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Allotropic modifications of cobalt upon chemical deposition / A. V. Chzhan, S. A. Podorozhnyak, V. K. Mal’tsev [et al.] // Phys. Solid State. - 2021. - Vol. 63, Is. 1. - P. 42-46, DOI 10.1134/S1063783421010054. - Cited References: 17. - This study was supported in part by the Russian Foundation for Basic Research, project no. 18-02-00161-a . - ISSN 1063-7834
Кл.слова (ненормированные):
Co–P thin magnetic films -- chemical deposition -- nuclear magnetic resonance -- allotropic modifications of Co
Аннотация: The effect of the solution acidity on the crystal structure of cobalt during its chemical deposition is reported. It has been shown using the structural and magnetic examination and nuclear magnetic resonance study that the change in the working solution acidity leads to deposition of cobalt with different allotropic modifications in the nearest environment: the hcp type in the small (up to ~8.5) pH region and the fcc type in the large (over ~8.5) pH region. The formation of these cobalt modifications is attributed to the size effects caused by a decrease in the particle size with increasing pH.

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Публикация на русском языке Аллотропные модификации кобальта при химическом осаждении [Текст] / А. В. Чжан, С. А. Подорожняк, В. К. Мальцев [и др.] // Физ. тверд. тела. - 2021. - Т. 63 Вып. 1. - С. 43-47

Держатели документа:
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Krasnoyarsk State Agrarian University, Krasnoyarsk, 660049, Russian Federation
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Chzhan, A. V.; Podorozhnyak, S. A.; Mal'tsev, V. K.; Мальцев, Вадим Константинович; Krayukhin, I. N.; Patrin, G. S.; Патрин, Геннадий Семёнович
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B-11-NMR study of low-temperature phase transition in CuB2O4 / Y. . Yasuda [et al.] // J. Phys.: Condens. Matter. - 2007. - Vol. 19: International Conference on Highly Frustrated Magnetism (AUG 15-19, 2006, Osaka, JAPAN), Is. 14. - Ст. 145277, DOI 10.1088/0953-8984/19/14/145277. - Cited References: 10 . - ISSN 0953-8984

РУБ Physics, Condensed Matter
Рубрики:
COPPER METABORATE
Кл.слова (ненормированные):
Copper compounds -- Low temperature effects -- Magnetic field effects -- Nuclear magnetic resonance -- B T phase diagram -- Dzialoshinskii Moriya interaction -- Phase transitions
Аннотация: The material CuB2O4 presents a variety of phases in the B - T phase diagram, caused by the frustration and the Dzialoshinskii - Moriya interaction. In order to investigate the nature of the phase transitions, a B-11- NMR experiment on CuB2O4 has been performed under an applied magnetic field along the a- axis down to 0.4 K. A new incommensurate - incommensurate phase transition has been found at 0.8 K under a field of 0.5 T. Further, another phase transition has been observed at 4.7 K under a field of about 2 T, which is consistent with the transition reported by the neutron diffraction experiment.

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Держатели документа:
Univ Fukui, Dept Appl Phys, Fukui 9108507, Japan
Japan Adv Inst Sci & Technol, Ishikawa 9231292, Japan
RAS, SB, Inst Phys, Krasnoyarsk 660036, Russia
ИФ СО РАН
Department of Applied Physics, University of Fukui, Fukui 910-8507, Japan
Japan Advanced Institute of Science and Technology, Ishikawa 923-1292, Japan
Institute of Physics, SB RAS, 660036 Krasnoyarsk, Russian Federation

Доп.точки доступа:
Yasuda, Y.; Nakamura, H.; Fujii, Y.; Kikuchi, H.; Chiba, M.; Yamamoto, Y.; Hori, H.; Petrakovskii, G. A.; Петраковский, Герман Антонович; Popov, M. A.; Bezmaternykh, L. N.
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Chemical exchange in NH4HSeO4 single crystals studied by two-dimensional H-2 nuclear magnetic resonance / Y. N. Ivanov [et al.] // J. Phys.: Condens. Matter. - 1999. - Vol. 11, Is. 18. - P. 3751-3760, DOI 10.1088/0953-8984/11/18/310. - Cited References: 16 . - ISSN 0953-8984

