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A complex of ceftriaxone with Pb(II): synthesis, characterization, and antibacterial activity study / A. O. Lykhin [et al.] // J. Coord. Chem. - 2014. - Vol. 67, Is. 16. - З. 2783-2794, DOI 10.1080/00958972.2014.938065. - Cited References: 48. - The reported study was supported by RFBR, research project No. 14-03-31, 170 MOJI_a and Krasnoyarsk regional fund for supporting scientific and technological activities. We thank the Center for Equipment Joint Use of the Siberian Federal University. We are grateful to the HPC Research Departments of Siberian Federal University and Moscow University Supercomputing Center (SKIF MSU "Chebyshev") for the access to the high-performance computer clusters. . - ISSN 0095-8972. - ISSN 1029-0389

РУБ Chemistry, Inorganic & Nuclear
Рубрики:
BETA-LACTAM ANTIBIOTICS
   TERNARY COMPLEX
   METAL-COMPLEXES
   BASIS-SETS
   3 DECADES
   RESISTANCE
   COPPER(II)
   CEPHALOSPORINS
   EVOLUTION
   1ST-ROW
Кл.слова (ненормированные):
Ceftriaxone lead(II) complex -- DFT -- IR spectroscopy -- TGA -- Antibacterial screening
Аннотация: A Pb(II) complex with ceftriaxone (H2Ceftria) antibiotic was synthesized by reaction of ceftriaxone disodium salt (hemi)heptahydrate with lead nitrate in water–ethanol medium. The complex was characterized on the basis of complexometric titration, spectrophotometric and thermogravimetric analyses, capillary electrophoresis, IR, Raman and UV–vis spectroscopies, and density functional theory calculations. Pb(II) is five-coordinate with distorted square pyramidal geometry. The coordination of Ceftria2− to Pb(II) occurs through N and O of the triazine, lactam carbonyl, carboxylate, and amine groups. The antibacterial activity study showed that Klebsiella pneumoniae is resistant to [Pb(Ceftria)]·3H2O. The antibacterial activity of [Pb(Ceftria)]·3H2O against Staphylococcus aureus is reduced compared with ceftriaxone. In contrast, the antibacterial activity of [Pb(Ceftria)]·3H2O against Escherichia coli is 28% higher than that of ceftriaxone antibiotic.

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Держатели документа:
Siberian Fed Univ, Dept Chem, Krasnoyarsk, Russia
Siberian State Aerosp Univ, Informat Sci & Telecommun Inst, Krasnoyarsk, Russia
Russian Acad Sci, LV Kirensky Inst Phys, Siberian Branch, Krasnoyarsk, Russia
Siberian State Technol Univ, Dept Phys, Krasnoyarsk, Russia
Univ Nevada, Dept Chem, Reno, NV 89557 USA

Доп.точки доступа:
Lykhin, A. O.; Лыхин А. О.; Novikova, G. V.; Новикова Г. В.; Kuzubov, A. A.; Кузубов, Александр Александрович; Staloverova, N. A.; Сталоверова Н. А.; Sarmatova, N. I.; Сарматова Н. И.; Varganov, S. A.; Варганов, Сергей Александрович; Krasnov, P. O.; Краснов, Павел Олегович; RFBR [14-03-31, 170 MOJI_a]
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Andreev reflections and experimental current-voltage characteristics of break junctions of polycrystalline HTSC / M. I. Petrov [et al.] // Physica C. - 2004. - Vol. 408: 7th International Conference on Materials and Mechanisms of Superconductive and High Temperature Superconductors (MAY 25-30, 2003, Rio de Janeiro, BRAZIL). - P. 620-622, DOI 10.1016/j.physc.2004.03.085. - Cited References: 3 . - ISSN 0921-4534

