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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : LUKINYKH V. F., MYSLIVETS S. A., SLABKO V. V.
Заглавие : IMPULSE LASER SYSTEM ON GLASS WITH NEODYMIUM FOR THE STUDY OF NONLINEAR OPTICAL PHENOMENA IN GASES
Место публикации : Zhurnal Tek. Fiz.: MEZHDUNARODNAYA KNIGA, 1984. - Vol. 54, Is. 5. - P879-882. - ISSN 0044-4642
Примечания : Cited References: 7
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : VOROTINOV A. M., SABLINA K. A.
Заглавие : SPIN-GLASS STATE IN AMORPHOUS BI2CUO4
Место публикации : Solid State Commun.: PERGAMON-ELSEVIER SCIENCE LTD, 1993. - Vol. 87, Is. 3. - P209-211. - ISSN 0038-1098, DOI 10.1016/0038-1098(93)90477-5
Примечания : Cited References: 6
Предметные рубрики: RESONANCE
Аннотация: The magnetic susceptibility and magnetic resonance measurements of an amorphous compound Bi2CuO4 have been carried out. It was pointed out, that a part of Cu2+ ions stays in the paramagnetic state down to T=4,2 K. The magnitude of the effective exchange integral in amorphous Bi2CuO4 has been estimated. The magnetic resonance measurements revealed the existance of the magnetic phase transition to spin-glass state at T=100 K.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Feher A., Yyurkin I. M., Deich L. I., Orendac M., Turyanitsa I. D.
Заглавие : The comparative-analysis of some low-frequency vibrational-state density models of the amorphous materials - applied to the as2s3 glass
Коллективы : International Conference on Low Temperature Physics
Место публикации : Physica B/ International Conference on Low Temperature Physics (20 ; 1993 ; Aug. 04-11 ; Eugene, OR). - 1994. - Vol. 194. - P.395-396. - ISSN 0921-4526, DOI 10.1016/0921-4526(94)90527-4
Примечания : Cited References: 6
Предметные рубрики: SPECTRUM
Аннотация: The specific heat from 3K to 15K and the Raman spectra were measured on the As2S3 glass. The specific heat data were fitted using two different models of the vibrational state density, i.e. the phonon-fraction model and the model of lognormal distribution of frequencies. We have shown that the excess vibrational state density which governs the specific heat behaviour gives only a little contribution to the intensity of Raman scattering in the boson peak region.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sysoev A. M., Parshikov S. A., Zaitsev A. I., Zamkov A. V., Aleksandrov K. S.
Заглавие : Piezoelectric properties of glassceramic based on lithium tetraborate
Место публикации : Ferroelectrics. - 1996. - Vol. 186, Is. 1. - P.277-280. - ISSN 0015-0193, DOI 10.1080/00150199608218083
Примечания : Cited References: 4
Ключевые слова (''Своб.индексиров.''): ceramic materials--crystal growth--dielectric properties--electroacoustic transducers--glass--hydrophones--lithium compounds--single crystals--acoustoelectric transducer--glass ceramic--lithium tetraborate--microcomposite materials--piezoelectric materials
Аннотация: The preparation and study of a glassceramic based on lithium tetraborate was carried out. It was shown that due to favourable piezoelectric properties this material has good prospects for use as acoustoelectric transducer in devices such as hydrophones.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Val'kov V. V., Dzebisashvili D. M.
Заглавие : Magnetopolaron states of a spin-correlated antiferromagnet in the neighborhood of the spin-glass transition
Место публикации : Phys. Solid State: AMER INST PHYSICS, 1998. - Vol. 40, Is. 2. - P282-286. - ISSN 1063-7834, DOI 10.1134/1.1130293
Примечания : Cited References: 20
Предметные рубрики: OSCILLATIONS
CEAS
Аннотация: The problem of the spectrum of magnetopolaron states of a strongly correlated conducting canted antiferromagnet is solved. The approach used to study the spectrum is based on an atomic representation and a diagram technique for Hubbard operators. This approach makes it possible to include strong intra-ion interactions in a first-principles way, and to obtain the dispersion equation for the magnetopolaron spectrum for arbitrary values of the magnitude of the spin, temperature, and magnetic field. In the vicinity of the spin-flip transition an analytic expression is obtained for the spectrum of magnetopolaron states that goes beyond the framework of the quasiclassical approximation. (C) 1998 American Institute of Physics.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Potseluyko A. M., Edelman I. S., Zabluda V. N., Bolsunovskaya O. A., Zamkov A. V., Parshikov S. A., Zaytsev A. I.
