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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Dudnikov V. A., Ovchinnikov S. G., Orlov Yu.S., Kazak N. V., Michel C. R., Patrin G. S., Yurkin G.Yu.
Заглавие : Contribution of Co3+ ions to the high-temperature magnetic and electrical properties of GdCoO3
Место публикации : J. Exp. Theor. Phys.: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 114, Is. 5. - P.841-849. - ISSN 1063-7761, DOI 10.1134/S106377611203003X
Примечания : Cited References: 28. - This work was supported by the Ural Branch of the Russian Academy of Sciences and Siberian Branch of the Russian Academy of Sciences (project no. 40), the Russian Foundation for Basic Research (project nos. 09-02-00171-a, 10-02-00251), program 2.3 of the Department of Physical Sciences of Russian Academy of Sciences, and Nonprofit Dinastiya Foundation.
Предметные рубрики: SPIN-STATE
RCOO3 R
TRANSITIONS
COBALTITES
LACOO3
OXIDES
SM
EU
ND
Аннотация: The temperature dependence of the static magnetization of polycrystalline rare-earth cobaltite GdCoO3 is measured in the temperature range 2-800 K. The magnetic behaviors of GdCoO3 and Gd3+ are found to be different at temperatures above room temperature, which is caused by the appearance of a contribution from Co3+ ions at high temperatures. The temperature dependence of the magnetic susceptibility of GdCoO3 is determined by the magnetization of rare-earth gadolinium ions and the additional paramagnetic contribution induced by the thermally excited magnetic terms of Co3+ ions. The LDA + GTB method is used to calculate the electronic structure of GdCoO3 in the temperature range 0-300 K with allowance for strong electron correlations. The energy spectrum of GdCoO3 is found to have intragap states that decrease the dielectric gap width with increasing temperature.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Dudnikov V. A., Velikanov D. A., Kazak N. V., Michel C. R., Bartolome J., Arauzo A., Ovchinnikov S. G., Patrin G. S.
Заглавие : Antiferromagnetic ordering in REM cobaltite GdCoO3
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 54, Is. 1. - P.79-83. - ISSN 1063-7834, DOI 10.1134/S106378341201009X
Примечания : Cited References: 16. - This study was supported by the program of the Branch of Physical Sciences of the Russian Academy of Sciences "Strong Electron Correlations," the Russian Foundation for Basic Research (project no. 09-02-00171-a), and Federal Agency for Science and Innovations (grant no. MK-5632.2010.2).
Предметные рубрики: SPIN-STATE
RCo3O3 R
Sm
Eu
Nd
Аннотация: Temperature and magnetic-field dependences of the static magnetization of polycrystalline cobaltite GdCoO3 have been measured. The magnetic properties of the GdCoO3 sample have been studied in the paramagnetic and antiferromagnetic states. The magnetic phase diagram has been constructed. The exchange field between the Gd-Gd sublattices and the anisotropy field have been estimated.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Petrakovskii G. A., Drokina T. V., Velikanov D. A., Bayukov O. A., Molokeev M. S., Kartashev A. V., Shadrina A. L., Mitsuk A. A.
Заглавие : Magnetic state of the GdFeTi2O7 compound
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 54, Is. 9. - P.1813-1816. - ISSN 1063-7834, DOI 10.1134/S1063783412090235
Примечания : Cited References: 11
Предметные рубрики: SPIN-GLASS
GD
SM
Аннотация: The X-ray diffraction, Mossbauer, calorimetric, and magnetic characteristics of zirconolite GdFeTi2O7 have been measured to determine the ground magnetic state. A kink dependent on the magnetic prehistory of the sample has been revealed in the temperature dependence of the magnetic moment at T = 3 K. Mossbauer spectroscopy has confirmed the nonequivalence of the iron ion positions in GdFeTi2O7. The experimental data obtained allow the conclusion on the formation of a spin glass state with the freezing temperature T (f) = 3 K in the GdFeTi2O7 compound.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boldyrev K. N., Stanislavchuk T. N., Sirenko A. A., Bezmaternykh L. N., Popova M. N.
