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1.


   
    Experimental implementation of tunable hybrid Tamm-microcavity modes / P. S. Pankin, V. S. Sutormin, V. A. Gunyakov [et al.] // Appl. Phys. Lett. - 2021. - Vol. 119, Is. 16. - Ст. 161107, DOI 10.1063/5.0067179. - Cited References: 60. - The authors are grateful to M. N. Krakhalev for helpful discussions. Electrical control of hybrid modes was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research, Project No. 19-42-240004. Temperature control of hybrid modes was funded by Russian Foundation for Basic Research, Project No. 19-52-52006 and No. MOST 108-2923-E-009-003-MY3, Taiwan. P. S. Pankin is grateful for the support of the President of the Russian Federation under Grant No. MK-4012.2021.1.2. This study was supported by the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center KSC SB RAS . - ISSN 0003-6951. - ISSN 1077-3118
РУБ Physics, Applied
Рубрики:
STATES
   CRYSTALS

   LAYER

Аннотация: Mode hybridization is a unique way to manipulate the mode inside a fixed cavity or at interface. For example, Tamm plasmon-polariton at solid interface can be spectrally shifted without tuning the interface. Experimental implementation of tunable hybrid Tamm-microcavity modes is reported. The hybrid modes are excited in a one-dimensional photonic crystal bounded with a gold layer by attaching a nematic liquid crystal microcavity. Coupling between Tamm plasmon-polariton and microcavity modes leads to repulsion of their dispersion curves controlled by the refractive index of a liquid crystal and the polarization of incident light. Effective tuning of hybrid modes through heating or applying an external electric field to the liquid crystal layer is demonstrated. The experimentally measured strength coupling value between Tamm and microcavity modes was 20.7 meV.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
AO NPP Radiosvyaz, Krasnoyarsk 660021, Russia.
Reshetnev Siberian State Univ Sci & Technol, Krasnoyarsk 660037, Russia.
Natl Yang Ming Chiao Tung Univ, Tainan 71150, Taiwan.

Доп.точки доступа:
Pankin, P. S.; Панкин, Павел Сергеевич; Sutormin, V. S.; Сутормин, Виталий Сергеевич; Gunyakov, V. A.; Гуняков, Владимир Алексеевич; Zelenov, F. V.; Tambasov, I. A.; Тамбасов, Игорь Анатольевич; Masyugin, A. N.; Volochaev, M. N.; Волочаев, Михаил Николаевич; Baron, F. A.; Барон, Филипп Алексеевич; Chen, K. P.; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Vetrov, S. Ya.; Ветров, Степан Яковлевич; Timofeev, I. V.; Тимофеев, Иван Владимирович; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of Krasnoyarsk Territory; Krasnoyarsk Region Science and Technology Support Fund [19-42-240004]; Russian Foundation for Basic Research, TaiwanRussian Foundation for Basic Research (RFBR) [19-52-52006, MOST 108-2923-E-009-003-MY3]; Russian FederationRussian Federation [MK-4012.2021.1.2]; Krasnoyarsk Regional Center of Research Equipment of Federal Research Center KSC SB RAS
}
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2.


   
    Monoclinic SmAl3(BO3)4: synthesis, structural and spectroscopic properties / A. S. Oreshonkov, N. P. Shestakov, M. S. Molokeev [et al.] // Acta Crystallogr. B. - 2020. - Vol. 76. - P. 654-660, DOI 10.1107/S2052520620008781. - Cited References: 38. - Funding for this research was provided by: Russian Foundation for Basic Research (grant Nos. 18-03-00750, 18-05-00682 and 18-32-20011 to AO) . - ISSN 2052-5206
   Перевод заглавия: Моноклинный SmAl3(BO3)4: синтез, структура и спектроскопические свойства
РУБ Chemistry, Multidisciplinary + Crystallography
Рубрики:
Optical-properties
   Luminescence

