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1.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Кузовникова, Людмила Александровна, Iskhakov R. S., Denisova E. A.
Заглавие
: Nanostructured cobalt-based materials produced with using of
mechanochemical
technology
Коллективы
: Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism
Место публикации
: V Euro-Asian simposium "Trend in MAGnetism": Nanomagnetism: abstracts. - Vladivostok: FEFU, 2013. - С. 190. - ISBN 978-5-7444-3124-2
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2.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Denisova E. A., Kuzovnikova L. A., Iskhakov R. S., Bukaemskiy A. A., Eremin E. V., Nemtsev I. V.
Заглавие
: Effect of ball milling and dynamic compaction on magnetic properties of Al2O3/Co(P) composite particles
Коллективы
: Russian Foundation of Basic Research [13-03-00476-a]
Место публикации
: J. Appl. Phys.: American Institute of Physics, 2014. - Vol. 115, Is. 17. - Ст.17B530. - ISSN 0021-8979,
DOI
10.1063/1.4869158. - ISSN 1089-7550
Примечания
: Cited References: 18. - This work was partially supported by Russian Foundation of Basic Research 13-03-00476-a.
Предметные рубрики:
MECHANOCHEMICAL
SYNTHESIS
MECHANICAL-PROPERTIES
NANOCOMPOSITE POWDER
ALLOYS
NANOCRYSTALLINE
MICROSTRUCTURE
FERROMAGNETS
Аннотация:
The evolution of the magnetic properties of composite Al2O3/Co(P) particles during ball milling and dynamic compaction is investigated. To prepare starting composite particles, the Al2O3 granules were coated with a Co95P5 shell by electroless plating. The magnetic and structural properties of the composite particles are characterized by scanning electron microscopy, X-ray diffraction, and the use of the Physical Property Measurement System. The use of composite core-shell particles as starting powder for mechanoactivation allows to decrease treatment duration to 1 h and to produce a more homogeneous bulk sample than in the case of the mixture of Co and Al2O3 powders. The magnetic properties of the milled composite particles are correlated with changes in the microstructure. Reduction in grain size of Co during milling leads to an increase of the volume fraction of superparamagnetic particles and to a decrease of the saturation magnetization. The local magnetic anisotropy field depends on the amount of hcp-Co phase in sample. The anisotropy field value decreases from 8.4 kOe to 3.8 kOe with an increase in milling duration up to 75 min. The regimes of dynamic compaction were selected so that the magnetic characteristics-saturation magnetization and coercive field-remained unchanged. (C) 2014 AIP Publishing LLC.
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3.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Лесков М. Б., Немцев, Иван Васильевич, Абылкалыкова Р. Б., Квеглис, Людмила Иосифовна
Заглавие
: Структурообразование в системе вольфрам–медь при сварке взрывом
Коллективы
: "Решетневские чтения", международная научно-практическая конференция
Место публикации
: Решетневские чтения: материалы XIX Междунар. науч. конф. : в 2-х ч. - Красноярск, 2015. - Ч. 1. - С. 531-534
Примечания
: Библиогр.: 9
Ключевые слова
(''Своб.индексиров.''): структурообразование--твердофазная реакция--механохимическая реакция--сварка взрывом--structure formation--solid-phase reaction--
mechanochemical
reaction--explosion welding
Аннотация:
Исследованы процессы структурообразования на границе раздела практически нерастворимых друг в друге компонентов вольфрама и меди при сварке взрывом.The research investigates the processes of structure formation at the interface is copper and tungsten components practically insoluble in each other during welding explosion.
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4.
Вид документа
: Статья из сборника (выпуск монографической серии)
Шифр издания
:
Автор(ы)
: Zhuravlev V., Nevmyvaka A., Itin V., Velikanov D. A.
