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Laser processing of polymer films fabricated from phas differing in their monomer composition / T. G. Volova, A. I. Golubev, I. V. Nemtsev [и др.] // Биотехнология новых материалов - окружающая среда - качество жизни : материалы IV Международной научной конференция : Красноярск, 10–13 октября 2021 г. - Красноярск, 2021. - С. 51-54

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Доп.точки доступа:
Volova, T. G.; Волова, Татьяна Григорьевна; Golubev, A. I.; Голубев Алексей И.; Nemtsev, I. V.; Немцев, Иван Васильевич; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Dudaev, A. E.; Shishatskaya, E. I.; Шишацкая, Екатерина Игоревна; "Biotechnology of new materials - environment - quality of life", International scientific conference(4 ; 2021 ; Oct. ; Krasnoyarsk (on-line)); "Биотехнология новых материалов - окружающая среда - качество жизни", международная научная конференция(4 ; 2021 ; окт. ; Красноярск (on-line))
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The effect of the composition and pressure on the phase stability and electronic, magnetic, and elastic properties of M2AX (M = Mn, Fe; A = Al, Ga, Si, Ge; X = C, N) phases / V. S. Zhandun, N. G. Zamkova, O. N. Draganyuk [et al.] // Phys. Chem. Chem. Phys. - 2021. - Vol. 23, Is. 46. - P. 26376-26384, DOI 10.1039/d1cp03427h. - Cited References: 40. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science to the research project no. 20-42-240004: "The effect of the composition, pressure, and dimension on the magnetic, electronic, optical, and elastic properties of the magnetic Mn+1AXn (M = Cr, Mn; Fe, A = Al, Ga, Si, Ge, P, In; X = C, N; n = 1-3) MAX-phases'' and by the Government of the Russian Federation (agreement no. 075-152019-1886). The calculations were performed with the computer resources of "Complex modeling and data processing research installations of mega-class'' SRC "Kurchatovsky Institute'' (http://ckp.urcki.ru).The ternary phase diagrams for the calculation of formation enthalpies were taken from Materials Project (https://materialsproject.org).U.W.and M. F. also thank the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) -Project-ID 405553726 -TRR 270 for funding . - ISSN 1463-9076. - ISSN 1463-9084

РУБ Chemistry, Physical + Physics, Atomic, Molecular & Chemical
Рубрики:
MAX PHASE
Аннотация: The magnetic properties of M2AX (M = Mn, Fe; A = Al, Ga, Si, Ge; X = C, N) phases were studied within DFT-GGA. The magnetic electronic ground state is determined. The investigation of the phase stability of M2AX phases is performed by comparing the total energy of MAX phases to that of the set of competitive phases for calculation of the phase formation enthalpy. As the result of such an approach, we have found one stable compound (Mn2GaC), and seven metastable ones. It is shown that several metastable MAX phases (Mn2AlC, Fe2GaC, Mn2GeC, and Mn2GeN) become stable at a small applied pressure (1.5–7 GPa). The mechanical, electronic and elastic properties of metastable MAX phases are studied.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Univ Duisburg Essen, Fac Phys, D-47057 Duisburg, Germany.

Доп.точки доступа:
Zhandun, V. S.; Жандун, Вячеслав Сергеевич; Zamkova, N. G.; Замкова, Наталья Геннадьевна; Draganyuk, O. N.; Драганюк, Оксана Николаевна; Shinkorenko, A. S.; Шинкоренко, Алексей Сергеевич; Wiedwald, Ulf; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Farle, M.; Фарле, Михаель; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of Krasnoyarsk Territory; Krasnoyarsk Regional Fund of Science [20-42-240004]; Government of the Russian Federation [075-152019-1886]; Deutsche Forschungsgemeinschaft (DFG, German Research Foundation)German Research Foundation (DFG) [405553726 -TRR 270]
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Regulation of the phase transition temperature and hysteresis width by changing the composition of solid solution / K. N. Boldyrev, V. M. Burlakov, I. A. Gudim [et al.] // Phys. Rev. Mater. - 2021. - Vol. 5, Is. 9. - Ст. 094414, DOI 10.1103/PhysRevMaterials.5.094414. - Cited References: 52. - This work is supported by the Russian Science Foundation under Grant No. 19-12-00413 . - ISSN 2475-9953
Кл.слова (ненормированные):
Crystal impurities -- Electronic cooling -- Hysteresis -- Hysteresis loops -- Magnetic materials -- Magnetic storage -- Optical switches -- Rare earths -- Temperature -- Virtual storage -- F-f transitions -- Frequency shift -- Hysteresis widths -- Mixed crystals -- Optical spectrum -- Phase transition temperatures -- Rectangular hysteresis loop -- Structural phase transition -- Thermal hysteresis -- Transition hysteresis -- Solid solutions
Аннотация: A detailed study of the structural phase transition in Eu1–xLaxFe3(BO3)4 mixed crystals as a function of composition is reported. By analyzing a frequency shift of an electronic f-f transition in high-resolution optical spectra of Eu3+ ions, we detected a decrease in the phase transition temperature Ts from 87.05 to 12.2 K (upon cooling) and a simultaneous increase in thermal hysteresis ΔTs from 0.29 to 4.7 K with increasing x from x=0 to x=0.12. A rectangular hysteresis loop was observed. The experimental Ts(x) and ΔTs(x) dependences are described within the developed analytical model utilizing linear decrease in Ts with x and treating the increase in ΔTs in terms of the impurity-related decrease in the interaction between some local order parameters. We argue that R1−xR′xFe3(BO3)4 solid solutions, where R and R′ are different rare-earth elements, can be used to implement optical storage devices and switches operating at any chosen temperature between 0 and 450 K. It is found that the changes in the composition and, correspondingly, structural phase transition parameters do not affect the magnetic phase transformation. Eu0.88La0.12Fe3(BO3)4 demonstrates the structural phase transition at about 12 K, well below the Néel temperature TN=32K.

