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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Fedorov A. S., Fedorov D. A., Kuzubov A. A., Avramov P. V., Nishimura Y., Irle S., Witek H. A.
Заглавие : Relative Isomer Abundance of Fullerenes and Carbon Nanotubes Correlates with Kinetic Stability
Разночтения заглавия :авие SCOPUS: Relative isomer abundance of fullerenes and carbon nanotubes correlates with kinetic stability
Место публикации : Phys. Rev. Lett.: AMER PHYSICAL SOC, 2011. - Vol. 107, Is. 17. - Ст.175506. - ISSN 0031-9007, DOI 10.1103/PhysRevLett.107.175506
Примечания : Cited References: 29. - S. I, P. V. A, and A. S. F gratefully acknowledge generous hospitality during their visits to Krasnoyarsk (S. I) and Fukui Institute for Fundamental Chemistry in Kyoto and Nagoya University (P. V. A and A. S. F) under support of the joint JSPS-RFBR travel grant 09-02-92107. This work was partially supported by National Science Council (grants NSC96-2113-M009-022-MY3 and NSC96-2113-M009-011-MY3) and Ministry of Education of Taiwan (MOE-ATU project), as well as by the JAEA Research fellowship (P. V. A). We thank the Institute of Computer Modeling (Siberian Division of RAS) and the Joint Supercomputer Center RAS for opportunity to use cluster computers for performing all calculations.
Предметные рубрики: CHEMICAL MOLECULAR-DYNAMICS
C-60
BUCKMINSTERFULLERENE
MECHANISM
ROAD
Ключевые слова (''Своб.индексиров.''): carbon nanostructures--kinetic factors--kinetic stability--thermal vibration--carbon nanotubes--fullerenes--isomers--kinetics
Аннотация: A methodology to evaluate the kinetic stability of carbon nanostructures is presented based on the assumption of the independent and random nature of thermal vibrations. The kinetic stability is directly correlated to the cleavage probability for the weakest bond of a given nanostructure. The application of the presented method to fullerenes and carbon nanotubes yields clear correlation to their experimentally observed relative isomer abundances. The general and simple formulation of the method ensures its applicability to other nanostructures for which formation is controlled by kinetic factors.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Rubab N., Erkaev N. V., Langmayr D., Biernat H. K.
Заглавие : Kinetic Alfven wave instability in a Lorentzian dusty magnetoplasma
Коллективы :
Разночтения заглавия :авие SCOPUS: Kinetic Alfv́n wave instability in a Lorentzian dusty magnetoplasma
Место публикации : Phys. Plasmas: AMER INST PHYSICS, 2010. - Vol. 17, Is. 10. - Ст.103704. - ISSN 1070-664X, DOI 10.1063/1.3491336
Примечания : Cited References: 54. - This work is funded by the Higher Education Commission of Pakistan under the HEC-Overseas scholarship program Grant No. Ref: 1-1/PM OS /Phase-II/Batch-I/Austria/2007/. Part of this work was done while N. V. Erkaev was at the Space Research Institute of the Austrian Academy of Sciences in Graz. This work is also supported due to the RFBR Grant No. 09-05-91000-ANF-a. Further support is due to the "Austrian Fonds zur Forderung der Wissenschaftlichen Forschung" under Grant No. P20145-N16.
Предметные рубрики: MAXWELLIAN DISTRIBUTION-FUNCTIONS
FREQUENCY ELECTROMAGNETIC-WAVES
SOLAR-WIND
CHARGE FLUCTUATION
2-STREAM INSTABILITIES
ELECTROSTATIC MODES
SPACE PLASMAS
ION PLASMA
TEMPERATURE
PROPAGATION
Ключевые слова (''Своб.индексиров.''): analytical expressions--dispersion relations--distributed streaming--dust acoustic--dust particle--growth rate of instabilities--magnetized electrons--n-waves--potential theory--slow motion--streaming velocity--theoretical approach--two stream instability--whistler waves--dust--magnetic field effects--plasma waves--stability--acoustic wave propagation
Аннотация: This study presents a theoretical approach to analyze the influence of kappa distributed streaming ions and magnetized electrons on the plasma wave propagation in the presence of dust by employing two-potential theory. In particular, analytical expressions under certain conditions are derived for various modes of propagation comprising of kinetic Alfven wave streaming instability, two stream instability, and dust acoustic and whistler waves. A dispersion relation for kinetic Alfven-like streaming instability has been derived. The effects of dust particles and Lorentzian index on the growth rates and the threshold streaming velocity for the excitation of the instability are examined. The streaming velocity is observed to be destabilizing for slow motion and stabilizing for fast streaming motions. It is also observed that the presence of magnetic field and superthermal particles hinders the growth rate of instability. Possible applications to various space and astrophysical situations are discussed. (C) 2010 American Institute of Physics. [doi:10.1063/1.3491336]
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Varnakov S. N., Komogortsev S. V., Ovchinnikov S. G., Bartolome J., Sese J.
