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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krasnov P. O., Eliseeva N. S., Kuzubov A. A.
Заглавие : Interaction of Scandium and Titanium Atoms with a Carbon Surface Containing Five- and Seven-Membered Rings
Коллективы : Ministry of Education and Science of the Russian Federation
Место публикации : J. Exp. Theor. Phys.: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 114, Is. 1. - P.80-84. - ISSN 1063-7761, DOI 10.1134/S1063776111160059. - ISSN 1090-6509
Примечания : Cited References: 25. - We are grateful to the Joint Supercomputer Center, Russian Academy of Sciences, for the possibility of using the computer cluster for our quantum-chemical calculations. This work was supported by the Ministry of Education and Science of the Russian Federation (federal program "Human Capital for Science and Education in Innovative Russia" for 2009-2013).
Предметные рубрики: MOLECULAR-HYDROGEN COMPLEXES
STORAGE
NANOTUBES
TRANSITION
ENERGY
TEMPERATURE
EXCHANGE
DYNAMICS
METALS
C60
Аннотация: The use of carbon nanotubes coated by atoms of transition metals to store molecular hydrogen is associated with the problem of the aggregation of these atoms, which leads to the formation of metal clusters. The quantum-chemical simulation of cluster models of the carbon surface of a graphene type with scandium and titanium atoms has been performed. It has been shown that the presence of five- and seven-membered rings, in addition to six-membered rings, in these structures makes it possible to strongly suppress the processes of the migration of metal atoms over the surface, preventing their clustering.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kuzubov A. A., Krasnov P. O., Kozhevnikov T. A., Popov M. A.
Заглавие : Calculation of the energy of binding of titanium and scandium complexes to the surface of carbon nanotubes
Коллективы : Analytical departmental program "Development of Higher Education Potential" [2.1.1/2584]; Russian Foundation for Basic Research [09-02-00324-a]
Место публикации : Russ. J. Phys. Chem. B. - 2009. - Vol. 3, Is. 4. - P.679-683. - ISSN 1990-7931, DOI 10.1134/S1990793109040289
Примечания : Cited References: 27. - This work was supported by the analytical departmental program "Development of Higher Education Potential (2009-2100)" (grant 2.1.1/2584) and by the Russian Foundation for Basic Research, project no. 09-02-00324-a.
Предметные рубрики: MOLECULAR-HYDROGEN COMPLEXES
STORAGE
TEMPERATURE
TRANSITION
DYNAMICS
METALS
Аннотация: Complexes of zigzag-type carbon nanotubes (CNTs) with transition metal atoms, scandium and titanium, were studied. It was demonstrated that the energy of binding of both atoms with a carbon surface decreases whereas the rate of diffusion along the surface increases with increasing nanotube diameter. The rate constant of migration of scandium atoms over a CNT surface are several orders of magnitude higher than that for titanium atoms, because the CNT surface-Sc atom binding energy is substantially lower.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Квеглис, Людмила Иосифовна, Носков Ф. М., Волочаев, Михаил Николаевич, Джее А. В.
