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Effect of uncontrolled impurities on magnetic and structural transitions of the GdFe3(BO3)4 multiferroic / I. A. Gudim, E. V. Eremin, A. S. Krylov, V. R. Titova // V International Baltic Conference on Magnetism. IBCM : Book of abstracts. - 2023. - P. 128. - Cited References: 3. - Support by RSF and KRFS № 22-12-20019 are acknowledged

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS

Доп.точки доступа:
Gudim, I. A.; Гудим, Ирина Анатольевна; Eremin, E. V.; Еремин, Евгений Владимирович; Krylov, A. S.; Крылов, Александр Сергеевич; Titova, V. R.; International Baltic Conference on Magnetism(5 ; 2023 ; Aug. 20-24 ; Svetlogorsk, Russia); Балтийский федеральный университет им. И. Канта
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    Effect of magnetic and electric fields on the AC resistance of a silicon-on-insulator-based transistor-like device / D. Smolyakov, A. Tarasov, L. Shanidze [et al.] // Phys. Status Solidi A. - 2022. - Vol. 219. Is. 1. - Ст. 2100459, DOI 10.1002/pssa.202100459. - Cited References: 19. - The authors thank the Krasnoyarsk Territorial Center for Collective Use, Krasnoyarsk Scientific Center of the SB RAS, for electron microscope investigations. This study was supported by RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, projects nos. 20-42-243007 and 20-42-240013, and by the Government of the Russian Federation, the Mega-grant for the Creation of Competitive World-Class Laboratories, agreement no. 075-15-2019-1886 . - ISSN 1862-6300. - ISSN 1862-6319
   Перевод заглавия: Влияние магнитного и электрического полей на сопротивление на переменном токе транзисторного устройства на основе кремния на изоляторе

РУБ Materials Science, Multidisciplinary + Physics, Applied + Physics, Condensed Matter
Рубрики:
NANOSTRUCTURES
Кл.слова (ненормированные):
impurities states -- magnetoimpedance -- magnetoresistance -- pseudo-MOSFET -- semiconductors -- SOI structure -- transistor
Аннотация: Herein, the AC magnetoresistance (MR) in the silicon-on-insulator (SOI)-based Fe/Si/SiO2/p-Si structure is presented. The structure is used for fabricating a back-gate field-effect pseudo-metal-oxide-semiconductor field-effect transistor (MOSFET) device. The effects of the magnetic field and gate voltage on the transport characteristics of the device are investigated. Magnetoimpedance value of up to 100% is obtained due to recharging of the impurity and surface centers at the insulator/semiconductor interface. A resistance variation of up to 1000% is found, which is caused by the voltage applied to the gate and the field effect on the band structure of the sample. Combining the magnetic and electric fields, one can either change the absolute value of the AC resistance while having the MR fixed or change the sign and character of the field dependence of the MR. The observed effects can be used in the development of magnetic-field-driven SOI-based devices and high-frequency circuits.

