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Antiferromagnetic resonance and phase diagram of HoFe3(BO3)4 [Text] / A. Pankrats, G. Petrakovskii [et al.] // International Symposium "Spin waves - 2009" : Saint Petersburg, Russia, June 7-12, 2009 : Simposium program. Abstracts. - 2009. - P40

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Доп.точки доступа:
Pankrats, A.; Petrakovskii, G. A.; Tugarinov, V.; Temerov, V.; Российская академия наук; Физико-технический институт им. А.Ф. Иоффе РАН; "Spin Waves", International Symposium(2009 ; JUN ; Saint-Petersburg)
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Aplesnin, S. S.
Influence of the four-spin exchange interaction on the magnetic properties of manganites / S. S. Aplesnin, N. I. Piskunova // J. Phys.: Condens. Matter. - 2005. - Vol. 17, Is. 37. - P. 5881-5888, DOI 10.1088/0953-8984/17/37/023. - Cited References: 18 . - ISSN 0953-8984

РУБ Physics, Condensed Matter
Рубрики:
METAL-INSULATOR-TRANSITION
   PHASE
   SUSCEPTIBILITY
   LA1-XSRXMNO3
   FERROMAGNET
   TRANSPORT
Кл.слова (ненормированные):
Computer simulation -- Ion exchange -- Lanthanum compounds -- Magnetic properties -- Monte Carlo methods -- Phase diagrams -- Phase transitions -- Four-spin exchange interaction -- Magnetic phase diagram -- Manganites -- Metal-dielectric transition -- Manganese compounds
Аннотация: It is shown that non-Heisenberg exchange interaction should be taken into account to reproduce the magnetic phase diagram of La(1-x)A(x)MnO(3) (A = Ca, Sr) using only effective exchange parameters and spins. The formation of the four-spin exchange arises from carrier hopping and coincides with the critical concentration metal-dielectric transition. The two- and four-spin exchange parameters are determined by Monte Carlo simulations.

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Держатели документа:
MF Reshetneva Aircosm Siberian State Univ, Krasnoyarsk 660036, Russia
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
M F Reshetneva Aircosmic Siberian State University, Krasnoyarsk 660036, Russian Federation
L V Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Science, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Piskunova, N. I.; Аплеснин, Сергей Степанович
}
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Avramov, P. V.
Non-diagram transitions in polarized X-ray absorption CuL(3) spectra of HTSC-ceramics / P. V. Avramov, S. G. Ovchinnikov // Fiz. Tverd. Tela. - 1996. - Vol. 38, Is. 11. - P. 3226-3240. - Cited References: 28 . - ISSN 0367-3294

РУБ Physics, Condensed Matter
Рубрики:
HIGH-TC SUPERCONDUCTIVITY
   LA2CUO4
   ALPHA
   SATELLITES
   STATES
   OXIDES
   XANES

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Доп.точки доступа:
Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Аврамов, Павел Вениаминович
}
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B-11-NMR study of low-temperature phase transition in CuB2O4 / Y. . Yasuda [et al.] // J. Phys.: Condens. Matter. - 2007. - Vol. 19: International Conference on Highly Frustrated Magnetism (AUG 15-19, 2006, Osaka, JAPAN), Is. 14. - Ст. 145277, DOI 10.1088/0953-8984/19/14/145277. - Cited References: 10 . - ISSN 0953-8984

РУБ Physics, Condensed Matter
Рубрики:
COPPER METABORATE
Кл.слова (ненормированные):
Copper compounds -- Low temperature effects -- Magnetic field effects -- Nuclear magnetic resonance -- B T phase diagram -- Dzialoshinskii Moriya interaction -- Phase transitions
Аннотация: The material CuB2O4 presents a variety of phases in the B - T phase diagram, caused by the frustration and the Dzialoshinskii - Moriya interaction. In order to investigate the nature of the phase transitions, a B-11- NMR experiment on CuB2O4 has been performed under an applied magnetic field along the a- axis down to 0.4 K. A new incommensurate - incommensurate phase transition has been found at 0.8 K under a field of 0.5 T. Further, another phase transition has been observed at 4.7 K under a field of about 2 T, which is consistent with the transition reported by the neutron diffraction experiment.

