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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrovsky A. S., Vyunishev A. M., Zaitsev A. I., Ikonnikov A. A., Pospelov G. I., Slabko V. V., Zhokhova A. A.
Заглавие : Deep UV generation and fs pulses characterization using strontium tetraborate
Коллективы : Nonlinear Optics and Applications (5; 2011 ; Apr. ; 19-21; Prague, Czech Republic)
Место публикации : Proc. of SPIE: SPIE-Int. Soc. Optical Engineering, 2011. - Vol. 8071. - Ст.80710K. - ISSN 0277-786X, DOI 10.1117/12.886189. - ISSN 978-0-81948-661-5
Примечания : Cited References: 12
Предметные рубрики: CRYSTAL
Ключевые слова (''Своб.индексиров.''): nonlinear photonic crystal--strontium tetraborate--second harmonic generation--random quasi phase matching--ultrafast diagnostics
Аннотация: The properties of NPC structures in strontium tetraborate are analyzed. Different types of NPC structures are revealed that possess different nonlinear properties, and their spectral dependences of frequency conversion efficiency are calculated and compared. Experimental study of these structures is reported for the process of doubling of the second harmonic of fs Ti:S laser. Tuning of generated radiation is obtained in the range 187.5 - 232.5 nm, with extreme insensitivity to the angular orientation of NPC. Behavior of tuning curve along investigated fundamental wave range is similar in all studied samples, but efficiency obtained depends on the type of structure. Conversion efficiency and spectral quality of generated radiation is experimentally shown to grow better when using NPC with improved structure. Prospects of VUV converter on a single NPC are discussed. NPCs of SBO are demonstrated to be useful for autocorrelation diagnostics both in random QPM geometry and in the geometry of nonlinear diffraction from virtual beam.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Atuchin V. V., Molokeev M. S., Yurkin G. Yu., Gavrilova T. A., Kesler V. G., Laptash N. M., Flerov I. N., Patrin G. S.
Заглавие : Synthesis, structural, magnetic, and electronic properties of cubic CsMnMoO3F3 oxyfluoride
Место публикации : J. Phys. Chem. C: American Chemical Society, 2012. - Vol. 116, Is. 18. - P.10162-10170. - ISSN 1932-7447, DOI 10.1021/jp302020f
Примечания : Cited References: 64. - We thank Dr. A.M. Ziatdinov for the electron paramagnetic resonance measurements. This study was partly supported by SB RAS (Grant 28).
Предметные рубрики: RAY PHOTOELECTRON-SPECTROSCOPY
PHASE-TRANSITIONS
CORE LEVELS
SURFACE CHARACTERIZATION
CRYSTAL-STRUCTURE
CLEAVED SURFACE
MIXED-VALENCE
OXIDES
MN
MOLYBDENUM
Chemical bondings
Cubic phase
Energy differences
Heat capacity measurements
Oxyfluorides
Powder samples
Solid-state synthesis
Space Groups
Temperature range
Valence electron
Binding energy
Chemical bonds
Electronic structure
Fluorine compounds
Magnetic properties
Metal ions
Photoelectrons
Rietveld method
X ray photoelectron spectroscopy
Electronic properties
Аннотация: A powder sample of CsMnMoO3F3 oxyfluoride has been prepared by solid state synthesis. The pyrochlore-related crystal structure of CsMnMoO3F3 has been refined by the Rietveld method at T = 298 K (space group Fd-3m, a = 10.59141(4) angstrom, V = 1188.123(8) angstrom(3); R-B = 3.44%). The stability of the cubic phase has been obtained over the temperature range T = 110-293 K by heat capacity measurements. Magnetic properties have been measured over the range of T = 2-300 K. The electronic structure of CsMnMoO3F3 has been evaluated by X-ray photoelectron spectroscopy. Chemical bonding effects have been discussed for all metal ions using binding energy difference parameters and wide comparison with related oxides and fluorides. The competition between O-2(-) and F- ions for metal valence electrons has been found.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bovina A. F., Gudim I. A., Eremin E. V., Temerov V. L.
