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Pulsed laser deposition of europium borate glass films and their optical and magneto-optical properties / A. S. Aleksandrovsky [et al.] // Laser-Assisted Micro- and Nanotechnologies. Proceedings of SPIE : [11-15 May 2005]. - 2006. - P. 61610A

РИНЦ
Держатели документа:
L. V. Kirensky Institute of Physics, Akademgorodok, Krasnoyarsk 660036

Доп.точки доступа:
Konov, V. I. \ed.\; Panchenko, V. Y. \ed.\; Sugioka, K. \ed.\; Veiko, V. P. \ed.\; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Krylov, A. S.; Крылов, Александр Сергеевич; Potseluyko, A. M.; Potseluyko; Seredkin, V. A.; Середкин, Виталий Александрович; Zaitsev, A. I.; Зайцев, Александр Иванович; Zamkov, A. V.; Замков, Анатолий Васильевич; International Conference on Lasers, Applications, and Technologies(2005 ; May ; St. Peterburg, Russia)
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    Zhiguo, Xia.
    Crystal structure and photoluminescence properties of europium doped Ca7La3(PO4)3(SiO4)3F2 / X Zhiguo, M. S. Molokeev, V. V. Atuchin // XVI Международная конференция "Опто-, наноэлектроника, нанотехнологии и микросистемы" : Труды. - Ульяновск, 2013. - P. 156
   Перевод заглавия: Кристаллическая структура и фотолюминесцентные свойства Ca7La3(PO4)3(SiO4)3F2 допированного Eu

Материалы конференции

Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич; Atuchin, V. V.; Институт нанотехнологий микроэлектроники РАН; Ульяновский государственный университет; Российский фонд фундаментальных исследованийАкадемия наук Татарстана; "Opto-, nanoelectronics, nanotechnology, and microsystems", International Conference (2013 ; Jul. ; 26-30 ; Ulyanovsk, Russia); "Опто-, наноэлектроника, нанотехнологии и микросистемы", международная конференция (2013 ; июль.; 26-30 ; Ульяновск)
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Terahertz spectroscopy of multiferroic EuFe3(BO3)4 / K. N. Boldyrev [et al.] // Phys. Lett. A. - 2012. - Vol. 376, Is. 37. - P. 2562-2564, DOI 10.1016/j.physleta.2012.06.028. - Cited References: 19. - This work was partially supported by the Russian Foundation for Basic Research under Grants No. 10-02-01071-a and No. 09-02-00171-a, by the Ministry of Education and Science under Grant HIII-4828.2012.2, and by the Russian Academy of Sciences under the programs for basic research. . - ISSN 0375-9601

РУБ Physics, Multidisciplinary
Рубрики:
SINGLE-CRYSTAL
GDFE3(BO3)4
Кл.слова (ненормированные):
Terahertz spectroscopy -- Multiferroics -- Europium iron borate
Аннотация: The terahertz spectra of a rare-earth iron borate with the huntite structure are obtained for the first time. We study the low-temperature (4.0–90 K) α-polarized transmittance spectra of the EuFe3(BO3)4 single crystal in the region 0.9–6.0 THz. Pronounced shifts of phonon frequencies and appearance of new phonon modes at the temperature T S = 58 K of the R 32 → P 3 1 21 structural phase transition are observed. Additional shifts of phonon frequencies occur at the temperature T N = 34 K of the magnetic ordering of the Fe subsystem, thus evidencing the spin–phonon coupling in this multiferroic material.

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Держатели документа:
[Boldyrev, K. N.
Klimin, S. A.
Popova, M. N.] RAS, Inst Spect, Troitsk 142190, Moscow Region, Russia
[Stanislavchuk, T. N.] New Jersey Inst Technol, Dept Phys, Newark, NJ 07102 USA
[Bezmaternykh, L. N.] RAS, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Boldyrev, K. N.; Stanislavchuk, T. N.; Klimin, S. A.; Popova, M. N.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
}
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Crystal structures of EuLnCuS3 (Ln = Nd and Sm) / A. V. Ruseikina [et al.] // Russ. J. Inorg. Chem. - 2012. - Vol. 57, Is. 1. - P. 79-83, DOI 10.1134/S0036023612010172. - This work was supported by the Federal Target Program "Scientific and Pedagogical Personnel of Innovative Russia" for 2009-2013 (grant nos. 6K/143-09 (P 646) and NK-409/5 (P2263)) and the President of the Russian Federation (Support Program for Leading Scientific Schools of the Russian Federation, grant NSh-4645.2010.2). - The results of this study have been presented at the X International Scientific Conference “Solid-State Chemistry: Nanomaterials, Nanotechnologies” (Stavropol, October 17–22, 2010) and the All-Russia Scientific Conference “Challenges of Modern Chemistry. Theory and Practice” (Ufa, October 21–23, 2010). . - ISSN 0036-0236

РУБ Chemistry, Inorganic & Nuclear
Рубрики:
RARE-EARTH
   MAGNETIC-PROPERTIES
   COPPER SULFIDE
   CHALCOGENIDES
   EUROPIUM
   EU2CUS3
Аннотация: The compound sulfides EuLnCuS3 (Ln = Nd and Sm) were obtained for the first time. Their crystal structures were determined from X-ray powder diffraction data. The crystals of both compounds are orthorhombic (space group Pnma). The compound EuNdCuS3 is isostructural with BaLaCuS3; the unit cell parameters are a = 11.0438(2) Å, b = 4.0660(1) Å, c = 11.4149(4) Å. The compound EuSmCuS3 is isostructural with Eu2CuS3; the unit cell parameters are a = 10.4202(2) Å, b = 3.9701(1) Å, c = 12.8022(2) Å.

