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Aminated magnetic nanoparticles for epithelial cell separation / A. V. Tyumentseva, E. S. Tyutrina, S. V. Stolyar [et al.] // 4th International Baltic Conference on Magnetism (IBCM 2021) : Book of abstracts. - 2021. - P. 208. - This work was supported by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research projects No. 20-42-242902 and by the Council of the President of the Russian Federation for State Support of Young Scientists and Leading Scientific Schools (project no. MK-1263.2020.3). We are grateful to the Center of collective use of FRC KSC SB RAS for the provided equipment.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS

Доп.точки доступа:
Tyumentseva, A. V.; Tyutrina, E. S.; Stolyar, S. V.; Столяр, Сергей Викторович; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; International Baltic Conference on Magnetism: focus on nanobiomedicine and smart materials(4 ; 2021 ; Aug. 29-Sept. 2 ; Svetlogorsk, Russia); Балтийский федеральный университет им. И. Канта
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Aminated magnetic nanoparticles functionalized with antibodies for cell separation / A. V. Tyumentseva, R. N. Yaroslavtsev, S. V. Stolyar [et al.] // VIII Euro-Asian symposium "Trends in magnetism" (EASTMAG-2022) : Book of abstracts / program com. S. G. Ovchinnikov [et al.]. - 2022. - Vol. 2, Sect. M : Magnetism in biology and medicine. - Ст. M.P10. - P. 442-443. - Cited References: 2. - The study was supported by the Russian Science Foundation and the Krasnoyarsk Region Science and Technology Support Fund, grant No. 22-14-20020 . - ISBN 978-5-94469-051-7

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia
Krasnoyarsk Scientific Center, FRC KSC SB RAS Krasnoyarsk, Russia

Доп.точки доступа:
Tyumentseva, A. V.; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Stolyar, S. V.; Столяр, Сергей Викторович; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Gerasimova, Yu. V.; Герасимова, Юлия Валентиновна; Knyazev, Yu. V.; Князев, Юрий Владимирович; Российская академия наук; Физико-технический институт им. Е.К. Завойского ФИЦ Казанского научного центра РАН; Казанский (Приволжский) федеральный университет; Euro-Asian Symposium "Trends in MAGnetism"(8 ; 2022 ; Aug. ; 22-26 ; Kazan); "Trends in MAGnetism", Euro-Asian Symposium(8 ; 2022 ; Aug. ; 22-26 ; Kazan)
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Anisometric iron oxide-based nanoparticles and sols based on them: Preparation and properties / S. V. Stolyar [et al.] // J. Supercond. Novel Magn. - 2019. - Vol. 32, Is. 4. - P. 971–975, DOI 10.1007/s10948-018-4784-7. - Cited References: 18. - The reported study was carried out with the financial support of the Russian Foundation for Fundamental Research, the Government of the Krasnoyarsk Territory, and the Krasnoyarsk Territory Fund for Support of Scientific and Technical Activity in the framework of scientific Projects No. 18-43-243003, No. 17-42-240080 and No. 17-43-240527. The work is supported by the Special Program of the Ministry of Education and Science of the Russian Federation for the Siberian Federal University. . - ISSN 1557-1939
Кл.слова (ненормированные):
Nanoparticles and nanorods -- Chemical preparation -- Superparamagnetism
Аннотация: We have synthesized magnetic powders of the magnetite-maghemite series by the chemical reaction of the FeSO4 iron salt and the natural arabinogalactan polysaccharide. These particles with a high magnetization value (∼ 300 Gs) represent a mixture of spherical particles and nanorods. Particles of a spherical shape (diameter of ∼ 5–6 nm) show a superparamagnetic behavior at room temperature, while rods with a diameter of ∼ 5 nm and a length of 30 nm are magnetic. We have prepared sol samples based on the nanoparticle aqueous solution of arabinogalactan. Our results on the magnetism of the circular dichroism (MCD) on sol are consistent with the of Mössbauer spectroscopy data.

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Держатели документа:
Siberian Federal University, Krasnoyarsk, Russian Federation
Krasnoyarsk Scientific Center, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Stolyar, S. V.; Bayukov, O. A.; Баюков, Олег Артемьевич; Chekanova, L. A.; Чеканова, Лидия Александровна; Gerasimova, Y. V.; Герасимова, Юлия Валентиновна; Sokolov, A. Е.; Соколов, Алексей Эдуардович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Volochaev, M. N.; Волочаев, Михаил Николаевич; Artemyeva, A. S.; Cheremiskina, E. V.; Knyazev, Yu. V.; Князев, Юрий Владимирович
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Bacterial ferrihydrite nanoparticles: preparation, magnetic properties, and application in medicine / S. V. Stolyar [et al.] // J. Supercond. Novel Magn. - 2018. - Vol. 31, Is. 8. - P. 2297-2304, DOI 10.1007/s10948-018-4700-1. - Cited References: 37. - The electron microscopy examination was carried out at the Center for Collective Use of the Krasnoyarsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences (Krasnoyarsk, Russia). . - ISSN 1557-1939
Кл.слова (ненормированные):
Nanoparticles -- Ferrihydrite -- Magnetic properties -- Drug delivery
Аннотация: Nanoparticles of antiferromagnetically ordered materials acquire the uncompensated magnetic moment caused by defects and surface effects. A bright example of such a nano-antiferromagnet is nanoferrihydrite consisting of particles 2–5 nm in size, the magnetic moment of which amounts to hundreds of Bohr magnetons per particle. We present a brief review of the studies on magnetic properties of ferrihydrite produced by bacteria. Special attention is focused on the aspects of possible biomedical applications of this material, i.e., the particle elimination, toxicity, and possible use for targeted drug delivery.

