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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Pankrats A. I., Zharkov S. M., Zeer G. M., Gudim I. A.
Заглавие : Antiferromagnetic resonance and magnetic anisotropy in PrxY1−xFe3(BO3)4 crystals in the region of the magnetic structure transformation “easy axis – easy plane”
Место публикации : J. Alloys Compd. - 2022. - Vol. 909. - Ст.164821. - ISSN 09258388 (ISSN), DOI 10.1016/j.jallcom.2022.164821
Примечания : Cited References: 37. - The authors acknowledge the assistance of R. Mironov in some resonance measurements. The SEM and EDS investigations were conducted in the SFU Joint Scientific Center supported by the State assignment (#FSRZ-2020–0011) of the Ministry of Science and Higher Education of the Russian Federation
Аннотация: The spin dynamics, magnetic structures and magnetic anisotropy of single crystals PrxY1−xFe3(BO3)4 have been studied using antiferromagnetic resonance (AFMR) in a wide range of frequencies, magnetic fields, and temperatures. The frequency-field dependences of AFMR for the crystals with x = 0.25 and 0.45 are characteristic of antiferromagnets with the easy plane (EP) anisotropy. The crystals with x = 0.75 and 1.0 exhibit frequency-field dependences that are typical for antiferromagnets with the easy axis (EA) anisotropy. In these crystals, a significant decrease in the effective anisotropy fields of praseodymium upon the transition to the spin-flop state has been found. It is shown that this is the main reason for the large lability intervals, within which the regions of coexistence of the collinear and spin-flop states overlap. In the crystal with x = 0.67, the magnetic field applied along the trigonal axis of the crystal leads to the spin reorientation transition from the EA to the EP state. A magnetic phase diagram of the states on the plane "magnetic field - temperature" is built. In this crystal, the effective anisotropy field of praseodymium also decreases upon the transition to the field-induced EP state. Diamagnetic dilution of the praseodymium subsystem leads to the contribution of this subsystem to the total anisotropy field depending almost linearly on the praseodymium concentration.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bludov A. N., Pashchenko V. A., Kobets M. I., Bedarev V. A., Merenkov D. N., Gnatchenko S. L., Gudim I. A.
Заглавие : Antiferromagnetic resonance in crystalline PrFe3(BO3)4
Место публикации : Low Temp. Phys. - 2018. - Vol. 44, Is. 2. - P.139-143. - ISSN 1063-777X, DOI 10.1063/1.5020909. - ISSN 1090-6517(eISSN)
Примечания : Cited References: 18
Аннотация: Experimental AFMR studies of crystalline PrFe3(BO3)4 over a wide frequency range of 10–143 GHz at a temperature of 4.2 K have been carried out. The high-frequency properties of praseodymium ferroborate are well described in terms of a model of a two-sublattice antiferromagnet with an “easy axis” anisotropy. An energy gap of 134.3 ± 0.5 GHz is determined and the magnitude of the effective magnetic anisotropy field is estimated to be 1.9 ± 0.1 kOe. An analysis indicates that the spin-orientational phase transition in this compound is a first order transition.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kobets M. I., Dergachev K. G., Khatsko E. N., Gnatchenko S. L., Bezmaternykh L. N., Gudim, I. A.