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Публикация на русском языке Кристаллическая структура соединений EuLnCuS3 (Ln = Nd, Sm) [Текст] / А. В. Русейкина [и др.] // Журн. неорг. химии : Наука, 2012. - Т. 57 № 1. - С. 86-90

Держатели документа:
GOU VPO Tyumen State Univ, Tyumen, Russia
Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk, Russia
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk, Russia

Доп.точки доступа:
Ruseikina, A. V.; Solovyov, L. A.; Соловьев, Леонид Александрович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Andreev, O. V.
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    Synthesis and spectroscopic properties of monoclinic α-Eu2(MoO4)3 / V. V. Atuchin [et al.] // J. Phys. Chem. C. - 2014. - Vol. 118, Is. 28. - P. 15404-15411, DOI 10.1021/jp5040739. - Cited References: 63. - This study is partly supported by the Ministry of Education and Science of the Russian Federation. . - ISSN 1932-7447
   Перевод заглавия: Синтез и спектроскопические свойства моноклинного а-Eu2(MoO4)3

РУБ Chemistry, Physical + Nanoscience & Nanotechnology + Materials Science, Multidisciplinary
Рубрики:
RARE-EARTH MOLYBDATES
   VIBRATIONAL PROPERTIES
   LUMINESCENCE PROPERTIES
   CRYSTAL-STRUCTURE
   PHASE-TRANSITIONS
   TRIPLE MOLYBDATE
   SINGLE-CRYSTAL
   X-RAY
   PHOSPHORS
   EUROPIUM
Аннотация: The microcrystals of monoclinic europium molybdate, alpha-Eu-2(MoO4)(3), have been fabricated by solid-state synthesis at T = 753-1273 K for 300 h. The crystal structure of alpha-Eu-2(MoO4)(3) has been refined by the Rietveld method and was found to belong to the space group C2/c with unit cell parameters a = 7.5576(1), b = 11.4709(2), c = 11.5158(2) angstrom, and beta = 109.278(1)degrees (R-B = 3.39%). About 40 narrow Raman lines have been observed in the Raman spectrum of the alpha-Eu-2(MoO4)(3) powder sample. The luminescence spectra of alpha-Eu-2(MoO4)(3) under excitation at 355 and 457.9 nm reveal domination of induced electric dipole transition D-5(0) - F-7(2) and the presence of ultranarrow lines at D-5(0) - F-7(0) and D-5(1) - F-7(0) transitions.

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Держатели документа:
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia
SB RAS, Lab Coherent Opt, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
SB RAS, Lab Oxide Syst, Baikal Inst Nat Management, Ulan Ude 670047, Russia
SB RAS, Inst Semicond Phys, Lab Nanodiagnost & Nanolithog, Novosibirsk 630090, Russia
SB RAS, Kirensky Inst Phys, Lab Mol Spect, Krasnoyarsk 660036, Russia
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Atuchin, V. V.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Chimitova, O. D.; Gavrilova, T. A.; Krylov, A. S.; Крылов, Александр Сергеевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Bazarov, B. G.; Bazarova, J. G.; Ministry of Education and Science of the Russian Federation
}
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New yellow-emitting whitlockite-type structure Sr1.75Ca 1.25(PO4)2:Eu2+ phosphor for near-UV pumped white light-emitting devices / H. P. Ji [et al.] // Inorg. Chem. - 2014. - Vol. 53, Is. 10. - P. 5129-5135, DOI 10.1021/ic500230v. - Cited References: 31. - This work was supported by the National Natural Science Foundations of China (Grant Nos. 51032007, 51002146, 51272242), the Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20130022110006), and the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950). V.V.A. gratefully acknowledges the Ministry of Education and Science of the Russian Federation for the financial support. S.H. would like to acknowledge the China Scholarship Council (CSC) for providing a doctoral scholarship for his Ph.D. study at the University of Auckland. . - ISSN 0020-1669. - ISSN 1520-510X

РУБ Chemistry, Inorganic & Nuclear
Рубрики:
LUMINESCENCE PROPERTIES
   CRYSTAL-STRUCTURE
   RED PHOSPHOR
   DIODES
   LEDS
   SR
   CA
   ORTHOPHOSPHATE
   CA-3(PO4)2
   EUROPIUM
Аннотация: New compound discovery is of interest in the field of inorganic solid-state chemistry. In this work, a whitlockite-type structure Sr1.75Ca1.25(PO4)2 newly found by composition design in the Sr3(PO4)2–Ca3(PO4)2 join was reported. Crystal structure and luminescence properties of Sr1.75Ca1.25(PO4)2:Eu2+ were investigated, and the yellow-emitting phosphor was further employed in fabricating near-ultraviolet-pumped white light-emitting diodes (w-LEDs). The structure and crystallographic site occupancy of Eu2+ in the host were identified via X-ray powder diffraction refinement using Rietveld method. The Sr1.75Ca1.25(PO4)2:Eu2+ phosphors absorb in the UV–vis spectral region of 250–430 nm and exhibit an intense asymmetric broadband emission peaking at 518 nm under λex = 365 nm which is ascribed to the 5d–4f allowed transition of Eu2+. The luminescence properties and mechanism are also investigated as a function of Eu2+ concentration. A white LED device which is obtained by combining a 370 nm UV chip with commercial blue phosphor and the present yellow phosphor has been fabricated and exhibit good application properties.

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Держатели документа:
China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia

Доп.точки доступа:
Ji, H. P.; Huang, Z. H.; Xia, Z. G.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Atuchin, V. V.; Fang, M. H.; Huang, S. F.
}
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Golovnev, N. N.
Crystal structure and some properties of europium(III) Catena-{tris(1,3-diethyl-2-thiobarbiturate)} / N. N. Golovnev, M. S. Molokeev, S. N. Vereshchagin // J. Struct. Chem. - 2016. - Vol. 57, Is. 1. - P. 167-174, DOI 10.1134/S0022476616010200. - Cited References: 25. - The work was supported within the State Contract of the Ministry of Education and Science of the Russian Federation for research in the Siberian Federal University in 2015. . - ISSN 0022-4766