Заглавие : Coupling between phonon and crystal-field excitations in multiferroic PrFe3(BO3)4
Коллективы : Russian Scientific Foundation [14-12-01033]; President of Russian Federation [MK-1700.2013.2]; U.S. Department of Energy [DE-FG02-07ER46382, DE-AC02-98CH10886]
Место публикации : Phys. Rev. B: American Physical Society, 2014. - Vol. 90, Is. 12. - Ст.121101. - ISSN 1098-0121, DOI 10.1103/PhysRevB.90.121101. - ISSN 1550-235X
Примечания : Cited References: 35. - This research was supported by the Russian Scientific Foundation under Grant No. 14-12-01033, the President of Russian Federation (MK-1700.2013.2; K.N.B.), and the U.S. Department of Energy under Grant No. DE-FG02-07ER46382 (experiments at U4-IR beamline NSLS-BNL; T.N.S. and A.A.S.). The National Synchrotron Light Source is operated as a User Facility for the U.S. Department of Energy under Contract No. DE-AC02-98CH10886. M.N.P. thanks B. Z. Malkin for drawing her attention to the work [33] and for helpful discussions.
Предметные рубрики: MAGNETOELECTRIC PROPERTIES
GROUND-STATE
SM
Аннотация: Far-infrared reflection and ellipsometry measurements on multiferroic PrFe3(BO3)4 and SmFe3(BO3)4 single crystals were used to investigate the interaction between lattice phonons and electronic excitations associated with 4f crystal-field transitions. A temperature-dependent interference between two types of excitations was observed in PrFe3(BO3)4 in which the frequency of 4f crystal-field electronic excitation of Pr3+ falls into the TO-LO frequency interval of the optical phonon mode near 50 cm−1 (1.5 THz). Experimental data were explained on the basis of a theoretical model of coupled electron-phonon modes. The fitting procedure revealed the value 14.8 cm−1 for the electron-phonon coupling constant. This rather large value points to an essential role played by the electron-phonon interaction in the physics of multiferroics.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Popova M. N., Boldyrev K. N., Klimin S. A., Stanislavchuk T. N., Sirenko A. A., Bezmaternykh L. N.
Заглавие : Spectral signatures of spin-phonon and electron-phonon interactions in multiferroic iron borates
Коллективы : Moscow International Symposium on Magnetism , Russian Science Foundation [14-12-01033], U.S. Department of Energy [DE-FG02-07ER46382, DE-AC02-98CH10886]
Место публикации : J. Magn. Magn. Mater.: Elsevier Science, 2015. - Vol. 383. - P.250-254. - ISSN 0304-8853, DOI 10.1016/j.jmmm.2014.10.095. - ISSN 1873-4766 (eISSN)
Примечания : Cited References:32. - This work was supported by the Russian Science Foundation (Grant no. 14-12-01033). Experiments at U4-IR beamline NSLS-BNL (T.N.S. and A.A.S.) were performed under Contract no. DE-FG02-07ER46382 from the U.S. Department of Energy. The National Synchrotron Light Source is operated as a User Facility for the U.S. Department of Energy under Contract no. DE-AC02-98CH10886. M.N.P. thanks B.Z. Malkin for helpful discussions.
Предметные рубрики: SMFE3(BO3)4
SPECTROSCOPY
CRYSTALS
SM
Ключевые слова (''Своб.индексиров.''): rare-earth iron borates--spin phonon interactions--electron phonon coupling--optical spectroscopy
Аннотация: High-resolution far-infrared reflection and polarized ellipsometry, as well as Raman scattering temperature-dependent measurements are used to study spin-phonon and electron-phonon interactions in rare-earth (RE) iron borates with the R32 structure of a natural mineral huntite, namely, in RFe3(BO3)4 with R=Pr, Nd, and Sm. Pronounced peculiarities in the ω(T) dependences at the Néel temperature TN≈32 K are observed for all the compounds studied and the origin of these peculiarities is discussed. A coupling between lattice phonons and crystal-field excitations of a RE ion manifests itself by a renormalization of frequencies and intensities of coupled modes. Modeling of the spectra has revealed the value of about 15 cm−1 for the electron–phonon coupling constant in PrFe3(BO3)4.Высокоразрешающая эллипсометрия дальнего инфракрасного отражения и поляризованный света, а также температурнозависимые измерения комбинационного рассеяния используются для изучения спин-фононных и электрон-фононных взаимодействий в редкоземельных (RE) боратах железа со структурой R32 природного минерала хантита , а именно, в RFe3 (BO3) 4 с R = Pr, Nd, и Sm. Выраженные особенности ω (T) зависимостей при температуре Нееля TN ≈32 K наблюдаются для всех исследованных соединений и происхождение этих особенностей обсуждается.Связь между фононами решетки и возбуждениями кристаллического поля РЗ иона проявляется себя перенормализации частоты и интенсивности связанных мод. Моделирование спектров показал значение около 15cm-1 для константы электрон-фононной связи в PrFe3 (BO3) 4.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova N. B., Kazak N. V., Michel C. R., Balaev A. D., Ovchinnikov S. G.