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Держатели документа:
Siberian Federal University, Krasnoyarsk, Russian Federation
Krasnoyarsk Scientific Center, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian Clinical Center, Krasnoyarsk, Russian Federation
Scientific Research Institute of Medical Problems of the North, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Balaev, D. A.; Балаев, Дмитрий Александрович; Ladygina, V. P.; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Popkov, S. I.; Попков, Сергей Иванович; Bayukov, O. A.; Баюков, Олег Артемьевич; Knyazev, Yu. V.; Князев, Юрий Владимирович; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Volochaev, M. N.; Волочаев, Михаил Николаевич; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Dobretsov, K. G.; Morozov, E. V.; Морозов, Евгений Владимирович; Falaleev, O. V.; Фалалеев, Олег Владимирович; Inzhevatkin, E. V.; Kolenchukova, O. A.; Chizhova, I. A.
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Bacterial ferrihydrite nanoparticles: preparation, magnetic properties, and application in medicine / S. V. Stolyar [и др.] // Moscow Int. Symp. on Magnet. (MISM-2017) : 1-7 July 2017 : book of abstracts. - 2017. - Ст. 3RP-O-10. - P. 417. - Cited References: 8. - Support by the Special Program for Siberian Federal University of the Ministry of Education and Science of the Russian Federation is acknowledged

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Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Balaev, D. A.; Балаев, Дмитрий Александрович; Ladygina, V. P.; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Popkov, S. I.; Попков, Сергей Иванович; Bayukov, O. A.; Баюков, Олег Артемьевич; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Volochaev, M. N.; Волочаев, Михаил Николаевич; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Dobretsov, K. G.; Falaleev, O.V.; Chizhova, I. A.; Moscow International Symposium on Magnetism(7 ; 2017 ; Jul. ; Moscow); Московский государственный университет им. М.В. Ломоносова; Российский фонд фундаментальных исследований
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Biogenic ferrihydrite nanoparticles: Synthesis, properties in vitro and in vivo testing and the concentration effect / S. V. Stolyar, O. A. Kolenchukova, A. V. Boldyreva [et al.] // Biomedicines. - 2021. - Vol. 9, Is. 3. - Ст. 323, DOI 10.3390/biomedicines9030323. - Cited References: 52. - This research was funded by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory and the Regional Science Foundation, grant number 20-416-242907 . - ISSN 2227-9059

РУБ Biochemistry & Molecular Biology + Medicine, Research & Experimental + Pharmacology & Pharmacy

Кл.слова (ненормированные):
ferrihydrite nanoparticles -- concentration effect -- microorganisms Klebsiella oxytoca -- neutrophilic granulocytes -- chemiluminescence -- toxicology
Аннотация: Biogenic ferrihydrite nanoparticles were synthesized as a result of the cultivation of Klebsiella oxytoca microorganisms. The distribution of nanoparticles in the body of laboratory animals and the physical properties of the nanoparticles were studied. The synthesized ferrihydrite nanoparticles are superparamagnetic at room temperature, and the characteristic blocking temperature is 23-25 K. The uncompensated moment of ferrihydrite particles was determined to be approximately 200 Bohr magnetons. In vitro testing of different concentrations of ferrihydrite nanoparticles for the functional activity of neutrophilic granulocytes by the chemiluminescence method showed an increase in the release of primary oxygen radicals by blood phagocytes when exposed to a minimum concentration and a decrease in secondary radicals when exposed to a maximum concentration. In vivo testing of ferrihydrite nanoparticles on Wister rats showed that a suspension of ferrihydrite nanoparticles has chronic toxicity, since it causes morphological changes in organs, mainly in the spleen, which are characterized by the accumulation of hemosiderin nanoparticles (stained blue according to Perls). Ferrihydrite can also directly or indirectly stimulate the proliferation and intracellular regeneration of hepatocytes. The partial detection of Perls-positive cells in the liver and kidneys can be explained by the rapid elimination from organs and the high dispersion of the nanomaterial. Thus, it is necessary to carry out studies of these processes at the systemic level, since the introduction of nanoparticles into the body is characterized by adaptive-proliferative processes, accompanied by the development of cell dystrophy and tension of the phagocytic system.

