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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boldyrev K. N., Stanislavchuk T. N., Sirenko A. A., Kamenskyi D., Bezmaternykh L. N., Popova M. N.
Заглавие : Bifurcations observed in the spectra of coupled electron-phonon modes in multiferroic PrFe3(BO3)4 subjected to a magnetic field [Electronic resource]
Место публикации : ArXiv. - 2016. - Ст.1609.02125
Вид и объем ресурса: Electronic text data
Примечания : Cited References: 19. - This research was supported by the Russian Scientific Foundation under Grant No 14-12-01033, the President of Russian Federation (MK-3521-2015.2, K.N.B.), and the U.S. Department of Energy under Grant No DE-FG02-07ER46382 (experiments at U4-IR beamline NSLS-BNL, T.N.S. and A.A.S.). The National Synchrotron Light Source is operated as a User Facility for he U.S. Department of Energy under Contract No. DE-AC02-98CH10886. Part of this work was supported by EMFL (contract No. 26211). M.N.P. thanks B.Z. Malkin helpful discussions.
Аннотация: We report on bifurcations effect mediated by the electron-phonon coupling in a concentrated rare-earth-containing antiferromagnet, observed in the spectra of coupled 4f-electron-phonon modes under the influence of an external magnetic field. The effect was observed in the low-temperature far-infrared (terahertz) reflection spectra of a multiferroic easy-axis antiferromagnet PrFe3(BO3)4 in magnetic fields Bext||c. Both paramagnetic and magnetically ordered phases (including a spin-flop one) were studied in magnetic fields up to 30 T. We show that the field behavior of the coupled modes can be successfully explained and modeled on the base of the equation derived in the frame of the theory of coupled electron-phonon modes, with the same field-independent electron-phonon interaction constant |W|=14.8cm−1.
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2.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Flerov I. N., Mikhaleva E. A., Kartashev A. V., Gorev M. V.
Заглавие : Caloric Effects in Multiferroic Composites (x)La0.7Pb0.3MnO3 — (1-x)PbTiO3
Коллективы : Joint Russia/CIS/Baltic/Japan Symposium on Ferroelectricity, Young scientists school on the spectroscopic, Физико-технический институт им. А.Ф. Иоффе РАН, Санкт-Петербургский политехнический университет им. Петра Великого
Место публикации : Joint 14th Rus./CIS/Baltic/Japan Symp. on Ferroelectricity (RCBJSF)/ Young sci. school on the spect. studies of critical dynamics at struct. phase trans.: Abstract book/ org. comm. A. N. Vtyurin ; progr. comm. I. N. Flerov. - 2018. - P.11. - ISBN 978-5-9651-1144-2
Примечания : Cited References:
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3.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Malakhovskii A. V., Gnatchenko S. L., Kachur I. S., Piryatinskaya V. G., Sukhachev A. L., Temerov V. L.
Заглавие : Change of the local magnetic properties during f-f transitions in multiferroic Nd0.5Gd0.5Fe3(BO3)4 single crystal
Коллективы : Ultrafast Magnetism Conference
Место публикации : Ultrafast magnetism conf. (UMC 2015): program. - Nijmegen, 2015
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mukhin A. A., Vorob'ev G. P., Ivanov V. Y., Kadomtseva A. M., Narizhnaya A. S., Kuz'menko A. M., Popov Y. F., Bezmaternykh L. N., Gudim I. A.
Заглавие : Colossal magnetodielectric effect in SmFe3(BO3)(4) multiferroic
Разночтения заглавия :авие SCOPUS: Colossal magnetodielectric effect in SmFe 3(BO 3) 4 multiferroic
Место публикации : JETP Letters. - 2011. - Vol. 93, Is. 5. - P.275-281. - ISSN 0021-3640, DOI 10.1134/S0021364011050079
Примечания : Cited References: 17. - We are grateful to A.K. Zvezdin and A.P. Pyatakov for the discussion of this work and valuable comments. This work was supported by the Russian Foundation for Basic Research, project nos. 10-02-00846 and 09-02-01355.