Заглавие : Antiferromagnetic resonance study of the magnetic structure of Nd0.75Dy0.25Fe3(BO3)(4)
Место публикации : Low Temp. Phys.: American Institute of Physics, 2014. - Vol. 40, Is. 7. - P.629-634. - ISSN 1063-777X, DOI 10.1063/1.4890992. - ISSN 1090-6517
Примечания : Cited References: 17
Аннотация: The effect of replacing Nd3+ ions with Dy3+ ions on the resonance properties of Nd0.75Dy0.25Fe3(BO3)(4) is studied. The antiferromagnetic resonance (AFMR) method is used to detect an easy axis-easy plane magnetic spin-reorientation phase transition owing to competing exchange interactions of Nd-Fe and Dy-Fe, and the frequency-field dependence of the AFMR spectrum before and after the phase transition is studied. At 4.2 K, the detected resonance spectra in the H parallel to c direction are AFMR modes of iron, and their frequency-field dependences correspond to easy-axis (H 15 kOe) and easy-plane (H 16 kOe) magnetic structures with magnon excitation energy gaps of 77.2 and 100.3 GHz, respectively. The effective magnetic anisotropies responsible for these gaps are 0.7 and 1.2 kOe, respectively. Substitution by Dy3+ ions in crystalline Nd0.75Dy0.25Fe3(BO3)(4) in the paramagnetic region produces an additional static internal field owing to polarization, which leads to a shift in the resonance field of the EPR absorption line and a change in the g-factor of the Fe3+ ions. (C) 2014 AIP Publishing LLC.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mukhin A. A., Vorob'ev G. P., Ivanov V. Y., Kadomtseva A. M., Narizhnaya A. S., Kuz'menko A. M., Popov Y. F., Bezmaternykh L. N., Gudim I. A.
Заглавие : Colossal magnetodielectric effect in SmFe3(BO3)(4) multiferroic
Разночтения заглавия :авие SCOPUS: Colossal magnetodielectric effect in SmFe 3(BO 3) 4 multiferroic
Место публикации : JETP Letters. - 2011. - Vol. 93, Is. 5. - P.275-281. - ISSN 0021-3640, DOI 10.1134/S0021364011050079
Примечания : Cited References: 17. - We are grateful to A.K. Zvezdin and A.P. Pyatakov for the discussion of this work and valuable comments. This work was supported by the Russian Foundation for Basic Research, project nos. 10-02-00846 and 09-02-01355.
Предметные рубрики: FERROELECTRICITY
MAGNETOSTRICTION
GARNETS
Аннотация: The colossal (more than threefold) decrease in the dielectric constant E in the easy-plane SmFe3(BO3)(4) ferroborate in a magnetic field of similar to 5 kOe applied in the basal ab plane of the crystal has been found. A close relation of this effect to anomalies in the field dependence of the electric polarization has been established. It has been shown that this magnetodielectric effect is due to the contribution to E from the electric susceptibility, which is related to the rotation of spins in the ab plane, arises in the region of the antiferromagnetic ordering T T (N) and electric polarization in the magnetic field has been proposed, taking into account the additional anisotropy in the basal plane induced by the magnetoelastic stresses.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Sokolov V. V., Malakhovskii A. V., Gudim I. A.
Заглавие : Comparative study of magnetic circular dichroism of f-f transitions in ErAl3(BO3)4 and ErFe3(BO3)4
Коллективы : International Feofilov Symposium on spectroscopy of crystals doped with rare earth and transition metal ions
Место публикации : XVII International Feofilov Symposium on spectroscopy of crystals doped with rare earth and transition metal ions (IFS'XVII): book of abstracts. - 2018. - P.207-208
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Freydman A. L., Balaev A. D., Dubrovskiy A. A., Temerov V. L., Gudim, I. A.
Заглавие : Comparative study of magnetoelectric effect in HoAl3(BO3)4 and HoGa3(BO3)4 single crystals
Коллективы : Moscow International Symposium on Magnetism, Московский государственный университет им. М.В. Ломоносова, Российский фонд фундаментальных исследований
Место публикации : Moscow International Symposium on Magnetism (MISM-2017): 1-7 July 2017 : book of abstracts. - 2017. - Ст.5PO-I2-5. - P.1050 (Шифр 29916280)
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Freydman A. L., Dubrovskii A. A., Temerov V. L., Gudim I. A.
