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Antiferromagnetic Resonance and Dielectric Properties of Rare-earth Ferroborates in the Submillimeter Frequency Range / A. M. Kuz'menko, A. A. Mukhin, V. Yu. Ivanov [et al.] // J. Exp. Theor. Phys. - 2011. - Vol. 113, Is. 1. - P113-120, DOI 10.1134/S106377611105013X. - Cited Reference Count: 27. - Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [10-02-00846], This work was supported by the Russian Foundation for Basic Research, project no. 10-02-00846. . - JUL. - ISSN 1063-7761. - ISSN 1090-6509
Рубрики:
Physics, Multidisciplinary
Аннотация: The magnetoresonance and dielectric properties of a number of crystals of a new family of multiferroics, namely, rare-earth ferroborates RFe3(BO3)(4) (R = Y, Eu, Pr, Tb, Tb0.25Er0.75), are studied in the submillimeter frequency range (nu = 3-20 cm(-1)). Ferroborates with R = Y, Tb, and Eu exhibit permittivity jumps at temperatures of 375, 198, and 58 K, respectively, which are caused by the R32 - P3(1)2(1) phase transition. Antiferromagnetic resonance (AFMR) modes in the subsystem of Fe3+ ions are detected in the range of antiferromagnetic ordering (T≺T-N=30-40K) in all ferroborates that have either an easy-plane (Y, Eu) or easy-axis (Pr, Tb, Tb0.25Er0.75) magnetic structure. The AFMR frequencies are found to depend strongly on the magnetic anisotropy of a rare-earth ion and its exchange interaction with the Fe subsystem, which determine the type of magnetic structure and the sign and magnitude of an effective anisotropy constant. The basic parameters of the magnetic interactions in these ferroborates are found, and the magnetoelectric contribution to AFMR is analyzed.

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Держатели документа:
Russian Acad Sci, Inst Gen Phys, Moscow 119991, Russia;
Moscow MV Lomonosov State Univ, Moscow 119991, Russia;
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Kuz'menko, A. M.; Mukhin, A. A.; Ivanov, V. Yu.; Kadomtseva, A. M.; Lebedev, S. P.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
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Antiferromagnetic Resonance and Dielectric Properties of Rare-earth Ferroborates in the Submillimeter Frequency Range / A. M. Kuz'menko [et al.] // J. Exp. Theor. Phys. - 2011. - Vol. 113, Is. 1. - P. 113-120, DOI 10.1134/S106377611105013X. - Cited References: 27. - This work was supported by the Russian Foundation for Basic Research, project no. 10-02-00846. . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
GDFE3(BO3)(4)
SPECTROSCOPY
CRYSTAL
Кл.слова (ненормированные):
Antiferromagnetic resonance -- Basic parameters -- Effective anisotropy constant -- Ferroborates -- Ferroics -- Ferromagnetic orderings -- Frequency ranges -- Magnetic interactions -- Magnetoresonance -- Millimeter frequency range -- Rare earth ions -- Submillimeters -- Antiferromagnetic materials -- Crystallography -- Erbium -- Europium -- Ferromagnetic resonance -- Ion exchange -- Magnetic anisotropy -- Magnetic devices -- Magnetic structure -- Permittivity -- Resonance -- Antiferromagnetism
Аннотация: The magnetoresonance and dielectric properties of a number of crystals of a new family of multiferroics, namely, rare-earth ferroborates RFe(3)(BO(3))(4) (R = Y, Eu, Pr, Tb, Tb(0.25)Er(0.75)), are studied in the submillimeter frequency range (nu = 3-20 cm(-1)). Ferroborates with R = Y, Tb, and Eu exhibit permittivity jumps at temperatures of 375, 198, and 58 K, respectively, which are caused by the R32 -> P3(1)2(1) phase transition. Antiferromagnetic resonance (AFMR) modes in the subsystem of Fe(3+) ions are detected in the range of antiferromagnetic ordering (T < T(N) = 30-40 K) in all ferroborates that have either an easy-plane (Y, Eu) or easy-axis (Pr, Tb, Tb(0.25)Er(0.75)) magnetic structure. The AFMR frequencies are found to depend strongly on the magnetic anisotropy of a rare-earth ion and its exchange interaction with the Fe subsystem, which determine the type of magnetic structure and the sign and magnitude of an effective anisotropy constant. The basic parameters of the magnetic interactions in these ferroborates are found, and the magnetoelectric contribution to AFMR is analyzed.