РУБ Physics, Condensed Matter
Рубрики:
PHASE-TRANSITIONS
CONDUCTIVITY PROCESSES
AMMONIUM
Кл.слова (ненормированные):
Hydrogen bonds -- Nuclear magnetic resonance -- Single crystals -- Thermal effects -- Ammonium hydrogen selenate -- Ammonium compounds
Аннотация: Processes of chemical exchange of deuterons in partially deuterated ammonium hydrogen selenate, NH4HSeO4 (AHSe), crystals are investigated by means of H-2 nuclear magnetic resonance (NMR) experiments over a wide temperature range. The temperature dependencies of the quadrupole line splittings in the one-dimensional spectra of AHSe above 350 K revealed lineshape changes which are characteristic for chemical exchange processes. A detailed study of these exchange processes in AHSe is achieved by means of two-dimensional H-2 NMR experiments. In the temperature range investigated, a chemical exchange occurs only between those deuteron (proton) sites which are involved in hydrogen bonds (alpha- and beta-positions). It was established that the rates of exchange between all types of hydrogen-bound deuteron are approximately the same. Exchange between these positions and the deuterons in the ND4 groups could not be detected. On the basis of our findings, we finally discuss a model for the microscopic mechanism of hydrogen transport in AHSe.

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Держатели документа:
LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
Univ Leipzig, Fak Phys & Geowissensch, D-04103 Leipzig, Germany
ИФ СО РАН
L V Kirensky Institute of Physics, Russian Academy of Science, Siberian Branch, 660036 Krasnoyarsk, Russian Federation
Universitat Leipzig, Fakultat fur Physik und Geowissenschaften, Linnestra?e 5, D-04103 Leipzig, Germany

Доп.точки доступа:
Ivanov, Y. N.; Иванов, Юрий Николаевич; Totz, J.; Michel, D.; Klotzsche, G.; Sukhovsky, A. A.; Суховский, Андрей Андреевич; Aleksandrova, I. P.; Александрова, Инга Петровна
}
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    Chemistry of vinylidene complexes. XVIII. Synthesis and molecular structure of the novel trinuclear mu(3)-vinylidene complex CpReFePt(mu(3)-C=CHPh)(CO)(6)(PPh(3)) / A. B. Antonova [et al.] // J. Organomet. Chem. - 2009. - Vol. 694, Is. 1. - P. 127-130, DOI 10.1016/j.jorganchem.2008.08.037. - Cited Reference Count: 17. - Гранты: This work was supported by the Council of the Russian Federation President for Support of Young Scientists and Leading Scientific Schools (Project No. NSch-4137.2006.2) and the Krasnoyarsk Regional Science Foundation (Grants 10TS145 and 17G002). - Финансирующая организация: Council of the Russian Federation President for Support of Young Scientists and Leading Scientific Schools [NSch-4137.2006.2]; Krasnoyarsk Regional Science Foundation [10TS145, 17G002] . - ISSN 0022-328X
Рубрики:
CLUSTERS
   CRYSTAL
   MNFEPT
Кл.слова (ненормированные):
Vinylidene complexes -- Heterometallic clusters -- Rhenium -- Iron -- Platinum -- Crystal structure -- Crystal structure -- Heterometallic clusters -- Iron -- Platinum -- Rhenium -- Vinylidene complexes -- Atomic physics -- Atoms -- Bond length -- Chemical bonds -- Coordination reactions -- Crystal structure -- Iron compounds -- Nuclear magnetic resonance -- Nuclear magnetic resonance spectroscopy -- Platinum -- Quantum chemistry -- Rhenium -- Rhenium compounds -- Bond angles -- Co groups -- Double bonds -- Fe atoms -- Heterometallic -- Heterometallic clusters -- Pt atoms -- Trimetallic -- Vinylidene complexes -- X-ray diffractions -- Platinum compounds
Аннотация: The interaction between Cp(CO)(2)RePt(mu-C=CHPh)(PPh(3))(2) (1) and Fe(2)(CO)(9) afforded the new heterometallic mu(3)-vinylidene cluster CpReFePt(mu(3)-C=CHPh)(CO)(6)(PPh(3)) (2). An X-ray diffraction study shows the complex 2 possesses a trimetallic Re-Fe-Pt chain core. The bond lengths are Re-Fe 2.8221(8), Fe-Pt 2.5813(8) angstrom; the Re center dot center dot center dot Pt distance is 3.3523(7) angstrom; the bond angle Re-Fe-Pt is 76.55(3)degrees. The mu(3)-C=CHPh ligand is eta(1)-bound to the Re and Pt atoms and eta(2)-coordinated to the Fe atom. The C=C bond length is 1.412(4) angstrom. The Pt atom is coordinated by the PPh(3) and CO groups. Complex 2 is characterized by the IR and (1)H, (13)C and (31)P NMR spectra. (C) 2008 Elsevier B.V. All rights reserved.