Предметные рубрики: FERROELECTRICITY
MAGNETOSTRICTION
GARNETS
Аннотация: The colossal (more than threefold) decrease in the dielectric constant E in the easy-plane SmFe3(BO3)(4) ferroborate in a magnetic field of similar to 5 kOe applied in the basal ab plane of the crystal has been found. A close relation of this effect to anomalies in the field dependence of the electric polarization has been established. It has been shown that this magnetodielectric effect is due to the contribution to E from the electric susceptibility, which is related to the rotation of spins in the ab plane, arises in the region of the antiferromagnetic ordering T T (N) and electric polarization in the magnetic field has been proposed, taking into account the additional anisotropy in the basal plane induced by the magnetoelastic stresses.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Matveeva A. N., Zobkalo I. A., Meven M., Freidman A. L., Semenov S. V., Terentjev K. Yu., Pavlovskiy N. S., Kolkov M. I., Shaykhutdinov K. A., Hutanu V.
Заглавие : Complex interplay between 3d and 4f magnetic systems in multiferroic DyMnO3
Место публикации : J. Magn. Magn. Mater. - 2023. - Vol. 569. - Ст.170415. - ISSN 03048853 (ISSN), DOI 10.1016/j.jmmm.2023.170415
Примечания : Cited References: 28. - The authors are grateful to S.V. Gavrilov for the technical assistance. This work was supported by the Russian Foundation for Basic Research grant # 19-52-12047, and DFG grant # SA 3688/1-1, also by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science to the research projects number 18-42-243024 and 20-42-243008. The neutron data were obtained at the instrument HEiDi operated jointly by RWTH Aachen University and Jülich Centre for Neutron Science within JARA cooperation
Аннотация: Structural and magnetic properties of single crystals of DyMnO3 were investigated by neutron diffraction in order to study the peculiarities of 3d-4f interactions in this compound. Precise magnetic order and its detailed temperature evolution were determined using single crystal neutron diffraction. Elliptical cycloid on manganese subsystem below TCh = 19 K was confirmed, with temperature decrease the elipticity of the Mn magnetic structure reduces significantly, creating almost circular cycloid. Temperature evolution of the magnetic structure demonstrate specific hysteretic behavior. The results show a complex interplay between transition metal and rare earth magnetic sublattices leading to so-called “Mn- controlled” and “Dy- controlled” magnetic states. The strong and complicate 3d-4f interaction leads to the unusual very slow magnetic structure relaxation.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golosovsky I. V., Vasilev A. I., Mukhin A. A., Ressouche E., Skumryev V., Urcelay-Olabarria I., Gudim I. A., Bezmaternykh L. N.
Заглавие : Complex magnetic order in the Nd(Tb)Fe3(BO3)4 multiferroic revealed by single-crystal neutron diffraction
Место публикации : Phys. Rev. B. - 2019. - Vol. 99, Is. 13. - Ст.134439. - ISSN 24699950 (ISSN) , DOI 10.1103/PhysRevB.99.134439
Примечания : Cited References: 33. - This work was supported by the Russian Grant No. RFBR 16-02-00058. A.A.M. acknowledges the financial support from the Russian Science Foundation (16-12-10531).
Аннотация: Magnetic structure of the substituted multiferroics-ferroborates Nd0.9Tb0.1Fe3(BO3)4 and Nd0.8Tb0.2Fe3(BO3)4 were determined in the framework of a self-consistent refinement of the single crystal neutron diffraction data. The small substitution of Nd for Tb leads to the reorientation of the main antiferromagnetic vector L from the basal plane towards the hexagonal axis. The reorientation takes place via an angular structure for which L does not coincide with the principal crystallographic directions and evolves with temperature due to competing magnetic anisotropies of Fe, Nd, and Tb subsystems. Our refinement at 2 K reveals the existence of distortions in the collinear antiferromagnetic Fe spin arrangement suggested before in other ferroborates. Therefore, besides the main antiferromagnetic vector L, the magnetic structure involves additional fine symmetrized combinations of spin components allowed by symmetry. They coexist with certain L components and could originate from the antisymmetric Dzyaloshinsky-Moriya Fe-Fe exchange interactions. At higher temperatures, the magnetic structure is described by the simple collinear model, where the L vector is deviated from the hexagonal plane. © 2019 American Physical Society.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boldyrev K. N., Stanislavchuk T. N., Sirenko A. A., Bezmaternykh L. N., Popova M. N.