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Держатели документа:
[Kuz'menko, A. M.
Mukhin, A. A.
Ivanov, V. Yu.
Lebedev, S. P.] Russian Acad Sci, Inst Gen Phys, Moscow 119991, Russia
[Kadomtseva, A. M.] Moscow MV Lomonosov State Univ, Moscow 119991, Russia
[Bezmaternykh, L. N.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Institute of General Physics, Russian Academy of Sciences, ul. Vavilova 38, Moscow, 119991, Russian Federation
Moscow State University, Moscow, 119991, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Kuz'menko, A. M.; Mukhin, A. A.; Ivanov, V. Y.; Kadomtseva, A. M.; Lebedev, S. P.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
}
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Antiferromagnetic resonance and magnetic investigations of rare-earth ferroborates [Text] / V. Tugarinov, A. Pankrats, S. Kondyan [et al.] // Moscow Int. Symp. on Magnet. (MISM-2011) : Book of abstracts. - 2011. - Ст. 24OR-O-10. - P. 623. - Библиогр.: 3. - Work is supported by RFBR grant 10-02-00765

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Доп.точки доступа:
Tugarinov, V. I.; Тугаринов, Василий Иванович; Pankrats, A. I.; Панкрац, Анатолий Иванович; Kondyan, S.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Temerov, V. L.; Темеров, Владислав Леонидович; Moscow International Symposium on Magnetism(5 ; 2011 ; Aug. ; 21-25 ; Moscow)
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Comparison of magnetic properties of GdFe3(BO3)4, ferroborates grown using various solvents / I. A. Gudim, E. V. Eremin, N. V. Mikhashenok, V. R. Titova // Phys. Solid State. - 2023. - Vol. 65, Is. 2. - P. 235-239, DOI 10.21883/PSS.2023.02.55406.505. - Cited References: 18. - This study was supported by grant No. 22-12-20019 provided by the Russian Science Foundation and the Krasnoyarsk Regional Science Foundation (https://rscf.ru/project/22-72-00017/) . - ISSN 1063-7834. - ISSN 1090-6460
Кл.слова (ненормированные):
crystal growth -- antiferromagnets -- multferroics
Аннотация: GdFe3(BO3)4, single crystals were grown from melt-solutions based on bismuth trimolybdate and lithium tungstate. Single crystals of gadolinium ferroborate from lithium-tungstate solution-melt were grown for the first time. The magnetic properties of the grown crystals are compared. It is shown that the GdFe3(BO3)4, ferroborate obtained using bismuth solution-melt trimolybdate contains impurities of Bi3+ ions (6% at.), which replace Gd3+ ions. Whereas GdFe3(BO3)4, ferroborate grown from a solution-melt based on lithium tungstate does not seem to contain such uncontrolled impurities.

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Публикация на русском языке Сравнение магнитных свойств ферроборатов GdFe3(BO3)4, выращенных с использованием различных растворителей [Текст] / И. А. Гудим, Е. В. Еремин, Н. В. Михашенок, В. Р. Титова // Физ. тверд. тела. - 2023. - Т. 65 Вып. 2. - С. 243-247

Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia

Доп.точки доступа:
Gudim, I. A.; Гудим, Ирина Анатольевна; Eremin, E. V.; Еремин, Евгений Владимирович; Mikhashenok, N. V.; Михашенок, Наталья Владимировна; Titova, V. R.; Титова, Вероника Романовна
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Comparison of the absorption spectra of Nd3+ ions in the NdFe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4, and Ho0.75Nd0.25Fe3(BO3)4 crystals / A. L. Sukhachev, A. V. Malakhovskii, C. S. Nelson [et al.] // Phys. Solid State. - 2021. - Vol. 63, Is. 1. - P. 113-121, DOI 10.1134/S1063783421010200. - Cited References: 21. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, to the research project: number 19-42-240003 “Influence of the local en-vironment on magneto-optical properties of f–f transitions in rare-earth aluminum and iron borates” . - ISSN 1063-7834
Кл.слова (ненормированные):
neodymium -- hantite-structure ferroborates -- f–f electronic transitions -- structural transition
Аннотация: The polarized optical absorption spectra in the region of a series of the f–f transitions of Nd3+ ions in the Ho0.75Nd0.25Fe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4, and NdFe3(BO3)4 crystals at 90 K have been compared. The spectral features related to the difference in the local environment of Nd3+ ions in these crystals have been established. In the region of the transition 4I9/2 → 4G5/2 + 2G7/2 of Nd3+ ions in the Ho0.75Nd0.25Fe3(BO3)4 crystal, the appearance of some absorption lines at the structural transition R32 → P3121 around ~200 K due to the local symmetry variation has been found. The intensity of these lines smoothly increases with a decrease in temperature from the transition point. The temperature dependence of the lattice parameters of the Ho0.75Nd0.25Fe3(BO3)4 crystal has been measured. It has been found that, at the transition temperature, the lattice parameter a changes stepwise, which is indicative of the occurrence of a first-order phase transition. The lattice parameter c changes smoothly.