Заглавие : Growth and characterization of Fe1-xMxVO(4) single crystals (M = Al, Cr, Co, Ga)
Место публикации : Crystallogr. Rep.: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 57, Is. 7. - P.955-958. - ISSN 1063-7745, DOI 10.1134/S106377451207005X
Примечания : Cited References: 4
Предметные рубрики: FeVO4
Аннотация: Triclinic Fe1-xMxVO4 single crystals (M = Al, Ga, Co, Cr) have been grown by the flux method from systems based on PbO-V 2O5. Their crystallographic parameters are determined by powder X-ray dif- fraction. Fe1-xGaxVO4 single crystals (x = 0-0.3) with a volume more than 1cm3 are grown using the seeding technique. The temperature and field dependences of magnetization and magnetic susceptibility of the grown Fe1-xGaxVO4 and Fe1-xAlxVO4 single crystals (x = 0.3 in the solution-melt) are reported. It is shown that the magnetizations of these crystals exceed that of FeVO4, and both of their antiferromagnetic phase transi- tions are shifted to lower temperatures.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisov V. M., Volkov N. V., Irtyugo L. A., Patrin G. S., Denisova L. T.
Заглавие : High-temperature heat capacity of the BiFeO3 multiferroic
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 54, Is. 6. - P.1312-1314. - ISSN 1063-7834, DOI 10.1134/S1063783412060108
Примечания : Cited References: 27
Предметные рубрики: STRUCTURAL-CHARACTERIZATION
SINGLE-CRYSTALS
FEATURES
SYSTEM
RANGE
Аннотация: Data on the heat capacity of the BiFeO3 multiferroic have been obtained within a broad temperature interval. Correlation has been established between the composition of the Bi2O3-Fe2O3 pseudobinary system and the specific heat capacity of the oxide compounds.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Anghel L., Balasoiu M., Ishchenko L. A., Stolyar S. V., Kurkin T. S., Rogachev A. V., Kuklin A. I., Kovalev Yu.S., Raikher Yu.L., Iskhakov R. S., Duca G.
Заглавие : Characterization of bio-synthesized nanoparticles produced by Klebsiella oxytoca
Коллективы : International Workshop on SANS-YuMO User Meeting at the Start-up of Scientific Experiments on the IBR-2M Reactor: Devoted to the 75th Anniversary of Yu M Ostanevich's Birth
Место публикации : Journal of Physics: Conference Series. - 2012. - Vol. 351, Is. 1. - Ст.012005. - P. - ISSN 1742-6588, DOI 10.1088/1742-6596/351/1/012005
Ключевые слова (''Своб.индексиров.''): absorption peaks--biominerals--chemical compositions--exopolysaccharides--ferrihydrites--fitting procedure--ftir spectroscopy--klebsiella oxytoca--model calculations--morphological analysis--radius of gyration--scattering objects--small angle x-ray scattering--structural and morphological properties--structural investigation--uv-vis spectroscopy--water dispersion--water-dispersed--experiments--nanoparticles--polysaccharides--raman spectroscopy--scattering--ultraviolet visible spectroscopy--synthesis (chemical)
Аннотация: Structural and morphological properties of biogenic ferrihydrite nanoparticles produced by bacteria Klebsiella oxytoca are investigated. The stability of water dispersions of biomineral particles produced by Klebsiella oxytoca was monitored by UV-Vis spectroscopy. Their chemical composition was determined by FT-IR spectroscopy. The vibrational spectra of biogenic ferrihydrite nanoparticles revealed typical absorption peaks of exopolysaccharides. Morphological analysis based on Raman spectroscopy indicated the presence of exopolysaccharides on the surface as well as inside the pores of the ferrihydrite nanoparticles. Structural investigations of ultrasonic assisted samples of different concentration of water dispersed particles were performed using small angle X-ray scattering analysis. Model calculations and fitting procedures revealed scattering objects of an elongated shape with 6.73В±0.16 nm radius of gyration. В© Published under licence by IOP Publishing Ltd.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovnev N. N., Vasiliev A. D., Kirik S. D.
Заглавие : Enrofloxacinium citrate monohydrate: Preparation, crystal structure, thermal stability and IR-characterization
Место публикации : J. Mol. Struct.: Elsevier Science BV, 2012. - Vol. 1021. - P.112-117. - ISSN 0022-2860, DOI 10.1016/j.molstruc.2012.04.059
Примечания : Cited References: 22. - The authors are grateful to the Ministry of Education and Science (Government Contracts # 02.740.11.0629) for the financial support of the investigation.