Заглавие : Coupling between phonon and crystal-field excitations in multiferroic PrFe3(BO3)4
Коллективы : Russian Scientific Foundation [14-12-01033]; President of Russian Federation [MK-1700.2013.2]; U.S. Department of Energy [DE-FG02-07ER46382, DE-AC02-98CH10886]
Место публикации : Phys. Rev. B: American Physical Society, 2014. - Vol. 90, Is. 12. - Ст.121101. - ISSN 1098-0121, DOI 10.1103/PhysRevB.90.121101. - ISSN 1550-235X
Примечания : Cited References: 35. - This research was supported by the Russian Scientific Foundation under Grant No. 14-12-01033, the President of Russian Federation (MK-1700.2013.2; K.N.B.), and the U.S. Department of Energy under Grant No. DE-FG02-07ER46382 (experiments at U4-IR beamline NSLS-BNL; T.N.S. and A.A.S.). The National Synchrotron Light Source is operated as a User Facility for the U.S. Department of Energy under Contract No. DE-AC02-98CH10886. M.N.P. thanks B. Z. Malkin for drawing her attention to the work [33] and for helpful discussions.
Предметные рубрики: MAGNETOELECTRIC PROPERTIES
GROUND-STATE
SM
Аннотация: Far-infrared reflection and ellipsometry measurements on multiferroic PrFe3(BO3)4 and SmFe3(BO3)4 single crystals were used to investigate the interaction between lattice phonons and electronic excitations associated with 4f crystal-field transitions. A temperature-dependent interference between two types of excitations was observed in PrFe3(BO3)4 in which the frequency of 4f crystal-field electronic excitation of Pr3+ falls into the TO-LO frequency interval of the optical phonon mode near 50 cm−1 (1.5 THz). Experimental data were explained on the basis of a theoretical model of coupled electron-phonon modes. The fitting procedure revealed the value 14.8 cm−1 for the electron-phonon coupling constant. This rather large value points to an essential role played by the electron-phonon interaction in the physics of multiferroics.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Popova M. N., Chukalina E. P., Malkin B. Z., Erofeev D. A., Bezmaternykh L. N., Gudim, I. A.
Заглавие : Crystal field and exchange interactions in the SmFe3(BO3)4 multiferroic
Коллективы : Russian Foundation for Basic Research [13-02-00787]; basic research program Quantum Mesoscopic and Disordered Structures of the Presidium of the Russian Academy of Sciences
Место публикации : J. Exp. Theor. Phys.: MAIK Nauka-Interperiodica / Springer, 2014. - Vol. 118, Is. 1. - P.111-123. - ISSN 1063-7761, DOI 10.1134/S1063776114010142. - ISSN 1090-6509
Примечания : Cited References: 22. - This work was supported by the Russian Foundation for Basic Research (project no. 13-02-00787) and the basic research program Quantum Mesoscopic and Disordered Structures of the Presidium of the Russian Academy of Sciences.
Аннотация: The optical spectra of oriented SmFe3(BO3)4 single crystals are studied in the region of the f-f transitions in the Sm3+ ion by Fourier spectroscopy. The energies, the symmetry properties, and the exchange splittings of the Stark sublevels of the ground and 17 excited multiplets of the Sm3+ ion in a crystal field of symmetry D 3 are determined from the measured temperature dependences of polarized-radiation absorption spectra. The parameters of the crystal field acting on samarium ions and the parameters of the exchange interaction between Sm3+ and Fe3+ ions are found. The anisotropy of the effective exchange interaction is shown to be substantially stronger than the magnetic anisotropy, due to a strong crystal-field-induced mixing of the ground and excited multiplets.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Smirnova E. S., Alekseeva O. A., Dudka A. P., Verin I. A., Artemov V. V., Lyubutina M. V., Gudim I. A., Frolov K. V., Lyubutin I. S.
