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1.
Antiferromagnetic resonance and
magnetic anisotropy in PrxY1−xFe3(BO3)4 crystals in the region of the magnetic structure transformation “easy axis – easy plane” / A. I. Pankrats, S. M. Zharkov, G. M. Zeer, I. A. Gudim> // J. Alloys Compd. - 2022. -
Vol. 909
. - Ст. 164821,
DOI
10.1016/j.jallcom.2022.164821. - Cited References: 37. - The authors acknowledge the assistance of R. Mironov in some resonance measurements. The SEM and EDS investigations were conducted in the SFU Joint Scientific Center supported by the State assignment (#FSRZ-2020–0011) of the Ministry of Science and Higher Education of the Russian Federation . - ISSN 0925-8388
Кл.слова (ненормированные):
Magnetically ordered materials
--
Rare earth alloys and compounds
--
Spin dynamics
--
Anisotropy
--
Magnetic measurements
--
Scanning electron microscopy, SEM
Аннотация:
The spin dynamics, magnetic structures and magnetic anisotropy of single crystals PrxY1−xFe3(BO3)4 have been studied using antiferromagnetic resonance (AFMR) in a wide range of frequencies, magnetic fields, and temperatures. The frequency-field dependences of AFMR for the crystals with x = 0.25 and 0.45 are characteristic of antiferromagnets with the easy plane (EP) anisotropy. The crystals with x = 0.75 and 1.0 exhibit frequency-field dependences that are typical for antiferromagnets with the easy axis (EA) anisotropy. In these crystals, a significant decrease in the effective anisotropy fields of praseodymium upon the transition to the spin-flop state has been found. It is shown that this is the main reason for the large lability intervals, within which the regions of coexistence of the collinear and spin-flop states overlap. In the crystal with x = 0.67, the magnetic field applied along the trigonal axis of the crystal leads to the spin reorientation transition from the EA to the EP state. A magnetic phase diagram of the states on the plane "magnetic field - temperature" is built. In this crystal, the effective anisotropy field of praseodymium also decreases upon the transition to the field-induced EP state. Diamagnetic dilution of the praseodymium subsystem leads to the contribution of this subsystem to the total anisotropy field depending almost linearly on the praseodymium concentration.
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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Akademgorodok 50/38, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, 79 Svobodny st., Krasnoyarsk, 660041, Russian Federation
Доп.точки доступа:
Pankrats, A. I.; Панкрац, Анатолий Иванович; Zharkov, S. M.; Жарков, Сергей Михайлович; Zeer, G. M.; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
}
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2.
Antiferromagnetic resonance in
crystalline PrFe3(BO3)4 / A. N. Bludov [et al.]> // Low Temp. Phys. - 2018. -
Vol. 44
,
Is. 2
. - P. 139-143,
DOI
10.1063/1.5020909. - Cited References: 18 . - ISSN 1063-777X. - ISSN 1090-6517
РУБ
Physics, Applied
Аннотация:
Experimental AFMR studies of crystalline PrFe3(BO3)4 over a wide frequency range of 10–143 GHz at a temperature of 4.2 K have been carried out. The high-frequency properties of praseodymium ferroborate are well described in terms of a model of a two-sublattice antiferromagnet with an “easy axis” anisotropy. An energy gap of 134.3 ± 0.5 GHz is determined and the magnitude of the effective magnetic anisotropy field is estimated to be 1.9 ± 0.1 kOe. An analysis indicates that the spin-orientational phase transition in this compound is a first order transition.
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Публикация на русском языке
Антиферромагнитный резонанс в кристалле PrFe3(BO3)4 [Текст] / А. Н. Блудов [и др.] // Физ. низк. температур. - 2018. - Т. 44 Вып. 2. - С. 185-190
Держатели документа:
Natl Acad Sci Ukraine, BI Verkin Inst Low Temp Phys & Technol, Pr Nauki 47, UA-61103 Kharkov, Ukraine.
Russian Acad Sci, Siberian Branch, LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia.
Доп.точки доступа:
Bludov, A. N.; Pashchenko, V. A.; Kobets, M. I.; Bedarev, V. A.; Merenkov, D. N.; Gnatchenko, S. L.; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
}
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3.
Antiferromagnetic resonance study
of the magnetic structure of Nd0.75Dy0.25Fe3(BO3)(4) / M. I. Kobets [et al.]> // Low Temp. Phys. - 2014. -
Vol. 40
,
Is. 7
. - P. 629-634,
DOI
10.1063/1.4890992. - Cited References: 17 . - ISSN 1063-777X. - ISSN 1090-6517
РУБ
Physics, Applied
Аннотация:
The effect of replacing Nd3+ ions with Dy3+ ions on the resonance properties of Nd0.75Dy0.25Fe3(BO3)(4) is studied. The antiferromagnetic resonance (AFMR) method is used to detect an easy axis-easy plane magnetic spin-reorientation phase transition owing to competing exchange interactions of Nd-Fe and Dy-Fe, and the frequency-field dependence of the AFMR spectrum before and after the phase transition is studied. At 4.2 K, the detected resonance spectra in the H parallel to c direction are AFMR modes of iron, and their frequency-field dependences correspond to easy-axis (H 15 kOe) and easy-plane (H 16 kOe) magnetic structures with magnon excitation energy gaps of 77.2 and 100.3 GHz, respectively. The effective magnetic anisotropies responsible for these gaps are 0.7 and 1.2 kOe, respectively. Substitution by Dy3+ ions in crystalline Nd0.75Dy0.25Fe3(BO3)(4) in the paramagnetic region produces an additional static internal field owing to polarization, which leads to a shift in the resonance field of the EPR absorption line and a change in the g-factor of the Fe3+ ions. (C) 2014 AIP Publishing LLC.