Заглавие : Comparative study of the magnetoelectric effect in HoAl3(BO3)4 and HoGa3(BO3)4 single crystals
Коллективы : Russian Foundation for Basic Research [16-38-00245, 16-32-00163]; Russian Foundation for Basic Research, Government of the Krasnoyarsk Territory; Krasnoyarsk Territorial Foundation [16-48-243040]
Место публикации : Phys. Solid State. - 2018. - Vol. 60, Is. 3. - P.510-514. - ISSN 1063-7834, DOI 10.1134/S1063783418030113. - ISSN 1090-6460(eISSN)
Примечания : Cited References:13. - This study was supported by the Russian Foundation for Basic Research, projects nos. 16-38-00245 and 16-32-00163 and the Russian Foundation for Basic Research, Government of the Krasnoyarsk Territory, and Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project no. 16-48-243040.
Предметные рубрики: MAGNETIZATION
Аннотация: The comparative study of the magnetoelectric properties and magnetostriction of HoGa3(BO3)4 and HoAl3(BO3)4 single crystals has been carried out. The investigated compounds exhibit qualitatively similar magnetodielectric and inverse magnetoelectric ME E effects with the close absolute values, which is indicative of the weak effect of a nonmagnetic metal ion. On the contrary, the magnetostriction of the galloborate has been found to be threefold higher than that of the alumoborate. In addition, the difference between the qualitative behaviors of magnetostriction has been established: the magnetic-field dependence of magnetostriction for the alumoborate has the maximum near 70 kOe at T = 4.2 K, while the galloborate magnetostriction has no maximum and does not saturate in a field of 140 kOe.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Eremin E. V., Gudim I. A., Temerov V. L., Smolyakov D. A., Molokeev M. S.
Заглавие : Comparing the magnetic and magnetoelectric properties of the SmFe3(BO3)4 ferroborate single crystals grown using different solvents
Коллективы : Russian Foundation for Basic Research (RFBR) [18-02-00696_a]; RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund [18-42-240011 p_a]
Место публикации : J. Cryst. Growth. - 2019. - Vol. 518. - P.1-4. - ISSN 0022-0248, DOI 10.1016/j.jcrysgro.2019.04.017. - ISSN 1873-5002(eISSN)
Примечания : Cited References: 17. - This study was supported by the Russian Foundation for Basic Research (RFBR) according to the research projects No. 18-02-00696_a and RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund by project No. 18-42-240011 p_a.
Предметные рубрики: POLARIZATION
FEATURES
Ключевые слова (''Своб.индексиров.''): impurities--growth from solutions--single crystal growth--borates--ferroelectric materials--magnetic materials
Аннотация: SmFe3(BO3)4 single crystals have been grown from the bismuth trimolybdate and lithium tungstate-based melt–solutions. Samarium ferroborate single crystals were grown first from the lithium–tungstate flux. The magnetic and magnetoelectric properties of the synthesized crystals have been compared. It is shown that the SmFe3(BO3)4 ferroborate grown from the bismuth trimolybdate-based melt–solution contains impurities of Bi3+ ions (∼5% at.), which replace Sm3+ ions, while the SmFe3(BO3)4, ferroborate grown from the lithium tungstate-based melt–solution contains minor or zero amounts of such impurities. The magnetoelectric and magnetodielectric effects with the Bi3+ admixture appeared 1.5× stronger than in SmFe3(BO3)4; this is probably due to twinning.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Gudim, I. A., Eremin E. V., Temerov V. L., Volkov N. V.
