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1.
Bayukov, O. A.
Application of the
superexchange
model to the evaluation method of exchange and 3d-electron transfer parameters in magnetodielectrics / O. A. Bayukov, A. F. Savitskii> // Phys. Status Solidi B. - 1989. -
Vol. 152
,
Is. 2
. - P. K51-K53,
DOI
10.1002/pssb.2221520236. - Cited References: 6 . - ISSN 0370-1972
РУБ
Physics, Condensed Matter
WOS
Доп.точки доступа:
Savitskii, A. F.; Баюков, Олег Артемьевич
}
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2.
Gavrichkov, V. A.
Cation spin and
superexchange
interaction in oxide materials below and above spin crossover under high pressure / V. A. Gavrichkov, S. I. Polukeev, S. G. Ovchinnikov. - Electronic text data> // ArXiv. - 2019. - Ст. 1911.06482. - Cited References: 63. - We acknowledge the support of the Russian Science Foundation through Grant 18-12-00022.
Рубрики:
Materials Science
Strongly Correlated Electrons
Аннотация:
We derived simple rules for the sign of
superexchange
interaction based on the multielectron calculations of the
superexchange
interaction in the transition metal oxides that are valid both below and above spin crossover under high pressure. The
superexchange
interaction between two cations in dn configurations is given by a sum of individual contributions related to the electron-hole virtual excitations to the different states of the dn+1 and dn−1 configurations. Using these rules, we have analyzed the sign of the
superexchange
interaction of a number of oxides with magnetic cations in electron configurations from d2 till d8: the iron, cobalt, chromium, nickel, copper and manganese oxides with increasing pressure. The most interesting result concerns the magnetic state of cobalt and nickel oxides CoO, Ni2O3 and also La2CoO4, LaNiO3 isostructural to well-known high-TC and colossal magnetoresistance materials. These oxides have a spin 12 at the high pressure. Change of the interaction from antiferromagnetic below spin crossover to ferromagnetic above spin crossover is predicted for oxide materials with cations in d5(FeBO3) and d7(CoO) configurations, while for materials with the other dn configurations spin crossover under high pressure does not change the sign of the
superexchange
interaction.
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Держатели документа:
Kirensky Institute of Physics, Akademgorodok 50, bld.38, Krasnoyarsk, 660036 Russia
Доп.точки доступа:
Polukeev, S. I.; Полукеев, Семен Игоревич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Гавричков, Владимир Александрович
}
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3.
Gavrichkov, V. A.
Cation spin and
superexchange
interaction in oxide materials below and above spin crossover under high pressure / V. A. Gavrichkov, S. I. Polukeev, S. G. Ovchinnikov> // Phys. Rev. B. - 2020. -
Vol. 101
,
Is. 9
. - Ст. 094409,
DOI
10.1103/PhysRevB.101.094409. - Cited References: 65. - We acknowledge the support of the Russian Science Foundation through Grant No. 18-12-00022 . - ISSN 2469-9950. - ISSN 2469-9969
РУБ
Materials Science, Multidisciplinary + Physics, Applied + Physics, Condensed Matter
Рубрики:
EXCHANGE INTERACTION
PHASE-TRANSITIONS
STATE
ELECTRON
IRON
Аннотация:
We derived simple rules for the sign of 180°
superexchange
interaction based on the multielectron calculations of the
superexchange
interaction in the transition metal oxides that are valid both below and above spin crossover under high pressure. The
superexchange
interaction between two cations in dn configurations is given by a sum of partial contributions related to the electron-hole virtual excitations to the different states of the dn+1 and dn−1 configurations. Using these rules, we have analyzed the sign of the 180°
superexchange
interaction of a number of oxides with magnetic cations in electron configurations from d2 until d8: the iron, cobalt, chromium, nickel, copper, and manganese oxides with increasing pressure. The most interesting result concerns the magnetic state of cobalt and nickel oxides CoO, Ni2O3 and also La2CoO4, LaNiO3 isostructural to well-known high-TC and colossal magnetoresistance materials. These oxides have a spin 12 at the high pressure. Change of the interaction from antiferromagnetic below spin crossover to ferromagnetic above spin crossover is predicted for oxide materials with cations in d5(FeBO3) and d7(CoO) configurations, while for materials with the other dn configurations spin crossover under high pressure does not change the sign of the 180∘
superexchange
interaction.
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Держатели документа:
Kirensky Inst Phys, Akadeingorodok 50,Bld 38, Krasnoyarsk 660036, Russia.
Доп.точки доступа:
Polukeev, S. I.; Полукеев, Семен Игоревич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Гавричков, Владимир Александрович; Russian Science FoundationRussian Science Foundation (RSF) [18-12-00022]
}
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4.