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Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Krasnoyarsk Sci Ctr, Siberian Branch, Akademgorodok 50,Bld 38, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Pr Svobodny 79, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Krasnoyarsk Sci Ctr, Siberian Branch, Akademgorodok 50, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Smolyakov, D. A.; Смоляков, Дмитрий Александрович; Tarasov, A. S.; Тарасов, Антон Сергеевич; Shanidze, Lev; Шанидзе, Лев Викторович; Bondarev, I. A.; Бондарев, Илья Александрович; Baron, F. A.; Барон, Филипп Алексеевич; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Yakovlev, I. A.; Яковлев, Иван Александрович; Volochaev, M. N.; Волочаев, Михаил Николаевич; Volkov, N. V.; Волков, Никита Валентинович; RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science [20-42-243007, 20-42-240013]; Government of the Russian Federation; Mega-grant for the Creation of Competitive World-Class Laboratories [075-15-2019-1886]
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Effect of surfactants on the structure, phase composition, and magnetic properties of FexSy nanoparticles synthesized by thermal decomposition / R. D. Ivantsov, C.-R. Lin, Y.-Z. Chen [et al.] // Nanobiotechnol. Rep. - 2022. - Vol. 17, Is. 3. - P. 336-344, DOI 10.1134/S2635167622030089. - Cited References: 27. - This study was supported by the Russian Foundation for Basic Research with Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, the research project no. 19-42-240005: “Features of the Electronic Structure, Magnetic Properties, and Optical Excitations in Nanocrystals of Multifunctional Magnetic Chalcogenides Fe3S4 and FeSe” and the Russian Foundation for Basic Research and the Ministry of Science and Technology of Taiwan, joint projects nos. 19-52-52002 and 109-2112-M-153-003 and 108-2923-M-153-001-MY3. - The electron-microscopy study was carried out at the Laboratory of Electron Microscopy of the Center for Collective Use of the Siberian Federal University within the state assignment of the Ministry of Science and Higher Education of the Russian Federation (research code FSRZ-2020-0011). The magnetic measurements were carried out on a vibrating sample magnetometer at the Krasnoyarsk Regional Center for Collective Use, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences . - ISSN 2635-1676
Кл.слова (ненормированные):
Agglomeration -- Crystal impurities -- Fourier transform infrared spectroscopy -- High resolution transmission electron microscopy -- Magnetic properties -- Magnetite -- Magnetization -- Nanomagnetics -- Sulfur compounds -- Synthesis (chemical) -- Thermogravimetric analysis -- Thermolysis -- Electron diffraction analysis -- Greigites -- Hexadecylamine -- Inverse spinel structures -- Iron sulfide -- Isostructural -- Octadecyl amine -- Organic shells -- Structures phase -- Synthesised -- Surface active agents
Аннотация: The effect of surfactants on the structure, morphology, and magnetic properties of FexSy iron-sulfide nanoparticles synthesized by thermal decomposition is studied. Oleylamine, hexadecylamine, and octadecylamine are used as surfactants. It is established by X-ray and electron-diffraction analysis combined with Mossbauer spectroscopy that, in samples 1 and 2 prepared using oleylamine and hexadecylamine, respectively, the Fe3S4 greigite phase dominates, with an inverse spinel structure isostructural to the iron oxide Fe3O4 magnetite with minor Fe9S11 impurities. Deviations in the distribution of iron cations over the tetrahedral and octahedral sites relative to the bulk greigite crystals are observed. The nanoparticles synthesized using octadecylamine (sample 3) are found to be multiphase with a greigite fraction of ~20%. In all three cases, as showed the results of transmission electron microscopy and Fourier transform infrared spectroscopy together with thermogravimetry analysis, the magnetic nanoparticles have an organic shell chemically bonded to their magnetic core, which prevents the agglomeration of the particles. This shell is much more massive in samples 2 and 3. The magnetization values for samples 1 and 2 are similar to those of greigite nanoparticles reported in publications, while the magnetization of sample 3 is several times lower, in accordance with the greigite fraction in it. The combination of fairly high magnetization with a massive organic shell allows one to consider hexadecylamine to be a promising surfactant for the synthesis of iron-sulfide nanoparticles protected from external impact and agglomeration.

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Публикация на русском языке Влияние ПАВ на структуру, фазовый состав и магнитные свойства наночастиц FexSy, полученных методом термического разложения [Текст] / Р. Д. Иванцов, Ч. Р. Лин, Ю. Ж. Чэнь [и др.] // Рос. нанотехнол. - 2022. - Т. 17 № 3. - С. 358-367

