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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : OVCHINNIKOV S.G.
Заглавие : THE INFLUENCE OF THE ANTIFERROMAGNETISM ON THE ELECTRONIC-STRUCTURE OF LA2CUO4
Разночтения заглавия :авие SCOPUS: The influence of the antiferromagnetism on the electronic structure of La2CuO4
Место публикации : J. Supercond.: PLENUM PUBL CORP, 1995. - Vol. 8: University-of-Miami Workshop on High-Temperature Superconductivity - Physical Properties and Mechanisms (JAN 05-11, 1995, CORAL GABLES, FL), Is. 5. - P675-676. - ISSN 0896-1107, DOI 10.1007/BF00727473
Примечания : Cited References: 15
Предметные рубрики: OXIDES
MODEL
Ключевые слова (''Своб.индексиров.''): electron correlations--electron structure--spin fluctuations--electron correlations--electron structure--spin fluctuations--antiferromagnetism--band structure--calculations--correlation theory--electrons--lanthanum compounds--paramagnetism--perturbation techniques--antiferromagnetic phase--electron correlations--intercluster interactions--spin fluctuations--electronic structure
Аннотация: The quasiparticle approach for electronic structure calculations considering strong electron correlations is given. The exact diagonalization of a multiband Hubbard Hamiltonian for a small cluster is combined with perturbation theory for intercluster hopping. The band structure of paramagnetic and antiferromagnetic La2CuO4 are discussed.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Ospishchev S. V., Petrov M. I., Aleksandrov K. S.
Заглавие : The effect of paramagnetic impurities in normal metal on the critical current in a network of S-N-S Josephson junctions in bulk Y3/4Lu1/4Ba2Cu3O7+BaPb(1-x)Fe(x)O(3)composites
Разночтения заглавия :авие SCOPUS: The effect of paramagnetic impurities in normal metal on the critical current in a network of S-N-S Josephson junctions in bulk Y3/4Lu1/4Ba2Cu3O7 + BaPb1-xFexO3 composites
Место публикации : Supercond. Sci. Technol. - 2003. - Vol. 16, Is. 1. - P.60-64. - ISSN 0953-2048, DOI 10.1088/0953-2048/16/1/311
Примечания : Cited References: 41
Предметные рубрики: CURRENT-VOLTAGE CHARACTERISTICS
WEAK LINKS
RESISTIVE PROPERTIES
MAGNETIC-IMPURITIES
EXCHANGE FIELD
SNS JUNCTIONS
F-S
COMPOSITES
SUPERCONDUCTOR
SCATTERING
Ключевые слова (''Своб.индексиров.''): critical currents--interfaces (materials)--josephson junction devices--paramagnetism--transport properties--non-superconducting ingredient--paramagnetic impurities--superconductor normal metal superconductor--oxide superconductors
Аннотация: Bulk Y3/4Lu1/4Ba2Cu3O7 + BaPb1-xFexO3 composites representing a model of a network of superconductor-normal metal-superconductor (SNS) Josephson junctions with paramagnetic impurities (Fe) in the N layers have been prepared. The transport properties of the composites have been studied. An exponential decay of the critical current with increasing Fe content in the non-superconducting ingredient of the composite has been observed. Such a behaviour is accounted for in terms of the de Gennes proximity effect theory.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mikhlin Y. L., Borisov R. V., Vorobyev S. A., Tomashevich Y. V., Romanchenko A. S., Likhatski M. N., Karacharov A. A., Bayukov O. A., Knyazev Yu. V., Velikanov D. A., Zharkov S. M., Krylov A. S., Krylova S. N., Nemtsev I. V.
