Библиотека института физики им. Л.В. Киренского СО РАН

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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhang X., Jiang X., Molokeev M. S., Wang N., Liu Y., Lin Z.
Заглавие : Two-dimensional negative thermal expansion in a crystal of LiBO2
Место публикации : Chem. Mater. - 2022. - Vol. 34, Is. 9. - P.4195-4201. - ISSN 08974756 (ISSN), DOI 10.1021/acs.chemmater.2c00621
Примечания : Cited References: 55. - The authors acknowledge Zhuohong Yin and Jincheng Feng for useful discussions. This work was supported by the National Scientific Foundations of China [Grants 51702330, 11974360, 51872297, and 51890864] and the Young Elite Scientist Sponsorship (YESS) Program by the China Association for Science and Technology [Grant YESS20200149 for X.J.]
Аннотация: Negative thermal expansion (NTE), violating the common sense of “thermal expansion and cold contraction” effects, is a novel temperature-responding behavior of great scientific and technical significance. Herein, we report a two-dimensional (2D) NTE behavior in a crystal of LiBO2, which is constructed by graphite-like [LiBO2]∞ layers. This intriguing thermal property originates from the synergistic effect of the distortion of in-plane [LiO3] bases in [LiO4] tetrahedra and the rotation of [BO3] triangles in the [LiBO2]∞ layer, driven by the force perpendicular to the layer owing to the large interlayer separation as temperature increases. Remarkably, the in-plane and out-of-plane Li–O bonds within the [LiO4] tetrahedra have nearly the same bond strength and exhibit the similar variation with respect to temperature, and this is quite different from the common sense on the 2D NTE behavior in layered structures that the intralayer atomic interaction must be much stronger than the interlayer ones. Our study deepens the understanding of the 2D NTE mechanism and would promote the exploration for NTE materials.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boca M., Molokeev M. S., Rakhmatullin A., Kubikova B., Netriova Z.
Заглавие : The structure of the metastable K18Ta5Zr5F63 phase
Место публикации : New J. Chem. - 2020. - Vol. 44, Is. 22. - P.9264-9270. - ISSN 11440546 (ISSN), DOI 10.1039/d0nj02428g
Примечания : Cited References: 30. - Financial support from TGIR-RMN-THC Fr3050 CNRS for conducting the research is gratefully acknowledged. This work was supported by the Slovak Research and Development Agency under the contract no. APVV-15-0479. This work was financially supported by the Scientific Grant Agency of the Ministry of Education of the Slovak Republic and the Slovak Academy of Sciences, grant no. Vega 2/0024/20
Аннотация: A metastable phase K18Ta5Zr5F63 was prepared by molten salt synthesis of K2TaF7 and K2ZrF6 in a sealed Pt crucible. This is the first example of a structure of a fluoride complex compound containing both tantalum and zirconium as central atoms. The asymmetric part of the unit cell contains two Ta/Zr sites and one pure Zr site. The Ta1/Zr1 ion is coordinated by seven F ions forming one capped trigonal prism. The Ta2/Zr2 ion is coordinated by six F ions forming a trigonal prism, and this polyhedron is fully ordered. The Zr3 ion is coordinated by six F ions, which are disordered over two positions. All (Zr/Ta)Fn (n = 6–8) polyhedra are isolated from each other, although the ZrF6 units have shared faces, forming an infinite channel along the c-axis. 19F MAS NMR experiments agree with the proposed structural model, identifying all five central non-equivalent polyhedra. The K18Ta5Zr5F63 phase decomposes within several months to its initial components; this can be monitored by NMR, DSC and XRD experiments. Moreover, accelerated decomposition can be achieved by thermal treatment, resulting in the formation of a K3ZrF7 phase.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kornienko V. S., Tsipotan A. S., Aleksandrovsky A. S., Slabko V. V.