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Держатели документа:
Univ Fukui, Dept Appl Phys, Fukui 9108507, Japan
Japan Adv Inst Sci & Technol, Ishikawa 9231292, Japan
RAS, SB, Inst Phys, Krasnoyarsk 660036, Russia
ИФ СО РАН
Department of Applied Physics, University of Fukui, Fukui 910-8507, Japan
Japan Advanced Institute of Science and Technology, Ishikawa 923-1292, Japan
Institute of Physics, SB RAS, 660036 Krasnoyarsk, Russian Federation

Доп.точки доступа:
Yasuda, Y.; Nakamura, H.; Fujii, Y.; Kikuchi, H.; Chiba, M.; Yamamoto, Y.; Hori, H.; Petrakovskii, G. A.; Петраковский, Герман Антонович; Popov, M. A.; Bezmaternykh, L. N.
}
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Behaviour of thermal expansion of (1-x)Pb(Ni1/3Nb2/3)O3-xPbTiO3 solid solutions / K. Bormanis [et al.] // Proc. Est. Acad. Sci. - 2017. - Vol. 66, Is. 4. - P. 363-371, DOI 10.3176/proc.2017.4.09. - Cited References: 25. - The publication costs of this article were covered by the Estonian Academy of Sciences and the University of Tartu. . - ISSN 1736-6046
Кл.слова (ненормированные):
Ferroelectrics -- Relaxors -- Ceramics -- Solid solutions -- Thermal expansion -- Phase diagram
Аннотация: The features of the dependence of the bulk coefficient of thermal expansion of the (1-x)Pb(Ni1/3Nb2/3)O3-xPbTiO3 solid solution studied in the series of x = 0-0.8 in the temperature range from 100 to 750 K are reported. The obtained data and observed anomalies of thermal expansion are compared with dielectric properties, heat capacity, and the phase diagram of concentration. The anomalous and lattice constituents of deformation and of the coefficient of thermal expansion are analysed and the data on deformation are used to estimate the Burns temperature and the mean square polarization of the samples found to decrease with the decrease of the PbTiO3 concentration.

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Держатели документа:
Institute of Solid State Physics, University of LatviaRiga, Latvia
L.V. Kirensky Institute of Physics, Siberian SC RAS, Krasnoyarsk, Russian Federation
Institute of Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Bormanis, K.; Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич; Sternberg, A.; Lace, L.; Ignatans, R.; Kalvane, A.; Antonova, M.
}
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Bulgakov, E. N.
Phase-diagram of the quantum magnet with competing couplings / E. N. Bulgakov // Phys. Status Solidi B. - 1988. - Vol. 148, Is. 2. - P. K139-K141, DOI 10.1002/pssb.2221480242. - Cited References: 7 . - ISSN 0370-1972

РУБ Physics, Condensed Matter

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Доп.точки доступа:
Булгаков, Евгений Николаевич
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Bulgakov, E. N.
Vortex phase diagram of F=1 spinor Bose-Einstein condensates / E. N. Bulgakov, A. F. Sadreev // Phys. Rev. Lett. - 2003. - Vol. 90, Is. 20. - Ст. 200401, DOI 10.1103/PhysRevLett.90.200401. - Cited References: 15 . - ISSN 0031-9007

РУБ Physics, Multidisciplinary
Рубрики:
ATOMS
CREATION
GASES
Аннотация: We have calculated the F=1 ground state of a spinor Bose-Einstein condensate trapped harmonic potential with an applied Ioffe-Pitchard magnetic field. The vortex phase diagram is found in the plane spanned by perpendicular and longitudinal magnetic fields. The ferromagnetic condensate has two vortex phases which differ by winding number in the spinor components. The two vortices for the F-z=-1 antiferromagnetic condensate are separated in space. Moreover, we considered an average local spin \[(S) over right arrow]\ to testify to what extent it is parallel to magnetic field (the nonadiabatic effects). We have shown that the effects are important at vortex cores.