Держатели документа:
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Department of Applied Physics, National Pingtung University, Pingtung City, 90003, Taiwan
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Lin, C. -R.; Chen, Y. -Z.; Ivanova, O. S.; Иванова, Оксана Станиславовна; Altunin, R. R.; Knyazev, Yu. V.; Князев, Юрий Владимирович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zharkov, S. M.; Жарков, Сергей Михайлович; Shestakov, N. P.; Шестаков, Николай Петрович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Edelman, I. S.; Эдельман, Ирина Самсоновна
}
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Effect of magnetic impurities on superconductivity in LaH10 / D. V. Semenok, I. A. Troyan, A. V. Sadakov [et al.] // Adv. Mater. - 2022. - Vol. 34, Is. 42. - Ст. 2204038, DOI 10.1002/adma.202204038. - Cited References: 106. - In situ X-ray diffraction experiments at high pressure were performed on SPring-8, station BL10XU, Sayo, Japan (proposal No. 2020A0576). This work was supported by JSPS KAKENHI Grant Number 20H05644. Low-pressure studies were carried out on a synchrotron source of the Kurchatov institute (KISI-Kurchatov), station RKFM. The high-pressure experiments were supported by the Ministry of Science and Higher Education of the Russian Federation within the state assignment of the FSRC Crystallography and Photonics of the RAS. I.A.T. was supported by the Russian Science Foundation, project No. 22-12-00163. A.R.O. thanks the Russian Science Foundation (grant 19-72-30043). D.V.S. thanks the Russian Foundation for Basic Research (project 20-32-90099). I.A.K. thanks the Russian Science Foundation (grant No. 21-73-10261) for the financial support of the anharmonic phonon density of states calculations and molecular dynamics simulations. SEM, XRF, and XRD studies of the initial alloys were performed using the equipment of the Shared Research Center FSRC Crystallography and Photonics of the RAS. I.A.T. and A.G.I. acknowledge the use of the facilities of the Center for Collective Use “Accelerator Center for Neutron Research of the Structure of Substance and Nuclear Medicine” of the INR RAS for high-pressure cell preparation. The research used resources of the LPI Shared Facility Center. V.M.P acknowledge the support of the state assignment of the Ministry of Science and Higher Education of the Russian Federation (Project No. 0023-2019-0005) and A.V.S. and O.A.S. acknowledge the support of the Russian Science Foundation, grant 22-22-00570. K.S.P. thanks the Russian Foundation for Basic Research (project 19-02-00888). I.A.K. thanks the Russian Science Foundation (grant No. 19-73-00237) for the financial support of the development of T-USPEX method and anharmonic phonon density of states calculation algorithm. S.W.T was supported by NSF Cooperative Agreement No. DMR-1157490/1644779 and by the State of Florida. A.D.G. was supported by T.H. and T.F. funding. The authors acknowledge the support of the HLD at HZDR, member of the European Magnetic Field Laboratory (EMFL). The authors also thank Igor Grishin (Skoltech) for proofreading the manuscript, and Dr. C. Tantardini (University of Tromsø) for calculations using the virtual crystal approximation, and Dr. E. Talantsev (IMP RAS) for useful discussions . - ISSN 0935-9648. - ISSN 1521-4095
Кл.слова (ненормированные):
Anderson's theorem -- high pressure -- hydrides -- superconductivity
Аннотация: Polyhydrides are a novel class of superconducting materials with extremely high critical parameters, which is very promising for sensor applications. On the other hand, a complete experimental study of the best so far known superconductor, lanthanum superhydride LaH10, encounters a serious complication because of the large upper critical magnetic field HC2(0), exceeding 120–160 T. It is found that partial replacement of La atoms by magnetic Nd atoms results in significant suppression of superconductivity in LaH10: each at% of Nd causes a decrease in TC by 10–11 K, helping to control the critical parameters of this compound. Strong pulsed magnetic fields up to 68 T are used to study the Hall effect, magnetoresistance, and the magnetic phase diagram of ternary metal polyhydrides for the first time. Surprisingly, (La,Nd)H10 demonstrates completely linear HC2(T) ∝ |T – TC|, which calls into question the applicability of the Werthamer–Helfand–Hohenberg model for polyhydrides. The suppression of superconductivity in LaH10 by magnetic Nd atoms and the robustness of TC with respect to nonmagnetic impurities (e.g., Y, Al, C) under Anderson's theorem gives new experimental evidence of the isotropic (s-wave) character of conventional electron–phonon pairing in lanthanum decahydride.