Заглавие : Comparision of magnetic properties of TmAl3(BO3)4 and TmAl2,75Sc0,25(BO3)4 crystals
Коллективы : "Магнитные материалы. Новые технологии", Байкальская международная конференция, "Magnetic materials. New tecnologies", Baikal International Conference, Байкальская международная конференция "Магнитные материалы. Новые технологии", Иркутский государственный университет
Место публикации : Магнитные материалы. Новые технологии: тез. докл. VII Байкал. Междунар. конф./ Иркутский гос. ун-т. - Иркутск, 2016. - P.97. - ISBN 978-591-345-152-1: тез. докл. VII Байкал. Междунар. конф. BICMM-2016/ "Magnetic materials. New tecnologies", Baikal International Conference (7 ; 2016 ; Aug. ; 22–26 ; Listvyanka, Irkutsk region), Иркутский гос. ун-т; чл. прогр. ком.: Р. С. Исхаков, С. С. Аплеснин, С. Г. Овчинников. - ISBN 978-591-345-152-1
Примечания : Библиогр.: 1 назв. - This study was supported by the Russian Foundation for Basic Research, project no. 13-02-12442, no. 14-02-00307 and no. 15-42-04186
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gudim I. A., Eremin E. V., Mikhashenok N. V., Titova V. R.
Заглавие : Comparison of magnetic properties of GdFe3(BO3)4, ferroborates grown using various solvents
Место публикации : Phys. Solid State. - 2023. - Vol. 65, Is. 2. - P.235-239. - ISSN 10637834 (ISSN), DOI 10.21883/PSS.2023.02.55406.505. - ISSN 10906460 (eISSN)
Примечания : Cited References: 18. - This study was supported by grant No. 22-12-20019 provided by the Russian Science Foundation and the Krasnoyarsk Regional Science Foundation (https://rscf.ru/project/22-72-00017/)
Аннотация: GdFe3(BO3)4, single crystals were grown from melt-solutions based on bismuth trimolybdate and lithium tungstate. Single crystals of gadolinium ferroborate from lithium-tungstate solution-melt were grown for the first time. The magnetic properties of the grown crystals are compared. It is shown that the GdFe3(BO3)4, ferroborate obtained using bismuth solution-melt trimolybdate contains impurities of Bi3+ ions (6% at.), which replace Gd3+ ions. Whereas GdFe3(BO3)4, ferroborate grown from a solution-melt based on lithium tungstate does not seem to contain such uncontrolled impurities.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sukhachev A. L., Malakhovskii A. V., Nelson C. S., Gudim I. A., Temerov V. L.
Заглавие : Comparison of the absorption spectra of Nd3+ ions in the NdFe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4, and Ho0.75Nd0.25Fe3(BO3)4 crystals
Место публикации : Phys. Solid State. - 2021. - Vol. 63, Is. 1. - P.113-121. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783421010200
Примечания : Cited References: 21. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, to the research project: number 19-42-240003 “Influence of the local en-vironment on magneto-optical properties of f–f transitions in rare-earth aluminum and iron borates”
Аннотация: The polarized optical absorption spectra in the region of a series of the f–f transitions of Nd3+ ions in the Ho0.75Nd0.25Fe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4, and NdFe3(BO3)4 crystals at 90 K have been compared. The spectral features related to the difference in the local environment of Nd3+ ions in these crystals have been established. In the region of the transition 4I9/2 → 4G5/2 + 2G7/2 of Nd3+ ions in the Ho0.75Nd0.25Fe3(BO3)4 crystal, the appearance of some absorption lines at the structural transition R32 → P3121 around ~200 K due to the local symmetry variation has been found. The intensity of these lines smoothly increases with a decrease in temperature from the transition point. The temperature dependence of the lattice parameters of the Ho0.75Nd0.25Fe3(BO3)4 crystal has been measured. It has been found that, at the transition temperature, the lattice parameter a changes stepwise, which is indicative of the occurrence of a first-order phase transition. The lattice parameter c changes smoothly.
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12.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Gudim, I. A.
Заглавие : Comparison of the magnetic properties of NdSc3(BO3)4 and NdSc1.5Ga1.5(BO3)4 crystals
Коллективы : Novel Trends in Physics of Ferroics, International Workshop , "Новые направления в развитии физики ферроиков", международный семинар, Физико-технический институт им. А.Ф. Иоффе РАН
Место публикации : Second Int. Workshop "Novel Trends in Physics of Ferroics": abstracts. - 2017. - P.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golosovsky I. V., Vasilev A. I., Mukhin A. A., Ressouche E., Skumryev V., Urcelay-Olabarria I., Gudim I. A., Bezmaternykh L. N.
