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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Lykhin A. O., Novikova G. V., Kuzubov A. A., Staloverova N. A., Sarmatova N. I., Varganov S. A., Krasnov P. O.
Заглавие : A complex of ceftriaxone with Pb(II): synthesis, characterization, and antibacterial activity study
Коллективы : RFBR [14-03-31, 170 MOJI_a]
Место публикации : J. Coord. Chem.: Taylor & Francis, 2014. - Vol. 67, Is. 16. - З2783-2794. - ISSN 0095-8972, DOI 10.1080/00958972.2014.938065. - ISSN 1029-0389
Примечания : Cited References: 48. - The reported study was supported by RFBR, research project No. 14-03-31, 170 MOJI_a and Krasnoyarsk regional fund for supporting scientific and technological activities. We thank the Center for Equipment Joint Use of the Siberian Federal University. We are grateful to the HPC Research Departments of Siberian Federal University and Moscow University Supercomputing Center (SKIF MSU "Chebyshev") for the access to the high-performance computer clusters.
Предметные рубрики: BETA-LACTAM ANTIBIOTICS
TERNARY COMPLEX
METAL-COMPLEXES
BASIS-SETS
3 DECADES
RESISTANCE
COPPER(II)
CEPHALOSPORINS
EVOLUTION
1ST-ROW
Ключевые слова (''Своб.индексиров.''): ceftriaxone lead(ii) complex--dft--ir spectroscopy--tga--antibacterial screening
Аннотация: A Pb(II) complex with ceftriaxone (H2Ceftria) antibiotic was synthesized by reaction of ceftriaxone disodium salt (hemi)heptahydrate with lead nitrate in water–ethanol medium. The complex was characterized on the basis of complexometric titration, spectrophotometric and thermogravimetric analyses, capillary electrophoresis, IR, Raman and UV–vis spectroscopies, and density functional theory calculations. Pb(II) is five-coordinate with distorted square pyramidal geometry. The coordination of Ceftria2− to Pb(II) occurs through N and O of the triazine, lactam carbonyl, carboxylate, and amine groups. The antibacterial activity study showed that Klebsiella pneumoniae is resistant to [Pb(Ceftria)]·3H2O. The antibacterial activity of [Pb(Ceftria)]·3H2O against Staphylococcus aureus is reduced compared with ceftriaxone. In contrast, the antibacterial activity of [Pb(Ceftria)]·3H2O against Escherichia coli is 28% higher than that of ceftriaxone antibiotic.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Petrov M. I., Gokhfeld D. M., Balaev D. A., Shaihutdinov K. A., Kummel R.
Заглавие : Andreev reflections and experimental current-voltage characteristics of break junctions of polycrystalline HTSC
Место публикации : Physica C: ELSEVIER SCIENCE BV, 2004. - Vol. 408: 7th International Conference on Materials and Mechanisms of Superconductive and High Temperature Superconductors (MAY 25-30, 2003, Rio de Janeiro, BRAZIL). - P620-622. - ISSN 0921-4534, DOI 10.1016/j.physc.2004.03.085
Примечания : Cited References: 3
Ключевые слова (''Своб.индексиров.''): andreev reflections--break junction--current-voltage characteristics--andreev reflections--break junction--current-voltage characteristics--andreev reflections--break junctions--elastic scattering--lattice defects--negative differential resistance--electric fields--heuristic methods--hysteresis--microcracks--polycrystalline materials--probability density function--quasicrystals--superconducting materials--yttrium barium copper oxides--current voltage characteristics
Аннотация: The temperature evolution of current-voltage characteristics (CVCs) of break junctions made from polycrystalline Y0.75Lu0.25Ba2Cu3O7 and La1.85Sr0.15CuO4 is investigated. The experimental CVCs have hysteretic features that reflect a part of a curve with negative differential resistance. The temperature evolution of the CVCs is discussed within the framework of the Kummel-Gunsenheimer-Nicolsky theory for superconductor/normal-metal/superconductor junctions considering multiple Andreev reflections. It is shown that the shape of the CVCs of break junctions is determined by the ratio of the number of "short" and "long" intergrain normal regions in the polycrystalline HTSC under investigation. (C) 2004 Elsevier B.V. All rights reserved.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Piskunova N. I.