Предметные рубрики: COCRYSTAL
ANTIBACTERIAL
BEHAVIOR
STATE
ACID
Ключевые слова (''Своб.индексиров.''): enrofloxacin--citric acid--crystal structure--ir spectra--thermal analysis
Аннотация: Enrofloxacinium citrate monohydrate (I), C19H 23FN3O3+В·C6H7O7- В·H2O, [C19H22FN3O3 - enrofloxacin, EnrH] has been crystallized from the mutual solution of citric acid and enrofloxacin in ambient conditions. The colorless crystals have been investigated using X-ray single crystal and powder techniques, and characterized by differential scanning calorimetry, thermogravimetry and infrared spectroscopy. The obtained compound can be considered as a salt with enrofloxacinium in the role of a cation and citrate as an anion. The ions ratio equals to 1:1. The compound crystallizes in the triclinic lattice with a = 9.0489(8) A, b = 9.6531(8) A, c = 14.913(1) A, ? = 98.813(1)В°, ? = 92.029(1)В°, ? = 91.013(1)В°, Z = 2, V = 1286.1(2) A3, S.G. P1?. The crystal structure determination reveals the importance of inter- and intramolecular interactions in the crystal formation. The EnrH2+andH3Cit- molecular ions are packed in alternating layers with water molecules inserted into the citrate layers. A citrate ion in the layer is linked via H-bondings with two adjacent ones and three water molecules. Enrofloxacinium cations are packaged by means of a benched mode and every cation is linked by three intermolecular thymus type H-bondings with nitrogens of adjacent cations and by two links with the oxygen of the citrate ions. The infrared spectra gave the evidence of H-bonding formation in the obtained salt. The ?-stacking interactions are observed between the aromatic cycles of the adjacent cations which are located in an antiparallel style in a layer. В© 2012 Elsevier B.V. All rights reserved.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Kosyrev N. N., Varnakov S. N., Tarasov I. A., Lyashenko S. A., Ovchinnikov S. G.
Заглавие : Characterization of manganese and iron silicides by in situ spectral generalized magneto-optical ellipsometry
Коллективы : Workshop Ellipsometry (7; 2012 ; март ; 5-7; Leipzig, Germany)
Место публикации : 7th Workshop on Ellipsometry: abstract book. - 2012. - P. - 82
Аннотация: Dilute magnetic semiconductors (DMS) combine the electronic transport properties of semiconductors and memory characteristics of magnetic materials. The complementary properties of semiconductor and ferromagnetic material can manipulate both degrees of freedoms of electrons0 spins and charges for spintronic devices. In recent years, group IV(Ge,Si)-based DMSs attract considerable experimental effort due to the compatibility with mainstream silicon technology. In ourworkwe present the investigation of structural,magnetic and optical properties ofmanganese and iron silicides thin films on Si (100) substrate by in situ spectral generalizedmagneto-optical ellipsometry. Themeasurementswere performed by spectral and laser ellipsometers (“Spectroscan“ and “LEF-71“ respectively by Institute Semiconductors Physics SB RAS), optimized tomeasure not only traditional ellipsometric parameters, but also magneto-optical response of the sample. The magnetoellipsometers were integrated into the ultrahigh vacuum chambers of molecular beam epitaxy setup, which allowed to control the optical and magnetic properties of thin films directly in the growth process. As a result of the magneto-optical response analysis, it was found that iron and manganese silicides in magnetic phase were formed on the Si surface and by analysis of the ellipsometric parameters dependence on evaporation time the silicide nanoclusters were identified and their structural properties were found. The work was supported by project 4.1 of the OFN RAS, project 27.10 of the Presidium RAS, integration project22 of SB RAS and FEB RAS, and also the FCP NK-744P/6 .
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Tarasov I. A., Varnakov S. N., Yakovlev I. A., Zharkov S. M., Kosyrev N. N., Ovchinnikov S. G.
Заглавие : Time-resolved ellipsometric characterization of (Fe/Si)n multilayer film synthesis
Коллективы : Donostia International Conference on Nanoscaled Magnetism and Applications (9 -13 Sept. 2013; San Sebastian, Spain)
Место публикации : Donostia Int. Conf. on Nanoscaled Magnetism and Applications: Abstracts book. - 2013. - Ст.P1-27. - P.260
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovnev N. N., Molokeev M. S., Tarasova L. S., Atuchin V. V., Vladimirova N. I.
Заглавие : The 5-(isopropylidene)-2-thiobarbituric acid: Preparation, crystal structure, thermal stability and IR-characterization
Место публикации : J. Mol. Struct.: Elsevier Science, 2014. - Vol. 1068. - P.216-221. - ISSN 0022-2860, DOI 10.1016/j.molstruc.2014.04.024. - ISSN 1872-8014
Примечания : Cited References: 30. - V.V.A. is grateful to the Ministry of Education and Science of Russian Federation for the financial support of the investigation.