Заглавие : Мартенситные превращения в никелиде титана через промежуточную фазу с ГЦК-решеткой
Место публикации : Физич. мезомеханика. - Томск, 2016. - Т. 19, № 2. - С. 100-107. - ISSN 1683-805X
Ключевые слова (''Своб.индексиров.''): никелид титана--пластическая деформация--мартенситное превращение--дифракция электронов--кристаллические структуры--кластеры--titanium nickelide--plastic deformation--martensitic transformation--electron diffraction--crystal structures--clusters
Аннотация: В работе рассматриваются процессы структурообразования в массивных образцах сплава Ni51Ti49, подвергнутых растягивающей нагрузке. Методами электронной микроскопии и дифракции электронов показана возможность существования фазы с ГЦК-решеткой в никелиде титана. Обнаружено, что межплоскостные расстояния ОЦК110, ГЦКШ и ГПУ002 в исследованном сплаве имеют близкие значения, что свидетельствует о возможности их взаимного полиморфного превращения. С позиции модульной самоорганизации предложена схема мартенситных превращений в никелиде титана из структуры В2 (ОЦК-решетка) в структуру В19' (ГПУ-решетка) через промежуточную фазу с ГЦК-решеткой.Structure formation in bulk Ni51Ti49 alloy specimens under tensile loading is studied. Electron microscopy and electron diffraction methods are applied to show that a phase with fcc lattice can be present in titanium nickelide. It is found that interplanar spacings bcc110, fcc111 and hcp002 in the studied alloy have close values, which demonstrates the possibility of their mutual polymorphic transformation. A scheme of B2B19' (bcchcp) martensitic transformation through an intermediate phase with fcc lattice is proposed for titanium nickelide from the standpoint of modular self-organization.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Джес, Алексей Владимирович, Носков, Федор Михайлович, Квеглис, Людмила Иосифовна, Волочаев, Михаил Николаевич, Тажибаева, Гаухар Баранбаевна
Заглавие : Особенности формирования линзовидных кристаллов при мартенситных превращениях в никелиде титана
Место публикации : Фундамент. проблемы совр. материаловед. - Барнаул: Общество с ограниченной ответственностью "Научно-исследовательский центр "Системы управления", 2016. - Т. 13, № 1. - С. 96-104. - ISSN 1811-1416
Ключевые слова (''Своб.индексиров.''): titanium nickelide--plastic deformation--martensitic transformation--lenticular crystals--bending extinction contours--method of magnetic torques--никелид титана--пластическая деформация--мартенситное превращение--линзовидные кристаллы--изгибные экстинкционные контуры--метод магнитных крутящих моментов
Аннотация: В работе рассматриваются процессы структурообразования в массивных образцах сплава Ni51Ti49 подвергнутых растягивающей нагрузке. Методами электронной микроскопии обнаружены линзовидные кристаллы, имеющие химический состав и структуру, отличающийся от состава матричного сплава. С помощью анализа изгибных экстинкционных контуров на электронно-микроскопических изображениях линзовидных кристаллов сделаны оценки внутренних напряжений в зонах локализации деформации. Показано, что образцы сплава Ni51Ti49 испытавшие множественные циклы прямых и обратных мартенситных переходов обладают ненулевой намагниченностью, вызванной ростом новой ферромагнитной фазы.The paper deals with the processes of structure formation in massive Ni51Ti49 alloy samples subjected to tensile loading. Electron microscopy revealed lenticular crystals having a chemical composition and structure, wherein the composition of the matrix alloy. By analyzing bending extinction contours on electron microscopic images of lenticular crystals made assessment of internal stresses in the areas of localization of deformation. It is shown that the alloy samples Ni51Ti49 experienced multiple cycles of direct and reverse martensitic transformations have a non-zero magnetization caused by the growth of new ferromagnetic phase.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Kveglis L. I., Volochaev M. N., Dzhes A. V., Noskov F. M.
Заглавие : Magnetic properties of plastically deformed nickel-titanium alloy
Коллективы : Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium, Институт физики им. Л.В. Киренского Сибирского отделения РАН
Место публикации : VI Euro-Asian Symposium "Trends in MAGnetism" (EASTMAG-2016): abstracts/ ed.: O. A. Maksimova, R. D. Ivantsov. - Krasnoyarsk: KIP RAS SB, 2016. - Ст.P9.30. - P.421. - ISBN 978-5-904603-06-9 (Шифр -478014040)
Примечания : References: 3
Ключевые слова (''Своб.индексиров.''): martensite transformation--ferromagnetic phase--lenticular nanocrystals
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Venugopal N., Gerasimov V. S., Ershov A. E., Karpov S. V., Polyutov S. P.