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Держатели документа:
RAS, Kirensky Inst Phys, Fed Res Ctr KSC SB, Krasnoyarsk 660036, Russia.
RAS, Krasnoyarsk Sci Ctr, Fed Res Ctr KSC SB, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Dept Biophys, Krasnoyarsk 660041, Russia.
RAS, Sci Res Inst Med Problems North, Fed Res Ctr KSC SB, Krasnoyarsk 660022, Russia.
RAS, Inst Biophys, Fed Res Ctr KSC SB, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Kolenchukova, Oksana A.; Boldyreva, Anna V.; Kudryasheva, Nadezda S.; Gerasimova, Yu. V.; Герасимова, Юлия Валентиновна; Krasikov, A. A.; Красиков, Александр Александрович; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Bayukov, O. A.; Баюков, Олег Артемьевич; Ladygina, Valentina P.; Birukova, Elena A.; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of the Krasnoyarsk Territory; Regional Science Foundation [20-416-242907]
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Change in the magnetic properties of nanoferrihydrite with an increase in the volume of nanoparticles during low-temperature annealing / D. A. Balaev [et al.] // Phys. Solid State. - 2016. - Vol. 58, Is. 9. - P. 1782-1791, DOI 10.1134/S1063783416090092. - Cited References: 32. - This study was supported by the Ministry of Education and Science of the Russian Federation within the State Task for 2014-2016. . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
FERRIHYDRITE NANOPARTICLES
   BACTERIAL FERRIHYDRITE
   FERRITIN
   HYSTERESIS
   MOSSBAUER
   ORIGIN
Аннотация: The results of the investigation into the effect of low-temperature annealing of a powder of nanoparticles of bacterial ferrihydrite on its magnetic properties have been presented. It has been found that an increase in the time (up to 240 h) and temperature (in the range from 150 to 200°C) of annealing leads to a monotonic increase in the superparamagnetic blocking temperature, the coercive force, and the threshold field of the opening of the magnetic hysteresis loop (at liquid-helium temperatures), as well as to an increase in the magnetic resonance line width at low temperatures and in the magnetic susceptibility at room temperature. At the same time, according to the results of the analysis of the Mossbauer spectra, the annealing of ferrihydrite does not lead to the formation of new iron oxide phases. Most of these features are well consistent with the fact that the low-temperature annealing of ferrihydrite causes an increase in the size of nanoparticles, which is confirmed by the results of transmission electron microscopy studies. © 2016, Pleiades Publishing, Ltd.

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Публикация на русском языке Изменение магнитных свойств наноферригидрита в ходе низкотемпературного отжига, обусловленное ростом объeма наночастиц [Текст] / Д. А. Балаев [и др.] // Физ. тверд. тела : Физико-технический институт им. А. Ф. Иоффе РАН, 2016. - Т. 58 Вып. 9. - С. 1724–1732

Держатели документа:
Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50/38, Krasnoyarsk, Russian Federation
Siberian Federal University, Svobodny pr. 79, Krasnoyarsk, Russian Federation
International Scientific Centre for Organism Extreme States Research, Presidium of the Krasnoyarsk Scientific Centre of the Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk, Russian Federation
International Laboratory of High Magnetic Fields and Low Temperatures, ul. Gajowicka 95, Wroclaw, Poland

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Stolyar, S. V.; Столяр, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ladygina, V. P.; Yaroslavtsev, R. N.; Bayukov, O. A.; Баюков, Олег Артемьевич; Vorotynov, A. M.; Воротынов, Александр Михайлович; Volochaev, M. N.; Волочаев, Михаил Николаевич; Dubrovskiy, A. A.; Дубровский, Андрей Александрович
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CoC films sinthezited whis arabinogalactan / S. V. Stolyar, R. N. Yaroslavtsev, L. A. Chekanova [et al.] // Nanostructures: physics and technology : proc. 28th Int. symp. - 2020. - Ст. NT.19. - P. 105-106. - Cited References: 1 . - ISBN 978-5-93634-066-6