Gavrichkov, V. A.
Contribution from optically excited many-electron states to the
superexchange
interaction in Mott-Hubbard insulators / V. A. Gavrichkov, S. I. Polukeev, S. G. Ovchinnikov> // Phys. Rev. B. - 2017. -
Vol. 95
,
Is. 14
. - Ст. 144424,
DOI
10.1103/PhysRevB.95.144424. - Cited References: 49. - This work was supported by the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory and Krasnoyarsk Region Science and Technology Support Fund to the research Project No. 17-42-240212. We are also grateful to the RFBR Grants No. 16-02-00273, No. 16-02-00098, and No. NSh-7559.2016.2. . - ISSN 1098-0121
Аннотация:
We investigated the effects of excited many-electron states in the optical control of the magnetic state in undoped Mott-Hubbard insulator. To derive the spin Hamiltonian in material under optical pumping one has used a many-electron approach based on the X-operator representation. Extending the projection operators approach on arbitrary energy spectra of the Mott-Hubbard insulator, we obtained the Hamiltonian of
superexchange
interaction in analytical form. The Hamiltonian includes the spin-exciton variables which are usually missing in discussion on the magnetic response to optical pumping. The
superexchange
is also not additive over contributions from the ground and optical excited states, and nonzero contributions to the Dzyaloshinskii-Moriya interaction are induced in insulators with different spins at the ground and excited cell states. As a test, a microscopic background for the optical induced
superexchange
was analyzed in La2CuO4 (further La214) and FeBO3 with spins 1/2 and 5/2, respectively. © 2017 American Physical Society.
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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
National Research Nuclear University MEPHI, Moscow Engineering Physics Institute, Moscow, Russian Federation
Доп.точки доступа:
Polukeev, S. I.; Полукеев, Семен Игоревич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Гавричков, Владимир Александрович
}
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5.
Crystal growth, structure,
magnetic properties and theoretical exchange interaction calculations of Cu2MnBO5 / S. Sofronova [et al.]> // J. Magn. Magn. Mater. - 2016. -
Vol. 420
. - P. 309-316,
DOI
10.1016/j.jmmm.2016.07.019. - Cited References: 35. - X-ray diffraction experiment was carried out at the Centre on Molecular Design and Ecologically Safe Technologies at the Novosibirsk State University. The reported study was funded by Russian Foundation for Basic Research (RFBR) and Government of Krasnoyarsk Territory according to the research project No. 16-42-243028. . - ISSN 0304-8853
РУБ
Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
SPIN-GLASS BEHAVIOR
SINGLE-CRYSTALS
SUPEREXCHANGE
INTERACTIONS
LUDWIGITE
DIELECTRICS
CO3B2O6NI3B2O6
WARWICKITES
FE3O2BO3
IFEFFIT
NI3B2O6
Кл.слова (ненормированные):
Oxyborates
--
Ludwigites
--
XMCD
--
EXAFS
--
Magnetism
Аннотация:
Single crystals of ludwigite Cu2MnBO5 were synthesized by flux growth technique. The detailed structural and magnetic characterizations of the synthesized samples have been carried out. The cations composition of the studied crystal was determined using X-ray diffraction and EXAFS technique, the resulting composition differ from the content of the initial Mn2O3–CuO components of the flux. Magnetic susceptibility measurements and the calculations of the exchange integrals in frameworks of indirect coupling model revealed that monoclinic distortions strongly affect exchange interactions and appearance of magnetic ordering phase at the temperature T=93 K. The hypothesis of the existence of several magnetic subsystems was supposed. © 2016 Elsevier B.V.
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Держатели документа:
L.V. Kirensky Institute of Physics, Siberian Branch of Russian Academy of Science, Krasnoyarsk, Russian Federation
M V Reshetnev Siberian State Aerospace University, Krasnoyarsk, Russian Federation
V.S. Sobolev Institute of Geology and Mineralogy, SB RAS, Novosibirsk, Russian Federation
Novosibirsk State University, Novosibirsk, Russian Federation
Institute of Physics, University of Mainz, Mainz, Germany
Institute of Inorganic and Analytical Chemistry, University of Mainz, Mainz, Germany
Lund University, MAX IV Laboratory, Lund, Sweden
National Research Centre “Kurchatov Institute”, Moscow, Russian Federation
Доп.точки доступа:
Sofronova, S. N.; Софронова, Светлана Николаевна; Moshkina, E. M.; Мошкина, Евгения Михайловна; Nazarenko, I. I.; Назаренко, Илья Иванович; Seryotkin, Yu. V.; Nepijko, S. A.; Ksenofontov, V.; Medjanik, K.; Veligzhanin, A. A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
}
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6.