Заглавие : Complex magnetic order in the Nd(Tb)Fe3(BO3)4 multiferroic revealed by single-crystal neutron diffraction
Место публикации : Phys. Rev. B. - 2019. - Vol. 99, Is. 13. - Ст.134439. - ISSN 24699950 (ISSN) , DOI 10.1103/PhysRevB.99.134439
Примечания : Cited References: 33. - This work was supported by the Russian Grant No. RFBR 16-02-00058. A.A.M. acknowledges the financial support from the Russian Science Foundation (16-12-10531).
Аннотация: Magnetic structure of the substituted multiferroics-ferroborates Nd0.9Tb0.1Fe3(BO3)4 and Nd0.8Tb0.2Fe3(BO3)4 were determined in the framework of a self-consistent refinement of the single crystal neutron diffraction data. The small substitution of Nd for Tb leads to the reorientation of the main antiferromagnetic vector L from the basal plane towards the hexagonal axis. The reorientation takes place via an angular structure for which L does not coincide with the principal crystallographic directions and evolves with temperature due to competing magnetic anisotropies of Fe, Nd, and Tb subsystems. Our refinement at 2 K reveals the existence of distortions in the collinear antiferromagnetic Fe spin arrangement suggested before in other ferroborates. Therefore, besides the main antiferromagnetic vector L, the magnetic structure involves additional fine symmetrized combinations of spin components allowed by symmetry. They coexist with certain L components and could originate from the antisymmetric Dzyaloshinsky-Moriya Fe-Fe exchange interactions. At higher temperatures, the magnetic structure is described by the simple collinear model, where the L vector is deviated from the hexagonal plane. © 2019 American Physical Society.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Popova M. N., Chukalina E. P., Malkin B. Z., Erofeev D. A., Bezmaternykh L. N., Gudim, I. A.
Заглавие : Crystal field and exchange interactions in the SmFe3(BO3)4 multiferroic
Коллективы : Russian Foundation for Basic Research [13-02-00787]; basic research program Quantum Mesoscopic and Disordered Structures of the Presidium of the Russian Academy of Sciences
Место публикации : J. Exp. Theor. Phys.: MAIK Nauka-Interperiodica / Springer, 2014. - Vol. 118, Is. 1. - P.111-123. - ISSN 1063-7761, DOI 10.1134/S1063776114010142. - ISSN 1090-6509
Примечания : Cited References: 22. - This work was supported by the Russian Foundation for Basic Research (project no. 13-02-00787) and the basic research program Quantum Mesoscopic and Disordered Structures of the Presidium of the Russian Academy of Sciences.
Аннотация: The optical spectra of oriented SmFe3(BO3)4 single crystals are studied in the region of the f-f transitions in the Sm3+ ion by Fourier spectroscopy. The energies, the symmetry properties, and the exchange splittings of the Stark sublevels of the ground and 17 excited multiplets of the Sm3+ ion in a crystal field of symmetry D 3 are determined from the measured temperature dependences of polarized-radiation absorption spectra. The parameters of the crystal field acting on samarium ions and the parameters of the exchange interaction between Sm3+ and Fe3+ ions are found. The anisotropy of the effective exchange interaction is shown to be substantially stronger than the magnetic anisotropy, due to a strong crystal-field-induced mixing of the ground and excited multiplets.
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15.

Вид документа : Однотомное издание
Шифр издания :
Автор(ы) : Gudim I. A., Eremin E. V., Temerov V. L.
Заглавие : Crystal growth and magnetic properties of Nd1-xDyxFe3(BO3)4"
Место публикации : ArXiv. - 2009. - Ст.arxiv:0906.2250
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Moshkina E. M., Krylov A. S., Sofronova S. N., Gudim, I. A., Temerov V. L.