Заглавие : Anomalies in magnetoresistance and in the bulk modulus for ferromagnetics with four-spin exchange interaction on the Kondo lattice
Место публикации : J. Phys.: Condens. Matter: IOP PUBLISHING LTD, 2006. - Vol. 18, Is. 29. - P.6859-6868. - ISSN 0953-8984, DOI 10.1088/0953-8984/18/29/023
Примечания : Cited References: 29
Предметные рубрики: MIXED-VALENCE MANGANITES
PHASE-SEPARATION
LA1-XSRXMNO3
BEHAVIOR
PECULIARITIES
TRANSITION
Ключевые слова (''Своб.индексиров.''): elastic moduli--electric resistance--ferromagnetism--function evaluation--paramagnetism--transceivers--adiabatic approximation--kondo lattice--paramagnetic state--ring exchange--magnetoresistance
Аннотация: The temperature dependence of resistivity and the bulk modulus are calculated on the Kondo lattice, with ring exchange between localized spins, using the spin-polaron and adiabatic approximation. Peak and zero values of the bulk modulus as functions of temperature and concentration are determined below the temperature of the transition to the paramagnetic state. The effects of the nearest order between transverse spin components and a value of the ring exchange between localized spins on magnetoresistivity are estimated.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev A. D., Gavrichkov V. A., Ovchinnikov S. G.
Заглавие : Quantum oscillations of resistance and magnetization in the degenerate semiconductor n-HgCr2Se4
Место публикации : J. Exp. Theor. Phys.: AMER INST PHYSICS, 1998. - Vol. 86, Is. 5. - P1026-1029. - ISSN 1063-7761, DOI 10.1134/1.558549
Примечания : Cited References: 6
Аннотация: In the magnetic field range Delta H = 8-60 kOe we observed and studied the anomalous oscillations in the magnetic field dependence of the resistance and magnetization of single crystals of n-HgCr2Se4. The absence of periodicity in 1/H in the Delta H = 8-20 kOe range can be explained by the non-Fermi-liquid behavior of the electron subsystem and agrees with the theory of the de Haas-van Alphen in systems with intermediate valence. In stronger fields, Delta H = 20-60 kOe, the amplitude of the fundamental harmonic decreases, with the number and amplitude of the higher-order harmonics increasing, As a result, noise is superimposed on the signal as magnetic field strength grows. The temperature dependence of the magnetization is the sum of the monotonic spin-wave contribution and the oscillating part. (C) 1998 American Institute of Physics. [S1063-7761(98)02205-7].
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Semenov S. V., Petrov M. I.
Заглавие : Correlation between magnetoresistance and magnetization hysteresis in a granular high-T C superconductor: Impact of flux compression in the intergrain medium
Место публикации : J. Supercond. Nov. Magn.: Springer, 2014. - Vol. 27, Is. 6. - P.1425-1429. - ISSN 1557-1939, DOI 10.1007/s10948-014-2491-6. - ISSN 1557-1947
Примечания : Cited References: 27
Предметные рубрики: HIGH-TEMPERATURE SUPERCONDUCTOR
JOSEPHSON MEDIUM
CRITICAL-STATE
YBA2CU3O7-DELTA
FIELDS
BEHAVIOR
HTSC
COMPOSITES
RESISTANCE
MOTION
Ключевые слова (''Своб.индексиров.''): granular superconductor--josephson medium--effective field--magnetoresistance--magnetization hysteresis
Аннотация: The correlation between experimental magnetic field dependences of magnetoresistance and magnetization hysteresis in granular YBa2Cu3O7 is established. Within the proposed approach, magnetoresistance is assumed to be determined by the effective field in the intergrain boundaries the ensemble of which is considered to be a Josephson medium. The effective field in the intergrain medium can be written in the form B (eff)(H)=H-4 pi M(H)x alpha, where alpha is the parameter of averaged demagnetizing factors of grains and the degree of flux compression. A comparison of experimental magnetoresistance R(H) and magnetization M(H) hysteresis dependences obtained at different external magnetic field sweep rates yields the value alpha similar to 10, which is caused by the flux compression between grains. The proposed model describes well most of the features of the magnetoresistance hysteresis in granular high-T (C) superconductors.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Baker, Syed, Prudnikova, Svetlana V., Shumilova, Anna A., Perianova, Olga V., Zharkov S. M., Kuzmin A.
