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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Grishina, Svetlana, Kodera, Peter, Goryainov, Sergey, Oreshonkov A. S., Seryotkin, Yurii, Simko, Frantisek, Polozov, Alexander G.
Заглавие : Application of Raman spectroscopy for identification of rinneite (K3NaFeCl6) in inclusions in minerals
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-05-00682]; European Regional Development FundEuropean Union (EU) [ITMS 26240220086]; Vedecka Grantova Agentura MSVVaS SR a SAV [1/0313/20]
Место публикации : J. Raman Spectrosc. - 2020. - Vol. 51, Is. 12. - P.2505-2516. - ISSN 0377-0486, DOI 10.1002/jrs.6005. - ISSN 1097-4555(eISSN)
Примечания : Cited References: 55. - Russian Foundation for Basic Research, Grant/Award Numbers: 18-05-00682, 18-05-00682; European Regional Development Fund, Grant/Award Number: ITMS 26240220086; Vedecka Grantova Agentura MSVVaS SR a SAV, Grant/Award Number: 1/0313/20
Предметные рубрики: SALT MELT
IRON
DEPOSIT
FLUIDS
TRANSFORMATIONS
FERRIHYDRITE
Аннотация: Solid daughter phases in fluid and salt melt inclusions in minerals provide important clues to characterization of mineral‐forming processes. The analysis of the fluid inclusions often requires the exposure of the daughter minerals. Rinneite (K3NaFeCl6), which is a hygroscopic mineral, decomposes in air and cannot thus be identified by conventional methods. A combined approach has been applied for investigation of synthetic and natural rinneite to acquire its diagnostic Raman spectrum for a nondestructive identification. We used natural rinneite inclusions in halite, suitable for applying a complex of methods, to clear up the reference spectrum. Improved high‐resolution X‐ray diffraction (XRD) data obtained from natural rinneite inclusion are comparable with that of previously published, with similar unit cell dimensions. Polarized Raman spectra of natural inclusions were obtained using different geometries and polarization of the incident and scattered light. Interpretation of experimental Raman spectra was performed within the framework of lattice dynamics simulations and group analysis. Individual spectral bands are interpreted in terms of Raman‐active vibrational modes of K3NaFeCl6 structural units. Raman spectrum of synthetic rinneite with main peaks at 75, 91, 103, 143, 167, 171, 187, and 239 cm−1 agrees well with the spectra of rinneite inclusions in halite from the Nepa potash deposit and rinneite daughter minerals in salt melt inclusions hosted by quartz veinlets from the porphyry gold systems in the Central Slovakia Volcanic Field. This provides a firm basis for any future identification of this mineral worldwide, using nondestructive Raman spectroscopy.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Stolyar S. V., Balaev D. A., Ladygina V. P., Dubrovskiy A. A., Krasikov A. A., Popkov S. I., Bayukov O. A., Yaroslavtsev R. N., Volochaev M. N., Iskhakov R. S., Dobretsov K. G., Falaleev O.V., Chizhova I. A.
Заглавие : Bacterial ferrihydrite nanoparticles: preparation, magnetic properties, and application in medicine
Коллективы : Moscow International Symposium on Magnetism, Московский государственный университет им. М.В. Ломоносова, Российский фонд фундаментальных исследований
Место публикации : Moscow Int. Symp. on Magnet. (MISM-2017): 1-7 July 2017 : book of abstracts. - 2017. - Ст.3RP-O-10. - P.417
Примечания : Cited References: 8. - Support by the Special Program for Siberian Federal University of the Ministry of Education and Science of the Russian Federation is acknowledged
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stolyar S. V., Balaev D. A., Ladygina V. P., Dubrovskiy A. A., Krasikov A. A., Popkov S. I., Bayukov O. A., Knyazev Yu. V., Yaroslavtsev R. N., Volochaev M. N., Iskhakov R. S., Dobretsov K. G., Morozov E. V., Falaleev O. V., Inzhevatkin E. V., Kolenchukova O. A., Chizhova I. A.