Polukeev, S. I.
Dependence of
superexchange
interaction in CrO2 on pressure / S. I. Polukeev, V. A. Gavrichkov, S. G. Ovchinnikov> //
Euro-asian symposium "Trends in magnetism" (EASTMAG-2019) : Book of abstracts / чл. конс. ком.: S. G. Ovchinnikov, N. V. Volkov [et al.] ; чл. прогр. ком. D. M. Dzebisashvili [et al.]. - 2019. -
Vol. 2
. - Ст. H.P19. - P. 103. - Cited References: 3. - Support by RSF grant 18-12-00022 is acknowledged . - ISBN 978-5-9500855-7-4
Материалы симпозиума
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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia
Доп.точки доступа:
Ovchinnikov, S. G. \чл. конс. ком.\; Овчинников, Сергей Геннадьевич; Volkov, N. V. \чл. конс. ком.\; Волков, Никита Валентинович; Dzebisashvili, D. M. \чл. прогр. ком.\; Дзебисашвили, Дмитрий Михайлович; Gavrichkov, V. A.; Гавричков, Владимир Александрович; Ovchinnikov, S. G.; Полукеев, Семен Игоревич; Российская академия наук; Уральское отделение РАН; Институт физики металлов им. М. Н. Михеева Уральского отделения РАН; Уральский федеральный университет им. первого Президента России Б.Н. Ельцина; Российский фонд фундаментальных исследований; Euro-Asian Symposium "Trends in MAGnetism"(7 ; 2019 ; Sept. ; 8-13 ; Ekaterinburg); "Trends in MAGnetism", Euro-Asian Symposium(7 ; 2019 ; Sept. ; 8-13 ; Ekaterinburg)
Нет сведений об экземплярах (Источник в БД не найден)
}
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7.
Polukeev, S. I.
Dependence of
superexchange
interaction in CrO2 on pressure / S. I. Polukeev, V. A. Gavrichkov, S. G. Ovchinnikov> //
Международная зимняя школа физиков-теоретиков "Коуровка-XXXVIII" : тезисы докладов : Верхняя Сысерть, 23 - 29 февр. 2020 г. - Екатеринбург, 2020. - P. 70. - Cited References: 3. - Support by RSF grant № 18-12-00022 is acknowledged . - ISBN 978-5-9500855-9-8
Материалы конференции
,
Доп.точки доступа:
Gavrichkov, V. A.; Гавричков, Владимир Александрович; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Полукеев, Семен Игоревич; Институт физики металлов им. М. Н. Михеева Уральского отделения РАН; Институт электрофизики УрО РАН; Международная зимняя школа физиков-теоретиков "Коуровка"(38 ; 2020 ; 23-29 февраля ; Верхняя Сысерть, Свердловская обл.); "Коуровка", международная зимняя школа физиков-теоретиков(38 ; 2020 ; февр. ; Верхняя Сысерть, Свердловская обл.)
}
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8.
Effect of magnetic
frustrations on magnetism of the Fe3BO5 and Co3BO5 ludwigites / Y. V. Knyazev [et al.]> // J. Magn. Magn. Mater. - 2019. -
Vol. 474
. - P. 493-500,
DOI
10.1016/j.jmmm.2018.10.126. - Cited References: 33. - The Russian Foundation for Basic Research, Russia (project no. 17-02-00826-a ). S.G.O. thanks the Russian Academy of Science , Russia (project no. 0356-2017-0030 ) for financial support. J.B. and A.A. acknowledge the financial support of the Spanish MINECO-MAT2017-83468R project, Aragonese E-12 17R RASMIA (co-funded by Fondo Social Europeo), and the European Union (FEDER (ES)). . - ISSN 0304-8853
Кл.слова (ненормированные):
Antiferromagnetics
--
Superexchange
interactions
--
Frustrations
Аннотация:
The magnetic structures of Fe3BO5 and Co3BO5 ludwigites have been studied experimentally by magnetic measurements and theoretically by the combination of the group theoretical analysis and semi empiric calculations of the
superexchange
interactions. The different collinear spin configurations in the triads 3-1-3 and 4-2-4 including ferromagnetic, antiferromagnetic and dimer have been considered. For Fe3BO5 the antiferromagnetic state with zero magnetic moment per unit cell, showing the lowest energy, results to be the most probable magnetic ground state. The unusual magnetic structure comprising two virtually independent orthogonal subsystems is formed to avoid heavy frustrations of
superexchange
interactions between the 3-1-3 and 4-2-4 spin ladders. In Co3BO5 the magnetic frustrations present for the Co3+ high-spin state are quenched for a Co3+ low spin state resulting in the ferrimagnetic long-range order. The obtained results are discussed in comparison with experimental magnetic data.