РУБ Chemistry, Inorganic & Nuclear + Chemistry, Physical
Рубрики:
1,3-diethyl-2-thiobarbituric acid
   Hydrogen-bond
   Diffraction
   Series
Кл.слова (ненормированные):
crystal structure -- complex -- europium(III) -- 1,3-diethyl-2-thiobarbituric acid -- thermal analysis -- IR spectroscopy -- photoluminescence
Аннотация: The [Eu(HDTBA)3] n complex (I), HDTBA is 1,3-diethyl-2-thiobarbituric acid (C8H12N2O2S) is synthesized and its structure is determined by X-ray crystallography. The crystals of I are triclinic: a = 11.0205(2) Å, b = 11.8811(3) Å, c = 12.7312(2) Å, α = 100.933(1)°, β = 109.704(1)°, γ = 101.161(1)°, V = 1479.88(5) Å3, space group P-1, Z = 2. Each of three independent DETBA- ions is a bridging μ2-O,O′-coordinated ligand. The coordination polyhedron of Eu(III) is a distorted octahedron. Bridging DETBA- organize the octahedra into an infinite two-dimensional layer. The structure contains intramolecular hydrogen bonds but intermolecular hydrogen bonds and the π-π interaction are absent. The results of IR spectroscopy and photoluminescence agree with the single crystal X-ray diffraction data. The main product of the thermal decomposition of I at 900°C is oxysulfate Eu2O2SO4. © 2016 Pleiades Publishing, Ltd.

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Публикация на русском языке Головнёв, Николай Николаевич. Кристаллическая структура и некоторые свойства катена-трис(1,3-диэтил-2-тиобарбитурата) европия(III) [Текст] / Н. Н. Головнёв, М. С. Молокеев, С. Н. Верещагин // Журн. структ. химии. - 2016. - Т. 57 № 1. - С. 171-178

Держатели документа:
Siberian Federal University, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Far Eastern State Transport University, Khabarovsk, Russian Federation
Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич; Vereshchagin, S. N.
}
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Antiferromagnetic Resonance and Dielectric Properties of Rare-earth Ferroborates in the Submillimeter Frequency Range / A. M. Kuz'menko [et al.] // J. Exp. Theor. Phys. - 2011. - Vol. 113, Is. 1. - P. 113-120, DOI 10.1134/S106377611105013X. - Cited References: 27. - This work was supported by the Russian Foundation for Basic Research, project no. 10-02-00846. . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
GDFE3(BO3)(4)
SPECTROSCOPY
CRYSTAL
Кл.слова (ненормированные):
Antiferromagnetic resonance -- Basic parameters -- Effective anisotropy constant -- Ferroborates -- Ferroics -- Ferromagnetic orderings -- Frequency ranges -- Magnetic interactions -- Magnetoresonance -- Millimeter frequency range -- Rare earth ions -- Submillimeters -- Antiferromagnetic materials -- Crystallography -- Erbium -- Europium -- Ferromagnetic resonance -- Ion exchange -- Magnetic anisotropy -- Magnetic devices -- Magnetic structure -- Permittivity -- Resonance -- Antiferromagnetism
Аннотация: The magnetoresonance and dielectric properties of a number of crystals of a new family of multiferroics, namely, rare-earth ferroborates RFe(3)(BO(3))(4) (R = Y, Eu, Pr, Tb, Tb(0.25)Er(0.75)), are studied in the submillimeter frequency range (nu = 3-20 cm(-1)). Ferroborates with R = Y, Tb, and Eu exhibit permittivity jumps at temperatures of 375, 198, and 58 K, respectively, which are caused by the R32 -> P3(1)2(1) phase transition. Antiferromagnetic resonance (AFMR) modes in the subsystem of Fe(3+) ions are detected in the range of antiferromagnetic ordering (T < T(N) = 30-40 K) in all ferroborates that have either an easy-plane (Y, Eu) or easy-axis (Pr, Tb, Tb(0.25)Er(0.75)) magnetic structure. The AFMR frequencies are found to depend strongly on the magnetic anisotropy of a rare-earth ion and its exchange interaction with the Fe subsystem, which determine the type of magnetic structure and the sign and magnitude of an effective anisotropy constant. The basic parameters of the magnetic interactions in these ferroborates are found, and the magnetoelectric contribution to AFMR is analyzed.

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Держатели документа:
[Kuz'menko, A. M.
Mukhin, A. A.
Ivanov, V. Yu.
Lebedev, S. P.] Russian Acad Sci, Inst Gen Phys, Moscow 119991, Russia
[Kadomtseva, A. M.] Moscow MV Lomonosov State Univ, Moscow 119991, Russia
[Bezmaternykh, L. N.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Institute of General Physics, Russian Academy of Sciences, ul. Vavilova 38, Moscow, 119991, Russian Federation
Moscow State University, Moscow, 119991, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Kuz'menko, A. M.; Mukhin, A. A.; Ivanov, V. Y.; Kadomtseva, A. M.; Lebedev, S. P.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
}
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Relaxation of low-temperature magnetoresistance and magnetization of polycrystalline (La0.5Eu0.5)(0.7)Pb0.3MnO3 / K. A. Shaykhutdinov [et al.] // J. Phys. D. - 2011. - Vol. 44, Is. 25. - Ст. 255001, DOI 10.1088/0022-3727/44/25/255001. - Cited References: 34. - This work was partially supported by the Lavrentyev Competition of the Young Scientist's Projects of the Siberian Branch of the Russian Academy of Sciences, Project No 12. The authors are grateful to A D Balaev and V M Sosnin for useful discussions on the results. . - ISSN 0022-3727