Заглавие : Bacterial ferrihydrite nanoparticles: preparation, magnetic properties, and application in medicine
Место публикации : J. Supercond. Novel Magn. - 2018. - Vol. 31, Is. 8. - P.2297-2304. - ISSN 15571939 (ISSN), DOI 10.1007/s10948-018-4700-1
Примечания : Cited References: 37. - The electron microscopy examination was carried out at the Center for Collective Use of the Krasnoyarsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences (Krasnoyarsk, Russia).
Ключевые слова (''Своб.индексиров.''): nanoparticles--ferrihydrite--magnetic properties--drug delivery
Аннотация: Nanoparticles of antiferromagnetically ordered materials acquire the uncompensated magnetic moment caused by defects and surface effects. A bright example of such a nano-antiferromagnet is nanoferrihydrite consisting of particles 2–5 nm in size, the magnetic moment of which amounts to hundreds of Bohr magnetons per particle. We present a brief review of the studies on magnetic properties of ferrihydrite produced by bacteria. Special attention is focused on the aspects of possible biomedical applications of this material, i.e., the particle elimination, toxicity, and possible use for targeted drug delivery.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Stolyar S. V., Bayukov O. A., Ladygina V. P., Ishchenko L. A., Iskhakov R. S.
Заглавие : Biogenic ferrihydrite nanoparticles doped with gadolinium
Коллективы : Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism
Место публикации : V Euro-Asian simposium "Trend in MAGnetism": Nanomagnetism: abstracts. - Vladivostok: FEFU, 2013. - С. 232. - ISBN 978-5-7444-3124-2
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Cazacu, Nicoleta, Chilom, Claudia G., Iftimie, Sorina, Balasoiu, Maria, Ladygina, Valentina P., Stolyar S. V., Orelovich, Oleg L., Kovalev, Yuriy S., Rogachev, Andrey V.
Заглавие : Biogenic ferrihydrite nanoparticles produced by Klebsiella oxytoca: Characterization, physicochemical properties and bovine serum albumin interactions
Место публикации : Nanomaterials. - 2022. - Vol. 12, Is. 2. - Ст.249. - ISSN 2079-4991(eISSN), DOI 10.3390/nano12020249
Примечания : Cited References: 59. - This research was funded by JINR Themes 02-1-1107-2011/2021, 04-5-1131-2017/2021 and 04-4-1133-2018/2023 and with the financial support of the RO-JINR Projects Nos. 366/11.05.2021 (items 7, 86, 97) and 365/11.05.2021 (items 8, 87 and 98). This work also benefited from the use of the SasView application, originally developed under NSF Award DMR-0520547. SasView also contains the code developed with funding from the EU Horizon 2020 program under the SINE2020 project Grant No 654000. The APC was funded by JINR Theme 02-1-1107-2011/2021, Project No. 366/11.05.2021, item 7. This study used the infrastructure of the Applied Genetics Resource Facility of MIPT (Suport Grant 075-15-2021-684)
Предметные рубрики: MAGNETIC-PROPERTIES
REDUCTION
MOSSBAUER
FERRITIN
DOCKING
BINDING
Аннотация: The synthesis of nanoparticles inside microorganisms is an economical alternative to chemical and physical methods of nanoparticle synthesis. In this study, ferrihydrite nanoparticles synthesized by Klebsiella oxytoca bacterium in special conditions were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDS), small-angle X-ray (SAXS), UV-Vis spectroscopy, fluorescence, fluorescence resonance energy transfer (FRET), and molecular docking. The morphology and the structure of the particles were characterized by means of SEM and SAXS. The elemental content was determined by means of the EDS method. The absorption properties of the ferrihydrite nanoparticles were investigated by UV-Vis spectroscopy. The binding mechanism of the biogenic ferrihydrite nanoparticles to Bovine Serum Albumin (BSA) protein, studied by fluorescence, showed a static and weak process, combined with FRET. Protein denaturation by temperature and urea in the presence of the ferrihydrite nanoparticles demonstrated their influence on the unfolding process. The AutoDock Vina and UCSF Chimera programs were used to predict the optimal binding site of the ferrihydrite to BSA and to find the location of the hydrophobic cavities in the sub-domain IIA of the BSA structure.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stolyar S. V., Kolenchukova, Oksana A., Boldyreva, Anna V., Kudryasheva, Nadezda S., Gerasimova Yu. V., Krasikov A. A., Yaroslavtsev R. N., Bayukov O. A., Ladygina, Valentina P., Birukova, Elena A.