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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian State University of Science and Technologies, Krasnoyarsk, 660014, Russian Federation
Instituto de Ciencia de Materiales de Aragon, CSIC-Universidad de Zaragoza and Departamento de Fisica de la Materia Condensada, Zaragoza, 50009, Spain
Servicio de Medidas Fisicas, Universidad de Zaragoza, Pedro Cerbuna 12, Zaragoza, 50009, Spain
Доп.точки доступа:
Knyazev, Yu. V.; Князев, Юрий Владимирович; Kazak, N. V.; Казак, Наталья Валерьевна; Nazarenko, I. I.; Назаренко, Илья Иванович; Sofronova, S. N.; Софронова, Светлана Николаевна; Rostovtsev, N. D.; Bartolome, J.; Arauzo, A.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич
}
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9.
Val'kov, V. V.
Effect of pressure on antiferromagnetic and superconducting ordering in systems with heavy fermions / V. V. Val'kov, A. O. Zlotnikov> // Bull. Russ. Acad. Sci.: Phys. - 2012. -
Vol. 76
,
Is. 7
. - P. 733-736,
DOI
10.3103/S1062873812070362. - Cited References: 7. - This work was supported by the Department of Physical Sciences, Russian Academy of Sciences (the Strong Electron Correlations Program); the Russian Foundation for Basic Research, projects nos. 100200251 and 110200741; the RFBR Sibir’, project no. 110298007; and by the federal target program Scientific and Pedagogical Personnel of an Innovative Russia, 2009–2013. . - ISSN 0022-2860
Кл.слова (ненормированные):
Antiferromagnetic orderings
--
Antiferromagnetic orders
--
Antiferromagnetic phasis
--
Antiferromagnetics
--
Cooper instability
--
Effect of pressure
--
External pressures
--
Heavy fermion
--
Impurity level
--
Localized state
--
Periodic Anderson model
--
Seed energy
--
Spin moments
--
Superconducting ordering
--
Superexchange
interaction
--
Superconductivity
--
Antiferromagnetism
Аннотация:
Characteristics of the superconducting and antiferromagnetic phases of heavy-fermion intermet-allides are described within a periodic Anderson model with allowance for the
superexchange
interaction between spin moments of the localized states. It is shown that an external pressure that changes the seed energy of an impurity level can rapidly destroy the long-range antiferromagnetic order. The development of the Cooper instability near such an order-disorder transition induces the experimentally observed state in which superconductivity coexists with the antiferromagnetic ordering. В© 2012 Allerton Press, Inc.
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Публикация на русском языке
Вальков, Валерий Владимирович. Влияние давления на антиферромагнитное и сверхпроводящее упорядочение в системах с тяжелыми фермионами [Текст] / В. В. Вальков, A. O. Злотников // Изв. РАН. Сер. физич. - 2012. - Т. 76 № 7. - С. 821-824
Доп.точки доступа:
Zlotnikov, A. O.; Злотников, Антон Олегович; Вальков, Валерий Владимирович; International Interdisciplinary Symposium “Ordering in Minerals and Alloys” (14th ; 8 -13 Sept. 2011 ; Rostov-on-Don)
}
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10.
Polukeev, S. I.
Effects of optical intra-gap transitions on
superexchange
interaction in La2CuO4 with nonequilibrium photoexcited centers / S. I. Polukeev, V. A. Gavrichkov, S. G. Ovchinnikov> // J. Sib. Fed. Univ. Math. Phys. - 2018. -
Vol. 11
,
Is. 2
. - P. 159-170 ; Журн. СФУ. Сер. "Математика и физика",
DOI
10.17516/1997-1397-2018-11-2-159-170. - Cited References: 39 . - ISSN 1997-1397
Перевод заглавия:
Эффекты оптических внутрищелевых переходов в суперобменном взамодействии в La2CuO4 с неравновесными фотовозбуждёнными центрами
Кл.слова (ненормированные):
Superexchange
--
Optically excited states
--
Mott-Hubbard insulator
--
суперобмен
--
оптически возбужденные состояния
--
диэлектрик Мотта-Хаббарда
Аннотация:
We investigated the effects of excited many-electron states in the optical control of the magnetic state in undoped Mott-Hubbard insulator. To derive the spin Hamiltonian in material under optical pumping we have used many-electron approach based on the X-operator representation. Extending the projection operators approach on arbitrary energy spectra of the Mott-Hubbard insulator, we obtained the Hamiltonian of
superexchange
interaction in analytical form. The Hamiltonian includes the spin-exciton variables which are usually missing in discussion on the magnetic response to optical pumping, and is not additive over contributions from the ground and optically excited states. As a test, a microscopic background for the optical induced
superexchange
was analyzed in La2CuO4 (further La214).
