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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Thomas S., V R., Maria H. J., Kiselev E. G., Nemtsev I. V.
Заглавие : Biodegradable microcarriers for herbicide delivery
Коллективы : "Biotechnology of new materials - environment - quality of life", International scientific conference, "Биотехнология новых материалов - окружающая среда - качество жизни", международная научная конференция, Сибирский федеральный университет
Место публикации : Биотехнология новых материалов - окружающая среда - качество жизни: материалы IV Международной научной конференция : Красноярск, 10–13 октября 2021 г. - Красноярск, 2021. - С. 156-159
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Nasluzov V. A., Rivanenkov V. V., Gordienko A. B., Neyman K. M., Birkenheuer U., Rosch N.
Заглавие : Cluster embedding in an elastic polarizable environment: Density functional study of Pd atoms adsorbed at oxygen vacancies of MgO(001)
Место публикации : J. Chem. Phys.: AMER INST PHYSICS, 2001. - Vol. 115, Is. 17. - P8157-8171. - ISSN 0021-9606, DOI 10.1063/1.1407001
Примечания : Cited References: 88
Предметные рубрики: TRANSITION-METAL ATOMS
AB-INITIO
OXIDE SURFACES
ELECTRONIC-PROPERTIES
ENERGY CALCULATIONS
MOLECULAR-DYNAMICS
MOTT-LITTLETON
MADELUNG FIELD
IONIC-CRYSTAL
MGO
Ключевые слова (''Своб.индексиров.''): atoms--binding energy--computer simulation--electron energy levels--electronic structure--magnesia--oxygen--palladium--polarization--probability density function--quantum theory--relaxation processes--charged defects--cluster embedding--elastic polarizable environment--electron affinity--oxygen vacancies--adsorption
Аннотация: Adsorption complexes of palladium atoms on F-s, F-s(+), F-s(2+), and O2- centers of MgO(001) surface have been investigated with a gradient-corrected (Becke-Perdew) density functional method applied to embedded cluster models. This study presents the first application of a self-consistent hybrid quantum mechanical/molecular mechanical embedding approach where the defect-induced distortions are treated variationally and the environment is allowed to react on perturbations of a reference configuration describing the regular surface. The cluster models are embedded in an elastic polarizable environment which is described at the atomistic level using a shell model treatment of ionic polarizabilities. The frontier region that separates the quantum mechanical cluster and the classical environment is represented by pseudopotential centers without basis functions. Accounting in this way for the relaxation of the electronic structure of the adsorption complex results in energy corrections of 1.9 and 5.3 eV for electron affinities of the charged defects F-s(+) and F-s(2+), respectively, as compared to models with a bulk-terminated geometry. The relaxation increases the stability of the adsorption complex Pd/F-s by 0.4 eV and decreases the stability of the complex Pd/F-s(2+) by 1.0 eV, but it only weakly affects the binding energy of Pd/F-s(+). The calculations provide no indication that the metal species is oxidized, not even for the most electron deficient complex Pd/F-s(2+). The binding energy of the complex Pd/O2- is calculated at -1.4 eV, that of the complex Pd/F-s(2+) at -1.3 eV. The complexes Pd/F-s and Pd/F-s(+) exhibit notably higher binding energies, -2.5 and -4.0 eV, respectively; in these complexes, a covalent polar adsorption bond is formed, accompanied by donation of electronic density to the Pd 5s orbital. (C) 2001 American Institute of Physics.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Draganyuk O. N., Zhandun V. S., Zamkova N. G.
Заглавие : Effect of the Local Environment on the Magnetic Properties of Mn3Si: Hybrid Ab Initio and Model Study
Место публикации : Phys. Status Solidi B. - 2019. - Vol. 256, Is. 12. - Ст.1900228. - ISSN 03701972 (ISSN), DOI 10.1002/pssb.201900228
Примечания : Cited References: 34. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science to the research Project No. 18‐42‐243019: “First‐principles studies of the polarization, magnetic, electronic, and magnetoelectric properties of functional compounds with a spinel structure containing 3d and 4f ions.”