Заглавие : Biogenic ferrihydrite nanoparticles: Synthesis, properties in vitro and in vivo testing and the concentration effect
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of the Krasnoyarsk Territory; Regional Science Foundation [20-416-242907]
Место публикации : Biomedicines. - 2021. - Vol. 9, Is. 3. - Ст.323. - ISSN 2227-9059(eISSN), DOI 10.3390/biomedicines9030323
Примечания : Cited References: 52. - This research was funded by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory and the Regional Science Foundation, grant number 20-416-242907
Аннотация: Biogenic ferrihydrite nanoparticles were synthesized as a result of the cultivation of Klebsiella oxytoca microorganisms. The distribution of nanoparticles in the body of laboratory animals and the physical properties of the nanoparticles were studied. The synthesized ferrihydrite nanoparticles are superparamagnetic at room temperature, and the characteristic blocking temperature is 23-25 K. The uncompensated moment of ferrihydrite particles was determined to be approximately 200 Bohr magnetons. In vitro testing of different concentrations of ferrihydrite nanoparticles for the functional activity of neutrophilic granulocytes by the chemiluminescence method showed an increase in the release of primary oxygen radicals by blood phagocytes when exposed to a minimum concentration and a decrease in secondary radicals when exposed to a maximum concentration. In vivo testing of ferrihydrite nanoparticles on Wister rats showed that a suspension of ferrihydrite nanoparticles has chronic toxicity, since it causes morphological changes in organs, mainly in the spleen, which are characterized by the accumulation of hemosiderin nanoparticles (stained blue according to Perls). Ferrihydrite can also directly or indirectly stimulate the proliferation and intracellular regeneration of hepatocytes. The partial detection of Perls-positive cells in the liver and kidneys can be explained by the rapid elimination from organs and the high dispersion of the nanomaterial. Thus, it is necessary to carry out studies of these processes at the systemic level, since the introduction of nanoparticles into the body is characterized by adaptive-proliferative processes, accompanied by the development of cell dystrophy and tension of the phagocytic system.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Chilom C. G., Gazdaru D. M., Balasoiu M., Bacalum M., Stolyar S. V., Popescu A. I.
Заглавие : Biomedical application of biogenic ferrihydrite nanoparticles
Место публикации : Rom. J. Phys. - 2017. - Vol. 62, Is. 3-4. - Ст.701. - С. P. - ISSN 1221146X (ISSN)
Примечания : Cited References: 13. - The work was accomplished with the financial support of the IUNC Structural and spectrophotometric characterization of biogenic systems, Grants 4-1069-2009/2014 and 04-4-1121-2015/2017. Biological studies were accomplished with the financial support of Romanian National Authority for Scientific Research, CNDI-UEFISCDI, Project number: PN 16 42 02 03. The authors are very much indebted to Virginia Dincă and Gabriel Prodan for TEM images and to Gabriel Socol for FT-IR spectra.
Ключевые слова (''Своб.индексиров.''): bacterial nanoparticles--albumins-ferrihydrite nanoparticles interaction--cell lines--cytotoxicity--hemolytic effect
Аннотация: Spectroscopic properties of biogenic ferrihydrite nanoparticles, produced by Klebsiella oxytoca, were investigated. Their interaction with two serum albumins was moderate. A very weak stabilization of protein structure to denaturation, in the presence of nanoparticles, was put in evidence. Nanoparticle cytotoxicity and their hemolytic effect were studied on healthy and tumour cells.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Krasikov A. A., Stolyar S. V., Iskhakov R. S., Ladygina V. P., Yaroslavtsev R. N., Bayukov O. A., Vorotynov A. M., Volochaev M. N., Dubrovskiy A. A.