Заглавие : Low-temperature magnetic behavior of the rare-earth cobaltites GdCoO3 and SmCoO3
Разночтения заглавия :авие SCOPUS: Low-temperature magnetic behavior of the rare-earth cobaltites GdCoO 3 and SmCoO3
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007. - Vol. 49, Is. 11. - P2126-2131. - ISSN 1063-7834, DOI 10.1134/S1063783407110182
Примечания : Cited References: 32. - This study was supported by the Branch of General Physics and Astronomy of the Russian Academy of Sciences within the framework of the program “Strong Electron Correlations” and the Russian Science Support Foundation
Предметные рубрики: METAL-INSULATOR-TRANSITION
RCOO3 R
SPIN-STATE
OXIDE
SM
ND
PEROVSKITE
GLASSES
PR
EU
Аннотация: The temperature and magnetic field dependences of the static magnetization of the polycrystalline rare-earth cobaltites GdCoO3 and SmCoO3 have been measured. It is shown that, below room temperature, the magnetization of both compounds derives primarily from the rare-earth ion paramagnetism. The GdCoO3 and SmCoO3 compounds have been found to differ substantially in magnetic behavior, which can be traced to differences in their electronic shell structures. The magnetic behavior of GdCoO3 is close to that of an array of free Gd3+ ions, whereas in SmCoO3 the deviation from the free-ion properties is very large because of the Sm3+ ground state being crystal-field split. Van Vleck magnetic susceptibility measurements of SmCoO3 suggest that the splitting is similar to 10 K.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova N. B., Kazak N. V., Michel C. R., Balaev A. D., Ovchinnikov S. G., Vasil'ev A. D., Bulina N. V., Panchenko E. B.
Заглавие : Effect of strontium and barium doping on the magnetic state and electrical conductivity of GdCoO3
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007. - Vol. 49, Is. 8. - P1498-1506. - ISSN 1063-7834, DOI 10.1134/S1063783407080161
Примечания : Cited References: 36
Предметные рубрики: PEROVSKITE
ORDER
OXIDE
BEHAVIOR
GLASSES
LACOO3
PR
GD
SM
ND
Аннотация: A coordinated investigation of the magnetic and electrical properties of polycrystalline cobalt oxide compounds CdCoO3, Gd0.9Ba0.1CoO3, and Gd0.9Sr0.1CoO3 is carried out. Undoped GdCoO3 reveals a low conductivity; a magnetic moment of 7.4 mu(B) per molecule, which is less than the theoretical value for the Gd3+ ion; and an asymptotic Curie temperature of -6 K. Doping GdCoO3 with barium and strontium to substitution of 10 at. % Gd brings about an increase in the conductivity and magnetic transitions at T = 300 K for Gd0.9Ba0.1CoO3 and T = 170 K for Gd0.9Sr0.1CoO3. The magnetization anomalies imply the formation of magnetic clusters. The behavior of the electrical conductivity at high temperatures suggests a variable activation energy. At low temperatures, Mott hopping conduction sets in.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Yen F., Lorenz B., Sun Y. Y., Chu C. W., Bezmaternykh L. N., Vasiliev A. N.
Заглавие : Magnetic field effect and dielectric anomalies at the spin reorientation phase transition of GdFe3(BO3)(4)
Разночтения заглавия :авие SCOPUS: Magnetic field effect and dielectric anomalies at the spin reorientation phase transition of GdFe3 (BO3) 4
Место публикации : Phys. Rev. B: AMERICAN PHYSICAL SOC, 2006. - Vol. 73, Is. 5. - Ст.54435. - ISSN 1098-0121, DOI 10.1103/PhysRevB.73.054435
Примечания : Cited References: 21
Предметные рубрики: IRON BORATE GDFE3(BO3)(4)
HOMNO3
ANISOTROPY
PR
SM
Аннотация: GdFe3(BO3)(4) exhibits a structural phase transition at 156 K, antiferromagnetic order of the Fe3+ moments at 36 K, followed by a spin reorientation phase transition at 9 K. The reorientation phase transition is studied through dielectric, magnetic, and heat capacity measurements under the application of external magnetic fields of up to 7 kOe. The dielectric constant indicates the existence of two distinct anomalies at T-SR=9 K that separate in temperature under external magnetic fields. The spin rotation phase transition is proven to be of the first-order nature through the magnetic analog of the Clausius-Clapeyron equation. Magnetodielectric effect of up to 1% is observed at 8 K and 7 kOe. The uniaxial magnetocaloric effect along the c axis is observed below the spin reorientation phase transition of 9 K.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Oreshonkov A. S., Shestakov N. P., Molokeev M. S., Aleksandrovsky A. S., Gudim I. A., Temerov V. L., Adichtchev S. V., Pugachev A. M., Nemtsev I. V., Pogoreltsev E. I., Denisenko Y. G.