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Держатели документа:
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660049, Russia
Russian Acad Sci, Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

Доп.точки доступа:
Antonova, A.B.; Chudin, O.S.; Pavlenko, N.I.; Sokolenko, W.A.; Rubaylo, A.I.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Semeikin, O.V.
}
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Shauro, V. P.
Exact solutions for time-optimal control of spin I=1 by NMR / V. Shauro // Quantum Inf. Process. - 2015. - Vol. 14, Is. 7. - P. 2345-2355, DOI 10.1007/s11128-015-0999-8. - Cited References:34. - The author thanks V.E. Zobov for fruitful discussions. This study was supported by the Russian Foundation for Basic Research, Project No. 14-07-31086. . - ISSN 1570. - ISSN 1573-1332. -

РУБ Physics, Multidisciplinary + Physics, Mathematical
Рубрики:
QUANTUM COMPUTATION
SYSTEMS
Кл.слова (ненормированные):
Quantum gate -- Qutrit -- Time-optimal control -- Nuclear magnetic resonance
Аннотация: We consider the problem of time-optimal control of quadrupole nucleus with the spin I = 1 by NMR. In contrast to the conventional methods based on selective pulses, the control is implemented using nonselective pulses separated by free-evolution intervals. Using the Cartan decomposition, the system of equations is obtained for finding parameters of a control field. Partial time-optimal solutions for the important single-qutrit gates (selective rotations and quantum Fourier transform) are found. The strong dependence of minimum gate implementation times on global phase of the gate is observed. The analytical values of minimum times are consistent with the numerical data.

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Доп.точки доступа:
Шауро, Виталий Павлович; Russian Foundation for Basic Research [14-07-31086]
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Exchange interaction in the Co-SiO2 nanocomposite films / E. A. Denisova [et al.] // TRENDS IN MAGNETISM. - 2011. - Vol. 168-169. - P265-268, DOI 10.4028/www.scientific.net/SSP.168-169.265 . - ISSN 1012-0394
Кл.слова (ненормированные):
exchange coupling parameter -- ferromagnetic resonance -- granular composite films -- cobalt -- exchange coupling -- exchange interactions -- ferromagnetic materials -- ferromagnetic resonance -- ferromagnetism -- magnetic resonance measurement -- nanocomposite films -- nanocomposites -- nuclear magnetic resonance -- resonance -- silicon compounds -- spin waves -- cobalt -- exchange coupling -- exchange interactions -- ferromagnetic materials -- ferromagnetic resonance -- ferromagnetism -- magnetic resonance measurement -- magnetism -- nanocomposite films -- nuclear magnetic resonance -- spin fluctuations -- spin waves -- co content -- coupling parameters -- dispersion relations -- granular composite films -- magnetic measurements -- nanogranulars -- nmr studies -- structural state -- granular composites -- nano-granular -- standing spin waves -- composite films -- composite films
Аннотация: The properties of Co-SiO2 nanogranular composite films, containing a Co volume fraction ranging from 0.3 to 0.8, have been characterized by means of magnetic measurements, NMR study, and ferromagnetic resonance. Thermal decrease of CoX(SiO2)100-X magnetization follows the T3/2 law and allows to estimate the exchange interaction constant A. With growing nominal Co content the transitions from granular to continuous structural state at 36% Co are registered by FMR measurements. The spectrum of standing spin-wave has been detected in the perpendicular experiment configuration for films with the Co content above 52 vol. %. It is found that the type of the dispersion relation of spin waves in Co-SiO2 composite films is affected by the exchange coupling fluctuations.