Заглавие : Magnetooptic activity of f-d and f-f electron transitions in Pr3+ in the glass matrix LiB3O5
Место публикации : Physica B. - 2000. - Vol. 291, Is. 1-2. - P.89-96. - ISSN 0921-4526, DOI 10.1016/S0921-4526(99)01869-4
Примечания : Cited References: 17
Предметные рубрики: FARADAY-ROTATION
OXIDE GLASSES
Ключевые слова (''Своб.индексиров.''): faraday rotation--magnetooptic activity--praseodymium--electron transitions--faraday effect--light absorption--lithium compounds--praseodymium compounds--faraday rotation--transition wavelength--optical glass
Аннотация: The results of absorption, Faraday rotation and magnetic circular dichroism measurements for glasses with the composition of LiB3O5 + Pr2O3 are presented. The effective wavelength of the transition giving the main contribution to Faraday rotation in these glasses is determined. The contributions of several f-f transitions to Faraday rotation are separated and their magnetooptical activities are evaluated in comparison with the activity of the f-d transition. (C) 2000 Elsevier Science B.V. All rights reserved.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Edelman I. S., Ivantsov R., Vasiliev A., Stepanov S., Kornilova E., Zarubina T.
Заглавие : Superparamagnetic and ferrimagnetic nanoparticles in glass matrix
Место публикации : Physica B. - 2001. - Vol. 301, Is. 3-4. - P.203-211. - ISSN 0921-4526, DOI 10.1016/S0921-4526(01)00274-5
Примечания : Cited References: 9
Предметные рубрики: MAGNETIC-PROPERTIES
PARTICLES
FILMS
Ключевые слова (''Своб.индексиров.''): magnetic nanoparticles--faraday rotation--faraday rotation--magnetic nanoparticles--crystal structure--faraday effect--ferrimagnetic materials--glass--particle size analysis--superparamagnetism--x ray diffraction analysis--amorphous glass matrices--faraday rotations--nanostructured materials
Аннотация: Faraday rotation (FR) spectral, field, and temperature dependencies in oxide glasses with small additions of paramagnetic elements are investigated. Formation of ferrite nanoparticles in amorphous glass matrices is revealed by X-ray diffraction. Particles have crystal structure similar to spinel structure, their dimensions are about 10-24 nm. The FR field dependencies are typical for ferrimagnetic or superparamagnetic substances depending on particle size. Strong FR increase at the samples cooling (more than twice for some samples) in the temperature interval 105-273 K is observed. (C) 2001 Elsevier Science B.V. All rights reserved.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Petrakovskii G. A., Aleksandrov K. S., Aplesnin S. S., Roessli B., Semadeni F., Amato A., Baines C., Bartolome J., Evangelisti M.