Заглавие : The possibility of self-assembly of complex nanostructures with pre-defined geometry under the action of laser field
Коллективы : Application of Mathematics in Technical and Natural Sciences: 11th International Conference for Promoting the Application of Mathematics in Technical and Natural Sciences
Место публикации : AIP Conf. Proc. - 2019. - Vol. 2164, Is. 1. - Ст.100004. - ISSN 0094-243X (ISSN), DOI 10.1063/1.5130841. - ISSN 1551-7616 (eISSN). - ISSN 978-0-7354-1909-4 (ISBN)
Примечания : Cited References: 22. - The reported study was funded by Russian Science Foundation (Grant 18-72-00003). V.V. Slabko is grateful for the support from the Ministry of Education and Science of the Russian Federation (Grant 3.6341.2017/VU).
Аннотация: Self-assembly remains one of the simplest and cheapest methods of nanostructuring. And the dependence of the properties of the objects obtained, not only on their composition, but also on the form, brings to the fore the question of developing methods for forming structures of a predetermined form and searching for system parameters in which the formation of a structure becomes possible. This paper is devoted to modeling the process of self-assembly of a multiparticle nanostructure of a predetermined shape in the field of laser radiation.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Alakshin E. M., Gazizulin R. R., Zakharov, M. Yu., Klochkov A. V., Morozov E. V., Salikhov T. M., Safin T. R., Safiullin K. R., Tagirov M. S., Shabanova O. B.
Заглавие : The influence of restricted geometry of diamagnetic nanoporous media on He-3 relaxation
Коллективы : RFBR [14-02-31361 mol_a], RF Ministry of Education and Sciences[02.G25.31.0029]
Место публикации : Low Temp. Phys.: American Institute of Physics, 2015. - Vol. 41, Is. 1. - P.39-42. - ISSN 1063, DOI 10.1063/1.4906335. - ISSN 10906517(eISSN)
Примечания : Cited References:12. - This study was funded by a grant issued within the framework of statesupport for the Kazan (Volga) Federal University, in order to improveits competitiveness among the world's leading research and educationcenters (RFBR Grant No. 14-02-31361 mol_a), with partial funding fromthe RF Ministry of Education and Sciences (Project No. 02.G25.31.0029).
Предметные рубрики: PORE-SIZE DISTRIBUTIONS
SPIN-LATTICE-RELAXATION
ADSORBED He-3
PrF3
Аннотация: This is an experimental study of the spin kinetics of 3He in contact with diamagnetic samples of inverse opals SiO2, and LaF3 nanopowder. It is demonstrated that the nuclear magnetic relaxation of the absorbed 3He occurs due to the modulation of dipole-dipole interaction by the quantum motion in the two-dimensional film. It is found that the relaxation of liquid 3He occurs through a spin diffusion to the absorption layer, and that the restricted geometry of diamagnetic nanoporous media has an influence on the 3He relaxation.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kostyukov A. S., Ershov A. E., Bikbaev R. G., Gerasimov V. S., Rasskazov I. L., Karpov S. V., Polyutov S. P.
Заглавие : Substrate-mediated lattice Kerker effect in Al metasurfaces
Место публикации : J. Opt. Soc. Am. B. - 2021. - Vol. 38, Is. 9. - P.C78-C83. - ISSN 07403224 (ISSN), DOI 10.1364/JOSAB.427939
Примечания : Cited References: 62. - Funding. Russian Foundation for Basic Research, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science (20-42-240003); Ministry of Science and Higher Education of the Russian Federation (FSRZ-2020-0008)
Аннотация: Surface lattice resonances (SLRs) emerging in regular arrays of plasmonic nanoparticles (NPs) are known to be exceptionally sensitive to the homogeneity of the environment. It is considered necessary to have a homogeneous environment for engineering narrowband SLRs, while in a half-space environment, SLRs rapidly vanish as the contrast between the refractive indices of the substrate and superstrate increases. From this conventional wisdom, it is apparent that the delicate lattice Kerker effect emerging from SLRs and resonances on constituent NPs should be difficult to achieve in a non-homogeneous environment. Using a rigorous theoretical treatment with multipolar decomposition, we surprisingly find and explain a narrowband substrate-mediated lattice Kerker effect in two-dimensional arrays of Al nanocylinders in a half-space geometry. We propose to use this effect for sensing applications and demonstrate its broad tunability across the UV/Vis wavelength range.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Karpov S. V., Gerasimov V. S., Isaev I. L., Markel V. A.