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Держатели документа:
Russian Acad Sci, Inst Phys, Krasnoyarsk 660036, Russia
Linkoping Univ, Dept Phys & Measurement Technol, S-58183 Linkoping, Sweden
ИФ СО РАН

Доп.точки доступа:
Sadreev, A. F.; Садреев, Алмаз Фаттахович; Булгаков, Евгений Николаевич
}
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Calorimetric and 23Na MAS NMR Study of the Phase Diagram of NaNb1-xTaxO3 Solid Solutions [Text] / Aleksandrova I.P.Ivanov Yu.N. [et al.] // Functional mate rials. - 2010. - Vol. 17. - P18-24

Доп.точки доступа:
Aleksandrova, I.P.; Ivanov, Yu.N.; Bondarev, V.S.; Sukhovskiy, A.A.; Voronov, V.N.
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Calorimetric and 23Na MAS NMR study of the phase diagram of NANB1_xTAxO3 solid solutions / I. P. Aleksandrova [et al.] // Functional Materials. - 2010. - Vol. 17, Is. 1. - P. 18-23 . - ISSN 1027-5495
Аннотация: The heat capacity of NaNb1_xTaxO3 solid solutions was measured in the temperature range 100 to 770 K. The step-like change of phase transition temperature is observed in the T-x phase diagram at concentration x = 0.55. The obtained results are in a good agreement with the data of dielectric studies. The 23Na MAS NMR spectra were obtained at Larmor frequency 79.35 MHz using a Bruker AVANCE 300 spectrometer. The quadru-polar coupling constant, (CQ=e2qQ/h) and asymmetry parameter (n) were determined by computer fitting of the NMR line shape using the DMFit software. The found parameters show that solid solution structure is NaTa03-based at 0.7<X ?1 and NaNbO3-based at 0?x?0.5. The spectra in the intermediate region (0.5<x?0.7) can be described at a reasonable accuracy when assuming the coexistence of NaTaO3 and NaNbO3 structures. В© 2010 - STC "Institute for Single Crystals".

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Держатели документа:
L. V. Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, 660036 Krasnoyarsk, Russian Federation
Siberian Federal University, 660041 Krasnoyarsk, Russian Federation

Доп.точки доступа:
Aleksandrova, I. P.; Александрова, Инга Петровна; Ivanov, Y. N.; Иванов, Юрий Николаевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Sukhovskii, A. A.; Суховский, Андрей Андреевич; Voronov, V. N.; Воронов, Владимир Николаевич
}
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10.

Chemical pressure as an effective tool for tuning the structural disordering and barocaloric efficiency of complex fluorides (NH4)3MF7 (M: Sn, Ti, Ge, Si) / I. N. Flerov, M. V. Gorev, E. V. Bogdanov, N. M. Laptash // J. Phys. D: Appl. Phys. - 2024. - Vol. 57, Is. 17. - Ст. 175301, DOI 10.1088/1361-6463/ad211b. - Cited References: 39. - The study was supported by a Grant from the Russian Science Foundation No. 23-22-00115, https://rscf.ru/project/23-22-00115/ . - ISSN 0022-3727. - ISSN 1361-6463
Кл.слова (ненормированные):
fluorides -- phase transformation -- phase diagram -- entropy -- pressure -- barocaloric effect
Аннотация: Double fluoride salts (NH4)3M4+F7 (M4+: Sn, Ti, Ge, Si) demonstrate a high efficiency of using chemical pressure as a tool for control and tuning structural ordering/disordering, sensitivity to hydrostatic pressure, successions of the phase transitions, etc and, as a result, for purposeful variation within a wide range of parameters of barocaloric effect (BCE). The conventional and inverse BCEs near the triple points were found on the T − p phase diagrams, combination of which can be used to construct original cooling cycle in narrow temperature and pressure ranges. Reconstructive transformation between two cubic phases, Pm3-m ↔ Pa3-, realized in (NH4)3SnF7 at atmospheric pressure and in (NH4)3TiF7 at p ˃ 0.4 GPa are characterized by rather low thermal hysteresis, δT0 = 1 K, and a great entropy change, ΔSBCE = 110–152 J (kg · K)−1, depending on the size of the central atom. At above 300–350 K, a contribution to BCE associated with the regular thermal expansion of the crystal lattice becomes comparable to entropy and temperature changes under pressure in the region of the phase transitions. An analysis of the absolute, relative and integral barocaloric characteristics of (NH4)3M4+F7 compounds showed their high competitiveness with respect to other barocaloric materials considered as promising solid-state refrigerants.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, 660074 Krasnoyarsk, Russia
Institute of Engineering Systems and Energy, Krasnoyarsk State Agrarian University, 660049 Krasnoyarsk, Russia
Institute of Chemistry, Far Eastern Department of RAS, 690022 Vladivostok, Russia

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Laptash, N. M.
}
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11.