Заглавие : Magnetic properties and nonmagnetic phases formation in (Fe/Si)(n) films
Коллективы :
Разночтения заглавия :авие SCOPUS: Magnetic properties and nonmagnetic phases formation in (Fe/Si) n films
Место публикации : J. Appl. Phys.: AMER INST PHYSICS, 2008. - Vol. 104, Is. 9. - Ст.94703. - ISSN 0021-8979, DOI 10.1063/1.3005973
Примечания : Cited References: 23. - This work was supported by the Russian Academy of Science program "Spintronics," the complex integration project of the Siberian Branch of the Russian Academy of Science. 3.5, the Russian Foundation for Basic Research (Grant No. 07-03-00320), the "Ramon y Cajal" program, and Project No. MAT 2005/01272 of the Spanish Ministry of Education and Science.
Предметные рубрики: FE/SI/FE TRILAYER FILMS
GIANT MAGNETORESISTANCE
ULTRAHIGH-VACUUM
SUPERLATTICES
MULTILAYERS
EXCHANGE
Ключевые слова (''Своб.индексиров.''): activation energy--integral equations--magnetic properties--magnetization--magnets--multilayers--rate constants--silicon--thermal evaporation--vacuum--vacuum evaporation--fe layers--high temperatures--interface layers--irreversible behaviors--kinetic equations--n films--nonmagnetic--nonmagnetic phases--prefactor--quantitative analysis--rate equations--synthetic procedures--temperature dependences--ultrahigh-vacuum systems--phase interfaces
Аннотация: The magnetization of Fe/Si multilayers, grown by thermal evaporation in an ultrahigh vacuum system, was investigated at high temperatures. Magnetization and its temperature dependence up to a high temperature of 800 K depend on individual Fe layer thickness d(Fe). This dependence is the result of the formation of an Fe-Si interface layer (nonmagnetic phase) during the synthetic procedure. The fraction of this Fe-Si nonmagnetic phase is estimated versus dFe. At temperatures higher than 400 K an irreversible decrease in the magnetization occurs. A quantitative analysis of this irreversible behavior is proposed in terms of an exponential diffusion-like kinetic equation for the reaction that produces the Fe-Si nonmagnetic phase. The coefficients of the rate equation are the activation energy E(a) and the prefactor D(0), which have been determined for different d(Fe). (C) 2008 American Institute of Physics. [DOI: 10.1063/1.3005973]
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shapiro V. E.
Заглавие : Kinetic method for waves in random-media
Место публикации : Physica A. - 1993. - Vol. 192, Is. 3. - P.323-341. - ISSN 0378-4371, DOI 10.1016/0378-4371(93)90042-3
Примечания : Cited References: 26
Предметные рубрики: EQUATIONS
Аннотация: New tools of statistical analysis for systems obeying differential equations in partial (and ordinary) derivatives with randomly alternating parameters of Markovian type and edge boundary conditions are presented. While the conventional master equation methods are valid only for the stochastic equations with given initial conditions, the method presented is more general and incorporates no embedding to an initial value problem. We develop a simple formalism by introduction of special double-sided conditional averages of dynamic variables. Its main advantage is that the averaging procedure for linear systems with multiplicative random influence is linear, yielding the possibility to obtain exact analytical solutions. The method is applied to a typical model of the theory of wave propagation in random media and exact results of its analysis are presented.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Maltsev V. K., Fish G. I., Tsifrinovich V. I.
Заглавие : NMR during kinetic transitions from amorphous to crystalline state in cop
Место публикации : Fiz. Tverd. Tela. - 1981. - Vol. 23, Is. 4. - P.1148-1150. - ISSN 0367-3294
Примечания : Cited References: 6
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Fedorov A. S., Kuzubov A. A., Visotin M. A., Tomilin F. N.