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Держатели документа:
Natl Acad Sci Ukraine, BI Verkin Inst Low Temp Phys & Engn, UA-61103 Kharkov, Ukraine
Russian Acad Sci, LV Kirenskii Inst Phys, Urals Branch, Krasnoyarsk 660036, Russia
Доп.точки доступа:
Kobets, M. I.; Dergachev, K. G.; Khatsko, E. N.; Gnatchenko, S. L.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
}
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4.
Chukalina, E. P.
Study of the magnetic properties of neodymium and samarium iron borates by the method of erbium spectroscopic probe / E. P. Chukalina, A. Jablunovskis, I. A. Gudim> // Opt. Spectrosc. - 2023. -
Vol. 131
,
Is. 8
. - P. 630-636,
DOI
10.1134/S0030400X23060024. - Cited References: 30. - This paper was carried out under financial support of the Russian Science Foundation (grant № 19-12-00413) . - ISSN 0030-400X. - ISSN 1562-6911
Кл.слова (ненормированные):
multiferroics
--
optical spectroscopy
--
crystals with rare earths
--
Kramers ions
Аннотация:
Iron borates NdFe3(BO3)4 and SmFe3 (BO3)4 activated with 1% erbium, with ahuntite structure (space symmetry group R32) were investigated by the method of erbium spectroscopic probe. From an analysis of the temperature dependence of the transmission spectra in the region of the 4I15/2 → 4113/2 transition in the Er3+ ion, it was found that both studied compounds order antiferromagnetically at TN ≈ 33 K into an easy-plane magnetic structure. No other phase transitions were found.
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Публикация на русском языке
Чукалина Е. П. Исследование магнитных свойств ферроборатов неодима и самария методом спектроскопического эрбиевого зонда [Текст] / Е. П. Чукалина, А. Яблуновский, И. А.
Гудим
// Опт. и спектроскоп. - 2022. - Т. 130 Вып. 1. - С. 104-110
Держатели документа:
Institute of Spectroscopy, Russian Academy of Sciences, 108840, Troitsk, Moscow, Russia
Moscow Institute of Physics and Technology (National Research University), 141701, Dolgoprudny, Moscow oblast, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia
Доп.точки доступа:
Jablunovskis, A.; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
}
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5.
Chukalina, E. P.
Study of the magnetic properties of neodymium and samarium iron borates by the method of erbium spectroscopic probe / E. P. Chukalina, A. Jablunovskis, I. A. Gudim> // Opt. Spectrosc. - 2022. -
Vol. 130
,
Is. 1
. - P. 98-104,
DOI
10.21883/EOS.2022.01.52993.23-21. - Cited References: 30. - This paper was carried out under financial support of the Russian Science Foundation (grant № 19-12-00413) . - ISSN 0030-400X. - ISSN 1562-6911
Кл.слова (ненормированные):
multiferroics
--
optical spectroscopy
--
crystals with rare earths
--
Kramers ions
Аннотация:
Iron borates NdFe3(BO3)4 and SmFe3(BO3)4 activated with 1% erbium, with a huntite structure (space symmetry group R32) were investigated by the method of erbium spectroscopic probe. From an analysis of the temperature dependence of the transmission spectra in the region of the 4I15/2 → 4I13/2 transition in the Er3+ ion, it was found that both studied compounds order antiferromagnetically at TN ≈ 33 K into an easy-plane magnetic structure. No other phase transitions were found.
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Публикация на русском языке
Чукалина Е. П. Исследование магнитных свойств ферроборатов неодима и самария методом спектроскопического эрбиевого зонда [Текст] / Е. П. Чукалина, А. Яблуновский, И. А.
Гудим
// Опт. и спектроскоп. - 2022. - Т. 130 Вып. 1. - С. 104-110
Держатели документа:
Institute of Spectroscopy, Russian Academy of Sciences, Troitsk, Moscow, Russia
Moscow Institute of Physics and Technology (National Research University), Dolgoprudny, Moscow Region, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
Доп.точки доступа:
Jablunovskis, A.; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
}
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6.