Comparative analysis of elastocaloric and barocaloric effects in single-crystal and ceramic ferroelectric (NH4)2SO4 / E. Mikhaleva, M. Gorev, V. Bondarev [et al.] // Scripta Mater. - 2021. - Vol. 191. - P. 149-154, DOI 10.1016/j.scriptamat.2020.09.030. - Cited References: 47. - The reported study was supported by the Russian Science Foundation (project no. 19-72-00023 ). X-ray and dilatometric data were obtained using the equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” . - ISSN 1359-6462
Кл.слова (ненормированные):
Polymorphic phase transformation -- Phase diagram -- Order–disorder phenomena -- Entropy -- Caloric effects
Аннотация: We report the influence of anisotropy and texture on elasto(ElCE)- and baro(BCE)-caloric effects in single-crystal and ceramic (NH4)2SO4. Inverse extensive and intensive ElCE in ceramics, (ΔSElCE)cer = 87 J/kg·K; ΔTAD = - 11.6 K), as well as in a single crystal along the ferroelectric axis a, (ΔSElCE)a = 115 J/kg·K; (ΔTAD)a = - 16 K, significantly exceed BCE, ΔSBCE = 75 J/kg·K; ΔTAD = - 9.8 K, even at low pressure ~ 0.3 GPa. Caloric parameters of ammonium sulphate are comparable with those for promising solid-state refrigerants.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, 660074, Russian Federation
Institute of Engineering Systems and Energy, Krasnoyarsk State Agrarian University, Krasnoyarsk, 660049, Russian Federation

Доп.точки доступа:
Mikhaleva, E. A.; Михалева, Екатерина Андреевна; Gorev, M. V.; Горев, Михаил Васильевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Flerov, I. N.; Флёров, Игорь Николаевич
}
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12.

    Comparative study of the magnetic phase diagrams and spin-flop-driven magnetodielectric responses of the pure and Mn3+-doped Pb2Fe2Ge2O9 single crystals / A. Pankrats, M. Kolkov, A. Balaev [et al.] // J. Magn. Magn. Mater. - 2021. - Vol. 534. - Ст. 168023, DOI 10.1016/j.jmmm.2021.168023. - Cited References: 21. - This study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory, and the Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project no. 18-42-240008 “Effect of the Magnetic Structure on the Magnetodielectric Properties of Oxide Crystals Containing Stereoactive Pb 2+ and Bi 3+ Ions” . - ISSN 0304-8853
   Перевод заглавия: Сравнительное исследование магнитных фазовых диаграмм и индуцированных спин-флоп переходом магнитодиэлектрических откликов в чистом и допированном Mn3+ монокристаллах Pb2Fe2Ge2O9
Кл.слова (ненормированные):
Magnetic structure -- Magnetic anisotropy -- Magnetodielectric properties -- Spin reorientation -- Magnetic phase diagram
Аннотация: The Pb2Fe2-xMnxGe2O9 (x = 0.43) orthorhombic antiferromagnet single crystals have been synthesized by a modified pseudo-flux technique and their magnetic and magnetodielectric properties have been investigated. It has been established that partial substitution of highly anisotropic Mn3+ ions for iron ones significantly affects the magnetic structure of the crystal. Under magnetization of the crystal along the rhombic b and c axes, magnetization jumps have been detected, which are indicative of the occurrence of orientational transitions identified as first-order ones. No weak ferromagnetism characteristic of the pure crystal in the rhombic a axis direction has been detected. The field dependences of the magnetization for the pure and Mn-doped crystals have been analyzed using the thermodynamic potential that takes into account the crystal symmetry. It has been shown that, in the Mn-substituted crystal, the antiferromagnetic vector in the ground state is parallel to the rhombic b axis; in this state, weak ferromagnetism has not been observed. Under magnetization along the b axis, a conventional spin-flop transition occurs. The orientational transition under magnetization along the c axis has been attributed to the reorientation of the antiferromagnetic vector relative to the a axis with the simultaneous occurrence of a weak ferromagnetic moment along the c axis. Magnetic phase diagrams of the Mn-doped crystal for the magnetic fields H||b and H||c have been built. In the Mn-doped crystal, at E||c and H||c, the orientational transition-induced magnetodielectric response jump has been detected, which is higher than the jumps observed for the undoped crystal by a factor of 3. The magnetodielectric properties of the pure and Mn-doped crystals have been analyzed using their magnetic phase diagrams.