Мы исcледовали эффекты возбужденных многоэлектронных состояний в оптическом способе управления магнитным состоянием недопированных Мотт-Хаббардовских материалов. Для вывода спинового гамильтониана в веществе под воздействием оптической накачки был использован многоэлектронный метод, основанный на представлении X-операторов. С помощью обобщенного на произвольный энергетический спектр метода проекционных операторов мы получили гамильтониан суперобменного взаимодействия в аналитической форме. Гамильтониан является не аддитивными по вкладам от основных и оптически возбуждённых состояний, а также содержит спин-экситонные переменные, которые обычно отсутствуют в обсуждении магнитного отклика на оптическую накачку. В качестве конкретного приложения для теории мы рассчитали индуцированный суперобмен для оптически возбужденного купрата La2CuO4 (в дальнейшем La214).
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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Akademgorodok, 50/38, Krasnoyarsk, Russian Federation
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Svobodny, 79, Krasnoyarsk, Russian Federation
Доп.точки доступа:
Gavrichkov, V. A.; Гавричков, Владимир Александрович; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Полукеев, Семен Игоревич
}
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11.
Polukeev, S. I.
Exchange interaction in LaCoO3 between cobalt ions Co3+ in different spin states / S. I. Polukeev, V. A. Gavrichkov, S. G. Ovchinnikov> // Phys. Solid State. - 2022. -
Vol. 64
,
Is. 12
. - P. 1887-1890,
DOI
10.21883/PSS.2022.12.54381.426. - Cited References: 38. - The work was carried out with the financial support of the Russian Foundation for Basic Research (project No. 20-42-240016) . - ISSN 1063-7834. - ISSN 1090-6460
Кл.слова (ненормированные):
superexchange
interaction
--
magnetic structure
--
Hubbard model
--
projection operator method
--
exchange loop
Аннотация:
The values and signs of the contributions to the
superexchange
interaction of Co3+ ions in LaCoO3 in different spin states, namely, the
superexchange
of a pair of ions in the intermediate (IS) state and the
superexchange
of a pair of ions, one of which is in the intermediate state and the other in the high-spin (HS) state, are studied. For this purpose, virtual electron-hole pairs produced in the course of
superexchange
(the so-called exchange loops) have been studied within the framework of a multiband generalization of the Hubbard model. It is shown that the cobalt ions in the intermediate state are ordered ferromagnetically, while a pair of ions in different HS and IS states makes an AFM contribution to the
superexchange
.
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Публикация на русском языке
Полукеев, Семен Игоревич. Обменное взаимодействие в LaCoO3 между ионами кобальта Co3+ в различных спиновых состояниях [Текст] / С. И. Полукеев, В. А. Гавричков, С. Г. Овчинников // Физ. тверд. тела. - 2022. - Т. 64 Вып. 12. - С. 1916-1919
Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
Доп.точки доступа:
Gavrichkov, V. A.; Гавричков, Владимир Александрович; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Полукеев, Семен Игоревич
}
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12.
KRUSTALEV, B. P.
EXCHANGE INTERACTIONS IN SUPERPARAMAGNETIC NANOCLUSTER FILMS FE-SIO / B. P. KRUSTALEV, A. D. BALAEV, V. M. SOSNIN> // Solid State Commun. - 1995. -
Vol. 95
,
Is. 5
. - P. 271-275,
DOI
10.1016/0038-1098(95)00264-2. - Cited References: 9 . - ISSN 0038-1098
РУБ
Physics, Condensed Matter
Кл.слова (ненормированные):
NANOSTRUCTURES
--
THIN FILMS
--
EXCHANGE AND
SUPEREXCHANGE
Аннотация:
The magnetic properties of superparamagnetic films Fe-SiO have been investigated. It has been shown that a proper consideration of intra- and intercluster interactions describes well the magnetic behavior of the films. Their main parameters have been determined. On the basis of a proposed cluster model, the decrease of the effective magnetic moment per one iron atom is explained.
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Доп.точки доступа:
BALAEV, A. D.; Балаев, Александр Дмитриевич; SOSNIN, V. M.; Соснин, Виктор Михайлович
}
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13.
