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    Colloidal and deposited products of the interaction of tetrachloroauric acid with hydrogen selenide and hydrogen sulfide in aqueous solutions / S. Vorobyev [et al.] // Minerals. - 2018. - Vol. 8, Is. 11. - Ст. 492, DOI 10.3390/min8110492. - Cited References: 63. - This research was funded by the Siberian Branch of the Russian Academy of sciences, Program of Interdisciplinary Studies, grant number 64 (project 303). . - ISSN 2075-163X
   Перевод заглавия: Коллоидные и осажденные продукты взаимодействия золотохлористоводородной кислоты с селеноводородом и сероводородом в водных растворах
Кл.слова (ненормированные):
Gold selenide -- Gold sulfoselenide -- Colloids -- Nanoparticles -- Nucleation -- Liquid intermediates -- Deposition
Аннотация: The reactions of aqueous gold complexes with H2Se and H2S are important for transportation and deposition of gold in nature and for synthesis of AuSe-based nanomaterials but are scantily understood. Here, we explored species formed at different proportions of HAuCl4, H2Se and H2S at room temperature using in situ UV-vis spectroscopy, dynamic light scattering (DLS), zeta-potential measurement and ex situ Transmission electron microscopy (TEM), electron diffraction, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. Metal gold colloids arose at the molar ratios H2Se(H2S)/HAuCl4 less than 2. At higher ratios, pre-nucleation “dense liquid” species having the hydrodynamic diameter of 20–40 nm, zeta potential −40 mV to −50 mV, and the indirect band gap less than 1 eV derived from the UV-vis spectra grow into submicrometer droplets over several hours, followed by fractional nucleation in the interior and coagulation of disordered gold chalcogenide. XPS found only one Au+ site (Au 4f7/2 at 85.4 eV) in deposited AuSe, surface layers of which partially decomposed yielding Au0 nanoparticles capped with elemental selenium. The liquid species became less dense, the gap approached 2 eV, and gold chalcogenide destabilized towards the decomposition with increasing H2S content. Therefore, the reactions proceed via the non-classical mechanism involving “dense droplets” of supersaturated solution and produce AuSe1−xSx/Au nanocomposites.

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Держатели документа:
Institute of Chemistry and Chemical Technology of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Kirensky Institute of Physics of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Electron Microscopy Laboratory, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Vorobyev, S.; Likhatski, M.; Romanchenko, A.; Maksimov, N.; Zharkov, S. M.; Жарков, Сергей Михайлович; Krylov, A. S.; Крылов, Александр Сергеевич; Mikhlin, Y.
}
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Gavrichkov, V. A.
Superexchange interaction in magnetic insulators with spin crossover / V. A. Gavrichkov, S. I. Polukeev, S. G. Ovchinnikov // J. Exp. Theor. Phys. - 2018. - Vol. 127, Is. 4. - P. 713-720, DOI 10.1134/S1063776118100023. - Cited References: 34. - This work was supported by the Russian Science Foundation (project no. 18-12-00022). . - ISSN 1063-7761
Кл.слова (ненормированные):
Antiferromagnetism -- Ground state -- High pressure engineering -- Ions -- Iron compounds -- Magnetic materials
Аннотация: We present the derivation of a microscopic superexchange Hamiltonian for undoped magnetic insulators with an arbitrary spin. It is established that the sign of the (ferromagnetic or antiferromagnetic) superexchange between magnetic ions in the dn configuration depends on the spin nature of virtual multielectron states dn± 1, viz., low-spin or high-spin partners with S ± 1/2 relative to ground state of the dn configuration with spin S. A macroscopic substantiation is given for the Goodenough–Kanamori rules and simple mean-field estimates connecting the magnetic ordering temperature with the exchange constant. The conventional Anderson superexchange for magnetic materials with spin S = 1/2 and the P/T magnetic phase diagram for ferroborate FeBO3 with spin crossover S = (5/2 ↔ 1/2) at the Fe3+ ion under a high pressure are also reproduced as a test.