Аннотация: The effect of the local environment on the formation of magnetic moments on Mn atoms in manganese silicide Mn3Si is studied by the combination of ab initio calculations and the model analysis. The suggested approach is related to the self-consistent mapping of the results of ab initio calculations to a multiorbital model. The model analysis allows to reveal the role played by the local environment of the transition metal atoms on the magnetic moments formation. It is found that the formation of the magnetic moment is controlled rather by hopping parameters between Mn atoms, not by the number of Mn–Si nearest neighbors. Particularly, the formation of magnetic moment on MnI atom is mainly controlled by the hopping parameter between nearest Mn atoms, while the magnetic moment on MnII atom is primarily determined by the hoppings between next-nearest Mn atoms. The obtained phase diagrams of the magnetic state show the presence of a sharp boundary with respect to the hopping between Mn atoms. This opens the opportunity to turn on or turn off the magnetic state by the external impacts. The ab initio calculations of Mn3Si well agree with the results of model consideration and confirm the model conclusions.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gao H., Molokeev M. S., Chen Q., Yang X., Wang X., Ma B.
Заглавие : Effect of ligand environment of rare-earth ions on temperature measurement performance of SrAO4:xEu3+ (A = Mo and W) phosphors
Место публикации : Ceram. Int. - 2022. - Vol. 48, Is. 24. - P.36835-36844. - ISSN 02728842 (ISSN), DOI 10.1016/j.ceramint.2022.08.247
Примечания : Cited References: 58. - This work was supported by the National Natural Science Foundation of China (Grant No. 51802172) and the Natural Science Foundation of Qinghai Province (Grant No. 2021-ZJ-713)
Аннотация: Molybdate and tungstate with scheelite-type structure are excellent self-luminescent materials, which can be used as ideal hosts for the doping of rare-earth ions. In this study, a series of Eu3+-activated SrAO4 (A = Mo and W) phosphors were successfully synthesized, and their crystal structures, photoluminescence properties, and temperature measurement performance were analyzed in detail. These phosphors were excited by UV light (291 nm and 247 nm, respectively), with clear energy transfer (ET) (MoO42−→Eu3+ or WO42−→Eu3+). According to fluorescence intensity ratio (FIR) and Judd–Ofelt (J–O) theory, compared to SrWO4:0.01Eu3+ phosphor, SrMoO4:0.01Eu3+ phosphor exhibited better thermal stability, with relatively low Sa value (maximum values were 5.082 %K−1 and 20.74 %K−1, respectively), and their Sr values were not significantly different (maximum values were 0.864 %K−1 and 0.83 %K−1, respectively). Sa value was negatively correlated to central asymmetry of Eu3+, but the optimal Sr value tended to be more suitable for central asymmetry of Eu3+. In addition, Eu3+ exhibited stronger central asymmetry as well as covalency of Eu–O bond in SrMoO4. Results reveal that SrMoO4:xEu3+ and SrWO4:xEu3+ can be used for luminescent thermometers.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ershov A. E., Gavrilyuk A. P., Karpov S. V., Semina P. N.
Заглавие : Effect of local environment in resonant domains of polydisperse plasmonic nanoparticle aggregates on optodynamic processes in pulsed laser fields
Коллективы : Russian Academy of Sciences [24.29, 24.31, III.9.5, 43, SB RAS-SFU (101), 3-9-5]
Место публикации : Chin. Phys. B: IOP Publishing, 2015. - Vol. 24, Is. 4. - Ст.047804. - ISSN 1674, DOI 10.1088/1674-1056/24/4/047804. - ISSN 17414199(eISSN)
Примечания : Cited References:25. - Project supported by the Russian Academy of Sciences (Grant Nos. 24.29, 24.31, III.9.5, 43, SB RAS-SFU (101), and 3-9-5).
Предметные рубрики: METAL NANOPARTICLES
GOLD NANOPARTICLES
OPTICAL-PROPERTIES
Ключевые слова (''Своб.индексиров.''): nanoparticle--surface plasmon--colloid aggregate--optodynamics
Аннотация: Interactions of pulsed laser radiation with resonance domains of multiparticle colloidal aggregates having an increasingly complex local environment are studied via an optodynamic model. The model is applied to the simplest configurations, such as single particles, dimers, and trimers consisting of mono- and polydisperse Ag nanoparticles. We analyze how the local environment and the associated local field enhancement by surrounding particles affect the optodynamic processes in domains, including their photomodification and optical properties.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zamkova N. G., Zhandun V. S., Ovchinnikov S. G., Sandalov I. S.