Ferromagnetism in single-valent
manganites / I. O. Troyanchuk [et al.]> // J. Alloys Compd. - 2015. -
Vol. 619
. - P. 719-725,
DOI
10.1016/j.jallcom.2014.08.236. - Cited References: 46. - The authors would like to thank J.B. Goodenough for the fruitful discussion. This work has been supported by Belarusian Republican Foundation for Fundamental Research (Grant F14R-040). . - ISSN 0925-8388. - ISSN 1873-4669
РУБ
Chemistry, Physical + Materials Science, Multidisciplinary + Metallurgy & Metallurgical Engineering
Рубрики:
PHASE-SEPARATION
DOPED MANGANITES
DOUBLE EXCHANGE
DIFFRACTION
OXIDES
NMR
Кл.слова (ненормированные):
Magnetically ordered materials
--
Solid state reactions
--
Exchange and
superexchange
--
Magnetic measurements
--
Neutron diffraction
Аннотация:
Structural and magnetization measurements have been performed on the La0.7Sr0.3Mn0.85 Nb 0.15 - x 5 + Mg x 2 + O3 stoichiometric compounds. With rise of the Mg2+ content the formal oxidation state manganese increases from +3 ( x = 0 ) up to +3.55 ( x = 0.15 ) . The compositions with 0 ⩽ x ≤ 0.08 undergo a structural transition from rhombohedral to orthorhombic symmetry below room temperature whereas x = 0.1 and x = 0.15 compounds are rhombohedral down to 2 K. The structural parameters evidence that the orthorhombic phase is not long-range orbitally ordered and that the structural transition is associated with a steric effect. The Mg-free compound is ferromagnetic with the Curie point of around 150 K and a magnetic moment of 3.1 μ B /Mn. The substitution of Nb5+ with Mg2+ leads to a gradual weakening of the ferromagnetic component while in the x = 0.15 compound A-type antiferromagnetic short-range order is stabilized in spite of macroscopic R 3 ¯ c symmetry. All the compositions show insulating behavior. It is suggested that ferromagnetism is originated from
superexchange
interactions via oxygen. Covalence enhances the positive part of the
superexchange
interactions whereas structural disorder induced by Nb5+ and Mg2+ ions leads to suppression of ferromagnetism.
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Держатели документа:
Sci Pract Mat Res Ctr NAS Belarus, Minsk 220072, Byelarus
Helmholtz Zentrum Berlin, D-14109 Berlin, Germany
Joint Inst Nucl Res, Dubna 141980, Russia
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Inst Max Von Laue Paul Langevin, F-38042 Grenoble 9, France
ISMRA Univ Caen, UMR Associee CNRS 6508, Lab CRISMAT, F-14050 Caen, France
Univ Caen, F-14050 Caen, France
Доп.точки доступа:
Troyanchuk, I. O.; Bushinsky, M. V.; Sikolenko, V.; Efimov, V.; Volkov, N. V.; Волков, Никита Валентинович; Tobbens, D. M.; Ritter, C.; Raveau, B.
}
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14.
Martynov, S. N.
Ground State of a Two-Sublattice Anisotropic Ferromagnet in a Magnetic Field / S. N. Martynov> // Phys. Solid State. - 2021. -
Vol. 63
,
Is. 8
. - P. 1253-1261,
DOI
10.1134/S1063783421080199. - Cited References: 38. - This study was supported by the Russian Foundation for Basic Research and the Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project no. 20-42-240006 "Synthesis and Study of Pb2+-and Bi3+Containing Oxide Single Crystals with Partial Substitution in One of the Subsystems: Magnetic Structures and Magnetodielectric Effect" . - ISSN 1063-7834. - ISSN 1090-6460
РУБ
Physics, Condensed Matter
Рубрики:
ANTIFERROMAGNETIC-RESONANCE
SUPEREXCHANGE
INTERACTION
WEAK FERROMAGNETISM
Кл.слова (ненормированные):
ferromagnetism
--
single-ion anisotropy
--
antisymmetric exchange
--
orientational phase transition
Аннотация:
The ground state of a classical two-sublattice ferromagnet with the noncollinear single-ion anisotropy axes of the sublattices and the antisymmetric and anisotropic symmetric exchanges between them has been investigated in a magnetic field applied along the hard magnetization directions in the crystal. The threshold relations for the parameters of the anisotropic interactions have been obtained, which determine the choice of the ground state among the three possible magnetic phases. Depending on the ground state type and the field direction, the transition between the phases is a first- or second-order phase transition. The antisymmetric exchange value above which the reorientation between the noncollinear phases ends with a second-order transition depends on the angle between the local easy axes and the single-ion anisotropy value. Field dependences of the magnetization and susceptibility for different ground states have been calculated. A comparison with the results of the magnetic measurements in the highly anisotropic PbMnBO4 ferromagnet has been made.
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Публикация на русском языке
Мартынов, Сергей Николаевич. Основное состояние двухподрешеточного анизотропного ферромагнетика в магнитном поле [Текст] / С. Н. Мартынов // Физ. тверд. тела. - 2021. - Т. 63 Вып. 8. - С. 1090-1097
Держатели документа:
Russian Acad Sci, Krasnoyarsk Sci Ctr, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.