Заглавие : Monoclinic SmAl3(BO3)4: synthesis, structural and spectroscopic properties
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-03-00750, 18-05-00682, 18-32-20011]
Место публикации : Acta Crystallogr. B. - 2020. - Vol. 76. - P.654-660. - ISSN 2052-5206(eISSN), DOI 10.1107/S2052520620008781
Примечания : Cited References: 38. - Funding for this research was provided by: Russian Foundation for Basic Research (grant Nos. 18-03-00750, 18-05-00682 and 18-32-20011 to AO)
Предметные рубрики: Optical-properties
Luminescence
Spectra
Crystals
Sm
Аннотация: Single crystals of SmAl3(BO3)4 were synthesized by the group growth on seeds method. The crystal structure was solved using a single-crystal experiment and the purity of the bulk material was proved by the Rietveld method. This borate crystallizes in the monoclinic C2/c space group with unit-cell parameters a = 7.2386 (3), b = 9.3412 (5), c = 11.1013 (4) Å and β = 103.2240 (10)°. IR and Raman spectroscopic analyses confirmed the monoclinic structure of SmAl3(BO3)4. Under 532.1 nm excitation, luminescence spectra exhibit bands assignable to the transitions from 4G5/2 to 6H5/2, 6H7/2, 6H9/2 and 6H11/2. The similarity of the luminescence spectra of the trigonal and monoclinic poly­morphs is explained by the minor role of Sm—O bond distortion and the primary role of rotational distortion of SmO6 octa­hedra. The smaller covalency of the Sm—O bond in alumoborates is deduced in comparison with galloborates. Calorimetric measurements did not reveal high-temperature structural phase transitions up to a temperature of 720 K.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kazak N. V., Ovchinnikov S. G., Balaev A. D., Ivanova N.B., Pashkevich, Yu. G., Michel C.R., Bondarenko G. V.
Заглавие : Magnetic and transport properties of Gd(0.9)A(0.1)CoO(3-delta) (A = Ba, Sr)
Место публикации : J. Magn. Magn. Mater. - 2009. - Vol. 321, Is. 9. - P.1266-1271. - ISSN 0304-8853, DOI 10.1016/j.jmmm.2008.11.087
Примечания : Cited Reference Count: 31. - Гранты: This study was supported by the Rosnauka (Project no. MK-4278.2008.2), Russian Foundation for Basic Research (Project no. 08-02-90708 mob_st) and "Strongly correlated electrons'' program of the Department of Physical Sciences of RAS.Финансирующая организация: Rosnauka [MK-4278.2008.2]; Russian Foundation for Basic Research [08-02-90708 mob_st]; "Strongly correlated electrons'' program of the Department of Physical Sciences of RAS
Предметные рубрики: PEROVSKITE
PR
LA
EU
ND
LN
TRANSITION
SPIN
GD
SM
Ключевые слова (''Своб.индексиров.''): perovskite structure--doped cobaltite--magnetic susceptibility--metal-insulator transition--doped cobaltite--magnetic susceptibility--metal-insulator transition--perovskite structure--antiferromagnetism--barium--cobalt compounds--electric conductivity--ferromagnetic materials--ferromagnetism--gadolinium--magnetic susceptibility--metal insulator boundaries--oxide minerals--paramagnetic materials--perovskite--phase separation--semiconductor insulator boundaries--transport properties--antiferromagnetic--doped cobaltite--doped samples--electrical conductivity measurements--ferromagnetic transitions--insulator-metal transitions--magnetic and transport properties--magnetic behaviors--perovskite structure--temperature ranges--transport datum--x- ray diffractions--metal insulator transition
Аннотация: The X-ray diffraction, magnetization and electrical conductivity measurements for Gd(0.9)A(0.1)CoO(3-delta) (A = Ba, Sr) have been made. The complicated magnetic behavior, including the paramagnetic-ferromagnetic-antiferromagnetic and paramagnetic-ferromagnetic transitions, was found for Ba- and Sr-doped samples. The gradual insulator-metal transitions were observed in a wide temperature range T = 600-800 K. The complex magnetic and transport data could be explained on the basis of the structural phase separation. (C) 2009 Elsevier B.V. All rights reserved.
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