Заглавие : Change in the magnetic properties of nanoferrihydrite with an increase in the volume of nanoparticles during low-temperature annealing
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2016. - Vol. 58, Is. 9. - P.1782-1791. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783416090092
Примечания : Cited References: 32. - This study was supported by the Ministry of Education and Science of the Russian Federation within the State Task for 2014-2016.
Предметные рубрики: FERRIHYDRITE NANOPARTICLES
BACTERIAL FERRIHYDRITE
FERRITIN
HYSTERESIS
MOSSBAUER
ORIGIN
Аннотация: The results of the investigation into the effect of low-temperature annealing of a powder of nanoparticles of bacterial ferrihydrite on its magnetic properties have been presented. It has been found that an increase in the time (up to 240 h) and temperature (in the range from 150 to 200°C) of annealing leads to a monotonic increase in the superparamagnetic blocking temperature, the coercive force, and the threshold field of the opening of the magnetic hysteresis loop (at liquid-helium temperatures), as well as to an increase in the magnetic resonance line width at low temperatures and in the magnetic susceptibility at room temperature. At the same time, according to the results of the analysis of the Mossbauer spectra, the annealing of ferrihydrite does not lead to the formation of new iron oxide phases. Most of these features are well consistent with the fact that the low-temperature annealing of ferrihydrite causes an increase in the size of nanoparticles, which is confirmed by the results of transmission electron microscopy studies. © 2016, Pleiades Publishing, Ltd.
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Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Balasoiu M., Kichanov S., Pantelica A., Pantelica D., Stolyar S. V., Iskhakov R. S., Aranghel D., Ionescu P., Badita C. R., Kurkin S., Orelovich O., Tiutiunikov S.
Заглавие : Characterization of biogenic ferrihydrite nanoparticles by means of SAXS, SRD and IBA methods
Коллективы : International School and Workshop on Complex and Magnetic Soft Matter Systems: Structure and Physico - Mechanical Properties
Место публикации : J. Phys.: Conf. Ser. - 2018. - Vol. 994: 3rd International School and Workshop on Complex and Magnetic Soft Matter Systems: Structure and Physico - Mechanical Properties, CMSMS 2017 (28 - 30 June 2017), Is. 1. - Ст.012012. - , DOI 10.1088/1742-6596/994/1/012012
Примечания : Cited References: 20. - The work was accomplished in the frame of IFIN-HH User Beam schedule at the 3 MV Tandetron accelerator and partially was supported by the Joint Institute for Nuclear Research (JINR) Dubna Theme No. 04-4-1121-2015/2017, RO-JINR Projects Nos. 95/15.02.2016 and 96/15.02.2016, items 77, 82; Nos. 219/10.04.2017 and 220/10.04.2017 item 38; RFBR and Krasnoyarsk region Project No. 17-43-240527. Support by the Special Program for Siberian Federal University of the Ministry of Education and Science of the Russian Federation is acknowledged.
Ключевые слова (''Своб.индексиров.''): bacteria--data handling--ion beams--mechanical properties--nanoparticles--synchrotron radiation
Аннотация: Investigations of biogenic ferrihydrite nanoparticles produced by bacteria Klebsiella oxytoca by applying small angle X-ray scattering, synchrotron radiation diffraction and ion beam analysis methods are reviewed. Different experimental data processing methods are used and analyzed.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stolyar S. V., Yaroslavtsev R. N., Ladygina V. P., Balaev D. A., Pankrats A. I., Iskhakov R. S.