Заглавие : Spectroscopic studies of fractal aggregates of silver nanospheres undergoing local restructuring
Место публикации : J. Chem. Phys.: AMER INST PHYSICS, 2006. - Vol. 125, Is. 11. - Ст.111101. - ISSN 0021-9606, DOI 10.1063/1.2229202
Примечания : Cited References: 30
Предметные рубрики: ENHANCED RAMAN-SCATTERING
SMALL-PARTICLE COMPOSITES
OPTICAL-PROPERTIES
DISORDERED CLUSTERS
NONLINEAR OPTICS
LOCALIZATION
NANOPARTICLES
EIGENMODES
BOUNDS
Ключевые слова (''Своб.индексиров.''): large-scale fractal geometry--nonlinear optical responses--restructuring--silver nanospheres--aggregates--colloids--electromagnetic fields--fractals--nonlinear optics--sampling--spectroscopic analysis--silver
Аннотация: We present an experimental spectroscopic study of large random colloidal aggregates of silver nanoparticles undergoing local restructuring. We argue that such well-known phenomena as strong fluctuation of local electromagnetic fields, appearance of "hot spots" and enhancement of nonlinear optical responses depend on the local structure on the scales of several nanosphere diameters, rather than the large-scale fractal geometry of the sample. (c) 2006 American Institute of Physics.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Volkov N. V., Rautskii M. V., Eremin E. V., Patrin G. S., Kim P. D., Lee C. G.
Заглавие : Response of a manganite-based magnetic tunnel structure to microwave radiation
Коллективы : Moscow International Symposium on Magnetism
Место публикации : Diffusion and Defect Data Pt.B: Solid State Phenomena. - 2012. - Vol. 190. - P.125-128. - ISBN 978, DOI 10.4028/www.scientific.net/SSP.190.125. - ISBN 9783037854365
Ключевые слова (''Своб.индексиров.''): magnetic tunnel structure--microwave detection effect--spintronics--current flowing--current-in-plane geometry--magnetic tunnels--magnetization dynamics--microwave detection--non-linearity--rectification effects--spin-polarized currents--voltage signals--magnetic materials--magnetoelectronics--manganese oxide--microwaves--magnetism
Аннотация: We demonstrate that a magnetic tunnel structure irradiated by microwaves can generate a significant voltage signal due to the rectification effect. The measurements were carried out using current-in-plane geometry with a current flowing parallel to the interfaces in the structure. A value of the microwave-induced voltage strongly depends on a bias current and can be driven by a magnetic field. The rectification effect is discussed both in "Classical" terms of nonlinearity of the current-voltage characteristic and using a mechanism that involves the interplay between the spinpolarized current and magnetization dynamics in the magnetic tunnel structure. В© (2012) Trans Tech Publications.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gerasimov V. S., Ershov A. E., Bikbaev R. G., Rasskazov I. L., Isaev I. L., Semina P. N., Kostyukov A. S., Zakomirnyi V. I., Polyutov S. P., Karpov S. V.
Заглавие : Plasmonic lattice Kerker effect in ultraviolet-visible spectral range
Место публикации : Phys. Rev. B. - 2021. - Vol. 103, Is. 3. - Ст.035402. - ISSN 24699950 (ISSN), DOI 10.1103/PhysRevB.103.035402
Примечания : Cited References: 66. - The research was supported by the Ministry of Science and High Education of Russian Federation, Project No. FSRZ-2020-0008, by RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, project number 20-42-240003 and by the Russian Science Foundation (Project No. 18-13-00363) (numerical calculations of phase dependences and corresponding research), A. E. acknowledges the grant of the President of the Russian Federation, agreement No. 075–15–2019–676
Аннотация: Mostly forsaken, but revived after the emergence of all-dielectric nanophotonics, the Kerker effect can be observed in a variety of nanostructures from high-index constituents with strong electric and magnetic Mie resonances. A necessary requirement for the existence of a magnetic response limits the use of generally nonmagnetic conventional plasmonic nanostructures for the Kerker effect. In spite of this, we demonstrate here the emergence of the lattice Kerker effect in regular plasmonic Al nanostructures. Collective lattice oscillations emerging from the delicate interplay between Rayleigh anomalies and localized surface plasmon resonances both of electric and magnetic dipoles, and electric and magnetic quadrupoles result in suppression of the backscattering in a broad spectral range. Variation of geometrical parameters of Al arrays allows for tailoring the lattice Kerker effect throughout UV and visible wavelength ranges, which is close to impossible to achieve using other plasmonic or all-dielectric materials. It is argued that our results set the ground for wide ramifications in the plasmonics and further application of the Kerker effect.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Volkov N. V., Lee C. G., Kim P. D., Eremin E. V., Patrin G. S.
