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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Anshits A. G., Bayukov O. A., Kondratenko E. V., Anshits N. N., Pletnev O. N., Rabchevskii E. V., Solovyov L. A.
Заглавие : Catalytic properties and nature of active centers of ferrospheres in oxidative coupling of methane
Коллективы : Russian Science Foundation [14-13-00289]
Место публикации : Appl. Catal. A-Gen.: Elsevier Science, 2016. - Vol. 524. - P.192-199. - ISSN 0926-860X, DOI 10.1016/j.apcata.2016.06.032. - ISSN 1873-3875(eISSN)
Примечания : Cited References:47. - This study was supported by the Russian Science Foundation (project no. 14-13-00289).
Предметные рубрики: GLASS CRYSTAL CATALYSTS
MAGNETIC-PROPERTIES
PROFILE REFINEMENT
FLY-ASH
MOSSBAUER
MICROSPHERES
PERFORMANCE
CONVERSION
ETHYLENE
OXIDE
Ключевые слова (''Своб.индексиров.''): methane coupling--active center--ferrospinel--mossbauer spectroscopy
Аннотация: Ferrospheres with the Fe2O3 content in the range from 76 to 97 wt% were applied as catalysts for the oxidative coupling of methane (OCM). To identify their phase composition and distribution of iron sites, the ferrospheres were characterized by X-ray powder diffraction and Mossbauer spectroscopy before and after the OCM reaction. Magnetite-based ferrite spinel, hematite and aluminosilicate glasses were established to be the main phases. The ferrospinel of all ferrospheres partially oxidized to hematite after the OCM reaction. It was established that the yield of C-2-hydrocarbons sharply increased at the ferrospheres with Fe2O3 content higher than 89 wt% The spinel phase of these ferrospheres includes Fevv3+(B) sites with a Ca2+ tetrahedral cation and an octahedral cation vacancy among the nearest neighbors. A linear correlation between the yield of C-2-hydrocarbons (ethane and ethylene) and the content of such sites was established, thus indicating that their electrophilic oxygen species participate in selective CH4 conversion to C2H6. (C) 2016 Elsevier B.V. All rights reserved.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Dudnikov V. A., Orlov Yu. S., Gavrilkin S. Yu., Gorev M. V., Vereshchagin S. N., Solovyov L. A., Perov N. S., Ovchinnikov S. G.
Заглавие : Effect of Gd and Sr ordering in a sites of doped Gd0.2Sr0.8CoO3-δ perovskite on its structural, magnetic, and thermodynamic properties
Место публикации : J. Phys. Chem. C: American Chemical Society, 2016. - Vol. 120, Is. 25. - P,13443-13449. - ISSN 19327447 (ISSN), DOI 10.1021/acs.jpcc.6b04810
Примечания : Cited References: 45. - The authors are thankful to the Russian Science Foundation (Project No. 16-13-00060) for financial support. The magnetic measurements were carried out in the Shared Facility Centre of P. N. Lebedev Physical Institute of RAS.
Предметные рубрики: Ln1-xSrxCoO(3-δ) Ln
PROFILE REFINEMENT
CRYSTAL-STRUCTURE
OXYGEN-CONTENT
COBALTITES
OXIDE
La1-xSrxCoO3-δ
Dy3+
SPIN
Ho3+
Аннотация: Magnetic and thermodynamic properties of perovskite Gd0.2Sr0.8CoO3−δ, with ordered and disordered states of Gd and Sr in the A-sites of the crystal lattice have been studied revealing remarkable differences in the physical properties of the ordered and disordered states. The ordered samples have larger oxygen nonstoichiometry, heat capacity, and thermal expansion anomalies, and abnormal temperature dependence of the magnetization around 350 K.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova N. B., Kazak N. V., Michel C. R., Balaev A. D., Ovchinnikov S. G., Vasil'ev A. D., Bulina N. V., Panchenko E. B.
Заглавие : Effect of strontium and barium doping on the magnetic state and electrical conductivity of GdCoO3
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007. - Vol. 49, Is. 8. - P1498-1506. - ISSN 1063-7834, DOI 10.1134/S1063783407080161
Примечания : Cited References: 36
Предметные рубрики: PEROVSKITE
ORDER
OXIDE
BEHAVIOR
GLASSES
LACOO3
PR
GD
SM
ND
Аннотация: A coordinated investigation of the magnetic and electrical properties of polycrystalline cobalt oxide compounds CdCoO3, Gd0.9Ba0.1CoO3, and Gd0.9Sr0.1CoO3 is carried out. Undoped GdCoO3 reveals a low conductivity; a magnetic moment of 7.4 mu(B) per molecule, which is less than the theoretical value for the Gd3+ ion; and an asymptotic Curie temperature of -6 K. Doping GdCoO3 with barium and strontium to substitution of 10 at. % Gd brings about an increase in the conductivity and magnetic transitions at T = 300 K for Gd0.9Ba0.1CoO3 and T = 170 K for Gd0.9Sr0.1CoO3. The magnetization anomalies imply the formation of magnetic clusters. The behavior of the electrical conductivity at high temperatures suggests a variable activation energy. At low temperatures, Mott hopping conduction sets in.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Popkov S. I., Krasikov A. A., Semenov S. V., Dubrovskii A. A., Yakushkin S. S., Kirillov V. L., Mart'yanov O. N., Balaev D. A.