Заглавие : Titanium nitride as light trapping plasmonic material in silicon solar cell
Место публикации : Opt. Mater.: Elsevier, 2017. - Vol. 72. - P.397-402. - ISSN 09253467 (ISSN), DOI 10.1016/j.optmat.2017.06.035
Примечания : Cited References: 56
Ключевые слова (''Своб.индексиров.''): photovoltaics--plasmonics--titanium nitride
Аннотация: Light trapping is a crucial prominence to improve the efficiency in thin film solar cells. However, last few years, plasmonic based thin film solar cells shows potential structure to improve efficiency in photovoltaics. In order to achieve the high efficiency in plasmonic based thin film solar cells, traditionally noble metals like Silver (Ag) and Gold (Au) are extensively used due to their ability to localize the light in nanoscale structures. In this paper, we numerically demonstrated the absorption enhancement due to the incorporation of novel plasmonic TiN nanoparticles on thin film Silicon Solar cells. Absorption enhancement significantly affected by TiN plasmonic nanoparticles on thin film silicon was studied using Finite-Difference-Time-Domain Method (FDTD). The optimal absorption enhancement 1.2 was achieved for TiN nanoparticles with the diameter of 100 nm. The results show that the plasmonic effect significantly dominant to achieve maximum absorption enhancement g(λ) at longer wavelengths (red and near infrared) and as comparable with Au nanoparticle on thin film Silicon. The absorption enhancement can be tuned to the desired position of solar spectrum by adjusting the size of TiN nanoparticles. Effect of nanoparticle diameters on the absorption enhancement was also thoroughly analyzed. The numerically simulated results show that TiN can play the similar role as gold nanoparticles on thin film silicon solar cells. Furthermore, TiN plasmonic material is cheap, abundant and more Complementary Metal Oxide Semiconductor (CMOS) compatible material than traditional plasmonic metals like Ag and Au, which can be easy integration with other optoelectronic devices.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Drozdova A. K., Cherepanov V. N., Svetlichny V. A., Kveglis L. I., Volochaev M. N., Velikanov D. A.
Заглавие : Structure and magnetic properties of titanium nickelide nanoparticles synthesized by pulsed laser ablation method
Коллективы : International Conference on Films and Coatings
Место публикации : J. Phys. Conf. Ser.: IOP, 2017. - Vol. 857, Is. 1. - Ст.012007. - ISSN 17426588 (ISSN), DOI 10.1088/1742-6596/857/1/012007
Примечания : Cited References: 9
Ключевые слова (''Своб.индексиров.''): ablation--coatings--high resolution transmission electron microscopy--laser ablation--nanomagnetics--nanoparticles--synthesis (chemical)--titanium--transmission electron microscopy--equiatomic composition--magnetization values--ti atoms--titanium nickelide--pulsed lasers
Аннотация: We have successfully synthesized magnetic titanium nickelide nanoparticles with equiatomic composition by pulsed laser ablation method. Using transmission electron microscopy and microanalysis was revealed that particles represent the homogeneous conglomerates containing identical amount of Ni and Ti atoms. The magnetization value of nanoparticles was estimated.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Drozdova A. K., Cherepanov V. N., Svetlichny V. A., Kveglis L. I., Volochaev M. N., Velikanov D. A.
Заглавие : Superparamagnetic behavior of titanium nickelide nanoparticles obtained by laser ablation
Коллективы : Moscow International Symposium on Magnetism, Московский государственный университет им. М.В. Ломоносова, Российский фонд фундаментальных исследований
Место публикации : Moscow Int. Symp. on Magnet. (MISM-2017): 1-7 July 2017 : book of abstracts. - 2017. - Ст.2PO-J-33. - P.286
Примечания : Cited References: 2
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zakomirnyi V. I., Rasskazov I. L., Gerasimov V. S., Ershov A. E., Polyutov S. P., Karpov S. V.
