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1.

Вид документа : Однотомное издание
Шифр издания :
Заглавие : International workshop on actual problems of condensed matter physics : Program. Book of abstracts
Выходные данные : Krasnoyarsk, 2017
Колич.характеристики :30 с
Коллективы : Federal Research Center KSC SB RAS, Kirensky Institute of Physics, Siberian Federal Univercity, International Workshop on Actual Problems of Condensed Matter Physics (27 Mar. - 1 Apr. 2017; Krasnoyarsk/ Cheremushki) :
Содержание : Magnetic and transport properties of the epitaxial Fe3Si film on a Si substrate/ I. A. Bondarev. The magnetic anisotropy of the Fe and Fe(1-x)Si(x) thin films depend on/ I. A. Yakovlev [и др.]. Inverted opals as the Josephson networks of weak links/ S. I. Popkov [и др.]. Electronic structure and Fermi surface within the cluster perturbation theory in X-operators representation/ S. Nikolaev, V. I. Kuz'min, S. G. Ovchinnikov. DFT investigation of electronic and optical magnetic properties of one dimensional transition metal halide structuresTmHaI3/ A. S. Fedorov [и др.]. Effect of interatomic exchange interaction on spin crossover and Mott-Hubbard transition under high pressure and the physical properties of the low Earth’s mantle/ S. G. Ovchinnikov [и др.]. Extremely high magnetic-field sensitivity of charge transport in the Mn/SiO2/p-Si hybrid structure/ I. A. Tarasov [и др.]. Marnetic-field sensitivity of charge transport in silicon-based hybrid structures/ N. V. Volkov [et al.]. Fabrication of multi-terminal planar devices based on epitaxial Fe1-xSix films grown on Si(111)/ A. V. Lukyanenko, A. S. Tarasov, I. A. Tarasov [et al.] ; A. V. Luyanenko [и др.]. Magnetic field-driven lateral photovoltaic effect in the Fe/SiO2/p-Si hibrid structure with the Scottky barrier/ M. V. Rautskii [и др.]. Small angle X-ray scattering and atomic structure of aptamer biomolecules/ R. Moryachkov [и др.]. Iron silicides and pure iron epitaxial and highly-textured nanostructures on silicon: growth and their physical properties/ I. A. Tarasov [и др.]. Magnetic nanoparticles and DNA-aptamers conjugates for diagnostics and therapy of cancer/ A. E. Sokolov [и др.]. The microscopic origin of ferromagnetism in Fe silicides/ I. S. Sandalov [и др.].
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2.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Stolyar S. V., Kryukova O. V., Yaroslavtsev R. N., Latyshev N. V.
Заглавие : Influence of Magnetic Nanoparticles on Cells of Ehrlich Ascites Carcinoma
Коллективы : Annual conference on мagnetism and мagnetic мaterials
Место публикации : 65th Annual conference on мagnetism and мagnetic мaterials (MMM-2020): abstract book. - 2020. - Ст.Q5-07. - P.530
Примечания : Cited References: 1
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3.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Komogortsev S. V., Balaev D. A., Krasikov A. A., Stolyar S. V., Yaroslavtsev R. N., Iskhakov R. S.
Заглавие : Magnetic Hysteresis of Blocked Ferrihydrite Nanoparticles
Коллективы : Annual conference on мagnetism and мagnetic мaterials
Место публикации : 65th Annual conference on мagnetism and мagnetic мaterials (MMM-2020): abstract book. - 2020. - Ст.C4-02. - P.74
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Komina A. V., Yaroslavtsev R. N., Gerasimova Yu. V., Stolyar S. V., Olkhovsky I. A., Bairmani M. S.
Заглавие : Magnetic Nanoparticles for Extracting DNA from Blood Cells
Место публикации : Bull. Russ. Acad. Sci. Phys. - 2020. - Vol. 84, Is. 11. - P.1362-1365. - ISSN 10628738 (ISSN), DOI 10.3103/S1062873820110155
Примечания : Cited References: 15
Аннотация: A technique for extracting DNA from blood cells using magnetic particles offers the advantage of saving time and prospects of automating the extraction process. A way of obtaining magnetic iron nanoparticles for extracting DNA from blood cells is developed. Magnetic nanoparticles with characteristics suitable for extracting genomic DNA from leukocytes are obtained and investigated.
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5.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Pugachevskii M.A., Chibisov A.N., Fedorov A. S.
