Библиотека института физики им. Л.В. Киренского СО РАН

Главная

Базы данных

Труды сотрудников ИФ СО РАН - результаты поиска

Вид поиска

Каталог книг и брошюр библиотеки ИФ СО РАН

Каталог журналов библиотеки ИФ СО РАН

Труды сотрудников ИФ СО РАН

Область поиска

в найденном

Найдено в других БД:

Каталог книг и брошюр библиотеки ИФ СО РАН (1)

Формат представления найденных документов:
полный	информационный	краткий

Отсортировать найденные документы по:
автору	заглавию	году издания	типу документа

Поисковый запрос: (<.>K=conversion<.>)

Общее количество найденных документов : 53
Показаны документы с 1 по 10

1-10 11-20 21-30 31-40 41-50 51-53

Morphology stability of polymethylmethacrylate nanospheres formed in water-acetone dispersion medium / I. V. Nemtsev [et al.] // Appl. Phys. A. - 2019. - Vol. 125, Is. 10. - Ст. 738, DOI 10.1007/s00339-019-3036-4. - Cited References: 93 . - ISSN 0947-8396. - ISSN 1432-0630

РУБ Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
OPAL PHOTONIC CRYSTALS
POLY(METHYL METHACRYLATE)
UP-CONVERSION
Аннотация: The aim of this study is to develop a manufacturing technique of polymethylmethacrylate (PMMA) nanospheres to produce a more stable opal template. Water-acetone mixture was used as a dispersion medium to synthesize a PMMA opal structure. Morphology features, IR vibrational spectra and glass transition temperatures of the PMMA nanospheres formed in the water-acetone dispersion medium (nanospheres A) have been studied comparing with the same prepared in distilled water solution without acetone (nanospheres B). A dependence of a shrinkage degree of the nanoparticles on the acetone volume has been investigated. It has been revealed that under an electron beam action the shrinkage degree of the nanospheres A is in the range of 7-16% while the shrinkage of the nanospheres B is 18-25% at the same conditions. The nanospheres A are less flexible and soft as compared to the nanospheres B. Additionally, an ability of the PMMA nanoparticles fabricated in the water-acetone dispersion medium to form the ordered opal structures is demonstrated to be the similar to the nanospheres B.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
Russian Acad Sci, Fed Res Ctr, Krasnoyarsk Sci Ctr, Siberian Branch, 50 Akademgorodok, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Kirensky Inst Phys, Fed Res Ctr, Krasnoyarsk Sci Ctr,Siberian Branch, 50 Akademgorodok,12 Str, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, 79 Svobodny Pr, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Special Designing & Technol Bur, Nauka Krasnoyarsk Sci Ctr, Siberian Branch, 50 Akademgorodok,45 Str, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Nemtsev, I. V.; Немцев, Иван Васильевич; Shabanova, Olga V.; Shestakov, N. P.; Шестаков, Николай Петрович; Cherepakhin, A. V.; Черепахин, Александр Владимирович; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич
}
Найти похожие

Popov, A. K.
Generation, amplification, frequency conversion, and reversal of propagation of THz photons in nonlinear hyperbolic metamaterial / A. K. Popov, S. A. Myslivets // Opt. Lett. - 2017. - Vol. 42, Is. 20. - P. 4151-4154, DOI 10.1364/OL.42.004151. - Cited References: 13. - Army Research Office (ARO) (W911NF-14-1-0619); Russian Foundation for Basic Research (RFBR) (15-02-03959A). The authors thank I. S. Nefedov for helpful discussions. . - ISSN 0146-9592
Кл.слова (ненормированные):
Carbon -- Metamaterials -- Optical frequency conversion -- Photons -- Terahertz waves -- Yarn -- Directed energy -- Electromagnetic modes -- Entangled photons -- Nonlinear hyperbolic -- Optical parametric amplification -- Proof of principles -- Three wave mixing -- THz photon -- Optical parametric amplifiers
Аннотация: We propose metamaterial (MM) that supports a mixture of three or more normal and backward electromagnetic modes with equal co-directed phase velocities and mutually contra-directed energy fluxes. This enables extraordinary three-wave mixing, greatly enhanced optical parametric amplification, and frequency-changing generation of entangled photons in the reflection direction. Proof-of-principle numerical simulation of such processes is presented based on the particular example of the wave-guided terahertz waves contra-propagating in the MM made of carbon nanotubes.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
Birck Nanotechnology Center, Purdue University, West Lafayette, IN, United States
Kirensky Institute of Physics, Federal Research Center KSC, SB RAS, 50, Akademgorodok, Krasnoyarsk, Russian Federation
Siberian Federal University, 79 Svobodny Av., Krasnoyarsk, Russian Federation