Заглавие : Refractory titanium nitride two-dimensional structures with extremely narrow surface lattice resonances at telecommunication wavelengths
Место публикации : Appl. Phys. Lett.: American Institute of Physics, 2017. - Vol. 111, Is. 12. - Ст.123107. - ISSN 00036951 (ISSN), DOI 10.1063/1.5000726
Примечания : Cited References: 54. - This work was supported by the RF Ministry of Education and Science, the State contract with Siberian Federal University for scientific research in 2017–2019. Numerical calculations were performed using the MVS-1000M system at the Institute of Computational Modeling of the Siberian Branch of the Russian Academy of Sciences.
Ключевые слова (''Своб.индексиров.''): bandwidth--nanoparticles--nanostructures--optical properties--plasmons--q factor measurement--refractory materials--titanium compounds--diffractive grating--electromagnetic response--localized surface plasmon--low cost fabrication--plasmonic nanoparticle--telecommunication bandwidth--telecommunication wavelengths--two-dimensional structures--titanium nitride
Аннотация: Regular arrays of plasmonic nanoparticles have brought significant attention over the last decade due to their ability to support localized surface plasmons (LSPs) and exhibit diffractive grating behavior simultaneously. For a specific set of parameters (i.e., period, particle shape, size, and material), it is possible to generate super-narrow surface lattice resonances (SLRs) that are caused by interference of the LSP and the grating Rayleigh anomaly. In this letter, we propose plasmonic structures based on regular 2D arrays of TiN nanodisks to generate high-Q SLRs in an important telecommunication range, which is quite difficult to achieve with conventional plasmonic materials. The position of the SLR peak can be tailored within the whole telecommunication bandwidth (from ≈ 1.26 μm to ≈ 1.62 μm) by varying the lattice period, while the Q-factor is controlled by changing nanodisk sizes. We show that the Q-factor of SLRs can reach a value of 2 × 103, which is the highest reported Q-factor for SLRs at telecommunication wavelengths so far. Tunability of optical properties, refractory behavior, and low-cost fabrication of TiN nanoparticles paves the way for manufacturing cheap nanostructures with extremely stable and adjustable electromagnetic response at telecommunication wavelengths for a large number of applications.
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10.

Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Ushakov A. V., Karpov I. V., Lepeshev A. A., Fedorov L. Y., Dorozhkina E. A., Karpova O. N., Shaikhadinov A. A., Demin V. G., Bachurina E. P., Lichargin D. V., Abkaryan A. K., Zeer G. M., Zharkov S. M.
Заглавие : Particular charactristics of the synthesis of titanium nitride nanopowders in the plasma of low pressure arc discharge
Коллективы : International Scientific Conference Reshetnev Readings
Место публикации : IOP Conf. Ser.: Mater. Sci. Eng. - 2017. - Vol. 255, Is. 1. - Ст.012006. - , DOI 10.1088/1757-899X/255/1/012006
Примечания : Cited References: 26
Аннотация: The method of producing TiN nanopowders in the plasma of low pressure arc discharge in nitrogen atmosphere is discussed. The influence of gas pressure on nanopowder dispersion is studied. It is shown that the particles have nanometer size and a narrow particle size distribution.
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11.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Churilov G. N., Dudnik A. I., Osipova I. V., Vnukova N. G., Nikolaev N. S., Volochaev M. N., Tomashevich Y. V.