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Держатели документа:
Institute of Spectroscopy, Russian Academy of Sciences, Troitsk, Moscow, 108840, Russian Federation
Linacre College, University of Oxford, St Cross Road, Oxford, OX1 3JA, United Kingdom
Kirensky Institute of Physics, Siberian Branch of RAS, Krasnoyarsk, 660036, Russian Federation
Lebedev Physical Institute, Russian Academy of Sciences, Moscow, 119991, Russian Federation

Доп.точки доступа:
Boldyrev, K. N.; Burlakov, V. M.; Gudim, I. A.; Гудим, Ирина Анатольевна; Gavrilkin, S. Y.; Popova, M. N.
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    Magnetic properties of 3-d metal rods with gradients of composition produced by electroless deposition / E. A. Denisova, L. A. Chekanova, S. V. Komogortsev, R. S. Iskhakov // Trends in MAGnetism (TMAG2020). - 2021. -
   Перевод заглавия: Магнитные свойства стержней на основе металлов с градиентом состава, изготовленные методом химического осаждения

Материалы конференции,

Доп.точки доступа:
Denisova, E. A.; Денисова, Елена Александровна; Chekanova, L. A.; Чеканова, Лидия Александровна; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Trends in MAGnetism Conference(2021 ; Sept. ; 6-10 ; Palermo, Italy (hybrid format))
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Multicomponent flux growth and composition control of Cu2MnBO5:Ga ludwigites / E. Moshkina, A. Krylov, D. Kokh [et al.] // CrystEngComm. - 2022. - Vol. 24, Is. 19. - P. 3565-3575, DOI 10.1039/d2ce00258b. - Cited References: 26. - This study was supported by the Russian Science Foundation (Grant No. 21-72-00130). The Raman, X-ray, and EDX data were obtained using the analytical equipment of the Krasnoyarsk Regional Center of Research Equipment of the Federal Research Center “Krasnoyarsk Science Center SB RAS” . - ISSN 1466-8033
Кл.слова (ненормированные):
Bismuth compounds -- Boron compounds -- Copper compounds -- Crystal symmetry -- Energy dispersive spectroscopy -- Gallium -- Manganese oxide -- Positive ions -- Sodium compounds
Аннотация: To reach the concentration phase boundary between antiferromagnetic Cu2GaBO5 and ferrimagnetic Cu2MnBO5 ludwigites, solid solutions Cu2Mn1−xGaxBO5 (x = 0.05, 0.1, 0.15, 0.175) were grown by the flux technique using a multi-component solvent based on Bi2Mo3O12 with the addition of Na2B4O7 which significantly influenced the crystal formation and cation composition of the studied compounds. The content of the flux system was corrected taking into account the earlier established relationship of the partition coefficients of Mn2O3 and Ga2O3. The influence of the solvent components on the ludwigite crystallization was analyzed. The maximum size of the grown crystal was 1 × 1 × 4 mm3. The structure and cation composition of the grown compounds were studied using X-ray (X-ray diffraction, EDX (energy-dispersive X-ray spectroscopy)) and vibrational (Raman) spectroscopy techniques. The phase boundary of Cu2MnBO5–Cu2GaBO5 was found to be in the concentration range of x = 0.15–0.175, corresponding to a change in the monoclinic axis direction and a leap in the lattice parameters. The symmetry evolution of metal–oxygen octahedra for four nonequivalent cation positions was analyzed, and the unique crystal structure of Cu2MnBO5 demonstrated high rigidity relative to the introduction of Ga3+ cations. The polarized Raman spectra of monoclinic ludwigites were obtained and studied for the first time. A comparison of the spectra of the studied samples in both phases and orthorhombic ludwigites was made. A number of spectral features due to the monoclinic distortions in the crystal were found. In agreement with the Raman experiment, the concentration phase boundary was close to 0.15.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian State University of Science and Technologies, Krasnoyarsk, 660037, Russian Federation
Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
St Petersburg University, St Petersburg, 199034, Russian Federation