Заглавие : Crystal structure of bis­muth-containing NdFe3(BO3)4 in the temperature range 20–500 K
Коллективы : Russian Ministry of Science and Higher Education; Ministry of Science and Higher Education within the State assignment FSRC 'Crystallography and Photonics' RAS
Место публикации : Acta Crystallogr. B. - 2022. - Vol. 78, Pt. 1. - P.1-13. - ISSN 2052-5206(eISSN), DOI 10.1107/S205252062101180X
Примечания : Cited References: 44. - This work was performed using the equipment of the Shared Research Center FSRC `Crystallography and Photonics' RAS supported by the Russian Ministry of Science and Higher Education. This work was supported by the Ministry of Science and Higher Education within the State assignment FSRC `Crystallography and Photonics' RAS
Предметные рубрики: MAGNETIC PHASE-TRANSITIONS
UNIT-CELL PARAMETERS
DIFFRACTION
Аннотация: Neodymium iron bor­ate NdFe3(BO3)4 is an intensively studied multiferroic with high electric polarization values controlled by a magnetic field. It is char­ac­ter­ized by a large quadratic magnetoelectric effect, rigidity in the base plane and a rather strong piezoelectric effect. In this work, the atomic structure of (Nd0.91Bi0.09)Fe3(BO3)4 was studied by single-crystal X-ray diffraction in the tem­per­ature range 20–500 K (space group R32, Z = 3). The Bi atoms found in the com­position partially substitute the Nd atoms in the 3a position; they entered the structure due to the growth conditions in the presence of Bi2Mo3O12. It was shown that in the tem­per­ature range 20–500 K there is no structural phase transition R32→P3121, which occurs in rare-earth iron bor­ates (RE = Eu–Er, Y) with an effective rare-earth cation radius smaller than that of Nd. The tem­per­ature dependence of the unit-cell c parameter reveals a slight increase on cooling below 90 K, which is similar to the results obtained previously for iron bor­ates of Gd, Y and Ho. The atomic distances (Nd,Bi)—O, (Nd,Bi)—B, (Nd,Bi)—Fe, Fe—O, Fe—B and Fe—Fe in the iron chains and between chains decrease steadily with decreasing tem­per­ature from 500 to 90 K, whereas the B1(3b)—O distance does not change and the average B2(9e)—O distance increases slightly. There is a uniform decrease in the atomic displacement parameters with decreasing tem­per­ature, with a more pronounced decrease for the Nd(3a) and O2(9e) atoms. The O2(9e) atoms are characterized by the maximum atomic displacement parameters and the most elongated atomic displacement ellipsoids. The characteristic Debye and Einstein tem­per­atures, and the static com­ponent in the atomic displacements were determined for cations using multi-tem­per­ature diffraction data. It was shown that the Nd cations have the weakest bonds with the surrounding atoms and the B cations have the strongest.
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10.

Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Tripathy A., Gautam K., Dey K., Ahad A., Gudim I. A., Sathe V. G., Shukla D. K.
Заглавие : Dielectric and Raman spectroscopy measurements across structural phase transition in multiferroic HoFe3(BO3)4 single crystal
Коллективы : International Conference on Advanced Materials
Место публикации : AIP Conf. Proc. - 2019. - Vol. 2162: International Conference on Advanced Materials, ICAM 2019. - Ст.020062. - , DOI 10.1063/1.5130272
Примечания : Cited References: 10. - DKS acknowledges support from the DST, New Delhi, India through the grant no INI/RUS/RFBR/P-269 (Indo Russian project). K.G. thanks, Council of Scientific and Industrial Research, New Delhi, India, for support in the form of SRF.
Аннотация: We report on findings in the HoFe3(BO3)4 single crystal across structural phase transition by the dielectric and Raman spectroscopic measurements. In most of the compounds of RFe3(BO3)4 (R=La-Lu) family low temperature P3121 structure is introduced through structural phase transition (from space group R32). Temperature dependent dielectric measurements on the HoFe3(BO3)4 crystal depicts a step like feature at the structural phase transition at ?366 K. The Raman spectroscopy study also confirms the structural transition around this temperature. A clear signature of structural transition is reflected in the Raman spectra, mainly in the frequency range (200-400 cm-1). Appearance of new Raman modes below the transition temperature also indicates that the transition is from a high symmetry phase to a low symmetry phase.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gavrichkov V. A., Malakhovskii A. V., Ovchinnikov S. G.