Доп.точки доступа:
Myslivets, S. A.; Мысливец, Сергей Александрович
}
Найти похожие

DFT investigation of electronic structures and magnetic properties of halides family MeHal3 (Me=Ti, Mo,Zr,Nb, Ru, Hal=Cl,Br,I) one dimensional structures / A. A. Kuzubov [et al.] // J. Magn. Magn. Mater. - 2017. - Vol. 440: EURO-Asian Symposium on Trends in Magnetism (EASTMAG) (AUG 15-19, 2016, Siberian Fed Univ, Krasnoyarsk, RUSSIA). - P. 93-96, DOI 10.1016/j.jmmm.2016.12.054. - Cited References:16. - This work was supported by the Russian Science Foundation, Project no. 16-13-00060. N.S.M. thanks the Russian Foundation for Basic Research, project RFBR 16-32-60003 mol_a_dk, for the financial support of ZrIINF3/INF, TiIINF3/INF and NbIINF3/INF electronic structure calculations . - ISSN 0304-8853. - ISSN 1873-4766

РУБ Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
INITIO MOLECULAR-DYNAMICS
TOTAL-ENERGY CALCULATIONS
AUGMENTED-WAVE
Кл.слова (ненормированные):
Transition metal trihalides -- Magnetic properties -- Thermoelectric -- conversion -- Density functional theory
Аннотация: Using DFT GGA calculations, electronic structure and magnetic properties of wide family of transition metal trihalides (TMHal3) (Zr, Ti and Nb iodides, Mo, Ru, Ti and Zr bromides and Ti or Zr chlorides) are investigated. These structures consist of transition metal atoms chains surrounded by halides atoms. Chains are connected to each other by weak interactions. All TMHal3 compounds were found to be conductive along chain axis except of MoBr3 which is indirect gap semiconductor. It was shown that NbI3 and MoBr3 have large magnetic moments on metal atoms (1.17 and 1.81 µB, respectively) but other TMHal3 materials have small or zero magnetic moments. For all structures ferromagnetic and anti-ferromagnetic phases have almost the same energies. The causes of these properties are debated.

Смотреть статью,
WOS,
Читать в сети ИФ

Доп.точки доступа:
Kuzubov, A. A.; Кузубов, Александр Александрович; Kovaleva, E. A.; Ковалева, Евгения Андреевна; Popova, M. I.; Kholtobina, A. S.; Mikhaleva, N. S.; Михалева, Наталья Сергеевна; Visotin, M. A.; Высотин Максим Александрович; Fedorov, A. S.; Федоров, Александр Семенович; Russian Science Foundation [16-13-00060]; Russian Foundation for Basic Research [RFBR 16-32-60003 mol_a_dk]; Euro-Asian Symposium "Trends in MAGnetism"(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); "Trends in MAGnetism", Euro-Asian Symposium(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); Институт физики им. Л.В. Киренского Сибирского отделения РАН
}
Найти похожие