Предметные рубрики: 2-THIOBARBITURIC ACID
COMPLEXES
DERIVATIVES
Ключевые слова (''Своб.индексиров.''): 5-(isopropylidene)-2-thiobarbituric acid--synthesis--thiobarbituric acid--x-ray diffraction--infrared spectroscopy--thermography
Аннотация: 5-(Isopropylidene)-2-thiobarbituric acid (1), C7H8N2O2S, has been crystallized by reacting 2-thiobarbituric acid with excessing acetone for 5–6 days under ambient conditions. The pale yellow crystals have been investigated using X-ray single crystal and powder techniques and characterized by differential scanning calorimetry, thermogravimetry and infrared spectroscopy. The compound crystallizes in the monoclinic system with a = 8.8268(19) Å, b = 12.044(3) Å, c = 8.0998(19) Å, β = 105.388(6)°, Z = 4, V = 830.2(3) Å3, space group P21/c. The geometric parameters of the heterocycle of the molecule 1 are similar to those found previously for the molecule of thionedicarbonyl tautomer in polymorphic modifications of 2-thiobarbituric acid. Infrared spectroscopy also evidences the thionedicarbonyl structure of the 1 heterocyclic ring. Intermolecular NH⋯O hydrogen bonds join the molecules in the chains along b axis. The 1 compound is thermally stable up to 230.0 °С and melts with decomposition at 261.4 °C. The results of mass spectrometric analysis are consistent with the structural parameters found by X-ray diffraction methods.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Myagkov V. G., Tambasov I. A., Bayukov O. A., Zhigalov V. S., Bykova L. E., Mikhlin Yu. L., Volochaev M. N., Bondarenko G. N.
Заглавие : Solid state synthesis and characterization of ferromagnetic nanocomposite Fe-In2O3 thin films
Место публикации : J. Alloys Compd.: Elsevier Science, 2014. - Vol. 612. - P.189-194. - ISSN 0925-8388, DOI 10.1016/j.jallcom.2014.05.176. - ISSN 1873-4669
Примечания : Cited References: 56
Предметные рубрики: HIGH-TEMPERATURE FERROMAGNETISM
PHASE-FORMATION
In2O
OXIDE
NANOPARTICLES
CO
SEMICONDUCTORS
NANOCRYSTALS
COMBUSTION
SYSTEMS
Ключевые слова (''Своб.индексиров.''): thermite reactions--reactive films--ferromagnetic nanocomposite films--transparent conducting oxides
Аннотация: We have successfully synthesized ferromagnetic Fe-In2O 3 nanocomposite thin films for the first time using the thermite reaction Fe2O3 + In = In2O3 + Fe. The initial In/Fe2O3 bilayers were obtained by the deposition of In layers on α-Fe2O3 films. The reaction occurs in a self-propagating mode in a homogeneous thermal film plane field at heating rates above 20 K/s and at temperatures above initiation temperature T[[d]]in[[/d]] ~ 180 °C. At heating rates lower than 20 K/s the mixing of the In and Fe2O3 layers occurs across the whole In/Fe2O3 interface and the synthesis of the ferromagnetic α-Fe phase starts above the initiation temperature T[[d]]in[[/d]] = 180 °C. X-ray diffraction, X-ray photoelectron spectroscopy, Mossbauer spectroscopy, transmission electron microscopy and magnetic measurements were used for phase identification and microstructure observation of the synthesized Fe-In2O3 samples. The reaction products contain (1 1 0) textured α-Fe nanocrystals with a diameter around 100 nm and surrounded by an In2O3 matrix. These results enable new efficient low-temperature methods for synthesizing ferromagnetic nanocomposite films containing ferromagnetic nanoclusters embedded in transparent conducting oxides. © 2014 Elsevier B.V. All rights reserved.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Voronkov M. G., Grebneva E. A., Albanov A. I., Zel'bst E. A., Trofimova O. M., Vasil'ev A. D., Chernov N. F., Timofeeva E. N.
Заглавие : Neutral pentacoordinate silicon complexes with SiO2FC skeleton:. Synthesis, structural characterization and stereodynamical behavior
Коллективы : Found of President of Russian Federation [3649.2014.3]; Russian Foundation for Basic Research [14-03-31381 \14]
Место публикации : J. Organomet. Chem.: Elsevier Science, 2014. - Vol. 768. - P.10-14. - ISSN 0022-328X, DOI 10.1016/j.jorganchem.2014.05.025. - ISSN 1872-8561
Примечания : Cited References: 31. - We thank the Found of President of Russian Federation (Science Schools' Grant - 3649.2014.3) and Russian Foundation for Basic Research (No. 14-03-31381 \14) for financial support. We thank Prof. Bagrat Shainyan (Irkutsk Institute of Chemistry) for calculation SUP19/SUPF NMR spectra and helpful discussion and Dr. Svetlana Kirpichenko (Irkutsk Institute of Chemistry) for all the help rendered.