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Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Chekanova, L. A.; Чеканова, Лидия Александровна; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Cheremiskina, E. V.; Neznakhin, D. S.; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Nanostructures: Physics and Technology, International Symposium(28 ; 2020 ; 28 Sept.-2 Oct. ; Minsk, Belarus); Институт физики им. Б. И. Степанова НАН Беларуси; Санкт-Петербургский национальный исследовательский Академический университет Российской академии наук; Физико-технический институт им. А.Ф. Иоффе РАН; Научно-технологический центр микроэлектроники и субмикронных гетероструктур Российской академии наук
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Collective Spin Glass State in Nanoscale Particles of Ferrihydrite / S. V. Stolyar, R. N. Yaroslavtsev, V. P. Ladygina [et al.] // Semiconductors. - 2020. - Vol. 54, Is. 12. - P. 1710-1712DOI 10.1134/S1063782620120362. - Cited References: 16. - This work was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory, the Krasnoyarsk Regional Fund for the Support of Scientific and Technical Activities (project no. 19-42-240012 r_a “Magnetic resonance in ferrihydrite nanoparticles: Effects associated with the “core–shell” structure). This work was supported by a grant from the President of the Russian Federation for state support of young Russian scientists – candidates of sciences no. MK-1263.2020.3
Кл.слова (ненормированные):
nanoparticles -- ferrihydrite -- magnetic anisotropy -- magnetic resonance
Аннотация: Ferromagnetic resonance was used to study three types of ferrihydrite nanoparticles: nanoparticles formed as a result of the cultivation of microorganisms Klebsiella oxytoca; chemically prepared ferrihydrite nanoparticles; chemically prepared ferrihydrite nanoparticles doped with Cu. It is established from the ferromagnetic resonance data that the frequency-field dependence (in the temperature range ТP ‹ T ‹ T*) is described by the expression: 2πν/γ ⁼ НR + HA(T = 0)(1 – T/Т*), where γ is the gyromagnetic ratio, HR is the resonance field. The induced anisotropy HA is due to the spin-glass state of the near-surface regions. TP temperature characterizes the energy of the interparticle interaction of nanoparticles.

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Держатели документа:
Kirensky Institute of Physics, SB Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Krasnoyarsk Scientific Center, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Ladygina, V. P.; Balaev, D. A.; Балаев, Дмитрий Александрович; Pankrats, A. I.; Панкрац, Анатолий Иванович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; International Symposium “Nanostructures: Physics and Technology”(28th ; Sept 28 - Oct 2, 2020 ; Minsk, Republic of Belarus)
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10.

Effect of nanoparticles in growth of test - bacteria / S. V. Stolyar [et al.] // J. Phys. Conf. Ser. - 2019. - Vol. 1399. - Ст. 022029, DOI 10.1088/1742-6596/1399/2/022029. - Cited References: 10 . - ISSN 1742-6588. - ISSN 1742-6596
Рубрики:
Applied Physics
Аннотация: Confident effect of five magnetic composite nanoparticles (FeP@Ag, FeP@Pd, CoP, NiP, Fe2O3@AГ) on growth of test bacteria colonies (Acinetobacter baumannii, Еscherichia coli, Klebsiella pneumoniae, Pseudomonas aeruginosa, Staphylococcus aureus) in five replicates each is considered. Reliable inhibitors of colonies of all five test bacteria were nanoparticles FeP@Ag. CoP nanoparticles are reliable inhibitors of growth of 4 test bacteria (except for test bacteria Escherichia сoli). NiP nanoparticles are reliable inhibitors of growth of 2 test bacteria: Escherichia сoli and Klebsiella pneumoniae. Bacteria Escherichia сoli were most sensitive to the effect of magnetic nanoparticles; and bacteria Pseudomonas aeruginosa and Staphylococcus aureus were most resistant to the effect of magnetic nanoparticles. The prospects of the method are in the possibility of multiple reuse of the magnetic particles with antimicrobial properties for bacterial decontamination of the studied sources of water and removal of magnetic nanoparticles from the treated liquids by electromagnet. The method can find use in water treatment facilities for household, Industrial and medical wastes.

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Держатели документа:
Federal Research Center "Krasnoyarsk Science Center" of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, Akademgorodok, 50, Russia
Siberian Federal University, Krasnoyarsk, Svobodnyi pr., 79, Russia
Kirensky Institute of Physics, Krasnoyarsk, Akademgorodok, 50/38, Russia
Institute of Biophysics of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, Akademgorodok, 50/12, Russia

Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Chekanova, L. A.; Чеканова, Лидия Александровна; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Ladygina, V. P.; Tirranen, L. S.; International Scientific Conference "Conference on Applied Physics, Information Technologies and Engineering"(25-27 September 2019 ; Krasnoyarsk, Russian Federation)
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11.