Заглавие : Features of the pulsed magnetization switching in a high-coercivity material based on ε-Fe2O3 nanoparticles
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of the Krasnoyarsk Krai; Krasnoyarsk Territorial Foundation [18-42-240012]
Место публикации : Phys. Solid State. - 2020. - Vol. 62, Is. 3. - P.445-453. - ISSN 1063-7834, DOI 10.1134/S1063783420030166. - ISSN 1090-6460(eISSN)
Примечания : Cited References: 44. - The study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Krai, and the Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project no. 18-42-240012 "Magnetization Switching of Magnetic Nanoparticles in Strong Pulsed Magnetic Fields: New Approach to Studying the Dynamic Effects Related to the Magnetization of Magnetic Nanoparticles."
Предметные рубрики: HIGH-TEMPERATURE
WAVE ABSORBER
OXIDE
FIELD
TRANSITION
RESONANCE
Аннотация: The magnetic structure of the ε-Fe2O3 iron oxide polymorphic modification is collinear ferrimagnetic in the range from room temperature to ~150 K. As the temperature decreases, ε-Fe2O3 undergoes a magnetic transition accompanied by a significant decrease in the coercivity Hc and, in the low-temperature range, the compound has a complex incommensurate magnetic structure. We experimentally investigated the dynamic magnetization switching of the ε-Fe2O3 nanoparticles with an average size of 8 nm in the temperature range of 80–300 K, which covers different types of the magnetic structure of this iron oxide. A bulk material consisting of xerogel SiO2 with the ε-Fe2O3 nanoparticles embedded in its pores was examined. The magnetic hysteresis loops under dynamic magnetization switching were measured using pulsed magnetic fields Hmax of up to 130 kOe by discharging a capacitor bank through a solenoid. The coercivity Нс upon the dynamic magnetization switching noticeably exceeds the Нс value under the quasi-static conditions. This is caused by the superparamagnetic relaxation of magnetic moments of particles upon the pulsed magnetization switching. In the range from room temperature to ~ 150 K, the external field variation rate dH/dt is the main parameter that determines the behavior of the coercivity under the dynamic magnetization switching. It is the behavior that is expected for a system of single-domain ferro- and ferrimagnetic particles. Under external conditions (at a temperature of 80 K) when the ε-Fe2O3 magnetic structure is incommensurate, the coercivity during the pulsed magnetization switching depends already on the parameter dH/dt and is determined, to a great extent, by the maximum applied field Hmax. Such a behavior atypical of systems of ferrimagnetic particles is caused already by the dynamic spin processes inside the ε-Fe2O3 particles during fast magnetization switching.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Bulavchenko O. A., Dubrovskii A. A., Tsybulya S. V., Cherepanova S. V., Gerasimov E. Y., Shaikhutdinov K. A.
Заглавие : Features of the structure, microstructure, and magnetic properties of manganese-aluminum spinels obtained in various thermal treatment conditions
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2013. - Vol. 55, Is. 7. - P.1401-1406. - ISSN 1063-7834, DOI 10.1134/S1063783413070056
Примечания : Cited References: 18. - This study was supported by the Russian Foundation for Basic Research (project no. 12-03-90839-mol_rf_nr) and the Ministry of Education and Science of the Russian Federation (agreement no. 8429).
Предметные рубрики: A-SITE SPINELS
CATALYSTS
OXIDE
MN3O4
Аннотация: The structural, microstructural, and magnetic properties of aluminum-manganese oxide in the ratio Mn: Al = 1: 1 in the well-crystallized and nanoheterogeneous states have been investigated. This oxide is obtained under various thermal treatment conditions and at different partial pressures of oxygen. The composition and cation distribution of the manganese and aluminum ions in spinel sites are determined. It is shown that the studied compound is a ferrimagnet with the Curie point T (C) a parts per thousand 26 K.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Voronin A. S., Ivanchenko F. S., Simunin M. M., Shiverskiy A. V., Aleksandrovsky A. S., Nemtsev I. V., Fadeev Y. V., Karpova D. V., Khartov S. V.
