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Каталог книг и брошюр библиотеки ИФ СО РАН

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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boldyrev K. N., Stanislavchuk T. N., Klimin S. A., Popova M. N., Bezmaternykh L. N.
Заглавие : Terahertz spectroscopy of multiferroic EuFe3(BO3)4
Место публикации : Phys. Lett. A: Elsevier Science BV, 2012. - Vol. 376, Is. 37. - P.2562-2564. - ISSN 0375-9601, DOI 10.1016/j.physleta.2012.06.028
Примечания : Cited References: 19. - This work was partially supported by the Russian Foundation for Basic Research under Grants No. 10-02-01071-a and No. 09-02-00171-a, by the Ministry of Education and Science under Grant HIII-4828.2012.2, and by the Russian Academy of Sciences under the programs for basic research.
Предметные рубрики: SINGLE-CRYSTAL
GDFE3(BO3)4
Ключевые слова (''Своб.индексиров.''): terahertz spectroscopy--multiferroics--europium iron borate
Аннотация: The terahertz spectra of a rare-earth iron borate with the huntite structure are obtained for the first time. We study the low-temperature (4.0–90 K) α-polarized transmittance spectra of the EuFe3(BO3)4 single crystal in the region 0.9–6.0 THz. Pronounced shifts of phonon frequencies and appearance of new phonon modes at the temperature T S = 58 K of the R 32 → P 3 1 21 structural phase transition are observed. Additional shifts of phonon frequencies occur at the temperature T N = 34 K of the magnetic ordering of the Fe subsystem, thus evidencing the spin–phonon coupling in this multiferroic material.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Atuchin V. V., Aleksandrovsky A. S., Chimitova O. D., Gavrilova T. A., Krylov A. S., Molokeev M. S., Oreshonkov A. S., Bazarov B. G., Bazarova J. G.
Заглавие : Synthesis and spectroscopic properties of monoclinic α-Eu2(MoO4)3
Коллективы : Ministry of Education and Science of the Russian Federation
Место публикации : J. Phys. Chem. C: American Chemical Society, 2014. - Vol. 118, Is. 28. - P.15404-15411. - ISSN 1932-7447, DOI 10.1021/jp5040739
Примечания : Cited References: 63. - This study is partly supported by the Ministry of Education and Science of the Russian Federation.
Предметные рубрики: RARE-EARTH MOLYBDATES
VIBRATIONAL PROPERTIES
LUMINESCENCE PROPERTIES
CRYSTAL-STRUCTURE
PHASE-TRANSITIONS
TRIPLE MOLYBDATE
SINGLE-CRYSTAL
X-RAY
PHOSPHORS
EUROPIUM
Аннотация: The microcrystals of monoclinic europium molybdate, alpha-Eu-2(MoO4)(3), have been fabricated by solid-state synthesis at T = 753-1273 K for 300 h. The crystal structure of alpha-Eu-2(MoO4)(3) has been refined by the Rietveld method and was found to belong to the space group C2/c with unit cell parameters a = 7.5576(1), b = 11.4709(2), c = 11.5158(2) angstrom, and beta = 109.278(1)degrees (R-B = 3.39%). About 40 narrow Raman lines have been observed in the Raman spectrum of the alpha-Eu-2(MoO4)(3) powder sample. The luminescence spectra of alpha-Eu-2(MoO4)(3) under excitation at 355 and 457.9 nm reveal domination of induced electric dipole transition D-5(0) - F-7(2) and the presence of ultranarrow lines at D-5(0) - F-7(0) and D-5(1) - F-7(0) transitions.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zaitsev A. I., Aleksandrovsky A. S., Kozhukhov A. S., Pokrovsky L. D., Atuchin V. V.