Заглавие : Effect of local environment on moment formation in iron silicides
Место публикации : J. Alloys Compd.: Elsevier, 2017. - Vol. 695. - P.1213-1222. - ISSN 09258388 (ISSN), DOI 10.1016/j.jallcom.2016.10.248
Примечания : Cited References: 40. - This work was supported by the Grants of Russian Foundation for Basic Research № 14-02-00186, № 17-02-00161 and by the Grants of Russian Foundation for Basic Research and Government of Krasnoyarsk Territory № 16-42-243035, 16-42-242036. The authors would like to thank AS Shinkorenko for the technical support.
Ключевые слова (''Своб.индексиров.''): ab initio calculations--iron silicides--magnetic properties--multiorbital model--spin-crossover
Аннотация: he effect of local environment on the formation of magnetic moments on Fe atoms in iron silicides is studied by combination of ab initio and model calculations. The suggested model includes all Fe d- and Si p-orbitals, intra-atomic Coulomb interactions, inter-atomic Fe-Fe exchange and hopping of electrons to nearest and next nearest neighboring atoms. The parameters of the model are found from the requirement that self-consistent moments on atoms and density of states found from ab initio and model calculations within the Hartree-Fock approximation are close to each other as much as possible. Contrary to the commonly accepted statement that in the ordered Fe3Si and FexSi1−x alloys an increase of the Si concentration within nearest environment of Fe atoms results in a decrease of Fe magnetic moment we find that a crucial role in the formation of magnetic moments is played by the second coordination sphere of Fe atoms. Particularly, the Fe atoms have higher magnetic moments in amorphous films compared to the epitaxial ones due to decreasing the number of iron-atoms in the next nearest environment. Both our model and ab initio calculations confirm existence of known spin crossover with pressure and predict second crossover at higher pressure.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Yakushkin S. S., Balaev D. A., Dubrovskiy A. A., Semenov S. V., Shaikhutdinov K. A., Kazakova M. A., Bukhtiyarova G. A., Martyanov O. N., Bayukov O. A.
Заглавие : Evolution of the Fe3+ ion local environment during the phase transition ε-Fe2O3 → α-Fe2O3
Место публикации : J. Supercond. Nov. Magn. - 2018. - Vol. 31, Is. 4. - P.1209–1217. - ISSN 15571939 (ISSN), DOI 10.1007/s10948-017-4307-y
Примечания : Cited References: 37. - The work was supported by the Russian Science Foundation (Grant No. 17-12-01111).
Ключевые слова (''Своб.индексиров.''): ε−fe2o3 iron oxide nanoparticles--phase transition--structure size effect--magnetic properties--mossbauer spectroscopy
Аннотация: Evolution of the local environment of Fe3+ ions in deposited Fe2O3/SiO2 nanoparticles formed in samples with different iron contents was investigated in order to establish the conditions for obtaining the stable ε-Fe2O3/SiO2 samples without impurities of other iron oxide polymorphs. Microstructure of the samples with an iron content of up to 16% is studied by high-resolution transmission electron microscopy, X-ray diffraction analysis, and Mössbauer spectroscopy, and their magnetic properties are examined. At iron concentrations below 6%, calcinations of iron-containing precursor nanoparticles in a silica gel matrix lead to the formation of the ε-Fe2O3 iron oxide polymorphic modification without foreign phase impurities, while at the iron concentration in the range of 6–12%, the hematite phase forms in the sample in the fraction of no more than 5%. It is concluded on the basis of the data obtained that the spatial stabilization of iron-containing particles is one of the main factors facilitating the formation of the ε-Fe2O3 phase in a silica gel matrix without other iron oxide polymorphs. It is demonstrated that the increase in the iron content leads to the formation of larger particles in the sample and gradual changes of the Fe3+ ion local environment during the phase transition ε-Fe2O3 → α-Fe2O3.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zeyliger A. M., Muzalevskiy K. V., Zinchenko E. V., Ermolaeva O. S.