Effect of sodium hypophosphite content to the deposition rate, structure and magnetic properties of electroless deposited Ni-P alloy / R. N. Yaroslavtsev [et al.] // Solid State Phenom. : Selected, peer reviewed papers. - 2014. - Vol. 215: Trends in Magnetism: Nanomagnetism (EASTMAG-2013). - P. 237-241, DOI 10.4028/www.scientific.net/SSP.215.237. - Cited References: 15 . - ISSN 978-30383. - ISSN 1662-9779
Кл.слова (ненормированные):
Electroless coatings -- Nickel-phosphorus alloy
Аннотация: The deposition kinetics, structure and magnetic properties of electroless deposited films Ni-P were investigated depending on the amount of sodium hypophosphite in the electroless bath. It was found that the film deposition rate is linear and unambiguously varies with the hypophosphite content from 2 to 13 g/l and from 23 to 25 g/l. The deposition rate varies widely in the hypophosphite concentration range from 13 to 23 g/l. The films are composed of amorphous Ni-P phase and fcc Ni-P solid solution with phosphorus content from 1 to 4 at.% P according to X-ray diffraction. The partial amount of amorphous phase is increased with concentration of sodium hypophosphite. The ferromagnetic resonance field is independent on the concentration of sodium hypophosphite, which assumes to be result from the laminated allocation of the amorphous and fcc phases in the film. © (2014) Trans Tech Publications, Switzerland.

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Доп.точки доступа:
Ovchinnikov, S. G. \ed.\; Овчинников, Сергей Геннадьевич; Samardak, A. \ed.\; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Chekanova, L. A.; Чеканова, Лидия Александровна; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism(5 ; 2013 ; sept. ; 15-21 ; Vladivostok)
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12.

Effect of the interparticle interactions on superparamagnetic relaxation / D. A. Balaev, S. V. Stolyar, A. A. Krasikov [et al.] // VIII Euro-Asian symposium "Trends in magnetism" (EASTMAG-2022) : Book of abstracts / program com. S. G. Ovchinnikov [et al.]. - 2022. - Vol. 1, Sect. : Magnetotransport, magnetooptics and magnetophotonics. - Ст. D.O11. - P. 437-438. - Cited References: 3. - This study was supported by the Russian Science Foundation, Project No. 21-72-00025 (https://rscf.ru/project/21-72-00025/) . - ISBN 978-5-94469-051-7

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia
Krasnoyarsk Scientific Center, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia

Доп.точки доступа:
Ovchinnikov, S. G. \program com.\; Овчинников, Сергей Геннадьевич; Balaev, D. A.; Балаев, Дмитрий Александрович; Stolyar, S. V.; Столяр, Сергей Викторович; Krasikov, A. A.; Красиков, Александр Александрович; Bayukov, O. A.; Баюков, Олег Артемьевич; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Knyazev, Yu. V.; Князев, Юрий Владимирович; Российская академия наук; Физико-технический институт им. Е.К. Завойского ФИЦ Казанского научного центра РАН; Казанский (Приволжский) федеральный университет; Euro-Asian Symposium "Trends in MAGnetism"(8 ; 2022 ; Aug. ; 22-26 ; Kazan); "Trends in MAGnetism", Euro-Asian Symposium(8 ; 2022 ; Aug. ; 22-26 ; Kazan)
}
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13.

Effect of ultrasonic treatment on magnetic ferrihydrite nanoparticles in a suspended state / S. V. Stolyar [et al.] // Bull. Russ. Acad. Sci. Phys. - 2017. - Vol. 81, Is. 5. - P. 608-611, DOI 10.3103/S1062873817050227. - Cited References: 11 . - ISSN 1062-8738
Кл.слова (ненормированные):
Nanoparticles -- Ultrasonic equipment -- Fe-ions -- Ferrihydrites -- Metal reduction -- Metal state -- Organic components -- Ssbauer spectroscopies -- Ultrasonic treatments -- Nanomagnetics
Аннотация: Dried sediments of magnetic ferrihydrite nanoparticles subjected to ultrasonic treatment in the cavitation mode are studied via Mossbauer spectroscopy. Fe ions are reduced to the metal state. In all experiments with detected metal reduction, the investigated suspensions contain organic components. © 2017, Allerton Press, Inc.

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Публикация на русском языке Влияние ультразвуковой обработки на магнитные наночастицы ферригидрита в суспензионном состоянии [Текст] / С. В. Столяр, О. А. Баюков, В. П. Ладыгина [и др.] // Изв. РАН. Сер. физич. - 2017. - Т. 81 № 5. - С. 660-663

Держатели документа:
Siberian Federal University, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
International Scientific Center for Studying the Extreme States of an Organism, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Bayukov, O. A.; Баюков, Олег Артемьевич; Ladygina, V. P.; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Yaroslavtsev, R. N.
}
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14.