Заглавие : Effect of optical f - f excitations on the Nd-Fe exchange interaction in Nd ferroborate with multiferroic properties
Коллективы : RFBRRussian Foundation for Basic Research (RFBR) [19-02-00034]; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Krasnoyarsk Regional Fund of Science [20-42-240016]; Government of Krasnoyarsk Territory
Место публикации : Phys. Rev. B. - 2021. - Vol. 104, Is. 6. - Ст.064445. - ISSN 2469-9950, DOI 10.1103/PhysRevB.104.064445. - ISSN 2469-9969(eISSN)
Примечания : Cited References: 28. - The reported study was supported by the RFBR Grant 19-02-00034. V.A.G. is also grateful to the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, and Krasnoyarsk Regional Fund of Science according to the research project "Studies of superexchange and electron-phonon interactions in correlated systems as a basis for searching for promising functional materials" No. 20-42-240016
Предметные рубрики: LOCAL MAGNETIC-PROPERTIES
SINGLE-CRYSTAL
EXCITED-STATES
Аннотация: We considered the effect of optical pumping at the f−f transitions frequency on d−f superexchange in the rare-earth antiferromagnetic ferroborate Nd0.5Gd0.5Fe3(BO3)4 between Nd3+ ions in the excited states of the 4G5/2, 2G7/2, and Fe3+ in the ground state 6A1. In the ferroborate, d−f superexchange is directly related to the strong magnetoelectric coupling observed in the ground state of the material. We show that under optical pumping at the frequency of f−f transitions 4I9/2↔(4G5/2+2G7/2) in the Nd3+ ion, the nature of the d−f interaction changes to FM. The phenomena can be explained by the occupation of the excited Nd3+ “spin pure” states with spin 1/2, or their mixing to the optically excited states with spin 3/2 due to the spin-orbit interaction. Near optically excited ions Nd3+, magnetic frustrations change from FM ordering under the d−f AFM interaction to AFM ordering under the FM interaction in the basal hexagonal plane.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mikhaleva E. A., Flerov I. N., Gorev M. V., Shabanov A. V.
Заглавие : Effect of Sequential Heat Impacts on the Formation of a Stable State of the xLPM-(1-x)PT Multiferroic Composites
Коллективы : Russian Foundation for Basic Research [17-42-240076]; Government of the Krasnoyarsk Territory [17-42-240076]; Krasnoyarsk Territorial Foundation [17-42-240076]
Место публикации : Phys. Solid State. - 2018. - Vol. 60, Is. 12. - P.2524-2531. - ISSN 1063-7834, DOI 10.1134/S1063783419010189. - ISSN 1090-6460(eISSN)
Примечания : Cited References: 15. - This study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory, and the Krasnoyarsk Territorial Foundation for Support of the Scientific and R&D Activity, project no. 17-42-240076 "Complex Approach to Searching and Development of Promising Solid-State Ferroic Cooling Agents Based on the Single- and Multicaloric Effects."
Предметные рубрики: PbTiO3
Аннотация: The effect of thermal cycling and sintering temperature on the chemical and thermodynamic stability of the bulk multiferroic xLa0.7Pb0.3MnO3–(1 – x)PbTiO3 quasi-ceramic and ceramic composites has been experimentally investigated. It is shown that the limiting temperature of the long-term sample firing should not exceed 1070 K. It has been found that sintering at this temperature and/or short-term exposure of the samples at higher temperatures (up to 1220 K) significantly increase the sample compactness, stabilize the thermal expansion, and enhance the quality of the composites. It has been established that the component grain integrity is violated by shrinkage of the samples and a sharp change in their volume during the phase transition of a ferroelectric component.
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13.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Gudim I. A., Eremin E. V., Krylov A. S., Titova V. R.
Заглавие : Effect of uncontrolled impurities on magnetic and structural transitions of the GdFe3(BO3)4 multiferroic
Коллективы : International Baltic Conference on Magnetism, Балтийский федеральный университет им. И. Канта
Место публикации : V International Baltic Conference on Magnetism. IBCM: Book of abstracts. - 2023. - P.128
Примечания : Cited References: 3. - Support by RSF and KRFS № 22-12-20019 are acknowledged
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14.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Shinkorenko A. S., Zinenko V. I., Pavlovskii M. S.