Заглавие : New method for calculations of nanostructure kinetic stability at high temperature
Коллективы : Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium, Институт физики им. Л.В. Киренского Сибирского отделения РАН , Russian Foundation for Basic Research [N15-02-06869A]; President of Russia Scientific School Program [NSh 7559.2016.2]
Место публикации : J. Magn. Magn. Mater.: Elsevier Science, 2017. - Vol. 440: EURO-Asian Symposium on Trends in Magnetism (EASTMAG) (AUG 15-19, 2016, Siberian Fed Univ, Krasnoyarsk, RUSSIA). - P.167-170. - ISSN 0304-8853, DOI 10.1016/j.jmmm.2016.12.131. - ISSN 1873-4766(eISSN)
Примечания : Cited References:8. - The work was supported by the Russian Foundation for Basic Research Grant N15-02-06869A and by President of Russia Scientific School Program NSh 7559.2016.2. The authors would like to thank Joint Supercomputer Center of RAS, Moscow, for the access to the MVS 100K cluster and Institute of Computational Modelling of SB RAS, Krasnoyarsk, for providing the computational resources.
Предметные рубрики: AUGMENTED-WAVE METHOD
Ключевые слова (''Своб.индексиров.''): kinetic stability--nanostructures--graphene nanoribbons
Аннотация: A new universal method is developed for determination of nanostructure kinetic stability (KS) at high temperatures, when nanostructures can be destroyed by chemical bonds breaking due to atom thermal vibrations. The method is based on calculation of probability for any bond in the structure to stretch more than a limit value L-max, when the bond breaks. Assuming the number of vibrations is very large and all of them are independent, using the central limit theorem, an expression for the probability of a given bond elongation up to L-max is derived in order to determine the KS. It is shown that this expression leads to the effective Arrhenius formula, but unlike the standard transition state theory it allows one to find the contributions of different vibrations to a chemical bond cleavage. To determine the KS, only calculation of frequencies and eigenvectors of vibrational modes in the groundstate of the nanostructure is needed, while the transition states need not be found. The suggested method was tested on calculating KS of bonds in some alkanes, octene isomers and narrow graphene nanoribbons of different types and widths at the temperature T=1200 K. The probability of breaking of the C-C bond in the center of these hydrocarbons is found to be significantly higher than at the ends of the molecules. It is also shown that the KS of the octene isomers decreases when the double C=C bond is moved to the end of the molecule, which agrees well with the experimental data. The KS of the narrowest graphene nanoribbons of different types varies by 1-2 orders of magnitude depending on the width and structure, while all of them are by several orders of magnitude less stable at high temperature than the hydrocarbons and benzene.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Romanova O. B., Aplesnin S. S., Khar’kov A. M., Kretinin V. V., Zhivul’ko A. M.
Заглавие : Kinetic properties of the Mn1 – xGdxSe solid solutions
Место публикации : Phys. Solid State. - 2018. - Vol. 60, Is. 9. - P.1691-1697. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783418090263
Примечания : Cited References: 18. - This study was supported by the Russian Foundation for Basic Research, project no. 18-52-00009 Bel_a and the state task no. 3.5743.2017/6.7.
Аннотация: The results of kinetic study of the Mn1 – xGdxSe chalcogenide solid solutions with different substitute concentrations (0 ≤ x ≤ 0.15) in the temperature range of 80–400 K are reported. The difference between the Hall constant and thermopower signs has been found. The electron-type conductivity determined from the Hall constant and hysteresis of the I–V characteristics have been explained by the existence of nanoareas with local electric polarizations. The sharp extrema observed in the temperature dependence of thermopower are explained by splitting of a narrow 4f subband by the crystal field.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Val'kov V. V., Aksenov S. V.
Заглавие : Nonequilibrium Green’s functions in the atomic representation and the problem of quantum transport of electrons through systems with internal degrees of freedom
Место публикации : Theor. Math. Phys. - 2018. - Vol. 194, Is. 2. - P.236-251. - ISSN 00405779 (ISSN), DOI 10.1134/S0040577918020046
Примечания : Cited References: 14. - This research was supported by the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund (Grant Nos. 16-02-00073, 16-42-243056, 16-42-242036, and 17-42-240441) and in part (S. V. A.) by the Program for Governmental Support for Young Scientists and Candidates of Science (Grant No. MK-1398.2017.2).