Заглавие : Theoretical and experimental studies of structural defects in CeO2 nanoparticles
Коллективы : Asian School-Conference on Physics and Technology of Nanostructured Materials, Азиатская школа-конференция по физике и технологии наноструктурированных материалов
Место публикации : The Fifth Asian School-Conference on Physics and Technology of Nanostructured Materials: Proceedings. - VLadivostok: Dalnauka Publishing, 2020. - Ст.I.30.06o. - P.45. - ISBN 978-5-8044-1698-1
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6.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Sokolov A. Е., Kurilova A. V., Svetlichniy V. A., Velikanov D. A., Sherepa A. V., Volochaev M. N., Goncharova D. A., Shabalina A. V.
Заглавие : Obtaining and properties of biomagnetic nanoconjugates based on DNA aptamers and magnetic nanoparticles for magnetodynamic cell therapy
Коллективы : Asian School-Conference on Physics and Technology of Nanostructured Materials, Азиатская школа-конференция по физике и технологии наноструктурированных материалов
Место публикации : The Fifth Asian School-Conference on Physics and Technology of Nanostructured Materials: Proceedings. - VLadivostok: Dalnauka Publishing, 2020. - Ст.V.01.17o. - P.147. - ISBN 978-5-8044-1698-1
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7.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Fedorov A. S., Krasnov P.O., Visotin M. A., Ågren H.
Заглавие : Study of plasmons and thermoelectric properties of nanoparticles connected by thin conductive bridges
Коллективы : Asian School-Conference on Physics and Technology of Nanostructured Materials, Азиатская школа-конференция по физике и технологии наноструктурированных материалов
Место публикации : The Fifth Asian School-Conference on Physics and Technology of Nanostructured Materials: Proceedings. - VLadivostok: Dalnauka Publishing, 2020. - Ст.VI.30.03o. - P.168. - ISBN 978-5-8044-1698-1
Примечания : This study was supported by the Russian Science Foundation, project no. 16-13-00060.
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8.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Kurilova A. V., Sokolov A. Е., Sherepa A. V., Volochaev M. N., Velikanov D. A., Goncharova D. A., Shabalina A. V., Svetlichnyi V.
Заглавие : Magnetic and optical properties of nanoparticles of iron and nickel decorated with gold and the possibility of their medical use
Коллективы : Pulsed Lasers and Laser Applications, International Conference
Место публикации : Pulsed Lasers and Laser Applications, International Conference (14 ; 2019 ; 15-20 Sept. ; Tomsk). Pulsed lasers and laser applications (AMPL-2019): abstracts of XIV Int. conf. - 2019. - Ст.Y-30. - P.30. - ISBN 978-5-93629-634-5
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9.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Sokolov A. Е., Kurilova A. V., Sherepa A. V., Volochaev M. N., Velikanov D. A., Goncharova D. A., Shabalina A. V., Svetlichnyi V.
Заглавие : Magneto-optical properties of the iron oxide nanoparticles obtained by laser ablation
Коллективы : Pulsed Lasers and Laser Applications, International Conference
Место публикации : Pulsed lasers and laser applications (AMPL-2019): abstracts of XIV Int. conf. - 2019. - Ст.B-12. - P.61-62. - ISBN 978-5-93629-634-5
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stolyar S. V., Kryukova O. V., Yaroslavtsev R. N., Bayukov O. A., Knyazev Yu. V., Gerasimova Yu. V., Pyankov V. F., Latyshev N. V., Shestakov N. P.
Заглавие : Influence of magnetic nanoparticles on cells of Ehrlich ascites carcinoma
Место публикации : AIP Adv. - 2021. - Vol. 11, Is. 1. - Ст.015019. - ISSN 21583226 (ISSN), DOI 10.1063/9.0000165
Примечания : Cited References: 22. - The electron microscopy and magnetic resonance study was carried out on the equipment of the Krasnoyarsk Territorial Center for Collective Use, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences. This work was supported by the Council of the President of the Russian Federation for State Support of Young Scientists and Leading Scientific Schools (project no. MK-1263.2020.3). The research was funded by RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, project number 20-42-242902
Аннотация: The effect of magnetic nanoparticles coated with arabinogalactan on the viability of Ehrlich ascites carcinoma (EAC) cells was studied. The nanoparticles were studied by transmission electron microscopy, Mossbauer spectroscopy, IR spectroscopy, and ferromagnetic resonance. A correlation between the proportion of dead EAC cells in suspension and the intensity of the EPR signal of dinitrosyl iron complexes was found. This result may be due to the presence of NO molecules.