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Держатели документа:
Materials Discovery Laboratory, Skolkovo Institute of Science and Technology, Bolshoy Boulevard, 30/1, Moscow, 121205, Russian Federation
Shubnikov Institute of Crystallography, Federal Scientific Research Center “Crystallography and Photonics”, Russian Academy of Sciences, 59 Leninsky Prospekt, Moscow, 119333, Russian Federation
V.L. Ginzburg Center for High-Temperature Superconductivity and Quantum Materials, P. N. Lebedev Physical Institute, Russian Academy of Sciences, Moscow, 119991, Russian Federation
Center for Fundamental and Applied Research, Dukhov Research Institute of Automatics (VNIIA), st. Sushchevskaya, 22, Moscow, 127055, Russian Federation
Laboratory of Computational Materials Discovery, Moscow Institute of Physics and Technology, 9 Institutsky Lane, Dolgoprudny, 141700, Russian Federation
Crystal Physics Laboratory, NRC “Kurchatov Institute” PNPI, 1, mkr. Orlova roshcha, Gatchina, 188300, Russian Federation
Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50, bld. 38, Krasnoyarsk, 660036, Russian Federation
Synchrotron radiation source “KISI-Kurchatov”, National Research Center “Kurchatov Institute”, Moscow, 123182, Russian Federation
Hochfeld-Magnetlabor Dresden (HLD-EMFL), Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Dresden, 01328, Germany
National High Magnetic Field Laboratory, Florida State University, Tallahassee, FL 32310, United States
Brazilian Synchrotron Light Laboratory (LNLS/Sirius), Brazilian Center for Research in Energy and Materials (CNPEM), Campinas, 13083-100, Brazil
KYOKUGEN, Graduate School of Engineering Science, Osaka University, Machikaneyamacho 1-3, Osaka, Toyonaka, 560-8531, Japan
HSE Tikhonov Moscow Institute of Electronics and Mathematics, National Research University Higher School of Economics, 20 Myasnitskaya ulitsa, Moscow, 101000, Russian Federation

Доп.точки доступа:
Semenok, D. V.; Troyan, I. A.; Sadakov, A. V.; Zhou, D.; Galasso, M.; Kvashnin, A. G.; Ivanova, A. G.; Kruglov, I. A.; Bykov, A. A.; Terent'ev, K. Yu.; Терентьев, Константин Юрьевич; Cherepakhin, A. V.; Черепахин, Александр Владимирович; Sobolevskiy, O. A.; Pervakov, K. S.; Seregin, A. Y.; Helm, T.; Forster, T.; Grockowiak, A. D.; Tozer, S. W.; Nakamoto, Y.; Shimizu, K.; Pudalov, V. M.; Lyubutin, I. S.; Oganov, A. R.
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Admittance spectroscopy of dopants implanted in silicon and impurity state-induced AC magnetoresistance effect / D. A. Smolyakov, A. S. Tarasov, M. A. Bondarev [et al.] // Mater. Sci. Semicond. Process. - 2021. - Vol. 126. - Ст. 105663, DOI 10.1016/j.mssp.2021.105663. - Cited References: 21. - This study was supported by the Government of the Russian Federation , Mega Grant for the Creation of Competitive World-Class Laboratories (Agreement no. 075-15-2019-1886) . - ISSN 1369-8001
Кл.слова (ненормированные):
Semiconductors -- Magnetoimpedance -- Impurities -- Implantation
Аннотация: A silicon structure doped with Ga using ion implantation has been investigated by admittance spectroscopy. It has been established that the presence of the Ga impurity, along with the B one, in the silicon structure leads to the appearance of the second peak in the temperature dependence of the real part of the impedance (admittance). Moreover, switching-on a magnetic field parallel to the sample plane shifts the singularities in the temperature curve to the high-temperature region. This results in the manifestation of both the positive and negative magnetoresistance effect upon temperature and magnetic field variation. It has been found by the standard admittance spectroscopy analysis of the impedance data that the energy structure of the investigated sample includes two interfacial energy levels ES1(0) = 42 meV and ES2(0) = 69.4 meV. As expected, these energies are consistent with the energies of B and Ga dopants. In a magnetic field, these levels increase by 3 meV for B and 2 meV for Ga, which induces the magnetoresistance effect. It has been demonstrated that the interfacial state-induced magnetoresistance effect can be tuned by ion implantation and dopant selection.