    Microstrip resonator for nonlinearity investigation of thin magnetic films and magnetic frequency doubler / B. A. Belyaev, A. O. Afonin, A. V. Ugrymov [et al.] // Rev. Sci. Instrum. - 2020. - Vol. 91, Is. 11. - Ст. 114705, DOI 10.1063/5.0009045. - Cited References: 40. - This work was supported by the Russian Science Foundation under Grant No. 19-72-10047 . - ISSN 0034-6748
   Перевод заглавия: Микрополосковый резонатор для исследования нелинейностей в тонких магнитных пленках и магнитного умножителя частоты на два
Кл.слова (ненормированные):
Binary alloys -- Conversion efficiency -- Efficiency -- Frequency doublers -- Iron alloys -- Magnetic devices -- Magnetic films -- Microwave resonators -- Silica -- Thin films
Аннотация: A structure that consists of a λ/4 stepped-impedance microstrip resonator is proposed as an instrument for the investigation of nonlinear effects in thin magnetic films and also can be used as a microwave frequency doubler. A conversion efficiency of 0.65% is observed at a one-layer 100 nm Ni80Fe20 thin film at an input signal level of 4.6 W for a 1 GHz probe signal. The maximum measured conversion efficiency (1% at 1 GHz) was achieved for the 9-layer Ni80Fe20 film where 150 nm magnetic layers were separated by SiO2 layers.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
Kirensky Institute of Physics SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Belyaev, B. A.; Беляев, Борис Афанасьевич; Afonin, A. O.; Афонин, Алексей Олегович; Ugryumov, A. V.; Угрюмов, Андрей Витальевич; Govorun, I. V.; Говорун, Илья Валерьевич; Solovev, P. N.; Соловьев, Платон Николаевич; Leksikov, An. A.; Лексиков, Андрей Александрович
}
Найти похожие

    Thermometry and up-conversion luminescence of Ln3+ (Ln = Er, Ho, Tm)-doped double molybdate LiYbMo2O8 / X. Y. Yun, J. Zhou, Y. H. Zhu [et al.] // J. Mater. Sci.: Mater. Electron. - 2020. - Vol. 31, Is. 21. - P. 18370-18380, DOI 10.1007/s10854-020-04382-8. - Cited References: 41. - This work is supported by the National Natural Science Foundation of China (No. 21576002 and 61705003) and Beijing Technology and Business University Research Team Construction Project (No. PXM2019_014213_000007) . - ISSN 0957-4522. - ISSN 1573-482X
   Перевод заглавия: Термометрия и апконверсионная люминесценции двойного молибдата LiYbMo2O8, легированного Ln (3+) (Ln = Er, Ho, Tm)

РУБ Engineering, Electrical & Electronic + Materials Science, Multidisciplinary + Physics, Applied + Physics, Condensed Matter
Рубрики:
TEMPERATURE SENSING BEHAVIOR
   OPTICAL THERMOMETRY
   EMISSION
   PHOSPHOR
Аннотация: The discovery of stable and highly sensitive up-conversion (UC) phosphors using the fluorescence intensity ratio (FIR) is a significant challenge in the field of optical temperature sensor. Er3+/Ho3+/Tm3+-doped LiYbMo2O8 UC phosphors with excellent luminescence properties were successfully synthesized through a high-temperature solid-state reaction, and the crystal structure and UC luminescence properties were discussed in detail. The UC process has been investigated by spectra pump power dependence and further explained via the energy level diagram. All emission processes about Er3+ ions and Ho3+ ions are two-photon processes and the blue emission process about Tm3+ ions is a combination of two-photon process and three-photon process. Thermal sensing performances depended on FIR technology were estimated and the sensitivities of LiYb1−xMo2O8:xLn3+ included absolute sensitivity (Sa) and relative sensitivity (Sr) can produce particular change rules with the temperature, which can serve as excellent candidates for applications in optical temperature sensing. With the increase of temperature, the maximum values of Sr of LiYb1−xMo2O8:xLn3+ are 1.16% K−1 (0.05Er3+), 0.25% K−1 (0.01Ho3+), and 0.51% K−1 (0.01Tm3+), respectively. In addition, the Sa value of LiYb0.95Mo2O8:0.05Er3+ phosphor will reach the maximum (1.08% K−1) at 475 K, while the maximum values of Sa of LiYb0.99Mo2O8:0.01Ho3+ and LiYb0.99Mo2O8:0.01Tm3+ are 0.16% K−1, 0.14% K−1.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
Beijing Technol & Business Univ, Sch Sci, Beijing 100048, Peoples R China.
RAS, Fed Res Ctr, Kirensky Inst Phys, Lab Crystal Phys,KSC,SB, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.