Заглавие : Spin-glass state in CuGa2O4
Место публикации : Phys. Rev. B. - 2001. - Vol. 63, Is. 18. - Ст.184425. - ISSN 0163-1829, DOI 10.1103/PhysRevB.63.184425
Примечания : Cited References: 28
Предметные рубрики: TRANSITION
Ключевые слова (''Своб.индексиров.''): copper--gallium--glass--oxygen--acceleration--article--magnetism--measurement--molecular dynamics--phase transition
Аннотация: Magnetic susceptibility, magnetization, specific-heat, and positive muon spin relaxation (?SR) measurements have been used to characterize the magnetic ground state of the spinel compound CuGa2O4. We observe a spin-glass transition of the S = 1/2 Cu2+ spins below Tf = 2.5 K characterized by a cusp in the susceptibility curve which is suppressed when a magnetic field is applied. We show that the magnetization of CuGa2O4 depends on the magnetic history of the sample. Well below Tf, the muon signal resembles the dynamical Kubo-Toyabe expression reflecting that the spin freezing process in CuGa2O4 results in a Gaussian distribution of the magnetic moments. By means of Monte Carlo simulations, we obtain the relevant exchange integrals between the Cu2+ spins in this compound.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Patrin G. S., Vas'kovskii V. O., Velikanov D. A., Svalov A. V., Panova M. A.
Заглавие : Spin-glass-like behavior of low field magnetisation in multilayer (Gd/Si/Co/Si)(n) films
Разночтения заглавия :авие SCOPUS: Spin-glass-like behavior of low field magnetisation in multilayer (Gd/Si/Co/Si)n films
Место публикации : Phys. Lett. A. - 2003. - Vol. 309, Is. 1-2. - P.155-159. - ISSN 0375-9601, DOI 10.1016/S0375-9601(03)00169-5
Примечания : Cited References: 13
Предметные рубрики: BIQUADRATIC EXCHANGE
Ключевые слова (''Своб.индексиров.''): cobalt--gadolinium--glass--silicon--silicon derivative--acceleration--article--film--magnetic field--magnetism--molecular dynamics--molecular interaction
Аннотация: The results of experimental investigations of magnetic properties of multilayer (Gd/Si/Co/Si)(n) films in low magnetic fields are represented. The spin-glass-like behavior of magnetization is found. The role of biquadratic exchange coupling in a forming of magnetic state of system is discussed. (C) 2003 Elsevier Science B.V. All rights reserved.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kliava J., Edelman I. S., Potseluyko A. M., Petrakovskaja E. A., Berger R., Bruckental I., Yeshurun Y., Malakhovskii A. V., Zarubina Y. V.
Заглавие : Magnetic and optical properties and electron paramagnetic resonance of gadolinium-containing oxide glasses
Место публикации : J. Phys.: Condens. Matter: IOP PUBLISHING LTD, 2003. - Vol. 15, Is. 40. - P6671-6681. - ISSN 0953-8984, DOI 10.1088/0953-8984/15/40/005
Примечания : Cited References: 30
Предметные рубрики: ABSORPTION-SPECTRA
FARADAY-ROTATION
SPIN-RESONANCE
IONS
GD3+
SPECTROSCOPY
BEHAVIOR
GD-3
Ключевые слова (''Своб.индексиров.''): doping (additives)--electronic structure--glass--lanthanum compounds--light absorption--magnetic susceptibility--oxides--paramagnetic resonance--positive ions--rate constants--substitution reactions--absorption band--gadolinium containing oxide glasses--positive weiss constants--gadolinium compounds
Аннотация: Magnetic susceptibility, electron paramagnetic resonance (EPR) and optical absorption have been studied in a glass system 20La(2)O(3)-22Al(2)O(3)-23B(2)O(3)-35(SiO2 + GeO2) with a part of La2O3 substituted by Gd2O3 in different concentrations. Positive Weiss constants have been found in more heavily doped glasses and ascribed to clustering of Gd3+ ions. Computer simulations of the EPR spectra show that the short-range ordering in the environment of the Gd3+ ions is well preserved. The relative distribution widths of the ligand coordinates are less than 2%. In the more heavily doped glasses the EPR spectra are superpositions of signals arising from isolated ions and ferromagnetic clusters. The increase of Gd3+ concentration is shown to change substantially the strong optical absorption edge while only small changes of f-f absorption band characteristics are observed. This difference is associated with the different effect of the Gd ion clustering on the mechanisms of the strong absorption in the ultraviolet region and the f-f absorption.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vasil'eva I. G., Dovlitova L. S., Zajkovskij V. I., Malakhov V. V., Edel'man I. S., Stepanov A. S., Aleksandrov K. S.
