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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Li, Oksana A., Lin, Chun-Rong, Chen, Hung-Yi, Hsu, Hua-Shu, Wu, Kai-Wun, Tseng, Yaw-Teng, Bayukov O. A., Edelman I. S., Ovchinnikov S. G., Shih, Kun-Yauh
Заглавие : Structural and magnetic properties of Fe1−xCoxSe1.09 nanoparticles obtained by thermal decomposition
Место публикации : Mater. Res. Express: IOP Publishing, 2015. - Vol. 2, No. 12. - Ст.126501. - ISSN 2053-1591, DOI 10.1088/2053-1591/2/12/126501
Примечания : Cited References: 30. - This work is supported by the Ministry of Science and Technology of Taiwan (MOST103-2811-M-153 -001 and MOST102-2112-M-153 -002 -MY3).
Предметные рубрики: X-RAY-DIFFRACTION
MOSSBAUER-SPECTROSCOPY
CRYSTAL-STRUCTURES
IRON SELENIDES
SUPERCONDUCTIVITY
FeSe
MARCASITE
PYRITE
Ключевые слова (''Своб.индексиров.''): nanoparticles--chalcogenide--iron-cobalt selenide--ferrimagnetism--paramagnetism--mossbauer spectroscopy
Аннотация: A series of Fe1−xCoxSe1.09 (x = 0 to ) nanoparticles were synthesized by thermal decomposition method. Particles in composition range Fe0.5Co0.5Se1.09 to CoSe1.09 crystallized in monoclinic structure of Co6.8Se8 , while FeSe1.09 crystallized in hexagonal structure of FeSe achavalite. Magnetization dependences on temperature and external magnetic field reveal complicated magnetic behavior and correspond to the sum of paramagnetic and superparamagnetic response. Mössbauer spectra contain several paramagnetic doublets with parameters corresponding to nonequivalent positions of divalent and trivalent iron cations with low spin. The nonequivalent positions appeared due to inhomogeneous distribution of Co ions or metal vacancies in iron surrounding.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Berry F. J., Dmitrieva T. V., Ovanesyan N. S., Lyubutin I. S., Thomas M. F., Sarkisyan V. A., Ren X., Aminov T. G., Shabunina G. G., Rudenko V., Vorotynov A. M., Dubinskaya Y. L.
Заглавие : Magnetic order in FeCr2S4-type chalcogenide spinels
Место публикации : J. Phys.: Condens. Matter: IOP PUBLISHING LTD, 2007. - Vol. 19, Is. 26. - Ст.266204. - ISSN 0953-8984, DOI 10.1088/0953-8984/19/26/266204
Примечания : Cited References: 15
Предметные рубрики: COLOSSAL-MAGNETORESISTANCE
TRANSITION
Ключевые слова (''Своб.индексиров.''): doping (additives)--iron compounds--magnetization--magnetoresistance--mossbauer spectroscopy--x ray absorption fine structure spectroscopy--chalcogenide spinels--low temperature magnetic behaviour--magnetic ordering temperature--thiospinels--chalcogenides
Аннотация: The thiospinels of composition FeCr2S4 and Fe1+xCr2-2xSnxS4 with 0 x 0.1 have been examined by means of extended x- ray absorption fine structure, Mossbauer spectroscopy and magnetoresistance techniques. The structural characterization shows that tin enters the spinel- related lattice as Sn4+ and occupies the octahedral B site. Appreciable magnetoresistance is observed in the temperature range 160 - 185 K which includes the magnetic ordering temperature. The effect of slight non- stoichiometry in FeCr2S4 and of tin doping is observed in the M r ossbauer spectra which show the Fe2+ ions to occupy the tetrahedral A sites. The M r ossbauer spectra recorded around the magnetic ordering temperature are sensitive to small ( 0.03 T) applied magnetic fields. The influence of tin on the low temperature magnetic behaviour is associated with the distribution of Cr3+, Sn4+ and Fe3+ ions around tetrahedral Fe2+ sites and vacancies in the anionic sublattice. An interpretation of the colossal magnetoresistance phenomena below TN is suggested.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev A. D., Zhukov E. G., Ivanova N. B., Kazak N. V., Ovchinnikov S. G., Popel E. P.