Доп.точки доступа:
Moshkina, E. M.; Мошкина, Евгения Михайловна; Krylov, A. S.; Крылов, Александр Сергеевич; Kokh, D.; Shabanova, K.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bovina, A. F.; Бовина, Ася Федоровна; Plyaskin, M.; Пляскин, Михаил Е.; Rostovtsev, N.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
}
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Magnetic properties of three-dimensional metal rods with composition gradients produced by electroless deposition / E. A. Denisova, L. A. Chekanova, S. V. Komogortsev [et al.] // IEEE Magn. Lett. - 2022. - Vol. 13. - Ст. 6103405, DOI 10.1109/LMAG.2022.3163015. - Cited References: 30. - This work was supported in part by the Russian Foundation for Basic Research (RFBR), Krasnoyarsk Territory and in part by the Krasnoyarsk Regional Fund of Science under Grant 20-43-240003. The authors thank the Center of Collective Use of the Federal Research Center Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences for the equipment. Sergey V. Komogortsev thank the RFBR, Krasnoyarsk Region and the Krasnoyarsk Regional Science Foundation (Project 20-42-240001) for the support in the contribution of numerical simulation. The authors also thank V. S. Plotnikov and V. V. Tkachev for electron microscopy images . - ISSN 1949-307X
Кл.слова (ненормированные):
nanomagnetics -- rods with gradients of composition -- electroless deposition -- coercivity -- magnetic anisotropy
Аннотация: A comparative study of the magnetic properties of arrays of Co–Ni rods with different composition gradients (smooth or step-like) along the rod axes was carried out. Ordered arrays of Co–Ni nanorods with diameters up to 400 nm and 8 µm length were prepared by electroless plating into a porous nuclear-track-etched polycarbonate membrane. The gradient in Co and Ni composition was confirmed by energy-dispersive X-ray analysis. The variation of Co–Ni contents along the long axis of the rods correlates with the gradient of the magnetization within the rod. Magnetization reversal was studied by analyzing the angular dependence of coercivity and using micromagnetic simulations. For both types of gradient rods, reversal occurs by curling. The local magnetic anisotropy field of rods with a step-type gradient is significantly higher than that for rods with a smooth gradient.

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Держатели документа:
Federal Research Center Ksc Sb Ras, Kirensky Institute Of Physics, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Reshetnev Siberian State University Of Science And Technology, Krasnoyarsk, 660037, Russian Federation
Federal Research Center Ksc Sb Ras, Krasnoyarsk Scientific Center, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Denisova, E. A.; Денисова, Елена Александровна; Chekanova, L. A.; Чеканова, Лидия Александровна; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Satsuk, S. A.; Сацук, Светлана Александровна; Nemtsev, I. V.; Немцев, Иван Васильевич; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Semenov, S. V.; Семёнов, Сергей Васильевич
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Influence of chemical composition and thermomechanical treatment of low-carbon steels on the microstructure and mechanical properties of their laser welded joints / A. I. Gordienko, A. G. Malikov, M. N. Volochaev, A. D. Panyukhina // Mater. Sci. Eng. A. - 2022. - Vol. 839. - Ст. 142845, DOI 10.1016/j.msea.2022.142845. - Cited References: 38. - Microstructural studies and mechanical tests of laser welds were performed according to the Government research assignment for ISPMS SB RAS, project FWRW-2021-0009. Part of the research related to the selection of optimal laser welding parameters for low carbon steels was carried out within Basic State Project No. 121030900259-0 . - ISSN 0921-5093. - ISSN 1873-4936

РУБ Nanoscience & Nanotechnology + Materials Science, Multidisciplinary + Metallurgy & Metallurgical Engineering
Рубрики:
AUSTENITE GRAIN-SIZE
HEAT-AFFECTED ZONE
MARTENSITE START TEMPERATURE
Кл.слова (ненормированные):
Low-carbon steels -- Laser welding -- Cross-helical rolling -- Weld metal -- Microstructure -- Microhardness
Аннотация: The paper reports microstructures (revealed by transmission electron microscopy) in various zones of laser welds of the X70 and X80 low-carbon steels with different initial microstructures, as well as chemical and phase compositions. In the X70 steels with 0.13% C, the microstructure refinement has been achieved through helical rolling at temperatures of 920 °C and 850 °C (designated as X70-920 and X70-850, respectively). For all studied cases, both initial steel microstructures and phase compositions have determined the formation of different microstructures with various microhardness levels in the weld metal and heat-affected zones. For the X70-850 steel with a more dispersed and homogeneous microstructure (dF = 3.3 μm), a lower microhardness level of 340 HV has been observed in the weld metal, compared with the X70-920 one (dF = 5.5 μm, 370 HV). The reason has been the formation of both bainite and martensite laths in the X70-850 weld metal, while only lath and lamellar martensite has formed in the X70-920 one. For the X80 steel (0.55% C), lowering the carbon content and additional microalloying with chromium, molybdenum and nickel have enabled to decrease the microhardness level down to 295 HV in the weld metal due to the degenerate upper bainite formation and the carbon level reduction in martensite. The dispersed and homogeneous initial microstructures of the X70-850 and X80 steels has provided the formation of granular ferrite-bainite microstructures in the intercritical heat-affected zone. They have possessed a lower proportion of residual austenite regions and small sizes of twinned martensite areas. The welded X80 steel specimen has been characterized by higher ductile properties compared to both X70 ones.

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Держатели документа:
Russian Acad Sci, Inst Strength Phys & Mat Sci, Siberian Branch, 2-4 Pr Akad Skii, Tomsk 634055, Russia.
Russian Acad Sci, Khristianovich Inst Theoret & Appl Mech, Siberian Branch, 4-1 Inst Skaya Str, Novosibirsk 630090, Russia.
Russian Acad Sci SB RAS, Kirensky Inst Phys, Siberian Branch, Akademgorodok 50,Bld 38, Krasnoyarsk 660036, Russia.
Reshetnev Siberian State Univ Sci & Technol, 31 Pr Krasnoyarsk Worker, Krasnoyarsk 660037, Russia.
Tomsk Polytech Univ, 30 Lenin Ave, Tomsk 634050, Russia.