Заглавие
:
Mechanochemical
synthesis of hexagonal ferrites BaFe12O19
Коллективы
: International Conference on Radiation-Thermal Effects and Processes in Inorganic Materials
Место публикации
: Key Eng. Mater. - 2018. - Vol. 781 KEM. - P.119-124. - ,
DOI
10.4028/www.scientific.net/KEM.781.119
Примечания
: Cited References: 15
Ключевые слова
(''Своб.индексиров.''): ferromagnetic resonance--magnetization curve--magnetocrystalline anisotropy--
mechanochemical
synthesis--nanostructure hexaferrites
Аннотация:
The phase composition, structural parameters, and basic magnetic characteristics of BaFe12O19 hexaferrites prepared by the
mechanochemical
synthesis with subsequent annealing at a temperature of 1000°С and 1100°С for 1 h are investigated. The influence of the annealing temperature on the properties of synthesized materials is analyzed. Values of the saturation magnetization and the anisotropy field are determined. It is established that annealing temperature in the interval 1000 - 1100 °C does not significantly affect on the phase composition and the size of nanoparticles. The value of the anisotropy field increases substantially with increasing temperature.
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5.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Kuzovnikova L. A., Denisova E. A., Komogortsev S. V., Iskhakov R. S., Nemtsev I. V., Shepeta N. A.
Заглавие
: Effect of intensive plastic deformation on structure and magnetic properties of Al2O3/Co(P) nanocomposite particles
Коллективы
: Fundamental Bases of
Mechanochemical
Technologies, International Conference, "Фундаментальные основы механохимических технологий", международная конференция, Институт химии твердого тела и механохимии Сибирского отделения РАН, Новосибирский государственный университет
Место публикации
: V International conference "Fundamental bases of
mechanochemical
technologies". FBMT- 2018: book of abstracts : [25-28 June 2018, Novosibirsk, Russia]. - 2018. - P.141. - ISBN 978-5-4437-0794-5
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6.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Pavlov E. A., Chuprov I. V., Nikulin M. V., Mal'tsev E. V., Pshenichnaya A. A., Grigoreva T. F., Pastukhov E. A., Skuratov A. P., Lyakhov N. Z.
Заглавие
:
Mechanochemical
synthesis of intermetallic compounds in the gallium-iridium system
Место публикации
: Russ. Metall. - 2018. - Is. 8. - P.728-732. - ISSN 0036-0295,
DOI
10.1134/S0036029518080141. - ISSN 1555-6255(eISSN)
Примечания
: Cited References: 18. - This work was performed in terms of project no. 1622/17 of the Krasnoyarsk Plant of Nonferrous Metals and the Institute of Solid State Chemistry and Mechanochemistry.
Предметные рубрики:
ALUMINUM
Ключевые слова
(''Своб.индексиров.''):
mechanochemical
synthesis--intermetallic compounds--gallium--iridium--complex compounds of iridium
Аннотация:
The interaction between a solid inert metal (Ir) and an active liquid metal (Ga) during mechanical activation in a high-energy planetary mill is studied by X-ray diffraction and scanning electron microscopy with EDS-apparatus for high-resolution energy dispersive X-ray microanalysis. The influence of mechanical activation conditions on the formation of GaxIry intermetallic compounds and GaxIry/Ir composites and on their solubility in various acids is investigated. Being a surfactant for iridium, gallium propagates along the grain boundaries of polycrystalline iridium particles during mechanical activaiton and, hence, sharply decreases their strength. As a result of strong mechanical deformation during activation, the contact surface area between the solid and liquid metals, where the intermetallic compounds form intensely, increases sharply. As a result of treatment of the products of mechanical activaiton by a mixture of concentrated hydrochloric and nitric acids, iridium (30%) from passes into an acid solution and forms HxIrCly complex compounds, which can interact with bases to form soluble complex salts.