Заглавие : Synthesis and characterization of nanoscale composite particles formed by 2D layers of Cu-Fe sulfide and Mg-based hydroxide
Место публикации : J. Mater. Chem. A. - 2022. - Vol. 10, Is. 17. - P.9621-9634. - ISSN 20507488 (ISSN), DOI 10.1039/d2ta00877g
Примечания : Cited References: 84. - This research was supported by the Russian Foundation for Basic Research, Krasnoyarsk Territory Administration and Krasnoyarsk Territory Science Foundation, project 20-43-242903. Facilities of the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” were employed in the work
Аннотация: We introduce here a multifunctional material composed of alternating atomic sulfide sheets close to the composition of CuFeS2 and Mg-based hydroxide ones (valleriite), which are assembled due to their electric charges of opposite sign. Valleriite particles 50-200 nm in lateral size and 10-20 nm in thickness were synthesized via a simple hydrothermal pathway using various concentrations of precursors and dopants, and examined with XRD, TEM, EDS, X-ray photoelectron spectroscopy, reflection electron energy loss spectroscopy (REELS), Mossbauer, Raman and UV-vis-NIR spectroscopies, and magnetization, dynamic light scattering, and zeta potential measurements. The electronic, magnetic and optical characteristics are found to be critically dependent on the charge (electron density) at the narrow-gap sulfide layers containing Cu+ and Fe3+ cations, and can be tuned via the composition of the hydroxide part. Particularly, substitution of Mg2+ with Al3+ increases the negative charge of the hydroxide layers and reduces the content of Fe3+-OH centers (10-45% of total iron); the effects of Cr and Co dopants entering both layers are more complicated. Mossbauer doublets of paramagnetic Fe3+ detected at room temperature transform into several Zeeman sextets at 4.2 K; the hyperfine fields up to 500 kOe and complex magnetic behavior, but not pure paramagnetism or antiferromagnetism, were observed for valleriites with the higher positive charge of the sulfide sheets, probably due to the depopulation of the minority-spin 3d states of S-bonded Fe3+ ions. Aqueous colloids of valleriite show optical absorption at 500-750 nm, which, along with the peaks at the same energies in REELS, may arise due to quasi-static dielectric resonance involving the vacant Fe 3d band and being dependent on the composition of both layers too. These and other findings call attention to valleriites as a new rich family of 2D materials for a variety of potential applications.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Li, Oksana A., Lin, Chun-Rong, Chen, Hung-Yi, Hsu, Hua-Shu, Wu, Kai-Wun, Tseng, Yaw-Teng, Bayukov O. A., Edelman I. S., Ovchinnikov S. G., Shih, Kun-Yauh
Заглавие : Structural and magnetic properties of Fe1−xCoxSe1.09 nanoparticles obtained by thermal decomposition
Место публикации : Mater. Res. Express: IOP Publishing, 2015. - Vol. 2, No. 12. - Ст.126501. - ISSN 2053-1591, DOI 10.1088/2053-1591/2/12/126501
Примечания : Cited References: 30. - This work is supported by the Ministry of Science and Technology of Taiwan (MOST103-2811-M-153 -001 and MOST102-2112-M-153 -002 -MY3).
Предметные рубрики: X-RAY-DIFFRACTION
MOSSBAUER-SPECTROSCOPY
CRYSTAL-STRUCTURES
IRON SELENIDES
SUPERCONDUCTIVITY
FeSe
MARCASITE
PYRITE
Ключевые слова (''Своб.индексиров.''): nanoparticles--chalcogenide--iron-cobalt selenide--ferrimagnetism--paramagnetism--mossbauer spectroscopy
Аннотация: A series of Fe1−xCoxSe1.09 (x = 0 to ) nanoparticles were synthesized by thermal decomposition method. Particles in composition range Fe0.5Co0.5Se1.09 to CoSe1.09 crystallized in monoclinic structure of Co6.8Se8 , while FeSe1.09 crystallized in hexagonal structure of FeSe achavalite. Magnetization dependences on temperature and external magnetic field reveal complicated magnetic behavior and correspond to the sum of paramagnetic and superparamagnetic response. Mössbauer spectra contain several paramagnetic doublets with parameters corresponding to nonequivalent positions of divalent and trivalent iron cations with low spin. The nonequivalent positions appeared due to inhomogeneous distribution of Co ions or metal vacancies in iron surrounding.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Dolgov O. V., Efremov D. V., Korshunov M. M., Charnukha A., Boris A. V., Golubov A. A.
Заглавие : Multiband description of optical conductivity in ferropnictide superconductors
Место публикации : J. Supercond. Nov. Magn. - 2013. - Vol. 26, Is. 8. - P.2637-2640. - ISSN 1557-1939, DOI 10.1007/s10948-013-2150-3
Ключевые слова (''Своб.индексиров.''): effects of disorder--multiband superconductivity--optical conductivity--effects of disorder--experimental datum--multi-band superconductors--multiband superconductivity--novel superconductor--order parameter symmetry--paramagnetic impurity--single-band superconductors--optical conductivity--paramagnetism--superconductivity--superconducting materials
Аннотация: We study optical properties of the multiband superconductors with an s В± order parameter symmetry. By comparing results of our theory with experimental data on optical conductivity for Ba0.68K 0.32Fe2As2 single crystals, we show that satisfactory description of the novel superconductors can be obtained only considering a strong electron-boson coupling. We reexamine the effect of disorder and demonstrate that multiband superconductors are more robust with respect to it than naively expected by simple analogy with paramagnetic impurities in single-band superconductors. Moreover, disorder may give rise to new effects, in particular to a phase transition s В±s ++. We discuss how the systematic study of disorder impact on the density of states and the optical conductivity may provide information on the underlying order parameter structure. В© 2013 Springer Science+Business Media New York.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Pisarev R. V., Sanger I., Petrakovskii G. A., Fiebig M.