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Публикация на русском языке Сравнение спектров поглощения ионов Nd3+ в кристаллах NdFe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4 и Ho0.75Nd0.25Fe3(BO3)4 [Текст] / А. Л. Сухачев, А. В. Малаховский, C. S. Nelson [и др.] // Физ. тверд. тела. - 2021. - Т. 63 Вып. 1. - С. 111-119

Держатели документа:
Kirensky Institute of Physics, FRC KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
National Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY 11973, United States

Доп.точки доступа:
Sukhachev, A. L.; Сухачев, Александр Леонидович; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Nelson, C. S.; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович
}
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    Crystal growth and Raman spectroscopy study of Sm1-xLaxFe3(BO3)4 ferroborates / E. Moshkina [et al.] // Cryst. Growth Des. - 2016. - Vol. 16, Is. 12. - P. 6915-6921, DOI 10.1021/acs.cgd.6b01079. - Cited References: 17. - This work was supported by the Russian Foundation for Basic Research, Project No. 14-02-00307. . - ISSN 1528-7483
   Перевод заглавия: Рост кристаллов и исследование ферроборатов Sm1-xLaxFe3(BO3)4 методом спектроскопии комбинационного рассеяния света
Кл.слова (ненормированные):
Crystal lattices -- Iron compounds -- Raman spectroscopy -- Single crystals -- Crystal nucleation -- Flux methods -- Internal structure -- Magnetic phase transitions -- Magnon scattering -- Spectral region -- Temperature range -- Wave numbers -- Lanthanum
Аннотация: Sm1-xLaxFe3(BO3)4 (x = 0, 0.75) single crystals were synthesized using the flux method. The crystal nucleation procedure and flux parameters are reported. Conditions for growing the Sm1-xLaxFe3(BO3)4 (x = 0, 0.75) single crystals are described. The prepared crystals were studied by Raman spectroscopy in the temperature range of T = 10-300 K. The spectral region corresponding to temperatures of T = 10-55 K, which involves the temperatures of the magnetic phase transition TN = 32 K for x = 0 and TN = 31 K for x = 0.75, was thoroughly analyzed. Anomalies related to the magnetic ordering established in both compounds were found. The main changes occur in the low-wavenumber region (up to 100 cm-1), where the mode corresponding to magnon scattering arises. This mode is shown to have the internal structure indicative of the occurrence of unstable vibrations (40-80 cm-1). The results obtained are analyzed by calculating the empirical lattice dynamics in Sm1-xLaxFe3(BO3)4 with x = 0 and x = 1. © 2016 American Chemical Society.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian State Aerospace University, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Moshkina, E. M.; Мошкина, Евгения Михайловна; Krylov, A. S.; Крылов, Александр Сергеевич; Sofronova, S. N.; Софронова, Светлана Николаевна; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович
}
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Elastic and piezoelectric moduli of Nd and Sm ferroborates / T. N. Gaydamak [et al.] // Low Temp. Phys. - 2015. - Vol. 41, Is. 8. - P. 614-618, DOI 10.1063/1.4929719. - Cited References: 17 . - ISSN 1063. - ISSN 1090-6517. -

РУБ Physics, Applied

Аннотация: The sound speeds are measured and the elastic and piezoelectric moduli are calculated for single crystal NdFe3(BO3)4 and SmFe3(BO3)4. These compounds are characterized by enhanced rigidity in the base plane with respect to stress-strain deformations and by a rather strong piezoelectric effect.