Доп.точки доступа:
Gordienko, A., I; Malikov, A. G.; Volochaev, M. N.; Волочаев, Михаил Николаевич; Panyukhina, A. D.; [FWRW-2021-0009]; [121030900259-0]
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    Magnesium Boride Nanotubes: Relative Stability and Atomic and Electronic Structure / P. B. Sorokin [et al.] // J. Phys. Chem. C. - 2010. - Vol. 114, Is. 11. - P. 4852-4856, DOI 10.1021/jp9112014. - Cited Reference Count: 38. - Гранты: P.B.S. and B.I.Y. acknowledge support by the Basic Energy Sciences division of the Department of Energy, award DE-SC0001479. L.A.C. was supported by the Russian Academy of Sciences, program No. 21. P.V.A ad P.B.S. also acknowledge the collaborative RFBR-JSPS grant No. 09-02-92107-R Phi. We are grateful to the Joint Supercomputer Center of the Russian Academy of Sciences for the possibility of using a cluster computer for quantum chemical calculations. The geometry of all presented structures was visualized by commercial ChemCraft software (http://www.chemcraftprog.com). - Финансирующая организация: Basic Energy Sciences division of the Department of Energy [DE-SC0001479]; Russian Academy of Sciences [21]; RFBR-JSPS [09-02-92107-RPhi] . - MAR 25. - ISSN 1932-7447
Рубрики:
BORON
   PSEUDOPOTENTIALS
   FULLERENES
   SIMULATION
   FORM
Кл.слова (ненормированные):
Basic composition -- Bending behavior -- Comparative studies -- Diborides -- Energy analysis -- Energy minima -- Magnesium atom -- Magnesium boride -- MgB2 -- Relative stabilities -- Semiconducting behavior -- Small-diameter -- Staggered configuration -- Sub-lattices -- Bending (forming) -- Borides -- Boron -- Electronic properties -- Electronic structure -- Energy management -- Magnesium -- Nanotubes -- Density functional theory
Аннотация: A comparative study of file energies and the electronic structure of MgBx nanotubes is performed within the framework of the density functional theory. Different basic compositions (x = 2 for diboride and x = 3 for triboride) and different diameters (3 angstrom < D < 18 angstrom), as well the exterior, interior, and staggered placement of magnesium atoms, are considered. Energy analysis reveals a nontrivial bending behavior of the MgB2 sheets. such that the tubes with exterior and staggered configurations display the energy minima at certain small diameters (of the boron cage sublattice). The semiconducting behavior of narrow MgB2 nanotubes with exterior Mg position was observed.

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Держатели документа:
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Rice Univ, Dept Mech Engn & Mat Sci, Houston, TX 77251 USA
Rice Univ, Dept Chem, Houston, TX 77251 USA
Russian Acad Sci, Emanuel Inst Biochem Phys, Moscow 119334, Russia
Russian Acad Sci, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Sorokin, P. B.; Avramov, P.V.; Yakobson, B.I.; Chernozatonskii, L.A.
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Properties of degradable polyhydroxyalkanoates (PHAs) synthesized by a new strain, Cupriavidus necator IBP/SFU-1, from various carbon sources / N. O. Zhila, K. Yu. Sapozhnikova, E. G. Kiselev [et al.] // Polymers. - 2021. - Vol. 13, Is. 18. - Ст. 3142, DOI 10.3390/polym13183142. - Cited References: 78. - This work was financially supported by Project “Agropreparations of the new generation: a strategy of construction and realization” (Agreement No 075-15-2021-626) in accordance with Resolution No 220 of the Government of the Russian Federation of 9 April 2010, “On measures designed to attract leading scientists to the Russian institutions of higher learning” (strain isolation, polymer synthesis and investigation), and by the State Assignment of the Ministry of Science and Higher Education of the Russian Federation No. FSRZ-2020-0006 (study of film properties) . - ISSN 2073-4360
Кл.слова (ненормированные):
Cupriavidus necator IBP/SFU-1 -- cell growth and PHA synthesis -- various carbon sources -- PHA composition and properties -- polymer films
Аннотация: The bacterial strain isolated from soil was identified as Cupriavidus necator IBP/SFU-1 and investigated as a PHA producer. The strain was found to be able to grow and synthesize PHAs under autotrophic conditions and showed a broad organotrophic potential towards different carbon sources: sugars, glycerol, fatty acids, and plant oils. The highest cell concentrations (7–8 g/L) and PHA contents were produced from oleic acid (78%), fructose, glucose, and palm oil (over 80%). The type of the carbon source influenced the PHA chemical composition and properties: when grown on oleic acid, the strain synthesized the P(3HB-co-3HV) copolymer; on plant oils, the P(3HB-co-3HV-co-3HHx) terpolymer, and on the other substrates, the P(3HB) homopolymer. The type of the carbon source influenced molecular-weight properties of PHAs: P(3HB) synthesized under autotrophic growth conditions, from CO2, had the highest number-average (290 ± 15 kDa) and weight-average (850 ± 25 kDa) molecular weights and the lowest polydispersity (2.9 ± 0.2); polymers synthesized from organic carbon sources showed increased polydispersity and reduced molecular weight. The carbon source was not found to affect the degree of crystallinity and thermal properties of the PHAs. The type of the carbon source determined not only PHA composition and molecular weight but also surface microstructure and porosity of the polymer films. The new strain can be recommended as a promising P(3HB) producer from palm oil, oleic acid, and sugars (fructose and glucose) and as a producer of P(3HB-co-3HV) from oleic acid and P(3HB-co-3HV-co-3HHx) from palm oil.