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11.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Denissenko P., Denisenko V. V., Denisov I., Kantsler V., Kolovskaya O. S., Lapin I. N., Sokolov A. Е., Svetlichnyi V., Zabluda V. N., Zamay S. S., Kichkailo A.S.
Заглавие : Magnetic sorting of tumor cells with attached magnetic nanoparticles in a microchannel
Коллективы : Aptamers in Russia, international conference
Место публикации : Aptamers in Russia, international conference (1 ; 2019 ; Aug. 27-30 ; Krasnoyarsk). Molecular Therapy - Nucleic Acids: book of abstracts of the 1st Int. conf. "Aptamers in Russia 2019". - 2019. - Vol. 17, Suppl. 1. - P.14
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stolyar S. V., Yaroslavtsev R. N., Ladygina V. P., Balaev D. A., Pankrats A. I., Iskhakov R. S.
Заглавие : Collective Spin Glass State in Nanoscale Particles of Ferrihydrite
Коллективы : International Symposium “Nanostructures: Physics and Technology”
Место публикации : Semiconductors. - 2020. - Vol. 54, Is. 12. - P.1710-1712. - DOI 10.1134/S1063782620120362
Примечания : Cited References: 16. - This work was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory, the Krasnoyarsk Regional Fund for the Support of Scientific and Technical Activities (project no. 19-42-240012 r_a “Magnetic resonance in ferrihydrite nanoparticles: Effects associated with the “core–shell” structure). This work was supported by a grant from the President of the Russian Federation for state support of young Russian scientists – candidates of sciences no. MK-1263.2020.3
Аннотация: Ferromagnetic resonance was used to study three types of ferrihydrite nanoparticles: nanoparticles formed as a result of the cultivation of microorganisms Klebsiella oxytoca; chemically prepared ferrihydrite nanoparticles; chemically prepared ferrihydrite nanoparticles doped with Cu. It is established from the ferromagnetic resonance data that the frequency-field dependence (in the temperature range ТP ‹ T ‹ T*) is described by the expression: 2πν/γ ⁼ НR + HA(T = 0)(1 – T/Т*), where γ is the gyromagnetic ratio, HR is the resonance field. The induced anisotropy HA is due to the spin-glass state of the near-surface regions. TP temperature characterizes the energy of the interparticle interaction of nanoparticles.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stolyar S. V., Ladygina V. P., Boldyreva A. V., Kolenchukova O. A., Vorotynov A. M., Bairmani M. S., Yaroslavtsev R. N., Iskhakov R. S.
Заглавие : Synthesis, Properties, and in vivo Testing of Biogenic Ferrihydrite Nanoparticles
Место публикации : Bull. Russ. Acad. Sci. Phys. - 2020. - Vol. 84, Is. 11. - P.1366-1369. - ISSN 10628738 (ISSN), DOI 10.3103/S106287382011026X
Примечания : Cited References: 12. - The study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk krai, the Krasnoyarsk Regional Fund for the Support of Scientific and Technical Activities (project no. 19-42-240012 r_a “Magnetic Resonance in Ferrihydrite Nanoparticles: Effects Associated with the Core–Shell Structure”), and the grant of the President of the Russian Federation for state support of young Russian scientists—Candidates of sciences no. MK-1263.2020.3
Аннотация: A sol containing biogenic ferrihydrite nanoparticles is obtained by cultivating Klebsiella oxytoca microorganisms. Data on the physical properties of the biogenic ferrihydrite and its effect on the organism of laboratory animals are obtained using a model of experimental hemolytic anemia, according to indicators of the functional activity of erythrocytes and morphological descriptions of organs.
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14.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Sokolov A. Е., Zabluda V. N., Sherepa A. V., Knyazev Yu. V., Volochaev M. N., Kurilina A., Velikanov D. A., Goncharova D. A., Shabalina A., Svetlichnyi V.
Заглавие : Magnetic properties of iron oxide nanoparticles to create aptamer bionanoconjugates
Коллективы : Aptamers in Russia, international conference
Место публикации : Aptamers in Russia, international conference (1 ; 2019 ; Aug. 27-30 ; Krasnoyarsk). Molecular Therapy - Nucleic Acids: book of abstracts of the 1st Int. conf. "Aptamers in Russia 2019". - 2019. - Vol. 17, Suppl. 1. - P.12
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Knyazev Yu. V., Balaev D. A., Stolyar S. V., Bayukov O. A., Yaroslavtsev R. N., Ladygina V. P., Velikanov D. A., Iskhakov R. S.