Colossal magnetodielectric effect
in SmFe3(BO3)(4) multiferroic / A. A. Mukhin [et al.]> // JETP Letters. - 2011. -
Vol. 93
,
Is. 5
. - P. 275-281,
DOI
10.1134/S0021364011050079. - Cited References: 17. - We are grateful to A.K. Zvezdin and A.P. Pyatakov for the discussion of this work and valuable comments. This work was supported by the Russian Foundation for Basic Research, project nos. 10-02-00846 and 09-02-01355. . - ISSN 0021-3640
РУБ
Physics, Multidisciplinary
Рубрики:
FERROELECTRICITY
MAGNETOSTRICTION
GARNETS
Аннотация:
The colossal (more than threefold) decrease in the dielectric constant E in the easy-plane SmFe3(BO3)(4) ferroborate in a magnetic field of similar to 5 kOe applied in the basal ab plane of the crystal has been found. A close relation of this effect to anomalies in the field dependence of the electric polarization has been established. It has been shown that this magnetodielectric effect is due to the contribution to E from the electric susceptibility, which is related to the rotation of spins in the ab plane, arises in the region of the antiferromagnetic ordering T T (N) and electric polarization in the magnetic field has been proposed, taking into account the additional anisotropy in the basal plane induced by the magnetoelastic stresses.
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Держатели документа:
[Mukhin, A. A.
Ivanov, V. Yu.
Kuz'menko, A. M.] Russian Acad Sci, Prokhorov Gen Phys Inst, Moscow 119991, Russia
[Vorob'ev, G. P.
Kadomtseva, A. M.
Narizhnaya, A. S.
Popov, Yu. F.] Moscow MV Lomonosov State Univ, Moscow 119992, Russia
[Bezmaternykh, L. N.
Gudim, I. A.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 880036, Russia
ИФ СО РАН
Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow 119991, Russian Federation
Moscow State University, Moscow 119992, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk 880036, Russian Federation
Доп.точки доступа:
Mukhin, A. A.; Vorob'ev, G. P.; Ivanov, V. Y.; Kadomtseva, A. M.; Narizhnaya, A. S.; Kuz'menko, A. M.; Popov, Y. F.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
}
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7.
Comparative study of
magnetoelectric effect in HoAl3(BO3)4 and HoGa3(BO3)4 single crystals / A. L. Freydman [et al.]> //
Moscow International Symposium on Magnetism (MISM-2017) : 1-7 July 2017 : book of abstracts. - 2017. - Ст. 5PO-I2-5. - P. 1050
РИНЦ
,
Материалы конференции
,
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Доп.точки доступа:
Freydman, A. L.; Фрейдман, Александр Леонидович; Balaev, A. D.; Балаев, Александр Дмитриевич; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
; Moscow International Symposium on Magnetism(7 ; 2017 ; Jul. ; Moscow); Московский государственный университет им. М.В. Ломоносова; Российский фонд фундаментальных исследований
Нет сведений об экземплярах (Источник в БД не найден)
}
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8.
Comparative study of
the magnetoelectric effect in HoAl3(BO3)4 and HoGa3(BO3)4 single crystals / A. L. Freidman [et al.]> // Phys. Solid State. - 2018. -
Vol. 60
,
Is. 3
. - P. 510-514,
DOI
10.1134/S1063783418030113. - Cited References:13. - This study was supported by the Russian Foundation for Basic Research, projects nos. 16-38-00245 and 16-32-00163 and the Russian Foundation for Basic Research, Government of the Krasnoyarsk Territory, and Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project no. 16-48-243040. . - ISSN 1063-7834. - ISSN 1090-6460
РУБ
Physics, Condensed Matter
Рубрики:
MAGNETIZATION
Аннотация:
The comparative study of the magnetoelectric properties and magnetostriction of HoGa3(BO3)4 and HoAl3(BO3)4 single crystals has been carried out. The investigated compounds exhibit qualitatively similar magnetodielectric and inverse magnetoelectric ME E effects with the close absolute values, which is indicative of the weak effect of a nonmagnetic metal ion. On the contrary, the magnetostriction of the galloborate has been found to be threefold higher than that of the alumoborate. In addition, the difference between the qualitative behaviors of magnetostriction has been established: the magnetic-field dependence of magnetostriction for the alumoborate has the maximum near 70 kOe at T = 4.2 K, while the galloborate magnetostriction has no maximum and does not saturate in a field of 140 kOe.
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Публикация на русском языке
Сравнительное исследование магнитоэлектрического эффекта в монокристаллах HoAl3(BO3)4 и HoGa3(BO3)4 [Текст] / А. Л. Фрейдман [и др.] // Физ. тверд. тела. - 2018. - Т. 60 Вып. 3. - С. 505–509
Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Fed Res Ctr KSC, Krasnoyarsk 660036, Russia.
Доп.точки доступа:
Freydman, A. L.; Фрейдман, Александр Леонидович; Dubrovskii, A. A.; Дубровский, Андрей Александрович; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
; Russian Foundation for Basic Research [16-38-00245, 16-32-00163]; Russian Foundation for Basic Research, Government of the Krasnoyarsk Territory; Krasnoyarsk Territorial Foundation [16-48-243040]
}
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9.
