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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zaitsev A. I., Aleksandrovsky A. S., Kozhukhov A. S., Pokrovsky L. D., Atuchin V. V.
Заглавие : Growth, optical and microstructural properties of PbB4O7 plate crystals
Коллективы : SB RAS [28.14, 43.14]; President of the Russian Federation for the support of leading scientific schools [SS-4828.2012.2]; PSB RAS [2.5.2]; Ministry of Education and Science of the Russian Federation
Место публикации : Opt. Mater.: Elsevier Science, 2014. - Vol. 37. - P.298–301. - ISSN 0925-3467, DOI 10.1016/j.optmat.2014.06.012. - ISSN 1873-1252
Примечания : Cited References: 42. - This study is supported by SB RAS via Projects 28.14 and 43.14, and the Grant of the President of the Russian Federation for the support of leading scientific schools SS-4828.2012.2 and by PSB RAS, Grant 2.5.2. V.V.A. gratefully acknowledge the Ministry of Education and Science of the Russian Federation for financial support
Предметные рубрики: LEAD TETRABORATE
SINGLE-CRYSTAL
SUSCEPTIBILITIES
ANISOTROPY
STRONTIUM
SURFACES
RAMAN
Ключевые слова (''Своб.индексиров.''): pbb4o7--czochralski growth--facet--rheed--afm
Аннотация: Centimeter-sized optical quality plate-like PbB4O7 crystals have been grown by Czochralski method. The fundamental absorption edge has been found at 237 nm (corresponding bandgap 5.75 eV) with the distinct sideband protruding up to 300 nm. The crystals are well faceted with the (100), (010) and (101) planes, (100) surfaces being mostly developed. The etching in diluted nitric acid (5 wt.%) at the temperature of 90 °C have been used to reveal the defect structure and remove melt residuals. The (100) surface shows the presence of etching pits and twin boundaries. The Kikuchi line pattern and developed microrelief with the roughness of ~8 nm have been observed by RHEED and AFM, respectively.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Liu, Ji-Cai, Savchenko, Viktoriia, Kimberg V., Gel'mukhanov F., Odelius, Michael
Заглавие : High-resolution x-ray spectra of carbon monoxide reveal ultrafast dynamics induced by long UV pulse
Коллективы : RFBRRussian Foundation for Basic Research (RFBR) [19-29-12015]; National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11974108, 11574082]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [2021MS046]; European UnionEuropean Commission [860553]; Carl Tryggers Foundation [CTS18:285]; Helmholtz Virtual Institute [VI419]; Swedish Research CouncilSwedish Research CouncilEuropean Commission [VR 2019-03470, 2018-05973]
Место публикации : New J. Phys. - 2021. - Vol. 23, Is. 6. - Ст.063030. - ISSN 1367-2630, DOI 10.1088/1367-2630/ac0198
Примечания : Cited References: 47. - The reported study was funded by RFBR, project number 19-29-12015. J-CL thanks the support by the National Science Foundation of China under Grant Nos. 11974108, 11574082, and the Fundamental Research Funds for the Central Universities (No. 2021MS046). MO acknowledges funding from the European Union's Horizon 2020 research and innovation programme under the Marie Skodowska-Curie Grant Agreement No. 860553 and the Carl Tryggers Foundation (contract CTS18:285). FG acknowledges also the support from the Helmholtz Virtual Institute VI419 'Dynamic Pathways in Multidimensional Landscapes'. VK acknowledges the Swedish Research Council (VR 2019-03470). The calculations were partially enabled by resources provided by the Swedish National Infrastructure for Computing (SNIC) partially funded by the Swedish Research Council through Grant Agreement No. 2018-05973
Предметные рубрики: VIBRATIONAL STRUCTURE
SCATTERING
RAMAN
CO
COLLAPSE
PROBE
Аннотация: In theoretical simulations of a UV + x-ray pump-probe (UVX-PP) setup, we show that frequency detuning of the pump UV pulse acts as a camera shutter by regulating the duration of the UVX-PP process. This two-photon absorption with long overlapping UV and x-ray pulses, allowing for high spectral resolution, thereby provides information about ultrafast dynamics of the nuclear wave packet without the requirement of ultrashort pulses and controlled delay times. In a case study of carbon monoxide, the calculated UVX-PP spectra of the O1s−12π1 and C1s−12π1 core-excited states show different vibrational profiles. The interference of intermediate vibrational states reveals details of nuclear dynamics in the UVX-PP process related to a variable duration time controlled by the UV detuning. Both O1s−12π1 and C1s−12π1 pump-probe channels display a splitting of the spectral profile, which however is associated with different physical mechanisms. At the O1s−12π1 resonance, the observed dispersive and non-dispersive spectral bands intersect and result in destructive interference.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kim J., Shvyd'ko Y., Ovchinnikov S. G.