Заглавие : High performance hybrid rGO/ Ag quasi-periodic mesh transparent electrodes for flexible electrochromic devices
Место публикации : Appl. Surf. Sci.: Elsevier Science, 2016. - Vol. 364. - P.931–937. - ISSN 0169-4332, DOI 10.1016/j.apsusc.2015.12.182. - ISSN 1873-5584
Примечания : Cited References: 31
Предметные рубрики: NANOWIRE NETWORKS
GRAPHENE FILMS
OXIDE
OXIDATION
HEATERS
Ключевые слова (''Своб.индексиров.''): quasi-periodic mesh transparent electrode self-organized template--reduced graphene oxide (rgo)--flexible electrochromic device
Аннотация: A possibility of creating a stable hybrid coating based on the hybrid of a reduced graphene oxide (rGO)/ Ag quasi-periodic mesh (q-mesh) coating has been demonstrated. The main advantages of the suggested method are the low cost of the processes and the technology scalability. The Ag q-mesh coating is formed by means of the magnetron sputtering of silver on the original template obtained as a result of quasi-periodic cracking of a silica film. The protective rGO film is formed by low temperature reduction of a graphene oxide (GO) film, applied by the spray-deposition in the solution of NaBH4. The coatings have low sheet resistance (12.3 Ω/sq) and high optical transparency (82.2%). The hybrid coating are characterized by high chemical stability, as well as they show high stability to deformation impacts. High performance of the hybrid coatings as electrodes in the sandwich-system «electrode – electrochromic composition – electrode» has been demonstrated. The hybrid electrodes allow the electrochromic sandwich to function without any visible degradation for a long time, while an unprotected mesh electrode does not allow performing even a single switching cycle.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zamkova N. G., Zinenko V. I.
Заглавие : Lattice dynamics of ionic crystals in a model of "breathing" and polarizable ions
Место публикации : Phys. Solid State: AMER INST PHYSICS, 1998. - Vol. 40, Is. 2. - P320-324. - ISSN 1063-7834, DOI 10.1134/1.1130302
Примечания : Cited References: 14
Предметные рубрики: OXIDE
Аннотация: An expression is written down for the dynamic matrix of ionic crystals in terms of a microscopic, parameterless model of "breathing" and polarizable ions. Results from a calculation of the complete spectrum of the lattice vibrations of ionic crystals having an NaCl structure are presented as an illustration. (C) 1998 American Institute of Physics.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova N. B., Kazak N. V., Michel C. R., Balaev A. D., Ovchinnikov S. G.
Заглавие : Low-temperature magnetic behavior of the rare-earth cobaltites GdCoO3 and SmCoO3
Разночтения заглавия :авие SCOPUS: Low-temperature magnetic behavior of the rare-earth cobaltites GdCoO 3 and SmCoO3
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007. - Vol. 49, Is. 11. - P2126-2131. - ISSN 1063-7834, DOI 10.1134/S1063783407110182
Примечания : Cited References: 32. - This study was supported by the Branch of General Physics and Astronomy of the Russian Academy of Sciences within the framework of the program “Strong Electron Correlations” and the Russian Science Support Foundation
Предметные рубрики: METAL-INSULATOR-TRANSITION
RCOO3 R
SPIN-STATE
OXIDE
SM
ND
PEROVSKITE
GLASSES
PR
EU
Аннотация: The temperature and magnetic field dependences of the static magnetization of the polycrystalline rare-earth cobaltites GdCoO3 and SmCoO3 have been measured. It is shown that, below room temperature, the magnetization of both compounds derives primarily from the rare-earth ion paramagnetism. The GdCoO3 and SmCoO3 compounds have been found to differ substantially in magnetic behavior, which can be traced to differences in their electronic shell structures. The magnetic behavior of GdCoO3 is close to that of an array of free Gd3+ ions, whereas in SmCoO3 the deviation from the free-ion properties is very large because of the Sm3+ ground state being crystal-field split. Van Vleck magnetic susceptibility measurements of SmCoO3 suggest that the splitting is similar to 10 K.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Yakushkin S. S., Dubrovskiy A. A., Balaev A. D., Shaykhutdinov K. A., Bukhtiyarova G. A., Martyanov O. N.
Заглавие : Magnetic properties of few nanometers ɛ-Fe2O3 nanoparticles supported on the silica
Место публикации : J. Appl. Phys.: American Institute of Physics, 2012. - Vol. 111, Is. 4. - Ст.44312. - ISSN 0021-8979, DOI 10.1063/1.3686647
Примечания : Cited References: 27. - authors thank A. D. Balaev and N. V. Volkov for fruitful discussions and comments. This work was supported by Program of RAS No. 27.46.