Comparing the magnetic
and magnetoelectric properties of the SmFe3(BO3)4 ferroborate single crystals grown using different solvents / E. Eremin [et al.]> // J. Cryst. Growth. - 2019. -
Vol. 518
. - P. 1-4,
DOI
10.1016/j.jcrysgro.2019.04.017. - Cited References: 17. - This study was supported by the Russian Foundation for Basic Research (RFBR) according to the research projects No. 18-02-00696_a and RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund by project No. 18-42-240011 p_a. . - ISSN 0022-0248. - ISSN 1873-5002
РУБ
Crystallography + Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
POLARIZATION
FEATURES
Кл.слова (ненормированные):
Impurities
--
Growth from solutions
--
Single crystal growth
--
Borates
--
Ferroelectric materials
--
Magnetic materials
Аннотация:
SmFe3(BO3)4 single crystals have been grown from the bismuth trimolybdate and lithium tungstate-based melt–solutions. Samarium ferroborate single crystals were grown first from the lithium–tungstate flux. The magnetic and magnetoelectric properties of the synthesized crystals have been compared. It is shown that the SmFe3(BO3)4 ferroborate grown from the bismuth trimolybdate-based melt–solution contains impurities of Bi3+ ions (∼5% at.), which replace Sm3+ ions, while the SmFe3(BO3)4, ferroborate grown from the lithium tungstate-based melt–solution contains minor or zero amounts of such impurities. The magnetoelectric and magnetodielectric effects with the Bi3+ admixture appeared 1.5× stronger than in SmFe3(BO3)4; this is probably due to twinning.
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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Siberian State Univ Sci & Technol, Krasnoyarsk 660037, Russia.
Доп.точки доступа:
Eremin, E. V.; Еремин, Евгений Владимирович; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
; Temerov, V. L.; Темеров, Владислав Леонидович; Smolyakov, D. A.; Смоляков, Дмитрий Александрович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Russian Foundation for Basic Research (RFBR) [18-02-00696_a]; RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund [18-42-240011 p_a]
}
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10.
Comparision of magnetic
properties of TmAl3(BO3)4 and TmAl2,75Sc0,25(BO3)4 crystals / I. A. Gudim [et al.]> // Магнитные материалы. Новые технологии : тез. докл. VII Байкал. Междунар. конф. / Иркутский гос. ун-т. - Иркутск, 2016. - P. 97. - Библиогр.: 1 назв. - This study was supported by the Russian Foundation for Basic Research, project no. 13-02-12442, no. 14-02-00307 and no. 15-42-04186 . - ISBN 978-591-345-152-1. - ISBN 978-591-345-152-1
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Доп.точки доступа:
Исхаков, Рауф Садыкович \чл. прогр. ком.\; Iskhakov, R. S.; Аплеснин, Сергей Степанович \чл. прогр. ком.\; Aplesnin, S. S.; Овчинников, Сергей Геннадьевич \чл. прогр. ком.\; Ovchinnikov, S. G.; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
; Eremin, E. V.; Еремин, Евгений Владимирович; Temerov, V. L.; Темеров, Владислав Леонидович; Volkov, N. V.; Волков, Никита Валентинович; "Магнитные материалы. Новые технологии", Байкальская международная конференция(7 ; 2016 ; авг. ; 22-26 ; Листвянка, пос. (Иркутская обл.)); "Magnetic materials. New tecnologies", Baikal International Conference(7 ; 2016 ; Aug. ; 22-26 ; Listvyanka, Irkutsk region); Байкальская международная конференция "Магнитные материалы. Новые технологии"(7 ; 2016 ; авг. ; 22-26 ; п. Листвянка, Иркутская обл.); Иркутский государственный университет
}
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11.
Comparison of magnetic
properties of GdFe3(BO3)4, ferroborates grown using various solvents / I. A. Gudim, E. V. Eremin, N. V. Mikhashenok, V. R. Titova> // Phys. Solid State. - 2023. -
Vol. 65
,
Is. 2
. - P. 235-239,
DOI
10.21883/PSS.2023.02.55406.505. - Cited References: 18. - This study was supported by grant No. 22-12-20019 provided by the Russian Science Foundation and the Krasnoyarsk Regional Science Foundation (https://rscf.ru/project/22-72-00017/) . - ISSN 1063-7834. - ISSN 1090-6460
Кл.слова (ненормированные):
crystal growth
--
antiferromagnets
--
multferroics
Аннотация:
GdFe3(BO3)4, single crystals were grown from melt-solutions based on bismuth trimolybdate and lithium tungstate. Single crystals of gadolinium ferroborate from lithium-tungstate solution-melt were grown for the first time. The magnetic properties of the grown crystals are compared. It is shown that the GdFe3(BO3)4, ferroborate obtained using bismuth solution-melt trimolybdate contains impurities of Bi3+ ions (6% at.), which replace Gd3+ ions. Whereas GdFe3(BO3)4, ferroborate grown from a solution-melt based on lithium tungstate does not seem to contain such uncontrolled impurities.