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Держатели документа:
Basic Department of Biotechnology, School of Fundamental Biology and Biotechnology, Siberian Federal University, 79 Svobodnyi Av., Krasnoyarsk, 660041, Russian Federation
Federal Research Center, “Krasnoyarsk Science Center SB RAS”, Institute of Biophysics SB RAS, 50/50 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Federal Research Center, “Krasnoyarsk Science Center SB RAS”, L.V. Kirensky Institute of Physics SB RAS, 50/38 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Federal Research Center, “Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences”, 50 Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Zhila, N. O.; Sapozhnikova, K. Yu.; Kiselev, E. G.; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Nemtsev, I. V.; Немцев, Иван Васильевич; Shishatskaya, E. I.; Volova, T. G.
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10.

    Исследование микроструктурных особенностей, фазового состава и магнитных свойств композитов на основе YBCO и добавок несверхпроводящего компонента СuО, полученного в плазме дугового разряда низкого давления / И. В. Карпов, А. В. Ушаков, А. А. Лепешев [и др.] // Материаловедение. - 2020. - № 6. - С. 27-32, DOI 10.31044/1684-579X-2020-0-6-27-32. - Библиогр.: 12 . - ISSN 1684-579X
   Перевод заглавия: Investigation of microstructural features, phase composition and magnetic properties of YBCO-based composites and additives of nonsuperconducting component cuo obtained in low-pressure arc plasma
Кл.слова (ненормированные):
плазма дугового разряда низкого давления -- нанопорошок CuO -- центры пиннинга -- высокотемпературный сверхпроводник -- low-pressure arc plasma -- CuO nanopowder -- Pinning center -- high-temperature superconductor
Аннотация: Разработан метод, позволяющий формировать на поверхности дисперсных частиц порошка ВТСП-керамики несверхпроводящего покрытия, состоящего из самоорганизующихся кристаллов CuO, размеры которых менее длины когерентности, т.е. в пределах нескольких десятков нанометров. Показано, что сочетание самоорганизующихся структур в виде «усов» и наночастиц, появляющихся в результате совместного спекания порошков YBa2Cu3O7-x и электродуговых нанопорошков CuO, приводит к существенному увеличению плотности тока и появлению пик-эффекта в области сильных магнитных полей. Очень высокая плотность тока возникает из сложного пиннинга вихрей, где дефекты в виде «усов» обеспечивают большую энергию пиннинга, а наночастицы подавляют крип потока. Регулирование морфологии подобных структур возможно простым изменением концентрации нанодисперсных добавок. Показано, что наиболее оптимальной является добавка CuO в количестве 20% (мас.).
A method has been developed, that allows one to form a non-superconducting coating on the surface of dispersed particles of an HTSC ceramic powder consisting of self-organizing CuO crystals whose sizes are less than the coherence length, i.e. within a few tens of nanometers. It was found out that the combination of self-organizing structures in the form of «whiskers» and nanoparticles resulting from the joint sintering of YBa2Cu3O7-x powders and CuO nanocrystals led to a significant increase in current density and the appearance of a peak effect in the region of strong magnetic fields. A very high current density arises from complex pinning of vortices, where defects in the form of «whiskers» provide a large pinning energy, and nanoparticles suppress creep flux. Morphology of such structures can be regulated by a simple change in the concentration of nanodispersed additives. It was determined that the addition of CuO in an amount of 20 wt.% was the most optimal.

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Переводная версия Investigation of microstructural features, phase composition, and magnetic characteristics of YBCO-based composites and additives of CuO non-superconducting component prepared in low-pressure arc discharge plasma [Текст] / I. V. Karpov, A. V. Ushakov, A. A. Lepeshev [et al.] // Inorg. Mater.: Appl. Res. - 2021. - Vol. 12 Is. 1.- P.142-146

Держатели документа:
Институт физики им. Л. В. Киренского СО РАН
Сибирский федеральный университет
Федеральный исследовательский центр «Красноярский научный центр Сибирского отделения РАН»

Доп.точки доступа:
Карпов, И. В.; Ушаков, А. В.; Лепешев, Анатолий Александрович; Дёмин, В. Г.; Федоров, Л. Ю.; Гончарова, Е. А.; Зеер, Г. М.; Жарков, Сергей Михайлович; Zharkov, S. M.; Абкарян, А. К.
}
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11.

Investigation of microstructural features, phase composition, and magnetic characteristics of YBCO-based composites and additives of CuO non-superconducting component prepared in low-pressure arc discharge plasma / I. V. Karpov, A. V. Ushakov, A. A. Lepeshev [et al.] // Inorg. Mater.: Appl. Res. - 2021. - Vol. 12, Is. 1. - P. 142-146, DOI 10.1134/S2075113321010172. - Cited References: 12. - This work was supported by the Russian Science Foundation (project no. 16-19-10054) . - ISSN 2075-1133
Кл.слова (ненормированные):
low-pressure arc discharge plasma -- CuO nanopowder -- pinning centers -- high-temperature superconductor
Аннотация: A method making it possible to form HTS ceramics of non-superconducting coating consisting of self-organizing CuO crystals, whose sizes are less than the coherence length, i.e., within several tens of nanometers, has been developed. It has been shown that the combination of self-organizing structures in the form of whiskers and nanoparticles which arise as a result of combined sintering of YBa2Cu3O(7–x) powders and electric arc CuO nanopowders results in a significant increase in the current density and appearance of peak effect at high magnetic fields. Very high current density arises from the complex vortex pinning, where whisker defects provide high pinning energy and nanoparticles suppress flux creep. The morphology of such structures can be controlled by a simple change in the concentration of nanodisperse additives. It has been shown that 20 wt % of CuO additive is optimal.