Заглавие : On the two-phase magnetic state in a CuxZn1-xCr2Se4 cation-substituted chalcogenide spinel
Место публикации : Phys. Solid State: AMER INST PHYSICS, 2001. - Vol. 43, Is. 6. - P1089-1092. - ISSN 1063-7834, DOI 10.1134/1.1378149
Примечания : Cited References: 8
Аннотация: The region of the concentration magnetic phase transition in a CuxZn1-xCr2Se4 chalcogenide spinel in which the substituted ion concentration x smoothly varies from 0.1 to 0.2 with a step of 0.02 is thoroughly investigated. An anomalous behavior of the Curie temperature is observed. This anomaly is associated with the nucleation of ferromagnetically ordered microregions in the vicinity of Cr ions with an intermediate valence and subsequent long-range magnetic ordering at a critical Cu concentration in the range 0.12 x(c) 0.14. The possible coexistence of ferro- and antiferromagnetism in the same temperature range is revealed. (C) 2001 MAIK "Nauka/Interperiodica".
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Berzhanskii V. N., Gavrichkov S. A., Ivanov V. I., Kalinnikov V. T.
Заглавие : Bond formation effect on the g-factor of chalcogenide chromium spinels
Место публикации : Fiz. Tverd. Tela. - 1982. - Vol. 24, Is. 3. - P.945-948. - ISSN 0367-3294
Примечания : Cited References: 15
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Berzhanskii V. N., GAVRICHKOV S. A., IVANOV V. I.
Заглавие : Electron-paramagnetic-res relaxation in chromium chalcogenide spinels
Место публикации : Fiz. Tverd. Tela. - 1982. - Vol. 24, Is. 7. - P.2215-2218. - ISSN 0367-3294
Примечания : Cited References: 8
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Valkov V. V., Ovchinnikov S. G.
Заглавие : Phase-transition with valency changing in chalcogenide chromium spinels
Место публикации : Fiz. Tverd. Tela: MEZHDUNARODNAYA KNIGA, 1980. - Vol. 22, Is. 11. - P3418-3425. - ISSN 0367-3294
Примечания : Cited References: 18
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Romanova O. B., Aplesnin S. S., Sitnikov M. N., Kharkov A. M., Demidenko O. F., Galyas A. I., Yanyshkevich K. I.
Заглавие : Conductivity, structural and magnetic properties of manganese chalcogenide films under anionic substitution by tellurium
Коллективы : Moscow International Symposium on Magnetism, Московский государственный университет им. М.В. Ломоносова, Российский фонд фундаментальных исследований
Место публикации : Moscow International Symposium on Magnetism (MISM-2017): 1-7 July 2017 : book of abstracts. - 2017. - Ст.4PO-I1-30. - P.885 (Шифр 29916280)
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Xia Z., Fang H., Zhang X., Molokeev M. S., Gautier R., Yan Q., Wei S. -H., Poeppelmeier K. R.
Заглавие : CsCu5Se3: a copper-rich ternary chalcogenide semiconductor with nearly direct band gap for photovoltaic application
Место публикации : Chem. Mater. - 2018. - Vol. 30, Is. 3. - P.1121-1126. - ISSN 08974756 (ISSN), DOI 10.1021/acs.chemmater.7b05104
Примечания : Cited References: 35. - The present work was supported by the National Natural Science Foundation of China (Grants 51722202, 91622125, 51572023, 51672023, 11774239, and U1530401), and Natural Science Foundation of Beijing (Grant 2172036). K.R.P. recognizes that this work was made possible by support from the National Science Foundation (Awards DMR-1608218 and DMR-1307698). X.Z. and S.H.W. acknowledge the support from National Key R&D Program of China (Grant 2016YFB0700700).