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Публикация на русском языке
Сравнение магнитных свойств ферроборатов GdFe3(BO3)4, выращенных с использованием различных растворителей [Текст] / И. А.
Гудим
, Е. В. Еремин, Н. В. Михашенок, В. Р. Титова // Физ. тверд. тела. - 2023. - Т. 65 Вып. 2. - С. 243-247
Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
Доп.точки доступа:
Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
; Eremin, E. V.; Еремин, Евгений Владимирович; Mikhashenok, N. V.; Михашенок, Наталья Владимировна; Titova, V. R.; Титова, Вероника Романовна
}
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12.
Comparison of the
absorption spectra of Nd3+ ions in the NdFe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4, and Ho0.75Nd0.25Fe3(BO3)4 crystals / A. L. Sukhachev, A. V. Malakhovskii, C. S. Nelson [et al.]> // Phys. Solid State. - 2021. -
Vol. 63
,
Is. 1
. - P. 113-121,
DOI
10.1134/S1063783421010200. - Cited References: 21. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, to the research project: number 19-42-240003 “Influence of the local en-vironment on magneto-optical properties of f–f transitions in rare-earth aluminum and iron borates” . - ISSN 1063-7834
Кл.слова (ненормированные):
neodymium
--
hantite-structure ferroborates
--
f–f electronic transitions
--
structural transition
Аннотация:
The polarized optical absorption spectra in the region of a series of the f–f transitions of Nd3+ ions in the Ho0.75Nd0.25Fe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4, and NdFe3(BO3)4 crystals at 90 K have been compared. The spectral features related to the difference in the local environment of Nd3+ ions in these crystals have been established. In the region of the transition 4I9/2 → 4G5/2 + 2G7/2 of Nd3+ ions in the Ho0.75Nd0.25Fe3(BO3)4 crystal, the appearance of some absorption lines at the structural transition R32 → P3121 around ~200 K due to the local symmetry variation has been found. The intensity of these lines smoothly increases with a decrease in temperature from the transition point. The temperature dependence of the lattice parameters of the Ho0.75Nd0.25Fe3(BO3)4 crystal has been measured. It has been found that, at the transition temperature, the lattice parameter a changes stepwise, which is indicative of the occurrence of a first-order phase transition. The lattice parameter c changes smoothly.
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Публикация на русском языке
Сравнение спектров поглощения ионов Nd3+ в кристаллах NdFe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4 и Ho0.75Nd0.25Fe3(BO3)4 [Текст] / А. Л. Сухачев, А. В. Малаховский, C. S. Nelson [и др.] // Физ. тверд. тела. - 2021. - Т. 63 Вып. 1. - С. 111-119
Держатели документа:
Kirensky Institute of Physics, FRC KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
National Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY 11973, United States
Доп.точки доступа:
Sukhachev, A. L.; Сухачев, Александр Леонидович; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Nelson, C. S.; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
; Temerov, V. L.; Темеров, Владислав Леонидович
}
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13.
Comparison of the
magnetic properties of NdSc3(BO3)4 and NdSc1.5Ga1.5(BO3)4 crystals / I. A. Gudim> //
Second Int. Workshop "Novel Trends in Physics of Ferroics" : abstracts. - 2017. - P.
Материалы семинара
,
Материалы семинара
Доп.точки доступа:
Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
; Novel Trends in Physics of Ferroics, International Workshop (2 ; 2017, July 6-8 ; St. Petersburg, Russia); "Новые направления в развитии физики ферроиков", международный семинар(2 ; 2017, Июль, 6-8 ; Санкт-Петербург)Физико-технический институт им. А.Ф. Иоффе РАН
}
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14.
Complex magnetic order
in the Nd(Tb)Fe3(BO3)4 multiferroic revealed by single-crystal neutron diffraction / I. V. Golosovsky [et al.]> // Phys. Rev. B. - 2019. -
Vol. 99
,
Is. 13
. - Ст. 134439,
DOI
10.1103/PhysRevB.99.134439. - Cited References: 33. - This work was supported by the Russian Grant No. RFBR 16-02-00058. A.A.M. acknowledges the financial support from the Russian Science Foundation (16-12-10531). . - ISSN 2469-9950
Кл.слова (ненормированные):
Antiferromagnetism
--
Binary alloys
--
Crystal structure
--
Crystallography
--
Magnetic structure
--
Neodymium compounds
--
Neutron diffraction
--
Single crystals
--
Terbium compounds
Аннотация:
Magnetic structure of the substituted multiferroics-ferroborates Nd0.9Tb0.1Fe3(BO3)4 and Nd0.8Tb0.2Fe3(BO3)4 were determined in the framework of a self-consistent refinement of the single crystal neutron diffraction data. The small substitution of Nd for Tb leads to the reorientation of the main antiferromagnetic vector L from the basal plane towards the hexagonal axis. The reorientation takes place via an angular structure for which L does not coincide with the principal crystallographic directions and evolves with temperature due to competing magnetic anisotropies of Fe, Nd, and Tb subsystems. Our refinement at 2 K reveals the existence of distortions in the collinear antiferromagnetic Fe spin arrangement suggested before in other ferroborates. Therefore, besides the main antiferromagnetic vector L, the magnetic structure involves additional fine symmetrized combinations of spin components allowed by symmetry. They coexist with certain L components and could originate from the antisymmetric Dzyaloshinsky-Moriya Fe-Fe exchange interactions. At higher temperatures, the magnetic structure is described by the simple collinear model, where the L vector is deviated from the hexagonal plane. © 2019 American Physical Society.