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Держатели документа:
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Pankrats, A. I.; Панкрац, Анатолий Иванович; Kolkov, M. I.; Колков, Максим Игоревич; Balaev, A. D.; Балаев, Александр Дмитриевич; Freydman, A. L.; Фрейдман, Александр Леонидович; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Balaev, D. A.; Балаев, Дмитрий Александрович
}
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13.

Conventional and inverse barocaloric effects in ferroelectric NH4HSO4 / M. V. Gorev [et al.] // J. Alloys Compd. - 2019. - Vol. 806. - P. 1047-1051, DOI 10.1016/j.jallcom.2019.07.273. - Cited References: 22 . - ISSN 0925-8388
Кл.слова (ненормированные):
Polymorphic phase transformation -- Phase diagram -- Order–disorder phenomena -- Entropy -- Barocaloric effect
Аннотация: In this study, the conventional and inverse barocaloric effects (BCE) in ferroelectric NH4HSO4 are reported. Maximum extensive and intensive BCE near order–disorder phase transition can be achieved at low pressure p≤0.1 GPa. Large thermal expansion of the crystal lattice plays a very important role in the developing conventional BCE and conversation between BCE of different sign in the narrow temperature range.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, Russian Federation
Institute of Engineering Systems and Energy, Krasnoyarsk State Agrarian University, Krasnoyarsk, 660049, Russian Federation

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Mikhaleva, E. A.; Михалева, Екатерина Андреевна; Flerov, I. N.; Флёров, Игорь Николаевич; Bogdanov, E. V.; Богданов, Евгений Витальевич
}
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14.

Diagram Approach to the Problem of the Normal Phase Properties of the Spin-Polaron Ensemble in Cuprate Superconductors / V. V. Val'kov [et al.] // J. Low Temp. Phys. - 2019. - Vol. 197, Is. 1-2. - P. 34-43, DOI 10.1007/s10909-019-02211-9. - Cited References: 29. - The work was supported by the program of the Presidium of the Russian Academy of Sciences No. 12 “Fundamental problems of high-temperature superconductivity,” the Russian Foundation for Basic Research (RFBR) (Projects Nos. 18-02-00837 and 19-02-00509) and partly by the Government of Krasnoyarsk Region and the Krasnoyarsk Region Science and Technology Support Fund (Projects Nos. 18-42-243002 “Manifestation of spin-nematic correlations in spectral characteristics of electronic structure and their influence on practical properties of cuprate superconductors,” 18-42-243018 “Contact phenomena and magnetic disorder in the problem of the formation and detection of topological edge states in semiconductor nanostructures,” and 18-42-240014 “Single-orbit effective model of an ensemble of spin-polaron quasiparticles in the problem of describing the intermediate state and pseudogap behavior of cuprate superconductors”). . - ISSN 0022-2291
Кл.слова (ненормированные):
Cuprate superconductors -- Unconventional superconductivity -- Spin-charge correlations
Аннотация: Taking into account the real crystalline structure of the CuO 2 plane within the spin-fermion model and using the diagram technique, the spin-polaron concept of the fermionic excitations in cuprate superconductors is implemented. It is shown that an account of the on-site scattering processes leads to considerable binding energy of the spin-polaron quasiparticles. An account of the two-site spin-fermion scattering processes results in the energy spectrum and spectral properties of the spin-polaron quasiparticles which agree well with experimental data on cuprate superconductors.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian State University of Science and Technology, Krasnoyarsk, 660037, Russian Federation
Vereshchagin Institute for High Pressure Physics, Troitsk, Moscow, 108840, Russian Federation

Доп.точки доступа:
Val'kov, V. V.; Вальков, Валерий Владимирович; Mitskan, V. A.; Мицкан, Виталий Александрович; Korovushkin, M. M.; Коровушкин, Максим Михайлович; Dzebisashvili, D. M.; Дзебисашвили, Дмитрий Михайлович; Barabanov, A. F.
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15.