РУБ Physics, Applied

Кл.слова (ненормированные):
Andreev reflections -- break junction -- current-voltage characteristics -- Andreev reflections -- Break junction -- Current-voltage characteristics -- Andreev reflections -- Break junctions -- Elastic scattering -- Lattice defects -- Negative differential resistance -- Electric fields -- Heuristic methods -- Hysteresis -- Microcracks -- Polycrystalline materials -- Probability density function -- Quasicrystals -- Superconducting materials -- Yttrium barium copper oxides -- Current voltage characteristics
Аннотация: The temperature evolution of current-voltage characteristics (CVCs) of break junctions made from polycrystalline Y0.75Lu0.25Ba2Cu3O7 and La1.85Sr0.15CuO4 is investigated. The experimental CVCs have hysteretic features that reflect a part of a curve with negative differential resistance. The temperature evolution of the CVCs is discussed within the framework of the Kummel-Gunsenheimer-Nicolsky theory for superconductor/normal-metal/superconductor junctions considering multiple Andreev reflections. It is shown that the shape of the CVCs of break junctions is determined by the ratio of the number of "short" and "long" intergrain normal regions in the polycrystalline HTSC under investigation. (C) 2004 Elsevier B.V. All rights reserved.

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Держатели документа:
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Reshetnev Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
Univ Wurzburg, Inst Theoret Phys & Astrophys, D-97074 Wurzburg, Germany
ИФ СО РАН
Kirensky Intitute of Physics, Akademgorodok, 660036 Krasnoyarsk, Russian Federation
Reshetnev Siberian Stt. Aerosp. U., 660014 Krasnoyarsk, Russian Federation
Inst. fur Theor. Phys./Astrophys., Universitat Wurzburg, D-97074 Wurzburg, Germany

Доп.точки доступа:
Petrov, M. I.; Петров, Михаил Иванович; Gokhfeld, D. M.; Гохфельд, Денис Михайлович; Balaev, D. A.; Балаев, Дмитрий Александрович; Shaihutdinov, K. A.; Kummel, R.
}
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Aplesnin, S. S.
Anomalies in magnetoresistance and in the bulk modulus for ferromagnetics with four-spin exchange interaction on the Kondo lattice / S. S. Aplesnin, N. I. Piskunova // J. Phys.: Condens. Matter. - 2006. - Vol. 18, Is. 29. - P. 6859-6868, DOI 10.1088/0953-8984/18/29/023. - Cited References: 29 . - ISSN 0953-8984

РУБ Physics, Condensed Matter
Рубрики:
MIXED-VALENCE MANGANITES
   PHASE-SEPARATION
   LA1-XSRXMNO3
   BEHAVIOR
   PECULIARITIES
   TRANSITION
Кл.слова (ненормированные):
Elastic moduli -- Electric resistance -- Ferromagnetism -- Function evaluation -- Paramagnetism -- Transceivers -- Adiabatic approximation -- Kondo lattice -- Paramagnetic state -- Ring exchange -- Magnetoresistance
Аннотация: The temperature dependence of resistivity and the bulk modulus are calculated on the Kondo lattice, with ring exchange between localized spins, using the spin-polaron and adiabatic approximation. Peak and zero values of the bulk modulus as functions of temperature and concentration are determined below the temperature of the transition to the paramagnetic state. The effects of the nearest order between transverse spin components and a value of the ring exchange between localized spins on magnetoresistivity are estimated.

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Держатели документа:
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
MF Reshetneva Aircosm Siberian State Univ, Krasnoyarsk 660014, Russia
ИФ СО РАН
L v Kirenskii Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
M F Reshetneva Aircosmic Siberian State University, Krasnoyarsk, 660014, Russian Federation

Доп.точки доступа:
Piskunova, N. I.; Аплеснин, Сергей Степанович
}
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Balaev, A. D.
Quantum oscillations of resistance and magnetization in the degenerate semiconductor n-HgCr2Se4 / A. D. Balaev, V. A. Gavrichkov, S. G. Ovchinnikov // J. Exp. Theor. Phys. - 1998. - Vol. 86, Is. 5. - P. 1026-1029, DOI 10.1134/1.558549. - Cited References: 6 . - ISSN 1063-7761