Заглавие : Charge transfer and Mott-Hubbard excitations in FeBO3: An Fe K-edge resonant inelastic x-ray scattering study
Разночтения заглавия :авие SCOPUS: Charge transfer and Mott-Hubbard excitations in FeBO 3: An Fe K-edge resonant inelastic x-ray scattering study
Место публикации : Phys. Rev. B: AMER PHYSICAL SOC, 2011. - Vol. 83, Is. 23. - Ст.235109. - ISSN 1098-0121, DOI 10.1103/PhysRevB.83.235109
Примечания : Cited References: 67. - Yu.Sh. acknowledges the long-standing effort of his colleagues from the IXS Collaborative Design Team in building MERIX instrument at the XOR-IXS 30-ID beamline at the APS, in particular, J. Hill, S. Coburn (BNL), C. Burns (WMU), E. Alp, T. Toellner, and H. Sinn (APS). He is also indebted to R. Khachatryan (APS), M. Wieczorek (APS), and A. Said (APS) for the help in manufacturing the Ge(620) analyzer. P. Siddons (BNL) is acknowledged for building the microstrip detector for the MERIX spectrometer. The help of the XOR-IXS 30-ID beamline personnel at the Advanced Photon Source: T. Roberts, A. Said, and M. Upton are greatly appreciated. Use of the Advanced Photon Source was supported by the US DOE, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. S.O. acknowledges Russian Academy of Science Physical Department program 5.7 "Strongly correlated electrons," RFFI Grant No. 09-02-00171, RFFI Grant No. 10-02-00251, and the Siberian-Ural integration Project No. 40.
Предметные рубрики: TRANSITION-METAL COMPOUNDS
ELECTRONIC-STRUCTURE
OPTICAL-PROPERTIES
ABSORPTION-SPECTRA
EMISSION SPECTRA
FERROMAGNET
DEPENDENCE
COMPLEXES
RAMAN
Аннотация: Momentum-resolved resonant inelastic x-ray scattering (RIXS) spectroscopy has been carried out successfully at the Fe K-edge for the first time. The RIXS spectra of a FeBO3 single crystal reveal a wealth of information on similar or equal to 1-10 eV electronic excitations. The IXS signal resonates when the incident photon energy approaches the pre-edge (1s-3d) and the main-edge (1s-4p) of the Fe K-edge absorption spectrum. The RIXS spectra measured at the pre-edge and the main-edge show quantitatively different dependences on the incident photon energy, momentum transfer, photon polarization, and temperature. We present a multielectron analysis of the Mott-Hubbard (MH) and charge transfer (CT) excitations, and calculate their energies. Electronic excitations observed in the pre-edge and main-edge RIXS spectra are interpreted as MH and CT excitations, respectively. We propose the electronic structure around the chemical potential in FeBO3 based on the experimental data.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Dubrovskiy A. A., Balaev D. A., Krasikov A. A., Yakushhkin S. S., Kirillov V. L., Martyanov O. N.
Заглавие : Magnetodielectric effect in a metamaterial consisting of xerogel with embedded ε-Fe2O3 iron oxide nanoparticles
Коллективы : Russian Science Foundation [17-12-01111]
Место публикации : Solid State Commun. - 2019. - Vol. 289. - P.27-29. - ISSN 0038-1098, DOI 10.1016/j.ssc.2018.11.020. - ISSN 1879-2766(eISSN)
Примечания : Cited References: 30. - This work was supported by the Russian Science Foundation, project no. 17-12-01111.
Предметные рубрики: MAGNETIC-PROPERTIES
HIGH-TEMPERATURE
PHASE
RAMAN
Аннотация: The ε-Fe2O3 iron oxide is a fairly rare polymorphic modification, which only exists in the form of nanoparticles embedded, as a rule, into a silica gel matrix. This magnetically ordered iron oxide, which exhibits a significant room-temperature coercivity, is a ferroelectric; therefore, the magnetoelectric and magnetodielectric properties of this material evoke keen interest. In this work, we investigate the magnetodielectric (MD) effect in a metamaterial consisting of xerogel SiO2 with embedded ε-Fe2O3 nanoparticles 9 nm in size on average in a concentration of 20 mass.%. This bulk material exhibits the MD effect in a wide temperature range. The temperature behavior of the permittivity is related to the magnetic state of the ε-Fe2O3 oxide, which undergoes the magnetic transition from the magnetically hard to magnetically soft phase in the temperature range of 80–150 K, indicating the interplay of the ε-Fe2O3 magnetic and charge subsystems.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mel'nikova S. V., Grankina V. A., Kartashev A. V.
