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Общее количество найденных документов : 197
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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Iskhakov R. S., Kuzovnikova L. A., Komogortsev S. V., Denisova E. A., Balaev A. D., Mal'tsev V. K., Bondarenko G. N.
Заглавие : Magnetostructural Investigation of Ball-Milled Cobalt-Copper Alloy
Место публикации : Phys. Met. Metallogr. - Vol. 102, Suppl. 1, Chapter 11. - р.S64-S66. - DOI 10.1134/S0031918X0614016X
Примечания : Библиогр.: 6. - Russian Foundation for Basic Research (project no. 04-02-16230)
Аннотация: In this work we investigate a metastable inhomogeneous Co–Cu alloy produced by mechanical alloying. We use both conventional structural method (X-ray diffraction) and magnetic measurements of M(T) and M(H) dependences to obtain additional information about the process of mechanical alloying.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhang, Xingyu, Liu, Youquan, Molokeev M. S., Xu, Bohui, Jiang, Xingxing, Lin, Zheshuai
Заглавие : Realizing persistent zero area compressibility over a wide pressure range in Cu2GeO4 by microscopic orthogonal-braiding strategy
Колич.характеристики :6 с
Место публикации : Angew. Chem. - 2024. - Vol. 136, Is. 7. - Ст.e202318401. - ISSN 00448249 (ISSN), DOI 10.1002/ange.202318401. - ISSN 15213757 (eISSN)
Примечания : Cited References: 24. - The authors would like to acknowledge Zhuohong Yin for useful discussions and experimental time for the 4W2 beamline in the Beijing synchrotron radiation facility (BSRF). This work was supported by the National Scientific Foundations of China (Grants T2222017, 12274425, 22133004, 11974360 and 51890864) and the CAS Project for Young Scientists in Basic Research (YSBR-024). M.S. Molokeev would like to acknowledge support fromthe Ministry of Science and High Education of the Russian Federation (Project No. FSRZ-2023-0006)
Аннотация: Zero area compressibility (ZAC) is an extremely rare mechanical response that exhibits an invariant two-dimensional size under hydrostatic pressure. All known ZAC materials are constructed from units in two dimensions as a whole. Here, we propose another strategy to obtain the ZAC by microscopically orthogonal-braiding one-dimensional zero compressibility strips. Accordingly, ZAC is identified in a copper-based compound with a planar [CuO4] unit, Cu2GeO4, that possesses an area compressibility as low as 1.58(26) TPa-1 over a wide pressure range from ≈0 GPa to 21.22 GPa. Based on our structural analysis, the subtle counterbalance between the shrinkage of [CuO4] and the expansion effect from the increase in the [CuO4]-[CuO4] dihedral angle attributes to the ZAC response. High-pressure Raman spectroscopy, in combination with first-principles calculations, shows that the electron transfer from in-plane bonding dx2-y2 to out-of-plane nonbonding dz2 orbitals within copper atoms causes the counterintuitive extension of the [CuO4]-[CuO4] dihedral angle under pressure. Our study provides an understanding on the pressure-induced structural evolution of copper-based oxides at an electronic level and facilitates a new avenue for the exploration of high-dimensional anomalous mechanical materials.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhang, Xingyu, Liu, Youquan, Molokeev M. S., Xu, Bohui, Jiang, Xingxing, Lin, Zheshuai
Заглавие : Realizing persistent zero area compressibility over a wide pressure range in Cu2GeO4 by microscopic orthogonal-braiding strategy
Колич.характеристики :6 с
Место публикации : Angew. Chem. Int. Ed. - 2024. - Vol. 63, Is. 7. - Ст.e202318401. - ISSN 14337851 (ISSN), DOI 10.1002/anie.202318401. - ISSN 15213773 (eISSN)
Примечания : Cited References: 24. - The authors would like to acknowledge Zhuohong Yin for useful discussions and experimental time for the 4W2 beamline in the Beijing synchrotron radiation facility (BSRF). This work was supported by the National Scientific Foundations of China (Grants T2222017, 12274425, 22133004, 11974360 and 51890864) and the CAS Project for Young Scientists in Basic Research (YSBR-024). M.S. Molokeev would like to acknowledge support fromthe Ministry of Science and High Education of the Russian Federation (Project No. FSRZ-2023-0006)
Аннотация: Zero area compressibility (ZAC) is an extremely rare mechanical response that exhibits an invariant two-dimensional size under hydrostatic pressure. All known ZAC materials are constructed from units in two dimensions as a whole. Here, we propose another strategy to obtain the ZAC by microscopically orthogonal-braiding one-dimensional zero compressibility strips. Accordingly, ZAC is identified in a copper-based compound with a planar [CuO4] unit, Cu2GeO4, that possesses an area compressibility as low as 1.58(26) TPa-1 over a wide pressure range from ~0 GPa to 21.22 GPa. Based on our structural analysis, the subtle counterbalance between the shrinkage of [CuO4] and the expansion effect from the increase in the [CuO4]-[CuO4] dihedral angle attributes to the ZAC response. High-pressure Raman spectroscopy, in combination with first-principles calculations, shows that the electron transfer from in-plane bonding dx2-y2 to out-of-plane nonbonding dz2 orbitals within copper atoms causes the counterintuitive extension of the [CuO4]-[CuO4] dihedral angle under pressure. Our study provides an understanding on the pressure-induced structural evolution of copper-based oxides at an electronic level and facilitates a new avenue for the exploration of high-dimensional anomalous mechanical materials.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Volkova I. R., Tyryshkina L. E., Volochaev M. N., Zaloga A. N., Shabanova K. A., Ovchinnikov A. V., Lyamkin A. I.