Доп.точки доступа:
Yun, Xiangyan; Zhou, Jun; Zhu, Yaohui; Molokeev, M. S.; Молокеев, Максим Сергеевич; Jia, Yetong; Wei, Chao; Xu, Denghui; Sun, Jiayue
}
Найти похожие

    Structural analysis and optical temperature sensing performance of Eu3+-doped Ba3In(PO4)3 / G. Q. Zhang, M. S. Molokeev, Q. C. Ma [et al.] // CrystEngComm. - 2020. - Vol. 22, Is. 35. - P. 5809-5817, DOI 10.1039/d0ce00997k. - Cited References: 52. - This work was supported by the National Natural Science Foundation of China (Grant No. 51802172) and the Qinghai Provincial Natural Science Foundation for Young Scholars (No. 2018-ZJ-957Q) . - ISSN 1466-8033
   Перевод заглавия: Структурный анализ и эффективность оптического измерения температуры Ba3In(PO4)3, легированного Eu3+

РУБ Chemistry, Multidisciplinary + Crystallography
Рубрики:
FLUORESCENCE INTENSITY RATIO
UP-CONVERSION EMISSIONS
RARE-EARTH IONS
Аннотация: Eu3+-Doped Ba3In(PO4)3 was synthesized through a high-temperature solid-phase method. According to the structure refinement based on X-ray diffraction and density functional theory, the crystal and energy band structures of Ba3In(1−x)(PO4)3:xEu3+ were studied and analyzed in detail. The effect of Eu3+ doping concentrations on emission was studied at an excitation wavelength of 393 nm. For the material Ba3In(1−x)(PO4)3:xEu3+(x = 0.01–0.30), the optimal doping level is confirmed to be 0.18. Due to the thermal quenching differences of Eu3+ at the 5D0 and 5D1 energy levels, and based on the temperature-variable fluorescence intensity ratio between emission peaks, the optical temperature measurement performance of this material in the temperature range from 298.15 K to 623.15 K was characterized, and the maximum absolute and relative sensor sensitivities (Sa and Sr) were determined to be 0.1002 K−1 and 4.058%, respectively. With temperature as the only variable, the color of the phosphor changes from red to yellow light with rising temperature. Besides, Sa and Sr values of this phosphor are comparable to other sensing materials. The results indicate that Eu3+-doped Ba3In(PO4)3 phosphors have great potential to be applied in optical temperature sensing.

Смотреть статью,
Scopus,
WOS
Держатели документа:
Qinghai Univ, Qinghai Prov Engn Res Ctr High Performance Light, Qinghai Prov Key Lab New Light Alloys, Xining 810016, Peoples R China.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.

Доп.точки доступа:
Zhang, Guangqing; Molokeev, M. S.; Молокеев, Максим Сергеевич; Ma, Qianchao; Yang, Xuening; Han, Shuiquan; Chen, Q.i.; Zhong, Binnian; Ma, Bin
}
Найти похожие

    Crystal structure characterization and up-conversion luminescent properties of BaIn2O4 phosphor / S. Chen [et al.] // J. Lumin. - 2017. - Vol. 192. - P. 218-223, DOI 10.1016/j.jlumin.2017.06.034. - Cited References: 29. - This present work was supported by the National Natural Science Foundations of China (Grant No. 51202226), the Fundamental Research Funds for the Central Universities (Grant nos. 2652016051, 2652016037), and Science and Technology Innovation Fund of the China University of Geosciences (Beijing) (Grant no. 201511415021). . - ISSN 0022-2313
   Перевод заглавия: Кристаллическая структура и апконверсионные люминесцентные свойства BaIn2O4
Кл.слова (ненормированные):
Crystal structure -- Up-conversion -- BaIn2O4
Аннотация: Er3+ / Yb3+ doped BaIn2O4 up-conversion (UC) phosphors are synthesized and their UC luminescent properties are characterized. BaIn2O4 has P21/c space group but Rietveld refinement suggests it has twice smaller cell parameter (a = 10.3975 Å, b = 5.8295 Å, c = 14.4457 Å) and volume than previous reported structure. Refinement also reveals Er3+/Yb3+ replaces In3+ ions in lattice because of the existence of InO6 octahedra. In these BaIn2O4 phosphors, co-doping with Yb3+ ions changes the predominant UC emission from green ( 2H11/2, 4S3/2 → 4I15/2 of Er3+) to red (about 665 nm, 4F9/2 → 4I15/2 of Er3+). By controlling of Er3+/Yb3+ concentrations, the BaIn2O4 phosphors have the potential of generating various UC spectra and color tunability. The pumping powers study shows two-photon process in these phosphors.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
School of Materials Science and Technology, Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, China University of Geosciences, Beijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation