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Публикация на русском языке Гавричков, Владимир Александрович. Суперобменное взаимодействие в магнитных диэлектриках со спиновым кроссовером [Текст] : статья / В. А. Гавричков, С. И. Полукеев, С. Г. Овчинников // Журн. эксперим. и теор. физ. - 2018. - Т. 154 Вып. 4. - С. 835-843

Держатели документа:
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Polukeev, S. I.; Полукеев, Семен Игоревич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Гавричков, Владимир Александрович
}
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Parshin, A. M.
Structuring of the surface layer of polycarbonate film upon interaction with nematic liquid crystal / A. M. Parshin, V. Y. Zyryanov, V. F. Shabanov // Polym. Sci. Ser. C. - 2018. - Vol. 60, Is. 1. - P. 23-31, DOI 10.1134/S181123821801006X. - Cited References: 24. - This work was partially supported by the Russian Foundation for Basic Research (project nos. 15-02-06924 and 16-53-00073). . - ISSN 1811-2382. - ISSN 1555-614X

РУБ Polymer Science
Рубрики:
TEMPERATURE-DEPENDENCE
   MAGNETIC-FIELD
   ALIGNMENT
   ORIENTATION
Аннотация: The structure formation observed in the surface layer of polycarbonate which proceeds when nematic liquid crystal is deposited on a film is studied. Films prepared from polycarbonate solutions in dichloromethane, chloroform, or pyridine and dried in thermobalance at different temperatures and different drying times are studied. Textures are prepared in the process of domain growth. The effect of the orientation of the disclination lines in a magnetic field and the memory effect of molecular ordering after removal and redeposition of the liquid crystal layer are observed. The process of structure formation is analyzed on the basis of the model of cooperative interaction of liquid crystal molecules with polymer chains taking into account the adsorption mechanism.

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Публикация на русском языке Паршин, Александр Михайлович. Структурообразование в поверхностном слое пленки поликарбоната при взаимодействии с нематическим жидким кристаллом [Текст] / А. М. Паршин, В. Я. Зырянов, В. Ф. Шабанов // Высокомолек. соед. С. - 2018. - Т. 60 № 1. - С. 27-36

Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Shabanov, V. F.; Шабанов, Василий Филиппович; Паршин, Александр Михайлович; Russian Foundation for Basic Research [15-02-06924, 16-53-00073]
}
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Komogortsev, S. V.
The magnetic dipole-dipole interaction effect on the magnetic hysteresis at zero temperature in nanoparticles randomly dispersed within a plane / S. V. Komogortsev, V. A. Fel'k, O. A. Li // J. Magn. Magn. Mater. - 2019. - Vol. 473. - P. 410-415, DOI 10.1016/j.jmmm.2018.10.091. - Cited References: 58. - This work was supported by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project № 18-42-240006. . - ISSN 0304-8853
Кл.слова (ненормированные):
Micromagnetic simulation -- Magnetic hysteresis -- Magnetic nanoparticles -- Dipole-dipole interaction
Аннотация: The dipole-dipole interaction effect on the magnetic hysteresis of nanoparticles randomly dispersed within a plane is studied by micromagnetic simulation. The dependence of the coercive field with the concentration of nanoparticles varies from nonlinear and monotonic to non-monotonic dependence with a maximum at a certain concentration. It happens when the ratio of the magnetic anisotropy constant to the maximal dipole energy changes from value much larger than 1 to the value much less than unity.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Reshetnev Siberian State University of Science and Technology, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Fel'k, V. A.; Li, O. A.; Комогорцев, Сергей Викторович
}
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    An effect of reduced S-rich fluids on diamond formation under mantle-slab interaction / Y. V. Bataleva [et al.] // Lithos. - 2019. - Vol. 336-337. - P. 27-39, DOI 10.1016/j.lithos.2019.03.027. - Cited References: 73. - This work was supported by the Russian Science Foundation under Grant No. 14-27-00054 and a state assignment of IGM SB RAS. The authors thank S. Ovchinnikov for his assistance in implementation of the Mossbauer spectroscopy measurements. . - ISSN 0024-4937
   Перевод заглавия: Влияние восстановленных S-обогащенных флюидов на образование алмаза при взаимодействии мантиевых плит
Кл.слова (ненормированные):
Sulfur-rich fluid -- Iron carbide -- Diamond -- Mantle sulfides -- High-pressure experiment
Аннотация: Experimental study, dedicated to understanding the effect of S-rich reduced fluids on the diamond-forming processes under subduction settings, was performed using a multi-anvil high-pressure split-sphere apparatus in Fe3C-(Mg,Ca)CO3-S and Fe0-(Mg,Ca)CO3-S systems at the pressure of 6.3 GPa, temperatures in the range of 900–1600 °C and run time of 18–60 h. At the temperatures of 900 and 1000 °C in the carbide-carbonate-sulfur system, extraction of carbon from cohenite through the interaction with S-rich reduced fluid, as well as C0-producing redox reactions of carbonate with carbide were realized. As a result, graphite formation in assemblage with magnesiowüstite, cohenite and pyrrhotite (±aragonite) was established. At higher temperatures (≥1100 °C) formation of assemblage of Fe3+-magnesiowüstite and graphite was accompanied by generation of fO2-contrasting melts - metal-sulfide with dissolved carbon (Fe-S-C) and sulfide-oxide (Fe-S-O). In the temperature range of 1400–1600 °C spontaneous diamond nucleation was found to occur via redox interactions of carbide or iron with carbonate. It was established, that interactions of Fe-S-C and Fe-S-O melts as well as of Fe-S-C melt and magnesiowüstite, were С0-forming processes, accompanied by disproportionation of Fe. These resulted in the crystallization of Fe3+-magnesiowüstite+graphite assemblage and growth of diamond. We show that a participation of sulfur in subduction-related elemental carbon-forming processes results in sharp decrease of partial melting temperatures (~300 °C), reducting the reactivity of the Fe-S-C melt relatively to FeC melt with respect to graphite and diamond crystallization and decrease of diamond growth rate.