Заглавие : Preparation of polymers based on fullerenes and nanoparticles of titanium carbide and their properties
Коллективы : "Advanced carbon nanostructures", International conference, Физико-технический институт им. А.Ф. Иоффе РАН, Национальный исследовательский центр "Курчатовский институт", Санкт-Петербургский государственный технологический институт (технический университет)
Место публикации : 13th Int. Conf. "Adv. Carbon Nanostructures": Book of abstracts. - 2017. - Poster session 1: Fullerenes and Nanodiamond Particles. - Ст.P1-14. - P.83. - ISBN 978-5-93634-037-6
Примечания : Библиогр.: 1
Аннотация: When carbon condensate (CC) is synthesized by spraying graphite rods containing doping powders in arc discharge plasma, usually, in addition to fullerenes, nanoparticles, metal nanoparticles with a carbon shell or nanoparticles of metal carbide are formed [1]. The description of a procedure for the preparation of polymers based on fullerenes and nanodispersed titanium carbide particles and the results of investigation of these polymers will be given in this paper. Titanium and titanium oxide are used as doping powders. The solutions extracted with carbon disulfide are filtered through paper filters. According to X-ray diffraction analysis and transmission electron microscope, the carbon disulphide extract from CC synthesized with the inputting of metallic titanium, does not contain nanoparticles of this metal or its carbide and is characterized by the presence of fullerite clusters (extract 1). While the extract from the CC synthesized with the titanium oxide inputting contains TiC nanoparticles with size of 7–10 nm, while fullerenes are also contained, but in the amorphous state (extract 2) of Fig.1. HPLC analysis of the fullerenes toluene solution, obtained by redissolution of extract 1, allowed to isolate the fullerenes with the usual composition and with the usual ratio between components (C60 – 74.4 %, C70 – 18.9 % and higher fullerenes – 6.7 %). The redissolution of extract 2 in toluene, did not allow to obtain fullerenes solution. Thus, the presence of nanodispersive particles of TiC in the fullerenes solution, upon their drying, leads to polymers formation.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zakomirnyi V. I., Rasskazov I. L., Gerasimov V. S., Ershov A. E., Polyutov S. P., Karpov S. V., Agren H.
Заглавие : Titanium nitride nanoparticles as an alternative platform for plasmonic waveguides in the visible and telecommunication wavelength ranges
Место публикации : Photonics Nanostruc. Fundam. Appl. - 2018. - Vol. 30. - P.50-56. - ISSN 15694410 (ISSN), DOI 10.1016/j.photonics.2018.04.005
Примечания : Cited References: 85. - This work was supported by the RF Ministry of Education and Science, the State contract with Siberian Federal University for scientific research in 2017–2019 and SB RAS Program No II.2P (0358-2015-0010).
Ключевые слова (''Своб.индексиров.''): nanoparticle--titanium nitride--surface plasmon polariton--plasmon waveguide--refractory plasmonics
Аннотация: We propose to utilize titanium nitride (TiN) as an alternative material for linear periodic chains (LPCs) of nanoparticles (NPs) which support surface plasmon polariton (SPP) propagation. Dispersion and transmission properties of LPCs have been examined within the framework of the dipole approximation for NPs with various shapes: spheres, prolate and oblate spheroids. It is shown that LPCs of TiN NPs support high-Q eigenmodes for an SPP attenuation that is comparable with LPCs from conventional plasmonic materials such as Au or Ag, with the advantage that the refractory properties and cheap fabrication of TiN nanostructures are more preferable in practical implementations compared to Au and Ag. We show that the SPP decay in TiN LPCs remains almost the same even at extremely high temperatures which is impossible to reach with conventional plasmonic materials. Finally, we show that the bandwidth of TiN LPCs from non-spherical particles can be tuned from the visible to the telecommunication wavelength range by switching the SPP polarization, which is an attractive feature for integrating these structures into modern photonic devices.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zeer G. M., Zelenkova E. G., Nikolaeva N. S., Zharkov S. M., Abkaryan A. K., Mikheev A. A.
Заглавие : Microstructure and phase composition of the two-phase ceramic synthesized from titanium oxide and zinc oxide
Место публикации : Sci. Sinter. - 2018. - Vol. 50, Is. 2. - P.173-181. - ISSN 0350820X (ISSN), DOI 10.2298/SOS1802173Z
Примечания : Cited References: 22
Ключевые слова (''Своб.индексиров.''): nanopowders--titanium oxide--zinc oxide--solid phase reaction--ceramic
Аннотация: We have made investigations of the phase formation and microstructure on the ceramics obtained from a starting nanopowder mixture with the weight ratio ZnO : TiO2 = 4 : 1. Ceramic is obtained at different sintering temperatures, namely, 948, 1223 and 1473 К. Using the characterization methods of electron microscopy, energy dispersive microanalysis and X-ray diffraction phase analysis it has been shown that the ceramics structure is consisted of two dispersed phases of Zn2TiO4 and ZnO with the grain sizes being in range 0,5-1 μm. It has been found also that, at ceramic`s sintering temperature of 1223 К, the solid phase interactions are completed with the structure ZnO : Zn2TiO4 ≈ 1 : 1,5 phase ratio.