Доп.точки доступа:
Chen, S.; Wang, W.; Wang, K.; Guan, M.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Mei, L.; Huang, Z.
}
Найти похожие

Upconversion luminescence of CsScF4 crystals doped with erbium and ytterbium / D. A. Ikonnikov [et al.] // Opt. Mater. - 2016. - Vol. 60. - P. 584-589, DOI 10.1016/j.optmat.2016.09.016. - Cited References:33. - The authors are grateful to D. L. Chertkova for excellent technical assistance. The work was partially supported by the Russian Foundation for Basic Research Grant 15-52-53080, by the Russian President Grant SS-7612.2016.2, and by Project No0358-2015-0012 of SB RAS Program NoII.2P. . - ISSN 0925-3467. - ISSN 1873-1252

РУБ Materials Science, Multidisciplinary + Optics
Рубрики:
MODULATED STRUCTURE
   LANTHANIDE
   NANOCRYSTALS
   PHOSPHORS
Кл.слова (ненормированные):
Fluoride crystals -- Erbium -- Ytterbium -- Up-conversion -- Luminescence -- Crystal structure -- Power dependence -- Pump wavelength dependence
Аннотация: Tetragonal CsScF4 crystals doped with (5 at.%) Er and Er/Yb (0.5 at.%/5 at.%) are grown and their crystal structure is determined to belong to Pmmn space group. Er and Yb ions are shown to occupy distorted octahedral Sc sites with the center of inversion. Bright visible upconversion luminescence was observed under 970-980 nm pumping with red (4F9/2), yellow (4S3/2) and green (2H11/2) bands of comparable intensity. UCL tuning curves maximize at 972 nm (CSF:Er) and at 969.7 nm (CSF:Er,Yb) pumping wavelengths. Different ratios between yellow-green and red luminescence intensities in CSF:Er and CSF:Er, Yb are explained by contribution of cross-relaxation in CSF:Er UCL UC in CSF:Er is a three stage process while UC in CSF:Er, Yb is a two stage process. The peculiarities of power dependences are explained by the power-dependent repopulation between starting levels of UC. (C) 2016 Elsevier B.V. All rights reserved.

Смотреть статью,
WOS,
Читать в сети ИФ
Держатели документа:
Siberian Fed Univ, Krasnoyarsk, Russia.
LV Kirenskii Inst Phys, Krasnoyarsk, Russia.
Far Eastern State Transport Univ, Khabarovsk, Russia.

Доп.точки доступа:
Ikonnikov, D. A.; Voronov, V. N.; Воронов, Владимир Николаевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Russian Foundation for Basic Research [15-52-53080]; Russian President [SS-7612.2016.2, 0358-2015-0012, II.2P]
}
Найти похожие