Заглавие : Magnetic-field induced second harmonic generation in CuB2O4
Разночтения заглавия :авие SCOPUS: Magnetic-field induced second harmonic generation in CuB2O 4
Место публикации : Phys. Rev. Lett.: AMER PHYSICAL SOC, 2004. - Vol. 93, Is. 3. - Ст.37204. - ISSN 0031-9007, DOI 10.1103/PhysRevLett.93.037204
Примечания : Cited References: 28
Предметные рубрики: COPPER METABORATE
PHASE
CR2O3
Ключевые слова (''Своб.индексиров.''): antiferromagnetic materials--crystal structure--energy gap--magnetic moments--magnetization--monochromators--nonlinear optics--paramagnetism--phase diagrams--polarization--second harmonic generation--single crystals--electric-field induced second harmonic (efish)--magnetic structure--magnetic-field induced second harmonic (mfish)--phonon transitions--copper compounds
Аннотация: Three types of optical magnetic-field induced second harmonic (MFISH) generation are observed in CuB2O4. Unusually sharp and intense electronic transitions in MFISH and linear absorption spectra provide selective access to the two nonequivalent Cu2+ sublattices. The magnetic phase diagram for both sublattices is determined by MFISH. Magnetic structure is dominated by antiferromagnetic order at the 4b site. Sublattice interactions transfer it to the 8d site where it coexists with a discoupled paramagnetic component.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Orlov Yu. S., Nikolaev S. V., Ovchinnikov S. G.
Заглавие : Magnetic properties and spin crossover in transition metal oxides with d5 Ions at high pressures
Место публикации : J. Exp. Theor. Phys. - 2019. - Vol. 129, Is. 6. - P.1062-1069. - ISSN 10637761 (ISSN), DOI 10.1134/S1063776119120185
Примечания : Cited References: 33. - This study was supported by the Russian Science Foundation (project no. 18-12-00022)
Аннотация: We analyze the influence of cooperative effects on the magnetic properties and spin crossover between the high-spin (HS) term S = 5/2 and low-spin (LS) term S = 1/2 in Mott–Hubbard dielectrics with 3d5 ions under high pressures. Two cooperation mechanisms (superexchange interaction and effective interaction via the elastic system) are considered. The sign of the exchange interaction changes because of the crossover from the antiferromagnetic in the HS state to the ferromagnetic in the LS state. In view of the large difference between the ionic radii of the HS and LS states, the systems with spin crossover acquire an additional strong coupling via the elastic system. Using the Hubbard operator representation and considering the electronic states of the two terms simultaneously, we obtain the effective Hamiltonian with allowance for the cooperative effects. The magnetic phase diagram and the spin crossover are investigated in the mean field approximation. It is shown that the inclusion of cooperative effects at low temperatures leads to a first-order phase transition between the antiferromagnetic HS state and the ferromagnetic LS state. At higher temperatures, more complicated sequences of phase transitions are possible upon an increase in pressure, including the HS paramagnet–HS antiferromagnet–LS paramagnet and HS antiferromagnet–LS paramagnet–LS ferromagnet transitions.
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Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Edelman I. S., Ivanova O. S., Ivantsov R. D., Velikanov D. A., Petrakovskaja E. A., Artemenko A., Curely J., Kliava J., Zaikovskiy V. I., Stepanov S.
Заглавие : Magnetic properties and morphology of manganese ferrite nanoparticles in glasses
Коллективы : Baltic Conference on Silicate Materials
Место публикации : IOP Conf. Ser.: Mater. Sci. Eng. - 2011. - Vol. 25, Is. 1. - Ст.012017. - , DOI 10.1088/1757-899X/25/1/012017
Ключевые слова (''Своб.индексиров.''): average diameter--borate glass--co-doped--electron magnetic resonance--magnetic and magneto-optical properties--magnetic behaviour--magnetic circular dichroisms--magnetic nanoparticles--magnetically ordered material--manganese ferrite nanoparticles--manganese ferrites--morphological characteristic--paramagnetic ions--resonance field--size and shape--static magnetization--temperature dependence--temperature dependent--variable temperature--visible and near infrared--alumina--dichroism--ferrite--glass--iron oxides--magnetic properties--magnetic resonance--magnetocrystalline anisotropy--manganese--manganese oxide--nanoparticles--paramagnetism--silicates--spectroscopy--nanomagnetics
Аннотация: Static magnetization (SM), magnetic circular dichroism (MCD) and electron magnetic resonance (EMR) studies are reported of borate glasses 22.5 K 2O-22.5 Al 2O 3-55 B 2O 3 co-doped with iron and manganese oxides. In as-prepared glasses the paramagnetic ions usually are in diluted state; however, if the ratio of the iron and manganese oxides in the charge is 3/2, magnetic nanoparticles are found already in as-prepared glass. After additional thermal treatment all glasses show magnetic behaviour, MCD and EMR due to the presence of magnetic nanoparticles with characteristics close to those of manganese ferrite. By computer simulating the EMR spectra at variable temperatures, their morphological characteristics are deduced: relatively broad size and shape distribution with average diameter of ca. 3-4 nm. The characteristic temperature-dependent shift of the apparent resonance field is explained by a strong temperature dependence of the magnetocrystalline anisotropy in the nanoparticles. The potassium-alumina-borate glasses containing magnetic nanoparticles represent a novel class of materials: "transparent magnets". Indeed, they remain transparent in a part of visible and near infrared spectral range while showing magnetic and magneto-optical properties characteristic of magnetically ordered materials.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Romanova O., Gorev M. V., Velikanov D. A., Gamzatov A. G., Aliev A. M.