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14.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Zakomirnyi V. I., Rasskazov I. L., Gerasimov V. P., Ershov A. E., Ågren H., Polyutov S. P., Karpov S. V.
Заглавие : Ultra-narrow surface lattice resonances in periodic structures of refractory titanium nitride nanodiscs
Коллективы : Novel Optical Materials and Applications, Topical Meeting, OSA Optics and Photonics Congress
Место публикации : 14th Topical Meeting Novel Optical Materials and Applications: program. - 2018. - Polaritonics. - Ст.NOW4J.3. - P.85
Аннотация: We show that regular arrays of TiN nanodiscs support high-Q surface lattice resonances at telecom range. The obtained data open new prospects for utilization of refractory TiN in new photonics interconnects operating at high temperatures.
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15.

Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Anikeev S. G., Artyukhova N. V., Kaftaranova M. I., Khodorenko V. N., Monogenov A. N., Volochaev M. N., Garin A. S., Mamazakirov O. R.
Заглавие : Using titanium additives to produce high porous tiNi-based alloys with martensitic transformations
Коллективы : International Conference on Physical Mesomechanics. Materials with Multilevel Hierarchical Structure and Intelligent Manufacturing Technology 2020
Место публикации : AIP Conf. Proc. - 2020. - Vol. 2310. - Ст.020018. - DOI 10.1063/5.0034809
Примечания : Cited References: 13. - The study is funded by the Russian Science Foundation (project No. 19-79-10045)
Аннотация: Structural features of porous TiNi-based materials with Ti additives produced by diffusion sintering have been studied. TiNi powder fraction with a size of 100–160 µm used for sintering provides highly porous material. It is found that increased concentrations of Ti additives decrease the porosity coefficient of the material and increase the volumetric content of the secondary Ti2Ni and Ti4Ni2 (0, N, C) phases. It is shown that Ti powder additives can be used to improve the atomic composition of the TiNi compound.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Pavlov A. V., Kveglis L. I., Saprykin D. N., Nasibullin R. T., Kalitova A. A., Velikanov D. A., Nemtsev I. V., Kantai N.
Заглавие : Emergence of ferromagnetism in nanoparticles of BeTiO3 ceramic with the perovskite structure
Место публикации : Inorg. Mater.: Appl. Res. - 2021. - Vol. 12, Is. 1. - P.88-93. - ISSN 20751133 (ISSN), DOI 10.1134/S2075113321010330
Примечания : Cited References: 21. - The part of the work involving calculations was supported by the Russian Science Foundation (grant no. 18-19-00268)
Аннотация: Emergence of ferromagnetism and an increase in the electrical conductance of BeTiO3 beryllium ceramic with the perovskite structure were discovered experimentally. To explain the reason for appearance of the metallic properties, models are proposed, and calculations of the electronic structure of nanoclusters with different short-range order are performed.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kveglis, Ludmila I., Noskov, Fedor M., Volochaev M. N., Nyavro, Alexander V., Filarowski, Aleksander
Заглавие : Magnetic properties of nickel-titanium alloy during martensitic transformations under plastic and elastic deformation
Место публикации : Symmetry. - 2021. - Vol. 13, Is. 4. - Ст.665. - ISSN 2073-8994(eISSN), DOI 10.3390/sym13040665
Примечания : Cited References: 61
Предметные рубрики: NITI SHAPE-MEMORY
CRYSTAL-STRUCTURE
WAVE MECHANICS
TRANSITIONS
Аннотация: This paper focuses on the processes of the occurrence of magnetization during structure formation in samples of Ni51Ti49 alloy under deformation conditions. The possibility of the existence of a phase with an FCC (face-centered cubic) lattice in titanium nickelide has been demonstrated by electron microscopy and electron diffraction. It has been discovered that the interplanar distances of BCC110 (body-centered cubic), FCC111, and HCP002 (hexagonal close packed) in the alloy under study have similar values, which indicates the possibility of their mutual polymorphic transformation. Based on the modular self-organization, a scheme of