   Spectra

   Crystals

   Sm

Кл.слова (ненормированные):
IR spectroscopy -- monoclinic structure -- luminescence -- Raman spectroscopy -- X-ray diffraction -- crystal structure
Аннотация: Single crystals of SmAl3(BO3)4 were synthesized by the group growth on seeds method. The crystal structure was solved using a single-crystal experiment and the purity of the bulk material was proved by the Rietveld method. This borate crystallizes in the monoclinic C2/c space group with unit-cell parameters a = 7.2386 (3), b = 9.3412 (5), c = 11.1013 (4) Å and β = 103.2240 (10)°. IR and Raman spectroscopic analyses confirmed the monoclinic structure of SmAl3(BO3)4. Under 532.1 nm excitation, luminescence spectra exhibit bands assignable to the transitions from 4G5/2 to 6H5/2, 6H7/2, 6H9/2 and 6H11/2. The similarity of the luminescence spectra of the trigonal and monoclinic poly­morphs is explained by the minor role of Sm—O bond distortion and the primary role of rotational distortion of SmO6 octa­hedra. The smaller covalency of the Sm—O bond in alumoborates is deduced in comparison with galloborates. Calorimetric measurements did not reveal high-temperature structural phase transitions up to a temperature of 720 K.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Mol Spect, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Sch Engn & Construct, Krasnoyarsk 660041, Russia.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk, Russia.
Siberian Fed Univ, Sch Engn Phys & Radio Elect, Krasnoyarsk 660041, Russia.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Coherent Opt, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Inst Nanotechnol Spect & Quantum Chem, Krasnoyarsk 660041, Russia.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Radiospect & Spintron, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Inst Automat & Electrometry, Novosibirsk 630090, Russia.
Fed Res Ctr KSC SB RAS, Dept Mol Elect, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660074, Russia.
Tyumen State Univ, Dept Inorgan & Phys Chem, Tyumen 625003, Russia.
Ind Univ Tyumen, Dept Gen & Special Chem, Tyumen 625000, Russia.

Доп.точки доступа:
Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Shestakov, N. P.; Шестаков, Николай Петрович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович; Adichtchev, S. V.; Pugachev, A. M.; Nemtsev, I. V.; Немцев, Иван Васильевич; Pogoreltsev, E. I.; Погорельцев, Евгений Ильич; Denisenko, Y. G.; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-03-00750, 18-05-00682, 18-32-20011]
}
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3.


   
    Temperature-dependent absorption lines observation in Raman spectra of SmFe3 (BO3)4 ferroborate / E. Moshkina [et al.] // J. Raman Spectrosc. - 2018. - Vol. 49, Is. 10. - P. 1732-1735, DOI 10.1002/jrs.5430. - Cited References: 12. - RFBR, Grant/Award Numbers: 18-02-00696 and 18-02-00754 . - ISSN 0377-0486. - ISSN 1097-4555
   Перевод заглавия: Температурно зависимые линии поглощения в спектрах комбинационного рассеяния ферробората SmFe3(BO3)4
РУБ Spectroscopy
Рубрики:
SmFe3 (BO3)4
   Ho1-xNdxFe3(BO3)4

   CRYSTALS

Кл.слова (ненормированные):
absorption -- ferroborates -- huntite -- level splitting -- magnetic phase -- transitions
Аннотация: The paper demonstrates possibilities of observation and thermal dependency study of the absorption lines as a co‐product of Raman spectroscopy study in SmFe3 (BO3)4 ferroborate. Raman spectra of the ferroborate were studied in a wide temperature range (T = 10÷300 K). Temperature‐dependent absorption lines sensitive to the magnetic phase transition have been observed in Raman spectra at two spectral ranges.

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Держатели документа:
RAS, Fed Res Ctr KSC SB, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian State Univ Sci & Technol, Krasnoyarsk, Russia.

Доп.точки доступа:
Moshkina, E. M.; Мошкина, Евгения Михайловна; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович; Krylov, A. S.; Крылов, Александр Сергеевич; RFBR [18-02-00696, 18-02-00754]
}
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4.