Заглавие : Growth, optical and microstructural properties of PbB4O7 plate crystals
Коллективы : SB RAS [28.14, 43.14]; President of the Russian Federation for the support of leading scientific schools [SS-4828.2012.2]; PSB RAS [2.5.2]; Ministry of Education and Science of the Russian Federation
Место публикации : Opt. Mater.: Elsevier Science, 2014. - Vol. 37. - P.298–301. - ISSN 0925-3467, DOI 10.1016/j.optmat.2014.06.012. - ISSN 1873-1252
Примечания : Cited References: 42. - This study is supported by SB RAS via Projects 28.14 and 43.14, and the Grant of the President of the Russian Federation for the support of leading scientific schools SS-4828.2012.2 and by PSB RAS, Grant 2.5.2. V.V.A. gratefully acknowledge the Ministry of Education and Science of the Russian Federation for financial support
Предметные рубрики: LEAD TETRABORATE
SINGLE-CRYSTAL
SUSCEPTIBILITIES
ANISOTROPY
STRONTIUM
SURFACES
RAMAN
Ключевые слова (''Своб.индексиров.''): pbb4o7--czochralski growth--facet--rheed--afm
Аннотация: Centimeter-sized optical quality plate-like PbB4O7 crystals have been grown by Czochralski method. The fundamental absorption edge has been found at 237 nm (corresponding bandgap 5.75 eV) with the distinct sideband protruding up to 300 nm. The crystals are well faceted with the (100), (010) and (101) planes, (100) surfaces being mostly developed. The etching in diluted nitric acid (5 wt.%) at the temperature of 90 °C have been used to reveal the defect structure and remove melt residuals. The (100) surface shows the presence of etching pits and twin boundaries. The Kikuchi line pattern and developed microrelief with the roughness of ~8 nm have been observed by RHEED and AFM, respectively.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Gnatchenko S. L., Kachur I. S., Piryatinskaya V. G., Sukhachev A. L., Temerov V. L.
Заглавие : Local magnetic properties of multiferroic Nd0.5Gd0.5Fe3(BO3)4 in the excited states of Nd3+ ion
Коллективы : Russian Foundation for Basic Researches [12-02-00026]; President of Russia grant [Nsh-2886.2014.2]
Место публикации : J. Magn. Magn. Mater.: Elsevier, 2015. - Vol. 375. - P.153-163. - ISSN 0304-8853, DOI 10.1016/j.jmmm.2014.09.077
Примечания : Cited References: 35. - The work was supported by the Russian Foundation for Basic Researches Grant 12-02-00026 and by the President of Russia grant No Nsh-2886.2014.2.
Предметные рубрики: SINGLE-CRYSTAL
NdFe3(BO3)4
GdFe3(BO3)4
Ключевые слова (''Своб.индексиров.''): f-f transitions--nd3+ ion--excited states--local magnetic properties
Аннотация: Polarized absorption spectra of single-crystal Nd0.5Gd0.5Fe3(BO3)4 were studied in the region of the transition 4I9/2(4G5/2+2G7/2) in Nd3+ ion as a function of temperature (2-34 K) and magnetic field (0-65 kOe). The spectra of natural circular dichroism were measured in the range of 5-40 K. It was found out that the local magnetic properties in the vicinity of the excited ion substantially depended on its state. In particular, a weak ferromagnetic moment appears in some excited states. It was found out that the selection rules for electron transitions in the magnetically ordered state substantially deviated from those in the paramagnetic state of the crystal. They are different for different transitions and they are very sensitive to the orientation of the sublattice magnetic moment relative to the light polarization. In the spectrum of the natural circular dichroism, the transition is revealed which is not observed in the absorption spectrum.Поляризованные спектры поглощения монокристаллов Nd0.5Gd0.5Fe3 (BO3) 4 изучались в области переход 4 I9 / 2 (4G5 / 2þ27/2), в Nd3+ иона в зависимости от температуры (2-34 К) и магнитного поля (0-65 кЭ). Спектры природного кругового дихроизма были измерены в диапазоне 5-40 К. Было установлено, что локальные магнитные свойства в непосредственной близости от возбужденного иона существенно зависит от его состояния. В частности, в некоторых возбужденных состояниях появляется слабый ферромагнитный момент . Выяснилось, что правила отбора для электронных переходов в магнитоупорядоченных состоянии существенно отклонились от тех, которые в парамагнитного состояния кристалла. Они различны для разных переходов, и они очень чувствительны к ориентации подрешетки магнитного момента по отношению к поляризации света. В спектре естественного кругового дихроизма, проявляется переход , который не наблюдается в спектре поглощения.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrov K. S., Beznosikov B. V.