Заглавие : Collective Spin Glass State in Nanoscale Particles of Ferrihydrite
Коллективы : International Symposium “Nanostructures: Physics and Technology”
Место публикации : Semiconductors. - 2020. - Vol. 54, Is. 12. - P.1710-1712. - DOI 10.1134/S1063782620120362
Примечания : Cited References: 16. - This work was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory, the Krasnoyarsk Regional Fund for the Support of Scientific and Technical Activities (project no. 19-42-240012 r_a “Magnetic resonance in ferrihydrite nanoparticles: Effects associated with the “core–shell” structure). This work was supported by a grant from the President of the Russian Federation for state support of young Russian scientists – candidates of sciences no. MK-1263.2020.3
Аннотация: Ferromagnetic resonance was used to study three types of ferrihydrite nanoparticles: nanoparticles formed as a result of the cultivation of microorganisms Klebsiella oxytoca; chemically prepared ferrihydrite nanoparticles; chemically prepared ferrihydrite nanoparticles doped with Cu. It is established from the ferromagnetic resonance data that the frequency-field dependence (in the temperature range ТP ‹ T ‹ T*) is described by the expression: 2πν/γ ⁼ НR + HA(T = 0)(1 – T/Т*), where γ is the gyromagnetic ratio, HR is the resonance field. The induced anisotropy HA is due to the spin-glass state of the near-surface regions. TP temperature characterizes the energy of the interparticle interaction of nanoparticles.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stolyar S. V., Bayukov O. A., Ladygina V. P., Iskhakov R. S., Yaroslavtsev R. N.
Заглавие : Effect of ultrasonic treatment on magnetic ferrihydrite nanoparticles in a suspended state
Место публикации : Bull. Russ. Acad. Sci. Phys.: Allerton Press, 2017. - Vol. 81, Is. 5. - P.608-611. - ISSN 10628738 (ISSN), DOI 10.3103/S1062873817050227
Примечания : Cited References: 11
Ключевые слова (''Своб.индексиров.''): nanoparticles--ultrasonic equipment--fe-ions--ferrihydrites--metal reduction--metal state--organic components--ssbauer spectroscopies--ultrasonic treatments--nanomagnetics
Аннотация: Dried sediments of magnetic ferrihydrite nanoparticles subjected to ultrasonic treatment in the cavitation mode are studied via Mossbauer spectroscopy. Fe ions are reduced to the metal state. In all experiments with detected metal reduction, the investigated suspensions contain organic components. © 2017, Allerton Press, Inc.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Krasikov A. A., Dubrovskiy A. A., Popkov S. I., Stolyar S. V., Iskhakov R. S., Ladygina V. P., Yaroslavtsev R. N.
Заглавие : Exchange bias in nano-ferrihydrite
Место публикации : J. Appl. Phys.: American Institute of Physics, 2016. - Vol. 120, Is. 18. - Ст.183903. - ISSN 00218979, DOI 10.1063/1.4967912
Примечания : Cited References: 43. - The authors are grateful to M. Volochaev for measurements and O. A. Bayukov for Mössbauer study.This work was supported in part by the Ministry of Education and Science of the Russian Federation.
Ключевые слова (''Своб.индексиров.''): anisotropy--cooling systems--hysteresis--magnetic fields--magnetic materials--magnetism--nanomagnetics--nanoparticles--particle size--characteristic value--exchange bias--exchange bias effects--external magnetic field--field cooling--high anisotropy--minor hysteresis loop--superparamagnetic blocking--hysteresis loops
Аннотация: We report the results of investigations of the effect of cooling in an external magnetic field starting from the temperature over superparamagnetic blocking temperature TB on the shift of magnetic hysteresis loops in systems of ferrihydrite nanoparticles from ∼2.5 to ∼5 nm in size with different TB values. In virtue of high anisotropy fields of ferrihydrite nanoparticles and open hysteresis loops in the range of experimentally attainable magnetic fields, the shape of hysteresis loops of such objects in the field-cooling mode is influenced by the minor hysteresis loop effect. A technique is proposed for distinguishing the exchange bias effect among the effects related to the minor hysteresis loops caused by high anisotropy fields of ferrihydrite particles. The exchange bias in ferrihydrite is stably observed for particles not less than 3 nm in size or with TB over 40 K, and its characteristic value increases with the particle size. © 2016 Author(s).
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Krasikov A. A., Balaev A. D., Stolyar S. V., Ladygina V. P., Iskhakov R. S.