    Martynov, S. N.
    Single-ion mechanism of weak ferromagnetism and a spin-flop transition in one- and two-position antiferromagnets / S. N. Martynov // JETP Letters. - 2018. - Vol. 108, Is. 3. - P. 196-200, DOI 10.1134/S0021364018150080. - Cited References: 10. - I am grateful to A.D. Balaev, V.I. Zinenko, and A.I. Pankrats for stimulating discussions. This work was supported by the Russian Foundation for Basic Research (project no. 16-02-00563). . - ISSN 0021-3640. - ISSN 1090-6487
Рубрики:
HEISENBERG FERRIMAGNET
   PB2FE2GE2O9

   CRYSTALS

Аннотация: A system of equations describing the ground state in an external magnetic field has been obtained for a twoposition antiferromagnet with noncollinear axes of single-ion anisotropy of moments of different sublattices. It has been shown that the antiferromagnetism vector changes sign at a spin-flop transition. This leads to a first-order magnetic phase transition with hysteresis in the field dependence of the magnetization. Explicit relations have been obtained between the parameters of a microscopic Hamiltonian and the experimentally observed spontaneous moment and spin-flop transition field. It has been shown that the field dependence of the total magnetic moment of the antiferromagnet with magnetic ions at two crystallographically nonequivalent positions (two-position antiferromagnet) obtained within the two-sublattice model is nonlinear above the transition field at any orientation of the crystal with respect to the magnetic field.

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Публикация на русском языке Мартынов, Сергей Николаевич. Одноионный механизм слабого ферромагнетизма и спин-флоп переход в одно- и двухпозиционном антиферромагнетике [Текст] / С. Н. Мартынов // Письма в ЖЭТФ. - 2018. - Т. 108 Вып. 3. - С. 196-200

Держатели документа:
Russian Acad Sci, Siberian Branch, Krasnoyarsk Sci Ctr, Kirensky Inst Phys,Fed Res Ctr, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Мартынов, Сергей Николаевич; Russian Foundation for Basic Research [16-02-00563]
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5.


   
    Thermal properties of rare earth cobalt oxides and of La1–xGdxCoO3 solid solutions / Y. S. Orlov [et al.] // JETP Letters. - 2016. - Vol. 103, Is. 9. - P. 607-612, DOI 10.1134/S0021364016090058. - Cited References: 21. - This work was supported by the Russian Foundation for Basic Research, project nos. 16-02-00507 and 16-02-00098, and by the Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools, project no. SP-1844.2016.1. The X-ray diffraction analysis of the crystal structure and the measurement of specific heat were supported by the Siberian Branch, Russian Academy of Sciences (project no. V.45.3.1). . - ISSN 0021-3640
РУБ Physics, Multidisciplinary
Рубрики:
PROFILE REFINEMENT
   SPIN

   CRYSTALS

Аннотация: Powder X-ray diffraction data for the crystal structure, phase composition, and molar specific heat for La1‒xGdxCoO3 cobaltites in the temperature range of 300–1000 K have been analyzed. The behavior of the volume thermal expansion coefficient in cobaltites with isovalent doping in the temperature range of 100–1000 K is studied. It is found that the β(T) curve exhibits two peaks at some doping levels. The rate of the change in the occupation number for the high-spin state of cobalt ions is calculated for the compounds under study taking into account the spin–orbit interaction. With the Birch–Murnaghan equation of state, it is demonstrated that the low-temperature peak in the thermal expansion shifts with the growth of the pressure toward higher temperatures and at pressure P ∼ 7 GPa coincides with the second peak. The similarity in the behavior of the thermal expansion coefficient in the La1–xGdxCoO3 compounds with the isovalent substitution and the undoped LnCoO3 compound (Ln is a lanthanide) is considered. For the whole series of rare earth cobalt oxides, the nature of two specific features in the temperature dependence of the specific heat and thermal expansion is revealed and their relation to the occupation number for the high-spin state of cobalt ions and to the insulator–metal transition is established.