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Держатели документа:
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences660036, Russian Federation
Lobachevsky State University, Nizhny Novgorod603950, Russian Federation

Доп.точки доступа:
Smolyakov, D. A.; Смоляков, Дмитрий Александрович; Tarasov, A. S.; Тарасов, Антон Сергеевич; Bondarev, M. A.; Бондарев, Михаил Александрович; Nikolskaya, A. A.; Vasiliev, V. K.; Volochaev, M. N.; Волочаев, Михаил Николаевич; Volkov, N. V.; Волков, Никита Валентинович
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Decisive proofs of the s± → s++ transition in the temperature dependence of the magnetic penetration depth / V. A. Shestakov, M. M. Korshunov, Y. N. Togushova, O. V. Dolgov // Supercond. Sci. Technol. - 2021. - Vol. 34, Is. 7. - Ст. 075008, DOI 10.1088/1361-6668/abff6f. - Cited References: 40. - We are grateful to D V Efremov, A S Fedorov, S G Ovchinnikov, E I Shneyder, D Torsello, and A N Yaresko for useful discussions. This work was supported in part by the Russian Foundation for Basic Research (RFBR) Grant No. 19-32-90109 and by RFBR and Government of Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science to the Research Projects 'Electronic correlation effects and multiorbital physics in iron-based materials and cuprates' Grant No. 19-42-240007. . - ISSN 0953-2048. - ISSN 1361-6668

РУБ Physics, Applied + Physics, Condensed Matter
Рубрики:
ORDER-PARAMETER
   IMPURITIES
   SUPERCONDUCTORS
   STATES
   MODEL
Кл.слова (ненормированные):
unconventional superconductors -- iron pnictides -- iron chalcogenides -- impurity scattering -- penetration depth
Аннотация: One of the features of the unconventional s± state in iron-based superconductors is possibility to transform to the s++ state with the increase of the nonmagnetic disorder. Detection of such a transition would prove the existence of the s± state. Here we study the temperature dependence of the London magnetic penetration depth within the two-band model for the s± and s++ superconductors. By solving Eliashberg equations accounting for the spin-fluctuation mediated pairing and nonmagnetic impurities in the T-matrix approximation, we have derived a set of specific signatures of the s± → s++ transition: (1) sharp change in the behavior of the penetration depth λL as a function of the impurity scattering rate at low temperatures; (2) before the transition, the slope of ΔλL(T) = λL(T) - λL(0) increases as a function of temperature, and after the transition this value decreases; (3) the sharp jump in the inverse square of the penetration depth as a function of the impurity scattering rate, λL-2(Γa), at the transition; (4) change from the single-gap behavior in the vicinity of the transition to the two-gap behavior upon increase of the impurity scattering rate in the superfluid density ρs(T).

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Держатели документа:
RAS, Fed Res Ctr KSC SB, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
RAS, PN Lebedev Phys Inst, Moscow 119991, Russia.
Donostia Int Phys Ctr, San Sebastian 20018, Spain.

Доп.точки доступа:
Shestakov, V. A.; Шестаков, Вадим Андреевич; Korshunov, M. M.; Коршунов, Максим Михайлович; Togushova, Yu. N.; Тогушова Ю. Н.; Dolgov, O., V; Russian Foundation for Basic Research (RFBR)Russian Foundation for Basic Research (RFBR) [19-32-90109]; RFBRRussian Foundation for Basic Research (RFBR); Government of Krasnoyarsk Territory; Krasnoyarsk Regional Fund of Science to the Research Projects 'Electronic correlation effects and multiorbital physics in iron-based materials and cuprates' [19-42-240007]
}
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Regulation of the phase transition temperature and hysteresis width by changing the composition of solid solution / K. N. Boldyrev, V. M. Burlakov, I. A. Gudim [et al.] // Phys. Rev. Mater. - 2021. - Vol. 5, Is. 9. - Ст. 094414, DOI 10.1103/PhysRevMaterials.5.094414. - Cited References: 52. - This work is supported by the Russian Science Foundation under Grant No. 19-12-00413 . - ISSN 2475-9953
Кл.слова (ненормированные):
Crystal impurities -- Electronic cooling -- Hysteresis -- Hysteresis loops -- Magnetic materials -- Magnetic storage -- Optical switches -- Rare earths -- Temperature -- Virtual storage -- F-f transitions -- Frequency shift -- Hysteresis widths -- Mixed crystals -- Optical spectrum -- Phase transition temperatures -- Rectangular hysteresis loop -- Structural phase transition -- Thermal hysteresis -- Transition hysteresis -- Solid solutions
Аннотация: A detailed study of the structural phase transition in Eu1–xLaxFe3(BO3)4 mixed crystals as a function of composition is reported. By analyzing a frequency shift of an electronic f-f transition in high-resolution optical spectra of Eu3+ ions, we detected a decrease in the phase transition temperature Ts from 87.05 to 12.2 K (upon cooling) and a simultaneous increase in thermal hysteresis ΔTs from 0.29 to 4.7 K with increasing x from x=0 to x=0.12. A rectangular hysteresis loop was observed. The experimental Ts(x) and ΔTs(x) dependences are described within the developed analytical model utilizing linear decrease in Ts with x and treating the increase in ΔTs in terms of the impurity-related decrease in the interaction between some local order parameters. We argue that R1−xR′xFe3(BO3)4 solid solutions, where R and R′ are different rare-earth elements, can be used to implement optical storage devices and switches operating at any chosen temperature between 0 and 450 K. It is found that the changes in the composition and, correspondingly, structural phase transition parameters do not affect the magnetic phase transformation. Eu0.88La0.12Fe3(BO3)4 demonstrates the structural phase transition at about 12 K, well below the Néel temperature TN=32K.