РУБ Physics, Multidisciplinary

Аннотация: In the magnetic field range Delta H = 8-60 kOe we observed and studied the anomalous oscillations in the magnetic field dependence of the resistance and magnetization of single crystals of n-HgCr2Se4. The absence of periodicity in 1/H in the Delta H = 8-20 kOe range can be explained by the non-Fermi-liquid behavior of the electron subsystem and agrees with the theory of the de Haas-van Alphen in systems with intermediate valence. In stronger fields, Delta H = 20-60 kOe, the amplitude of the fundamental harmonic decreases, with the number and amplitude of the higher-order harmonics increasing, As a result, noise is superimposed on the signal as magnetic field strength grows. The temperature dependence of the magnetization is the sum of the monotonic spin-wave contribution and the oscillating part. (C) 1998 American Institute of Physics. [S1063-7761(98)02205-7].

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Публикация на русском языке Квантовые осцилляции сопротивления и намагниченности в вырожденном полупроводнике n-HgCr_2Se_4 [Текст] / А. Д. Балаев [и др.] // Журн. эксперим. и теор. физ. - 1998. - Т. 113 Вып. 5. - С. 1877-1882

Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
Krasnoyarsk State Univ, Krasnoyarsk 660074, Russia
Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia
ИФ СО РАН

Доп.точки доступа:
Gavrichkov, V. A.; Гавричков, Владимир Александрович; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Балаев, Александр Дмитриевич
}
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Balaev, D. A.
Correlation between magnetoresistance and magnetization hysteresis in a granular high-T C superconductor: Impact of flux compression in the intergrain medium / D. A. Balaev, S. V. Semenov, M. I. Petrov // J. Supercond. Nov. Magn. - 2014. - Vol. 27, Is. 6. - P. 1425-1429, DOI 10.1007/s10948-014-2491-6. - Cited References: 27 . - ISSN 1557-1939. - ISSN 1557-1947

РУБ Physics, Applied + Physics, Condensed Matter
Рубрики:
HIGH-TEMPERATURE SUPERCONDUCTOR
   JOSEPHSON MEDIUM
   CRITICAL-STATE
   YBA2CU3O7-DELTA
   FIELDS
   BEHAVIOR
   HTSC
   COMPOSITES
   RESISTANCE
   MOTION
Кл.слова (ненормированные):
Granular superconductor -- Josephson medium -- Effective field -- Magnetoresistance -- Magnetization hysteresis
Аннотация: The correlation between experimental magnetic field dependences of magnetoresistance and magnetization hysteresis in granular YBa2Cu3O7 is established. Within the proposed approach, magnetoresistance is assumed to be determined by the effective field in the intergrain boundaries the ensemble of which is considered to be a Josephson medium. The effective field in the intergrain medium can be written in the form B (eff)(H)=H-4 pi M(H)x alpha, where alpha is the parameter of averaged demagnetizing factors of grains and the degree of flux compression. A comparison of experimental magnetoresistance R(H) and magnetization M(H) hysteresis dependences obtained at different external magnetic field sweep rates yields the value alpha similar to 10, which is caused by the flux compression between grains. The proposed model describes well most of the features of the magnetoresistance hysteresis in granular high-T (C) superconductors.

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Доп.точки доступа:
Semenov, S. V.; Семёнов, Сергей Васильевич; Petrov, M. I.; Петров, Михаил Иванович; Балаев, Дмитрий Александрович
}
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Bio-functionalization of phytogenic Ag and ZnO nanobactericides onto cellulose films for bactericidal activity against multiple drug resistant pathogens / S. Baker [et al.] // J. Microbiol. Methods. - 2019. - Vol. 159. - P. 42-50, DOI 10.1016/j.mimet.2019.02.009. - Cited References: 59 . - ISSN 0167-7012. - ISSN 1872-8359