Electronic transitions and genuine crystal-field parameters in copper metaborate CuB2O4 / R. V. Pisarev [et al.] // Phys. Rev. B. - 2011. - Vol. 84, Is. 7. - Ст. 75160, DOI 10.1103/PhysRevB.84.075160. - Cited References: 65. - Useful discussions with W. Weber on crystal-field splitting of 3d states in cuprates are appreciated. We thank H.-J. Weber for the help in using Cary 2300 spectrophotometer. This work is supported by the Russian Foundation for Basic Research (project No. 09-02-00070) and Federal Agency for Science and Innovations (Grant No. 02.740.11.0384). A. M. K. acknowledges the financial support from the Committee for Science and Higher Education of the Government of Saint Petersburg. . - ISSN 1098-0121

РУБ Physics, Condensed Matter
Рубрики:
OPTICAL-ABSORPTION
   PHASE-DIAGRAM
   CUGEO3
   SPECTRUM
   SUPERCONDUCTORS
   EXCITATIONS
   SR2CUO2CL2
   SCATTERING
   LA2CUO4
   CUPRATE
Аннотация: We present and analyze high-resolution alpha-, sigma-, and pi-polarized absorption spectra related to d-d electronic transitions in tetragonal metaborate CuB2O4 where copper Cu2+ ions occupy two crystallographically distinct 4b and 8d positions. The spectra are characterized by exceptionally rich fine structure in the spectral range of 1.4-2.4 eV. Six zero-phonon (ZP) lines originating from the electronic transitions within the Cu2+ ions in both positions are distinguished and identified. Symmetry analysis explains polarization properties of the ZP lines in the 8d positions but only partially explains them in the 4b positions. Reliable assignment of all six ZP lines to specific transitions allowed us to calculate genuine cubic Dq and tetragonal Ds and Dt crystal-field parameters for both positions. We show that the (3r(2) - z(2)) state, the energy of which is the measure of the Jahn-Teller splitting, is the highest 3d state for both types of Cu2+ ion positions. Using the obtained crystal-field parameters as the reference values, we estimated Dq, Ds, and Dt for several other cuprates with different Cu-O bond lengths. In particular, the 3d level splitting in La2CuO4, Nd2CuO4, CuGeO3, Sr2CuO2Cl2, and Cu3B7O13Cl was analyzed. Our estimates suggest that the Jahn-Teller splitting in some of these cuprates is larger than it was assumed previously.

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Держатели документа:
[Pisarev, R. V.
Kalashnikova, A. M.] Russian Acad Sci, AF Ioffe Phys Tech Inst, St Petersburg 194021, Russia
[Schoeps, O.] Dortmund Tech Univ, Inst Phys, D-44221 Dortmund, Germany
[Bezmaternykh, L. N.] Russian Acad Sci, Siberian Branch, Inst Phys, Krasnoyarsk 660036, Russia
ИФ СО РАН
Ioffe Physical-Technical Institute, Russian Academy of Sciences, 194021 St. Petersburg, Russian Federation
Institute of Physics, Dortmund Technical University, 44221 Dortmund, Germany
Institute of Physics, Siberian Branch, Russian Academy of Sciences, 660036 Krasnoyarsk, Russian Federation

Доп.точки доступа:
Pisarev, R. V.; Kalashnikova, A. M.; Schops, O.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
}
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16.