martensitic transformations in titanium nickelide from the B2 structure (BCC lattice) to the B19' structure (HCP lattice) through an intermediate phase with an FCC lattice is proposed. It is shown that lenticular crystals appear in the Ni51Ti49 alloy under tensile deformation until rupture, which is accompanied by the onset of ferromagnetism. The effect of magnetization in Ni51Ti49 samples when immersed in liquid nitrogen has been also discovered. In this case, the reason for the appearance and disappearance of magnetization can be associated with microdeformation processes caused by direct and reverse martensitic transitions that occur during cooling and heating of the samples.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Baron F. A., Mikhlin, Yurii L., Molokeev M. S., Rautskiy M. V., Tarasov I. A., Volochaev M. N., Shanidze L. V., Lukyanenko A. V., Smolyarova T. E., Konovalov, Stepan O., Zelenov, Fyodor, V, Tarasov A. S., Volkov N. V.
Заглавие : Structural, optical, and electronic properties of Cu-doped TiNxOy grown by ammonothermal atomic layer deposition
Коллективы : RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science [20-42-240013]; Government of the Russian Federation for Creation of World Tier Laboratories [075-15-2019-1886]
Место публикации : ACS Appl. Mater. Interfaces. - 2021. - Vol. 13, Is. 27. - P.32531-32541. - ISSN 1944-8244, DOI 10.1021/acsami.1c08036. - ISSN 1944-8252(eISSN)
Примечания : Cited References: 69. - This research was funded by the RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science (project code 20-42-240013) and by the grant of the Government of the Russian Federation for Creation of World Tier Laboratories (contract no. 075-15-2019-1886)
Предметные рубрики: OXYNITRIDE THIN-FILMS
TITANIUM-NITRIDE
CONFORMAL TIN
Аннотация: Copper-doped titanium oxynitride (TiNxOy) thin films were grown by atomic layer deposition (ALD) using the TiCl4 precursor, NH3, and O2 at 420 °C. Forming gas was used to reduce the background oxygen concentration and to transfer the copper atoms in an ALD chamber prior to the growth initiation of Cu-doped TiNxOy. Such forming gas-mediated Cu-doping of TiNxOy films had a pronounced effect on their resistivity, which dropped from 484 ± 8 to 202 ± 4 μΩ cm, and also on the resistance temperature coefficient (TCR), which decreased from 1000 to 150 ppm °C–1. We explored physical mechanisms causing this reduction by performing comparative analysis of atomic force microscopy, X-ray photoemission spectroscopy, X-ray diffraction, optical spectra, low-temperature transport, and Hall measurement data for the samples grown with and without forming gas doping. The difference in the oxygen concentration between the films did not exceed 6%. Copper segregated to the TiNxOy surface where its concentration reached 0.72%, but its penetration depth was less than 10 nm. Pronounced effects of the copper doping by forming gas included the TiNxOy film crystallite average size decrease from 57–59 to 32–34 nm, considerably finer surface granularity, electron concentration increase from 2.2(3) × 1022 to 3.5(1) × 1022 cm–3, and the electron mobility improvement from 0.56(4) to 0.92(2) cm2 V–1 s–1. The DC resistivity versus temperature R(T) measurements from 4.2 to 300 K showed a Cu-induced phase transition from a disordered to semimetallic state. The resistivity of Cu-doped TiNxOy films decreased with the temperature increase at low temperatures and reached the minimum near T = 50 K revealing signatures of the quantum interference effects similar to 2D Cu thin films, and then, semimetallic behavior was observed at higher temperatures. In TiNxOy films grown without forming gas, the resistivity decreased with the temperature increase as R(T) = – 1.88T0.6 + 604 μΩ cm with no semimetallic behavior observed. The medium range resistivity and low TCR of Cu-doped TiNxOy make this material an attractive choice for improved matching resistors in RF analog circuits and Si complementary metal–oxide–semiconductor integrated circuits.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Elesina V. I., Churilov G. N., Vnukova N. G., Nikolaev N. S., Glushenko G. A., Isakova V. G.