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Держатели документа:
Kirensky Institute of Physics, SB, RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Siberian University of Technology, Krasnoyarsk, 660049, Russian Federation
Voronezh State Technical University, Voronezh, Russian Federation

Доп.точки доступа:
Denisova, E. A.; Денисова, Елена Александровна; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Stolyar, S. V.; Столяр, Сергей Викторович; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Chekanova, L. A.; Чеканова, Лидия Александровна; Maltsev, V. K.; Мальцев, Вадим Константинович; Kalinin, Y. E.; Sitnikov, A. V.
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Ignatchenko, V. A.
Exchange narrowing of magnetic resonance linewidths in inhomogeneous ferromagnets / V. A. Ignatchenko, V. A. Felk // Phys. Rev. B. - 2005. - Vol. 71, Is. 9. - Ст. 94417, DOI 10.1103/PhysRevB.71.094417. - Cited References: 32 . - ISSN 1098-0121

РУБ Physics, Condensed Matter
Рубрики:
AMORPHOUS FERROMAGNETS
   RANDOM ANISOTROPY
   NANOCRYSTALLINE
   CRYSTALS
   ALLOYS
Кл.слова (ненормированные):
ferromagnetic material -- anisotropy -- article -- calculation -- correlation analysis -- crystal structure -- magnetism -- mathematical analysis -- nanotechnology -- nuclear magnetic resonance
Аннотация: The theory of exchange narrowing of ferromagnetic and spin-wave resonance linewidths in ferromagnets with the randomly inhomogeneous magnetic anisotropy is developed. The calculation is carried out by the method of averaged Green functions in the framework of the coherent potential approximation (CPA). One- and three-dimensional inhomogeneities with an arbitrary correlation wave number k(c) are considered (r(c)=k(c)(-1) is the correlation radius of the inhomogeneities). The method of the approximate solution of the CPA equation is proposed which has the quick convergence. Effects of exchange narrowing of the magnetic resonance lines and shifts of these lines are calculated in the whole region of the values of the correlation wave number k(c). The approximate analytical expressions for the linewidth of the FMR in the limiting cases of the small and large k(c) are obtained. Large narrowing of the FMR and spin-wave linewidths with the decrease of the correlation, radius of inhomogeneities is the substantiation. of the main advantage of nanocrystalline and amorphous materials over usual polycrystals when they are used at high frequency devices.

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Держатели документа:
RAS, SB, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
L. V. Kirensky Institute of Physics SB RAS, 660036, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Felk, V. A.; Игнатченко, Вальтер Алексеевич
}
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Morozov, E. V.
Magnetic resonance imaging study of water absorption of polymer composite materials subjected to mechanical and temperature impact / E. V. Morozov, A. V. Il’ichev, V. M. Bouznik // Russ. J. Phys. Chem. B. - 2023. - Vol. 17, Is. 6. - P. 1361-1369, DOI 10.1134/S1990793123060064. - Cited References: 18. - The research was carried out as part of a state assignment of the Institute of Chemistry and Chemical Technology of the Siberian Branch of the Russian Academy of Sciences (project no. 0287-2021-0012) using the equipment of the Krasnoyarsk Regional Center for Collective Use of the Federal Research Center "Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences" . - ISSN 1990-7931. - ISSN 1990-7923
Кл.слова (ненормированные):
composite material -- fiberglass -- nuclear magnetic resonance -- magnetic resonance imaging -- water absorption
Аннотация: The results of a study of water absorption processes by samples of polymer composite materials (PCMs) based on fiberglass, subjected to low-speed impact with controlled impact energy and alternating temperature cycling are presented. Using magnetic resonance imaging (MRI), the distribution of absorbed water in the fiberglass structure is visualized and the dynamics of its accumulation in various areas of the sample are studied. It is found that mechanical impact leads to a nonuniform distribution of the absorbed water in the samples and a significant accumulation of free water in the areas of destruction and adjacent layers in the event of a violation of the integrity of the outer layer of the material. It is shown that cyclic alternating temperature effects do not lead to a noticeable change in the water absorption processes and are comparable in effect to mechanical nondestructive impacts. The results obtained using MRI are in close agreement with the data of traditional weight measurements, which shows the effectiveness of the method in diagnosing defects and mechanical damage to PCMs exposed to the humid environment.