Предметные рубрики: 1,3-DIOXA-6-AZA-2-SILACYCLOOCTANES
DIETHANOLAMINES
DERIVATIVES
SILATRANES
REACTIVITY
NITROGEN
ELEMENTS
Ключевые слова (''Своб.индексиров.''): pentacoordinate silicon--1-fluoro-1-aryl-5-methylquasisilatranes--synthesis--x-ray diffraction
Аннотация: A series of new pentacoordinate intramolecular organosilicon complexes F(Ar)Si(OCH2CH2)2NMe (Ar = 4-MeC6H4 (1), 4-MeOC6H4 (2), 4-ClC6H4 (3), 2-BrC6H4 (4), 3-NO2C6H4 (5)) has been synthesized by transsilylation of aryltrifluorosilanes ArSiF3 by N-methyl-bis(2-trimethylsiloxyethyl)amine. Compounds 1–5 have been fully characterized by 1H, 13C, 19F, 29Si NMR spectroscopy and X-ray diffraction analysis (for compound 3). Variable-temperature 19F NMR studies of 5 indicate stereodynamic process of the ligand exchange with activation barrier Δ G c ≠ of 13.1 kcal mol−1.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Lykhin A. O., Novikova G. V., Kuzubov A. A., Staloverova N. A., Sarmatova N. I., Varganov S. A., Krasnov P. O.
Заглавие : A complex of ceftriaxone with Pb(II): synthesis, characterization, and antibacterial activity study
Коллективы : RFBR [14-03-31, 170 MOJI_a]
Место публикации : J. Coord. Chem.: Taylor & Francis, 2014. - Vol. 67, Is. 16. - З2783-2794. - ISSN 0095-8972, DOI 10.1080/00958972.2014.938065. - ISSN 1029-0389
Примечания : Cited References: 48. - The reported study was supported by RFBR, research project No. 14-03-31, 170 MOJI_a and Krasnoyarsk regional fund for supporting scientific and technological activities. We thank the Center for Equipment Joint Use of the Siberian Federal University. We are grateful to the HPC Research Departments of Siberian Federal University and Moscow University Supercomputing Center (SKIF MSU "Chebyshev") for the access to the high-performance computer clusters.
Предметные рубрики: BETA-LACTAM ANTIBIOTICS
TERNARY COMPLEX
METAL-COMPLEXES
BASIS-SETS
3 DECADES
RESISTANCE
COPPER(II)
CEPHALOSPORINS
EVOLUTION
1ST-ROW
Ключевые слова (''Своб.индексиров.''): ceftriaxone lead(ii) complex--dft--ir spectroscopy--tga--antibacterial screening
Аннотация: A Pb(II) complex with ceftriaxone (H2Ceftria) antibiotic was synthesized by reaction of ceftriaxone disodium salt (hemi)heptahydrate with lead nitrate in water–ethanol medium. The complex was characterized on the basis of complexometric titration, spectrophotometric and thermogravimetric analyses, capillary electrophoresis, IR, Raman and UV–vis spectroscopies, and density functional theory calculations. Pb(II) is five-coordinate with distorted square pyramidal geometry. The coordination of Ceftria2− to Pb(II) occurs through N and O of the triazine, lactam carbonyl, carboxylate, and amine groups. The antibacterial activity study showed that Klebsiella pneumoniae is resistant to [Pb(Ceftria)]·3H2O. The antibacterial activity of [Pb(Ceftria)]·3H2O against Staphylococcus aureus is reduced compared with ceftriaxone. In contrast, the antibacterial activity of [Pb(Ceftria)]·3H2O against Escherichia coli is 28% higher than that of ceftriaxone antibiotic.
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13.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Tarasov I. A., Varnakov S. N., Yakovlev I. A., Zharkov S. M., Kosyrev N. N., Ovchinnikov S. G.
Заглавие : Time-resolved ellipsometric characterization of (Fe/Si)n multilayer film synthesis
Коллективы : Leibniz-Institut für Polymerforschung Dresden e. V., Workshop Ellipsometry (8; 2014 ; March 10-12; Dresden, Germany)
Место публикации : 8th Workshop Ellipsometry: Book of abstracts. - 2014. - P.81
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Edelman I. S., Ivanova O. S., Petrakovskaja E. A., Velikanov D. A., Tarasov I. A., Zubavichus Y. V., Trofimova N. N., Zaikovskii V. I.