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Держатели документа:
Sobolev Institute of Geology and Mineralogy, Mineralogy Siberian Branch of the Russian Academy of Sciences, Academican Koptyug Ave., 3, Novosibirsk, 630090, Russian Federation
Novosibirsk State University, Pirogova str., 2, Novosibirsk, 630090, Russian Federation
Kirensky Institute of Physics, Siberian Branch of Russian Academy of Sciences, Akademgorodok 50, bld. 38, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Bataleva, Y. V.; Palyanov, Y. N.; Borzdov, Y. M.; Novoselov, I. D.; Bayukov, O. A.; Баюков, Олег Артемьевич
}
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Brownian dynamics of the self-assembly of complex nanostructures in the field of quasi-resonant laser radiation / V. S. Kornienko [et al.] // Photonics Nanostruc. Fundam. Appl. - 2019. - Vol. 35. - Ст. 100707, DOI 10.1016/j.photonics.2019.100707. - Cited References: 32. - The reported study was funded by Russian Science Foundation (Grant 18-72-00003 ). V.V. Slabko is grateful for the support from the Ministry of Education and Science of the Russian Federation (Grant 3.6341.2017/VU ). . - ISSN 1569-4410
Кл.слова (ненормированные):
Dipole-dipole interaction -- Laser field -- Brownian dynamics -- Self-assembly of nanostructures -- Colloidal crystals
Аннотация: Self-assembly of nanoparticles under the action of laser field can be an universal method for the formation of nanostructures with specific properties for application in sensorics and nanophotonics. For prognosis of the self-assembly processes, the model of movement of an ensemble of nanoparticles in a viscous media under the action of laser radiation with the account for interaction of laser-induced polarizations and Brownian dynamics is developed. This model is applied to the investigation of the self-assembly process of a triple of nanoparticles into three-particle structure with a predetermined geometry.Two specific cases of formation of nanostructure from a preliminarily formed pair of particles are studied: either for the pair fixed in space or from the unfixed pair of nanoparticles. The geometry of resulting nanostructures is shown to be determined by the polarization direction of laser radiation and the laser wavelength. Under proper choice of these parameters the formation of structures is shown to be highly efficient. E. g., maximum probability of structures formation is as hig as 36–46% per single laser pulse of 10 ns duration. © 2019 Elsevier B.V.