Предметные рубрики: HIGH-TEMPERATURE
IRON
STABILIZATION
OXIDE
GEL
Аннотация: Magnetic properties of ɛ-Fe2O3nanoparticles supported on silica with the average size of few nanometers, narrow size distribution and no admixture of any other iron oxide polymorphs are investigated. The investigation of the temperature behavior of magnetization within the temperature range from 4.2 to 1000 K revealed the presence of several magnetic subsystems in the species under study. The temperatures’ behavior of the magnetic moment value indicates ferrimagnetic ordering in the ɛ-Fe2O3nanoparticles with a Curie temperature of about 800 K and points to the existence of a significant paramagnetic contribution becoming apparent at low temperatures. According to the electron spin resonance data, the particles possess superparamagnetic behavior at temperature higher ∼120 K. The model of the magnetic structure of monophase system of few nanometers ɛ-Fe2O3nanoparticles supported on silica is proposed.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Dubrovskiy A. A., Krasikov A. A., Popkov S. I., Balaev A. D., Shaikhutdinov K. A., Kirillov V. L., Mart'yanov O. N.
Заглавие : Magnetic properties of NiO nano particles: Contributions of the antiferromagnetic and ferromagnetic subsystems in different magnetic field ranges up to 250 kOe
Коллективы : Russian Foundation for Basic Research; Government of the Krasnoyarsk Territory; Krasnoyarsk Territorial Foundation [17-42-240138]
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2017. - Vol. 59, Is. 8. - P.1547-1552. - ISSN 1063-7834, DOI 10.1134/S1063783417080029. - ISSN 1090-6460(eISSN)
Примечания : Cited References:40. - This study was supported by the Russian Foundation for Basic Research, Government of the Krasnoyarsk Territory, and Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activity, project no. 17-42-240138.
Предметные рубрики: EXCHANGE-BIAS
FERRIHYDRITE NANOPARTICLES
HYSTERESIS ANOMALIES
OXIDE
Аннотация: The magnetic properties of antiferromagnetic NiO nanoparticles prepared by thermal decomposition of nickel hydroxocarbonate are investigated. According to the data of magnetization measurements in fields of up to 250 kOe, the magnetic moment linearly grows in strong fields, which is caused by the contribution of the antiferromagnetically ordered nanoparticle core, and the antiferromagnetic susceptibility corresponds to that of bulk polycrystalline NiO. This allowed the antiferromagnetic and ferromagnetic contributions to the total magnetic response of a sample to be quantitatively determined. The latter occurs due to the incomplete spin compensation in an antiferromagnetic nanoparticle caused by defects on its surface. It is demonstrated that to correctly determine the superparamagnetic blocking temperature, it is necessary to take into account the antiferromagnetic susceptibility of the particle core.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shtarev D. S., Shtareva, A., V, Kevorkyants R., Rudakova, A., V, Molokeev M. S., Bakiev, T., V, Bulanin K. M., Ryabchuk V. K., Serpone N.
Заглавие : Materials synthesis, characterization and DFT calculations of the visible-light-active perovskite-like barium bismuthate Ba1.264(4)Bi1.971(4)O4 photocatalyst
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [19-73-10013]; Saint-Petersburg State University [39054581]; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-03-00855]
Место публикации : J. Mater. Chem. C. - 2020. - Vol. 8, Is. 10. - P.3509-3519. - ISSN 2050-7526, DOI 10.1039/c9tc06457e. - ISSN 2050-7534(eISSN)
Примечания : Cited References: 42. - The current research was kindly funded by a grant from the Russian Science Foundation (project No. 19-73-10013). R. K., A. V. R., V. K. R. and T. V. B. acknowledge financial support from Saint-Petersburg State University (Pure ID 39054581). A. V. R. thanks the Russian Foundation for Basic Research for a Grant No. 18-03-00855 that supported studies into the photoinduced hydrophilicity of the bismuthate. The authors are further grateful to the staff of the Khabarovsk Innovation and Analytical Center of the Yu. A. Kosygin Institute of Tectonics and Geophysics of the Far Eastern Branch of the Russian Academy of Sciences, and the Resource Centers of the Research Park at the Saint-Petersburg State University: (i) the Center for Diagnostics of Functional Materials for Medicine, Pharmacology and Nanoelectronics, (ii) the Center for Physical Methods of Surface Investigation, (iii) the Center for Optical and Laser Materials Research, and the laboratories of (iv) Nanotechnology and (v) Nanophotonics for their valuable assistance in carrying out the research and in providing the needed equipment. One of us (N.S.) is grateful to Prof. Angelo Albini and the staff of the PhotoGreen Laboratory at the University of Pavia, Italy, for their continued hospitality.