Заглавие : Mechanical activation of fullerene containing soot during extraction of higher and endohedral metallofullerenes
Место публикации : Fuller. Nanotub. Carbon Nanostruct. - 2022. - Vol. 30, Is. 5. - P.553-558. - ISSN 1536383X (ISSN), DOI 10.1080/1536383X.2021.1966421
Примечания : Cited References: 33
Аннотация: For extraction of higher fullerenes and endohedral metallofullerenes (EMF) with yttrium from fullerene-containing carbon soot (soot) obtained by combined spraying of graphite and yttrium oxide powders in an arc plasma, we developed a device (Extractor*) that provides mechanical activation effects on agents combined with filtration. It has been shown that the soot recovery percentage of a mixture of higher fullerenes and EMF with different solvents (carbon disulfide, o-xylene, pyridine) and the EMF mass fraction in the mixture is significantly higher than in the extraction with a Soxhlet apparatus traditionally used for these purposes. The time spent on the extraction process is reduced significantly. Due to a known reaction with titanium chloride (TiCl4) and removal of a solution of empty fullerenes, subsequent bonding of EMF with yttrium into an insoluble complex directly in the extractor allows the product to be significantly enriched with EMF. In general, we were able to significantly reduce both the duration of extraction of the fullerenes mixture and EMF and the production of EMF separately.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shanidze L. V., Tarasov A. S., Rautskiy M. V., Zelenov F. V., Konovalov S. O., Nemtsev I. V., Voloshin A. S., Tarasov I. A., Baron F. A., Volkov N. V.
Заглавие : Cu-doped TiNxOy thin film resistors DC/RF performance and reliability
Коллективы : RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science [20-42-240013]; Government of the Russian Federation for Creation ofWorld Tier Laboratories [075-15-2019-1886]
Место публикации : Appl. Sci. - 2021. - Vol. 11, Is. 16. - Ст.7498. - ISSN 2076-3417(eISSN), DOI 10.3390/app11167498
Примечания : Cited References: 13. - This research was funded by RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, project code 20-42-240013 and by Grant of the Government of the Russian Federation for Creation ofWorld Tier Laboratories (contract No. 075-15-2019-1886)
Предметные рубрики: GROWTH
Аннотация: We fabricated Cu-doped TiNxOy thin film resistors by using atomic layer deposition, optical lithography, dry etching, Ti/Cu/Ti/Au e-beam evaporation and lift-off processes. The results of the measurements of the resistance temperature dependence, non-linearity, S-parameters at 0.01–26 GHz and details of the breakdown mechanism under high-voltage stress are reported. The devices’ sheet resistance is 220 ± 8 Ω/□ (480 ± 20 µΩ*cm); intrinsic resistance temperature coefficient (TCR) is ~400 ppm/°C in the T-range of 10–300 K; and S-parameters versus frequency are flat up to 2 GHz with maximum variation of 10% at 26 GHz. The resistors can sustain power and current densities up to ~5 kW*cm−2 and ~2 MA*cm−2, above which they switch to high-resistance state with the sheet resistance equal to ~200 kΩ/□ (~0.4 Ω*cm) caused by nitrogen and copper desorption from TiNxOy film. The Cu/Ti/TiNxOy contact is prone to ageing due to gradual titanium oxidation while the TiNxOy resistor body is stable. The resistors have strong potential for applications in high-frequency integrated and hybrid circuits that require small-footprint, medium-range resistors of 0.05–10 kΩ, with small TCR and high-power handling capability.
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