Exchange bias in nano-ferrihydrite / D. A. Balaev [et al.] // J. Appl. Phys. - 2016. - Vol. 120, Is. 18. - Ст. 183903, DOI 10.1063/1.4967912. - Cited References: 43. - The authors are grateful to M. Volochaev for measurements and O. A. Bayukov for Mössbauer study. - This work was supported in part by the Ministry of Education and Science of the Russian Federation. . - ISSN 0021-8979
Кл.слова (ненормированные):
Anisotropy -- Cooling systems -- Hysteresis -- Magnetic fields -- Magnetic materials -- Magnetism -- Nanomagnetics -- Nanoparticles -- Particle size -- Characteristic value -- Exchange bias -- Exchange bias effects -- External magnetic field -- Field cooling -- High anisotropy -- Minor hysteresis loop -- Superparamagnetic blocking -- Hysteresis loops
Аннотация: We report the results of investigations of the effect of cooling in an external magnetic field starting from the temperature over superparamagnetic blocking temperature TB on the shift of magnetic hysteresis loops in systems of ferrihydrite nanoparticles from ∼2.5 to ∼5 nm in size with different TB values. In virtue of high anisotropy fields of ferrihydrite nanoparticles and open hysteresis loops in the range of experimentally attainable magnetic fields, the shape of hysteresis loops of such objects in the field-cooling mode is influenced by the minor hysteresis loop effect. A technique is proposed for distinguishing the exchange bias effect among the effects related to the minor hysteresis loops caused by high anisotropy fields of ferrihydrite particles. The exchange bias in ferrihydrite is stably observed for particles not less than 3 nm in size or with TB over 40 K, and its characteristic value increases with the particle size. © 2016 Author(s).

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Держатели документа:
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Presidium of Krasnoyarsk Scientific Center, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Popkov, S. I.; Попков, Сергей Иванович; Stolyar, S. V.; Столяр, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ladygina, V. P.; Yaroslavtsev, R. N.
}
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15.

Fe3O4/Au nanocomposites: Characterization and cytotoxicity effects in vitro / R. N. Yaroslavtsev, A. V. Tyumentseva, D. A. Velikanov [et al.] // Mater. Chem. Phys. - 2024. - Vol. 322. - Ст. 129524, DOI 10.1016/j.matchemphys.2024.129524. - Cited References: 44 . - ISSN 0254-0584. - ISSN 1879-3312
Кл.слова (ненормированные):
Magnetic nanoparticles -- Magnetite -- Gold nanoparticles -- Cytotoxicity
Аннотация: Magnetic nanocomposites containing iron oxide and gold components take great attention last years because of their relative biocompatibility and the ability to combine the magnetic properties of iron and the chemical bonding properties of gold for the possible drug delivery or diagnostics for various diseases. However, such particles have some toxicity to living cells, and the effect depends on many factors, including size, shape, the ratio of components in the composites, and the type of cells affected. And thus, the search for compositions and technologies for producing iron-gold particles with improved properties and reduced cytotoxicity remains relevant. The aim of the study was to synthesize and characterize Fe3O4/Au nanocomposites and evaluate their influence on living cells using the example of cell line HEK293. Fe3O4 nanoparticles (NPs) were synthesized by co-precipitation of Fe2+/Fe3+ water solution in alkaline conditions and then boiled with HAuCl4 in 0.1 M sodium citrate. The NPs properties were estimated by transmission electron microscopy (TEM), vibration magnetometry and ferromagnetic resonance (FMR). According to magnetometric measurements, nanoparticles are mainly in a superparamagnetic state. By fitting magnetization curves, the magnetic characteristics of nanoparticles were determined: saturation magnetization (59.3 emu/g) and magnetic anisotropy constant (K = 0.86·105 erg/cm3). The average particle size estimated from magnetic measurements was 8.7 nm. Considering the presence of a magnetically dead layer, this is in good agreement with the TEM results. The temperature dependence of the FMR linewidth was analyzed using two models. As a result, the parameters MSV and K/MS were determined. The models used showed good agreement. The values of the anisotropy constant (K = 1.06·105 erg/cm3) and the average particle size (6.8 nm) are estimated. The effect of the NPs on the HEK293 cells was studied by MTT-assay, flow cytometry and RT-PCR. The exposure with the NPs lead to a significant decrease of cell metabolic activity in HEK293 cell culture, but this effect was not accompanied by cell death. It was shown that the expression of antioxidant enzymes SOD1 and GPX1 was reduced at the mRNA stage. So the NPs synthesized may affect gene expression and metabolism of HEK293 cells, but this does not have fatal consequences for cell viability.

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Держатели документа:
Krasnoyarsk Science Center, Federal Research Center KSC SB RAS, Akademgorodok 50, Krasnoyarsk, 660036, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Akademgorodok 50, bld. 38, Krasnoyarsk, 660036, Russia

Доп.точки доступа:
Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Tyumentseva, A.V.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Vazhenina, I. G.; Важенина, Ирина Георгиевна; Volochaev, M. N.; Волочаев, Михаил Николаевич; Stolyar, S. V.; Столяр, Сергей Викторович
}
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16.