Заглавие : The effect of aluminum-oxide powders on the structure and properties of copper electrodeposited composite coatings
Место публикации : Prot. Met. Phys. Chem. Surf. - 2023. - Vol. 59, Is. 1. - P.71-75. - ISSN 20702051 (ISSN), DOI 10.1134/S2070205122700022. - ISSN 2070206X (eISSN)
Примечания : Cited References: 9
Аннотация: Copper electrodeposited composite coatings containing two types of aluminum-oxide powders with different dispersities (alumina Al2O3-1 and electroexplosive aluminum-oxide nanopowder Al2O3-2) are obtained during the work. The studies show that introducing the powders leads to a change in the microstructure of the composites and a change in the grain growth principles during the formation of the coatings. Refinement and ordering of the grain structure of the coatings occurs and twinning defects and texture are formed. The change in the formation of the microstructure of the composites leads to a change in some operational characteristics: an increase in the microhardness (by 10% in the composites with the addition of alumina and by more than 30% in the coatings with electroexplosive aluminum oxide) and ultimate tensile strength (by 20% in the composites with Al2O3-1 and almost 1.5-fold in the samples with Al2O3-2).
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Afonnikova S. D., Bauman, Yury I., Stoyanovskii, Vladimir O., Volochaev M. N., Mishakov, Ilya V., Vedyagin, Aleksey A.
Заглавие : Effect of Cu on performance of self-dispersing Ni-catalyst in production of carbon nanofibers from ethylene
Колич.характеристики :17 с
Место публикации : C – J. Carbon Res. - 2023. - Vol. 9, Is. 3: Advanced Carbon Nanomaterials and Hybrids. - Ст.77. - ISSN 23115629 (eISSN), DOI 10.3390/c9030077
Примечания : Cited References: 72. - This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov Institute of Catalysis (project AAAA-A21-121011390054-1). The physicochemical characterization of samples was supported by the Russian Science Foundation (project No. 22-13-00406, https://rscf.ru/en/project/22-13-00406/BIC SB RAS (accessed on 30 March 2023))Analysis of the physicochemical properties of the samples was performed using the equipment of the ‘National Center for Catalyst Research’ (Novosibirsk, BIC SB RAS) and Krasnoyarsk regional Center of the Collective Use (KSS SB RAS). The authors are grateful to A.N. Serkova for the performed SEM studies, B.A. Kolesov for the Raman spectra data, to A.B. Ayupov for analyzing samples by low-temperature adsorption/desorption of nitrogen, to Y.V. Shubin for the XRD analysis and to E.I. Belyaeva for the particle distribution analysis
Аннотация: The development of effective catalysts for the pyrolysis of light hydrocarbons with the production of carbon nanomaterials represents a relevant direction. In the present work, the influence of copper addition on performance of a self-dispersed Ni-catalyst and structural features of the obtained carbon nanofibers (CNFs) was studied. The precursors of Ni and Ni-Cu catalysts were prepared by activation of metal powders in a planetary mill. During contact with the C2H4/H2 reaction mixture, a rapid disintegration of the catalysts with the formation of active particles catalyzing the growth of CNFs has occurred. The kinetics of CNF accumulation during ethylene decomposition on Ni- and Ni-Cu catalysts was studied. The effect of temperature on catalytic performance was explored and it was shown that introduction of copper promotes 1.5–2-fold increase in CNFs yield in the range of 525–600 °C; the maximum CNFs yield (100 g/gcat and above, for 30-min reaction) is reached on Ni-Cu-catalyst at 575–600 °C. A comparative analysis of the morphology and structure of CNF was carried out using electron microscopy methods. The growth mechanism of carbon filaments in the shape of “railway crossties” on large nickel crystals (d 250 nm) was proposed. It was found that the addition of copper leads to a decrease in the bulk density of the carbon product from 40–60 to 25–30 g/L (at T = 550–600 °C). According to the low-temperature nitrogen adsorption data, specific surface area (SSA) of CNF samples (at T ˂ 600 °C) lies in the range of 110–140 m2/g, regardless of the catalyst composition; at T = 600 °C the introduction of copper contributed to an increase in the specific surface of CNF by 100 m2/g.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Molchanova A. D., Moshkina E. M., Molokeev M. S., Tropina E. V., Bovina A. F., Boldyrev K. N.
