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Magnetic ordering of NdFe3(BO3)(4) studied by infrared absorption spectroscopy / E. P. Chukalina [et al.] // Phys. Lett. A. - 2004. - Vol. 322, Is. 3-4. - P. 239-243, DOI 10.1016/j.physleta.2003.12.062. - Cited References: 8 . - ISSN 0375-9601

РУБ Physics, Multidisciplinary
Рубрики:
CRYSTALS
Кл.слова (ненормированные):
ferroborates -- Fourier-transform spectroscopy -- magnetic ordering -- Ferroborates -- Fourier-transform spectroscopy -- Magnetic ordering -- iron -- neodymium -- absorption spectroscopy -- article -- electronics -- infrared spectroscopy -- magnetism -- molecular interaction -- molecular physics -- temperature
Аннотация: We report the first measurements of the optical spectra of NdFe3(BO3)(4), a promising material for optoelectronics. Exchange splitting of Nd3+ spectral lines due to magnetic interactions in a magnetically ordered state was observed. The temperature dependences of the exchange splitting and of the linewidth point to the temperature T-c 33 +/- 1K of the magnetic ordering in both iron and neodymium. magnetic subsystems. 2004 Elsevier B.V. All rights reserved.

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Держатели документа:
Russian Acad Sci, Inst Spect, Troitsk 142190, Moscow Region, Russia
RAS, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Institute of Spectroscopy, Russian Academy of Sciences, 142190 Troitsk, Moscow Region, Russian Federation
L.V. Kirensky Institute of Physics, Siberian Branch of RAS, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Chukalina, E. P.; Kuritsin, D. Y.; Popova, M. N.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Kharlamova, S. A.; Temerov, V. L.; Темеров, Владислав Леонидович
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Optical properties and electronic structure of rare-earth ferroborates / V. N. Zabluda [et al.] // Phys. Solid State. - 2005. - Vol. 47, Is. 3. - P. 489-494, DOI 10.1134/1.1884710. - Cited References: 19. - This work was supported by the Russian Foundation for Basic Research (project no. 03-02-16268) and the program of the Department of Physical Sciences of the Russian Academy of Sciences "Strongly Correlated Electrons" . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
TRIGONAL GDFE3(BO3)(4)
   MAGNETIC-PROPERTIES
   BAND-STRUCTURE
   FEBO3
   ABSORPTION
Аннотация: The optical absorption spectra of single-crystal ferroborate GdFe3(BO3)(4) and GdFe2.1Ga0.9(BO3)(4) are measured and interpreted. It is found that the absorption edge and the absorption bands A, B, and C observed below the edge are close to those for FeBO3. A many-electron model of the band structure of GdFe3(BO3)(4) is suggested including strong electron correlations between the iron d states. It is shown that GdFe3(BO3)(4) has a charge-transfer dielectric gap. A rise in pressure is predicted to result in a crossover between the high-spin and low-spin states of the Fe ion, collapse of the magnetic moment, a weakening of Coulomb correlations, an abrupt reduction in the energy gap, and an insulator-semiconductor transition. (c) 2005 Pleiades Publishing, Inc.

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Публикация на русском языке Оптические свойства и электронная структура редкоземельных ферроборатов [Текст] / В. Н. Заблуда [и др.] // Физ. тверд. тела. - 2005. - Т. 47 Вып. 3. - С. 474-479

Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, Akademgorodok, 660036, Russian Federation

Доп.точки доступа:
Zabluda, V. N.; Заблуда, Владимир Николаевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Potseluliko, A. M.; Kharlamova, S. A.
}
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Ovchinnikov, S. G.
The mechanism of the electronic transition in ferroborates under high pressure / S. G. Ovchinnikov // J. Phys.: Condens. Matter. - 2005. - Vol. 17: 2nd International Symposium on Physics of Solids Under High Pressure Using Nuclear Probes (JUL 20-24, 2004, Cologne, GERMANY), Is. 11. - P. S743-S751, DOI 10.1088/0953-8984/17/11/003. - Cited References: 20 . - ISSN 0953-8984