Ключевые слова (''Своб.индексиров.''): nonequilibrium green’s functions--keldysh contour--atomic representation--kinetic equation--inelastic scattering
Аннотация: We develop the theory of quantum transport of electrons through systems with strong correlations between fermionic and internal spin degrees of freedom. The atomic representation for the Hamiltonian of a device and nonequilibrium Green’s functions constructed using the Hubbard operators allow overcoming difficulties in the perturbation theory encountered in the traditional approach because of a larger number of bare scattering amplitudes. Representing the matrix elements of effective interactions as a superposition of terms each of which is split in matrix indices, we obtain a simple method for solving systems of very many equations for nonequilibrium Green’s functions in the atomic representation. As a result, we obtain an expression describing the electron currents in a device one of whose sites is in tunnel coupling with the left contact and the other, with the right contact. We derive closed kinetic equations for the occupation numbers under conditions where the electron flow leads to significant renormalization of them.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Tomilin F. N., Fedorov A. S., Artyushenko P. V., Ovchinnikov S. G., Ovchinnikova T. M., Tsikalova P. E., Soukhovolsky V. G.
Заглавие : Estimation of the thermal and photochemical stabilities of pheromones
Место публикации : J. Mol. Model. - 2018. - Vol. 24, Is. 11. - Ст.323. - ISSN 16102940 (ISSN), DOI 10.1007/s00894-018-3859-5
Примечания : Cited References: 35. - This study was supported by the Russian Foundation for Basic Research, Government of the Krasnoyarsk Territory, and the Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project no. 16-44-243019 and the Russian Foundation for Basic Research, project no. 15-02-06869 and no. 16-04-00132.
Ключевые слова (''Своб.индексиров.''): kinetic stability--atomic structure--density functional theory--excited states--terpenes
Аннотация: The correlation between the kinetic stability of molecules against temperature and variations in their geometric structure under optical excitation is investigated by the example of different organic pheromone molecules sensitive to temperature or ultraviolet radiation using the density functional theory. The kinetic stability is determined by the previously developed method based on the calculation of the probability of extension of any structural bond by a value exceeding the limit value Lмах corresponding to the breaking of the bond under temperature excitation. The kinetic stability calculation only requires the eigenfrequencies and vibrational mode vectors in the molecule ground state to be calculated, without determining the transition states. The weakest bonds in molecules determined by the kinetic stability method are compared with the bond length variations in molecules in the excited state upon absorption of light by a molecule. Good agreement between the results obtained is demonstrated and the difference between them is discussed. The universality of formulations within both approaches used to estimate the stability of different pheromone molecules containing strained cycles and conjugated, double, and single bonds allows these approaches to be applied for studying other molecules.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Romanova O. B., Aplesnin S. S., Sitnikov M. N., Kharkov A. M., Masyugin A. N., Yanushkevich K. I.
Заглавие : Polymorphism in MnSe1-xTex thin-films
Коллективы : Russian Foundation for Basic Research [18-52-00009 bel_a, 18-32-00079 mol_a, 18-42-240001 r_a, 3.5743.2017/6.7]
Место публикации : Solid State Commun. - 2019. - Vol. 287. - P.72-76. - ISSN 0038-1098, DOI 10.1016/j.ssc.2018.10.009. - ISSN 1879-2766(eISSN)
Примечания : Cited References: 27. - This study was supported by the Russian Foundation for Basic Research, project no. 18-52-00009 bel_a, No 18-32-00079 mol_a, No 18-42-240001 r_a; the state order No 3.5743.2017/6.7.