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Держатели документа:
Institute of Spectroscopy, Russian Academy of Sciences, Troitsk, Moscow, 108840, Russian Federation
Linacre College, University of Oxford, St Cross Road, Oxford, OX1 3JA, United Kingdom
Kirensky Institute of Physics, Siberian Branch of RAS, Krasnoyarsk, 660036, Russian Federation
Lebedev Physical Institute, Russian Academy of Sciences, Moscow, 119991, Russian Federation

Доп.точки доступа:
Boldyrev, K. N.; Burlakov, V. M.; Gudim, I. A.; Гудим, Ирина Анатольевна; Gavrilkin, S. Y.; Popova, M. N.
}
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Zhandun, V. S.
The effect of the impurities on the magnetic, electronic and optical properties of Mn5Ge3 / V. Zhandun, A. Matsynin // Chin. J. Phys. - 2020. - Vol. 68. - P. 9-18, DOI 10.1016/j.cjph.2020.06.027. - Cited References: 29. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science to the research projects № № 19-42-240016 : «Control of structural, magnetic, electronic, and optical properties by pressure and intercalation into functional compounds with a spinel structure containing 3d and 4f ions» and 18-42-243009: «New magnetic film nanocomposites based on layered GeO/Mn systems: synthesis, experimental and theoretical study of structural and magnetic properties». The calculations were performed with the computer resources of "Complex modeling and data processing research installations of mega-class" SRC "Kurchatovsky Institute” ( http://ckp.urcki.ru ) . - ISSN 0577-9073
Кл.слова (ненормированные):
Ab initio calculations -- Mn-Ge system -- Mn5Ge3 alloy -- Nowotny Mn5Ge3Oy phase -- Magnetic properties -- Impurities -- Spin-crossover
Аннотация: Earlier, we experimentally showed a significant effect of oxygen on the magnetic and structural properties of Mn5Ge3 due to the formation of a Nowotny phase of Mn5Ge3Ox. Here, in continuation of this study, we present a theoretical study of the magnetic and electronic properties of Mn5Ge3 and Mn5Ge3Dx (D = B, C, O). It was found that hexagonal Mn5Ge3 is a ferromagnetic metal with two nonequivalent manganese atoms in the structure. Our ab initio calculations also predict the existence of a spin-crossover in Mn5Ge3 under pressure. Impurities reduce saturation magnetization and electrical and thermal conductivity; however, the magnetic susceptibility and Curie temperature increase. Microscopic mechanisms of the effect of the impurities on the magnetic and electronic properties Mn5Ge3 are discussed.