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Публикация на русском языке Термодинамические свойства редкоземельных оксидов кобальта и твердых растворов La1–xGdxCoO3 [Текст] / Ю. С. Орлов [и др.] // Письма в Журн. эксперим. и теор. физ. : Наука, 2016. - Т. 103 Вып. 9-10. - С. 689-694

Держатели документа:
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, Russian Federation
Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk, Russian Federation
Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, Russian Federation
National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), Kashirskoe sh. 31, Moscow, Russian Federation

Доп.точки доступа:
Orlov, Yu. S.; Орлов, Юрий Сергеевич; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Gorev, M. V.; Горев, Михаил Васильевич; Vereshchagin, S. N.; Solov’ev, L. A.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич
}
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6.


    Klimin, S. A.
    Spin-phonon and electron-phonon interactions in multiferroic GdFe3(BO3)4 and TbFe3(BO3)4 evidenced by IR reflection spectroscopy / S. A. Klimin, M. A. Kashchenko, L. N. Bezmaternykh // J. Low Temp. Phys. - 2016. - Vol. 185, Is. 5-6. - P. 538-543, DOI 10.1007/s10909-016-1597-6. - Cited References:19. - The authors thank Alexey Kuzmenko and Marina Popova for fruitful discussions. This paper was supported by the Russian Science Foundation under Grant No. 14-12-01033, by the Swiss National Science Foundation (SNSF), and by the Science and Technology cooperation program "Switzerland-Russia" of the University of Geneva. . - ISSN 0022-2291. - ISSN 1573-7357
РУБ Physics, Applied + Physics, Condensed Matter
Рубрики:
PHASE-TRANSITIONS
   GdFe3(BO3)4

   CRYSTALS

   SPECTRUM

Кл.слова (ненормированные):
Multiferroics -- IR-active phonons -- Spin-phonon interaction -- Coupled -- electron-phonon mode
Аннотация: We study temperature-dependent polarized reflection spectra of multiferroic GdFe3(BO3)4 and TbFe3(BO3)4 single crystals. Signatures of spin–lattice interactions in both compounds and of a formation of the electron–phonon coupled mode in TbFe3(BO3)4 are discussed.

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Держатели документа:
Inst Spect RAS, Moscow 108840, Russia.
Moscow Inst Phys & Technol, Dolgoprudnyi 141700, Moscow Region, Russia.
RAS, Siberian Branch, Kirenskiy Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Kashchenko, M. A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Russian Science Foundation [14-12-01033]; Swiss National Science Foundation (SNSF); Science and Technology cooperation program "Switzerland-Russia" of the University of Geneva
}
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7.


   
    Structural transformations and phenomenological description of the formation of phase states in elpasolites Cs2RbDyF6 and Rb2KB′F6 (B′ = Ho, Dy, Tb) / I. N. Safonov [et al.] // Phys. Solid State. - 2015. - Vol. 57, Is. 3. - P. 491-498, DOI 10.1134/S1063783415030282. - Cited References:20. - This study was supported by the Ministry of Education and Science of the Russian Federation within the framework of the State Task for the Russian Siberian Federal University for Implementation of Scientific Research Work in 2014 (assignment no. 3.2534.2014/K). . - ISSN 1063. - ISSN 1090-6460. -
РУБ Physics, Condensed Matter
Рубрики:
TRANSITIONS
   CRYSTALS

Аннотация: The structures of the cubic and monoclinic phases of an Rb2KHoF6 crystal from a series of elpasolites Rb2KB′F6 (B′ = Ho, Dy, Tb), which undergoes a trigger phase transition, have been investigated using X-ray powder diffraction. The critical and noncritical displacements of atoms in the Rb2KHoF6 structure have been determined from the group-theoretical analysis of the complete condensate of order parameters. It has been reliably established that a change in the symmetry due to the phase transition in this crystal can be represented in the form Fmˉ3m11−9(Γ+4)⊕10−3(X+3)(ϕ,ϕ,ψ)P121/n1Fm\bar 3m\frac{{11 - 9(\Gamma _4. + ) \oplus 10 - 3(X_3. + )}} {{(\phi ,\phi ,\psi )}}P12_1 /n1 . A phenomenological analysis of the conditions responsible for the formation of phase states upon the phase transitions in elpasolites Cs2RbDyF6 and Rb2KB′F6 (B′ = Ho, Dy, Tb) has been carried out. Taking into account the structural data and using the phenomenological theory, it has been found that the main factor determining the formation of phase states in these and related crystals is the instability of the elpasolite structure with respect to rotational distortions of two types. It has been shown that an important role in the formation of a sequence of structural transformations in these crystals is played by the interaction of rotational order parameters and displacements of the cation from the center of a cuboctahedral hole.