РУБ Physics, Condensed Matter
Рубрики:
STRUCTURAL PHASE-TRANSITION
   MAGNETIC COLLAPSE
   OPTICAL-SPECTRA
   BAND-STRUCTURE
   FEBO3
   MODEL
Кл.слова (ненормированные):
Carrier concentration -- Correlation methods -- Electron transitions -- High pressure effects -- Magnetic moments -- Mathematical models -- Metal insulator transition -- Crystal field -- Electron correlations -- Electronic transition -- Ferroborates -- Ferromagnetic materials
Аннотация: A novel mechanism for the insulator-semiconductor transition and magnetic collapse in FeBO3 is proposed in the framework of the multielectron model with account taken of strong electron correlations. The electronic transition results from the crossover of the high spin and low spin Fe3+ states induced by the crystal field increasing with pressure. In the high pressure phase a semiconductor-metal transition is expected.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
L V Kirensky Institute of Physics, Siberian Br. Russ. Acad. of Sci., Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Овчинников, Сергей Геннадьевич
}
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Studies of magnetic and optic properties of rare-earth gallo-ferroborates by Mossbauer and optical spectroscopy / O. A. Bayukov [et al.] // Physica B. - 2005. - Vol. 359: International Conference on Strongly Correlated Electron Systems (SCES 04) (JUL 26-30, 2004, Karlsruhe, GERMANY). - P. 1321-1323, DOI 10.1016/j.physb.2005.01.397. - Cited References: 3 . - ISSN 0921-4526

РУБ Physics, Condensed Matter

Кл.слова (ненормированные):
strongly correlated electron system -- antiferromagnets -- borates -- Antiferromagnets -- Borates -- Strongly correlated electron system -- Antiferromagnetism -- Cryostats -- Energy gap -- Magnetic moments -- Magnetic properties -- Mossbauer spectroscopy -- Optical properties -- Single crystals -- Borates -- Coulomb correlations -- Liquid helium -- Strongly correlated electron systems -- Gadolinium compounds
Аннотация: Magnetic and optical properties of GdFe3-xGax(BO3)(4) single crystals are investigated by Mossbauer and optical spectroscopy. The GdFe3(BO3)(4) multielectron band structure model is derived. A high- and low-spin crossover of Fe3+ ion, a collapse of the magnetic moment, the suppression of Coulomb correlations, and insulator-semiconductor transition are predicted. The jump of an energy gap is measured at pressure 43 GPa. (c) 2005 Elsevier B.V. All rights reserved.

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Держатели документа:
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk, Russia
Inst High Pressure Phys, Troitsk 142190, Russia
Inst Crystallog, Moscow 117333, Russia
Univ Liverpool, Liverpool L69 3BX, Merseyside, England
ИФ СО РАН
LV Kirensky Institute of Physics, Siberian Branch of RAS, Krasnoyarsk, Russian Federation
Institute of High Pressure Physics, 142190, Troisk, Moscow region, Russian Federation
Institute of Crystallograhy, Leninsky Av. 59, 117333, Moscow, Russian Federation
The University of Liverpool, Liverpool L69 3BX, United Kingdom

Доп.точки доступа:
Bayukov, O. A.; Баюков, Олег Артемьевич; Gavrilyuk, A. M.; Zabluda, V. N.; Заблуда, Владимир Николаевич; Lyubutin, I. S.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Potseluyko, A. M.; Tomas, M.; Trojan, I. A.; Kharlamova, S. A.
}
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Magnetoelectric interactions in rare-earth ferroborates / A. M. Kadomtseva [et al.] // J. Exp. Theor. Phys. - 2007. - Vol. 105, Is. 1. - P. 116-119, DOI 10.1134/S1063776107070254. - Cited References: 14 . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
GDFE3(BO3)(4)
Кл.слова (ненормированные):
Gadolinium compounds -- Magnetoelectric effects -- Phase transitions -- Polarization -- Single crystals -- Magnetic control -- Magnetoelectric interactions -- Rare earth ferroborates -- Torque curves -- Rare earths
Аннотация: Magnetic-field-induced phase transitions in single crystals of the rare-earth ferroborates GdFe3(BO3)(4) and NdFe3(BO3)(4) have been studied by measuring magnetoelectric dependences and torque curves. These phase transitions can serve as one of the possible mechanisms for magnetic control of electric polarization. Magnetic phase transitions in GdFe3(BO3)(4) are analyzed theoretically.