    Triple molybdate scheelite-type upconversion phosphor NaCaLa(MoO4)3:Er3+/Yb3+: Structural and spectroscopic properties / C. S. Lim [et al.] // Dalton Trans. - 2016. - Vol. 45, Is. 39. - P. 15541-15551, DOI 10.1039/c6dt02378a. - Cited References: 71 . - ISSN 1477-9226
   Перевод заглавия: Тройной молибдат со структурой шеелита NaCaLa(MoO4)3:Er3+/Yb3+: структурные и спектроскопические свойства
Кл.слова (ненормированные):
Light emission -- Optical properties -- Phosphors -- Sol-gel process -- Sol-gels -- Tungstate minerals -- After-heat treatment -- Crystallized particles -- Homogeneous morphology -- Photoluminescence emission -- Spectroscopic property -- Triple molybdates -- Up-conversion emission -- Upconversion phosphors -- Optical emission spectroscopy
Аннотация: Triple molybdate NaCaLa(1-x-y)(MoO4)3:xEr3+,yYb3+ (x = y = 0, x = 0.05 and y = 0.45, x = 0.1 and y = 0.2, x = 0.2 and y = 0) phosphors were successfully synthesized for the first time by the microwave sol-gel method. Well-crystallized particles formed after heat treatment at 900 °C for 16 h showed a fine and homogeneous morphology with particle sizes of 2-3 ?m. The structures were refined by the Rietveld method in the space group I41/a. The optical properties were examined comparatively using photoluminescence emission and Raman spectroscopy. Under excitation at 980 nm, the NaCaLa0.7(MoO4)3:0.1Er3+,0.2Yb3+ and NaCaLa0.5(MoO4)3:0.05Er3+,0.45Yb3+ particles exhibited a strong 525 nm emission band, a weaker 550 nm emission band in the green region, and three weak 655 nm, 490 nm and 410 nm emission bands in the red, blue and violet regions. The pump power dependence and Commission Internationale de L'Eclairage chromaticity of the upconversion emission intensity were evaluated in detail. © 2016 The Royal Society of Chemistry.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
Department of Advanced Materials Science and Engineering, Hanseo University, Seosan, South Korea
Laboratory of Coherent Optics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Laboratory for Nonlinear Optics and Spectroscopy, Siberian Federal University, Krasnoyarsk, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Department of Photonics and Laser Technologies, Siberian Federal University, Krasnoyarsk, Russian Federation
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, Russian Federation
Functional Electronics Laboratory, Tomsk State University, Tomsk, Russian Federation
Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk, Russian Federation
Institute of Chemistry, Tyumen State University, Tyumen, Russian Federation

Доп.точки доступа:
Lim, C. S.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Ikonnikov, D. A.; Atuchin, V. V.
}
Найти похожие

10.

    Catalytic properties and nature of active centers of ferrospheres in oxidative coupling of methane / A. G. Anshits [et al.] // Appl. Catal. A-Gen. - 2016. - Vol. 524. - P. 192-199, DOI 10.1016/j.apcata.2016.06.032. - Cited References:47. - This study was supported by the Russian Science Foundation (project no. 14-13-00289). . - ISSN 0926-860X. - ISSN 1873-3875
   Перевод заглавия: Каталитические свойства и природа активных центров ферросфер в оксидативной связи метана

РУБ Chemistry, Physical + Environmental Sciences
Рубрики:
GLASS CRYSTAL CATALYSTS
   MAGNETIC-PROPERTIES
   PROFILE REFINEMENT
   FLY-ASH
   MOSSBAUER
   MICROSPHERES
   PERFORMANCE
   CONVERSION
   ETHYLENE
   OXIDE
Кл.слова (ненормированные):
Methane coupling -- Active center -- Ferrospinel -- Mossbauer spectroscopy
Аннотация: Ferrospheres with the Fe2O3 content in the range from 76 to 97 wt% were applied as catalysts for the oxidative coupling of methane (OCM). To identify their phase composition and distribution of iron sites, the ferrospheres were characterized by X-ray powder diffraction and Mossbauer spectroscopy before and after the OCM reaction. Magnetite-based ferrite spinel, hematite and aluminosilicate glasses were established to be the main phases. The ferrospinel of all ferrospheres partially oxidized to hematite after the OCM reaction. It was established that the yield of C-2-hydrocarbons sharply increased at the ferrospheres with Fe2O3 content higher than 89 wt% The spinel phase of these ferrospheres includes Fevv3+(B) sites with a Ca2+ tetrahedral cation and an octahedral cation vacancy among the nearest neighbors. A linear correlation between the yield of C-2-hydrocarbons (ethane and ethylene) and the content of such sites was established, thus indicating that their electrophilic oxygen species participate in selective CH4 conversion to C2H6. (C) 2016 Elsevier B.V. All rights reserved.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Akad Gorodok 50-24, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Akad Gorodok 50-38, Krasnoyarsk 660036, Russia.
Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 a, D-18059 Rostock, Germany.

Доп.точки доступа:
Anshits, A. G.; Bayukov, O. A.; Баюков, Олег Артемьевич; Kondratenko, E. V.; Anshits, N. N.; Pletnev, O. N.; Плетнев, Олег Николаевич; Rabchevskii, E. V.; Solovyov, L. A.; Russian Science Foundation [14-13-00289]
}
Найти похожие