Заглавие : Synthesis and optical properties of nickel-doped copper metaborate crystals
Колич.характеристики :6 с
Место публикации : Opt. Spectrosc. - 2023. - Vol. 131, Is. 8. - P.717-722. - ISSN 0030400X (ISSN), DOI 10.1134/S0030400X23060127. - ISSN 15626911 (eISSN)
Примечания : Cited References: 18. - The study was performed with the support of Russian Science Foundation, RSF grant no. 19-12-00413
Аннотация: This work presents information on the growth and spectroscopic study of single crystals of copper metaborate doped with nickel Cu1–xNixB2O4 (x = 0.05, 0.1). In the absorption spectra of both crystals, satellites related to Cu centers distorted by impurity Ni atoms were observed near the lines of zero phonon transitions. Polarization studies in the isotropic ab-plane of the tetragonal crystal Cu1–xNixB2O4 show the presence of linear magnetic dichroism in the magnetically ordered state, which was previously observed both in manganese-doped and undoped copper metaborates CuB2O4. The temperature of magnetic phase transitions into the collinear antiferromagnetic and into helicoidal structures, TN = 19.1 K and T * = 8.6 K, respectively, were determined from the temperature dependence of the dichroic signal.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Saikova, Svetlana, Pavlikov, Aleksandr, Karpov, Denis, Samoilo, Aleksandr, Kirik, Sergey, Volochaev M. N., Trofimova, Tatyana, Velikanov D. A., Kuklin, Artem
Заглавие : Copper ferrite nanoparticles synthesized using anion-exchange Resin: Influence of synthesis parameters on the cubic phase stability
Место публикации : Materials. - 2023. - Vol. 16, Is. 6. - Ст.2318. - ISSN 19961944 (eISSN), DOI 10.3390/ma16062318
Примечания : Cited References: 67. - The Russian team acknowledges the support of the Russian Science Foundation (Project 22-73-10047)
Аннотация: Copper ferrite is of great interest to researchers as a material with unique magnetic, optical, catalytic, and structural properties. In particular, the magnetic properties of this material are structurally sensitive and can be tuned by changing the distribution of Cu and Fe cations in octahedral and tetrahedral positions by controlling the synthesis parameters. In this study, we propose a new, simple, and convenient method for the synthesis of copper ferrite nanoparticles using a strongly basic anion-exchange resin in the OH form. The effect and possible mechanism of polysaccharide addition on the elemental composition, yield, and particle size of CuFe2O4 are investigated and discussed. It is shown that anion-exchange resin precipitation leads to a mixture of unstable cubic (c-CuFe2O4) phases at standard temperature and stable tetragonal (t-CuFe2O4) phases. The effect of reaction conditions on the stability of c-CuFe2O4 is studied by temperature-dependent XRD measurements and discussed in terms of cation distribution, cooperative Jahn–Teller distortion, and Cu2+ and oxygen vacancies in the copper ferrite lattice. The observed differences in the values of the saturation magnetization and coercivity of the prepared samples are explained in terms of variations in the particle size and structural properties of copper ferrite.