Предметные рубрики: OXIDE
NIO/SRBI2O4
SPECTRA
DRIVEN
CO2
LA
Аннотация: A perovskite-like barium bismuthate of the BaBi2O4 class, Ba1.264(4)Bi1.971(4)O4, has been prepared by solid-state synthesis and subsequently characterized by a number of experimental techniques (XPS, DRS, SEM, EDX and Raman spectroscopy), as well as by a DFT computational approach using the GGA Perdew–Burke–Ernzerhof (PBE) density functional to determine the energy band structure. XRD peaks were indexed to a rhombohedral cell (R[3 with combining macron]m) with parameters close to Ba0.156Bi0.844O1.422 (i.e., to Ba0.439Bi2.374O4), which upon Rietveld refinement gave Ba1.264(4)Bi1.971(4)O4. The Bi–O bond lengths determined from this refinement (1.86 and 2.31 Å) accorded with the bond lengths estimated from Raman spectra (1.97 and 2.26 Å). DFT calculations revealed the bismuthate to display two bandgaps that correspond to lower-energy indirect (2.28 eV) and to higher-energy direct (2.36 eV) electronic transitions in good agreement with the experimental bandgaps of 2.26 eV and 2.43 eV, respectively, from Tauc plots of DRS spectra. Relative to the indirect bandgap energy of 2.26 eV, the energies of the valence band and of the conduction band were, respectively, +1.14 eV and −1.12 eV. The photoactivity of Ba1.264(4)Bi1.971(4)O4 was examined toward the photoreduction of the greenhouse gas CO2 in aqueous media photoelectrochemically yielding alcohols and alkanes, while in the gas phase in an infrared cell reactor the products were carbon monoxide and alkanes.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Sokolov A. E., Temerov V. L., Bezmaternykh L. N., Sukhachev A. L., Seredkin V. A., Gnatchenko S. L., Kachur I. S., Piryatinskaya V. G.
Заглавие : Polarized absorption spectra and spectroscopic parameters of Tm3+ in the TmAl3(BO3)(4) single crystal
Разночтения заглавия :авие SCOPUS: Polarized absorption spectra and spectroscopic parameters of Tm 3+ in the TmAl3(BO3)4 single crystal
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2008. - Vol. 50, Is. 7. - P1287-1293. - ISSN 1063-7834, DOI 10.1134/S1063783408070159
Примечания : Cited References: 36
Предметные рубрики: RARE-EARTH IONS
ELECTRONIC ENERGY LEVELS
DIODE-PUMPED LASER
OPTICAL-ABSORPTION
ALUMINUM GARNET
MU-M
INTENSITIES
FLUORESCENCE
GLASSES
OXIDE
Аннотация: High-optical-quality single crystals of the TmAl3(BO3)(4) compound were synthesized from a solution in the melt. The absorption spectra in the sigma and pi polarizations for the H-3(6) - F-3(4), H-3(6) - H-3(5), H-3(6) - H-3(4), H-3(6) - F-3(3), H-3(6) - F-3(2), H-3(6) - (1)G(4), and H-3(6) - D-1(2) transitions in the Tm3+ ion were recorded at room temperature. The transition intensities were analyzed in the framework of the Judd-Ofelt theory generalized to the case of anisotropic crystals, and the following parameters of the theory were obtained: Omega(2) = 6.14 x 10(-20) cm(2), Omega(4) = 3.09 x 10(-20) cm(2), and Omega(6) = 2.04 x 10(-20) cm(2). The lifetimes and the branching ratios were determined for all possible transitions.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shtarev, Dmitry S., Shtareva, Anna, V, Kevorkyants, Ruslan, Molokeev M. S., Serpone, Nick
Заглавие : Revisiting the BaBiO3 semiconductor photocatalyst: synthesis, characterization, electronic structure, and photocatalytic activity
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [19-73-10013]
Место публикации : Photochem. Photobiol. Sci. - 2021. - Vol. 20, Is. 9. - P.1147-1160. - ISSN 1474-905X, DOI 10.1007/s43630-021-00086-y. - ISSN 1474-9092(eISSN)
Примечания : Cited References: 48. - We wish to thank the Russian Science Foundation for a Grant (Project No. 19-73-10013) in support of our study. The authors are also grateful to the staff of the following Institutes/Centers for their valuable technical assistance and in providing the needed equipment: (i) the Khabarovsk Innovation and Analytical Center of the Yu. A. Kosygin Institute of Tectonics and Geophysics FEB RAS; and (ii) the Resource Centers of the Research Park at Saint-Petersburg State University, especially the Center for Physical Methods of Surface Investigation and the Nanophotonics Center. One of us (NS) is grateful to the staff of the PhotoGreen Laboratory of the University of Pavia, Italy, for their continued hospitality