Заглавие : A study of the effect of gradual substitution NH4 - Cs on phase transitions in NH4LiSO4 crystals
Разночтения заглавия :авие SCOPUS: A study of the effect of gradual substitution NH4 Cs on phase transitions in NH4LiSO4 crystals
Место публикации : Phys. Solid State: AMER INST PHYSICS, 2002. - Vol. 44, Is. 2. - P379-385. - ISSN 1063-7834, DOI 10.1134/1.1451032
Примечания : Cited References: 22
Предметные рубрики: MIXED-CRYSTALS
TEMPERATURE PHASE
LINH4SO4
BIREFRINGENCE
SULFATE
RAMAN
Аннотация: Solid solutions in the Cs-x(NH4)(1 - x)LiSO4 (0 less than or equal to x less than or equal to 0.35) system are grown and investigated. The birefringence (n(a) - n(b)) and the heat capacity are measured in the temperature range 100-530 K. The (x-T) phase diagram is constructed. It is demonstrated that the substitution of cesium for ammonium in the NH4LiSO4 crystal affects the transition temperatures in such a way that the region of the ferroelectric phase increases and the ferroelastic phase disappears at x 0.22. The character of the high-temperature transition remains unchanged (2beta = 0.24 +/- 0.01 for all compositions), but the birefringence anomaly and enthalpy decrease. As the concentration x increases, the low-temperature transition becomes more similar to a first-order transition: the birefringence jump deltan and the temperature hysteresis DeltaT increase. (C) 2002 MAIK "Nauka/Interperiodica".
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Pavlovskii M. S., Shinkorenko A. S., Zinenko V. I.
Заглавие : Calculation of lattice dynamics, elastic and dielectric properties of γ-BiB3O6 and δ-BiB3O6
Коллективы : Council on Grants from the President of the Russian Federation for Support of the "Leading Scientific Schools" [NSh-924.2014.2]
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2015. - Vol. 57, Is. 4. - P.675-682. - ISSN 1063, DOI 10.1134/S1063783415040241. - ISSN 10906460(eISSN)
Примечания : Cited References:14. - This study was supported by the Council on Grants from the President of the Russian Federation for Support of the "Leading Scientific Schools" (grant no. NSh-924.2014.2).
Предметные рубрики: BISMUTH BORATE BiB3O6
OPTICAL-PROPERTIES
CRYSTAL
RAMAN
Аннотация: The crystal lattice vibration frequencies, densities of phonon states, elastic moduli, and high-frequency permittivities have been calculated in terms of the density functional theory method for two polymorphs γ-BiB3O6 and δ-BiB3O6. Based on the calculated densities of phonon states, the temperature dependences of the free energies of two considered bismuth triborate modifications have been constructed, and the temperature of the phase transition between these modifications has been determined (1100 K). The structure of a possible nonpolar praphase of δ-BiB3O6 has been proposed. The polarization of δ-BiB3O6 has been estimated as 131 μC/cm2.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zaytseva I. V., Pugachev A. M., Okotrub K. A., Surovtsev N. V., Mikerin S. L., Krylov A. S.
Заглавие : Residual mechanical stresses in pressure treated BaTiO3 powder
Коллективы : RFBR [17-32-5009, 18-02-00399, AAAA-A17-117052410033-9]
Место публикации : Ceram. Int. - 2019. - Vol. 45, Is. 9. - P.12455-12460. - ISSN 0272-8842, DOI 10.1016/j.ceramint.2019.03.179. - ISSN 1873-3956(eISSN)
Примечания : Cited References: 33. - The reported study was funded by RFBR according to the research projects No. 17-32-5009, 18-02-00399 and State assignment No AAAA-A17-117052410033-9. The experiments were performed in the multiple-access center "High-Resolution Spectroscopy of Gases and Condensed Matter" in IA&E SBRAS (Novosibirsk, Russia) and Center for Common Use of the Krasnoyarsk Scientific Center, SBRAS (Krasnoyarsk, Russia).
Предметные рубрики: DIELECTRIC-PROPERTIES
PHASE-TRANSITION
DIAMOND ANVILS
RAMAN
Ключевые слова (''Своб.индексиров.''): residual mechanical stress--raman spectroscopy--high non-hydrostatic pressure--temperature treatment--residual pressure--batio3 ceramics
Аннотация: Here we present Raman spectroscopy approach to monitor the spatial distribution and the magnitude of the residual mechanical stresses in ceramic after non-hydrostatic pressure treatments. The residual pressure can be found from the E-phonon line shift (∼307 cm−1) in the Raman spectra. The relationship between the non-hydrostatic pressure (up to 11 GPa) and the shift of this line has been established. It is demonstrated that the change in the Raman line position (1332 cm−1) of the diamond anvil can be used for monitoring of applied non-hydrostatic pressures. A linear dependence of residual mechanical stresses on the applied pressures is found. Micro-Raman spectroscopy shows that the residual mechanical stresses are distributed fairly uniformly in the studied BaTiO3 samples at the micron scale. In the future, the proposed Raman technique can be used for monitoring the quality of produced BaTiO3 ceramics.
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