Заглавие : Features of relaxation of the remanent magnetization of antiferromagnetic nanoparticles by the example of ferrihydrite
Место публикации : Phys. Solid State. - 2020. - Vol. 62, Is. 7. - P.1172-1178. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783420070033
Примечания : Cited References: 53
Аннотация: The relaxation of the remanent magnetization of antiferromagnetically ordered ferrihydrite nanoparticles at the exchange bias effect implemented in these systems has been investigated. The magnetization relaxation depends logarithmically on time, which is typical of the thermally activated hoppings of particle magnetic moments through the potential barriers caused by the magnetic anisotropy. The barrier energy obtained by processing of the remanent magnetization relaxation data under the field cooling conditions significantly exceeds the barrier energy under standard (zero field cooling) conditions. The observed difference points out the possibility of using the remanent magnetization relaxation to analyze the mechanisms responsible for the exchange bias effect in antiferromagnetic nanoparticles and measure the parameters of the exchange coupling of magnetic subsystems in such objects.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Chilom C. G., Sandu N., Balasoiu M., Yaroslavtsev R. N., Stolyar S. V., Rogachev A. V.
Заглавие : Ferrihydrite nanoparticles insights: Structural characterization, lactate dehydrogenase binding and virtual screening assay
Место публикации : Int. J. Biol. Macromol. - 2020. - Vol. 164. - P.3559-3567. - ISSN 01418130 (ISSN), DOI 10.1016/j.ijbiomac.2020.08.242
Примечания : Cited References: 64. - The work was accomplished in the frame of JINR Themes 02-1-1107-2011/2021, 04-5-1131-2017/2021 and 04-4-1121-2015/2020 and with the financial support of the RO-JINR Projects Nos. 268/21.05.2020 items 8 and 77, and 269/21.05.2020 items 11 and – 80. MB acknowledges Dr. Alexander Kuklin for assistance for SANS measurements and fruitful discussions. The authors acknowledge Dr. George Stan of the National Institute of Materials Physics for facilitating the conduct of FTIR experiments
Аннотация: The binding between the enzyme lactate dehydrogenase (LDH) and ferrihydrite nanoparticles (Fh-NPs) was investigated by means of small-angle neutron scattering (SANS), Fourier-transform infrared (FTIR) spectroscopy, fluorescence and Forster resonance energy transfer (FRET) and molecular docking. Fh-NPs - LDH compounds of dimensions under 100 nm are formed. The conformational changes and the mechanism of interaction between LDH and Fh-NPs simple and doped with Cu and Co, and the effect of these NPs on the thermal denaturation of LDH were monitored. The quenching mechanism is static, the binding occurring with moderate affinity, being mainly driven by hydrogen bonding and van der Waals forces. FRET occurs at a minimal distance of 2.55 nm. Thermal denaturation of LDH in the presence of simple and doped Fh-NPs shows that the thermodynamic parameters of protein unfolding are significantly changed with temperature. The denaturation temperature of LDH shifts to higher values in the presence of all Fh-NPs, than in the case of simple LDH. The docking approach estimates the energy corresponding to the best fit of the ferrihydrite in the LDH binding site near Trp. These results have direct implications on the uses of the complex of LDH with Fh-NPs in various biochemical, biological, or clinical applications.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Chilom, Claudia G., Zorilă, Bogdan, Bacalum M., Bălăşoiu, Maria, Yaroslavtsev R. N., Stolyar S. V., Tyutyunnicov, Sergey
Заглавие : Ferrihydrite nanoparticles interaction with model lipid membranes.
Место публикации : Chem. Phys. Lipids. - 2020. - Vol. 226. - Ст.104851. - ISSN 0009-3084, DOI 10.1016/j.chemphyslip.2019.104851. - ISSN 1873-2941 (eISSN)
Примечания : Cited References: 70. - The work was accomplished with the financial support of the 2019 RO-JINR Project Investigation of biogenic and chemically synthesized systems in interaction with biostructures for applied research, Theme 02-1-1107-2011/2019 and of the Romanian National Authority for Scientific Research, CNDI-UEFISCDI, Project numbers: PN 18 09 02 02/2018 and PN 19 06 02 03/2019. The authors are very much indebted to Professor Dr. Aurel Popescu, for very helpful suggestions and permanent encouragement.