Заглавие : Crystal growth and Raman spectroscopy study of Sm1-xLaxFe3(BO3)4 ferroborates
Место публикации : Cryst. Growth Des.: American Chemical Society, 2016. - Vol. 16, Is. 12. - P.6915-6921. - ISSN 15287483 (ISSN), DOI 10.1021/acs.cgd.6b01079
Примечания : Cited References: 17. - This work was supported by the Russian Foundation for Basic Research, Project No. 14-02-00307.
Ключевые слова (''Своб.индексиров.''): crystal lattices--iron compounds--raman spectroscopy--single crystals--crystal nucleation--flux methods--internal structure--magnetic phase transitions--magnon scattering--spectral region--temperature range--wave numbers--lanthanum
Аннотация: Sm1-xLaxFe3(BO3)4 (x = 0, 0.75) single crystals were synthesized using the flux method. The crystal nucleation procedure and flux parameters are reported. Conditions for growing the Sm1-xLaxFe3(BO3)4 (x = 0, 0.75) single crystals are described. The prepared crystals were studied by Raman spectroscopy in the temperature range of T = 10-300 K. The spectral region corresponding to temperatures of T = 10-55 K, which involves the temperatures of the magnetic phase transition TN = 32 K for x = 0 and TN = 31 K for x = 0.75, was thoroughly analyzed. Anomalies related to the magnetic ordering established in both compounds were found. The main changes occur in the low-wavenumber region (up to 100 cm-1), where the mode corresponding to magnon scattering arises. This mode is shown to have the internal structure indicative of the occurrence of unstable vibrations (40-80 cm-1). The results obtained are analyzed by calculating the empirical lattice dynamics in Sm1-xLaxFe3(BO3)4 with x = 0 and x = 1. © 2016 American Chemical Society.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Smirnova E. S., Alekseeva O. A., Dudka A. P., Khmelenin D. N., Frolov K. V., Lyubutina M. V., Gudim I. A., Lyubutin I. S.
Заглавие : Crystal structure and structural phase transition in bismuth-containing HoFe3(BO3)4 in the temperature range 11–500 K
Место публикации : Acta Crystallogr. B. - 2019. - Vol. 75. - P.954-968. - ISSN 20525192 (ISSN), DOI 10.1107/S2052520619010473
Примечания : Cited References: 37. - The authors are grateful to D. Yu. Chernyshov (SNBL, ESRF, Grenoble) for his assistance in obtaining the experimental data. This work was performed using the equipment of the Shared Research Center FSRC ‘Crystallography and Photonics’ RAS and was supported by the Russian Ministry of Education and Science (project RFMEFI62119X0035)This work was supported by the Ministry of Science and Higher Education within the State assignment FSRC ‘Crystallography and Photonics’ RAS and partially by the Russian Foundation for Basic Research (grant No. 17-02-00766)
Аннотация: An accurate single-crystal X-ray diffraction study of bismuth-containing HoFe3(BO3)4 between 11 and 500 K has revealed structural phase transition at Tstr = 365 K. The Bi atoms enter the composition from Bi2Mo3O12-based flux during crystal growth and significantly affect Tstr. The content of Bi was estimated by two independent methods, establishing the composition as (Ho0.96Bi0.04)Fe3(BO3)4. In the low-temperature (LT) phase below Tstr the (Ho0.96Bi0.04)Fe3(BO3)4 crystal symmetry is trigonal, of space group P3121, whereas at high temperature (HT) above 365 K the symmetry increases to space group R32. There is a sharp jump of oxygen O1 (LT) and O2 (LT) atomic displacement parameters (ADP) at Tstr. O1 and O2 ADP ellipsoids are the most elongated over 90–500 K. In space group R32 specific distances decrease steadily or do not change with decreasing temperature. In space group P3121 the distortion of the polyhedra Ho(Bi)O6, Fe1O6 and Fe2O6, B2O3 and B3O3 increases with decreasing temperature, whereas the triangles B1O3 remain almost equilateral. All BO3 triangles deviate from the ab plane with decreasing temperature. Fe–Fe distances in Fe1 chains decrease, while distances in Fe2 chains increase with decreasing temperature. The Mössbauer study confirms that the FeO6 octahedra undergo complex dynamic distortions. However, all observed distortions are rather small, and the general change in symmetry during the structural phase transition has very little influence on the local environment of iron in oxygen octahedra. The Mössbauer spectra do not distinguish two structurally different Fe1 and Fe2 positions in the LT phase. The characteristic temperatures of cation thermal vibrations were calculated using X-ray diffraction and Mössbauer data.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Alekseeva O. A., Smirnova E. S., Frolov K. V., Lyubutina M. V., Lyubutin I. S., Gudim I. A.