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Публикация на русском языке Структурные превращения и феноменологическое описание формирования фазовых состояний в эльпасолитах Cs2RbDyF6 и Rb2KB'F6 (B'=Ho, Dy, Tb) [Текст] / И. Н. Сафонов [и др.] // Физ. тверд. тела : Физико-технический институт им. А. Ф. Иоффе РАН, 2015. - Т. 57 Вып. 3. - С. 480-486

Держатели документа:
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia.
Southern Fed Univ, Inst Phys Res, Rostov Na Donu 344090, Russia.

Доп.точки доступа:
Safonov, I. N.; Misyul', S. V.; Мисюль, Сергей Валентинович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Ivliev, M. P.; Ministry of Education and Science of the Russian Federation [3.2534.2014/K]
}
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8.


    Mel'nikova, S. V.
    Optical studies of the (T-x) phase diagram of oxyfluoride (NH4)2MoO2F4-Rb2MoO2F4 solid solutions / S. V. Mel'nikova, N. M. Laptash // Phys. Solid State. - 2015. - Vol. 57, Is. 6. - P. 1201-1205, DOI 10.1134/S1063783415060256. - Cited References:8. - This study was supported by the Council on Grants from the President of the Russian Federation for Supporting of Leading Scientific Schools of the Russian Federation (grant NSh-924.2014.2). . - ISSN 1063. - ISSN 1090-6460. -
РУБ Physics, Condensed Matter
Рубрики:
TRANSITIONS
   (NH4)2WO2F4

   CRYSTALS

   DISORDER

Аннотация: Single crystals of solid solutions (NH4)2 − x Rb x MoO2F4 (including individual complex Rb2MoO2F4) have been grown and studied using polarization-optical methods. The birefringence Δn(T) has been measured in the temperature range of 100–400 K. The complete (T-x) phase diagram has been constructed.

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Публикация на русском языке Мельникова, Светлана Владимировна. Оптические исследования фазовой (T-x)-диаграммы твердых растворов оксифторидов (NH4)2MoO2F4-Rb2MoO2F4 [Текст] / С. В. Мельникова, Н. М. Лапташ // Физ. тверд. тела : Физико-технический институт им. А. Ф. Иоффе РАН, 2015. - Т. 57 Вып. 6. - С. 1180-1184

Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Far Eastern Branch, Inst Chem, Vladivostok 690022, Russia.

Доп.точки доступа:
Laptash, N. M.; Мельникова, Светлана Владимировна; Russian Federation [NSh-924.2014.2]
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9.


   
    Enhancing of magnetic flux pinning in YBa2Cu3O7-x/CuO granular composites / A. V. Ushakov [et al.] // J. Appl. Phys. - 2015. - Vol. 118, Is. 2. - Ст. 023907, DOI 10.1063/1.4926549. - Cited References: 27. - This work was supported in part by the Ministry of Education and Science of the Russian Federation (Project No. 11.370.2014/K). . - ISSN 0021-8979
РУБ Physics, Applied
Рубрики:
HIGH-TEMPERATURE SUPERCONDUCTORS
   T-C SUPERCONDUCTORS

   CRITICAL CURRENTS

   GRAIN-BOUNDARIES

   CRYSTALS

   DEFECTS

Аннотация: This paper shows that the combination of self-assembled structures in the form of "whiskers" and nanoparticles, which appear as a result of the joint sintering powders YBa2Cu3O7-x and arc nanopowders CuO, leads to a significant increase in the current density and the appearance of the peak effect in strong magnetic fields range. Very high critical current density appears from a complex vortex pinning, where the defects in the form of "whiskers" provides more energy of pinning, and nanoparticles inhibit the flux creep. Regulation of the morphology of such structures can be achieved by simple change of the concentration of nanodispersed additives. It is shown that the optimal additive is CuO equal to 20 wt. %. © 2015 AIP Publishing LLC.