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Публикация на русском языке Исследование микроструктурных особенностей, фазового состава и магнитных свойств композитов на основе YBCO и добавок несверхпроводящего компонента СuО, полученного в плазме дугового разряда низкого давления [Текст] / И. В. Карпов, А. В. Ушаков, А. А. Лепешев [и др.] // Материаловедение. - 2020. - № 6. - С. 27-32

Держатели документа:
Federal Research Center, Krasnoyarsk Research Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Kirensky Institute of Physics, Subdivision of Federal Research Center, Krasnoyarsk Research Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Karpov, I. V.; Ushakov, A. V.; Lepeshev, A. A.; Demin, V. G.; Fedorov, L. Y.; Goncharova, E. A.; Zeer, G. M.; Zharkov, S. M.; Жарков, Сергей Михайлович; Akbaryan, A. K.
}
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12.

Composition-driven crystal structure transformation and magnetic properties of electrodeposited Co–W alloy nanowires / E. Yoo, A. Y. Samardak, Y. S. Jeon [et al.] // J. Alloys Compd. - 2020. - Vol. 843. - Ст. 155902, DOI 10.1016/j.jallcom.2020.155902. - Cited References: 48. - This study was supported by the Samsung Research Funding & Incubation Center of Samsung Electronics under Project Number SRFC-TA1703-06, and by the Russian Ministry of Science and Higher Education under the state task (0657 -2020-0013), by Act 211 of the Government of the Russian Federation (02.A03.21.0011). . - ISSN 0925-8388
Кл.слова (ненормированные):
Co–W alloy -- Nanowire -- Electrodeposition -- Crystal structure -- Electrodeposition -- First-order reversal curve
Аннотация: The cobalt (Co)–tungsten (W) alloys exhibit unique combinations of mechanical and magnetic properties, biocompatibility, resistance against corrosion, wear, and high-temperature, which makes them desirable materials for various practical applications. A nanoporous template with incorporated Co–W alloy nanowires is a soft magnetic composite, whose dielectric and magnetic properties can be tuned through the host material, pore distribution and size, Co–W composition and crystal structure, and geometry of the nanowires. Here, we report the composition-dependent structural and magnetic properties of Co–W alloy nanowires embedded in alumina templates by electrodeposition. The addition of W transforms cobalt from the crystalline hexagonal-close-packed (hcp) Co to a mixed nanocrystalline/amorphous-like Co(W) solid solution with ferromagnetic behavior and composition similar to that of the weakly magnetic Co3W compound. The combination of the approach to magnetic saturation, anisotropy field distribution method, micromagnetic simulations, and first-order reversal curve diagram identification method elucidates the structure-driven magnetization reversal processes in both individual nanowires and magnetostatically coupled array as a whole.

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Держатели документа:
Department of Materials Science and Engineering, Korea University, Seoul, 02841, South Korea
School of Natural Sciences, Far Eastern Federal University, Vladivostok, 690950, Russian Federation
National Research South Ural State University, Chelyabinsk, 454080, Russian Federation
Institute of Physics, SB Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Yoo, E.; Samardak, A. Y.; Jeon, Y. S.; Samardak, A. S.; Ognev, A. V.; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Kim, Y. K.
}
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13.

    Composition Graded Materials With Different Spatial Distribution / E. A. Denisova, L. A. Chekanova, S. V. Komogortsev [et al.] // 65th Annual conference on мagnetism and мagnetic мaterials (MMM-2020) : abstract book. - 2020. - Ст. G6-12. - P. 210. - Cited references: 2
   Перевод заглавия: Высоко-индукционные пленки FeCo: Зеленый синтез и магнитные свойства

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Доп.точки доступа:
Denisova, E. A.; Денисова, Елена Александровна; Chekanova, L. A.; Чеканова, Лидия Александровна; Nemtsev, I. V.; Немцев, Иван Васильевич; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Shepeta, N. A.; Kuzovnikova, L. A.; Кузовникова, Людмила Александровна; Annual conference on мagnetism and мagnetic мaterials(65 ; 2020 ; 2-6 Nov. ; Virtual Conference)
}
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14.