Заглавие : Field test of the surface soil moisture mapping using Sentinel-1 radar data
Место публикации : Sci. Total Environ. - 2022. - Vol. 807, Part 2. - Ст.151121. - ISSN 00489697 (ISSN), DOI 10.1016/j.scitotenv.2021.151121
Примечания : Cited References: 43. - The research was performed within the framework of the Russian Foundation for Basic Research project 19-29-05261 mk “Cartographic modelling of soil moisture reserves based on complex geophysical water content measurements for digital irrigated agriculture”
Аннотация: Soil surface moisture is one of the key parameters for describing the hydrological state and assessing the potential availability of water for irrigated plants. Because the radar backscattering coefficient is sensitive to soil moisture, the application of Sentinel-1 data may support soil surface moisture mapping at high spatial resolution by detecting spatial and temporal changes at the field scale for precision irrigation management. This mapping is required to control soil water erosion and preferential water flow to improve irrigation water efficiency and minimise negative impacts on surface and ground water bodies. Direct observations of soil surface moisture (5-cm thickness) were performed at an experimental plot in the study site of the All-Russian Scientific Research Institute of Irrigated Agriculture, near the village Vodnyy, Volgograd region. Soil surface moisture retrieval from Sentinel-1 was performed at the same location. A second set of soil surface moisture was calculated for the soil sampling sites using the permittivity model, based on the estimates of soil surface characteristics: a) reflectivity, obtained by the neural network method from Sentinel-1 observations; b) roughness, obtained from the geodata of the stereoscopic survey with unmanned aerial vehicle Phantom 4 Pro. The raster set of soil surface moisture geodata was obtained based on the reflectivity geodata raster set to solve the inverse problem using a permittivity model that considers the soil texture of the experimental plot. The determination coefficient (0.948) and standard deviation (2.04%) were obtained by comparing both sets of soil moisture point geodata taken from the same soil sampling sites. The values confirmed a satisfactory linear correlation between the directly measured and indirectly modelled sets. A comparison of the two sets of geodata indicated a satisfactory reproduction of the first set by the second set. As a result, the developed method can be considered as the scientific and methodological basis of the new technology of soil surface moisture monitoring by radar, which is one of the basic characteristics used in precision irrigation management.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Wigneron J. -P., Chanzy A., Kerr Y. H., Shi J. -C., Mironov V. L., de Rosnay, Escorihuela M. -J., Cano A., Demontoux F., Grant J., Lawrence H., Mialon A., Saleh H.
Заглавие : Improved parameterisation of the soil emission in L-MEB
Коллективы : Microwave Radiometry and Remote Sensing of the Environment, specialist Meeting on
Место публикации : MicroRad: March 11-14, 2008, Firenze, Italy : proceedings. - 2008. - С. 123-128
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovnev N. N., Molokeev M. S., Samoilo A. S., Atuchin V. V.
Заглавие : Influence of alkyl substituents in 1,3-diethyl-2-thiobarbituric acid on the coordination environment in M(H2O)2(1,3-diethyl-2-thiobarbiturate)2 M = Ca2+, Sr2+
Место публикации : J. Coord. Chem.: Taylor & Francis, 2016. - Vol. 69, Is. 6. - P.957-965. - ISSN 00958972 (ISSN), DOI 10.1080/00958972.2016.1149168
Примечания : Cited References: 42. - The study was carried out within the public task of the Ministry of Education and Science of the Russian Federation for research engineering of the Siberian Federal University in 2015-2016. V.V.A. is grateful to the Ministry of Education and Science of the Russian Federation for the financial support of the investigation.
Предметные рубрики: CRYSTAL-STRUCTURE
2-THIOBARBITURIC ACID
STRUCTURAL-CHARACTERIZATION
THIOBARBITURIC ACID
THERMAL-PROPERTIES
HYDROGEN-BOND
COMPLEXES
DIFFRACTION
NETWORKS
POLYMERS
Ключевые слова (''Своб.индексиров.''): 1,3-diethyl-2-thiobarbituric acid--alkaline earth metals--coordination compound--x-ray diffraction--thermal analysis
Аннотация: Two new isostructural complexes, [Ca(H2O)2(μ2-Detba-O,O′)2]n (1) and [Sr(H2O)2(μ2-Detba-O,O′)2]n (2) (HDetba = 1,3-diethyl-2-thiobarbituric acid), were synthesized and characterized by single-crystal and powder X-ray diffraction analysis, TG-DSC, FT-IR, and emission spectroscopy. The single-crystal X-ray diffraction data revealed that 1 and 2 are polymeric where M2+ (M = Ca, Sr) is a six-coordinate octahedral binding four Detba− ions and two water molecules. The octahedra are linked through bridging Detba− ions forming a 2-D layer. Two intermolecular hydrogen bonds O–H…S in the crystal form a 3-D net. The comparison of M(Detba)2 and M(Htba)2 (H2tba = 2-thiobarbituric acid) structures showed that the coordination number of metals in M(Detba)2 does not exceed six and there are no π–π interactions, unlike compounds with Htba−; Detba− ions are only bridges in HDetba coordination compounds. Thermal decomposition of 1 and 2 includes dehydration, which mainly ends at 200 °C, and organic ligand oxidation at 300–350 °C with a release of CO2, SO2, H2O, NH3, and isocyanate. Upon excitation at 220 nm, 1 and 2 exhibit an intense emission maximum at 557 nm.