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Держатели документа:
Kirensky Institute of Physics - Federal Research Center “Krasnoyarsk Science Centre, Siberian Branch of the Russian Academy of Sciences”, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Matsynin, A. A.; Мацынин, Алексей Александрович; Жандун, Вячеслав Сергеевич
}
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Comparing the magnetic and magnetoelectric properties of the SmFe3(BO3)4 ferroborate single crystals grown using different solvents / E. Eremin [et al.] // J. Cryst. Growth. - 2019. - Vol. 518. - P. 1-4, DOI 10.1016/j.jcrysgro.2019.04.017. - Cited References: 17. - This study was supported by the Russian Foundation for Basic Research (RFBR) according to the research projects No. 18-02-00696_a and RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund by project No. 18-42-240011 p_a. . - ISSN 0022-0248. - ISSN 1873-5002

РУБ Crystallography + Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
POLARIZATION
FEATURES
Кл.слова (ненормированные):
Impurities -- Growth from solutions -- Single crystal growth -- Borates -- Ferroelectric materials -- Magnetic materials
Аннотация: SmFe3(BO3)4 single crystals have been grown from the bismuth trimolybdate and lithium tungstate-based melt–solutions. Samarium ferroborate single crystals were grown first from the lithium–tungstate flux. The magnetic and magnetoelectric properties of the synthesized crystals have been compared. It is shown that the SmFe3(BO3)4 ferroborate grown from the bismuth trimolybdate-based melt–solution contains impurities of Bi3+ ions (∼5% at.), which replace Sm3+ ions, while the SmFe3(BO3)4, ferroborate grown from the lithium tungstate-based melt–solution contains minor or zero amounts of such impurities. The magnetoelectric and magnetodielectric effects with the Bi3+ admixture appeared 1.5× stronger than in SmFe3(BO3)4; this is probably due to twinning.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Siberian State Univ Sci & Technol, Krasnoyarsk 660037, Russia.

Доп.точки доступа:
Eremin, E. V.; Еремин, Евгений Владимирович; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович; Smolyakov, D. A.; Смоляков, Дмитрий Александрович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Russian Foundation for Basic Research (RFBR) [18-02-00696_a]; RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund [18-42-240011 p_a]
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10.

    Yurkin, G. Yu.
    Magnetic Properties of Fe1-xCoxSi Single Crystals at Low Co Impurity Concentrations / G. Y. Yurkin, G. S. Patrin, S. A. Yarikov // J. Sib. Fed. Univ. Math. Phys. - 2019. - Vol. 12, Is. 1. - P. 94-99 ; Журнал СФУ. Математика и физика, DOI 10.17516/1997-1397-2019-12-1-94-99. - Cited References: 17 . - ISSN 1997-1397. - ISSN 2313-6022
   Перевод заглавия: Магнитные свойства монокристаллов Fe1-x CoxSi при малой концентрации примеси Co
Кл.слова (ненормированные):
Co impurities -- iron silicide -- superparamagnetism -- силицид железа -- примесь Co -- суперпарамагнетизм
Аннотация: Magnetostatic properties of FeSi and Fe0,98Co0,02Si single crystals have been studied. It has been found that the temperature and field dependences of the magnetization of monocrystal FeSi are strongly affected by introduction of a small amount of Co (2 %). A description of the results were provided by a model accounting for the formation of superparamagnetic iron clusters, as well as Fe-Co complexes. It is assumed that Fe-Co complexes form a ferromagnetic phase, which is approximately 0.6% of the Fe0,98Co0,02Si sample weight.
В работе представлено исследование магнитостатических характеристик образцов FeSi и Fe0,98Co0,02Si. Обнаружено, что внесение небольшого количества примести Co(2%) значительно влияет на температурные и полевые зависимости намагниченности монокристалла FeSi. Результаты обработаны в рамках модели, учитывающей образование суперпарамагнитных кластеров железа, а также комплексов Fe-Co. Предполагается, что комплексы Fe-Co образуют ферромагнитную фазу, которая составляет примерно 0,6 % от массы образца Fe0,98Co0,02Si.

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Держатели документа:
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Svobodny 79, Krasnoyarsk 660041, Russia.
Kirensky Inst Phys SB RAS, Akademgorodok 50-38, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Patrin, G. S.; Патрин, Геннадий Семёнович; Yarikov, Stanislav A.; Яриков, Станислав Алексеевич; Юркин, Глеб Юрьевич

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