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Держатели документа:
National Research Center, Kurchatov Institute, B.P. Konstantinov Petersburg Nuclear Physics Institute, Gatchina, 188300, Russian Federation
Prokhorov General Physics Institute, RAS, Moscow, 119991, Russian Federation
Universite Grenoble Alpes, CEA, INAC-MEM, Grenoble, 38000, France
Institucio Catalana de Recerca i Estudis Avancats, Barcelona, E-08010, Spain
Fisika Aplikatua II, Zientzia Eta Teknologia Fakultatea, Universidad Del Pais Vasco, UPV/EHU, Bilbao, 48940, Spain
Kirenskii Institute of Physics, Siberian Division of RAS, Krasnoyarsk, 660038, Russian Federation
Доп.точки доступа:
Golosovsky, I. V.; Vasilev, A. I.; Mukhin, A. A.; Ressouche, E.; Skumryev, V.; Urcelay-Olabarria, I.; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
}
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15.
Crystal field and
exchange interactions in the SmFe3(BO3)4 multiferroic / M. N. Popova [et al.]> // J. Exp. Theor. Phys. - 2014. -
Vol. 118
,
Is. 1
. - P. 111-123,
DOI
10.1134/S1063776114010142. - Cited References: 22. - This work was supported by the Russian Foundation for Basic Research (project no. 13-02-00787) and the basic research program Quantum Mesoscopic and Disordered Structures of the Presidium of the Russian Academy of Sciences. . - ISSN 1063-7761. - ISSN 1090-6509
РУБ
Physics, Multidisciplinary
Аннотация:
The optical spectra of oriented SmFe3(BO3)4 single crystals are studied in the region of the f-f transitions in the Sm3+ ion by Fourier spectroscopy. The energies, the symmetry properties, and the exchange splittings of the Stark sublevels of the ground and 17 excited multiplets of the Sm3+ ion in a crystal field of symmetry D 3 are determined from the measured temperature dependences of polarized-radiation absorption spectra. The parameters of the crystal field acting on samarium ions and the parameters of the exchange interaction between Sm3+ and Fe3+ ions are found. The anisotropy of the effective exchange interaction is shown to be substantially stronger than the magnetic anisotropy, due to a strong crystal-field-induced mixing of the ground and excited multiplets.
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Исследование кристаллического поля и обменных взаимодействий в мультиферроике SmFe3( BO3)4 [Текст] / М. Н. Попова [и др.] // Журн. эксперим. и теор. физ. : Наука, 2014. - Т. 145 Вып. 1. - С. 128-142
Держатели документа:
Russian Acad Sci, Inst Spect, Moscow 142190, Russia
Kazan Privolzhsky Fed Univ, Kazan 420008, Russia
State Univ, Moscow Inst Phys & Technol, Dolgoprudnyi 141700, Moscow Oblast, Russia
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Доп.точки доступа:
Popova, M. N.; Chukalina, E. P.; Malkin, B. Z.; Erofeev, D. A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
; Russian Foundation for Basic Research [13-02-00787]; basic research program Quantum Mesoscopic and Disordered Structures of the Presidium of the Russian Academy of Sciences
}
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16.
Crystal growth and
magnetic properties of Nd1-xDyxFe3(BO3)4" / I. A. Gudim, E. V. Eremin, V. L. Temerov> // ArXiv. - 2009. - Ст. arxiv:0906.2250
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,
https://arxiv.org/abs/0906.2250
Доп.точки доступа:
Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
; Eremin, E. V.; Еремин, Евгений Владимирович; Temerov, V. L.; Темеров, Владислав Леонидович
}
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17.