Аннотация: In recent years was observed an increased interest towards the use of metal nanoparticles for various biomedical applications, such as therapeutics, delivery systems or imaging. As biological membranes are the first structures with which the nanoparticles interact, it is necessary to understand better the mechanisms governing these interactions. In the present paper we aim to characterize the effect of three different ferrihydrite nanoparticles (simple or doped with cooper or cobalt) on the fluidity of model lipid membranes. First we evaluated the physicochemical properties of the nanoparticles: size and composition. Secondly, their effect on lipid membranes was also evaluated using Laurdan, TMA-DPH and DPH fluorescence. Our results can help better understand the mechanisms involved in nanoparticles and membrane interactions.
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16.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Yaroslavtsev R. N., Stolyar S. V., Balaev D. A., Ladygina V. P., Bayukov O. A., Iskhakov R. S.
Заглавие : Ferrihydrite nanoparticles produced by chemical and biological methods
Коллективы : International Baltic Conference on Magnetism: Focus on Biomedical Aspects , Балтийский федеральный университет им. И. Канта
Место публикации : International Baltic Conference on Magnetism (IBCM-2015): book of abstracts. - 2015. - P.96
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stolyar S. V., Bayukov O. A., Balaev D. A., Ladygina V. P., Yaroslavtsev R. N., Knyazev Yu. V., Balasoiu M., Kolenchukova O. A., Iskhakov R. S.
Заглавие : Ferrihydrite nanoparticles produced by Klebsiella oxytoca: Structure and properties dependence on the cultivation time
Место публикации : Adv. Powder Technol. - 2022. - Vol. 33, Is. 8. - Ст.103692. - ISSN 09218831 (ISSN), DOI 10.1016/j.apt.2022.103692
Примечания : Cited References: 59. - This work was supported by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research projects No. 20-416-242907
Аннотация: Ferrihydrite nanoparticles were synthesized using Klebsiella oxytoca microorganisms under various cultivation conditions. The cultivation of bacteria was carried out under various lighting conditions, and the duration of cultivation varied from 3 to 56 days. Biogenic ferrihydrite nanoparticles were studied by Mössbauer spectroscopy, magnetometry, and small-angle X-ray scattering. The process of formation of ferrihydrite nanoparticles and the states arising during the cultivation of microorganisms have been investigated. The results of Mössbauer spectroscopy showed that, depending on the time of cultivation, three different states of ferrihydrite can be realized. States differ both in the ratio of defective and non-defective positions, and the size of the particle. Experimental results indicate that ferrihydrite nanoparticles are a system of variable composition and pass through several structural (or morphological) states during the cultivation of microorganisms. A model of the structure of ferrihydrite nanoparticles is proposed, which consists in the presence of an antiferromagnetic dense core with a high Néel temperature and a friable shell with a significantly lower temperature of magnetic ordering.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Teremova M. I., Petrakovskaya E. A., Romanchenko A. S., Tuzikov F. V., Gurevich Y. L., Tsibina O. V., Yakubailik E. K., Abhilash
Заглавие : Ferritization of industrial waste water and microbial synthesis of iron-based magnetic nanomaterials from sediments
Коллективы : RFFI [10-08-01278]; DST-RFBR Indo-Russian Long term Collaborative Project [DST-ILTP-A.2.61]
Место публикации : Environ. Prog. Sustain. Energy: Wiley-Blackwell, 2016. - Vol. 35, Is. 5. - P.1407-1414. - ISSN 1944-7442, DOI 10.1002/ep.12368. - ISSN 1944-7450(eISSN)
Примечания : Cited References:26. - The work has been carried out with support of grant of RFFI No 10-08-01278 and DST-ILTP-A.2.61 under DST-RFBR Indo-Russian Long term Collaborative Project. Authors are grateful to P.P. Pustoshilov, N.M. Kuchin, O.A. Bayukov, A.P. Puzyr and Lobova T.I. for assistance in experiment performance and valuable remarks.