Предметные рубрики: HEXAGONAL MNTE
MNSE
TEMPERATURE
Аннотация: To establish the polymorphic transition in polycrystalline MnSe1–ХTeХ (0.1 ≤ X ≤ 0.2) films, their structural, magnetic, kinetic, and optical properties have been investigated in the temperature range of 77–800 K and magnetic fields of up to 12 kOe. Using X-ray diffraction analysis, the coexistence of two crystalline phases in the films has been found. The magnetic moment of the films has been shown to increase with the increasing substitute concentration and decreasing temperature. The impedance maxima and thermopower sign change in the region of the polymorphic and magnetic transitions have been observed. The variation in the structural characteristics has been established using the infrared spectroscopy and thermal expansion coefficient data. The experimental results are explained within a model of domains and domain walls.С целью обнаружения полиморфного перехода в поликристаллических пленках системы MnSe1-ХTeХ с (0.1 ≤ X ≤ 0.2) проведены комплексные исследования структурных, магнитных, кинетических и оптических свойств в интервале температур 77-800К в магнитных полях до 12 кЭ. Найдено сосуществование двух кристаллических фаз методом рентгеноструктурного анализа. Обнаружено увеличение магнитного момента с ростом концентрации и с понижением температуры. Найдены максимумы импеданса, сопротивления и изменение знака термоЭДС в области полиморфного и магнитного переходов. Установлено изменение структурных характеристик из ИК спектроcкопии, коэффициента температурного линейного расширения пленок. Экспериментальные данные объясняются в модели существования доменов и доменных границ.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Novikov P. V., Osipova I. V., Churilov G. N., Dudnik A. I.
Заглавие : Simulation of fullerene formation in a carbon-helium plasma
Место публикации : Fuller. Nanotub. Carbon Nanostruct. - 2021. - Vol. 29, Is. 5. - P.337-342. - ISSN 1536383X (ISSN), DOI 10.1080/1536383X.2020.1842738
Примечания : Cited References: 22
Аннотация: A kinetic model of fullerene formation in the carbon-helium plasma of an arc discharge was proposed. In the model, in addition to the coagulation of carbon clusters, the cluster isomerization and their cooling with a buffer gas were taken into account. The simulation results of the fullerene formation are in qualitatively agreement with the experimental data, i.e., the fraction of higher fullerenes increases at high pressures in the fullerene mixture.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zharkov S. M., Altunin R. R., Yumashev V. V., Moiseenko E. T., Belousov O. V., Solovyov L. A., Volochaev M. N., Zeer G. M.
Заглавие : Kinetic study of a solid-state reaction in Ag/Al multilayer thin films by in situ electron diffraction and simultaneous thermal analysis
Коллективы : Russian Science Foundation, RussiaRussian Science Foundation (RSF) [181300 080]
Место публикации : J. Alloys Compd. - 2021. - Vol. 871. - Ст.159474. - ISSN 0925-8388, DOI 10.1016/j.jallcom.2021.159474. - ISSN 1873-4669(eISSN)
Примечания : Cited References: 47. - This work was supported by the Russian Science Foundation, Russia under grant #181300 080
Предметные рубрики: STRUCTURAL PHASE-TRANSFORMATIONS
COMMITTEE RECOMMENDATIONS
ICTAC KINETICS
Аннотация: A solid-state reaction process in Ag/Al multilayer thin films has been investigated by the methods of in situ electron diffraction, simultaneous thermal analysis, transmission electron microscopy and X-ray diffraction with the aim of studying the phase formation kinetics of intermetallic compounds. The sequence of the phase transformations in the solid-state reaction has been established: Ag+Al→(Ag)+(Al)→(Ag)+δ-Ag2Al→μ-Ag3Al. The process of the solid-state interaction has been shown to consist of two steps; each of them is described by a kinetic model of the nth order reactions with autocatalysis. The kinetic parameters of the autocatalytic process of the phase formation for δ-Ag2Al and µ-Ag3Al, have been determined, in particular, their apparent activation energy: 126 kJ/mol and 106 kJ/mol, respectively.
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13.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Романова, Оксана Борисовна, Аплеснин, Сергей Степанович, Удод, Любовь Викторовна
Заглавие : Кинетические эффекты в сульфидах марганца замещенных тулием и иттербием
Коллективы : "Новое в магнетизме и магнитных материалах", международная конференция, Научный совет по физике конденсированных сред РАН, МИРЭА - Российский технологический университет, Московский государственный университет им. М.В. Ломоносова, Магнитное общество России
Место публикации : Новое в магнетизме и магнитных материалах: сборник трудов XXIV международной конференции/ прогр. ком.: Р. С. Исхаков, С. Г. Овчинников. - 2021. - Секция 7: Кинетические эффекты в магнетиках. - С. 17-20
Примечания : Библиогр.: 9. - Исследование выполнено при финансовой поддержке РФФИ и БРФФИ в рамках научного проекта No 20-52-00005
Аннотация: Данная работа посвящена изучению кинетических эффектов в сульфидах марганца допированных элементами с переменной валентностью (Yb и Tm с Х≤0.05) измеренных в диапазоне температур (77-400 K) и магнитных полей до 12 кЭ. Из ВАХ определены механизмы проводимости, для системы Yb0.05Mn0.99S преобладает Пула– Френкеля, а для Tm0.01Mn0.99S описывается законом Ома. Обнаружен эффект магнитосопротивления в этих системах. Наблюдаются аномалии на температурной зависимости термоЭДС.This work is to the study of kinetic effects in manganese sulfides doped with elements with variable valence (Yb and Tm with X≤0.05) measured in the temperature range (77-400 K) and magnetic fields up to 12 kOe. The conduction mechanisms are determined by I – V characteristics: for the Yb0.05Mn0.99S is Poole – Frenkel, and for Tm0.01Mn0.99S it is described by Ohm's law. The effect of magnetoresistance is found in these systems. Anomalies are observed in the temperature dependence of the thermoEMF.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kononova O.N., Melnikov A.M., Borisova T.V., Krylov A. S.