Crystal growth and
Raman spectroscopy study of Sm1-xLaxFe3(BO3)4 ferroborates / E. Moshkina [et al.]> // Cryst. Growth Des. - 2016. -
Vol. 16
,
Is. 12
. - P. 6915-6921,
DOI
10.1021/acs.cgd.6b01079. - Cited References: 17. - This work was supported by the Russian Foundation for Basic Research, Project No. 14-02-00307. . - ISSN 1528-7483
Перевод заглавия:
Рост кристаллов и исследование ферроборатов Sm1-xLaxFe3(BO3)4 методом спектроскопии комбинационного рассеяния света
Кл.слова (ненормированные):
Crystal lattices
--
Iron compounds
--
Raman spectroscopy
--
Single crystals
--
Crystal nucleation
--
Flux methods
--
Internal structure
--
Magnetic phase transitions
--
Magnon scattering
--
Spectral region
--
Temperature range
--
Wave numbers
--
Lanthanum
Аннотация:
Sm1-xLaxFe3(BO3)4 (x = 0, 0.75) single crystals were synthesized using the flux method. The crystal nucleation procedure and flux parameters are reported. Conditions for growing the Sm1-xLaxFe3(BO3)4 (x = 0, 0.75) single crystals are described. The prepared crystals were studied by Raman spectroscopy in the temperature range of T = 10-300 K. The spectral region corresponding to temperatures of T = 10-55 K, which involves the temperatures of the magnetic phase transition TN = 32 K for x = 0 and TN = 31 K for x = 0.75, was thoroughly analyzed. Anomalies related to the magnetic ordering established in both compounds were found. The main changes occur in the low-wavenumber region (up to 100 cm-1), where the mode corresponding to magnon scattering arises. This mode is shown to have the internal structure indicative of the occurrence of unstable vibrations (40-80 cm-1). The results obtained are analyzed by calculating the empirical lattice dynamics in Sm1-xLaxFe3(BO3)4 with x = 0 and x = 1. © 2016 American Chemical Society.
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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian State Aerospace University, Krasnoyarsk, Russian Federation
Доп.точки доступа:
Moshkina, E. M.; Мошкина, Евгения Михайловна; Krylov, A. S.; Крылов, Александр Сергеевич; Sofronova, S. N.; Софронова, Светлана Николаевна; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
; Temerov, V. L.; Темеров, Владислав Леонидович
}
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18.
Crystal structure and
structural phase transition in bismuth-containing HoFe3(BO3)4 in the temperature range 11–500 K / E. S. Smirnova, O. A. Alekseeva, A. P. Dudka [et al.]> // Acta Crystallogr. B. - 2019. -
Vol. 75
. - P. 954-968,
DOI
10.1107/S2052520619010473. - Cited References: 37. - The authors are grateful to D. Yu. Chernyshov (SNBL, ESRF, Grenoble) for his assistance in obtaining the experimental data. This work was performed using the equipment of the Shared Research Center FSRC ‘Crystallography and Photonics’ RAS and was supported by the Russian Ministry of Education and Science (project RFMEFI62119X0035). - This work was supported by the Ministry of Science and Higher Education within the State assignment FSRC ‘Crystallography and Photonics’ RAS and partially by the Russian Foundation for Basic Research (grant No. 17-02-00766) . - ISSN 2052-5192
Кл.слова (ненормированные):
holmium iron borate
--
crystal structure
--
structural phase transition
--
Mossbauer spectroscopy
--
characteristic temperatures
Аннотация:
An accurate single-crystal X-ray diffraction study of bismuth-containing HoFe3(BO3)4 between 11 and 500 K has revealed structural phase transition at Tstr = 365 K. The Bi atoms enter the composition from Bi2Mo3O12-based flux during crystal growth and significantly affect Tstr. The content of Bi was estimated by two independent methods, establishing the composition as (Ho0.96Bi0.04)Fe3(BO3)4. In the low-temperature (LT) phase below Tstr the (Ho0.96Bi0.04)Fe3(BO3)4 crystal symmetry is trigonal, of space group P3121, whereas at high temperature (HT) above 365 K the symmetry increases to space group R32. There is a sharp jump of oxygen O1 (LT) and O2 (LT) atomic displacement parameters (ADP) at Tstr. O1 and O2 ADP ellipsoids are the most elongated over 90–500 K. In space group R32 specific distances decrease steadily or do not change with decreasing temperature. In space group P3121 the distortion of the polyhedra Ho(Bi)O6, Fe1O6 and Fe2O6, B2O3 and B3O3 increases with decreasing temperature, whereas the triangles B1O3 remain almost equilateral. All BO3 triangles deviate from the ab plane with decreasing temperature. Fe–Fe distances in Fe1 chains decrease, while distances in Fe2 chains increase with decreasing temperature. The Mössbauer study confirms that the FeO6 octahedra undergo complex dynamic distortions. However, all observed distortions are rather small, and the general change in symmetry during the structural phase transition has very little influence on the local environment of iron in oxygen octahedra. The Mössbauer spectra do not distinguish two structurally different Fe1 and Fe2 positions in the LT phase. The characteristic temperatures of cation thermal vibrations were calculated using X-ray diffraction and Mössbauer data.
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Держатели документа:
Shubnikov Inst. of Cristal. of Federal Scientific Research Centre Crystallography and Photonics, Russian Academy of Sciences, Moscow, 119333, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Доп.точки доступа:
Smirnova, E. S.; Alekseeva, O. A.; Dudka, A. P.; Khmelenin, D. N.; Frolov, K. V.; Lyubutina, M. V.; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
; Lyubutin, I. S.
}
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19.