Предметные рубрики: RHODAMINE-B
OXIDE
DRIVEN
SUPERCONDUCTIVITY
PSEUDOPOTENTIALS
Аннотация: This article revisits the properties of BaBiO3 examined extensively in the last two decades because of its electronic properties as a superconductor and as a semiconductor photocatalyst. Solid-state syntheses of this bismuthate have often involved BaCO3 as the barium source, which may lead to the formation of BaBiO3/BaCO3 heterostructures that could have an impact on the electronic properties and, more importantly, on the photocatalytic activity of this bismuthate. Accordingly, we synthesized BaBiO3 by a solid-state route to avoid the use of a carbonate; it was characterized by XRD, SEM, and EDX, while elemental mapping characterized the composition and the morphology of the crystalline BaBiO3 and its thin films with respect to structure, optoelectronic, and photocatalytic properties. XPS, periodic DFT calculations, and electrochemical impedance spectroscopy ascertained the electronic and electrical properties, while Raman and DRS spectroscopies assessed the relevant optical properties. The photocatalytic activity was determined via the degradation of phenol in aqueous media. Although some results accorded with earlier studies, the newer electronic structural data on this bismuthate, together with the photocatalytic experiments carried out in the presence of selective radical trapping agents, led to elucidating some of the mechanistic details of the photocatalytic processes that previous views of the BaBiO3 band structure failed to address or clarify. Analytical refinement of the XRD data inferred the as-synthesized BaBiO3 adopted the C2/m symmetry rather than the I2/m structure reported earlier, while Tauc plots from DRS spectra yielded a bandgap of 2.05 eV versus the range of 1.1–2.25 eV reported by others; the corresponding flatband potentials were 1.61 eV (EVB) and − 0.44 eV (ECB). The photocatalytic activity of BaBiO3 was somewhat greater than that of the well-known Evonik P25 TiO2 photocatalyst under comparable experimental conditions.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Myagkov V. G., Tambasov I. A., Bayukov O. A., Zhigalov V. S., Bykova L. E., Mikhlin Yu. L., Volochaev M. N., Bondarenko G. N.
Заглавие : Solid state synthesis and characterization of ferromagnetic nanocomposite Fe-In2O3 thin films
Место публикации : J. Alloys Compd.: Elsevier Science, 2014. - Vol. 612. - P.189-194. - ISSN 0925-8388, DOI 10.1016/j.jallcom.2014.05.176. - ISSN 1873-4669
Примечания : Cited References: 56
Предметные рубрики: HIGH-TEMPERATURE FERROMAGNETISM
PHASE-FORMATION
In2O
OXIDE
NANOPARTICLES
CO
SEMICONDUCTORS
NANOCRYSTALS
COMBUSTION
SYSTEMS
Ключевые слова (''Своб.индексиров.''): thermite reactions--reactive films--ferromagnetic nanocomposite films--transparent conducting oxides
Аннотация: We have successfully synthesized ferromagnetic Fe-In2O 3 nanocomposite thin films for the first time using the thermite reaction Fe2O3 + In = In2O3 + Fe. The initial In/Fe2O3 bilayers were obtained by the deposition of In layers on α-Fe2O3 films. The reaction occurs in a self-propagating mode in a homogeneous thermal film plane field at heating rates above 20 K/s and at temperatures above initiation temperature T[[d]]in[[/d]] ~ 180 °C. At heating rates lower than 20 K/s the mixing of the In and Fe2O3 layers occurs across the whole In/Fe2O3 interface and the synthesis of the ferromagnetic α-Fe phase starts above the initiation temperature T[[d]]in[[/d]] = 180 °C. X-ray diffraction, X-ray photoelectron spectroscopy, Mossbauer spectroscopy, transmission electron microscopy and magnetic measurements were used for phase identification and microstructure observation of the synthesized Fe-In2O3 samples. The reaction products contain (1 1 0) textured α-Fe nanocrystals with a diameter around 100 nm and surrounded by an In2O3 matrix. These results enable new efficient low-temperature methods for synthesizing ferromagnetic nanocomposite films containing ferromagnetic nanoclusters embedded in transparent conducting oxides. © 2014 Elsevier B.V. All rights reserved.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Smirnov M. B., Roginskii E. M., Kazimirov V. Y., Smirnov K. S., Baddour-Hadjean R., Pereira-Ramos J. P., Zhandun V. S.