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Держатели документа:
Moscow MV Lomonosov State Univ, Moscow 119992, Russia
Russian Acad Sci, Inst Gen Phys, Moscow 119991, Russia
Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Moscow State University, Moscow 119992, Russian Federation
Institute of General Physics, Russian Academy of Sciences, ul. Vavilova 38, Moscow 119991, Russian Federation
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Kadomtseva, A. M.; Zvezdin, A. K.; Pyatakov, A. P.; Kuvardin, A. V.; Vorob'ev, G. P.; Popov, Y. F.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
}
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Observation of spontaneous spin reorientation in Nd1-x Dy (x) Fe-3(BO3)(4) ferroborates with a competitive R-Fe exchange / Y. F. Popov [et al.] // JETP Letters. - 2009. - Vol. 89, Is. 7. - P. 345-351, DOI 10.1134/S002136400907008X. - Cited References: 14. - We are deeply grateful to A. K. Zvezdin and A. P. Pyatakov for useful advice and to E. A. Popova for placing the DyFeINF3/INF(BOINF3 /INF)INF4INF single crystal at our disposal. This work was supported by the Russian Foundation for Basic Research ( project no. 07-02-00580-a). . - ISSN 0021-3640

РУБ Physics, Multidisciplinary
Рубрики:
TRIGONAL GDFE3(BO3)(4)
MAGNETIC-PROPERTIES
DYFE3(BO3)(4)
Аннотация: The magnetic, magnetoelectric, and magnetoelastic properties of DyFe3(BO3)(4) single crystals and the Nd0.75Dy0.25Fe3(BO3)(4) substituted compound with the competitive Nd-Fe and Dy-Fe exchange interactions have been investigated in magnetic fields up to 210 kOe. It has been shown that the antiferromagnetic state in Nd0.75Dy0.25Fe3(BO3)(4) below the N,el temperature is easy-plane and a spontaneous spin-reorientation transition to a uniaxial state occurs near 25 K. Anomalies are observed in various physical characteristics in a spin-flop transition induced by the magnetic field along the trigonal axis. The H-T phase diagrams are constructed; they are in good agreement with a simple model taking into account the anisotropy of the exchange splitting and g factors of the ground doublets of the Dy3+ and Nd3+ ions. The features of the magnetoelectric effect in various magnetic phases have been studied. Spontaneous electric polarization has been revealed in the region of the existence of an easy-plane antiferromagnetic state in the substituted compound. A qualitative theoretical justification of the possibility of the appearance of the spontaneous spin-reorientation transition in the Nd0.75Dy0.25Fe3(BO3)(4) substituted compound is given.

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Держатели документа:
[Popov, Yu. F.
Kadomtseva, A. M.
Vorob'ev, G. P.] Moscow MV Lomonosov State Univ, Moscow 119992, Russia
[Mukhin, A. A.
Ivanov, V. Yu.
Kuz'menko, A. M.
Prokhorov, A. S.] Russian Acad Sci, Prokhorov Gen Phys Inst, Moscow 119991, Russia
[Bezmaternykh, L. N.
Temerov, V. L.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660038, Russia
ИФ СО РАН
Moscow State University, Moscow 119992, Russian Federation
Prokhorov General Physics Institute, Russian Academy of Sciences, ul. Vavilova 38, Moscow 119991, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660038, Russian Federation

Доп.точки доступа:
Popov, Y. F.; Kadomtseva, A. M.; Vorob'ev, G. P.; Mukhin, A. A.; Ivanov, V. Y.; Kuz'menko, A. M.; Prokhorov, A. S.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Temerov, V. L.; Темеров, Владислав Леонидович; Russian Foundation for Basic Research [07-02-00580-a]
}
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Magnetic Structure of the Field?Induced Polarization Phases of Rare Earth Ferroborates / Christie Nelson, Mo Haiding [et al.] // 18th International Conference on Magnetism (ICM-2009). - 2009. - Ст. Mo-A-5.1-03