РУБ Physics, Applied
Рубрики:
INSULATOR-METAL TRANSITION
   GRANULAR FILMS
   NANOPARTICLES
   PR0.7CA0.3MNO3
   PERCOLATION
   MANGANITES
Кл.слова (ненормированные):
Antiferromagnetic boundaries -- Characteristic value -- Ferromagnetic domains -- Ferromagnetic metal -- Lanthanum manganites -- Logarithmic law -- Low temperatures -- Magneto-resistive effect -- Polycrystalline -- Relative orientation -- Relaxation of magnetization -- Temperature fluctuation -- Time evolutions -- Time interval -- Tunnel magnetoresistance -- Antiferromagnetism -- Electric resistance -- Europium -- Ferromagnetic materials -- Ferromagnetism -- Grain boundaries -- Grain size and shape -- Lanthanum compounds -- Lead -- Magnetic domains -- Magnetic moments -- Magnetoelectronics -- Magnetoresistance -- Manganese oxide -- Magnetization
Аннотация: Hysteresis and relaxation of magnetoresistance and magnetization of substituted (La0.5Eu0.5)(0.7)Pb0.3MnO3 lanthanum manganite in a low-temperature region (< 40 K) are investigated. It is shown that at these temperature features of the magnetoresistive effect are determined mainly by spin-dependent tunnelling of carriers via insulating grain boundaries. As was demonstrated previously, the grain boundaries may be antiferromagnetically ordered. Therefore, relaxation of magnetization and resistance is determined by the processes of relative orientation of the magnetic moments of ferromagnetic domains neighbouring the antiferromagnetic boundary of ferromagnetic domains under the action of temperature fluctuations. It is shown that relaxation follows the logarithmic law within the time interval t similar to 10(2)-3x10(3) s. A comparison between time evolutions of the magnetic moment and resistance shows that magnetoresistance and magnetization are related as delta R = delta M-n, where n = 2.5. The obtained value n is close to the characteristic value n = 2 for tunnel magnetoresistance of granular ferromagnetic metal/insulator systems.

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Держатели документа:
[Shaykhutdinov, K. A.
Balaev, D. A.
Semenov, S. V.
Popkov, S. I.
Dubrovskiy, A. A.
Sapronova, N. V.
Volkov, N. V.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Shaykhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Balaev, D. A.; Балаев, Дмитрий Александрович; Semenov, S. V.; Семенов, Сергей Васильевич; Popkov, S. I.; Попков, Сергей Иванович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Sapronova, N. V.; Volkov, N. V.; Волков, Никита Валентинович
}
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10.

Low-temperature resistance and magnetoresistance hysteresis in polycrystalline (La0.5Eu0.5)(0.7)Pb0.3MnO3 / K. A. Shaykhutdinov [et al.] // J. Appl. Phys. - 2011. - Vol. 109, Is. 5. - Ст. 53711, DOI 10.1063/1.3559303. - Cited References: 20. - This study was partially supported by the Russian Foundation for Basic Research, Project No. 08-02-00259a and the Lavrentyev Competition of the Young Scientists' Projects of the Siberian Branch of the Russian Academy of Sciences, Project No. 12. . - ISSN 0021-8979

РУБ Physics, Applied
Рубрики:
RESISTIVITY MINIMUM
MANGANITES
FILMS
Кл.слова (ненормированные):
Antiferromagnets -- Electrical resistances -- Ferromagnets -- Field dependence -- Inter-grain -- Lanthanum manganites -- Low temperatures -- Low-temperature resistance -- Polycrystalline -- Temperature dependence -- Tunnel contacts -- Antiferromagnetic materials -- Europium -- Ferromagnetic materials -- Ferromagnetism -- Hysteresis -- Lead -- Magnetic field effects -- Magnetoelectronics -- Magnetoresistance -- Magnets -- Manganese oxide -- Paramagnetism -- Superconducting materials -- Electric resistance
Аннотация: The behavior of temperature dependences of electrical resistance and magnetoresistance of polycrystalline substituted lanthanum manganite (La0.5Eu0.5)(0.7)Pb0.3MnO3 at low temperatures was thoroughly studied. A broad hysteresis was found in the field dependences of electrical resistance in the low-temperature region. Above 40 K, no hysteresis feature was observed. The temperature T = 40 K corresponds to the temperature of minimum electrical resistance and the temperature T-N to the antiferromagnet-paramagnet phase transition of the material of the intergrain boundaries. In this work we propose a model which explains the observed features of the rho(T) and rho(H) curves at temperatures below T-N by the formation of a network of ferromagnet-antiferromagnet-ferromagnet tunnel contacts. (C) 2011 American Institute of Physics. [doi:10.1063/1.3559303]

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Держатели документа:
[Shaykhutdinov, K. A.
Popkov, S. I.
Semenov, S. V.
Balaev, D. A.
Dubrovskiy, A. A.
Sablina, K. A.
Sapronova, N. V.
Volkov, N. V.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Shaykhutdinov, K. A.
Balaev, D. A.
Dubrovskiy, A. A.
Volkov, N. V.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
ИФ СО РАН
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk 660036, Russian Federation
Siberian Federal University, Krasnoyarsk 660041, Russian Federation

Доп.точки доступа:
Shaykhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Popkov, S. I.; Попков, Сергей Иванович; Semenov, S. V.; Семенов, Сергей Васильевич; Balaev, D. A.; Балаев, Дмитрий Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Sablina, K. A.; Саблина, Клара Александровна; Sapronova, N. V.; Volkov, N. V.; Волков, Никита Валентинович
}
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11.

Non-linear current-voltage characteristics of (La0.5Eu0.5)(0.7)Pb0.3MnO3 single crystals: Possible manifestation of the internal heating of charge carriers / K. A. Shaykhutdinov [et al.] // Physica B. - 2010. - Vol. 405, Is. 24. - P. 4961-4965, DOI 10.1016/j.physb.2010.09.043. - Cited References: 19. - The authors are grateful to A.N. Lavrov for useful discussions on the results. This study was partially supported by the Russian Foundation for Basic Research, Project no. 08-02-00259a and the Lavrent'ev Young Scientists' Competition of the Siberian Branch of the Russian Academy of Sciences. Project no. 12. . - ISSN 0921-4526