Ferrihydrite nanoparticles insights: Structural characterization, lactate dehydrogenase binding and virtual screening assay / C. G. Chilom, N. Sandu, M. Balasoiu [et al.] // Int. J. Biol. Macromol. - 2020. - Vol. 164. - P. 3559-3567, DOI 10.1016/j.ijbiomac.2020.08.242. - Cited References: 64. - The work was accomplished in the frame of JINR Themes 02-1-1107-2011/2021, 04-5-1131-2017/2021 and 04-4-1121-2015/2020 and with the financial support of the RO-JINR Projects Nos. 268/21.05.2020 items 8 and 77, and 269/21.05.2020 items 11 and – 80. MB acknowledges Dr. Alexander Kuklin for assistance for SANS measurements and fruitful discussions. The authors acknowledge Dr. George Stan of the National Institute of Materials Physics for facilitating the conduct of FTIR experiments . - ISSN 0141-8130
Кл.слова (ненормированные):
Ferrihydrite nanoparticles -- Lactate dehydrogenase -- Binding mechanism -- Energy transfer -- Thermodynamic fingerprint -- Virtual screening
Аннотация: The binding between the enzyme lactate dehydrogenase (LDH) and ferrihydrite nanoparticles (Fh-NPs) was investigated by means of small-angle neutron scattering (SANS), Fourier-transform infrared (FTIR) spectroscopy, fluorescence and Forster resonance energy transfer (FRET) and molecular docking. Fh-NPs - LDH compounds of dimensions under 100 nm are formed. The conformational changes and the mechanism of interaction between LDH and Fh-NPs simple and doped with Cu and Co, and the effect of these NPs on the thermal denaturation of LDH were monitored. The quenching mechanism is static, the binding occurring with moderate affinity, being mainly driven by hydrogen bonding and van der Waals forces. FRET occurs at a minimal distance of 2.55 nm. Thermal denaturation of LDH in the presence of simple and doped Fh-NPs shows that the thermodynamic parameters of protein unfolding are significantly changed with temperature. The denaturation temperature of LDH shifts to higher values in the presence of all Fh-NPs, than in the case of simple LDH. The docking approach estimates the energy corresponding to the best fit of the ferrihydrite in the LDH binding site near Trp. These results have direct implications on the uses of the complex of LDH with Fh-NPs in various biochemical, biological, or clinical applications.

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Держатели документа:
Faculty of Physics, University of Bucharest, Romania
Joint Institute for Nuclear Research, Dubna, Russian Federation
Moscow Institute of Physics and Technology, Dolgoprudniy, Russian Federation
“Horia Hulubei” National Institute of Physics and Nuclear Engineering, Magurele, Romania
Siberian Federal University, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, SB RAS, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Chilom, C. G.; Sandu, N.; Balasoiu, M.; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Stolyar, S. V.; Столяр, Сергей Викторович; Rogachev, A. V.
}
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17.

Ferrihydrite nanoparticles interaction with model lipid membranes. / C. G. Chilom [et al.] // Chem. Phys. Lipids. - 2020. - Vol. 226. - Ст. 104851, DOI 10.1016/j.chemphyslip.2019.104851. - Cited References: 70. - The work was accomplished with the financial support of the 2019 RO-JINR Project Investigation of biogenic and chemically synthesized systems in interaction with biostructures for applied research, Theme 02-1-1107-2011/2019 and of the Romanian National Authority for Scientific Research, CNDI-UEFISCDI, Project numbers: PN 18 09 02 02/2018 and PN 19 06 02 03/2019. The authors are very much indebted to Professor Dr. Aurel Popescu, for very helpful suggestions and permanent encouragement. . - ISSN 0009-3084. - ISSN 1873-2941
Кл.слова (ненормированные):
Ferrihydrite nanoparticles -- Morphology -- Laurdan -- TMA-DPH -- Membrane -- Fluidity
Аннотация: In recent years was observed an increased interest towards the use of metal nanoparticles for various biomedical applications, such as therapeutics, delivery systems or imaging. As biological membranes are the first structures with which the nanoparticles interact, it is necessary to understand better the mechanisms governing these interactions. In the present paper we aim to characterize the effect of three different ferrihydrite nanoparticles (simple or doped with cooper or cobalt) on the fluidity of model lipid membranes. First we evaluated the physicochemical properties of the nanoparticles: size and composition. Secondly, their effect on lipid membranes was also evaluated using Laurdan, TMA-DPH and DPH fluorescence. Our results can help better understand the mechanisms involved in nanoparticles and membrane interactions.

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Держатели документа:
Department of Electricity, Solid State and Biophysics, Faculty of Physics, University of Bucharest, Magurele, Romania
Department of Life and Environmental Physics, "Horia Hulubei" National Institute of Physics and Nuclear Engineering, Magurele, Romania
Department of Nuclear Physics, "Horia Hulubei" National Institute of Physics and Nuclear Engineering, Magurele, Romania
Joint Institute for Nuclear Research, Dubna, Russia
Moscow Institute of Physics and Technology, Dolgoprudniy, Russia
Siberian Federal University, Krasnoyarsk, Russia
Kirensky Institute of Physics, SB RAS, Krasnoyarsk, 660036, Russia

Доп.точки доступа:
Chilom, Claudia G.; Zorilă, Bogdan; Bacalum, M.; Bălăşoiu, Maria; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Stolyar, S. V.; Столяр, Сергей Викторович; Tyutyunnicov, Sergey
}
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18.