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11.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Bukhanov E. R., Shikhov V. N., Lipshin A. G., Velichko V. V., Surin N. A.
Заглавие : Influence of growth environment on structural and optical characteristics of barley
Коллективы : International conference on photonics research
Место публикации : IV International conference on photonics research (Interphotonics 2022): book of abstracts/ International conference on photonics research (4 ; 2022 ; Apr. 22-28 ; Oludeniz, Turkey). - 2022. - Ст.Id-611. - P.13
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bukhanov E. R., Shikhov V. N., Velichko V. V., Lipshin A. G., Surin N. A.
Заглавие : Influence of growth environment on structural and optical characteristics of higher plants
Колич.характеристики :5 с
Коллективы : International Advances in Applied Physics and Materials Science Congress and Exhibition
Место публикации : AIP Conf. Proc. - 2024. - Vol. 2924: Proceedings of the 3rd International Advances in Applied Physics and Materials Science Congress & Exhibition, Is. 1. - Ст.040003. - ISSN 0094243X (ISSN), DOI 10.1063/5.0181655. - ISSN 15517616 (eISSN). - ISSN 978-073544852-0 (ISBN)
Примечания : Cited References: 26
Аннотация: Two barley samples were taken for the study – one grown in the field and the other in a special chamber under intensive light. Chloroplasts structure was obtained during electron microscopy process. The results showed that the maximum quantum yield of photosystem II in both samples was in the range of values typical for normal physiological state of plants. At the same time, electron transport speed comparison shows that electrons are transferred 1.7 times faster in the vegetation chamber compared to field environment. Such difference is confirmed by the results of microscopy performed with flag leaves tissue samples of barley grown under intensive light in a chamber and in the field. A grana structure significantly denser and better organized was observed in chloroplasts of barley grown in chamber. This study shows a clear connection between the environment, the ordering of thylakoid structures and fluorescent indicators of photosynthesis.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Gnatchenko S. L., Kachur I. S., Piryatinskaya V. G., Sukhachev A. L., Temerov V. L.
Заглавие : Influence of magnetic ordering on electronic structure of Tb3+ ion in TbFe3(BO3)(4) crystal
Разночтения заглавия :авие SCOPUS: Influence of magnetic ordering on electronic structure of Tb 3+ ion in TbFe 3(BO 3) 4 crystal
Место публикации : Eur. Phys. J. B: SPRINGER, 2011. - Vol. 80, Is. 1. - P1-10. - ISSN 1434-6028, DOI 10.1140/epjb/e2011-10806-x
Примечания : Cited References: 28. - The work was supported by the Russian Foundation for Basic Researches grant No. 09-02-00171-a, and by OFN RAS Program 2.3.3.1.