Заглавие : Formation, characterization and magnetic properties of maghemite γ-Fe2O3 nanoparticles in borate glasses
Коллективы : Russian Foundation for Basic Research - Russia [14-02-01211-a]; President of Russia [NSh-2886.2014.2]; Russian Ministry of Science and Education [RFMEFI61914X0002]
Место публикации : J. Alloys Compd.: Elsevier Science, 2015. - Vol. 624. - P.60-67. - ISSN 0925-8388, DOI 10.1016/j.jallcom.2014.11.059
Примечания : Cited References: 25. - This work was supported partly by the Russian Foundation for Basic Research - Russia, Grant No. 14-02-01211-a and by the President of Russia Grant No. NSh-2886.2014.2. This work was performed using the equipment of Unique Scientific Facility "Kurchatov Synchrotron Radiation Source'' supported by the Russian Ministry of Science and Education (project code RFMEFI61914X0002).
Предметные рубрики: SUPERPARAMAGNETIC RESONANCE
HYSTERESIS LOOPS
EXCHANGE BIAS
IONS
MATRIX
Ключевые слова (''Своб.индексиров.''): nanostructures--crystal structure and symmetry--magnetic measurements
Аннотация: A new type of nanocomposite materials based on maghemite, γ-Fe2O3, nanoparticles dispersed in borate glasses co-doped with low contents of iron together with the larger radius element combinations: Y and Bi, or Sm and Pb, or Y and Pb is studied. Nanoparticles arise as a result of heat treatment of the glasses which gives them properties characteristic of magnetically ordered substances. Transmission electron microscopy and XRD show that only one magnetic phase, namely γ-Fe2O3 nanoparticles, occurs in glasses subjected to the thermal treatment at 540 °C during 24 h independently on the doping element nature. At the same time doping element and their concentrations ratio in every combination affect the particles average size and glass magnetic properties, such as magnetization temperature dependences, Faraday rotation value and electron magnetic resonance spectrum characteristics.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovnev N. N., Molokeev M. S., Vereshchagin, Sergey N., Sterkhova I. V., Atuchin V. V.
Заглавие : The cis-trans isomer transformation, spectroscopic and thermal properties of Li, Na, K 1,3-diethyl-2-thiobarbiturate complexes
Коллективы : Ministry of Education and Science of the Russian Federation
Место публикации : Polyhedron: PERGAMON-ELSEVIER SCIENCE LTD, 2015. - Vol. 85. - P.493-498. - ISSN 0277-5387, DOI 10.1016/j.poly.2014.09.011
Примечания : Cited References:42. - The study has been carried out within the public task of the Ministry ofEducation and Science of the Russian Federation for research engineeringat the Siberian Federal University in 2014. V.V.A. is partly supportedby the Ministry of Education and Science of the Russian Federation.
Предметные рубрики: CRYSTAL-STRUCTURE
2-THIOBARBITURIC ACID
STRUCTURAL-CHARACTERIZATION
HYDROGEN-BOND
DIFFRACTION
THIOBARBITURATE
CHEMISTRY
NETWORKS
SPECTRA
SERIES
Ключевые слова (''Своб.индексиров.''): 1,3-diethyl-2-thiobarbituric acid--alkali ions--x-ray diffraction--infrared spectroscopy--thermal analysis
Аннотация: Three new complexes of 1,3-diethyl-2-thiobarbituric acid (C8H11N2O2S, HDETBA) with Li+, Na+, K+ alkali ions were synthesized. The complexes have been prepared by neutralization of 1,3-diethyl-2-thiobarbituric acid with the corresponding metal hydroxide in aqueous solution. The colorless crystals have been investigated using X-ray single crystal and powder techniques and characterized by differential scanning calorimetry, thermogravimetry and infrared spectroscopy. The compounds of MDETBA with M = Li and M = Na crystallize in the monoclinic lattice with a = 10.678(1) Å, b = 7.2687(9) Å, c = 13.202(2) Å, β = 108.841(2)°, Z = 4, V = 969.8(2) Å3, S.G. P21/n and a = 10.534(2) Å, b = 7.604(1) Å, c = 14.186(1) Å, β = 108.964(4)°, Z = 4, V = 1074.6(3) Å3, S.G. P21/n, respectively. Сompound KDETBA crystallizes in the orthorhombic lattice with a = 4.2541(6) Å, b = 14.739(2) Å, c = 16.635(3) Å, Z = 4, V = 1043.1(3) Å3, S.G. P212121. In Li(I) and Na(I) complexes, the DETBA− ion is in cis-configuration and, in the K(I) complex, this ion is in trans-configuration. The reason for the transformation from cis- to trans-configuration has been rationalized.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Myagkov V. G., Bykova L. E., Bayukov O. A., Zhigalov V. S., Tambasov I. A., Zharkov S. M., Matsynin A. A., Bondarenko G. N.