Предметные рубрики: ACIDITHIOBACILLUS FERROOXIDANS CELLS
POT MULTICOMPONENT SYNTHESIS
Ключевые слова (''Своб.индексиров.''): industrial wastes--ferritization--bacteria--magnetic--ferrihydrite--nanoparticles
Аннотация: The precipitation of iron and associated heavy metals in industrial waste water and in model solution using ferritization and aerobic bacterial culture was investigated. Magnetic sediments extractable by magnetic separation (specific saturation magnetization of 16–36.8 G cm3/g) were produced by precipitation of iron by ferritization method at рН (8–10) and 60–80°С for 15–30 min. Nanoparticles of ferrihydrite or ferric hydroxide doped with associated metals (Co, Ni) were produced under precipitation of ferric iron in model solution with bacteria at the temperature 26–34°С. The radii of synthesized particles are 1–5 nm and nanoparticles of ferrihydrite are superparamagnetic in both un-doped and doped (Co, Ni, Zn) sets. Dispersed structure of biogenic nanoparticle sols, their magnetic and other properties were studied by atomic force microscopy, X-ray small-angle scattering, X-ray diffraction, electron magnetic resonance, Mössbauer and X-ray photoelectron spectroscopy.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stolyar S. V., Balaev D. A., Ladygina V. P., Pankrats A. I., Yaroslavtsev R. N., Velikanov D. A., Iskhakov R. S.
Заглавие : Ferromagnetic resonance study of biogenic ferrihydrite nanoparticles: spin-glass state of surface spins
Место публикации : JETP Letters. - 2020. - Vol. 111, Is. 3. - P.183-187. - ISSN 0021-3640, DOI 10.1134/S0021364020030145. - ISSN 1090-6487(eISSN)
Примечания : Cited References: 41. - This work was supported by the Russian Foundation for Basic Research, project no. 18-02-40137.This work was supported by the Russian Foundation for Basic Research, by the Government of Krasnoyarsk krai, by the Krasnoyarsk Regional Fund for the Support of Scientific and Technical Activities (project no. 19-42-240012 r_a “Magnetic Resonance in Ferrihydrite Nanoparticles: Effects Associated with the Core-Shell Structure”), and by the Council of the President of the Russian Federation for State Support of Young Scientists and Leading Scientific Schools (project no. MK-1263.2020.3).
Предметные рубрики: MAGNETIC-PROPERTIES
NIO NANOPARTICLES
TRANSITION
ANISOTROPY
Аннотация: Ferrihydrite nanoparticles (2–3 nm in size), which are products of the vital activity of microorganisms, are studied by the ferromagnetic resonance method. The “core” of ferrihydrite particles is ordered antiferromagnetically, and the presence of defects leads to the appearance of an uncompensated magnetic moment in nanoparticles and the characteristic superparamagnetic behavior. It is established from the ferromagnetic resonance data that the field dependence of the frequency is described by the expression 2πν/γ = HR + H A(T=0) (1 − T/T*), where γ is the gyromagnetic ratio, HR is the resonance field, HA ≈ 7 kOe, and T* ≈ 50 K. The induced anisotropy HA is due to the spin-glass state of the near-surface regions.
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20.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Stolyar S. V., Li O. A., Ladygina V. P., Nikolaeva E. D., Vorotynov A. M., Velikanov D. A., Pyankov V. F., Iskhakov R. S.
Заглавие : Heat release by ferrihydrite nanoparticles at ferromagnetic resonance
Коллективы : Российская академия наук, Физико-технический институт им. Е.К. Завойского ФИЦ Казанского научного центра РАН, Казанский (Приволжский) федеральный университет, Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium
Место публикации : VIII Euro-Asian symposium "Trends in magnetism" (EASTMAG-2022): Book of abstracts/ program com. S. G. Ovchinnikov [et al.]. - 2022. - Vol. 2, Sect. M: Magnetism in biology and medicine. - Ст.M.P5. - P.434. - ISBN 978-5-94469-051-7
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