Заглавие : Magnetic and thermophysical properties of GdxMn1-xS solid solutions
Место публикации : J. Phys.: Condens. Matter. - 2013. - Vol. 25, Is. 2. - Ст.025802. - P. - ISSN 0953-8984, DOI 10.1088/0953-8984/25/2/025802
Ключевые слова (''Своб.индексиров.''): antiferromagnetic orders--band state--face-centered cubic lattices--magnetic phase transitions--paramagnetic phase--temperature dependence--antiferromagnetism--electron transitions--gadolinium--manganese--paramagnetism--sodium chloride--specific heat--organic polymers
Аннотация: The structural, magnetic, and thermophysical properties of cation-substituted sulfides GdXMn1-XS (0.04 ? X ? 0.25) with the NaCl-type face-centered cubic lattice have been investigated. The range of existence of long-range antiferromagnetic order has been established. The anomalies observed in the temperature dependence of the specific heat correspond to the temperatures of the magnetic phase transition. The anomaly in the specific heat caused by electron transitions between the 4f levels and d band states has been observed. It has been found that the coefficient of thermal expansion decreases with increasing concentration of substituents in the magnetically ordered region and remains nearly invariable in the paramagnetic phase. В© 2013 IOP Publishing Ltd.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Dyakonov V. P., Szymczak R., Prokhorov A. D., Zubov E., Prokhorov A. A., Petrakovskii G. A., Bezmaternykh L. N., Berkowski M., Varyukhin V., Szymczak H.
Заглавие : Magnetic and EPR studies of the EuFe3(BO3)(4) single crystal
Коллективы :
Разночтения заглавия :авие SCOPUS: Magnetic and EPR studies of the EuFe 3(BO 3) 4 single crystal
Место публикации : Eur. Phys. J. B: SPRINGER, 2010. - Vol. 78, Is. 3. - P291-298. - ISSN 1434-6028, DOI 10.1140/epjb/e2010-10059-3
Примечания : Cited References: 23. - A.A. Prokhorov is grateful to Mianowski Fund for financial support.
Предметные рубрики: EARTH
GDFE3(BO3)(4)
MULTIFERROICS
Ключевые слова (''Своб.индексиров.''): absorption lines--antiferromagnetic orderings--applied magnetic fields--basal planes--easy direction of magnetizations--electron paramagnetic resonance--epr measurements--epr spectra--epr studies--europium ions--exchange fields--g factors--lorentz--magnetic measurements--magnetic subsystems--orientation dependence--sub-lattices--temperature dependence--temperature range--trigonal symmetry--zeeman effect--antiferromagnetism--crystal orientation--europium--magnetic fields--magnetic moments--magnetic variables measurement--magnetization--paramagnetic resonance--paramagnetism--single crystals--spectroscopy--electron spin resonance spectroscopy
Аннотация: Magnetic and electron paramagnetic resonance (EPR) properties of EuFe3(BO3)(4) single crystals have been studied over the temperature range of 300-4.2 K and in a magnetic field up to 5 T. The temperature, field and orientation dependences of susceptibility, magnetization and EPR spectra are presented. An antiferromagnetic ordering of the Fe subsystem occurs at about 37 K. The easy direction of magnetization perpendicular to the c axis is determined by magnetic measurements. Below 10 K, we observe an increase of susceptibility connected with the polarization of the Eu sublattice by an effective exchange field of the ordered Fe magnetic subsystem. In a magnetic field perpendicular to the c axis, we have observed an increase of magnetization at T 10 K in the applied magnetic field, which can be attributed to the appearance of the magnetic moment induced by the magnetic field applied in the basal plane. According to EPR measurements, the distance between the maximum and minimum of derivative of absorption line of the Lorentz type is equal to 319 Gs. The anisotropy of g-factor and linewidth is due to the influence of crystalline field of trigonal symmetry. The peculiarities of temperature dependence of both intensity and linewidth are caused by the influence of excited states of europium ion (Eu3+). It is supposed that the difference between the g-factors from EPR and the magnetic measurements is caused by exchange interaction between rare earth and Fe subsystems via anomalous Zeeman effect.
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