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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Edelman I. S., Morozova T. P., Zabluda V. M., Kim T. A., Turpanov I. A., Betenkova A. Ya., Dynnik Y. A.
Заглавие : Dispersion of Faraday rotation in Co/SiO2 multilayer films
Место публикации : JETP Letters. - 1996. - Vol. 63, Is. 4. - P.273-277. - ISSN 0021-3640, DOI 10.1134/1.567015
Примечания : Cited References: 9
Предметные рубрики: PARTICLES
Аннотация: The Faraday rotation spectra of Co/SiO2 multilayer films were found to be substantially different from the well-known spectra of homogeneous Co films. The character of these changes was studied as a function of the thicknesses of the ferromagnetic metal and the nonmagnetic dielectric layers. (C) 1996 American Institute of Physics.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Edelman I. S., Ivantsov R., Vasiliev A., Stepanov S., Kornilova E., Zarubina T.
Заглавие : Superparamagnetic and ferrimagnetic nanoparticles in glass matrix
Место публикации : Physica B. - 2001. - Vol. 301, Is. 3-4. - P.203-211. - ISSN 0921-4526, DOI 10.1016/S0921-4526(01)00274-5
Примечания : Cited References: 9
Предметные рубрики: MAGNETIC-PROPERTIES
PARTICLES
FILMS
Ключевые слова (''Своб.индексиров.''): magnetic nanoparticles--faraday rotation--faraday rotation--magnetic nanoparticles--crystal structure--faraday effect--ferrimagnetic materials--glass--particle size analysis--superparamagnetism--x ray diffraction analysis--amorphous glass matrices--faraday rotations--nanostructured materials
Аннотация: Faraday rotation (FR) spectral, field, and temperature dependencies in oxide glasses with small additions of paramagnetic elements are investigated. Formation of ferrite nanoparticles in amorphous glass matrices is revealed by X-ray diffraction. Particles have crystal structure similar to spinel structure, their dimensions are about 10-24 nm. The FR field dependencies are typical for ferrimagnetic or superparamagnetic substances depending on particle size. Strong FR increase at the samples cooling (more than twice for some samples) in the temperature interval 105-273 K is observed. (C) 2001 Elsevier Science B.V. All rights reserved.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aver'yanov E. M.
Заглавие : Fluctuations of orientational order in a uniaxial nematic liquid crystal with biaxial molecules and its response to an external field
Место публикации : Phys. Solid State: AMER INST PHYSICS, 2003. - Vol. 45, Is. 5. - P990-1001. - ISSN 1063-7834, DOI 10.1134/1.1575350
Примечания : Cited References: 30
Предметные рубрики: PHASE-TRANSITION
SMECTIC-A
PARTICLES
SYSTEM
LANDAU
MODEL
Аннотация: Homogeneous thermal fluctuations of the orientational order parameters S and G of biaxial molecules in a uniaxial nematic liquid crystal are investigated in the framework of the molecular-statistical theory. It is demonstrated that the molecular biaxiality significantly affects the order parameters S and G, their temperature dependences in the nematic phase, the amplitude and the temperature dependence of the order parameter fluctuations in the nematic and isotropic phases, and the character of the transition from the nematic phase to the isotropic liquid phase. It is established that the fluctuations of the parameters S and G in the nematic phase are related to the temperature dependences of S and G and the susceptibilities chi(S) and chi(G) of the nematic liquid crystal to external fields, which leads to a change in the parameters S and G at a fixed director orientation. Explanations are offered for the known experimental data on the orientational ordering of biaxial molecules under the action of external fields in the isotropic phase of nematic liquid crystals. (C) 2003 MAIK "Nauka/Interperiodica".
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Lopatin V. N., Shepelevich N. V., Prostakova I. V.
Заглавие : Modelling optical properties of organic-mineral complexes in water ecosystems
Место публикации : J. Phys. D. - 2005. - Vol. 38, Is. 15. - P.2556-2563. - ISSN 0022-3727, DOI 10.1088/0022-3727/38/15/005
Примечания : Cited References: 22
Предметные рубрики: SCANNING FLOW-CYTOMETRY
LIGHT-SCATTERING
STRATIFIED SPHERE
PARTICLES
INDEX
Ключевые слова (''Своб.индексиров.''): approximation theory--ecosystems--inverse problems--light scattering--mathematical models--refractive index--suspensions (fluids)--water--generalization--integral light scattering indicatrix--organic-mineral complexes--spherical particles--complexation
Аннотация: Characteristics of organic-mineral complexes have been theoretically and experimentally studied in the paper, based on the method of integral light scattering indicatrix. Modelling of optical properties was realized using models of the coated spherical particles with a shell which is constant and changeable in the refractive index profile. General regularities have been revealed and generalized parameters for the method of integral light scattering indicatrix have been suggested.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Frolov G. I., Bachina O. I., Zav'yalova M. M., Ravochkin S. I.