Заглавие : Real composition and structure of manganese ferrite nanoparticles dispersed in the K-Al-B-O glasses
Место публикации : Dokl. Akad. Nauk. - 2005. - Vol. 401, Is. 3. - P.349-352. - ISSN 0869-5652
Ключевые слова (''Своб.индексиров.''): aluminum--boron compounds--ferrite--manganese--nanostructured materials--particles (particulate matter)--structure (composition)--borate glasses--exchange interaction--glass
Аннотация: For the first time the problem of determining real composition and structure of manganese ferrite nanoparticles dispersed borate glasses is solved using differentiating dissolution and high-resolution X-ray electron microscopy techniques. For the first time the nanosize effect of aluminum incorporation in manganese ferrite composition is experimentally shown, thus directly confirming the hypothesis of Al participation in exchange interaction between paramagnetic Fe and Mn ions as diamagnetic diluter.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kliava J., Malakhovskii A. V., Edelman I. S., Potseluyko A. M., Petrakovskaja E. A., Melnikova S.V., Zarubina T. V., Petrovskii G., Bruckental Y., Yeshurun Y.
Заглавие : Unusual magnetic transitions and nature of magnetic resonance spectra in oxide glasses containing gadolinium
Место публикации : Phys. Rev. B: AMER PHYSICAL SOC, 2005. - Vol. 71, Is. 10. - Ст.104406. - ISSN 1098-0121, DOI 10.1103/PhysRevB.71.104406
Примечания : Cited References: 40
Предметные рубрики: ELECTRON-PARAMAGNETIC-RESONANCE
BORATE GLASSES
IONS
BEHAVIOR
GD3+
SPECTROSCOPY
SYSTEMS
GD-3+
FIELD
SHAPE
Ключевые слова (''Своб.индексиров.''): gadolinium--glass--lanthanide--oxide--anisotropy--article--chemical structure--concentration response--electron spin resonance--energy--magnetism--molecular physics--nanoparticle--phase transition--refraction index--temperature sensitivity
Аннотация: Magnetic susceptibility, electron paramagnetic resonance (EPR), and optical properties have been studied in a glass system {20La(2)O(3)-22Al(2)O(3)-23B(2)O(3)-35(SiO2+GeO2)} with a part of La2O3 substituted by Gd2O3 in different concentrations. Positive Weiss constants have been found in the more heavily doped glasses and ascribed to clustering of Gd3+ ions. Two magnetic phase transitions at 55 and 12 K were detected and ascribed, respectively, to ferromagnetic and antiferromagnetic clusters containing Gd ions. The overall shape of the EPR spectra shows the presence of clustering at the higher Gd contents. At low temperatures the cluster-related resonance signal is altered in shape, indicating an onset of magnetic anisotropy field. This signal is convincingly fitted to superparamagnetic resonance arising from ferromagnetic nanoparticles. The clustering, depending on the Gd concentration, correlates with a significant shift to lower energies of the strong optical absorption band edge, ascribed to a charge transfer transition between Gd ions. A nonmonotonous change of refractive index with the increase of the Gd content indicates changes in the glass matrix and in Gd cluster structure.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vasilyeva I. G., Dovlitova L. S., Zaikovskii V. I., Malakhov V. V., Edel'man I. S., Stepanov A. S., Aleksandrov K. S.
Заглавие : Actual composition and structure of manganese ferrite nanoparticles dispersed in the borate glass matrix
Место публикации : Doklady Chemistry. - 2005. - Vol. 401, Is. 1-3. - P.47-50. - ISSN 0012-5008, DOI 10.1007/s10631-005-0029-y
Ключевые слова (''Своб.индексиров.''): boric acid--ferrite--glass--manganese derivative--analytic method--article--chemical composition--chemical structure--nanoparticle--stoichiometry--structure analysis--transmission electron microscopy--x ray analysis
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrovsky A. S., Krylov A. S., Potseluyko A. M., Seredkin V. A., Zaitsev A. I., Zamkov A. V.