Ключевые слова (''Своб.индексиров.''): abrupt change--absorption lines--crystal-field splitting--equilibrium geometries--exchange fields--excited electronic state--external magnetic field--ion environment--local environments--magnetic ordering--magnetic ordering temperatures--magnetically ordered state--optical absorption spectrum--singlet state--structural phase transition--sub-lattices--temperature intervals--temperature variation--absorption--crystal orientation--electric excitation--electronic structure--ground state--ions--light absorption--magnetic fields--magnetic moments--excited states
Аннотация: Optical absorption spectra of trigonal crystal TbFe3(BO3)(4) have been studied in the region of F-7(6) - D-5(4) transition in Tb3+ ion depending on temperature (2-220 K) and on magnetic field (0-60 kOe). Splitting of the Tb3+ excited states, both under the influence of the external magnetic field and effective exchange field of the Fe-sublattice, have been determined. Land, factors of the excited states have been found. Stepwise splitting of one of the absorption lines has been discovered in the region of the Fe-sublattice magnetic ordering temperature. This is shown to be due to the abrupt change of equilibrium geometry of the local Tb3+ ion environment only in the excited state of the Tb3+ ion. In general, the magnetic ordering is accompanied by temperature variations of the Tb3+ local environment in the excited states. The crystal field splitting components have been identified. In particular, it has been shown that the ground state (in D (3) symmetry approximation) consists of two close singlet states of A (1) and A (2) type, which are split and magnetized by effective exchange field of the Fe-sublattice. Orientations of magnetic moments of the excited electronic states relative to that of the ground state have been experimentally determined in the magnetically ordered state of the crystal. A pronounced shift of one of absorption lines has been observed in the vicinity of the TbFe3(BO3)(4) structural phase transition. The temperature interval of coexistence of the phases is about 3 K.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Lamonova K.V., Zhitlukhina E.S., Babkin R.Y., Orel S.M., Pashkevich Y.G., Ovchinnikov S. G.
Заглавие : Intermediate-spin state of a 3D ion in the octahedral environment and generalization of the Tanabe - Sugano diagrams
Место публикации : The Journal of Physical Chemistry A (Dynamics, Kinetics, Environmental Chemistry, Spectroscopy, Structure, Theory): American Chemical Society, 2011. - Т. 115, № 46. - С. 13596-13604. - ISSN 1089-5639, DOI 10.1021/jp2071265. - ISSN 1520-5215(eissn)
РИНЦ
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15.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Lawrence H., Demontoux F., Wigneron J.-P., Mialon A., Tzong-Dar Wu., Mironov V. L., Liang Chen, Jianchen Shi, Kerr Y
Заглавие : L-Band Emission of Rough Surfaces: Comparison between Ex perimental Data and Different Modeling Approaches
Коллективы : Microwave Radiometry and Remote Sensing of the Environment, specialist Meeting on
Место публикации : 11th Specialist Meeting on Microwave Radiometry and Remote Sensing of the Environment, MicroRad 2010: Proceedings. - 2010. - С. 27–32
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16.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Volova T. G., Golubev A. I., Nemtsev I. V., Lukyanenko A. V., Dudaev A. E., Shishatskaya E. I.
Заглавие : Laser processing of polymer films fabricated from phas differing in their monomer composition
Коллективы : "Biotechnology of new materials - environment - quality of life", International scientific conference, "Биотехнология новых материалов - окружающая среда - качество жизни", международная научная конференция
Место публикации : Биотехнология новых материалов - окружающая среда - качество жизни: материалы IV Международной научной конференция : Красноярск, 10–13 октября 2021 г. - Красноярск, 2021. - С. 51-54
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Lobach K. A., Ovchinnikov S. G., Ovchinnikova T. M.
Заглавие : Specific features of insulator-metal transitions under high pressure in crystals with spin crossovers of 3d ions in tetrahedral environment
Коллективы : program for supporting leading scientific schools [NSh-2886.2014.2], Presidium of the Russian Academy of Sciences [2.16]
Место публикации : J. Exp. Theor. Phys.: MAIK Nauka-Interperiodica / Springer, 2015. - Vol. 120, Is. 1. - P.132-138. - ISSN 1063, DOI 10.1134/S1063776115010045. - ISSN 10906509(eISSN)
Примечания : Cited References:13. - This work was supported by the program for supporting leading scientific schools (project no. NSh-2886.2014.2) and by the Presidium of the Russian Academy of Sciences within program no. 2.16.
Аннотация: For Mott insulators with tetrahedral environment, the effective Hubbard parameter U eff is obtained as a function of pressure. This function is not universal. For crystals with d 5 configuration, the spin crossover suppresses electron correlations, while for d 4 configurations, the parameter U eff increases after a spin crossover. For d 2 and d 7 configurations, U eff increases with pressure in the high-spin (HS) state and is saturated after the spin crossover. Characteristic features of the insulator-metal transition are considered as pressure increases; it is shown that there may exist cascades of several transitions for various configurations.