Заглавие : Solid state synthesis and characterization of Fe-ZrO2 ferromagnetic nanocomposite thin films
Место публикации : J. Alloys Compd.: Elsevier Science, 2015. - Vol. 636. - P.223-228. - ISSN 0925, DOI 10.1016/j.jallcom.2015.02.012. - ISSN 18734669(eISSN)
Примечания : Cited References:48
Предметные рубрики: HIGH-TEMPERATURE SYNTHESIS
ENERGETIC MATERIALS
MAGNETIC-PROPERTIES
Ключевые слова (''Своб.индексиров.''): thermite reactions--reactive films--ferromagnetic nanocomposite films--zro2
Аннотация: Fe-ZrO2 ferromagnetic nanocomposite thin films are successfully synthesized using a thermite reaction between the Zr and Fe2O3 layers. The initial Zr/Fe2O3 bilayers were obtained by the deposition of Zr layers on alpha-Fe2O3 films at room temperature. The mixing at the Zr/Fe2O3 interface and synthesis of alpha-Fe and the amorphous ZrO2 phases start at a temperature above the initiation temperature T-in similar to 250 degrees C. Together with the formation of alpha-Fe, partial transformation from Fe2O3 to Fe3O4 occurs after annealing at 300 degrees C. The secondary reaction between Fe3O4 and Zr starts soon after the Fe2O3 is converted to the Fe3O4 phase. The crystallization of amorphous ZrO2 and the formation of the ZrO2 cubic/tetragonal phase occurs above 400 degrees C. After annealing at 500 degrees C the reaction products contain (110) textured alpha-Fe nanocrystals with a diameter of about 34 nm embedded in an insulating c-ZrO2 (or t-ZrO2) matrix. The synthesized Fe-ZrO2 nanocomposite films possess soft magnetic behavior, high magnetization and good chemical stability. (C) 2015 Elsevier B.V. All rights reserved.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Волочаев, Михаил Николаевич, Жигалов, Виктор Степанович, Мягков, Виктор Григорьевич
Заглавие : Исследование магнитных композитных пленок Co-ZrO2 и Co-Al2O3, полученных методом твердофазного синтеза
Коллективы : "Решетневские чтения", международная научно-практическая конференция
Место публикации : Решетневские чтения: материалы XIX Междунар. науч. конф. : в 2-х ч. - Красноярск, 2015. - Ч. 1. - С. 504-506. - ISSN 1990-7702
Примечания : Библиогр.: 4. - Работа выполнена в рамках договора № 0011872 по программе «У.М.Н.И.К. 15-5». Электронно-микроскопические исследования пленок выполнены на оборудовании ЦКП КНЦ СО РАН
Ключевые слова (''Своб.индексиров.''): магнитные гранулированные пленки--твердофазный синтез--термитные реакции--magnetic granular thin films--solid state synthesis--thermite reactions
Аннотация: Показана возможность синтеза магнитных гранулированных пленок, состоящих из частиц Co, размером порядка 20–100 нм, вложенных в диэлектрическую матрицу. В основе синтеза лежат низкотемпературные термитные реакции в двухслойных системах Co3O4/Zr и Co3O4/Al.We have synthesized Co-based magnetic granular thin films (Co-particle size of 20-100 nm, surrounded by a dielectric matrix) by low-temperature thermite reactions in Co3O4/Zr and Co3O4/Al bilayer systems.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Myagkov V. G., Zhigalov V. S., Bykova L. E., Zharkov S. M., Matsynin A. A., Volochaev M. N., Tambasov I. A., Bondarenko G. N.
Заглавие : Thermite synthesis and characterization of Co-ZrO2 ferromagnetic nanocomposite thin films
Место публикации : J. Alloys Compd.: Elsevier, 2016. - Vol. 665. - P.197-203. - ISSN 09258388 (ISSN), DOI 10.1016/j.jallcom.2015.12.257
Примечания : Cited References: 56. - This study was partially supported by the Russian Foundation for Basic Research (grants ##15-02-00948, 14-03-00515), by the Council for Grants of the President of the Russian Federation (SP-317.2015.1), and by the program of the Foundation for Assistance to Small Innovative Enterprises in Science and Technology (“UMNIK” program). The TEM studies were carried out using the facilities of Electron Microscopy Laboratory of Siberian Federal University and the Performance Service at Krasnoyarsk Scientific Center.