Заглавие : Hierarchies of perovskite-like crystals (Review)
Место публикации : Phys. Solid State: AMER INST PHYSICS, 1997. - Vol. 39, Is. 5. - P.695-715. - ISSN 1063-7834, DOI 10.1134/1.1130120
Примечания : Cited References: 143
Предметные рубрики: CU-O SYSTEM
HIGH-PRESSURE SYNTHESIS
SUPERCONDUCTING COPPER OXIDES
STRUCTURAL PHASE-TRANSITIONS
NEUTRON POWDER DIFFRACTION
SINGLE-CRYSTAL
X-RAY
CUPRATE SUPERCONDUCTORS
DIELECTRIC-PROPERTIES
HOMOLOGOUS SERIES
Аннотация: A system of mutual relationships (a hierarchy) is constructed between various perovskite-like crystal structures based on available structural data. All the perovskite-like structures are characterized by a common indicator of their relationship-the presence of layers, stacks, or frameworks made up of BX6 octahedra linked at their vertices (where B is a cation, X is an anion) or fragments of octahedra in the form of BX5 pyramids or BX4 squares in anion-deficient compounds. In layered structures, these stacks are joined to each other by various intermediate blocks. It is well known that one homological series of compounds is constructed by increasing the number of layers in a stack while preserving the same kind of connecting block. Crystals of various series that contain identical stacks (but different blocks of one or two types) can also be related to one another via this feature. The hierarchical system includes compounds with small distortions in their structures for various reasons. (C) 1997 American Institute of Physics.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Myagkov V. G., Bykova L. E., Zhigalov V. S., Tambasov I. A., Bondarenko G. N., Matsynin A. A., Rybakova A. N.
Заглавие : Solid-state synthesis, structural and magnetic properties of CoPd films
Коллективы : Russian Foundation for Basic Research [15-02-00948]
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2015. - Vol. 57, Is. 5. - P.1014-1022. - ISSN 1063, DOI 10.1134/S1063783415050236. - ISSN 10906460(eISSN)
Примечания : Cited References:57. - This study was supported in part by the Russian Foundation for Basic Research (project no. 15-02-00948).
Предметные рубрики: HIGH-TEMPERATURE SYNTHESIS
EPITAXIAL THIN-FILMS
CENTERED-CUBIC CO
MARTENSITIC TRANSFORMATIONS
PHASE SYNTHESIS
SINGLE-CRYSTAL
FE FILMS
CO/PD MULTILAYERS
RECORDING MEDIA
ANISOTROPY
Аннотация: The results of the investigation of the structural and magnetic properties of CoPd films with equiatomic composition have been presented. The films have been synthesized by vacuum annealing of polycrystalline Pd/Co and epitaxial Pd/α-Co(110) and Pd/β-Co(001) bilayer samples. It has been shown that, for all samples, the annealing to 400°C does not lead to the mixing of layers and the formation of compounds. A further increase in the annealing temperature results in the formation of a disordered CoPd phase at the Pd/Co interface, which is fully completed after annealing at 650°C. The epitaxial relationships between the disordered CoPd phase and the MgO(001) substrate are determined as follows: CoPd(110)〈1¯11|| MgO(001)〈100〉 and CoPd(001)[100] || MgO(001)[100], which are formed in the Pd/αCo(110) and Pd/βCo(001) films, respectively. According to the calculations, the first magnetocrystalline anisotropy constants of the disordered CoPd phase for Pd/αCo(110) and Pd/βCo(001) samples have close values: = –(1.6 ± 0.4) × 105 erg/cm3. A possible mechanism of the solidstate synthesis of the CoPd alloy is proposed.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Sukhachev A. L., Sokolov V. V., Gudim, I. A.
Заглавие : Giant natural circular dichroism of vibronic transitions in HoAl3(BO3)4
Место публикации : JETP Letters. - 2015. - Vol. 102, Is. 8. - P.493-495. - ISSN 00213640 (ISSN), DOI 10.1134/S0021364015200084
Примечания : Cited References: 15. - This work was supported by the Council of the President of the Russian Federation for the Support of Leading Scientific Schools (project no. NSh-2886.2014.2).