Доп.точки доступа:
Nelson, Christie; Haiding, Mo; Bezmaternykh, L.N.; Gudim, I.A.; International Conference on Magnetism(18 ; 2009 ; July 26-31 ; Karlsruhe, Germany)
}
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Magnetic anisotropy and magnetoelectric properties of Tb1-x Er (x) Fe-3(BO3)(4) ferroborates / A. K. Zvezdin [et al.] // J. Exp. Theor. Phys. - 2009. - Vol. 109, Is. 1. - P. 68-73, DOI 10.1134/S1063776109070097. - Cited References: 18. - This study was supported by the Russian Foundation for Basic Research (project no. 07-02-00580). . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
GDFE3(BO3)(4)
Кл.слова (ненормированные):
Competing exchange -- Complex compositions -- Critical fields -- Electric polarization -- Er concentrations -- Exchange splitting -- Ferroborates -- G factors -- Magnetoelectric properties -- Nonmonotonic -- Simple model -- Spin-flop transitions -- Composite micromechanics -- Erbium -- Ions -- Magnetic anisotropy -- Magnetostriction -- Magnetostrictive devices -- Phase transitions -- Polarization -- Spin dynamics -- Terbium alloys -- Single crystals
Аннотация: Magnetic and magnetoelectric properties of ferroborate single crystals with complex composition (Tb1 - x Er (x) Fe-3(BO3)(4), x = 0, 0.75) and with competing exchange Tb-Fe and Er-Fe interactions are investigated. Jumps in electric polarization, magnetostriction, and magnetization are observed as a result of spin-flop transitions, as well as a considerable decrease in the critical field upon an increase in the Er concentration, in a field H (c) parallel to the c axis. The observed behavior of phase-transition fields is analyzed and explained using a simple model taking into account anisotropy in g factors and exchange splitting of funda-mental doublets of the easy-axis Tb3+ ion and easy-plane Er3+ ion. It is established that magnetoelectric and magnetostriction anomalies under spin-flop transitions are mainly controlled by the Tb subsystem. The Tb subsystem makes a nonmonotonic contribution Delta P (a) (H (a) , T) to polarization along the a axis: the value of Delta P (a) reverses its sign and increases with temperature due to the contribution from the excited states of the Tb3+ ion.

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Держатели документа:
[Zvezdin, A. K.
Pyatakov, A. P.
Ivanov, V. Yu.
Kuz'menko, A. M.
Mukhin, A. A.] Russian Acad Sci, Prokhorov Inst Gen Phys, Moscow 119991, Russia
[Kadomtseva, A. M.
Popov, Yu. F.
Vorob'ev, G. P.
Pyatakov, A. P.] Moscow MV Lomonosov State Univ, Moscow 119992, Russia
[Bezmaternykh, L. N.
Gudim, I. A.] Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660038, Russia
ИФ СО РАН
Moscow State University, Moscow 119992, Russian Federation
Prokhorov Institute of General Physics, Russian Academy of Sciences, Moscow 119991, Russian Federation
Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk 660038, Russian Federation

Доп.точки доступа:
Zvezdin, A. K.; Kadomtseva, A. M.; Popov, Y. F.; Vorob'ev, G. P.; Pyatakov, A. P.; Ivanov, V. Y.; Kuz'menko, A. M.; Mukhin, A. A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Russian Foundation for Basic Research [07-02-00580]
}
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Magnetoelectric and magnetoelastic properties of rare-earth ferroborates / A. M. Kadomtseva [et al.] // Low Temp. Phys. - 2010. - Vol. 36, Is. 6. - P. 511-521 ; Физика низких температур, DOI 10.1063/1.3457390. - Cited References: 37. - This work was performed with financial support from RFFI (grant No. 10-02-00848-a). . - ISSN 1063-777X

РУБ Physics, Applied

Аннотация: The magnetic, electric, magnetoelectric, and magnetoelastic properties of rare-earth ferroborates RFe(3)(BO(3))(4) (R=Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er) as well as yttrium ferroborate YFe(3)(BO(3))(4) have been studied comprehensively. A strong dependence not only of the magnetic but also magnetoelectric properties on the type of rare-earth ion, specifically, on its anisotropy, which determines the magnetic structure and the large contribution to the electric polarization, has been found. This is manifested in the strong temperature dependence of the polarization below the Neel point T(N) and its specific field dependence, which is determined by the competition between the external and exchange f-d fields. A close correlation has been found between the magnetoelastic properties of ferroborates and the magnetoelastic and magnetic anomalies at magnetic-field induced phase transitions. It is found that in easy-plane ferroborates, together with magnetic-field induced electric polarization spontaneous polarization also arises below the Neel point. The ferroelectric ordering in ferroborates is of extrinsic character, giving rise to strong magnetoelectric coupling below T(N). Aside from the antiferromagnetic phase transition, the particulars of the structural phase transition accompanied by anomalies of the dielectric and magnetoelectric properties are examined for the first time. The character of the dielectric anomalies at a structural transition is analyzed for the first time on the basis of Landau's approach. (c) 2010 American Institute of Physics. [doi:10.1063/1.3457390]