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8.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Анисимов Р. И., Колмаков А. А., Темерева А. С., Шараева А. Е., Шандаров С. М., Тимофеев, Иван Владимирович, Пятнов, Максим Владимирович
Заглавие : Анализ распределения меди в кристаллах LiNBO3:Cu с поверхностным легированием
Коллективы : Международная конференция по фотонике и информационной оптике, Российская академия наук, Национальный исследовательский ядерный университет "МИФИ"
Место публикации : XI Международная конференция по фотонике и информационной оптике: сборник научных трудов. - Москва, 2022. - С. 451-452. - ISBN 978-5-7262-2842-6
Примечания : Библиогр.:
Предметные рубрики:
Аннотация: Представлены результаты исследований распределения примеси по глубине в структурах, сформированных термической диффузией меди в пластинах X-среза ниобата лития.
РИНЦ,
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ronzhin N. O., Posokhina E. D., Mikhlina E. V., Shestakov N. P., Nemtsev I. V., Bondar V. S., Ryzhkov I. I.
Заглавие : The effect of copper and iron adsorption on the catalytic performance of alumina nanofiber / nanodiamond composite in sensing applications
Место публикации : J. Phys. Chem. Solids. - 2022. - Vol. 167. - Ст.110785. - ISSN 00223697 (ISSN), DOI 10.1016/j.jpcs.2022.110785
Примечания : Cited References: 68. - This work is supported by the Russian Foundation for Basic Research, Project 18–29–19078. The authors would like to express their special thanks to Krasnoyarsk Regional Center of Research Equipment of Federal Research Center «Krasnoyarsk Science Center SB RAS» for providing the equipment to ensure the accomplishment of this project
Аннотация: Phenolic compounds are common environmental pollutants, which are used in many industries and contaminate water environment due to industrial wastewater discharge. Presently, there is an increasing demand for the development and improvement of inexpensive, easy-to-use analytical tools for in-situ detection of phenolic compounds. In this work, we investigate the effect of adsorption of Cu2+ and Fe2+ ions on the catalytic activity of a composite material based on alumina nanofibers (ANF) and detonation nanodiamonds (DND) in the co-oxidation of phenols with 4-aminoantipyrine in the presence of hydrogen peroxide. We have found more than two-fold increase of the catalytic activity for ANF + DND + Cu composite, while the activity of ANF + DND + Fe composite is found to decrease by several times in comparison with the original ANF + DND material. The results of FTIR analysis indicate that the adsorption of iron ions occurs with the formation of hydroxide surface groups and hydrogen bonds, which apparently block their catalytic activity in the Fenton redox cycle. The higher catalytic performance of AND + DND composite functionalized with copper ions makes it possible to detect two times lower concentrations of analytes (phenol and 4-chlorophenol) in comparison with the original composite. It is shown that the AND + DND + Cu composite provides a linear yield of the co-oxidation reaction product in a wide range of analyte concentrations (0.25–100 μM for phenol and 0.5–25 μM for 4-chlorophenol). Model experiments demonstrate the applicability of copper-functionalized composite as a reusable sensor for the determination of phenol in aqueous samples.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Koblischka, Michael R., Koblischka-Veneva, Anjela, Gokhfeld D. M., Naik, S. Pavan Kumar, Nouailhetas, Quentin, Berger, Kevin, Douine, Bruno
Заглавие : Flux pinning docking interfaces in satellites using superconducting foams as trapped field magnets
Коллективы : ANRFrench National Research Agency (ANR); DFGGerman Research Foundation (DFG)European Commission [ANR-17-CE05-0030, DFG-ANR Ko2323-10]
Место публикации : IEEE Trans. Appl. Supercond. - 2022. - Vol. 32, Is. 4. - Ст.4900105. - ISSN 1051-8223, DOI 10.1109/TASC.2022.3147734. - ISSN 1558-2515(eISSN)
Примечания : Cited References: 44. - This work was supported in part by SUPERFOAM international project funded by ANR and DFG under Grants ANR-17-CE05-0030 and DFG-ANR Ko2323-10.
Предметные рубрики: BULK
RECONFIGURATION
MAGNETIZATION
Аннотация: Flux-Pinning Docking Interfaces (FPDI) in satellite systems were developed using bulk superconductors and permanent magnets in previous works. However, such FPDIs have limited magnetic field strength, consist of heavy-weight material, and can only be used with a single purpose, i.e., as chasing or docking satellite. Replacing the magnetic material in the FPDI by a trapped field (TF)-magnet would enable the interface to operate for both purposes, i.e., generating a (stronger) magnetic field and trapping it. We show the requirements for such a system and discuss the possible gains when using a TF-FPDI in satellites. To reduce the system weight, the use of superconducting foams as superconducting material is discussed in detail. Furthermore, the use of superconducting foams, the size of which can be easily upscaled, may also comprise the function of the damping material, so even more weight could be saved for the payload.
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