Предметные рубрики: SINGLE-CRYSTAL
OPTICAL-ABSORPTION
SPECTRA
Ho3+
IONS
PR3+
Аннотация: The giant natural optical activity of vibronic replicas of the f–f5/8 → 5F2 transition in HoAl3(BO3)4 is observed. It exceeds the optical activity related to purely electronic transitions by two orders of magnitude and corresponds to the almost complete circular polarization of the transitions. This effect is explained by the local distortions of the crystal in the excited electronic state, which lead to the mixing of electron and vibrational wavefunctions and, as a consequence, to the delocalization of the vibronic wavefunction and the enhancement of spatial dispersion, which is responsible for the optical activity.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Gnatchenko S. L., Kachur I. S., Piryatinskaya V. G., Temerov V. L.
Заглавие : Changes of the local magnetic properties of the optically excited Nd3+ ions and their manifestation in the near IR spectra of the Nd0.5Gd0.5Fe3(BO3)4 crystal
Коллективы : Russian Foundation [16-02-00273]; [Nsh-2886.2014.2]
Место публикации : Opt. Mater.: Elsevier Science, 2016. - Vol. 52. - P.126-133. - ISSN 0925-3467, DOI 10.1016/j.optmat.2015.12.029. - ISSN 1873-1252(eISSN)
Примечания : Cited References: 29. - The work was supported by the Russian Foundation for Basic Researches Grant 16-02-00273 and by the President of Russia Grant No. Nsh-2886.2014.2.
Предметные рубрики: SINGLE-CRYSTAL
GdFe3(BO3)4
STATES
Ключевые слова (''Своб.индексиров.''): f-f transitions--nd3+ ion--excited states--local magnetic properties
Аннотация: Polarized absorption spectra of f–f transitions 4I9/2 → 4F3/2 and (2H9/2 + 4F5/2) in the Nd3+ ion in the Nd0.5Gd0.5Fe3(BO3)4 single crystal were studied as a function of temperature in the range of 2–40 K and as a function of magnetic field in the range of 0–65 kOe at 2 K. It was found out that the selection rules for f–f electron transitions substantially changed in the magnetically ordered state of the crystal, and they strongly depended on the orientation of the Fe and Nd ions magnetic moments relative to the light polarization. The splitting of the ground and excited states of the Nd3+ ion in the exchange field of the Fe sublattice were determined. It was revealed that the value of the exchange splitting (the exchange interaction) in the excited states did not correlate with the theoretical Landé factors. The Landé factors of the excited states were experimentally found. In general, the local magnetic properties in the vicinity of the excited ion depend substantially on its electron state. In particular: (1) in one of the excited states a weak ferromagnetic moment appears, (2) the changes of type of the local magnetic anisotropy take place in some excited states, and (3) in some excited states the energetically favorable orientation of the Nd3+ ion magnetic moment is opposite to that in the ground state. In some excited states the nonequivalent Nd3+ centers were found out.Поляризованные спектры поглощения F-е переходов 4I9/2 → 4F3/2 и (2H9/2 + 4F5/2) в иона Nd3+ в Nd0.5Gd0.5Fe3(BO3)4 монокристалл изучались как функции температуры в интервале 2-40 K и в зависимости от магнитного поля в диапазоне 0-65 кЭ при 2 К. Выяснилось, что Правила отбора для F-F электронных переходов существенно изменился в магнитно-упорядоченном состоянии кристалла, и они сильно зависели от ориентации магнитных моментов ионов Fe и Nd по отношению к поляризация света. Расщепление основного и возбужденного состояний иона Nd3+ в обменном поле подрешетки Fe были определены. Было выявлено, что величина обменного расщепления (обменное взаимодействие) в возбужденных состояниях не коррелируют с теоретическими факторами Ланде. Факторы Ланде возбужденных состояний были найдены экспериментально. В целом, локальные магнитные свойства в непосредственной близости от возбужденного иона существенно зависят от его электронного состояния. В частности: (1) в одном из возбужденной состояния появляется слабый ферромагнитный момент, (2) изменения типа локальных магнитной анизотропии происходит в некоторых возбужденных состояниях, и (3) в некоторых возбужденных состояниях энергетически благоприятных ориентация иона Nd3+ магнитного момента противоположны тем, что в основном состоянии. В некоторых возбужденных состояниях были обнаружены неэквивалентные центры Nd3+.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Gnatchenko S. L., Kachur I. S., Piryatinskaya V. G., Temerov V. L.