Заглавие : Spectroscopic and computational study of structural changes in γ-LiV2O5 cathodic material induced by lithium intercalation
Место публикации : J. Phys. Chem. C: American Chemical Society, 2015. - Vol. 119, Is. 36. - P.20801-20809. - ISSN 1932-7447, DOI 10.1021/acs.jpcc.5b05540
Примечания : Cited References: 36. - This work was supported by the international collaboration program between the Centre National de la Recherche Scientifique (CNRS) of France and the Russian Foundation for Basic Research (RFBR), LIBASTRAM CNRS Project 6094, and RFBR Grant 13-03-91052.
Предметные рубрики: AUGMENTED-WAVE METHOD
LIXV2O5 SYSTEM
AB-INITIO
VANADIUM PENTOXIDE
RAMAN-SPECTROSCOPY
LI INTERCALATION
OXIDE
V2O5
TRANSITION
TRANSITION
Аннотация: Structure, electronic states, and vibrational dynamics of γ-LiV2O5 were studied by combined use of quantum-chemical calculations and Raman spectroscopy. The spin-polarized DFT+U calculations correctly mimic the structural changes induced by the Li intercalation into the V2O5 framework. The analysis of the density of electronic states shows that the electrons of Li atoms are transferred to the Vb atoms and are aligned in ferromagnetic order. The charge distribution in the system reflects the change of valence state of the Vb atoms from 5+ to 4+, and it is in line with changes of Vb–O bond lengths. The calculated Raman spectrum of the γ-LiV2O5 structure is in line with the experimental Raman spectra that allows a reliable assignment of all prominent Raman peaks. Comparison of the spectra of γ-LiV2O5 and γ'-V2O5 indicates spectral signatures of structural changes induced by the Li insertion into the γ'-V2O5 lattice. Results of the study present the opportunity of using Raman spectroscopy for characterization of structural modifications of the vanadate framework upon intercalation of guest species.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Yakushkin S. S., Dubrovskii A. A., Bukhtiyarova G. A., Shaikhutdinov K. A., Martyanov O. N.
Заглавие : Study of the high-coercivity material based on ε-Fe2O3 nanoparticles in the silica gel matrix
Место публикации : Tech. Phys. Lett.: MAIK Nauka-Interperiodica / Springer, 2016. - Vol. 42, Is. 4. - P.347-350. - ISSN 10637850 (ISSN), DOI 10.1134/S1063785016040039
Примечания : Cited References: 17. - This study was supported by the Federal Agency for Scientific Organizations of Russia (base budget financing no. V.44.1.15), the Scientific and Educational Center of Energy-Efficient Catalysis at the Novosibirsk State University, and the Russian Foundation for Basic Research (project no. 15-32-50919).
Предметные рубрики: Phase
Field
State
Oxide
Iron
Аннотация: We report the results of investigations of ε-Fe2O3 magnetic nanoparticles obtained by incipient wetness impregnation of silica gel. It was established that the obtained samples with an iron content of 12‒16% mass % containing ε-Fe2O3 nanoparticles with an average size of 10 nm on the silica gel surface exhibit a room-temperature coercivity of about 10 kOe. Along with fabrication simplicity, this fact makes the prepared samples promising for application as a magnetically hard material. © 2016, Pleiades Publishing, Ltd
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Uschakov A. V., Karpov I. V., Lepeshev A. A., Zharkov S. M.
Заглавие : The influence of oxygen concentration on the formation of CuO and Cu2O crystalline phases during the synthesis in the plasma of low pressure arc discharge
Место публикации : Vacuum: Elsevier, 2016. - Vol. 128. - P.123-127. - ISSN 0042207X (ISSN), DOI 10.1016/j.vacuum.2016.03.025
Примечания : Cited References: 19. - This study was supported by the Russian Foundation for Basic Research. (Project No 15-08-02132).
Предметные рубрики: Nanoparticles
Oxide
Ключевые слова (''Своб.индексиров.''): oxides--vapor deposition--x-ray diffraction--transmission electron microscopy (tem)--catalytic properties
Аннотация: This paper describes the synthesis of copper oxide nanoparticles with different percentages of CuO and Cu2O phases. It was achieved by the control of the percentage of oxygen in the gas mixture (N2 + O2) in a plasma-chemical process of evaporation-condensation by means of low-pressure arc discharge. In all the experiments, the pressure in the plasma-chemical reactor remained constant at 60 Pa. By means of X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM), energy-dispersive X-ray spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR) it was found that the average particle size was 6 nm, and Cu2O phase content decreases with increasing oxygen content in the gas mixture. High photocatalytic properties of Cu2O powder were shown by the example of the reaction of the methyl orange dye decomposition in water solution. The problems, associated with the performance of this method and the formation of crystalline phases, are discussed.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Churilov G. N., Nikolaev N. S., Cherepakhin A. V., Dudnik A. I., Tomashevich E. V., Trenikhin M. V., Bulina N. G.