Laser processing of polymer films fabricated from phas differing in their monomer composition / T. G. Volova, A. I. Golubev, I. V. Nemtsev [et al.] // Polymers. - 2021. - Vol. 13, Is. 10. - Ст. 1553, DOI 10.3390/polym13101553. - Cited References: 87. - This work was supported by the Russian Foundation for Basic Research/Regional State Autonomous Institution “Krasnoyarsk Regional Fund for the Support of Scientific and Scientific-Technical Activities” foundations under Grant number 19-43-240012 (laser treatment and films properties) and by the State Assignment of the Ministry of Science and Higher Education of the Russian Federation No. FSRZ-2020-0006 (polymer synthesis) . - ISSN 2073-4360
Кл.слова (ненормированные):
P(3HB) -- copolymers -- films -- CO2 laser -- SEM -- AFM -- water contact angles -- MTT assay -- NIH 3T3 fibroblasts
Аннотация: The study reports results of using a CO2-laser in continuous wave (3 W; 2 m/s) and quasi-pulsed (13.5 W; 1 m/s) modes to treat films prepared by solvent casting technique from four types of polyhydroxyalkanoates (PHAs), namely poly-3-hydroxybutyrate and three copolymers of 3-hydroxybutyrate: with 4-hydroxybutyrate, 3-hydroxyvalerate, and 3-hydroxyhexanoate (each second monomer constituting about 30 mol.%). The PHAs differed in their thermal and molecular weight properties and degree of crystallinity. Pristine films differed in porosity, hydrophilicity, and roughness parameters. The two modes of laser treatment altered these parameters and biocompatibility in diverse ways. Films of P(3HB) had water contact angle and surface energy of 92° and 30.8 mN/m, respectively, and average roughness of 144 nm. The water contact angle of copolymer films decreased to 80–56° and surface energy and roughness increased to 41–57 mN/m and 172–290 nm, respectively. Treatment in either mode resulted in different modifications of the films, depending on their composition and irradiation mode. Laser-treated P(3HB) films exhibited a decrease in water contact angle, which was more considerable after the treatment in the quasi-pulsed mode. Roughness parameters were changed by the treatment in both modes. Continuous wave line-by-line irradiation caused formation of sintered grooves on the film surface, which exhibited some change in water contact angle (76–80°) and reduced roughness parameters (to 40–45 mN/m) for most films. Treatment in the quasi-pulsed raster mode resulted in the formation of pits with no pronounced sintered regions on the film surface, a more considerably decreased water contact angle (to 67–76°), and increased roughness of most specimens. Colorimetric assay for assessing cell metabolic activity (MTT) in NIH 3T3 mouse fibroblast culture showed that the number of fibroblasts on the films treated in the continuous wave mode was somewhat lower; treatment in quasi-pulsed radiation mode caused an increase in the number of viable cells by a factor of 1.26 to 1.76, depending on PHA composition. This is an important result, offering an opportunity of targeted surface modification of PHA products aimed at preventing or facilitating cell attachment.

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Держатели документа:
Basic Department of Biotechnology, School of Fundamental Biology and Biotechnology, Siberian Federal University, 79 Svobodnyi Av, Krasnoyarsk, 660041, Russian Federation
Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/50 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
L.V. Kirensky Institute of Physics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/38 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Special Design and Technological Bureau ‘Nauka’ Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/45 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Federal Research Center “Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences”, 50 Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Volova, T. G.; Golubev, A. I.; Голубев Алексей И.; Nemtsev, I. V.; Немцев, Иван Васильевич; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Dudaev, A. E.; Shishatskaya, E. I.
}
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15.

The effect of composition and pressure on phase stability and properties of magnetic M2AX (M = Mn, Fe; A=Al, Ga, Si, Ge; X=C, N) phases / V. S. Zhandun, N. G. Zamkova, O. N. Draganyuk [et al.] // International workshop on the properties of functional MAX-materials (2nd FunMax) : book of abstracts / org. com. M. Farle [et al.]. - 2021. - P. 24

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Доп.точки доступа:
Farle, M. \org. com.\; Ovchinnikov, S. G. \org. com.\; Овчинников, Сергей Геннадьевич; Tarasov, A. S. \org. com.\; Тарасов, Антон Сергеевич; Smolyarova, T. E. \org. com.\; Смолярова, Татьяна Евгеньевна; Zhandun, V. S.; Жандун, Вячеслав Сергеевич; Zamkova, N. G.; Замкова, Наталья Геннадьевна; Draganyuk, O. N.; Драганюк, Оксана Николаевна; Shinkorenko, A. S.; Шинкоренко, Алексей Сергеевич; Wiedwald, U.; Ovchinnikov, S. G.; Farle, M.; Фарле, Михаель; International workshop on functional MAX-materials(2 ; 2021 ; Sept. 14-17 ; Krasnoyarsk (on-line)); Kirensky Institute of Physics; Siberian Federal Univercity
}
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16.

The dynamics of the amino acid composition of the medium in cultivating the isolated organs by controlled perfusion (Russian) / V. A. Barashkov [и др.] // Byulleten Eksperimentalnoi Biologii i Meditsiny. - 1975. - Vol. 80, Is. 7. - С. 36-38 . - ISSN 0365-9615

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Держатели документа:
L.V. Kirensky Inst. Phys., Siberian Branch, USSR Acad. Sci., Krasnoyarsk, Russia

Доп.точки доступа:
Barashkov, V. A.; Gitelzon, I. I.; Гительзон, Иосиф Исаевич; Nefedov, V. P.; Нефедов, Владимир Прокопьевич; Trubachev, I. N.; Трубачев, Иван Николаевич
}
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17.