РУБ Physics, Condensed Matter
Рубрики:
INSULATOR-METAL TRANSITION
PR0.7CA0.3MNO3
MANGANITES
Кл.слова (ненормированные):
Manganites -- Negative differential resistance -- CVC -- CVC -- Manganites -- Negative differential resistance -- Applied electric field -- Charge ordering -- Current switching -- CVC -- Dielectric regions -- Experimental data -- Internal heating -- Lanthanum manganites -- Metal-dielectric transition -- Negative differential resistances -- Non equilibrium -- Non-linear -- Sample heating -- Temperature evolution -- Transport currents -- Electric fields -- Electron gas -- Europium -- Heating -- Lanthanum -- Lead -- Manganites -- Negative resistance -- Phase separation -- Single crystals -- Thermal conductivity -- Manganese oxide
Аннотация: Temperature evolution of the current-voltage characteristics (CVCs) of a single-crystal lanthanum manganite (La0.5Eu0.5)(0.7)Pb0.3MnO3 is investigated in a wide (up to 1 A) range of instrumental currents. Effects of a transport current and an applied electric field on the resistance of the material are studied in view of possible implementation of the charge ordering break in dielectric regions occurring due to phase separation in manganites. A negative differential resistance portion observed in the CVCs suggests the presence of a current switching effect. Below the temperature of the metal-dielectric transition in (La0.5Eu0.5)(0.7)Pb0.3MnO3, the hysteresis is observed in the CVC. The detailed analysis of the internal sample heating on the basis of experimental data on thermal conductivity showed, however, that these CVC features can be explained within the concept of non-equilibrium heating of electron gas. (C) 2010 Elsevier B.V. All rights reserved.

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Держатели документа:
[Shaykhutdinov, K. A.
Popkov, S. I.
Balaev, D. A.
Semenov, S. V.
Bykov, A. A.
Dubrovskiy, A. A.
Sapronova, N. V.
Volkov, N. V.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Shaykhutdinov, K. A.
Popkov, S. I.
Balaev, D. A.
Dubrovskiy, A. A.
Volkov, N. V.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
ИФ СО РАН
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk 660036, Russian Federation
Siberian Federal University, Krasnoyarsk 660041, Russian Federation

Доп.точки доступа:
Shaykhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Popkov, S. I.; Попков, Сергей Иванович; Balaev, D. A.; Балаев, Дмитрий Александрович; Semenov, S. V.; Семенов, Сергей Васильевич; Bykov, A. A.; Быков, Алексей Анатольевич; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Sapronova, N. V.; Volkov, N. V.; Волков, Никита Валентинович
}
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12.

Magnetic and EPR studies of the EuFe3(BO3)(4) single crystal / V. P. Dyakonov [et al.] // Eur. Phys. J. B. - 2010. - Vol. 78, Is. 3. - P. 291-298, DOI 10.1140/epjb/e2010-10059-3. - Cited References: 23. - A.A. Prokhorov is grateful to Mianowski Fund for financial support. . - ISSN 1434-6028

РУБ Physics, Condensed Matter
Рубрики:
EARTH
GDFE3(BO3)(4)
MULTIFERROICS
Кл.слова (ненормированные):
Absorption lines -- Antiferromagnetic orderings -- Applied magnetic fields -- Basal planes -- Easy direction of magnetizations -- Electron paramagnetic resonance -- EPR measurements -- EPR spectra -- EPR studies -- Europium ions -- Exchange fields -- G factors -- Lorentz -- Magnetic measurements -- Magnetic subsystems -- Orientation dependence -- Sub-lattices -- Temperature dependence -- Temperature range -- Trigonal symmetry -- Zeeman effect -- Antiferromagnetism -- Crystal orientation -- Europium -- Magnetic fields -- Magnetic moments -- Magnetic variables measurement -- Magnetization -- Paramagnetic resonance -- Paramagnetism -- Single crystals -- Spectroscopy -- Electron spin resonance spectroscopy
Аннотация: Magnetic and electron paramagnetic resonance (EPR) properties of EuFe3(BO3)(4) single crystals have been studied over the temperature range of 300-4.2 K and in a magnetic field up to 5 T. The temperature, field and orientation dependences of susceptibility, magnetization and EPR spectra are presented. An antiferromagnetic ordering of the Fe subsystem occurs at about 37 K. The easy direction of magnetization perpendicular to the c axis is determined by magnetic measurements. Below 10 K, we observe an increase of susceptibility connected with the polarization of the Eu sublattice by an effective exchange field of the ordered Fe magnetic subsystem. In a magnetic field perpendicular to the c axis, we have observed an increase of magnetization at T < 10 K in the applied magnetic field, which can be attributed to the appearance of the magnetic moment induced by the magnetic field applied in the basal plane. According to EPR measurements, the distance between the maximum and minimum of derivative of absorption line of the Lorentz type is equal to 319 Gs. The anisotropy of g-factor and linewidth is due to the influence of crystalline field of trigonal symmetry. The peculiarities of temperature dependence of both intensity and linewidth are caused by the influence of excited states of europium ion (Eu3+). It is supposed that the difference between the g-factors from EPR and the magnetic measurements is caused by exchange interaction between rare earth and Fe subsystems via anomalous Zeeman effect.

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Держатели документа:
[Dyakonov, V. P.
Szymczak, R.
Berkowski, M.
Szymczak, H.] Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland
[Dyakonov, V. P.
Prokhorov, A. D.
Zubov, E.
Prokhorov, A. A.
Varyukhin, V.] NANU, AA Galkin Donetsk Physicotech Inst, UA-83114 Donetsk, Ukraine
[Petrakovskii, G.
Bezmaternikh, L.] RAS, SB, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Institute of Physics, PAS, Al. Lotnikyw 32/46, Warsaw 02-668, Poland
A.A. Galkin Donetsk Physico-Technical Institute, NANU, R. Luxembourg str. 72, Donetsk 83114, Ukraine
L.V. Kirenski Institute of Physics, SB of RAS, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Dyakonov, V. P.; Szymczak, R.; Prokhorov, A. D.; Zubov, E.; Prokhorov, A. A.; Petrakovskii, G. A.; Петраковский, Герман Антонович; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Berkowski, M.; Varyukhin, V.; Szymczak, H.
}
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13.