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Публикация на русском языке Морозов, Евгений Владимирович. Исследование водопоглощения полимерных композиционных материалов, подверженных механическому и температурному воздействиям, методом магнитно-резонансной томографии [Текст] / Е. В. Морозов, А. В. Ильичев, В. М. Бузник. - 9 с. // Химич. физика. - 2023. - Т. 42 № 11. - С. 54-62

Держатели документа:
Kirensky Institute of Physics of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, Russia
Institute of Chemistry and Chemical Technology of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, Russia

Доп.точки доступа:
Il’ichev, A. V.; Ильичев А. В.; Bouznik, V. M.; Бузник, Вячеслав Михайлович; Морозов, Евгений Владимирович
}
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Measurement of the maximum content of bound water in bentonitic clay using dielectric and NMR methods / V. L. Mironov [et al.] // Russ. Phys. J. - 2011. - Vol. 54, Is. 1. - P. 71-76. - Cited References: 4 . - ISSN 1064-8887

РУБ Physics, Multidisciplinary

Кл.слова (ненормированные):
dielectric permittivity -- nuclear magnetic resonance -- bentonitic clay -- bound water
Аннотация: An investigation of moisture dependences of refractive index and spectral width of the nuclear magnetic resonance (NMR) is performed for bentonitic clay specimens at different temperatures. These moisture dependences allowed identifying two types of moisture: bound and free water. The maximum content of water in the bentonitic clay is measured.

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Держатели документа:
[Mironov, V. L.
Sukhovskii, A. A.
Lukin, Yu. I.
Aleksandrova, I. P.] Russian Acad Sci, Siberian Branch, LV Kirenskii Inst Phys, Krasnoyarsk, Russia
ИФ СО РАН

Доп.точки доступа:
Mironov, V. L.; Миронов, Валерий Леонидович; Sukhovskii, A. A.; Суховский, Андрей Андреевич; Lukin, Y. I.; Лукин, Юрий Иванович; Aleksandrova, I. P.; Александрова, Инга Петровна
}
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10.

Zobov, V. E.
On the coordinate of a singular point of time correlation functions for the system of nuclear magnetic moments of a crystal / V. E. Zobov, M. A. Popov // J. Exp. Theor. Phys. - 2003. - Vol. 97, Is. 1. - P. 78-84, DOI 10.1134/1.1600799. - Cited References: 22 . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
DIPOLAR FLUCTUATION SPECTRUM
   FREE-INDUCTION DECAY
   CROSS-RELAXATION
   DOUBLE-RESONANCE
   SPIN SYSTEMS
   NMR-SPECTRA
   LINE SHAPE
   IRREVERSIBILITY
   ABSORPTION
   CAF2
Кл.слова (ненормированные):
Absorption spectroscopy -- Barium compounds -- Crystallography -- Lattice constants -- Magnetic fields -- Nuclear magnetic resonance -- Absorption spectrum -- Dipole-dipole interaction -- Magnetic field directions -- Nuclear magnetic moments -- Magnetic moments
Аннотация: The hypothesis concerning the existence of singular points on the imaginary time axis for a correlation function of a system with the dipole-dipole interaction of nuclear spins of a crystal is verified. Within the framework of the self-consistent fluctuating field theory taking into account the principal corrections related to the correlation of local fields, a result for this coordinate is obtained in terms of the ratios of lattice sums. Experimental values of this coordinate are calculated from the wings of the nuclear magnetic resonance absorption spectrum of a BaF2 crystal for the magnetic field directions along the three crystallographic axes. Good agreement of the theoretical and experimental results justifies this hypothesis. (C) 2003 MAIK "Nauka / Interperiodica".

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Держатели документа:
Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Krasnoyarsk State Univ, Krasnoyarsk 660041, Russia
ИФ СО РАН
Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Krasnoyarsk State University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Popov, M. A.; Зобов, Владимир Евгеньевич
}
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