Ключевые слова (''Своб.индексиров.''): sulfur compounds
Аннотация: Discovery of new semiconductor candidates with suitable band gaps is a challenge for optoelectronic application. A facile solvothermal synthesis of a new ternary chalcogenide semiconductor CsCu5Se3 is reported. The telluride CsCu5Te3 is also predicted to be stable. CsCu5Se3 is isostructural with CsCu5S3 (space group Pmma). The band gap calculations of these chalcogenide semiconductors using hybrid density functional theory indicate nearly direct band gaps, and their values (about 1.4 eV) were confirmed by the optical absorption spectroscopy. These alkali metal copper chalcogenides are interesting examples of copper-rich structures which are commonly associated with favorable photovoltaic application.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Romanova O. B., Sitnikov M. N., Kretinin V. V., Galyas, A., I, Yanushkevich, K., I
Заглавие : The alternating-sign magnetoresistance of polycrystalline manganese chalcogenide films
Коллективы : Russian Foundation for Basic Research (RFBR) [18-52-00009 Bel_a, 18-32-00079 mol_a, 18-42-240001 r_a]; [3.5743.2017/6.7]
Место публикации : Semicond. Sci. Technol. - 2018. - Vol. 33, Is. 8. - Ст.085006. - ISSN 0268-1242, DOI 10.1088/1361-6641/aace44. - ISSN 1361-6641(eISSN)
Примечания : Cited References: 33. - The reported study was funded by Russian Foundation for Basic Research (RFBR) according to the research project No 18-52-00009 Bel_a; No 18-32-00079 mol_a; No 18-42-240001 r_a; the state order No 3.5743.2017/6.7.
Предметные рубрики: NEUTRON-SCATTERING
SURFACE-STATES
MNTE
CONDUCTIVITY
MECHANISM
Ключевые слова (''Своб.индексиров.''): polycrystalline films--magnetoresistance--impedance--polaron--magnetic--properties--thermoelectric
Аннотация: The correlation between the dc and ac electrical resistance and the structural, magnetic, and thermoelectric properties of polycrystalline MnSe1−X Te Х (0.3 ≤ X ≤ 0.4) manganese chalcogenide films in the temperature range of 80–400 K has been investigated. Inhomogeneous electronic states and transitions between them accompanied by structural lattice deformations have been found at temperatures including the Neel temperature region. The magnetic susceptibility maximum above the Neel temperature in a magnetic field of 8.6 kOe has been observed. Temperature ranges of the coexistence of two types of electrically inhomogeneous states have been established by impedance spectroscopy in the frequency range of 0.1–1000 kHz and the change of the hopping conductivity for diffusion one accompanied by the magnetic susceptibility minimum has been found. The magnetoresistance in magnetic fields of up to 12 kОе has been established. It has been revealed that the thermopower and magnetoresistance change its sign upon heating. The experimental data are explained using a spin polaron model with the localization of polarons and formation of the electron phase-separation. The alternation of magnetoresistance in sign is attributed to the ferromagnetic orbital ordering of electrons and the negative magnetoresistance is explained by suppression of spin fluctuations in a magnetic field.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivantsov R. D., Petrov D. A., Ivanova O. S., Edelman I. S., Zharkov S. M., Velikanov D. A., Lin, Chun-Rong
Заглавие : Magnetooptics of nanocomposites based on iron chalcogenide nanoparticles
Коллективы : Asian School-Conference on Physics and Technology of Nanostructured Materials, Азиатская школа-конференция по физике и технологии наноструктурированных материалов
Место публикации : Solid State Phenom. - 2020. - Vol. 312. - P.160-165. - ISSN 1012-0394, DOI 10.4028/www.scientific.net/SSP.312.160. - ISSN 1662-9779
Примечания : Cited References: 13. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, to the research project: № 19-42-240005 «Features of the electronic structure, magnetic properties and optical excitations in nanocrystals of the multifunctional magnetic chalcogenides Fe3S4 and FeSe», by Joint Research Project of Russian Foundation for Basic Research № 19-52-52002 and Ministry of Science and Technology, Taiwan MOST № 108-2923-M-153-001-MY3 and № 106-2112-M-153-001-MY3.
Аннотация: Morphology, structure, magnetic properties and magnetic circular dichroism (MCD) were studied for the FexSy and FexSey nanoparticles (NPs) synthesized with the polyol mediated and the thermal decomposition processes, correspondingly, at different regimes. For all NPs samples, but Fe3S4, MCD was measured for the first time. It has been shown that in the case of sulfides, the character of the MCD spectrum changes as the NPs phase composition transforms from Fe3S4 to FeS with the synthesis temperature increase. At the same time, the shape of the MCD spectrum is almost independent of the NPs phase in the case of iron selenides.
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