Origin of color centers in the flux-grown europium gallium garnet / A. S. Aleksandrovsky [et al.] // J. Appl. Phys. - 2008. - Vol. 103, Is. 8. - Ст. 83102, DOI 10.1063/1.2902365. - Cited References: 7 . - ISSN 0021-8979

РУБ Physics, Applied
Рубрики:
SPECTRA
IONS
Кл.слова (ненормированные):
Absorption -- Europium alloys -- Garnets -- Ultraviolet radiation -- Calcium-free flux -- Flux-grown europium gallium garnet -- Color centers
Аннотация: Europium gallium garnet (EuGG) single crystals were grown from fluxes with various contents. Optical absorption spectra of EuGG grown from a flux containing calcium show an additional band in the ultraviolet and blue regions of the spectra as compared to the case of a calcium-free flux. Mossbauer spectra of the samples grown from the fluxes with different additives show no signs of other valence states of the europium ions except for 3+. However, they indicate changes in the crystal field due to the entrance of additive ions. The nature of the additional absorption must be the same as that for calcium-doped gadolinium gallium garnet, i.e., anion vacancies. Mossbauer isotope shifts and quadrupole splitting for EuGG are determined. (C) 2008 American Institute of Physics.

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Держатели документа:
[Aleksandrovsky, A. S.
Arkhipkin, V. G.
Bezmaternykh, L. N.
Gudim, I. A.
Krylov, A. S.] LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
[Aleksandrovsky, A. S.
Arkhipkin, V. G.
Bezmaternykh, L. N.
Gudim, I. A.
Krylov, A. S.] Siberian Fed Univ, Krasnoyarsk 660079, Russia
[Vagizov, F.] Texas A&M Univ, Dept Phys, College Stn, TX 77840 USA
ИФ СО РАН
L. V. Kirensky Institute of Physics, Siberian Federal University, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Department of Physics, Texas A and M University, College Station, TX 77840, United States

Доп.точки доступа:
Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Arkhipkin, V. G.; Архипкин, Василий Григорьевич; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Krylov, A. S.; Крылов, Александр Сергеевич; Vagizov, F.
}
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14.

Observation of mixed two-phase state in Eu0.7Pb0.3MnO3 single crystal by magnetic resonance method / N. V. Volkov [et al.] // Physica B. - 2002. - Vol. 324, Is. 1-4. - P. 254-260, DOI 10.1016/S0921-4526(02)01397-2. - Cited References: 19 . - ISSN 0921-4526

РУБ Physics, Condensed Matter
Рубрики:
OPTIMALLY DOPED MANGANITES
   COLOSSAL MAGNETORESISTANCE
   PARAMAGNETIC ANOMALIES
   CURIE-TEMPERATURE
   LA1-XCAXMNO3
   RELAXATION
   SEPARATION
Кл.слова (ненормированные):
manganites -- CMR -- magnetic resonance -- phase separation -- CMR -- Magnetic resonance -- Manganites -- Phase separation -- Europium compounds -- Ferromagnetic materials -- Paramagnetic resonance -- Phase separation -- Phase transitions -- Manganites -- Single crystals
Аннотация: The magnetic resonance measurements show that the mixed two-phase state takes place in the Eu0.7Pb0.3MnO3 single crystal. The coexistence of the magnetic phases is observed in vicinity of the magnetic phase transition, where the sample exhibits the effect of the CMR. The frequency-field dependencies of the spectra allow to conclude that these phases are paramagnetic and ferromagnetic ones. Moreover, the study of the frequency dependencies shows the sensitivity of the mixed-phase state to the external magnetic field. This suggests that the scenario of the phase separation is realized in this case and the mixed two-phase state is not related to simple chemical inhomogeneity. (C) 2002 Elsevier Science B.V. All rights reserved.

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Держатели документа:
RAS, SB, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
L.V. Kirensky Institute of Physics SB RAS, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Volkov, N. V.; Волков, Никита Валентинович; Petrakovskii, G. A.; Петраковский, Герман Антонович; Vasiliev, V. N.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Sablina, K. A.; Саблина, Клара Александровна; Patrin, K. G.; Патрин, Константин Геннадьевич
}
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15.

    New insight into the crystal structure of Sr4Ca(PO4)2SiO4 and the photoluminescence tuning of Sr4Ca(PO4)2SiO4:Ce3+,Na+,Eu2+ phosphors / M. Zhang [et al.] // J. Mater. Chem. C. - 2016. - Vol. 4, Is. 38. - P. 9078-9084, DOI 10.1039/c6tc03373c. - Cited References: 31 . - ISSN 2050-7534
   Перевод заглавия: Новый взгляд на кристаллическую структуру Sr4Ca(PO4)2SiO4 и управление люминесценцией в Sr4Ca(PO4)2SiO4:Ce3+,Na+,Eu2+
Кл.слова (ненормированные):
Calcium -- Energy transfer -- Europium -- Light emission -- Light emitting diodes -- Luminescence -- Phosphate minerals -- Phosphors -- Photoluminescence -- Positive ions -- Rietveld refinement -- Tuning -- Chemical compositions -- Energy transfer mechanisms -- Green component -- Hexagonal cells -- Luminescence properties -- Single phase -- Solid state method -- White lightemitting diodes (WLEDs) -- Crystal structure
Аннотация: A new single phase based on the substitution of a Sr cation by a Ca cation in the apatite-type Sr5(PO4)2(SiO4) has been fabricated with the nominal chemical composition of Sr4Ca(PO4)2(SiO4), which appears as a definite compound rather than a solid solution between (Sr,Ca)3(PO4)2 and (Sr,Ca)2SiO4. The crystal structure of Sr4Ca(PO4)2(SiO4) has been firstly analysed by the difference electron map, and further resolved by the Rietveld refinement, and the final composition has been determined as Sr4Ca(PO4)(2+x)(SiO4)(1-x)(OH)x (x = 0.64) with a hexagonal cell (P63/m). The Ce3+/Eu2+ codoped Sr4Ca(PO4)2SiO4 phosphors have been designed and prepared by the solid state method, and the photoluminescence tuning from blue to green upon 365 nm ultraviolet (UV) radiation can be realized, which is ascribed to the energy transfer from Ce3+ to Eu2+ ions. The luminescence properties and the energy transfer mechanism in Ce3+/Eu2+ codoped Sr4Ca(PO4)2SiO4 phosphors have been discussed, which might act as potential candidates for blue-green components in UV-pumped white light emitting diodes (WLEDs). © 2016 The Royal Society of Chemistry.

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Держатели документа:
School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation

Доп.точки доступа:
Zhang, M.; Xia, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Shi, L.; Liu, Q.
}
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16.