РУБ Biochemical Research Methods + Microbiology
Рубрики:
SILVER NANOPARTICLES
   ANTIMICROBIAL ACTIVITY
   SIZE
   COMPOSITES
   MEMBRANE
Кл.слова (ненормированные):
Bupleurum aureum -- Rio-functionalization -- Silver nanobactericides -- Zinc oxide nanobactericides -- Multi-drug resistance pathogens -- Bacterial cellulose
Аннотация: The present study describes the synthesis of silver and zinc oxide nanobactericides from the phytogenic source Bupleurum aureum The synthesized nanobactericides were characterized and evaluated for bio-functionalization onto bacterial cellulose membrane which was synthesized by Komagataeibactencylinus B-12068 culture strain. The synthesis of nanobacterides were initially confirmed using UV-Visible spectroscopy which indicated localized surface resonance (LSPR) peaks at 415 nm for silver nanobactericides and 280 nm for zinc nanobactericides. The nature of the capping agent for synthesized nanobactericides was predicted using FTIR which confirmed the presence of functional moieties. XRD analysis revealed their crystalline nature while morphological characteristics were studied using TEM which confirmed the polydispersity of nanobactericides with the average size in the range of 20-25 nm. The nanobactericides were tested for their antimicrobial activity against seven multi-drug resistant pathogens which were clinically isolated from patients suffering from a myriad of microbial infections. The tested pathogens had antimicrobial resistance to ten different antibiotics and have been reported to be the major cause of nosocomial infections. The nanobactericides displayed significant activity against the test pathogens. Silver nanobactericides showed the highest activity against Escherichia coli strain 55 with a 24 mm zone of inhibition while zinc oxide nanobactericides displayed the highest activity against methicillinresistant Staphylococcus aureus (MRSA) with a 20 mm inhibition zone. The bio- functionalized cellulose films (BCF) were characterized using SEM along with physicochemical analysis. The BCF's were evaluated for anti-bacterial activity against test pathogens which resulted in marked antimicrobial potential against multi-drug resistant bacteria and therefore has the potential to be utilized as an efficient alternative to counter drug resistant pathogens.

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Держатели документа:
Siberian Fed Univ, 79 Svobodny Pr, Krasnoyarsk 660041, Russia.
Siberian Fed Univ, Sch Fundamental Biol & Biotechnol, Krasnoyarsk, Russia.
Krasnoyasrk State Med Univ, Dept Microbiol, Krasnoyarsk Partizana Zheleznyakast 1, Krasnoyarsk 660022, Russia.
RAS, KSC SB, Fed Res Ctr, Kirensky Inst Phys, Akademgorodok 50,Bld 38, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Sch Petr & Nat Gas Engn, Krasnoyarsk, Russia.

Доп.точки доступа:
Baker, Syed; Prudnikova, Svetlana V.; Shumilova, Anna A.; Perianova, Olga V.; Zharkov, S. M.; Жарков, Сергей Михайлович; Kuzmin, A.
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    Bio-hybridization of nanobactericides with cellulose films for effective treatment against members of ESKAPE multi-drug-resistant pathogens / S. Baker [et al.] // Appl. Nanosci. - 2018. - Vol. 8, Is. 5. - P. 1101-1110, DOI 10.1007/s13204-018-0717-9. - Cited References: 51. - Authors are thankful for Ministry of Education and Science of the Russian Federation for providing funding under the scheme of 5-100: Russian Academic Excellence Project. Authors are grateful for facilities provided by Siberian Federal University to carry out the present study. . - ISSN 2190-5509. - ISSN 2190-5517
   Перевод заглавия: Биогибридизация нано-бактерицидов с целлюлозными пленками для эффективного воздействия на представителей группы патогенов ESKAPE, резистентных к различным препаратам