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Держатели документа:
Siberian Federal University, Krasnoyarsk, Russian Federation
Reshetnev Siberian State Aerospace University, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Ushakov, A. V.; Karpov, I. V.; Lepeshev, A. A.; Лепешев, Анатолий Александрович; Petrov, M. I.; Петров, Михаил Иванович; Ministry of Education and Science of the Russian Federation [11.370.2014/K]
}
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10.


   
    Spectral signatures of spin-phonon and electron-phonon interactions in multiferroic iron borates / M. N. Popova [et al.] // J. Magn. Magn. Mater. - 2015. - Vol. 383. - P. 250-254, DOI 10.1016/j.jmmm.2014.10.095. - Cited References:32. - This work was supported by the Russian Science Foundation (Grant no. 14-12-01033). Experiments at U4-IR beamline NSLS-BNL (T.N.S. and A.A.S.) were performed under Contract no. DE-FG02-07ER46382 from the U.S. Department of Energy. The National Synchrotron Light Source is operated as a User Facility for the U.S. Department of Energy under Contract no. DE-AC02-98CH10886. M.N.P. thanks B.Z. Malkin for helpful discussions. . - ISSN 0304-8853. - ISSN 1873-4766
РУБ Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
SMFE3(BO3)4
   SPECTROSCOPY

   CRYSTALS

   SM

Кл.слова (ненормированные):
Rare-earth iron borates -- Spin phonon interactions -- Electron phonon coupling -- Optical spectroscopy
Аннотация: High-resolution far-infrared reflection and polarized ellipsometry, as well as Raman scattering temperature-dependent measurements are used to study spin-phonon and electron-phonon interactions in rare-earth (RE) iron borates with the R32 structure of a natural mineral huntite, namely, in RFe3(BO3)4 with R=Pr, Nd, and Sm. Pronounced peculiarities in the ω(T) dependences at the Néel temperature TN≈32 K are observed for all the compounds studied and the origin of these peculiarities is discussed. A coupling between lattice phonons and crystal-field excitations of a RE ion manifests itself by a renormalization of frequencies and intensities of coupled modes. Modeling of the spectra has revealed the value of about 15 cm−1 for the electron–phonon coupling constant in PrFe3(BO3)4.
Высокоразрешающая эллипсометрия дальнего инфракрасного отражения и поляризованный света, а также температурнозависимые измерения комбинационного рассеяния используются для изучения спин-фононных и электрон-фононных взаимодействий в редкоземельных (RE) боратах железа со структурой R32 природного минерала хантита , а именно, в RFe3 (BO3) 4 с R = Pr, Nd, и Sm. Выраженные особенности ω (T) зависимостей при температуре Нееля TN ≈32 K наблюдаются для всех исследованных соединений и происхождение этих особенностей обсуждается.Связь между фононами решетки и возбуждениями кристаллического поля РЗ иона проявляется себя перенормализации частоты и интенсивности связанных мод. Моделирование спектров показал значение около 15cm-1 для константы электрон-фононной связи в PrFe3 (BO3) 4.

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Доп.точки доступа:
Popova, M. N.; Boldyrev, K. N.; Klimin, S. A.; Stanislavchuk, T. N.; Sirenko, A. A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Russian Science Foundation [14-12-01033]; U.S. Department of Energy [DE-FG02-07ER46382, DE-AC02-98CH10886]; Moscow International Symposium on Magnetism(6 ; 2014 ; June-July ; Moscow)
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