Заглавие : Pulsed laser deposition of europium borate glass films and their optical and magneto-optical properties
Коллективы : International Conference on Lasers, Applications, and Technologies
Место публикации : Laser-Assisted Micro- and Nanotechnologies. Proceedings of SPIE: [11-15 May 2005]/ ed. V. I. Konov [et al.]: SPIE-Int. Soc. Optical Engineering, 2006. - P.61610A
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Petrakovskii G. A., Bezmaternykh L. N., Gudim I. A., Bayukov O. A., Vorotynov A. M., Bovina A. F., Szymczak R., Baran M., Ritter C.
Заглавие : Spin glass state in crystals of barium ferrigermanate Ba2Fe2GeO7
Разночтения заглавия :авие SCOPUS: Spin glass state in crystals of barium ferrigermanate Ba2Fe 2GeO7
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2006. - Vol. 48, Is. 10. - P1906-1908. - ISSN 1063-7834, DOI 10.1134/S1063783406100155
Примечания : Cited References: 5
Аннотация: The temperature dependence of the magnetization and elastic neutron scattering spectra of Ba2Fe2GeO7 barium ferrigermanate polycrystals are studied. The magnetization is found to depend on the magnetic prehistory of a Ba2Fe2GeO7 sample below T = 8 K. Analysis of the neutron scattering spectra does not reveal long-range magnetic order down to 2 K. Our experimental data indicate the existence of a spin glass state in Ba2Fe2GeO7 polycrystals.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kliava J., Malakhovskii A. V., Edelman I. S., Potseluyko A. M., Petrakovskaja E. A., Bruckental I., Yeshurun Y., Zarubina T.
Заглавие : Unusual magnetic phase transitions in Gd3+ clusters in multicomponent oxide glasses
Разночтения заглавия :авие SCOPUS: Unusual magnetic phase transitions in Gd 3+ clusters in multicomponent oxide glasses
Место публикации : J. Supercond. Nov. Magn.: SPRINGER, 2007. - Vol. 20, Is. 2. - P149-153. - ISSN 1557-1939, DOI 10.1007/s10948-006-0116-4
Примечания : Cited References: 7
Предметные рубрики: GADOLINIUM
RESONANCE
Ключевые слова (''Своб.индексиров.''): oxide glasses--gadolinium--magnetic clusters--superparamagnetism--gadolinium--magnetic clusters--oxide glasses--superparamagnetism--magnetic clusters--magnetic phase transitions--oxide glasses--weiss constant--antiferromagnetic materials--ferromagnetic materials--gadolinium--magnetic anisotropy--magnetic susceptibility--paramagnetic resonance--phase transitions--positive ions--superparamagnetism--glass
Аннотация: Magnetic susceptibility, EPR and optical properties have been studied in a glass system {20La(2)O(3) - 22Al(2)O(3) - 23B(2)O(3) - 35(SiO2 + GeO2)} with a part of La2O3 substituted by Gd2O3 in different concentrations. Positive Weiss constants have been found in more heavily doped glasses; two magnetic transitions at 55 and 12 K have been detected and ascribed, respectively, to ferromagnetic and antiferromagnetic clusters of Gd3+ ions. The EPR spectra confirm the clustering at higher Gd contents. At low temperatures the cluster-related resonance indicates an onset of magnetic anisotropy. The clustering, depending on the Gd concentration, correlates with a shift to lower energies of the strong optical absorption band edge.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Isachenko V. A., Sukhachev A. L., Potseluyko A. M., Zabluda V. N., Zarubina T. V., Edelman I. S.