Заглавие : Magnetic anisotropy and core-shell structure origin of the biogenic ferrihydrite nanoparticles
Место публикации : J. Alloys Compd. - 2021. - Vol. 851. - Ст.156753. - ISSN 09258388 (ISSN), DOI 10.1016/j.jallcom.2020.156753
Примечания : Cited References: 82. - The electron microscopy study was carried out on the equipment of the Krasnoyarsk Territorial Center for Collective Use, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences. This study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory, and the Krasnoyarsk Territorial Foundation for Support of Scientific and R & D Activities, project no. 19-42-240012 p-a “Magnetic Resonance in Ferrihydrite Nanoparticles: Effects Related to the Core–Shell Structure”
Аннотация: Ferrihydrite is a low-crystalline nanoscale matter. The uncompensated magnetic moment of the ferrihydrite caused by the antiferromagnetic ordering of the magnetic moments of iron atoms and leads to the magnetic properties very similar to those of ferro- and ferrimagnetic nanoparticles. In this study, we investigated the biogenic ferrihydrite nanoparticles with the narrow size distribution and an average diameter of ≈2 nm obtained by the bacteria life cycle. The features caused by the surface effects and the inhomogeneous structure of ferrihydrite have been examined in the temperature range of 4–300 K using Mossbauer spectroscopy and magnetometry. Based on the Mossbauer data, we identified the superparamagnetic blocking temperature at the temperature of 30 K for the largest ferryhidrite particles. We established that the exceptional magnetic anisotropy of ferrihydrite (KV=1.2∙105 erg/cm3 and KS=0.1 erg/cm2) is reached because of the highly developed ferrihydrite nanoparticles’ surface. According to the Mossbauer data, we propose a core-shell structural model of the biogenic ferrihydrite particles. We found that the size of the dense core depends on the particle size. The well-crystallized core is formed only for nanoparticles larger than ≈2 nm, whereas smaller particles consist entirely of a matter with a lower density of iron atoms.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Воробьев С. А., Лихацкий М. Н., Романченко А. С., Иваненко Т. Ю., Машарова Д. А., Волочаев, Михаил Николаевич, Михлин Ю. Л.
Заглавие : Влияние реакционных условий на размер наночастиц серебра в концентрированных золях Carey Lea
Коллективы : RUSSIAN SCIENCE FOUNDATIONRussian Science Foundation (RSF) [18-73-00142]
Место публикации : Журн. СФУ. Химия. - 2020. - Т. 13, № 3. - С. 372-384. - ISSN 1998-2836, DOI 10.17516/1998-2836-0190; J. Sib. Fed. Univ. Chem. - ISSN 2313-6049(eISSN)
Примечания : Библиогр.: 34. - Работа выполнена при финансовой поддержке Российского научного фонда, грант No 18-73-00142
Предметные рубрики: AG NANOPARTICLES
CITRATE
AGGREGATION
SURFACE
STABILITY
KINETICS
Аннотация: В данной работе был изучен процесс восстановления растворов Ag (I) цитратными комплексами Fe (II), который позволяет получать наночастицы серебра с высокой стабильностью и концентрацией более 60 г/л. В ходе работы было установлено влияние скорости введения, скорости перемешивания, концентрации реагентов, рН среды и некоторых постсинтетических операций на средний размер наночастиц. Показано, что снижение концентрации Ag (I) и повышение концентрации стабилизатора, доведение рН реакционной среды до 7 позволяют получать наиболее мелкие и однородные частицы. В результате были найдены оптимальные условия, которые дали возможность уменьшить размер частиц и вместе с тем снизить концентрацию реактивов на 33 %. По данным РФЭС, ПЭМ, DLS и ИК были получены наночастицы металлического серебра с размером 6.5±1.8 нм, стабилизированные продуктом частичного распада цитрат-иона.The reaction of reduction solution of Ag (I) by Fe (II) citrate complex was studied herein. This allows you to receive silver nanoparticles with high stability with a concentration above 60 g/l. It was determined that the nanoparticles size depends on the injection rate, mixing rate, reagent concentration, pH and some post-synthetic operations on the average size of nanoparticles. It was shown that decreasing the concentration of Ag (I) and increasing the concentration of stabilizer also bringing pH to 7 lead to small and uniform particles. Optimal conditions were found that made it possible to reduce particle size and reduce the concentration of reagents by 33 % in the results. According to XPS, TEM, DLS and FTIR datas, nanoparticles of metallic silver with a size of 6.5±1.8 nm were obtained, which stabilized by the product of partial decay of the citrate ion.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Fedorov A. S., Krasnov, Pavel O., Visotin M. A., Tomilin F. N., Polyutov, Sergey P.
