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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Karpov S. V., Semina P. N.
Заглавие : On coagulation of polydisperse metal nanocolloids and conditions for applicability of the Muller-Smoluchowski theory
Место публикации : Colloid J.: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 74, Is. 3. - P.295-304. - ISSN 1061-933X, DOI 10.1134/S1061933X12030040
Примечания : Cited References: 15. - Authors are thankful to G. A. Chiganova and A. P. Gavrilyuk for discussions and helpful comments. Studies were carried out with the support of grants: the Presidium of RAS No 29 and No 31, OFN RAS III.9.5, IP SB RAS No 43, IP SB RAS (and SFU) No 101.
Аннотация: The regularities of the coagulation of metal nanocolloids with different degrees of polydispersity are studied by the Brownian dynamics method. The results of the numerical calculations of coagulation kinetics are compared with the conclusions of the Muller-Smoluchowski theory. It is revealed that these data deviate from the predictions of the theory upon a decrease in the viscosity of dispersion medium, an increase in the thickness of layers adsorbed on particles, and the combination of these factors. It is demonstrated that no acceleration of the colloid coagulation with a rise in the degree of polydispersity, which is predicted by the theory, takes place under these conditions.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Karpov S. V., Semina P. N., Gavrilyuk A. P.
Заглавие : The role of the electron tunneling effect in the coagulation kinetics of polydisperse metal nanocolloids
Место публикации : Colloid J.: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 74, Is. 3. - P.305-312. - ISSN 1061-933X, DOI 10.1134/S1061933X12030052
Примечания : Cited References: 16. - Authors are thankful to G. A. Chiganova for discussions and helpful comments. Studies were carried out with the support of grants: the Presidium of RAS No 29 and No 31, OFN RAS III.9.5, IP SB RAS No 43, IP SB RAS (and SFU) No 101.
Предметные рубрики: PARTICLES
Аннотация: The energy of pair interactions between metal nanoparticles of different sizes is shown to be able to increase upon coagulation due to the additional electrostatic effect resulting from mutual heteropolar charging of the particles. The tunnel electron transfer occurring upon the collisions between particles of different sizes may be the reason for the charging. The transfer is caused by the dependence of the electron work function on the particle size. The electron transfer through the interparticle gap equalizes the Fermi levels in particles of different sizes and is associated with this dependence. Using the example of bimodal silver nanocolloids, it is shown that mutual heteropolar charging of particles with different sizes may accelerate the coagulation of polydisperse colloidal systems by an order of magnitude or more as compared with monodisperse systems, in which this effect is absent.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gavrilyuk A. P., Gerasimov V. S., Ershov A. E., Karpov S. V.
Заглавие : Temperature dependent elastic repulsion of colloidal nanoparticles with a polymer adsorption layer
Коллективы : Russian Foundation for Basic Research; government of the Krasnoyarsk territory and Krasnoyarsk Regional Fund of Science [18-42-243023]; RF Ministry of Science and Education,; State contract with Siberian Federal University for scientific research in 2017-2019; SB RAS Program [II.2P (0358-2015-0010)]
Место публикации : Colloid Polym. Sci. - 2018. - Vol. 296, Is. 10. - P.1689-1697. - ISSN 0303-402X, DOI 10.1007/s00396-018-4383-y. - ISSN 1435-1536(eISSN)
Примечания : Cited References: 49. - The reported research was funded by the Russian Foundation for Basic Research, the government of the Krasnoyarsk territory and Krasnoyarsk Regional Fund of Science, grant 18-42-243023, the RF Ministry of Science and Education, the State contract with Siberian Federal University for scientific research in 2017-2019, and SB RAS Program No II.2P (0358-2015-0010).
Предметные рубрики: STERICALLY-STABILIZED PARTICLES
DEPLETION FLOCCULATION
AGGREGATION
Ключевые слова (''Своб.индексиров.''): nanoparticle--adsorption layer--elastic deformation--coagulation--kinetics--elasticity modulus
Аннотация: The model of pairwise elastic repulsion of contacting colloidal nanoparticles with a rigid core and deformable shell is discussed. A simple analytical equation is applied for the energy of elastic repulsion of nanoparticles with arbitrary sizes and the elasticity moduli of self-healing polymer adsorption layers. The model is based on the representation of the absorption layer as a continuous medium that is elastically deformed upon the contact of nanoparticles. The major characteristic of this medium is the elasticity modulus. The magnitude of the elasticity modulus is determined from the condition of balance of the van der Waals attractive forces of nanoparticles and the elastic repulsion of their adsorption layers in the contact area, taking into account the temperature variations. We employed the kinetic approach to describe the dependence of the elasticity modulus on both the temperature and the rate of its change.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gavrilyuk A. P., Isaev I. L., Gerasimov V. S., Karpov S. V.
Заглавие : Physical principles of the formation of a nanoparticle electric double layer in metal hydrosols
Место публикации : Colloid Polym. Sci. - 2020. - Vol. 298, Is. 1. - P.1-7. - ISSN 0303-402X, DOI 10.1007/s00396-019-04573-8. - ISSN 1435-1536 (eISSN)
Примечания : Cited References: 25. - The reported research was funded by the Russian Foundation for Basic Research and the government of the Krasnoyarsk territory, Krasnoyarsk Regional Fund of Science, grant No 18-42-243023, the RF Ministry of Education and Science, the State contract with Siberian Federal University for scientific research in 2017–2019.
Аннотация: The Brownian dynamics method is employed to study the formation of an electrical double layer (EDL) on the metal nanoparticle (NP) surface in hydrosols during adsorption of electrolyte ions from the interparticle medium. Also studied is the charge accumulation by NPs in the Stern layer. To simulate the process of the formation of EDL, we took into account the effect of image forces and specific adsorption, dissipative and random forces, and the degree of hydration of adsorbed ions on the EDL structure. The employed model makes it possible to determine the charge of NPs and the structure of EDL. For the first time, the charge of both the diffuse part of EDL and the dense Stern layer has been determined. A decrease in the electrolyte concentration (below c ˂ 0.1 mol/l) has been found to result in dramatic changes in the formation of the Stern layer.
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