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Держатели документа:
[Kadomtseva, A. M.
Popov, Yu. F.
Vorob'ev, G. P.
Pyatakov, A. P.
Krotov, S. S.
Kamilov, K. I.] Moscow MV Lomonosov State Univ, Moscow 119991, Russia
[Ivanov, V. Yu.
Mukhin, A. A.
Zvezdin, A. K.
Kuz'menko, A. M.] Russian Acad Sci, AM Prokhorov Inst Phys, Moscow 119991, Russia
[Bezmaternykh, L. N.
Gudim, I. A.
Temerov, V. L.] Russian Acad Sci, LV Kirenskii Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
M. V. Lomonosov Moscow State University, Vorob'evy gory, Moscow 119991, Russian Federation
A. M. Prokhorov Institute of Physics of the Russian Academy of Sciences, Moscow 119991, Russian Federation
L. V. Kirenskii Inst. of Physics, Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Kadomtseva, A. M.; Popov, Y. F.; Vorob'ev, G. P.; Pyatakov, A. P.; Krotov, S. S.; Kamilov, K. I.; Ivanov, V. Y.; Mukhin, A. A.; Zvezdin, A. K.; Kuz'menko, A. M.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович

}
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10.

Antiferromagnetic Resonance and Dielectric Properties of Rare-earth Ferroborates in the Submillimeter Frequency Range / A. M. Kuz'menko [et al.] // J. Exp. Theor. Phys. - 2011. - Vol. 113, Is. 1. - P. 113-120, DOI 10.1134/S106377611105013X. - Cited References: 27. - This work was supported by the Russian Foundation for Basic Research, project no. 10-02-00846. . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
GDFE3(BO3)(4)
SPECTROSCOPY
CRYSTAL
Кл.слова (ненормированные):
Antiferromagnetic resonance -- Basic parameters -- Effective anisotropy constant -- Ferroborates -- Ferroics -- Ferromagnetic orderings -- Frequency ranges -- Magnetic interactions -- Magnetoresonance -- Millimeter frequency range -- Rare earth ions -- Submillimeters -- Antiferromagnetic materials -- Crystallography -- Erbium -- Europium -- Ferromagnetic resonance -- Ion exchange -- Magnetic anisotropy -- Magnetic devices -- Magnetic structure -- Permittivity -- Resonance -- Antiferromagnetism
Аннотация: The magnetoresonance and dielectric properties of a number of crystals of a new family of multiferroics, namely, rare-earth ferroborates RFe(3)(BO(3))(4) (R = Y, Eu, Pr, Tb, Tb(0.25)Er(0.75)), are studied in the submillimeter frequency range (nu = 3-20 cm(-1)). Ferroborates with R = Y, Tb, and Eu exhibit permittivity jumps at temperatures of 375, 198, and 58 K, respectively, which are caused by the R32 -> P3(1)2(1) phase transition. Antiferromagnetic resonance (AFMR) modes in the subsystem of Fe(3+) ions are detected in the range of antiferromagnetic ordering (T < T(N) = 30-40 K) in all ferroborates that have either an easy-plane (Y, Eu) or easy-axis (Pr, Tb, Tb(0.25)Er(0.75)) magnetic structure. The AFMR frequencies are found to depend strongly on the magnetic anisotropy of a rare-earth ion and its exchange interaction with the Fe subsystem, which determine the type of magnetic structure and the sign and magnitude of an effective anisotropy constant. The basic parameters of the magnetic interactions in these ferroborates are found, and the magnetoelectric contribution to AFMR is analyzed.

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Держатели документа:
[Kuz'menko, A. M.
Mukhin, A. A.
Ivanov, V. Yu.
Lebedev, S. P.] Russian Acad Sci, Inst Gen Phys, Moscow 119991, Russia
[Kadomtseva, A. M.] Moscow MV Lomonosov State Univ, Moscow 119991, Russia
[Bezmaternykh, L. N.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Institute of General Physics, Russian Academy of Sciences, ul. Vavilova 38, Moscow, 119991, Russian Federation
Moscow State University, Moscow, 119991, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Kuz'menko, A. M.; Mukhin, A. A.; Ivanov, V. Y.; Kadomtseva, A. M.; Lebedev, S. P.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
}
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