Ferrihydrite nanoparticles produced by chemical and biological methods / R. N. Yaroslavtsev [и др.] // International Baltic Conference on Magnetism (IBCM-2015) : book of abstracts. - 2015. - P. 96

Доп.точки доступа:
Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Stolyar, S. V.; Столяр, Сергей Викторович; Balaev, D. A.; Балаев, Дмитрий Александрович; Ladygina, V. P.; Bayukov, O. A.; Баюков, Олег Артемьевич; Iskhakov, R. S.; Исхаков, Рауф Садыкович; International Baltic Conference on Magnetism: Focus on Biomedical Aspects (2015 ; 30 Aug.-3 Sept. ; Svetlogorsk); Балтийский федеральный университет им. И. Канта
}
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19.

Ferrihydrite nanoparticles produced by Klebsiella oxytoca: Structure and properties dependence on the cultivation time / S. V. Stolyar, O. A. Bayukov, D. A. Balaev [et al.] // Adv. Powder Technol. - 2022. - Vol. 33, Is. 8. - Ст. 103692, DOI 10.1016/j.apt.2022.103692. - Cited References: 59. - This work was supported by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research projects No. 20-416-242907 . - ISSN 0921-8831
Кл.слова (ненормированные):
Ferrihydrite nanoparticles -- Structure -- Microbial synthesis -- Mössbauer spectroscopy -- Small-angle X-ray scattering
Аннотация: Ferrihydrite nanoparticles were synthesized using Klebsiella oxytoca microorganisms under various cultivation conditions. The cultivation of bacteria was carried out under various lighting conditions, and the duration of cultivation varied from 3 to 56 days. Biogenic ferrihydrite nanoparticles were studied by Mössbauer spectroscopy, magnetometry, and small-angle X-ray scattering. The process of formation of ferrihydrite nanoparticles and the states arising during the cultivation of microorganisms have been investigated. The results of Mössbauer spectroscopy showed that, depending on the time of cultivation, three different states of ferrihydrite can be realized. States differ both in the ratio of defective and non-defective positions, and the size of the particle. Experimental results indicate that ferrihydrite nanoparticles are a system of variable composition and pass through several structural (or morphological) states during the cultivation of microorganisms. A model of the structure of ferrihydrite nanoparticles is proposed, which consists in the presence of an antiferromagnetic dense core with a high Néel temperature and a friable shell with a significantly lower temperature of magnetic ordering.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Krasnoyarsk Scientific Center, Federal Research Center KSC SB RAS Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Joint Institute for Nuclear Research, Dubna, Russian Federation

Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Bayukov, O. A.; Баюков, Олег Артемьевич; Balaev, D. A.; Балаев, Дмитрий Александрович; Ladygina, V. P.; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Knyazev, Yu. V.; Князев, Юрий Владимирович; Balasoiu, M.; Kolenchukova, O. A.; Iskhakov, R. S.; Исхаков, Рауф Садыкович
}
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20.

Ferromagnetic resonance in iron tubes deposited on a copper grid / S. V. Stolyar, R. N. Yaroslavtsev, L. A. Chekanova [et al.] // J. Magn. Magn. Mater. - 2020. - Vol. 511. - Ст. 166979, DOI 10.1016/j.jmmm.2020.166979. - Cited References: 22. - This work was supported by Russian Foundation for Basic Research , Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project No. 18-42-240006. We are grateful to the Center of collective use of FRC KSC SB RAS for the provided equipment . - ISSN 0304-8853
Кл.слова (ненормированные):
Magnetic tubes -- Ferromagnetic resonance
Аннотация: In the work, a composite material, which is an iron coating on a copper microgrid with a mesh size of 50 μm, is investigated. Iron coatings were synthesized by electroless deposition using arabinogalactan as a reducing agent. Samples were investigated using transmission electron microscopy, Mossbauer spectroscopy and ferromagnetic resonance methods. Magnetic anisotropy in the grid plane was studied by measuring the FMR spectra. The results of the study are discussed by modeling the composite as a wireframe system of magnetic tubes.

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Держатели документа:
Krasnoyarsk Scientific Center, Federal Research Center KSC SB RAS Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Chekanova, L. A.; Чеканова, Лидия Александровна; Rautskii, M. V.; Рауцкий, Михаил Владимирович; Bayukov, O. A.; Баюков, Олег Артемьевич; Cheremiskina, E. V.; Nemtsev, I. V.; Немцев, Иван Васильевич; Volochaev, M. N.; Волочаев, Михаил Николаевич; Iskhakov, R. S.; Исхаков, Рауф Садыкович
}
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