Magnetism(6 ; 2014 ; 29 June-3 July ; Moscow); Московский государственный университет им. М.В. Ломоносова
}
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