Заглавие : Magnetic properties of nanoparticles of 3d metals
Коллективы :
Место публикации : Tech. Phys.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2008. - Vol. 53, Is. 8. - P1059-1064. - ISSN 1063-7842, DOI 10.1134/S1063784208080136
Примечания : Cited References: 19. - This study was supported by the targeted program "Development of the Research Potential of Higher Education Institutions," grant no. RNP.2.1.1.7376.
Предметные рубрики: CLUSTERS
IRON
PARTICLES
Аннотация: The influence of size effects on the coercive force, magnetization, and Curie temperature in nanoparticles of 3d metals is considered. It is shown that experimental results obtained during the last two decades provide new information on peculiar magnetic properties of these particles.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Polyakov V. V., Polyakova K. P., Seredkin V. A., Zharkov S. M.
Заглавие : Synthesis and magneto-optical properties of nanogranular Co-Ti-O films
Коллективы : Russian Foundation for Basic Research [06-03-32970, 07-03-00190a]
Место публикации : Phys. Solid State. - 2009. - Vol. 51, Is. 9. - P.1866-1869. - ISSN 1063-7834, DOI 10.1134/S1063783409090169
Примечания : Cited References: 10. - This study was supported by the Russian Foundation for Basic Research (project nos. 06-03-32970 and 07-03-00190a).
Предметные рубрики: HIGH-TEMPERATURE SYNTHESIS
THIN-LAYERS
PARTICLES
Аннотация: Studies of the structural and magneto-optical properties of nanogranular Co-Ti-O films prepared under conditions of the solid-state reaction with oxygen exchange in the CoO/Ti layered structures are presented. The formation of granular films with compositions near or below the percolation threshold is shown. The specific features of the magneto-optical spectra of the prepared films as compared to the spectra of continuous metallic films are revealed.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vorotynov A. M., Petrakovskii G. A., Sablina K. A., Bovina A. F., Vasil'ev A. D.
Заглавие : EPR study of the Jahn-Teller effect of Cu2+ ions in ZnGa2O4
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2010. - Vol. 52, Is. 11. - P2415-2418. - ISSN 1063-7834, DOI 10.1134/S1063783410110314
Примечания : Cited References: 12
Предметные рубрики: MAGNETIC-PROPERTIES
PARTICLES
CUFE2O4
Аннотация: The Jahn-Teller effect in the ZnGa2O4 spinel single crystal has been investigated using electron paramagnetic resonance of Cu2+ ions in the temperature range 110-560 K. It has been shown that copper ions occupy octahedral sites 16d in the ZnGa2O4 crystal with cubic symmetry O (h) (7) (Fd-3m). At T 560 K, the octahedra undergo tetragonal distortions (predominantly tension) and rotation around the fourfold axes by the angle theta a parts per thousand 2.6A degrees. The parameters of the spin Hamiltonian, which characterize the prolate (g (aEuro-)
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ershov A. E., Isaev I. L., Semina P. N., Markel V. A., Karpov S. V.
Заглавие : Effects of size polydispersity on the extinction spectra of colloidal nanoparticle aggregates
Место публикации : Phys. Rev. B: American Physical Society, 2012. - Vol. 85, Is. 4. - Ст.045421. - P. - ISSN 1098-0121, DOI 10.1103/PhysRevB.85.045421
Примечания : Cited References: 41. - This work was supported by grants from the following foundations of the Russian Federation: Presidium of RAS, OFN RAS, and SB RAS.
Предметные рубрики: METAL FRACTAL CLUSTERS
OPTICAL-PROPERTIES
ABSORPTION
NONLINEARITIES
COMPOSITES
SCATTERING
PARTICLES
SPHERES
GRAINS
Аннотация: We investigate the effect of particle polydispersity on the optical extinction spectra of colloidal aggregates of spherical metallic (silver) nanoparticles, taking into account the realistic interparticle gaps caused by layers of stabilizing polymer adsorbed on the metal surface (adlayers). The spectra of computer-generated aggregates are computed using two different methods. The coupled-multipole method is used in the quasistatic approximation and the coupled-dipole method beyond the quasistatics. The latter approach is applicable if the interparticle gaps are sufficiently wide relative to the particle radii. Simulations are performed for two different particle size distribution functions (bimodal and Gaussian), varying the number of particles per aggregate, and different distribution functions of the interparticle gap width. The strong influence of the latter factor on the spectra is demonstrated and investigated in detail.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Karpov S. V., Semina P. N., Gavrilyuk A. P.