Заглавие : Thermoelectric and Plasmonic Properties of Metal Nanoparticles Linked by Conductive Molecular Bridges
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [16-13-00060]; Ministry of Science and High Education of the Russian Federation; FSRZ-2020-0008 (plasmonic properties)
Место публикации : Phys. Status Solidi B. - 2020. - Vol. 257, Is. 12. - Ст.2000249. - ISSN 0370-1972, DOI 10.1002/pssb.202000249. - ISSN 1521-3951(eISSN)
Примечания : Cited References: 53. - This study was supported by the Russian Science Foundation, project no. 16-13-00060 (thermoelectric properties), and by the Ministry of Science and High Education of the Russian Federation, project no. FSRZ-2020-0008 (plasmonic properties)
Предметные рубрики: POLYMERS
ARRAYS
RANGE
Аннотация: Thermoelectric and plasmonic properties of systems comprising small golden nanoparticles (NPs) linked by narrow conductive polymer bridges are studied using the original hybrid quantum-classical model. The bridges are considered here to be either conjugated polyacetylene, polypyrrole, or polythiophene chain molecules terminated by thiol groups. The parameters required for the model are obtained using density functional theory and density functional tight-binding simulations. Charge-transfer plasmons in the considered dumbbell structures are found to possess frequency in the infrared region for all considered molecular linkers. The appearance of plasmon vibrations and the existence of charge flow through the conductive molecule, with manifestation of quantum properties, are confirmed using frequency-dependent polarizability calculations implemented in the coupled perturbed Kohn-Sham method. To study the thermoelectric properties of the 1D periodical systems, a universal equation for the Seebeck coefficient is derived. The phonon part of the thermal conductivity for the periodical -NP-S-C8H8- system is calculated by the classical molecular dynamics. The thermoelectric figure of meritZTis calculated by considering the electrical quantum conductivity of the systems in the ballistic regime. It is shown that forAu309nanoparticles connected by polyacetylene, polypyrrole, or polythiophene chains atT = 300 K, the ZTvalue is {0.08;0.45;0.40}, respectively.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Chilom C. G., Sandu N., Balasoiu M., Yaroslavtsev R. N., Stolyar S. V., Rogachev A. V.
Заглавие : Ferrihydrite nanoparticles insights: Structural characterization, lactate dehydrogenase binding and virtual screening assay
Место публикации : Int. J. Biol. Macromol. - 2020. - Vol. 164. - P.3559-3567. - ISSN 01418130 (ISSN), DOI 10.1016/j.ijbiomac.2020.08.242
Примечания : Cited References: 64. - The work was accomplished in the frame of JINR Themes 02-1-1107-2011/2021, 04-5-1131-2017/2021 and 04-4-1121-2015/2020 and with the financial support of the RO-JINR Projects Nos. 268/21.05.2020 items 8 and 77, and 269/21.05.2020 items 11 and – 80. MB acknowledges Dr. Alexander Kuklin for assistance for SANS measurements and fruitful discussions. The authors acknowledge Dr. George Stan of the National Institute of Materials Physics for facilitating the conduct of FTIR experiments
Аннотация: The binding between the enzyme lactate dehydrogenase (LDH) and ferrihydrite nanoparticles (Fh-NPs) was investigated by means of small-angle neutron scattering (SANS), Fourier-transform infrared (FTIR) spectroscopy, fluorescence and Forster resonance energy transfer (FRET) and molecular docking. Fh-NPs - LDH compounds of dimensions under 100 nm are formed. The conformational changes and the mechanism of interaction between LDH and Fh-NPs simple and doped with Cu and Co, and the effect of these NPs on the thermal denaturation of LDH were monitored. The quenching mechanism is static, the binding occurring with moderate affinity, being mainly driven by hydrogen bonding and van der Waals forces. FRET occurs at a minimal distance of 2.55 nm. Thermal denaturation of LDH in the presence of simple and doped Fh-NPs shows that the thermodynamic parameters of protein unfolding are significantly changed with temperature. The denaturation temperature of LDH shifts to higher values in the presence of all Fh-NPs, than in the case of simple LDH. The docking approach estimates the energy corresponding to the best fit of the ferrihydrite in the LDH binding site near Trp. These results have direct implications on the uses of the complex of LDH with Fh-NPs in various biochemical, biological, or clinical applications.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Popkov S. I., Krasikov A. A., Semenov S. V., Dubrovskii A. A., Yakushkin S. S., Kirillov V. L., Mart'yanov O. N., Balaev D. A.