РУБ Nanoscience & Nanotechnology
Рубрики:
SILVER NANOPARTICLES
BACTERIAL CELLULOSE
ANTIBIOTIC-RESISTANCE
Кл.слова (ненормированные):
ESKAPE -- Bio-hybridization -- Silver nanobactericides -- Phytogenic -- Bactericidal activity
Аннотация: The rapid expansion of drug-resistant pathogens has created huge global impact and development of novel antimicrobial leads is one of the top priority studies in the current scenario. The present study aims to develop bio-hybridized nanocellulose films which comprise of phytogenic silver nanobactericides. The nanobactericides were synthesized by treating 1 mM silver nitrate with aqueous extract of Chamerion angustifolium which reduced the metal salt to produce polydispersed nanobactericides which were tested against the members of ESKAPE drug-resistant communities. The synthesized silver nanobactericides were subjected to characterization with UV–visible spectra which displayed maximum absorbance at 408 nm. The bio-molecular interaction of phyto-constituents to mediate synthesis and stabilization of nanobactericides was studied with Fourier-transform infrared spectroscopy (FTIR) which depicted functional groups associated with nanobactericides. The crystalline nature was studied with X-ray diffraction (XRD) which showed Bragg’s intensities at 2θ angle which denoted (111), (200), (220), and (311) planes. The morphological characteristics of silver nanobactericides were defined with transmission electron Microscopy (TEM) image which displayed polydispersity of silver nanobactericides with size ranging from 2 to 40 nm. The synthesized nanobactericides showed a significant activity against MRSA strain with 21 mm zone of inhibition. The minimal inhibitory concentration of silver nanobactericides to inhibit the growth of test pathogens was also determined which ranged between 0.625 and 1.25 μg/ml. The silver nanobactericides were bio-hybridized onto nanocellulose films produced by Komagataeibacter xylinus B-12068 culture strain. The films were dried to determine the mechanical properties which showed increased in Young’s modulus and tensile strength in comparison with control bacterial cellulose films. Overall, the results obtained in the present investigation are promising enough to report bactericidal activity of bio-hybridized nanobactericidal films against ESKAPE. These communities are reported to cause severe threats to all forms of lives irrespective to their habitats which can lead to huge economical crisis.

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Держатели документа:
Siberian Fed Univ, Lab Biotechnol New Mat, Svobodnyy Pr 79, Krasnoyarsk 660041, Russia.
SB RAS, Krasnoyarsk Sci Ctr, Fed Res Ctr, Inst Biophys, 50-50 Akademgorodok, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, 79 Svobodny Pr, Krasnoyarsk 660041, Russia.
Siberian Fed Univ, Sch Fundamental Biol & Biotechnol, Krasnoyarsk, Russia.
Krasnoyasrk State Med Univ, Dept Microbiol, Krasnoyarsk Partizana Zheleznyaka St 1, Krasnoyarsk 660022, Russia.
SB RAS, Fed Res Ctr KSC, Kirensky Inst Phys, Akademgorodok 50,Bld 38, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Sch Petr & Nat Gas Engn, Krasnoyarsk, Russia.

Доп.точки доступа:
Baker, Syed; Volova, Tatiana; Prudnikova, Svetlana V.; Shumilova, Anna A.; Perianova, Olga, V; Zharkov, S. M.; Жарков, Сергей Михайлович; Kuzmin, A. R.; Kondratenka, Olga; Kiryukhin, Bogdan; Shidlovskiy, Ivan P.; Potkina, Zoya K.; Khohlova, Olga Y.; Lobova, Tatiana I.; Ministry of Education and Science of the Russian Federation under the scheme of 5-100: Russian Academic Excellence Project
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BT-30 Ceramic Electrophysical Properties / N. A. Drokin, V. S. Kiiko, A. V. Pavlov, A. I. Malkin // Refract. Ind. Ceram. - 2020. - Vol. 61, Is. 3. - P. 341-348, DOI 10.1007/s11148-020-00484-2. - Cited References: 12 . - ISSN 1083-4877. - ISSN 1573-9139
Кл.слова (ненормированные):
(BeO + TiO2)-ceramic -- electrophysical properties -- electrical resistance activation energy
Аннотация: A total complex resistance (impedance) method is used to study the electrophysical characteristics of (BeO + TiO2)-ceramics modified with TiO2 micro- and nanoparticles in an amount of 30 wt.% (BT-30). Dispersion of the actual ε′ and imaginary ε′′ components of the dielectric permittivity component and specific conductivity in the frequency range from 100 Hz to 100 MHz from room temperature to the boiling point of liquid nitrogen are determined. High values of ε′ and ε′′ in the low-frequency range are typical for structurally inhomogeneous materials due to the accumulation of electric charges at the surface and within microcrystals. Two dielectric relaxation processes associated with electrical conductivity within the body and at the surface of ceramics are detected for the first time. An increase in conductivity with an increase in the microwave field frequency above 1 MHz is explained by the appearance of a current relaxation component. The activation energy of the static resistance of ceramic specimens is determined as a function of the reciprocal temperature that depends little on the weight content of TiO2 nanoparticles and varies in the range of 0.024 – 0.10 eV This also confirms the existence of two independent conduction processes, weakly dependent on the nanoparticle content in the ceramic composition. With placement of ceramic in a high-frequency electric field, spatial charges are formed, the field of which contributes to creation of additional polarization and dielectric losses.