Заглавие : Peculiarities of magnetic properties of Nd3+ ions in the Nd0.5Gd0.5Fe3(BO3)4 crystal in the optically excited states 4(F7/2 + S3/2) and (4G9/2 + 2K13/2 + 4G7/2)
Место публикации : J. Alloys Compd.: Elsevier, 2016. - Vol. 680. - P.87-94. - ISSN 09258388 (ISSN), DOI 10.1016/j.jallcom.2016.04.088
Примечания : Cited References: 32. - The work was supported by the Russian Foundation for Basic Researches grant 16-02-00273 and by the President of Russia grant No Nsh-2886.2014.2.
Предметные рубрики: Single-crystal
GdFe3(BO3)4
Ключевые слова (''Своб.индексиров.''): f-f transitions--nd3+ ion--excited states--local magnetic properties
Аннотация: Polarized absorption spectra of f-f absorption bands 4I9/2 → 4(F7/2 + S3/2) and (4G9/2 + 2K13/2 + 4G7/2) in the Nd3+ ion in the Nd0.5Gd0.5Fe3(BO3)4 single crystal were studied as a function of temperature in the range of 2–40 K and as a function of magnetic field in the range of 0–65 kOe at 2 K. It was found out that the selection rules for f-f electron transitions substantially changed in the magnetically ordered state of the crystal, and they strongly depended on the orientation of the Fe and Nd ions magnetic moments relative to the light polarization. The splitting of the excited states of the Nd3+ ion in the exchange field of the Fe sublattice were determined. It was revealed that the value of the exchange splitting (the exchange interaction) did not correlate with the theoretical Landé factor. The Landé factors of the excited states were experimentally found. The local reorientation field induced metamagnetic transitions were observed in the excited states. In some excited states the energetically favorable orientation of the Nd3+ ion magnetic moment is opposite to that in the ground state.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Sukhachev A. L., Leont'ev A. A., Temerov V. L.
Заглавие : Magnetic and natural optical activity of f–f transitions in multiferroic Nd0.5Gd0.5Fe3(BO3)4
Коллективы : Council on Grants from the President of the Russian Federation for the State Support of Leading Scientific Schools [NSh-2886.2014.2]; Russian Foundation for Basic Research [16-02-00273]
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2016. - Vol. 58, Is. 5. - P.952-958. - ISSN 1063-7834, DOI 10.1134/S1063783416050152. - ISSN 1090-6460(eISSN)
Примечания : Cited References:29. - This study was supported by the Council on Grants from the President of the Russian Federation for the State Support of Leading Scientific Schools (grant no. NSh-2886.2014.2) and the Russian Foundation for Basic Research (project no. 16-02-00273).
Предметные рубрики: Circular-dichroism spectra
Magnetooptical properties
Single-crystal
Absorption
Ions
NdFe3(BO3)4
Nd3+
Pr3+
Ho3+
Аннотация: Spectra of absorption, magnetic circular dichroism, and natural circular dichroism of the f–f transitions 4I9/2 → 4F3/2, 2H9/2 + 4F5/2, 4S3/2 + 4F7/2, 2G7/2 + 4G5/2, 2K13/2 + 4G7/2, and 4G9/2 in the Nd3+ ions in the Nd0.5Gd0.5Fe3(BO3)4 crystal have been measured as a function of the temperature in the interval of 90–300 K. Temperature dependences of the magneto-optical activity (MOA) and natural optical activity (NOA) of the transitions have been obtained. It has been found that, in contrast to allowed transitions, the temperature dependence of the MOA of the f–f transitions does not obey the Curie–Weiss law and the NOA depends on temperature. The NOA of some transitions changes the sign with variation in temperature. These phenomena have been explained by the presence of three contributions to the allowance of the f–f transitions, which lead to three contributions of different signs to the MOA and NOA. The range of the MOA of the f–f transitions in the Nd3+ ion has been predicted theoretically and confirmed experimentally.
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