Заглавие : General regularities and differences in the behavior of the dynamic magnetization switching of ferrimagnetic (CoFe2O4) and antiferromagnetic (NiO) nanoparticles
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of the Krasnoyarsk region; Krasnoyarsk Regional Foundation for Science [18-42-240012]
Место публикации : Phys. Solid State. - 2020. - Vol. 62, Is. 9. - P.1518-1524. - ISSN 1063-7834, DOI 10.1134/S1063783420090255. - ISSN 1090-6460(eISSN)
Примечания : Cited References: 46. - This work was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk region, and the Krasnoyarsk Regional Foundation for Science, project no. 18-42-240012: "Magnetization switching of magnetic nanoparticles in strong pulsed magnetic fields is a new approach to studying the dynamic effects related to the processes of magnetization of magnetic nanoparticles"
Предметные рубрики: PARTICLE-SIZE
EXCHANGE-BIAS
TEMPERATURE
STATE
COERCIVITY
Аннотация: In antiferromagnetic (AFM) nanoparticles, an additional ferromagnetic phase forms and leads to the appearance in AFM nanoparticles of a noncompensated magnetic moment and the magnetic properties typical of common FM nanoparticles. In this work, to reveal the regularities and differences of the dynamic magnetization switching in FM and AFM nanoparticles, the typical representatives of such materials are studied: CoFe2O4 and NiO nanoparticles with average sizes 6 and 8 nm, respectively. The high fields of the irreversible behavior of the magnetizations of these samples determine the necessity of using strong pulsed fields (amplitude to 130 kOe) to eliminate the effect of the partial hysteresis loop when studying the dynamic magnetic hysteresis. For both types of the samples, coercive force HC at the dynamic magnetization switching is markedly higher than HC at quasi-static conditions. HC increases as the pulse duration τP decreases and the maximum applied field H0 increases. The dependence of HC on field variation rate dH/dt = H0/2τP is a unambiguous function for CoFe2O4 nanoparticles, and it is precisely such a behavior is expected from a system of single-domain FM nanoparticles. At the same time, for AFM NiO nanoparticles, the coercive force is no longer an unambiguous function of dH/dt, and the value of applied field H0 influences more substantially. Such a difference in the behaviors of FM and AFM nanoparticles is caused by the interaction of the FM subsystem and the AFM “core” inside AFM nanoparticles. This circumstance should be taken into account when developing the theory of dynamic hysteresis of the AFM nanoparticles and also to take into account their practical application.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Saykova, Diana, Saikova, Svetlana, Mikhlin, Yuri, Panteleeva, Marina, Ivantsov R. D., Belova E.
Заглавие : Synthesis and characterization of core-shell magnetic nanoparticles NiFe2O4@Au
Место публикации : Metals. - 2020. - Vol. 10, Is. 8. - Ст.1075. - ISSN 2075-4701(eISSN), DOI 10.3390/met10081075
Примечания : Cited References: 45
Предметные рубрики: NICKEL FERRITE NANOPARTICLES
GOLD NANOPARTICLES
OXIDATION
REDUCTION
Аннотация: In this study, NiFe2O4@Au core–shell nanoparticles were prepared by the direct reduction of gold on the magnetic surface using amino acid methionine as a reducer and a stabilizing agent simultaneously. The obtained nanoparticles after three steps of gold deposition had an average size of about 120 nm. The analysis of particles was performed by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and UV-Vis spectroscopy techniques. The results indicate successful synthesis of core–shell particles with the magnetic core, which consists of a few agglomerated nickel ferrite crystals with an average size 25.2 ± 2.0 nm, and the thick gold shell consists of fused Au0 nanoparticles (NPs). Magnetic properties of the obtained nanoparticles were examined with magnetic circular dichroism. It was shown that the magnetic behavior of NiFe2O4@Au NPs is typical for superparamagnetic NPs and corresponds to that for NiFe2O4 NPs without a gold shell. The results indicate the successful synthesis of core–shell particles with the magnetic nickel ferrite core and thick gold shell, and open the potential for the application of the investigated hybrid nanoparticles in hyperthermia, targeted drug delivery, magnetic resonance imaging, or cell separation. The developed synthesis strategy can be extended to other metal ferrites and iron oxides.
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