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Держатели документа:
FGBOU VO Academician M. F. Reshetnev Siberian Aerospace University, Krasnoyarsk, Russia.
FGBUN Federal Research Center, Krasnoyarsk Scientific Center of the Siberian Section, Russian Academy of Sciences, Krasnoyarsk, Russia.
FGAOU VO Ural Federal University, Ekaterinburg, Russia.
FGAOU VO Siberian Federal University, Krasnoyarsk, Russia.

Доп.точки доступа:
Drokin, N. A.; Дрокин, Николай Александрович; Kiiko, V. S.; Pavlov, A. V.; Malkin, A. I.
}
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Bulgakov, E. N.
Mixing of bound states with electron transport by a radiation field in waveguides / E. N. Bulgakov, A. F. Sadreev // J. Exp. Theor. Phys. - 1998. - Vol. 87, Is. 6. - P. 1058-1067, DOI 10.1134/1.558621. - Cited References: 27 . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
CLASSICALLY UNBOUND SYSTEM
   HALL RESISTANCE ANOMALIES
   QUANTUM WAVE-GUIDES
   POINT CONTACTS
   WIRES
   TIME
   CONDUCTANCE
Аннотация: Electron transmission in the two-, three-, and four-terminal nanostructures is considered under the influence of a radiation field. The frequency of the radiation field is tuned to the transition between the energy of a bound state and the Fermi energy of the incident electrons. The radiation induced resonant peaks and dips of the electron transport are exhibited for zero and low magnetic fields. It is shown that rotation of the radiation field polarization can effectively control the electron transport into different electrodes attached to the structures because of the symmetry of the structures. The resonant anomalies of the Hall resistance are found in a weak magnetic field. (C) 1998 American Institute of Physics. [S1063-7761(98)00412-0].

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
Abo Akad Univ, Inst Fys, Dept Phys, SF-20500 Abo, Finland
ИФ СО РАН

Доп.точки доступа:
Sadreev, A. F.; Садреев, Алмаз Фаттахович; Булгаков, Евгений Николаевич
}
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10.

Bulgakov, E. N.
The effect of bound states in microwave waveguides on electromagnetic wave propagation / E. N. Bulgakov, A. F. Sadreev // Tech. Phys. - 2001. - Vol. 46, Is. 10. - P. 1281-1290, DOI 10.1134/1.1412064. - Cited References: 15 . - ISSN 1063-7842

РУБ Physics, Applied
Рубрики:
RADIATION-FIELD
   HALL RESISTANCE
   QUANTUM WIRES
   GUIDES
Аннотация: The transmission of a TE microwave field with a frequency omega through Gamma, T, and X waveguide junctions filled with a ferromagnetic is considered. These junctions are known to have bound states with below-cutoff frequencies. A probing microwave radiation with a frequency Omega applied to the scattering region generates magnetic oscillations with frequencies omega + n Omega (where n = 0, +/-1, +/-2, ...), which resonantly combine with the bound waveguide states. This effect provides for a new method of studying bound waveguide states and efficiently controlling the transmission of microwave radiation. (C) 2001 MAIK "Nauka/Interperiodica".

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Держатели документа:
Russian Acad Sci, Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
Linkoping Univ, Dept Phys & Measurement Technol, S-58183 Linkoping, Sweden
ИФ СО РАН
Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Dept. of Phys. and Msrmt. Technology, Linkoping University, S-581 83 Linkoping, Sweden

Доп.точки доступа:
Sadreev, A. F.; Садреев, Алмаз Фаттахович; Булгаков, Евгений Николаевич
}
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