Заглавие : Crystal structure dynamics of RFe3(BO3)4 single crystals in the temperature range 25–500 K
Место публикации : Crystals. - 2022. - Vol. 12, Is. 9. - Ст.1203. - ISSN 20734352 (ISSN), DOI 10.3390/cryst12091203
Примечания : Cited References: 67. - This research was funded by the Ministry of Science and Higher Education within the State assignment FSRC ‘Crystallography and Photonics’ RAS 075-01025-22-00
Аннотация: The multiferroic RFe3(BO3)4 family is characterized by diverse magnetic, magnetoelectric, and magnetoelastic properties, the fundamental aspects of which are essential for modern electronics. The present research, using single-crystal X-ray diffraction (XRD) and Mossbauer spectroscopy (MS) in the temperature range of 25–500 K, aimed to analyze the influence of local atomic coordination on magnetoelectric properties and exchange and super-exchange interactions in RFe3(BO3)4. Low-temperature, single-crystal XRD data of the magnetically ordered phase of RFe3(BO3)4 at 25 K, which were obtained for the first time, were supplemented with data obtained at higher temperatures, making it possible to draw conclusions about the mechanism of the structural dynamics. It was shown that, in structures with R = Gd, Ho, and Y (low-temperature space group P3121), a shift in oxygen atoms (O2, second coordination sphere of R atoms) was accompanied by rotation of the B2O3 triangle toward R atoms at low temperatures, and by different rearrangements in iron chains of two types, in contrast to Nd and Sm iron borates (space group R32). These rearrangements in the structures of space group P3121 affected the exchange and super-exchange paths at low temperatures. The MS results confirm the influence of the distant environment of atoms on the magnetoelectric properties of rare-earth iron borates at low temperatures.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Smirnova E. S., Alekseeva O. A., Artemov V. V., Sorokin T. A., Khmelenin D. N., Sidorova E. V., Frolov K. V., Gudim I. A.