Заглавие : Bio-functionalization of phytogenic Ag and ZnO nanobactericides onto cellulose films for bactericidal activity against multiple drug resistant pathogens
Место публикации : J. Microbiol. Methods. - 2019. - Vol. 159. - P.42-50. - ISSN 0167-7012, DOI 10.1016/j.mimet.2019.02.009. - ISSN 1872-8359(eISSN)
Примечания : Cited References: 59
Предметные рубрики: SILVER NANOPARTICLES
ANTIMICROBIAL ACTIVITY
SIZE
COMPOSITES
MEMBRANE
Аннотация: The present study describes the synthesis of silver and zinc oxide nanobactericides from the phytogenic source Bupleurum aureum The synthesized nanobactericides were characterized and evaluated for bio-functionalization onto bacterial cellulose membrane which was synthesized by Komagataeibactencylinus B-12068 culture strain. The synthesis of nanobacterides were initially confirmed using UV-Visible spectroscopy which indicated localized surface resonance (LSPR) peaks at 415 nm for silver nanobactericides and 280 nm for zinc nanobactericides. The nature of the capping agent for synthesized nanobactericides was predicted using FTIR which confirmed the presence of functional moieties. XRD analysis revealed their crystalline nature while morphological characteristics were studied using TEM which confirmed the polydispersity of nanobactericides with the average size in the range of 20-25 nm. The nanobactericides were tested for their antimicrobial activity against seven multi-drug resistant pathogens which were clinically isolated from patients suffering from a myriad of microbial infections. The tested pathogens had antimicrobial resistance to ten different antibiotics and have been reported to be the major cause of nosocomial infections. The nanobactericides displayed significant activity against the test pathogens. Silver nanobactericides showed the highest activity against Escherichia coli strain 55 with a 24 mm zone of inhibition while zinc oxide nanobactericides displayed the highest activity against methicillinresistant Staphylococcus aureus (MRSA) with a 20 mm inhibition zone. The bio- functionalized cellulose films (BCF) were characterized using SEM along with physicochemical analysis. The BCF's were evaluated for anti-bacterial activity against test pathogens which resulted in marked antimicrobial potential against multi-drug resistant bacteria and therefore has the potential to be utilized as an efficient alternative to counter drug resistant pathogens.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Baker, Syed, Volova, Tatiana, Prudnikova, Svetlana V., Shumilova, Anna A., Perianova, Olga, V, Zharkov S. M., Kuzmin A. R., Kondratenka, Olga, Kiryukhin, Bogdan, Shidlovskiy, Ivan P., Potkina, Zoya K., Khohlova, Olga Y., Lobova, Tatiana I.
Заглавие : Bio-hybridization of nanobactericides with cellulose films for effective treatment against members of ESKAPE multi-drug-resistant pathogens
Коллективы : Ministry of Education and Science of the Russian Federation under the scheme of 5-100: Russian Academic Excellence Project
Место публикации : Appl. Nanosci. - 2018. - Vol. 8, Is. 5. - P.1101-1110. - ISSN 2190-5509, DOI 10.1007/s13204-018-0717-9. - ISSN 2190-5517(eISSN)
Примечания : Cited References: 51. - Authors are thankful for Ministry of Education and Science of the Russian Federation for providing funding under the scheme of 5-100: Russian Academic Excellence Project. Authors are grateful for facilities provided by Siberian Federal University to carry out the present study.
Предметные рубрики: SILVER NANOPARTICLES
BACTERIAL CELLULOSE
ANTIBIOTIC-RESISTANCE
Ключевые слова (''Своб.индексиров.''): eskape--bio-hybridization--silver nanobactericides--phytogenic--bactericidal activity
Аннотация: The rapid expansion of drug-resistant pathogens has created huge global impact and development of novel antimicrobial leads is one of the top priority studies in the current scenario. The present study aims to develop bio-hybridized nanocellulose films which comprise of phytogenic silver nanobactericides. The nanobactericides were synthesized by treating 1 mM silver nitrate with aqueous extract of Chamerion angustifolium which reduced the metal salt to produce polydispersed nanobactericides which were tested against the members of ESKAPE drug-resistant communities. The synthesized silver nanobactericides were subjected to characterization with UV–visible spectra which displayed maximum absorbance at 408 nm. The bio-molecular interaction of phyto-constituents to mediate synthesis and stabilization of nanobactericides was studied with Fourier-transform infrared spectroscopy (FTIR) which depicted functional groups associated with nanobactericides. The crystalline nature was studied with X-ray diffraction (XRD) which showed Bragg’s intensities at 2θ angle which denoted (111), (200), (220), and (311) planes. The morphological characteristics of silver nanobactericides were defined with transmission electron Microscopy (TEM) image which displayed polydispersity of silver nanobactericides with size ranging from 2 to 40 nm. The synthesized nanobactericides showed a significant activity against MRSA strain with 21 mm zone of inhibition. The minimal inhibitory concentration of silver nanobactericides to inhibit the growth of test pathogens was also determined which ranged between 0.625 and 1.25 μg/ml. The silver nanobactericides were bio-hybridized onto nanocellulose films produced by Komagataeibacter xylinus B-12068 culture strain. The films were dried to determine the mechanical properties which showed increased in Young’s modulus and tensile strength in comparison with control bacterial cellulose films. Overall, the results obtained in the present investigation are promising enough to report bactericidal activity of bio-hybridized nanobactericidal films against ESKAPE. These communities are reported to cause severe threats to all forms of lives irrespective to their habitats which can lead to huge economical crisis.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Drokin N. A., Kiiko V. S., Pavlov A. V., Malkin A. I.