Shinkorenko, A. S.
Calculation of the electronic structure, lattice dynamics, and optical and magnetic properties of europium tetraborate EuB4O7 / A. S. Shinkorenko, M. S. Pavlovskii, V. I. Zinenko // Phys. Solid State. - 2016. - Vol. 58, Is. 11. - P. 2300-2306, DOI 10.1134/S1063783416110329. - Cited References: 20 . - ISSN 1063-7834
Аннотация: The electronic band structure, lattice vibration frequencies, and optical and magnetic properties of EuB4O7 crystal with α-SrB4O7-type structure are calculated within the density functional method. It is found that this compound is a dielectric with a band gap of the order of 4 eV. It is found that the ground state of this crystal is the state with ferromagnetic ordering of Eu2+ spins. Exchange interaction constants are calculated; the ferromagnetic ordering temperature is estimated within the molecular field approximation (Tc ≈ 1 K). The EuB4O7 compound is a magnetic pyroelectric and, hence, can exhibit magnetoelectric properties. The calculated polarization change during ferromagnetic ordering of this crystal is 3973 μC/m2. © 2016, Pleiades Publishing, Ltd.

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Публикация на русском языке Шинкоренко, Алексей Сергеевич. Расчет электронной структуры, динамики решетки, оптических и магнитных свойств тетрабората европия EuB4O7 [Текст] / А. С. Шинкоренко, М. С. Павловский, В. И. Зиненко // Физ. тверд. тела : Физико-технический институт им. А. Ф. Иоффе РАН, 2016. - Т. 58 Вып. 11. - С. 2218-2223

Доп.точки доступа:
Pavlovskii, M. S.; Павловский, Максим Сергеевич; Zinenko, V. I.; Зиненко, Виктор Иванович; Шинкоренко, Алексей Сергеевич
}
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17.

    Tuning of photoluminescence and local structures of substituted cations in xSr2Ca(PO4)2-(1 - x)Ca10Li(PO4)7:Eu2+ phosphors / M. Chen [et al.] // Chem. Mater. - 2017. - Vol. 29, Is. 3. - P. 1430-1438, DOI 10.1021/acs.chemmater.7b00006. - Cited References: 37. - The present work was supported by the National Natural Science Foundation of China (Grants 91622125 and 51572023), Natural Science Foundations of Beijing (2172036), and Fundamental Research Funds for the Central Universities (FRF-TP-15-003A2). . - ISSN 0897-4756
   Перевод заглавия: Управляемая люминесценция и локальная структура замещаемых катионов в люминофоре xSr2Ca(PO4)2-(1-x)Ca10Li(PO4)7:Eu2+
Кл.слова (ненормированные):
Calcium -- Energy transfer -- Europium -- Light emission -- Lithium -- Luminescence -- Phosphors -- Photoionization -- Photoluminescence -- Single crystals -- Composition ranges -- Crystal-field splitting -- Luminescence measurements -- Non-linear variation -- Photoionization process -- Polyhedra distortion -- Rare earth doped solids -- Temperature dependent -- Solid solutions
Аннотация: Local structure modification in solid solution is an essential part of photoluminescence tuning of rare earth doped solid state phosphors. Herein we report a new solid solution phosphor of Eu2+-doped xSr2Ca(PO4)2-(1 - x)Ca10Li(PO4)7 (0 ≤ x ≤ 1), which share the same β-Ca3(PO4)2 type structure in the full composition range. Depending on the x parameter variation in xSr2Ca(PO4)2-(1 - x)Ca10Li(PO4)7:Eu2+, the vacancies generated in the M(4) site enable the nonlinear variation of cell parameters and volume, and this increases the magnitude of M(4)O6 polyhedra distortion. The local structure modulation around the Eu2+ ions causes different luminescent behaviors of the two-peak emission and induces the photoluminescence tuning. The shift of the emission peaks in the solid solution phosphors with different compositions has been discussed. It remains invariable at x ≤ 0.5, but the red-shift is observed at x > 0.5 which is attributed to combined effect of the crystal field splitting, Stokes shift, and energy transfer between Eu2+ ions. The temperature-dependent luminescence measurements are also performed, and it is shown that the photoionization process is responsible for the quenching effect.

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Держатели документа:
Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
State Key Laboratory of Tribology, Tsinghua University, Beijing, China

Доп.точки доступа:
Chen, M.; Xia, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Wang, T.; Liu, Q.
}
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18.

    Temperature and Eu2+-doping induced phase selection in NaAlSiO4 polymorphs and the controlled yellow/blue emission / M. Zhao [et al.] // Chem. Mater. - 2017. - Vol. 29, Is. 15. - P. 6552-6559, DOI 10.1021/acs.chemmater.7b02548. - Cited References: 48. - The present work was supported by the National Natural Science Foundation of China (Grants 91622125 and 51572023 and 11574003), Natural Science Foundations of Beijing (2172036), and Fundamental Research Funds for the Central Universities (FRF-TP-16-002A3). L.N. acknowledges the support from the Special and Excellent Research Fund of Anhui Normal University. . - ISSN 0897-4756
   Перевод заглавия: Фазовый переход индуцированный температурой и допированием Eu2+ в NaAlSiO4, и контролируемое излучение желтого/голубого света
Кл.слова (ненормированные):
Chemical modification -- Coordination reactions -- Europium -- Light emitting diodes -- Photoluminescence -- Functional properties -- High color rendering index -- Local coordination structures -- Near ultraviolet excitations -- Structural transformation -- Synthesis temperatures -- Temperature dependent -- White light emitting diodes -- Density functional theory
Аннотация: The union of temperature-dependent phase transition and relating structural transformation via modification of chemical compositions is of fundamental importance for the discovery of new materials or their functional properties optimization. Herein, the synthesis temperature and Eu2+-doping content induced phase selection and variations of the local structures in nepheline, low-carnegieite and high-carnegieite types of NaAlSiO4 polymorphs were studied in detail. The luminescence of Eu2+ in low-carnegieite and nepheline phases shows blue (460 nm) and yellow (540 nm) broad-band emissions, respectively, under near-ultraviolet excitation. The photoluminescence evolution can be triggered by the different synthesis temperatures in relation to the Eu2+-doping concentration, as corroborated by density functional theory calculations on the local coordination structures and corresponding mechanical stabilities in terms of the Debye temperature. The fabricated white light-emitting diode device with high color rendering index demonstrates that the multicolor phosphors from one system provides a new gateway for the photoluminescence tuning. © 2017 American Chemical Society.