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Держатели документа:
Siberian Federal University, Krasnoyarsk, Russian Federation
Department of Computational Mathematics, Institute of Computational Modeling of Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Laboratory of Coherent Optics, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Kornienko, V. S.; Tsipotan, A. S.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Slabko, V. V.
}
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Val'kov, V. V.
Influence of the Coulomb repulsions on the formation of the superconducting gap of the spin-polaron quasiparticles in cuprates / V. V. Val'kov, M. M. Korovushkin, A. F. Barabanov // J. Low Temp. Phys. - 2019. - Vol. 196, Is. 1-2. - P. 242–252, DOI 10.1007/s10909-018-02120-3. - Cited References: 26. - The work was supported by the program of the Presidium of the Russian Academy of Sciences No. 12 “Fundamental problems of high-temperature superconductivity,” the Russian Foundation for Basic Research (Projects Nos. 16-02-00304 and 18-02-00837) and partly by the Government of Krasnoyarsk Region and the Krasnoyarsk Region Science and Technology Support Fund (Projects Nos. 18-42-243002 “Manifestation of spin-nematic correlations in spectral characteristics of electronic structure and their influence on practical properties of cuprate superconductors” and 18-42-243018 “Contact phenomena and magnetic disorder in the problem of the formation and detection of topological edge states in semiconductor nanostructures”), and the grant of the President of the Russian Federation (Project MK-1398.2017.2). . - ISSN 0022-2291. - ISSN 1573-7357
Кл.слова (ненормированные):
Cuprate superconductors -- Intersite Coulomb interaction -- Spin polarons -- Spin-charge correlations -- Unconventional superconductivity
Аннотация: Taking into account the real crystalline structure of the CuO2 plane and the strong spin-fermion coupling, the influence of the on-site Coulomb repulsion of holes Up and the intersite Coulomb repulsion V2 between holes located at the next-nearest-neighbor oxygen ions on the formation of the superconducting gap with the d-wave symmetry of the order parameter of the spin-polaron quasiparticles is studied. It is shown that the formation of the resulting superconducting gap within the spin-fermion model is caused by three components. The dependence of the narrowing of the superconducting gap on the values Up and V2 is analyzed.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia
Vereshchagin Institute for High Pressure Physics, Troitsk, Moscow, Russia

Доп.точки доступа:
Korovushkin, M. M.; Коровушкин, Максим Михайлович; Barabanov, A. F.; Вальков, Валерий Владимирович
}
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XMCD study of Ru/Co/W/Ru films with strong Dzyaloshinskii-Moriya interaction / A. S. Samardaki [et al.] // IEEE International Magnetics Conference (INTERMAG). - 2018. - Ст. UNSP 1800GW01, DOI 10.1109/INTMAG.2018.8508080. - Cited References: 5 . - ISBN 978-1-5386-6425-4
Аннотация: An enhancement of the spin-orbit effects arising on an interface between a ferromagnet (FM) and a heavy metal (HM) is possible through the strong breaking of the structural inversion symmetry in the layered films. We have found that the introduction of an ultrathin W interlayer between Co and Ru in Ru/Co/Ru films enables to preserve perpendicular magnetic anisotropy (PMA) and simultaneously induce a large interfacial Dzyaloshinskii-Moriya interaction (iDMI). We find that the Ru/Co/W/Ru films have PMA up to 0.35 nm of the nominal thickness of W(tW). The study of the spin-wave propagation in the Damon-Eshbach geometry by Brillouin light scattering (BLS) spectroscopy reveals the drastic increase of the iDMI value with the rising tW. The maximum iDMI of -3.1 erg/cm 2 is observed for tW=0.24 nm, which is 10 times larger than the latter for the quasi-symmetrical Ru/Co/Ru films [1]. Our polycrystalline Ru/Co/W/Ru films were prepared by magnetron sputtering on the SiO 2 substrates at room temperature. The base pressure in the chamber was 10−8 Torr. The working pressure of Ar+ was 10−4 Torr. In order to precise control the thickness of layers, we used low sputtering rates: V(Ru)=0.011 nm/s, V(Co)=0.018 nm/s, V(W)=0.02 nm/s. The Co thickness (tCo) was varied from 0.7 to 1.5 nm. The thickness of the buffer and capping Ru layers (tRu) was 10 and 2 nm, correspondingly. The W thickness (tW) was taken in the range from 0 to 0.4 nm. Polarization dependent X-ray spectroscopy measurements at the Co K− (7709 eV), WL3− (10207 eV) and WL2− (11544 eV) edges on the Ru(10nm)/Co(1nm)/W(x)/Ru(2nm) structures were performed at the ESRF ID12 beamline. Four different samples have been measured with x=0, 0.21, 0.25 and 0.29, where x is the thickness of the layer in nm. The APPLE-II undulator and a Si(111) double crystal monochromator were used to collect the spectra.

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Держатели документа:
Far Eastern Fed Univ, Sch Nat Sci, Vladivostok, Russia.
ESRF, Grenoble, France.
Kirensky Inst Phys, Krasnoyarsk, Russia.