Заглавие : Optically driven conductivity and magnetoresistance in a manganite-based tunnel structure
Коллективы : Russian Foundation for Basic Research [08-02-00259-a, 08-02-00397-a]; Division of Physical Sciences of the RAS; [2.4.2]
Место публикации : J. Phys. D. - 2009. - Vol. 42, Is. 20. - Ст.205009. - ISSN 0022-3727, DOI 10.1088/0022-3727/42/20/205009
Примечания : Cited References: 13. - This study was supported by the Russian Foundation for Basic Research (Projects Nos 08-02-00259-a and 08-02-00397-a) and the Division of Physical Sciences of the RAS, Programme 'Spin-dependent Effects in Solids and Spintronics' (Project No 2.4.2 of the Siberian Branch of the RAS).
Предметные рубрики: JUNCTIONS
Ключевые слова (''Своб.индексиров.''): conducting layers--current-in-plane geometry--dielectric layer--electron hole pairs--interband absorption--magnetic tunnel junction--magnetic tunnels--multilayer structures--optical radiations--photoinduced change--potential barriers--radiation power density--threshold characters--tunnel structures--electric resistance--lanthanum--light--magnetic field effects--magnetoelectronics--magnetoresistance--manganese compounds--oxide minerals--photovoltaic effects--semiconductor junctions--transport properties--vehicular tunnels--wind tunnels--tunnel junctions
Аннотация: In the multilayer structure, La(0.7)Sr(0.3)MnO(3)/depleted manganite layer/MnSi, the photovoltaic effect has been discovered. The depleted manganite layer in the structure is dielectric and serves as a potential barrier between the ferromagnetic conducting La(0.7)Sr(0.3)MnO(3) and MnSi layers by the formation of a magnetic tunnel junction. The photoinduced changes in the transport properties of the magnetic tunnel structure have been observed in the current-in-plane geometry. The changes are reversible and saturate at radiation power densities over 30 mW cm(-2). The photovoltaic effect has a threshold character: it reveals only at h nu 1.17 eV. Most likely, the effect of optical radiation is related to the formation of electron-hole pairs due to interband absorption of light in the dielectric layer. A photocurrent through the tunnel junctions separating the conducting layers causes a redistribution of the current channels between the conducting layers, which influences the conductivity and the magnetoresistance of the structure.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Morozov E. V., Shabanova O. V., Falaleev O. V.
Заглавие : MRI Comparative Study of Container Geometry Impact on the PMMA Spheres Sedimentation
Место публикации : Appl. Magn. Reson. - 2013. - Vol. 44, Is. 5. - P.619-636. - ISSN 0937-9347, DOI 10.1007/s00723-012-0432-8
Примечания : Cited References: 31
Предметные рубрики: OPAL PHOTONIC CRYSTALS
SUSPENSIONS
PARTICLES
VELOCITY
Аннотация: Nuclear magnetic resonance (NMR) imaging results are presented for the comparative study of sedimentation of the polymethylmethacrylate colloidal suspensions with spherical particle diameters of 475, 350 and 255 nm. The time evolution of the particle volume fraction in the sedimenting system, velocity of the fluid/suspension interface, interface broadening, and sediment growth velocity are measured against the system concentration as well as the container geometry. Using the experimental data the hindered settling function is evaluated. The influence of the container geometry on the parameters defining the hindered settling function in different approaches is evaluated for the first time. The limiting value of the particle diameter is estimated at which the container geometry has no impact any longer. This effect can be explained by the microscale structure persisting at low Peclet numbers. In addition, the influence of the container geometry on interface broadening and sediment formation for different particle diameters and volume fractions is studied. Spontaneous sediment packing induced by a modified container geometry has been found. NMR imaging has proven to be a highly efficient research tool for studying sedimentation at low Peclet numbers.
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