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Публикация на русском языке Упругие и пьезоэлектрические модули ферроборатов Nd и Sm [Текст] / Т. Н. Гайдамак [и др.] // Физ. низких температур : Физико-технический институт низких температур им. Б. И. Веркина НАН Украины, 2015. - Т. 41 Вып. 8. - С. 792-797

Держатели документа:
B. I. Verkin Institute of Low-temperature Physics and Engineering, National Academy of Sciences of Ukraine, pr. Lenina 47, Kharkov, Ukraine
L. V. Kirenskii Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Gaydamak, T. N.; Gudim, I. A.; Гудим, Ирина Анатольевна; Zvyagina, G. A.; Bilych, I. V.; Burma, N. G.; Zhekov, K. R.; Fil, V. D.
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Gudim, I. A.
Growth of single crystals of trigonal ferroborates (Ho1- xNdx)Fe3(BO3)4 with the huntite structure depending on the crystallochemical growth conditions / I. A. Gudim, V. R. Titova // Магнитные материалы. Новые технологии : тез. докл. VIII Байкал. междунар. конф. BICMM-2018 / чл. прогр. ком. R. S. Iskhakov [et al.]. - Иркутск, 2018. - P. 189. - Библиогр.: 2 . - ISBN 978-5-00133-051-6

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Доп.точки доступа:
Iskhakov, R. S. \чл. прогр. ком.\; Исхаков, Рауф Садыкович; Ovchinnikov, S. G. \чл. прогр. ком.\; Овчинников, Сергей Геннадьевич; Aplesnin, S. S. \чл. прогр. ком.\; Аплеснин, Сергей Степанович; Balaev, D. A. \чл. прогр. ком.\; Балаев, Дмитрий Александрович; Titova, Veronika; Гудим, Ирина Анатольевна; Байкальская международная конференция "Магнитные материалы. Новые технологии"(8 ; 2018 ; авг. ; 24-28 ; Иркутск); "Магнитные материалы. Новые технологии", Байкальская международная конференция(8 ; 2018 ; авг. ; 24-28 ; Иркутск); "Magnetic materials. New tecnologies", Baikal International Conference(8 ; 2018 ; Aug. 24-28 ; Irkutsk); Иркутский государственный университет
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Gudim, I. A.
Growth of single crystals of trigonal ferroborates (Ho1-xNdx) Fe3 (BO3)4 with the khantite structure depending on the crystallochemical growth conditions / I. A. Gudim, V. R. Titova // Sixth European Conference on Crystals Growth (ECCG-6). - 2018. - Ст. S02P. - Библиогр.: 2

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Доп.точки доступа:
Titova, Veronika; Гудим, Ирина Анатольевна; European Conference on Crystals Growth(6 ; 2018 ; Sept ; 15-20 ; Varna, Bulgaria); Bulgarian Academy of SciencesEuropean Network of Crystal Growth
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10.

Heat capacity of Gd0.5Nd0.5Fe3(BO3)4 in the temperature interval of 344–1021 K / L. T. Denisova [et al.] // Russ. J. Phys. Chem. A. - 2014. - Vol. 88, Is. 10. - P. 1626-1628, DOI 10.1134/S0036024414100082. - Cited References: 13. - This work was supported in part by Siberian Federal University, and by the RF Ministry of Education and Science. . - ISSN 0036-0244. - ISSN 1531-863X

РУБ Chemistry, Physical
Рубрики:
MAGNETIC-PROPERTIES
RFE3(BO3)4
Кл.слова (ненормированные):
rare-earth ferroborates -- high-temperature heat capacity
Аннотация: The molar heat capacity of Gd0.5Nd0.5Fe3(BO3)(4) is measured in the temperature interval of 344-1041 K by means of differential scanning calorimetry. Thermodynamic properties of the oxide compound are determined from the experimental data.

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Публикация на русском языке Теплоемкость Gd0.5Nd0.5Fe3(BO3)4 в интервале температур 344–1021 K [Текст] / Л. Т. Денисова [и др.] // Журн. физ. химии : Наука, 2014. - Т. 88 № 10. - С. 1464-1466

Держатели документа:
Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Krasnoyarsk 660041, Russia
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Denisova, L. T.; Денисова Л. Т.; Denisov, V. M.; Денисов, Виктор Михайлович; Gudim, I. A.; Гудим, Ирина Анатольевна; Volkov, N. V.; Волков, Никита Валентинович; Patrin, G. S.; Патрин, Геннадий Семёнович; Chumilina, L. G.; Чумилина, Любовь Геннадьевна; Temerov, V. L.; Темеров, Владислав Леонидович; Siberian Federal University; RF Ministry of Education and Science
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