Заглавие : BT-30 Ceramic Electrophysical Properties
Место публикации : Refract. Ind. Ceram. - 2020. - Vol. 61, Is. 3. - P.341-348. - ISSN 1083-4877 (ISSN), DOI 10.1007/s11148-020-00484-2. - ISSN 1573-9139 (eISSN)
Примечания : Cited References: 12
Аннотация: A total complex resistance (impedance) method is used to study the electrophysical characteristics of (BeO + TiO2)-ceramics modified with TiO2 micro- and nanoparticles in an amount of 30 wt.% (BT-30). Dispersion of the actual ε′ and imaginary ε′′ components of the dielectric permittivity component and specific conductivity in the frequency range from 100 Hz to 100 MHz from room temperature to the boiling point of liquid nitrogen are determined. High values of ε′ and ε′′ in the low-frequency range are typical for structurally inhomogeneous materials due to the accumulation of electric charges at the surface and within microcrystals. Two dielectric relaxation processes associated with electrical conductivity within the body and at the surface of ceramics are detected for the first time. An increase in conductivity with an increase in the microwave field frequency above 1 MHz is explained by the appearance of a current relaxation component. The activation energy of the static resistance of ceramic specimens is determined as a function of the reciprocal temperature that depends little on the weight content of TiO2 nanoparticles and varies in the range of 0.024 – 0.10 eV This also confirms the existence of two independent conduction processes, weakly dependent on the nanoparticle content in the ceramic composition. With placement of ceramic in a high-frequency electric field, spatial charges are formed, the field of which contributes to creation of additional polarization and dielectric losses.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bulgakov E. N., Sadreev A. F.
Заглавие : Mixing of bound states with electron transport by a radiation field in waveguides
Место публикации : J. Exp. Theor. Phys.: AMER INST PHYSICS, 1998. - Vol. 87, Is. 6. - P1058-1067. - ISSN 1063-7761, DOI 10.1134/1.558621
Примечания : Cited References: 27
Предметные рубрики: CLASSICALLY UNBOUND SYSTEM
HALL RESISTANCE ANOMALIES
QUANTUM WAVE-GUIDES
POINT CONTACTS
WIRES
TIME
CONDUCTANCE
Аннотация: Electron transmission in the two-, three-, and four-terminal nanostructures is considered under the influence of a radiation field. The frequency of the radiation field is tuned to the transition between the energy of a bound state and the Fermi energy of the incident electrons. The radiation induced resonant peaks and dips of the electron transport are exhibited for zero and low magnetic fields. It is shown that rotation of the radiation field polarization can effectively control the electron transport into different electrodes attached to the structures because of the symmetry of the structures. The resonant anomalies of the Hall resistance are found in a weak magnetic field. (C) 1998 American Institute of Physics. [S1063-7761(98)00412-0].
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bulgakov E. N., Sadreev A. F.
Заглавие : The effect of bound states in microwave waveguides on electromagnetic wave propagation
Место публикации : Tech. Phys.: AMER INST PHYSICS, 2001. - Vol. 46, Is. 10. - P1281-1290. - ISSN 1063-7842, DOI 10.1134/1.1412064
Примечания : Cited References: 15
Предметные рубрики: RADIATION-FIELD
HALL RESISTANCE
QUANTUM WIRES
GUIDES
Аннотация: The transmission of a TE microwave field with a frequency omega through Gamma, T, and X waveguide junctions filled with a ferromagnetic is considered. These junctions are known to have bound states with below-cutoff frequencies. A probing microwave radiation with a frequency Omega applied to the scattering region generates magnetic oscillations with frequencies omega + n Omega (where n = 0, +/-1, +/-2, ...), which resonantly combine with the bound waveguide states. This effect provides for a new method of studying bound waveguide states and efficiently controlling the transmission of microwave radiation. (C) 2001 MAIK "Nauka/Interperiodica".
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