Заглавие : Thermal oxidation of a carbon condensate formed in high-frequency carbon and carbon-nickel plasma flow
Коллективы : Russian Foundation for Basic Research; Government of Krasnoyarsk Territory; Krasnoyarsk Territorial Foundation for the Support of Scientific and RD Activities [16-43-242148]
Место публикации : Tech. Phys. - 2018. - Vol. 63, Is. 2. - P.216-219. - ISSN 1063-7842, DOI 10.1134/S1063784218020093. - ISSN 1090-6525(eISSN)
Примечания : Cited References:12. - Transmission electron microscopy investigations were carried out on equipment of the Omsk Regional Center of Collective Use of the Siberian Branch of the Russian Academy of Sciences. This study was supported by the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, and the Krasnoyarsk Territorial Foundation for the Support of Scientific and R&D Activities, project no. 16-43-242148.
Предметные рубрики: FULLERENES
OXIDE
METAL
Аннотация: We have reported on the comparative characteristics of thermal oxidation of a carbon condensate prepared by high-frequency arc evaporation of graphite rods and a rod with a hollow center filled with nickel powder. In the latter case, along with different forms of nanodisperse carbon, nickel particles with nickel core-carbon shell structures are formed. It has been found that the processes of the thermal oxidation of carbon condensates with and without nickel differ significantly. Nickel particles with the carbon shell exhibit catalytic properties with respect to the oxidation of nanosized carbon structures. A noticeable difference between the temperatures of the end of the oxidation process for various carbon nanoparticles and nickel particles with the carbon shell has been established. The study is aimed at investigations of the effect of nickel nanoparticles on the dynamics of carbon condensate oxidation upon heating in the argon-oxygen flow.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Myagkov V. G., Zhigalov V. S., Bykova L. E., Zharkov S. M., Matsynin A. A., Volochaev M. N., Tambasov I. A., Bondarenko G. N.
Заглавие : Thermite synthesis and characterization of Co-ZrO2 ferromagnetic nanocomposite thin films
Место публикации : J. Alloys Compd.: Elsevier, 2016. - Vol. 665. - P.197-203. - ISSN 09258388 (ISSN), DOI 10.1016/j.jallcom.2015.12.257
Примечания : Cited References: 56. - This study was partially supported by the Russian Foundation for Basic Research (grants ##15-02-00948, 14-03-00515), by the Council for Grants of the President of the Russian Federation (SP-317.2015.1), and by the program of the Foundation for Assistance to Small Innovative Enterprises in Science and Technology (“UMNIK” program). The TEM studies were carried out using the facilities of Electron Microscopy Laboratory of Siberian Federal University and the Performance Service at Krasnoyarsk Scientific Center.
Предметные рубрики: SOLID-STATE SYNTHESIS
PHASE-FORMATION
ZrO2
NANOPARTICLES
TRANSPORT
OXIDE
MICROSTRUCTURE
NANOTHERMITE
FABRICATION
PARTICLES
Ключевые слова (''Своб.индексиров.''): thermite reactions--reactive films--ferromagnetic nanocomposite films--zro2
Аннотация: Co-ZrO2 ferromagnetic nanocomposite thin films were successfully synthesized using a new thermite reaction between Zr and Co3O4 in layer geometry. The initial Zr/Co3O4 bilayers were obtained by the deposition of Zr layers onto Co3O4 films at room temperature. The process of mixing at the Zr/Co3O4 interface and synthesis of fine-crystalline Co and amorphous ZrO2 phases started at a temperature above the initiation temperature Tin ∼250 °C which did not depend on the bilayer thickness. For the bilayer thickness more than 300 nm high-temperature fcc-Co and cubic c-ZrO2 (or tetragonal t-ZrO2) phases were formed. For the bilayer thickness less than ∼50 nm stable low-temperature hexagonal hcp-Co and monoclinic m-ZrO2 phases were also present in the reaction product. A partial transformation from Co3O4 to CoO occurred after annealing at 300 °C. The secondary reaction between CoO and Zr started soon after Co3O4 had been converted to the CoO phase. After annealing at 500 °C more than 80% of Co was reduced and the final product contained Co nanoparticles above and below the superparamagnetic critical size embedded into a dielectric ZrO2 matrix. The synthesized Co-ZrO2 nanocomposite films possessed soft magnetic behavior, high magnetization and good chemical stability.
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