Доп.точки доступа:
Мартынов, Сергей Николаевич; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Krasnoyarsk Territorial Foundation [20-42-240006]
}
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15.
Polukeev, S. I.
In-gap excitation effect on a
superexchange
in La2CuO4 by creating a nonequilibrium photoexcited centers / S. I. Polukeev, V. A. Gavrichkov, S. G. Ovchinnikov> //
VI Euro-Asian Symposium "Trends in MAGnetism" (EASTMAG-2016) : abstracts / ed.: O. A. Maksimova, R. D. Ivantsov. - Krasnoyarsk : KIP RAS SB, 2016. - Ст. P1.30. - P. 90-91. - References: 10. - This work was supported by RFBR Grant 16-02-00273 . - ISBN 978-5-904603-06-9
Кл.слова (ненормированные):
superexchange
--
Mott-Hubbard materials
--
light pumping
--
La214
Доп.точки доступа:
Gavrichkov, V. A.; Гавричков, Владимир Александрович; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Полукеев, Семен Игоревич; Euro-Asian Symposium "Trends in MAGnetism"(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); "Trends in MAGnetism", Euro-Asian Symposium(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); Институт физики им. Л.В. Киренского Сибирского отделения РАН
Нет сведений об экземплярах
}
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16.
Gavrichkov, V. A.
Magnetic interaction in doped 2D perovskite cuprates with nanoscale inhomogeneity: Lattice nonlocal effects vs.
superexchange
/ V. A. Gavrichkov, S. I. Polukeev> // Condens. Matter. - 2022. -
Vol. 7
,
Is. 4
. - Ст. 57,
DOI
10.3390/condmat7040057. - Cited References: 78. - This work was supported by the Russian Science Foundation, research grant RSF No.22-22-00298 . - ISSN 2410-3896
Перевод заглавия:
Магнитное взаимодействие в допированных 2d перовскитах с наноразмерной неоднородностью: решеточные нелокальные эффекты против суперобмена
Кл.слова (ненормированные):
superexchange
interaction
--
nanoscale inhomogeneity
--
doped 2D perovskite cuprates
Аннотация:
We have studied the
superexchange
interaction Jij in doped 2D cuprates. The AFM interaction strongly depends on the state of the lattice of a CuO2 layer surrounded by two LaO rock salt layers. In a static U and D stripe nanostructure, the homogeneous AFM interaction is impossible due to the U/D/U… periodic stripe sequence and TN=0. In a dynamic stripe nanostructure, the ideal CuO2 layer with nonlocal effects and the homogeneous AFM interaction are restored. However, the interaction Jij decreases by the exponential factor due to partial dynamic quenching. The meaning of the transition from the dynamic to the static cases lies in the spontaneous θ-symmetry breaking with respect to the rotation of all the tilted CuO6 octahedra by an orientation angle δθ=n⋅(45°) (where n=1÷4) in the U and D stripe nanostructure of the CuO2 layer. Moreover, the structural features help to study various experimental data on the charge inhomogeneity, Fermi level pinning in the p type cuprates only and time reversal symmetry breaking from a unified point of view.
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Держатели документа:
Kirensky Institute of Physics, Akademgorodok 50, building 38, 660036 Krasnoyarsk, Russia
Доп.точки доступа:
Polukeev, S. I.; Полукеев, Семен Игоревич; Гавричков, Владимир Александрович
}
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17.
Gavrichkov, V. A.
Magnetic interaction in doped 2D perovskites with nanoscale inhomogenety: lattice nonlocal effects vs
superexchange
/ V. A. Gavrichkov, S. I. Polukeev> //
XIX Конференция "Сильно коррелированные электронные системы и квантовые критические явления" : сборник тезисов / чл. прогр. ком. С. Г. Овчинников и др. - Москва, 2022. - P. 194-196. - Библиогр.: 1 . - ISBN 978-5-4344-0954-4
,
Материалы конференции
Доп.точки доступа:
Овчинников, Сергей Геннадьевич \чл. прогр. ком.\; Ovchinnikov, S. G.; Polukeev, S. I.; Гавричков, Владимир Александрович; "Сильно коррелированные электронные системы и квантовые критические явления", конференция(19 ; 2022 ; 26 мая ; Москва); Российская академия наук; Физический институт им. П.Н. Лебедева РАН
}
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18.
Sofronova, S. N.