Properties of degradable polyhydroxyalkanoates with different monomer compositions / T. Volova, E. Kiselev, I. Nemtsev [et al.] // Int. J. Biol. Macromol. - 2021. - Vol. 182. - P. 98-114, DOI 10.1016/j.ijbiomac.2021.04.008. - Cited References: 109. - The part of the reported study on polymer synthesis and examination was funded by RFBR and KKRF [Grant No. 19-43-240012 “Biological and physical principles of production of new generation biomaterials”]. The work on production and investigation of polymer films was carried out as part of the State Assignment of the Ministry of Education and Science of the Russian Federation [Grant No. FSRZ-2020-0006] . - ISSN 0141-8130
Кл.слова (ненормированные):
Physicochemical properties -- Chemical composition -- Physicochemical properties -- Films -- Microstructure -- Surface properties
Аннотация: Purpose: To synthesize and investigate polyhydroxyalkanoates (PHAs) with different monomer composition and percentages and polymer films prepared from them. Results: Various PHAs: homopolymer poly-3-hydroxybutyrate P(3HB) and 2-, 3-, and 4-component copolymers comprising various combinations of 3-hydroxybutyrate (3HB), 3-hydroxyvalerate (3HV), 4-hydroxybutyrate (4HB), and 3-hydroxyhexanoate (3HHx) monomers were synthesized under specialized conditions. Relationships were found between the monomer composition of PHAs and their molecular-weight and thermal properties and degree of crystallinity. All copolymers had decreased weight average molecular weights, Mw (to 390–600 kDa), and increased values of polydispersity (3.2–4.6) compared to the P(3HB). PHA copolymers showed different thermal behavior: an insignificant decrease in Tmelt and the presence of the second peak in the melting region and changes in parameters of crystallization and glass transition. At the same time, they retained thermostability, and the difference between Tmelt and Tdegr was at least 100–120 °C. Incorporation of 4HB, 3HV, and 3HHx monomer units into the 3-hydroxybutyrate chain caused changes in the amorphous to crystalline ratio and decreased the degree of crystallinity (Cx) to 20–40%. According to the degree to which the monomers reduced crystallinity, they were ranked as follows: 4HB – 3HHx – 3HV. A unique set of films was produced; their surface properties and physical/mechanical properties were studied as dependent on PHA composition; monomers other than 3-hydroxybutyrate were found to enhance hydrophilicity, surface development, and elasticity of polymer films. Conclusion: An innovative set of PHA copolymers was synthesized and solution-cast films were prepared from them; the copolymers and films were investigated as dependent on polymer chemical composition. Results obtained in the present study contribute to the solution of a critical issue of producing degradable polymer materials.

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Держатели документа:
Siberian Federal University, 79 Svobodnyi av., Krasnoyarsk, 660041, Russian Federation
Institute of Biophysics SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/50 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
L.V. Kirensky Institute of Physics, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/12 Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Volova, T.; Kiselev, E.; Nemtsev, I. V.; Немцев, Иван Васильевич; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Sukovatyi, A.; Kuzmin, A.; Ryltseva, G.; Shishatskaya, E.
}
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18.

Structure and properties of multiferroic ferroborates of mixed composition SmFe3-xAlx(BO3)4 and Eu1-yLayFe3(BO3)4 / K. V. Frolov, E. S. Smirnova, E. V. Sidorova [et al.] // Book of abstacts of Samarkand International Symposium on Magnetism (SISM-2023) / int. adv. com. S. G. Ovchinnikov [et al.]. - 2023. - Ст. 3PO-L8-3. - P. 195. - Cited References: 6. - РНФ 23-22-00286 . - ISBN 978-5-00202-320-2

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Держатели документа:
Kirensky Institute of Physics SB RAS

Доп.точки доступа:
Ovchinnikov, S. G. \int. adv. com.\; Овчинников, Сергей Геннадьевич; Frolov, K. V.; Smirnova, E. S.; Sidorova, E. V.; Alekseeva, O. A.; Sorokin, T. A.; Artemov, V. V.; Chmelenin, D. N.; Gudim, I. A.; Гудим, Ирина Анатольевна; Samarkand International Symposium on Magnetism(2023 ; July 2-6 ; Samarkand); Samarkand State University
}
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19.

    Titova, V. R.
    Influence of melt-solution composition on the properties of NdSc3(BO3)4 single crystals / V. R. Titova, I. A. Gudim // XV Cимпозиум с международным участием "Термодинамика и материаловедение" : тез. докладов. - Новосибирск, 2023. - P. 238, DOI 10.26902/THERM_2023_228. - Библиогр.: 1. - РНФ № 22-12-20019 ; Красноярский региональный фонд науки . - ISBN 978-5-901688-27-4
   Перевод заглавия: Влияние состава раствора-расплава на свойства монокристаллов NdSc3(BO3)4

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Держатели документа:
Институт физики им. Л.В. Киренского СО РАН
Институт неорганической химии им. А. В. Николаева СО РАН

Доп.точки доступа:
Gudim, I. A.; Гудим, Ирина Анатольевна; "Термодинамика и материаловедение", симпозиум с международным участием(15 ; 2023 ; 3-7 июля ; Новосибирск); Российское химическое общество им. Д.И. МенделееваНаучный совет РАН по физической химии; Институт неорганической химии им. А.В. Николаева Сибирского отделения РАН; Институт химии твердого тела УрО РАН; Институт химии силикатов им. И. В. Гребенщикова РАН
}
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20.

Composition, morphology, properties of coal fly ash microspheres and their application for conditioning liquid radioactive waste / N. N. Anshits [et al.] // International Journal of Nuclear Energy Science and Technology. - 2006. - Т. 2, № 1-2. - С. 8-24 . - ISSN 1741-6361. - ISSN 1741-637X

ГРНТИ

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Держатели документа:
Federal State Unitary Enterprize ‘Mining Chemical Combine’ (MCC)
G.K. Boreskov’s Institute of Catalysis SB RAS (IC SB RAS)
Institute of Chemistry and Chemical Technology,SB RAS (ICCT SB RAS)
L.B. Kirenskii Institute of Physics SB RAS (IP SB RAS)
Доп.точки доступа:
Anshits, N. N. ; Аншиц, Наталья Николаевна; Salanov, A. N.; Vereshchagina, T. A.; Kruchek, D. M.; Bayukov, O. A.; Баюков, Олег Артемьевич; Tretyakov, A. A.; Revenko, Y. A.; Anshits, A. G.; Аншиц, Александр Георгиевич
}
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