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Держатели документа:
Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Anhui Key Laboratory of Optoelectronic Materials Science and Technology, Department of Physics, Anhui Normal University, Wuhu, Anhui, China

Доп.точки доступа:
Zhao, M.; Xia, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Ning, L.; Liu, Q.
}
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19.

    Probing Eu2+ luminescence from different crystallographic sites in Ca10M(PO4)7:Eu2+ (M = Li, Na, and K) with β-Ca3(PO4)2-type structure / M. Chen [et al.] // Chem. Mater. - 2017. - Vol. 29, Is. 17. - P. 7563-7570, DOI 10.1021/acs.chemmater.7b02724. - Cited References: 34. - The present work was supported by the National Natural Science Foundation of China (Grants 51722202, 91622125, and 51572023), Natural Science Foundations of Beijing (2172036), and Fundamental Research Funds for the Central Universities (FRF-TP-16-002A3). C.C.L. and C.C.S. acknowledge the financial support from the Ministry of Science and Technology of Taiwan (Contract No. MOST 104-2113-M-027-007-MY3), and M. Molokeev acknowledges support of the Russian Foundation for Basic Research (17-52-53031). . - ISSN 0897-4756
   Перевод заглавия: Исследование люминесценции Eu2+ в разных кристаллографических положениях в Ca10M(PO4)7:Eu2+ (M = Li, Na and K) со структурой типа beta-Ca3(PO4)2
Кл.слова (ненормированные):
Calcium -- Doping (additives) -- Excited states -- Light emission -- Lithium -- Luminescence -- Phosphors -- Photoluminescence -- Positive ions -- Rietveld refinement -- Single crystals -- Color tuning -- Crystallographic sites -- Different distributions -- Emission bands -- Local environments -- Long wavelength bands -- Luminescent centers -- Power diffraction data -- Europium
Аннотация: Eu2+ local environments in various crystallographic sites enable the different distributions of the emission and excitation energies and then realize the photoluminescence tuning of the Eu2+ doped solid state phosphors. Herein we report the Eu2+-doped Ca10M(PO4)7 (M = Li, Na, and K) phosphors with β-Ca3(PO4)2-type structure, in which there are five cation crystallographic sites, and the phosphors show a color tuning from bluish-violet to blue and yellow with the variation of M ions. The difference in decay rate monitored at selected wavelengths is related to multiple luminescent centers in Ca10M(PO4)7:Eu2+, and the occupied rates of Eu2+ in Ca(1), Ca(2), Ca(3), Na(4), and Ca(5) sites from Rietveld refinements using synchrotron power diffraction data confirm that Eu2+ enters into four cation sites except for Ca(5). Since the average bond lengths d(Ca-O) remain invariable in the Ca10M(PO4)7:Eu2+, the drastic changes of bond lengths d(M-O) and Eu2+ emission depending on the variation from Li to Na and K can provide insight into the distribution of Eu2+ ions. It is found that the emission band at 410 nm is ascribed to the occupation of Eu2+ in the Ca(1), Ca(2), and Ca(3) sites with similar local environments, while the long-wavelength band (466 or 511 nm) is attributed to Eu2+ at the M(4) site (M = Na and K). We show that the crystal-site engineering approach discussed herein can be applied to probe the luminescence of the dopants and provide a new method for photoluminescence tuning.

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Держатели документа:
Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center, KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Institute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei, Taiwan
National Synchrotron Radiation Research Center, Hsinchu, Taiwan

Доп.точки доступа:
Chen, M.; Xia, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Lin, C. C.; Su, C.; Chuang, Y. -C.; Liu, Q.
}
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20.

    Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups / Y. G. Denisenko [et al.] // J. Ind. Eng. Chem. - 2018. - Vol. 68. - P. 109-116, DOI 10.1016/j.jiec.2018.07.034. - Cited References: 83. - This work was supported by the Russian Foundation for Basic Research ( 16-52-48010 , 17-52-53031 ). The equipments of the Collective Use Center — Kirensky Institute of Physics, Federal Research Center KSC Siberian Branch Russian Academy of Sciences [ http://ccu.kirensky.ru/ ] was used. . - ISSN 1226-086X
   Перевод заглавия: Исследование структурных, тепловых и спектроскопических свойств самоактивируемого сульфата с изолированными SO4
Кл.слова (ненормированные):
Europium sulfate -- Synthesis -- Structure -- Thermal analysis -- Photoluminescence
Аннотация: Eu2(SO4)3 was synthesized by chemical precipitation method and the crystal structure was determined by Rietveld analysis. The compound crystallizes in monoclinic space group С2/с. In the air environment, Eu2(SO4)3 is stable up to 670 °C. The sample of Eu2(SO4)3 was examined by Raman, Fourier-transform infrared absorption and luminescence spectroscopy methods. The low site symmetry of SO4 tetrahedra results in the appearance of the IR inactive ν1 mode around 1000 cm−1 and ν2 modes below 500 cm−1. The band intensities redistribution in the luminescent spectra of Eu3+ ions is analyzed in terms of the peculiarities of its local environment.

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Держатели документа:
Institute of Chemistry, Tyumen State University, Tyumen, 625003, Russian Federation
Department of General and Special Chemistry, Industrial University of Tyumen, Tyumen, 625000, Russian Federation
Laboratory of Coherent Optics, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, 630090, Russian Federation
Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk, 630090, Russian Federation
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation

Доп.точки доступа:
Denisenko, Y. G.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Atuchin, V. V.; Krylov, A. S.; Крылов, Александр Сергеевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Shestakov, N. P.; Шестаков, Николай Петрович; Andreev, O. V.
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