Заглавие : Simultaneous ion exchange recovery of platinum and rhodium from chloride solutions
Место публикации : Hydrometallurgy. - 2011. - Vol. 105, Is. 3-4. - P.341-349. - JAN. - ISSN 0304-386X, DOI 10.1016/j.hydromet.2010.11.009
Примечания : Cited Reference Count: 46
Предметные рубрики: GROUP-METALS PGM
SEPARATION
CATALYST
ANION
ADSORPTION
EXTRACTION
CHEMISTRY
RESIN
Ключевые слова (''Своб.индексиров.''): platinum--rhodium--sorption--anion exchangers--chloride solutions--anion exchangers--chloride solutions--platinum--rhodium--sorption--ammonium thiocyanate--anion exchangers--basic parameters--chemical structure--chloride solutions--diffusion coefficients--distribution coefficient--exchange capacities--kinetic properties--noble metals--purolite--rhodium chloride--separation factors--sorption ability--work focus--ammonium compounds--chlorine compounds--desorption--hydrochloric acid--ion exchange--ion exchange resins--ions--platinum--platinum compounds--potassium hydroxide--precious metals--recovery--rhodium--sulfuric acid--thioureas--urea--rhodium compounds
Аннотация: This work focuses on the sorption recovery of platinum (II, IV) and rhodium (III) simultaneously present in chloride solutions, freshly prepared and stored over 3 months, on commercial anion exchangers with different physical and chemical structure. The sorption was carried out from solutions with 0.001-4.0 mol/L HCl. The initial platinum and rhodium concentrations in contacting solutions were 0.25-2.5 mmol/L Sorption and kinetic properties of the chosen anion exchangers were investigated and the basic parameters of exchange capacity, recovery, distribution coefficients, separation factors, process rate, diffusion coefficients and half-exchange times were calculated. It is shown that anion exchangers investigated possess high sorption ability to platinum and rhodium chloride complexes, which does not deteriorate in case of stored solutions. Desorption of platinum and rhodium from the resins investigated was carried out with hydrochloric acid (2 mol/L), thiourea (1 mol/L) in sulfuric acid (2 mol/L) or in potassium hydroxide (2 mol/L) as well as by ammonium thiocyanate (2 mol/L). It was shown that complete separation of platinum and rhodium can be carried out with 2 mol/L HCl on anion exchanger Purolite S 985, whereas 2 mol/L NH(4)SCN as an elution agent leads to complete separation of noble metals on anion exchangers Purolite S 985, Purolite A 500 and AM-2B. (C) 2010 Elsevier B.V. All rights reserved.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Romanova O. B., Sitnikov M. N., Loginov Yu. Yu., Abdelbaki H.
Заглавие : Concentration dependences of the structural, magnetic and kinetic properties of manganese chalcogenides doped with tellurium
Коллективы : Reshetnev Readings 2019
Место публикации : IOP Conf. Ser.: Mater. Sci. Eng. - 2022. - Vol. 1230. - Ст.012016. - ISSN 1757-8981 (ISSN), DOI 10.1088/1757-899X/1230/1/012016. - ISSN 1757-899X (eISSN)
Примечания : Cited References: 26. - The reported study was funded by RFBR according to the research project No 20-52-00005 Bel_a
Аннотация: The effect of anionic substitution on the structural, magnetic, and kinetic properties of chalcogenides of the MnSe1-XTeX system in the temperature range of 77-400K in magnetic fields up to 12 kOe was studied. With an increase in the substitution concentration, changes in the structural and magnetic characteristics, which correlate with changes in the electronic structure, were found. The type and mobility of the main current carriers were determined from the Hall effect measurements.
https://doi.org/10.1088/1757-899X/1230/1/012016
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Azarapin N. O., Khritokhin N. A., Atuchin V. V., Gubin A. A., Molokeev M. S., Mukherjee S., Andreev O. V.