Заглавие : Electronic structure, magnetic, optical and polarization properties of the multiferroic CaMnTi2O6 by first principles
Коллективы : Joint Russia/CIS/Baltic/Japan Symposium on Ferroelectricity, Young scientists school on the spectroscopic, Физико-технический институт им. А.Ф. Иоффе РАН, Санкт-Петербургский политехнический университет им. Петра Великого
Место публикации : Joint 14th Rus./CIS/Baltic/Japan Symp. on Ferroelectricity (RCBJSF)/ Young sci. school on the spect. studies of critical dynamics at struct. phase trans.: Abstract book/ org. comm. A. N. Vtyurin ; progr. comm. I. N. Flerov. - 2018. - P.148. - ISBN 978-5-9651-1144-2
Примечания : Cited References:
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Popova M. N., Malkin B. Z., Boldyrev K. N., Stanislavchuk T. N., Erofeev D. A., Temerov V. L., Gudim, I. A.
Заглавие : Evidence for a collinear easy-plane magnetic structure of multiferroic EuFe3(BO3)4: Spectroscopic and theoretical studies
Место публикации : Phys. Rev. B: American Physical Society, 2016. - Vol. 94, Is. 18. - Ст.184418. - ISSN 10980121 (ISSN), DOI 10.1103/PhysRevB.94.184418
Примечания : Cited References: 49. - This work was supported by the Russian Science Foundation under Grant No. 14-12-01033. I.A.G. and V.L.T. are grateful to L. N. Bezmaternykh for useful comments concerning the crystal growth, to M. S. Molokeev for the XRD characterization of the samples, and to the Russian Foundation for Basic Research for a financial support (Grants No. 13-02-12442 and No. 14-02-00307a).
Аннотация: We performed high-resolution polarized optical transmission spectroscopy and theoretical studies of multiferroic EuFe3(BO3)4 single crystals in the three phases: paramagnetic R32(T˃Ts=84K) and P3121(Ts˃T˃TN=34K), and antiferromagnetic (T˂TN) ones. The analysis of the spectra reveals interesting details of the magnetic structure, namely, a collinear arrangement of the iron magnetic moments along the C2 symmetry axis in the ab crystallographic plane of EuFe3(BO3)4 below TN. Spectral signatures of the phase transitions and the spin-phonon interaction are observed and discussed. Reliable crystal-field and exchange-interaction parameters are obtained and used to model the magnetic susceptibility of the compound. The results of detailed calculations of the electric polarization of EuFe3(BO3)4 in the R32 phase are presented, and mechanisms of the magnetoelectric response are discussed. We detect a strong effect of impurities (that enter the crystal from a flux in the course of the crystal growth) on the structural phase-transition temperature and demonstrate a coexistence of both R32 and P3121 phases down to the lowest temperatures in a EuFe3(BO3)4 crystal grown with the Bi2Mo3O12 based flux, due to inhomogeneous distribution of impurity Bi3+ ions. Our study can be considered as a demonstration of the abilities of optical spectroscopy in delivering new information on a magnetic compound, even in the case when other methods fail. © 2016 American Physical Society.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kuzmenko A. M., Shuvaev A., Dziom V., Pimenov A., Schiebl M., Mukhin A. A., Ivanov V. Yu., Bezmaternykh L. N., Pimenov A.
Заглавие : Giant gigahertz optical activity in multiferroic ferroborate
Коллективы : Russian Foundation for Basic Researches [12-02-01261, 12-02-31461 mol]; Austrian Science Funds [I815-N16, W1243]
Место публикации : Phys. Rev. B: American Physical Society, 2014. - Vol. 89, Is. 17. - Ст.174407. - ISSN 1098-0121, DOI 10.1103/PhysRevB.89.174407. - ISSN 1550-235X
Примечания : Cited References: 35. - This work was supported by the Russian Foundation for Basic Researches (Grants No. 12-02-01261 and No. 12-02-31461 mol) and by the Austrian Science Funds (Grants No. I815-N16 and No. W1243).