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18.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Krylova S. N., Krylov A. S., Senkovska I., Kaskel S., Slysareva E. A., Vtyurin A. N.
Заглавие : Low-wavenumber vibrational spectroscopy study of the metal-organic frameworks DUT-8
Коллективы : Royal Society of Chemistry, MOFs for energy and the environment Faraday Discussion
Место публикации : MOFs for energy and the environment: Faraday discussion. - 2021. - Ст.P27
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19.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Demontoux F., Mironov V. L., Lawrence H., Kosolapova L.G., Wigneron J.-P., Kerr Y.
Заглавие : Modeling of the L-band emission and scattering of soil layers with consideration of moisture and temperature gradients
Коллективы : Microwave Radiometry and Remote Sensing of the Environment, specialist Meeting on
Место публикации : MicroRad: Proceedings. - Munich, 2012. - С. 1-3. - ISBN 978-1-4673-1470-1, DOI 10.1109/MicroRad.2012.6185240
Аннотация: The studies were designed to ensure correct inclusion of profiles into our model. These promising results will be followed by a validation stage. To do that, we have experimental data sets. We have moisture measurements (with the presence of gradients) and emissivities from the site of SMOSREX (nearly no temperature gradients). On the other hand, we have measurements of high temperature gradients, moisture, emissivity and bi static scattering coefficients from a measurement site in Siberia [8].
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Wigneron J. -P., Jackson T. J., O'Neill P., De Lannoy G., de Rosnay P., Walker J. P., Ferrazzoli P., Mironov V. L., Bircher S., Grant J. P., Kurum M., Schwank M., Munoz-Sabater J., Das N., Royer A., Al-Yaari A., Al Bitar A., Fernandez-Moran R., Lawrence H., Mialon A., Parrens M., Richaume P., Delwart S., Kerr Y.
Заглавие : Modelling the passive microwave signature from land surfaces: A review of recent results and application to the L-band SMOS & SMAP soil moisture retrieval algorithms
Место публикации : Remote Sens. Environ.: Elsevier, 2017. - Vol. 192. - P.238-262. - ISSN 00344257 (ISSN), DOI 10.1016/j.rse.2017.01.024
Примечания : Cited References: 187. - This research work was funded by CNES (Centre National d'Etudes Spatiales) through the Science TOSCA (Terre Océan Surfaces Continentales et Atmosphère) program. The authors wish to thank the three anonymous reviewers for their helpful comments and Sylvie Renaud (IMS) for fruitful discusions.
Ключевые слова (''Своб.индексиров.''): atmospheric temperature--climate models--moisture--moisture control--scanning antennas--soils--vegetation--experimental campaign--microwave brightness temperature--passive microwave signatures--semiempirical models--soil moisture retrievals--surface soil moisture--surface temperatures--system configurations--soil moisture
Аннотация: Two passive microwave missions are currently operating at L-band to monitor surface soil moisture (SM) over continental surfaces. The SMOS sensor, based on an innovative interferometric technology enabling multi-angular signatures of surfaces to be measured, was launched in November 2009. The SMAP sensor, based on a large mesh reflector 6 m in diameter providing a conically scanning antenna beam with a surface incidence angle of 40°, was launched in January of 2015. Over the last decade, an intense scientific activity has focused on the development of the SM retrieval algorithms for the two missions. This activity has relied on many field (mainly tower-based) and airborne experimental campaigns, and since 2010–2011, on the SMOS and Aquarius space-borne L-band observations. It has relied too on the use of numerical, physical and semi-empirical models to simulate the microwave brightness temperature of natural scenes for a variety of scenarios in terms of system configurations (polarization, incidence angle) and soil, vegetation and climate conditions. Key components of the inversion models have been evaluated and new parameterizations of the effects of the surface temperature, soil roughness, soil permittivity, and vegetation extinction and scattering have been developed. Among others, global maps of select radiative transfer parameters have been estimated very recently. Based on this intense activity, improvements of the SMOS and SMAP SM inversion algorithms have been proposed. Some of them have already been implemented, whereas others are currently being investigated. In this paper, we present a review of the significant progress which has been made over the last decade in this field of research with a focus on L-band, and a discussion on possible applications to the SMOS and SMAP soil moisture retrieval approaches. © 2017 Elsevier Inc.
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