Заглавие : Kinetics and mechanism of BaLaCuS3 oxidation
Место публикации : Crystals. - 2023. - Vol. 13, Is. 6. - Ст.903. - ISSN 20734352 (eISSN), DOI 10.3390/cryst13060903
Примечания : Cited References: 65. - The work was partially carried out using the resources of the Research Resource Center “Natural Resources Management and Physico-Chemical Research” (Tyumen University) with financial support from the Ministry of Science and Higher Education of the Russian Federation (contract No. 05.594.21.0019., Unique identification number RFMEFI59420X0019). M.S. Molokeev was supported by the Tyumen Oblast Government, as part of the West-Siberian Interregional Science and Education Center’s project No. 89-DON (3)The authors would like to thank the staff of the Engineering Center of the Tyumen State University (special Alexej V. Matigorov) for their help in carrying out physical and chemical tests
Аннотация: The oxidation reactions of BaLaCuS3 in the artificial air atmosphere were studied at different heating rates in the temperature range of 50–1200 °C. The oxidation stages were determined by DSC-TG, XRD and IR–vis methods. The kinetic characteristics of the proceeding reactions were obtained with the use of the Kissinger model in a linearized form. Compound BaLaCuS3 was stable in the air up to 280 °C. Upon further heating up to 1200 °C, this complex sulfide underwent three main oxidation stages. The first stage is the formation of BaSO4 and CuLaS2. The second stage is the oxidation of CuLaS2 to La2O2SO4 and copper oxides. The third stage is the destruction of La2O2SO4. The final result of the high-temperature treatment in the artificial air atmosphere was a mixture of barium sulfate, copper (II) oxide and La2CuO4. The mechanism and stages of BaLaCuS3 oxidation and further interactions of the components were discussed.
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17.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Romanova O. B., Aplesnin S. S., Udod L. V., Galyas A. I., Zhivulko A. M., Yanushkevich K. I.
Заглавие : Kinetic effects in thulium manganese selenides
Коллективы : "Actual problems of solid state physics", International scientific conference, "Актуальные проблемы физики твердого тела", международная научная конференция, Научно-практический центр по материаловедению НАН Беларуси
Место публикации : X International scientific conference “Actual problems of solid state physics": Book of abstracts/ int. sci. com. S. S. Aplesnin [et al]. - Minsk, 2023. - Sect.: Functional materials and applications. - P.154. - ISBN 978-985-7299-65-2
Примечания : Cited References: 1
Материалы конференции
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Korovushkin M. M.
Заглавие : Electrical resistivity and the Hall effect in the doped Mott-Hubbard material with strong spin-charge coupling
Колич.характеристики :14 с
Место публикации : Phys. Scr. - 2023. - Vol. 98, Is. 12. - Ст.125922. - ISSN 00318949 (ISSN), DOI 10.1088/1402-4896/ad05ed. - ISSN 14024896 (eISSN)
Примечания : Cited References: 96. - Author is grateful to V V Val’kov, A D Fedoseev, D M Dzebisashvili and M S Shustin for fruitful discussions and permanent interest in this work. Author thanks V A Mitskan and A O Zlotnikov for technical support
Аннотация: The kinetic characteristics of the doped Mott-Hubbard material are considered within the realistic spin-fermion model which takes into account the strong spin-charge coupling. The kinetic equation constructed on the basis of the mechanism of carrier scattering on the spin fluctuations is solved using the multi-moment method, which allows one to analyze the temperature behavior of nonequilibrium distribution function in the problems of electrical resistivity ρ and the Hall coefficient RH. The calculated dependences ρ(T) and RH(T) for the underdoped and optimally doped regimes demonstrate good qualitative agreement with the experimental data. In particular, the Hall coefficient calculated for the underdoped regime reproduces the experimentally observed sharp drop and even a change in sign at low temperatures.
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