Crystal structure dynamics
of RFe3(BO3)4 single crystals in the temperature range 25–500 K / O. A. Alekseeva, E. S. Smirnova, K. V. Frolov [et al.]> // Crystals. - 2022. -
Vol. 12
,
Is. 9
. - Ст. 1203,
DOI
10.3390/cryst12091203. - Cited References: 67. - This research was funded by the Ministry of Science and Higher Education within the State assignment FSRC ‘Crystallography and Photonics’ RAS 075-01025-22-00 . - ISSN 2073-4352
Кл.слова (ненормированные):
rare-earth iron borates
--
low-temperature X-ray diffraction
--
single crystals
--
structural distortions
--
temperature structural dynamics
--
exchange and super-exchange interaction
--
Mossbauer spectroscopy
Аннотация:
The multiferroic RFe3(BO3)4 family is characterized by diverse magnetic, magnetoelectric, and magnetoelastic properties, the fundamental aspects of which are essential for modern electronics. The present research, using single-crystal X-ray diffraction (XRD) and Mossbauer spectroscopy (MS) in the temperature range of 25–500 K, aimed to analyze the influence of local atomic coordination on magnetoelectric properties and exchange and super-exchange interactions in RFe3(BO3)4. Low-temperature, single-crystal XRD data of the magnetically ordered phase of RFe3(BO3)4 at 25 K, which were obtained for the first time, were supplemented with data obtained at higher temperatures, making it possible to draw conclusions about the mechanism of the structural dynamics. It was shown that, in structures with R = Gd, Ho, and Y (low-temperature space group P3121), a shift in oxygen atoms (O2, second coordination sphere of R atoms) was accompanied by rotation of the B2O3 triangle toward R atoms at low temperatures, and by different rearrangements in iron chains of two types, in contrast to Nd and Sm iron borates (space group R32). These rearrangements in the structures of space group P3121 affected the exchange and super-exchange paths at low temperatures. The MS results confirm the influence of the distant environment of atoms on the magnetoelectric properties of rare-earth iron borates at low temperatures.
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Scopus
Держатели документа:
Shubnikov Institute of Crystallography of Federal Scientific Research Centre ‘Crystallography and Photonics’, Russian Academy of Sciences, Moscow, 119333, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Доп.точки доступа:
Alekseeva, O. A.; Smirnova, E. S.; Frolov, K. V.; Lyubutina, M. V.; Lyubutin, I. S.; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
}
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20.
Crystal structure of
bismuth-containing samarium iron–aluminium borates Sm1−xBixFe3−yAly(BO3)4 (x = 0.05–0.07, y = 0–0.28) in the temperature range of 25–500 K / E. S. Smirnova, O. A. Alekseeva, V. V. Artemov [et al.]> // Crystals. - 2023. -
Vol. 13
,
Is. 7
. - Ст. 1128,
DOI
10.3390/cryst13071128. - Cited References: 59. - This work was supported by the Russian Science Foundation (project No 23-22-00286) . - ISSN 2073-4352
Кл.слова (ненормированные):
rare-earth iron–aluminium borates
--
solid solutions
--
low-temperature X-ray diffraction
--
single crystals
--
temperature structural dynamics
--
negative thermal expansion
Аннотация:
Structural features of new mixed bismuth-containing samarium iron–aluminium borate single crystals Sm1−xBixFe3−yAly(BO3)4 (x = 0.05–0.07, y = 0–0.28) were studied using X-ray diffraction analysis based on aluminium content and temperature in the range 25–500 K. The crystals were grown using the solution-in-melt technique with Bi2Mo3O12 in a flux. The composition of the single crystals was analyzed using energy-dispersive X-ray fluorescence and energy-dispersive X-ray elemental analysis. Temperature dependencies of Sm1−xBixFe3−yAly(BO3)4 unit-cell parameters were studied. Negative thermal expansion was identified below 100 K and represented by characteristic surfaces of the thermal expansion tensor. (Sm,Bi)–O, (Sm,Bi)–(Fe,Al), (Fe,Al)–(Fe,Al), and (Fe,Al)–O interatomic distances decreased with the addition of aluminium atoms. An increase in the (Fe,Al)–(Fe,Al) intrachain bond length at low temperatures in the magnetically ordered state weakened this bond, whereas a decrease in the (Fe,Al)–(Fe,Al) interchain distance strengthened super-exchange paths between different chains. It was found that the addition of aluminium atoms influenced interatomic distances in Sm1−xBixFe3−yAly(BO3)4 much more than lowering the temperature from 293 K to 25 K. The effect of aluminium doping on magnetoelectric properties and structural symmetry of rare-earth iron borates is also discussed.
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Держатели документа:
Shubnikov Institute of Crystallography of Federal Scientific Research Centre ‘Crystallography and Photonics’, Russian Academy of Sciences, Moscow 119333, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
Доп.точки доступа:
Smirnova, E. S.; Alekseeva, O. A.; Artemov, V. V.; Sorokin, T. A.; Khmelenin, D. N.; Sidorova, E. V.; Frolov, K. V.; Gudim, I. A.;
Гудим
,
Ирина
Анатольевна
}
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