Exchange interaction between the high spin Co3+ states in LaCoO3 / Y. S. Orlov, S. V. Nikolaev, V. A. Gavrichkov, S. G. Ovchinnikov // Comput. Mater. Sci. - 2022. - Vol. 204. - Ст. 111134, DOI 10.1016/j.commatsci.2021.111134. - Cited References: 59. - We are thankful to the Russian Science Foundation, Russia for the financial support under the project 18-12-00022 . - ISSN 0927-0256
Кл.слова (ненормированные):
Exchange interaction -- Spin-orbital interaction -- Magnetic phase diagram -- Antiferromagnetism -- Ferromagnetism -- Hubbard model
Аннотация: The formation of the exchange interaction between HS Co3+ ions, which are excited in LaCoO3, is studied within the multielectron approach. Two main contributions appear to be antiferromagnetic (AFM) and ferromagnetic (FM). When the ground state is LS, the total interaction is AFM. The crossover to the HS state may result in the FM ordering. The mean-field magnetic phase diagrams on the plane spin gap-temperature have been calculated without and with spin-orbital interaction in the HS term. Without spin-orbital interaction the reentrant magnetic order is possible. The spin-orbital coupling removes the reentrant phase transition and stabilizes the LS state. For known from experimental data values of the spin gap and exchange interaction, the ideal stoichiometric LaCoO3 is very close to the LS–HS crossover and magnetic ordering border. The violations of local coordination and symmetry of the Co3+-oxygen complexes that take place in the intergrain boundaries, at the surface of single crystals, and in the thin films on the strained substrate, may result in the formation of the HS state and FM order for such materials.

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Держатели документа:
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Orlov, Yu. S.; Орлов, Юрий Сергеевич; Nikolaev, S. V.; Николаев, Сергей Викторович; Gavrichkov, V. A.; Гавричков, Владимир Александрович; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич
}
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17.

Features of the behavior of the barocaloric effect near ferroelectric phase transition close to the tricritical point / E. A. Mikhaleva, I. N. Flerov, M. V. Gorev [et al.] // Crystals. - 2020. - Vol. 10, Is. 1. - Ст. 51, DOI 10.3390/cryst10010051. - Cited References: 28. - The reported study was supported by the Russian Science Foundation (project no. 19-72-00023) . - ISSN 2073-4352
Кл.слова (ненормированные):
polymorphic phase transformation -- phase diagram -- order-disorder phenomena -- entropy -- barocaloric effect
Аннотация: A detailed study of the effect of temperature and pressure on heat capacity, entropy and hysteresis phenomena near the ferroelectric phase transition in ammonium sulfate (AS) was performed. An analysis of experimental results within the framework of the phenomenological theory showed that taking into account the temperature-dependent part of the anomalous entropy leads to a significant increase in the barocaloric effect (BCE). The maximum values of extensive and intensive BCE near the tricritical point are outstanding: ΔSmaxBCE≈85 J/kgK, ΔTmaxAD≈12 K and can be achieved at low pressure ∼0.5 GPa.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC Siberian Branch, Russian Academy of Sciences, 660036 Krasnoyarsk, Russia
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, 660074 Krasnoyarsk, Russia
Institute of Engineering Systems and Energy, Krasnoyarsk State Agrarian University, 660049 Krasnoyarsk, Russia

Доп.точки доступа:
Mikhaleva, E. A.; Михалева, Екатерина Андреевна; Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Bondarev, I. A.; Бондарев, Илья Александрович; Bogdanov, E. V.; Богданов, Евгений Витальевич
}
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18.

    Ferroelastic phase transitions in fluorides with cryolite and elpasolite structures / I. N. Flerov [et al.] // Crystallogr. Rep. - 2004. - Vol. 49, Is. 1. - P. 100-107, DOI 10.1134/1.1643969. - Cited References: 43 . - ISSN 1063-7745
Рубрики:
NUCLEAR MAGNETIC-RESONANCE
   THERMODYNAMIC PROPERTIES
   RB2KMIIIF6 ELPASOLITES
   NEUTRON-DIFFRACTION
   CRYSTALS
   PEROVSKITES
   DIAGRAM
   SC
   RB2KGAXSC1-XF6
   SCATTERING
Аннотация: The ferroelastic phase transitions are investigated in several series of fluoride crystals belonging to the elpasolite and cryolite families (space group Fm (3) over barm) with the general formula A(2)BB'F-6. The influence of the size and shape of cations and anions on the entropy and the mechanism of structural distortions is discussed. (C) 2004 MAIK "Nauka/Interperiodica".