Доп.точки доступа:
Samardaki, A. S.; Kolesnikovi, A.; Ognev, A.; Platunov, M. S.; Платунов, Михаил Сергеевич; Rogalev, A.; IEEE International Magnetics Conference(2018 ; Apr. ; 23-27 ; Singapore)
}
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    Manifestation of magnetoelastic interactions in Raman spectra of HoxNd1-хFe3(BO3)4 crystals / A. S. Krylov [et al.] // J. Adv. Dielectr. - 2018. - Vol. 08, Is. 02. - Ст. 1850011, DOI 10.1142/S2010135X1850011X. - Cited References: 32 . - ISSN 2010-135X
   Перевод заглавия: Проявление магнитоупругих взаимодействий в спектрах комбинационного рассеяния кристаллов HoxNd1-xFe3(BO3)4
Кл.слова (ненормированные):
Multiferroic -- magnetoelastic interaction -- Raman spectra -- phase transition -- magnetic ordering
Аннотация: Raman spectra of Ho1-xNdxFe(BO3)4 (x=1, 0.75, 0.5, 0.25) have been studied in temperature range 10-400K. Two compositions (x=1, x=0.75) demonstrate structural phase transition with soft mode restoration. The addition of Nd atoms increases interatomic spacing and decreases the temperature of structural phase transition. The solid solutions (x=0.75, 0.5, 0.25) demonstrate the emergence of the peaks corresponding to magnetoelastic interaction below Neel temperature. The order parameter of the magnetic phase transition has been determined. The equal concentrations of holmium and neodymium atoms prevent magnon soft modes condensation caused by exchange interactions in Fe-O-Fe chains are observed. Calculations confirm the data obtained in the experiment.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Material Research Laboratory, Discipline of Physics and MEMS, Indian Institute of Technology Indore, Simrol, India

Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Sofronova, S. N.; Софронова, Светлана Николаевна; Gudim, I. A.; Гудим, Ирина Анатольевна; Krylova, S. N.; Крылова, Светлана Николаевна; Kumar, R.; Vtyurin, A. N.; Втюрин, Александр Николаевич; International Workshop on Advanced Dielectric Materials and Their Applications(Oct. 8-11, 2017 ; Xi'an, China)
}
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10.

Stability of the superconducting d-wave pairing toward the intersite Coulomb repulsion in CuO2 plane / V. V. Val'kov [et al.] // J. Low Temp. Phys. - 2018. - Vol. 191, Is. 5-6. - P. 408-425, DOI 10.1007/s10909-018-1882-7. - Cited References: 70. - Acknowledgements The work was supported by the program of the Presidium of the Russian Academy of Sciences No. 12 “Fundamental problems of high-temperature superconductivity”, the Russian Foundation for Basic Research (RFBR) and partly by the Government of Krasnoyarsk Region and the Krasnoyarsk Region Science and Technology Support Fund (Projects Nos. 16-42-243057 and 16-42-240435). The work of A. F. B. was funded by RFBR (Project No. 16-02-00304). The work of M. M. K. was supported by a grant of the President of the Russian Federation (Project MK-1398.2017.2). . - ISSN 0022-2291
Кл.слова (ненормированные):
Cuprate superconductors -- Unconventional superconductivity -- Spin-charge coupling -- Spin polarons -- Intersite Coulomb interaction
Аннотация: Taking into account the real crystalline structure of the CuO2 plane and the strong spin-fermion coupling, we study the influence of the intersite Coulomb repulsion between holes on the Cooper instability of the spin-polaron quasiparticles in cuprate superconductors. The analysis shows that only the superconducting d-wave pairing is implemented in the whole region of doping, whereas the solutions of the self-consistent equations for the s-wave pairing are absent. It is shown that intersite Coulomb interaction V1 between the holes located at the nearest oxygen ions does not affect the d-wave pairing, because its Fourier transform Vq vanishes in the kernel of the corresponding integral equation. The intersite Coulomb interaction V2 of quasiparticles located at the next-nearest oxygen ions does not vanish in the integral equations, however, but it is also shown that the d-wave pairing is robust toward this interaction for physically reasonable values of V2.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian State University of Science and Technology, Krasnoyarsk, Russian Federation
Vereshchagin Institute for High Pressure Physics, Troitsk, Moscow, Russian Federation

Доп.точки доступа:
Val'kov, V. V.; Вальков, Валерий Владимирович; Dzebisashvili, D. M.; Дзебисашвили, Дмитрий Михайлович; Korovushkin, M. M.; Коровушкин, Максим Михайлович; Barabanov, A. F.
}
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