Предметные рубрики: SOLID-STATE SYNTHESIS
PHASE-FORMATION
ZrO2
NANOPARTICLES
TRANSPORT
OXIDE
MICROSTRUCTURE
NANOTHERMITE
FABRICATION
PARTICLES
Ключевые слова (''Своб.индексиров.''): thermite reactions--reactive films--ferromagnetic nanocomposite films--zro2
Аннотация: Co-ZrO2 ferromagnetic nanocomposite thin films were successfully synthesized using a new thermite reaction between Zr and Co3O4 in layer geometry. The initial Zr/Co3O4 bilayers were obtained by the deposition of Zr layers onto Co3O4 films at room temperature. The process of mixing at the Zr/Co3O4 interface and synthesis of fine-crystalline Co and amorphous ZrO2 phases started at a temperature above the initiation temperature Tin ∼250 °C which did not depend on the bilayer thickness. For the bilayer thickness more than 300 nm high-temperature fcc-Co and cubic c-ZrO2 (or tetragonal t-ZrO2) phases were formed. For the bilayer thickness less than ∼50 nm stable low-temperature hexagonal hcp-Co and monoclinic m-ZrO2 phases were also present in the reaction product. A partial transformation from Co3O4 to CoO occurred after annealing at 300 °C. The secondary reaction between CoO and Zr started soon after Co3O4 had been converted to the CoO phase. After annealing at 500 °C more than 80% of Co was reduced and the final product contained Co nanoparticles above and below the superparamagnetic critical size embedded into a dielectric ZrO2 matrix. The synthesized Co-ZrO2 nanocomposite films possessed soft magnetic behavior, high magnetization and good chemical stability.
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19.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Rautskii M. V., Lukyanenko A. V., Tarasov A. S., Yakovlev I. A., Tarasov I. A., Volochaev M. N., Volkov N. V.
Заглавие : Ferromagnetic resonance characterization of the single-crystal epitaxial Fe3Si film on the Si(111) substrate
Коллективы : Asian School-Conference on Physics and Technology of Nanostructured Materials, Азиатская школа-конференция по физике и технологии наноструктурированных материалов
Место публикации : Third Asian school-conf. on physics and technol. of nanostructured mater. (ASCO-NANOMAT 2015): proceedings. - Vladivostok: Dalnauka, 2015. - Ст.III.24.04p. - ISBN 978-5-8044-1556-4
Примечания : Библиогр.: 3. - The work was supported in part by the Grant of the President of the Pussian Federation and the Pussian Foundation for Basic Research, projects nos. 14-02-31156 and 14-02-00234
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mel'nikova S. V., Molokeev M. S., Laptash N. M., Misyul S. V.
Заглавие : A non-typical sequence of phase transitions in (NH4)3GeF7: optical and structural characterization
Коллективы : RFBR [15-02-02009 a]
Место публикации : Dalton Trans.: Royal Society of Chemistry, 2016. - Vol. 45, Is. 12. - P.5321-5327. - ISSN 1477-9226, DOI 10.1039/c5dt04907e. - ISSN 1477-9234(eISSN)
Примечания : Cited References:25. - The reported study was partially supported by RFBR, research project no. 15-02-02009 a
Предметные рубрики: Crystal-structure
Powder diffraction
NH4F
Fluorination
Аннотация: Single crystals of germanium double salt (NH4)3GeF7 = (NH4)2GeF6·NH4F = (NH4)3[GeF6]F were grown and studied by the methods of polarization optics and X-ray diffraction. The birefringence Δn = (no − ne), the rotation angle of the optical indicatrix ϕ(T) and unit cell parameters were measured in the temperature range 100–400 K. Three structural phase transitions were found at the temperatures: T1↓ = 279.2 K (T1↑ = 279.4 K), T2↑ = 270 K (T2↓ = 268.9 K), T3↓ = 218 K (T3↑ = 227 K). An unusual sequence of symmetry transformations with temperature change was established: P4/mbm (Z = 2) (G1) ↔ Pbam (Z = 4) (G2) ↔ P21/c (Z = 4) (G3) ↔ Pa (Z = 8) (G4). The crystal structures of different phases were determined. The experimental data were additionally interpreted by a group-theoretical analysis of the complete condensate of order parameters taking into account the critical and noncritical atomic displacements. Strengthening of the N–H⋯F hydrogen bonds can be a driving force of the observed phase transitions.
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