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Публикация на русском языке Сегнетоэластические фазовые переходы во фторидах со структурой криолита и эльпасолита [Текст] / И. Н. Флеров [и др.] // Кристаллография. - 2004. - Т. 49 Вып. 1. - С. 107-114

Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
Inst Chim Mat Condensee Bordeaux, F-33608 Pessac, France
ИФ СО РАН

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Tressaud, A.; Fokina, V. D.; Фокина, Валентина Дмитриевна
}
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19.

Flerov, I. N.
Entropy of Rb2KB3+F6 (B3+: Se, In, Lu, Er, Ho) ferroelastics and the triple point on T(R(B)(3+)) diagram / I. N. Flerov, M. V. Gorev, V. N. Voronov // Fiz. Tverd. Tela. - 1996. - Vol. 38, Is. 3. - P. 717-727. - Cited References: 26 . - ISSN 0367-3294

РУБ Physics, Condensed Matter
Рубрики:
STRUCTURAL PHASE-TRANSITIONS
RB2KMIIIF6 ELPASOLITES

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Доп.точки доступа:
Gorev, M. V.; Voronov, V. N.
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20.

    Flux pinning mechanisms and a vortex phase diagram of tin-based inverse opals / A. A. Bykov [et al.] // Supercond. Sci. Technol. - 2019. - Vol. 32, Is. 11. - Ст. 115004, DOI 10.1088/1361-6668/ab3db7. - Cited References: 31. - The work was supported by the Russian Foundation for Basic Research, project no. 17-72-10067. . - ISSN 0953-2048. - ISSN 1361-6668
   Перевод заглавия: Механизмы пиннинга магнитного потока и вихревая фазовая диаграмма оловянных инвертированных опалов

РУБ Physics, Applied + Physics, Condensed Matter
Рубрики:
SUPERCONDUCTIVITY
Кл.слова (ненормированные):
tin-based inverse opal -- superconductivity -- magnetic flux pinning -- three-dimensional inverse nanostructures
Аннотация: Three-dimensional periodic tin structures were synthesized by filling pores in silicon opals with a sphere diameter of 194 nm (Sn190) and 310 nm (Sn300). The samples were examined by the ultra-small-angle x-ray diffraction method, energy dispersive x-ray microanalysis and scanning electron microscopy. It was found that the inverse opal structure consists of tin nanoparticles inscribed in octahedral and tetrahedral pores with diameters of 128 nm and 70 nm for the sample Sn300, and 80 nm and 42 nm for the sample Sn190. The study of the magnetic properties of the samples by SQUID magnetometry showed that magnetization reversal curves exhibit hysteretic behavior. The mechanisms of magnetic flux pinning in the samples depend on the size of the tin nanoparticles. Tin nanoparticles in Sn300 behave like a classical type-I superconductor. The hysteretic behavior of the magnetization reversal curves at low magnetic fields is due to the formation of a network of superconducting contours in Sn300. These superconducting contours effectively trap the magnetic flux. The octahedral tin nanoparticles in Sn190 remain type-I superconductors, but smaller tetrahedral particles behave like type-II superconductors. Type-I and II superconducting particles in Sn190 lead to the coexistence of different mechanisms of flux pinning These are flux trapping by superconducting contours at low magnetic fields and flux pinning by tetrahedral particles due to the surface barrier at high magnetic fields.

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Держатели документа:
NRC KI, Petersburg Nucl Phys Inst, Gatchina, Russia.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk, Russia.
St Petersburg State Univ, St Petersburg, Russia.
Univ Texas Dallas, Alan G MacDiarmid NanoTech Inst, Dallas, TX USA.

Доп.точки доступа:
Bykov, A. A.; Gokhfeld, D. M.; Гохфельд, Денис Михайлович; Savitskaya, N. E.; Terentjev, K. Yu.; Терентьев, Константин Юрьевич; Popkov, S. I.; Попков, Сергей Иванович; Mistonov, A. A.; Grigoryeva, N. A.; Zakhidov, A.; Grigoriev, S., V; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [17-72-10067]
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