Заглавие : Magneto-optical properties of Dy3+ in oxide glasses: The origin of the magneto-optical activity of f-f transitions and its anomalous temperature dependence
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007. - Vol. 49, Is. 4. - P701-707. - ISSN 1063-7834, DOI 10.1134/S1063783407040178
Примечания : Cited References: 28
Предметные рубрики: MAGNETIC CIRCULAR-DICHROISM
FLUOROZIRCONATE ZBLAN GLASS
OPTICAL-ABSORPTION SPECTRA
DOPED SODA GLASS
SPECTROSCOPIC PROPERTIES
FLUOROBORATE GLASSES
LITHIUM BORATE
IONS
PR3+
GADOLINIUM
Аннотация: The temperature dependence of the absorption spectra and magnetic circular dichroism due to f-f transitions from the H-6(15/2) to F-6 (5/2) and (6)(F (7/2) + H (5/2)) states in the Dy3+ ion in (Dy2O3-P2O5-SiO2-GeO2) and (Dy2O3-La2O3-Al2O3-B2O3-SiO2-GeO2) glasses and the temperature dependence of the Faraday effect were studied. The temperature dependence of the Faraday effect caused by f-d transitions was found to differ from that of the magnetic circular dichroism due to f-f transitions. It was shown that f-f transitions occur preferentially in Dy3+ ions associated into clusters. The origin of the paramagnetic magneto-optical activity of f-f transitions was analyzed. It was shown that the contributions to this activity can differ in value and sign and that the ratio between these contributions depends on the transition type. In some cases, this difference results in an anomalous temperature dependence of the magneto-optical activity.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanov Y. N., Aleksandrova I. P., Sukhovsky A. A., Baranov A. I.
Заглавие : H-2 NMR investigation of the transition to the proton glass state in the CS5H3(SO4)(4)center dot 0.5H(2)O crystal
Разночтения заглавия :авие SCOPUS: 2H NMR investigation of the transition to the proton glass state in the Cs5H3(SO4)4В·0.5H 2O crystal
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007. - Vol. 49, Is. 6. - P1142-1148. - ISSN 1063-7834, DOI 10.1134/S1063783407060200
Примечания : Cited References: 19
Предметные рубрики: DIELECTRIC-RELAXATION
MAGNETIC-RESONANCE
PHASES
Аннотация: A crystal of the CS5H3(SO4)(4) (.) xH(2)O (x approximate to 0.5) (PCHS) compound, which belongs to the family of proton conductors with a complex system of hydrogen bonds, is investigated by H-2 NMR spectroscopy. The temperature and orientation dependences of the H-2 NMR spectra are measured and analyzed. It is established that, upon transition to the glassy phase at the temperature T-g = 260 K, the parameters characterizing the proton exchange between positions in hydrogen bonds remain unchanged to within the limits of experimental error. The protons in the two-dimensional network of hydrogen bonds in the (001) plane are dynamically disordered over possible positions down to temperatures considerably lower than the glass transition point T-g. However, water molecules are fixed at particular structural positions in the phase transition range. In PCHS crystals with a nonstoichiometric water content, this circumstance can be responsible for the frustration that leads to the formation of the glassy state.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kliava J., Edelman I. S., Ivanova O. S., Ivantsov R. D., Bayukov O. A., Petrakovskaja E. A., Zaikovskiy V., Bruckental I., Yeshurun Y., Stepanov S.
Заглавие : Formation and evolution of magnetic nanoparticles in borate glass simultaneously doped with Fe and Mn oxides
Коллективы :
Место публикации : J. Appl. Phys.: AMER INST PHYSICS, 2008. - Vol. 104, Is. 10. - Ст.103917. - ISSN 0021-8979, DOI 10.1063/1.3021289
Примечания : Cited References: 37. - A financial support from the Russian Foundation for Basic Research (RFBR)-CNRS (Grant No. 07-02-92174) is highly appreciated. R. Ivantsov is grateful to the Russian Science Support Foundation. Y. Yeshurun acknowledges the support of the Israel Scienc Foundation (ISF).