Magnetic ordering and the role of
superexchange
Ni–O–B–O–Ni upon the formation of magnetic order in ludwigite Ni2MnBO5 from first-principal calculations / S. Sofronova, A. Chernyshev> // Comput. Condens. Matter. - 2024. -
Vol. 40
. - Ст. e00918,
DOI
10.1016/j.cocom.2024.e00918. - Cited References: 28 . - ISSN 2352-2143
Кл.слова (ненормированные):
Exchange interactions
--
Magnetic order
--
Ferrimagnets
--
Non-collinear ordering
--
Superexchange
interactions
Аннотация:
The energies of various magnetically ordered structures for ludwigite Ni2MnBO5 have been calculated in the framework of the first-principles approach using the Wien2K program package, with the parameters of exchange interactions being determined. Two subsystems can be distinguished in the magnetic system, which are associated with the triads 4-2-4 and 3-1-3. The magnetic moments of the ions in both triads are antiferromagnetically oriented. The analysis of the exchange contribution to the energy shows that there occurs an increase of the magnetic cell relative to the crystallographic one due to antiferromagnetic ordering of the magnetic moments along the c axis in three-legged ladders formed by 4-2-4 triads. However, in three-legged ladders formed by 3-1-3 triads, the magnetic moments of the ions are ordered along the c-axis ferromagnetically. The predicted type of magnetic ordering in Ni2MnBO5 is similar to magnetic ordering in Fe3BO5. Non-collinear ordering of the magnetic moments of the subsystems at different temperatures is also likely to be observed in Ni2MnBO5, as is the case in Fe3BO5.
Superexchange
(indirect) interactions (No-O-B-O-Ni) influence the orientation of the magnetic moments of two 3-1-3 (4-2-4) triads within the unit cell. It is these interactions that may be responsible for the formation of long-range magnetic order in Co3BO5 and ferrimagnetic-antiferromagnetic spin-reorientation transition in Fe3BO5.
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Держатели документа:
Kirensky Institute of Physics of the Federal Research Center “Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences”, 660036, Krasnoyarsk, Russia
Доп.точки доступа:
Chernyshev, A. V.; Чернышев, Артем Валерьевич; Софронова, Светлана Николаевна
}
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19.
Magnetic structure of
CoFeBO4 warwickite in terms of
superexchange
[Текст] / Yu. V. Knyazev [и др.]> //
Moscow Int. Symp. on Magnet. (MISM-2014) : Book of abstracts. - 2014. - Ст. 1PO-I1-12. - P. 447 . - ISBN 978-5-91978-025-0
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Доп.точки доступа:
Knyazev, Yu.V.; Князев, Юрий Владимирович; Bayukov, O. A.; Баюков, Олег Артемьевич; Ivanova, N. B.; Иванова, Наталья Борисовна; Kazak, N. V.; Казак, Наталья Валерьевна; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Platunov, M. S.; Платунов, Михаил Сергеевич; Arauzo, A.; Араузо А.; Bartolomé, J.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Moscow International Symposium on Magnetism(6 ; 2014 ; 29 June-3 July ; Moscow); Московский государственный университет им. М.В. Ломоносова
}
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20.
Pressure effect on
the energy structure and
superexchange
interaction in undoped orthorhombic La2CuO4 / V. A. Gavrichkov [et al.]> // Int. J. Mod. Phys. B. - 2016. -
Vol. 30
,
Is. 25
,
DOI
10.1142/S0217979216501800 . - ISSN 0217-9792
Кл.слова (ненормированные):
antiferromagnetic La214
--
pressure
--
Superexchange
interaction
Аннотация:
We studied the pressure dependences of the electronic structure and
superexchange
interaction J(P)=JA−JB (where JA and JB are antiferromagnetic (AFM) and ferromagnetic (FM) contributions) in antiferromagnetic La214 under hydrostatic, uniaxial (along c-axial) 3% compressions and 1% in-plane compressions by the local density approximation with generalized tight-binding method (LDA + GTB cell approach). The changes in J(P) correlated with the experimentally known TC(P) dependence are in accordance with the relation dTC/dP=(∂TC/∂J)(∂J/∂P), where ∂TC/∂J∼0.1. The in-plane pressure more effectively stabilizes the ground singlet two-hole state A1 than the simple hydrostatic pressure, its effect on J and TC is the largest. Within the same cell approach together with the
superexchange
interaction J(P), the valence band structure was calculated. Its changes with pressure clearly reproduce the k-distribution of the singlet and triplet quasi-particles over the Brillouin zone (BZ).
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Держатели документа:
L. V. Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, Russian Federation
M. N. Miheev Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation
Department of Theoretical Physics and Applied Mathematics, Ural Federal University, 19 Mira St., Ekaterinburg, Russian Federation
Institute of Electrophysics, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation
Доп.точки доступа:
Gavrichkov, V. A.; Гавричков, Владимир Александрович; Pchelkina, Z. V.; Nekrasov, I. A.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич
}
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