Заглавие : The role of the electron tunneling effect in the coagulation kinetics of polydisperse metal nanocolloids
Место публикации : Colloid J.: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 74, Is. 3. - P.305-312. - ISSN 1061-933X, DOI 10.1134/S1061933X12030052
Примечания : Cited References: 16. - Authors are thankful to G. A. Chiganova for discussions and helpful comments. Studies were carried out with the support of grants: the Presidium of RAS No 29 and No 31, OFN RAS III.9.5, IP SB RAS No 43, IP SB RAS (and SFU) No 101.
Предметные рубрики: PARTICLES
Аннотация: The energy of pair interactions between metal nanoparticles of different sizes is shown to be able to increase upon coagulation due to the additional electrostatic effect resulting from mutual heteropolar charging of the particles. The tunnel electron transfer occurring upon the collisions between particles of different sizes may be the reason for the charging. The transfer is caused by the dependence of the electron work function on the particle size. The electron transfer through the interparticle gap equalizes the Fermi levels in particles of different sizes and is associated with this dependence. Using the example of bimodal silver nanocolloids, it is shown that mutual heteropolar charging of particles with different sizes may accelerate the coagulation of polydisperse colloidal systems by an order of magnitude or more as compared with monodisperse systems, in which this effect is absent.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Edelman I. S., Ivanova O. S., Ivantsov R. D., Velikanov D. A., Zabluda V. N., Zubavichus Y., Veligzhanin A. A., Zaikovskiy V. I., Stepanov S., Artemenko A., Curely J., Kliava J.
Заглавие : Magnetic nanoparticles formed in glasses co-doped with iron and larger radius elements
Место публикации : J. Appl. Phys.: American Institute of Physics, 2012. - Vol. 112, Is. 8. - Ст.84331. - P. - ISSN 0021-8979, DOI 10.1063/1.4759244
Примечания : Cited References: 65. - This work was partly supported by the Russian Foundation for Basic Research, Grant Nos. 07-02-92174 RFBR-CNRS and 11-02-00972, and President of Russia Federation Grant No NSh 1044.2012.2. A. Artemenko acknowledges financial support from the Marie Curie International Incoming Fellowship within the 7th European Community Framework Programme (EPREXINA, GA 255662). The synchrotron measurements were supported via the Russian federal Contract No. 16.552.11.7003. The authors thank K. P. Polyakova for the preparation of thin films.
Предметные рубрики: SUPERPARAMAGNETIC RESONANCE
FERROMAGNETIC-RESONANCE
TEMPERATURE-DEPENDENCE
FERRITE NANOPARTICLES
OXIDE NANOPARTICLES
FARADAY-ROTATION
CERAMICS
ANISOTROPY
PARTICLES
SPECTRA
Аннотация: A new type of nanoparticle-containing glasses based on borate glasses co-doped with low contents of iron and larger radius elements, Dy, Tb, Gd, Ho, Er, Y, and Bi, is studied. Heat treatment of these glasses results in formation of magnetic nanoparticles, radically changing their physical properties. Transmission electron microscopy and synchrotron radiation-based techniques: x-ray diffraction, extended x-ray absorption fine structure, x-ray absorption near-edge structure, and small-angle x-ray scattering, show a broad distribution of nanoparticle sizes with characteristics depending on the treatment regime; a crystalline structure of these nanoparticles is detected in heat treated samples. Magnetic circular dichroism (MCD) studies of samples subjected to heat treatment as well as of maghemite, magnetite, and iron garnet allow to unambiguously assign the nanoparticle structure to maghemite, independently of co-dopant nature and of heat treatment regime used. Different features observed in the MCD spectra are related to different electron transitions in Fe3+ ions gathered in the nanoparticles. The static magnetization in heat treated samples has non-linear dependence on the magnetizing field with hysteresis. Zero-field cooled magnetization curves show that at higher temperatures the nanoparticles occur in superparamagnetic state with blocking temperatures above 100 K. Below ca. 20 K, a considerable contribution to both zero field-cooled and field-cooled magnetizations occurs from diluted paramagnetic ions. Variable-temperature electron magnetic resonance (EMR) studies unambiguously show that in as-prepared glasses paramagnetic ions are in diluted state and confirm the formation of magnetic nanoparticles already at earlier stages of heat treatment. Computer simulations of the EMR spectra corroborate the broad distribution of nanoparticle sizes found by "direct" techniques as well as superparamagnetic nanoparticle behaviour demonstrated in the magnetization studies. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4759244]
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