Предметные рубрики: COBALT FERRITE PARTICLES
SUPERPARAMAGNETIC RESONANCE
GAMMA-FE2O3 NANOPARTICLES
MATRIX
SIZE
SYSTEMS
Ключевые слова (''Своб.индексиров.''): aluminium compounds--borate glasses--coercive force--faraday effect--heat treatment--iron compounds--magnetic hysteresis--magnetic particles--magnetic susceptibility--manganese compounds--mossbauer effect--nanoparticles--paramagnetic materials--potassium compounds--remanence--superparamagnetism--transmission electron microscopy--x-ray chemical analysis--atomic spectroscopy--auger electron spectroscopy--crystal structure--electric relays--electronic medical equipment--ferrite--ferrites--glass--heat treatment--hysteresis--hysteresis loops--magnetic properties--magnetic resonance measurement--magnetic susceptibility--magnetism--manganese--manganese compounds--molybdenum--nanoparticles--optical properties--ozone water treatment--polydispersity--superparamagnetism--borate glasses--concentration ratios--electron magnetic resonances--emr spectrums--experimental techniques--faraday rotations--glass compositions--glass matrixes--glass preparations--magnetic measurements--magnetic nano particles--magnetic orders--magnetically ordered systems--magneto-optical properties--manganese ferrites--mean diameters--mn oxides--phase states--polydisperse nanoparticles--remnant magnetizations--ssbauer spectroscopies--superparamagnetic--superparamagnetic states--thermal treatments--variable temperatures--magnetic materials
Аннотация: Evolution of the phase state of paramagnetic additions at various stages of synthesis and subsequent thermal treatment of glasses of the system Al(2)O(3)-K(2)O-B(2)O(3) simultaneously doped with Fe(2)O(3) and MnO is studied by means of a combination of experimental techniques: Faraday rotation (FR), electron magnetic resonance (EMR), transmission electron microscopy (TEM), Mossbauer spectroscopy, and magnetic measurements. Both FR and EMR show that magnetically ordered clusters occur already at the first stage of the glass preparation. In particular, for the ratio of the Fe and Mn oxides in the charge close to 3:2, fine magnetic nanoparticles are formed with characteristics similar to those of manganese ferrite. By computer simulating the EMR spectra at variable temperatures, a superparamagnetic nature of these nanoparticles is confirmed and their mean diameter is estimated as approximately 3.2 nm. In the thermally treated glasses larger magnetic nanoparticles are formed, giving rise to FR spectra, characteristic of magnetically ordered systems, and the EMR spectra different from those in as-prepared glasses but also showing superparamagnetic narrowing. The Mossbauer spectroscopy corroborates the manganese ferrite structure of the nanoparticles and indicates their coexistence in the ferrimagnetic and superparamagnetic states. The TEM shows the presence of polydisperse nanoparticles on the background of the glass matrix, and electron diffraction of a selected region containing larger particles indicates a crystal structure close to that of MnFe(2)O(4). Energy-dispersive atomic x-ray spectra confirm that the major part of Fe and Mn introduced to the glass composition is gathered in the particles, with the concentration ratio close to 2:1, characteristic of bulk MnFe(2)O(4). Magnetic hysteresis loops of samples subjected to an additional thermal treatment demonstrate a strong increase in the coercive force, remnant magnetization, and high-field magnetic susceptibility with temperature decrease. The consistent results obtained using various techniques demonstrate that the formation of nanoparticles with characteristics close to those of MnFe(2)O(4) confers to these glasses magnetic and magneto-optical properties typical of substances possessing magnetic order.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Edelman I. S.
Заглавие : Tranparent glass-ceramics containing nanoparticles of transition and rare earth elements
Коллективы : "Trends in Nanomechanics and Nanoengineering", workshop, Сибирский федеральный университет, Институт физики им. Л.В. Киренского Сибирского отделения РАН
Место публикации : Workshop "Trends in Nanomechanics and Nanoengineering": book of abstracts/ предс. сем. K. S. Aleksandrov ; зам. предс. сем.: G. S. Patrin, S. G. Ovchinnikov ; чл. лок. ком.: N. N. Kosyrev, A. S. Fedorov [et al]. - 2009. - P.25
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