Предметные рубрики: RFE3(BO3)4
Аннотация: In contrast to the well-studied multiferroic manganites with a spiral structure, the electric polarization in multiferroic borates is induced within a collinear antiferromagnetic structure and can easily be switched by small static fields. Because of specific symmetry conditions, the static and dynamic properties in borates are directly connected, which leads to giant magnetoelectric and magnetodielectric effects. Here we prove experimentally that the giant magnetodielectric effect in samarium ferroborate, SmFe3(BO3)4, is of intrinsic origin and is caused by an unusually large electromagnon situated in the microwave range. This electromagnon reveals a strong optical activity exceeding 120 degrees of polarization rotation in a millimeter thick sample.В отличие от хорошо изученных мультиферроиков манганитов со спиральной структуры, электрическая поляризация в мультиферроиков боратов индуцируется в коллинеарной антиферромагнитной структуре и может легко переключаться небольшими статическими полями. Из-за специфических условий симметрии, статические и динамические свойства боратов непосредственно связаны, что приводит к гигантским магнитоэлектрическому и магнитодиэлектрическому эффектам. Здесь мы экспериментально доказываем, что гигантский магнитодиэлектрический эффект в самариевом ферробората, SmFe3 (BO3) 4, имеет самостоятельное происхождение и вызван необычно большим электромагноном, расположеным в микроволновом диапазоне. Это электромагнон показывает сильную оптическую активность, более 120 градусов вращения поляризации в миллиметровом образце.
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17.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Mukhin A. A., Kuzmenko A. M., Ivanov V.Yu., Shuvaev A., Dziom V., Pimenov A., Bezmaternykh L. N., Gudim, I. A.
Заглавие : Giant optical activity near electromagnons in multiferroic ferroborites: SmFe3(BO3)4
Коллективы : Moscow International Symposium on Magnetism, Московский государственный университет им. М.В. Ломоносова
Место публикации : Moscow int. Symp. on Magnet. (MISM-2014): Book of abstracts. - 2014. - Ст.1RP-O-3. - P.394. - ISBN 978-5-91978-025-0
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18.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Rogalev A., Wilhelm F., Bosak A., Goulon J., Smekhova A., Gan’shina E. A., Bezmaternykh L. N., Kazak N. V., Ovchinnikov S. G.
Заглавие : Hard X-ray dichroisms studies of multiferroic Ga- Fe03 crystal
Коллективы : Moscow International Symposium on Magnetism
Место публикации : Moscow Int. Symp. on Magnet. (MISM-2011): Book of abstracts. - 2011. - Ст.24TL-H-5. - P.607-608
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisov V. M., Irtyugo L. A., Denisova L. T., Patrin G. S., Volkov N. V.
Заглавие : Heat capacity and thermodynamic properties of GaFeO3 in the range 330-900 K
Место публикации : Inorg. Mater. - 2013. - Vol. 49, Is. 12. - P.1227-1228. - ISSN 0020-1685, DOI 10.1134/S0020168513120042
Примечания : Cited References: 10
Предметные рубрики: MULTIFERROIC GAFEO3
SINGLE-CRYSTALS
TEMPERATURE
BIFEO3
Аннотация: The heat capacity of multiferroic GaFeO3 has been measured in a wide temperature range and the results have been used to evaluate its thermodynamic functions (enthalpy increment and entropy change).
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Popova M. N., Chukalina E. P., Erofeev D. S., Jablunovskis A., Gudim I. A., Malkin B. Z.
Заглавие : High-resolution optical spectroscopy and modeling of spectral and magnetic properties of multiferroic ErFe3(BO3)4
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [19-12-00413]
Место публикации : Phys. Rev. B. - 2020. - Vol. 101, Is. 20. - Ст.205108. - ISSN 2469-9950, DOI 10.1103/PhysRevB.101.205108. - ISSN 2469-9969(eISSN)
Примечания : Cited References: 38. - Financial support of the Russian Science Foundation under Grant No. 19-12-00413 is acknowledged.
Предметные рубрики: F-F TRANSITIONS
ENERGY-LEVELS
ER3+ IONS
GROWTH
Аннотация: We carried out the high-resolution broadband temperature-dependent polarized optical spectroscopy and theoretical studies of ErFe3(BO3)4 single crystals in the paramagnetic and antiferromagnetic (T˂TN=39K) phases. On the basis of the experimentally determined 45 crystal-field (CF) levels of Er3+ ions at sites with the C2 point symmetry, CF calculations were performed, a set of physically grounded CF parameters was obtained and used to model the temperature dependences of the Er magnetic moments measured in neutron-scattering experiments, as well as the magnetic susceptibility and magnetization of the compound; the contributions of the quasi-one-dimensional iron magnetic subsystem were calculated in the frame of the previously developed self-consistent four-particle cluster model. The modeling strongly supports an easy-plane collinear structure of iron magnetic moments and excludes earlier proposed additional magnetic phase.
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