Заглавие : Crystal structure of bismuth-containing samarium iron–aluminium borates Sm1−xBixFe3−yAly(BO3)4 (x = 0.05–0.07, y = 0–0.28) in the temperature range of 25–500 K
Колич.характеристики :20 с
Место публикации : Crystals. - 2023. - Vol. 13, Is. 7. - Ст.1128. - ISSN 20734352 (eISSN), DOI 10.3390/cryst13071128
Примечания : Cited References: 59. - This work was supported by the Russian Science Foundation (project No 23-22-00286)
Аннотация: Structural features of new mixed bismuth-containing samarium iron–aluminium borate single crystals Sm1−xBixFe3−yAly(BO3)4 (x = 0.05–0.07, y = 0–0.28) were studied using X-ray diffraction analysis based on aluminium content and temperature in the range 25–500 K. The crystals were grown using the solution-in-melt technique with Bi2Mo3O12 in a flux. The composition of the single crystals was analyzed using energy-dispersive X-ray fluorescence and energy-dispersive X-ray elemental analysis. Temperature dependencies of Sm1−xBixFe3−yAly(BO3)4 unit-cell parameters were studied. Negative thermal expansion was identified below 100 K and represented by characteristic surfaces of the thermal expansion tensor. (Sm,Bi)–O, (Sm,Bi)–(Fe,Al), (Fe,Al)–(Fe,Al), and (Fe,Al)–O interatomic distances decreased with the addition of aluminium atoms. An increase in the (Fe,Al)–(Fe,Al) intrachain bond length at low temperatures in the magnetically ordered state weakened this bond, whereas a decrease in the (Fe,Al)–(Fe,Al) interchain distance strengthened super-exchange paths between different chains. It was found that the addition of aluminium atoms influenced interatomic distances in Sm1−xBixFe3−yAly(BO3)4 much more than lowering the temperature from 293 K to 25 K. The effect of aluminium doping on magnetoelectric properties and structural symmetry of rare-earth iron borates is also discussed.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Smirnova E. S., Alekseeva O. A., Dudka A. P., Verin I. A., Artemov V. V., Lyubutina M. V., Gudim I. A., Frolov K. V., Lyubutin I. S.
Заглавие : Crystal structure of bismuth-containing NdFe3(BO3)4 in the temperature range 20–500 K
Коллективы : Russian Ministry of Science and Higher Education; Ministry of Science and Higher Education within the State assignment FSRC 'Crystallography and Photonics' RAS
Место публикации : Acta Crystallogr. B. - 2022. - Vol. 78, Pt. 1. - P.1-13. - ISSN 2052-5206(eISSN), DOI 10.1107/S205252062101180X
Примечания : Cited References: 44. - This work was performed using the equipment of the Shared Research Center FSRC `Crystallography and Photonics' RAS supported by the Russian Ministry of Science and Higher Education. This work was supported by the Ministry of Science and Higher Education within the State assignment FSRC `Crystallography and Photonics' RAS
Предметные рубрики: MAGNETIC PHASE-TRANSITIONS
UNIT-CELL PARAMETERS
DIFFRACTION
Аннотация: Neodymium iron borate NdFe3(BO3)4 is an intensively studied multiferroic with high electric polarization values controlled by a magnetic field. It is characterized by a large quadratic magnetoelectric effect, rigidity in the base plane and a rather strong piezoelectric effect. In this work, the atomic structure of (Nd0.91Bi0.09)Fe3(BO3)4 was studied by single-crystal X-ray diffraction in the temperature range 20–500 K (space group R32, Z = 3). The Bi atoms found in the composition partially substitute the Nd atoms in the 3a position; they entered the structure due to the growth conditions in the presence of Bi2Mo3O12. It was shown that in the temperature range 20–500 K there is no structural phase transition R32→P3121, which occurs in rare-earth iron borates (RE = Eu–Er, Y) with an effective rare-earth cation radius smaller than that of Nd. The temperature dependence of the unit-cell c parameter reveals a slight increase on cooling below 90 K, which is similar to the results obtained previously for iron borates of Gd, Y and Ho. The atomic distances (Nd,Bi)—O, (Nd,Bi)—B, (Nd,Bi)—Fe, Fe—O, Fe—B and Fe—Fe in the iron chains and between chains decrease steadily with decreasing temperature from 500 to 90 K, whereas the B1(3b)—O distance does not change and the average B2(9e)—O distance increases slightly. There is a uniform decrease in the atomic displacement parameters with decreasing temperature, with a more pronounced decrease for the Nd(3a) and O2(9e) atoms. The O2(9e) atoms are characterized by the maximum atomic displacement parameters and the most elongated atomic displacement ellipsoids. The characteristic Debye and Einstein temperatures, and the static component in the atomic displacements were determined for cations using multi-temperature diffraction data. It was shown that the Nd cations have the weakest bonds with the surrounding atoms and the B cations have the strongest.
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