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7.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Zhou, Guojun, Guo, Shaoqiang, Zhao, Jing, Molokeev M. S., Liu, Quanlin, Zhang, Junying, Xia, Zhiguo
Заглавие
: Unraveling the
mechanochemical
synthesis and luminescence in MnII-based two-dimensional hybrid perovskite (C4H9NH3)2PbCl4
Место публикации
: Sci. China Mater. - 2019. - Vol. 62, Is. 7. - P.1013-1022. - ISSN 2095-8226,
DOI
10.1007/s40843-018-9404-4. - ISSN 2199-4501(eISSN)
Примечания
: Cited References: 40. - The present work was supported by the National Natural Science Foundation of China (91622125, 51722202 and 51572023) and the Natural Science Foundation of Beijing (2172036), and Molokeev M acknowledges the support of the Russian Foundation for Basic Research (17-52-53031). The DFT calculation was carried out at the National Supercomputer Center in Tianjin, and the calculations were performed on TianHe-1(A).
Предметные рубрики:
DOPANT ENERGY-TRANSFER
EMISSION
EXCITON
MODEL
Аннотация:
The
mechanochemical
route is a facile and fast way and has received much attention for developing versatile advanced functional materials. Herein, we reported a
mechanochemical
synthesis for incorporating divalent manganese ions (MnII) into a two-dimensional (2D) hybrid perovskite (C4H9NH3)2PbCl4. The mild external stimuli originating from the grinding at room temperature enabled the formation of MnII-doped 2D hybrid perovskites, and rapidly changed the luminescence characteristics. The photoluminescence analyses show that the violet and orange emissions are attributed to (C4H9NH3)2Pb1–xMnxCl4 band-edge emission and the T1→6A1 transition of Mn2+ resulting from an efficient energy transfer process, respectively. Site preference and distribution of the doped Mn2+ cations on the locations of Pb2+ were analyzed. The formation energy calculated by the density functional theory (DFT) indicates that the Mn2+ ions can rapidly enter the crystal lattice due to the unique 2D crystal structure of the hybrid perovskite. Such a case of
mechanochemical
synthesis for the 2D hybrid perovskite motivates many novel emerging materials and the related applications.
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8.
Вид документа
: Статья из сборника (выпуск продолж. издания)
Шифр издания
:
Автор(ы)
: Kuzovnikova, Ludmila, Komogortsev S. V., Denisova E. A., Iskhakov R. S., Nemtsev I. V., Volochaev M. N., Shepeta, Natalia
Заглавие
: Structure and magnetism in ball-milled core-shell Al2O3@Co particles
Коллективы
: International Conference on Fundamental Bases of
Mechanochemical
, Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund [18-42-240006]
Место публикации
: Mater. Today: Proc. - 2019. - Vol. 12: 5th International Conference on Fundamental Bases of
Mechanochemical
(JUN 25-28, 2018, Russian Acad Sci, Siberian Branch, Inst Solid State Chem & Mechanochemistry, Novosibirsk, Russia), Pt. 1. - P.159-162. - ,
DOI
10.1016/j.matpr.2019.03.087
Примечания
: Cited References: 19. - This work was supported by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project No 18-42-240006.
Аннотация:
The core-shell Al2O3@Co particles were prepared by the ball-milling of the composite Al2O3-Co particles synthesized by electroless reduction. During the ball-milling process, both, the core-shell particle size and the ratio of hcp/fcc phases changed. To perform a phase analysis of the cobalt shell we used an approach based on the magnetic measurements. The use of Al2O3-Co composite particles as the precursors for the ball milling significantly shortens the time needed for a change in the phase composition of cobalt.
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9.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Golovnev N. N., Aleksandrovsky A. S., Gerasimova M. A., Tomilin F. N., Mironov V. A., Demina A. V., Xia Z., Molokeev M. S.
Заглавие
: Luminescent zero-dimensional hybrid lead thiohalide nanostructures for high quantum yield and broadband excitation
Место публикации
: ACS Appl. Nano Mat. - 2021. - Vol. 4, Is. 4. - P.3654-3663. - ISSN 25740970 (ISSN),
DOI
10.1021/acsanm.1c00162
Примечания
: Cited References: 55. - This work is supported by the RFBR according to the research project No. 19-52-80003. This work is also supported by the National Natural Science Foundation of China (51961145101). V.M. thanks Russian Foundation for Basic Research (project number 19-03-00043) for funding. The use of equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” is acknowledged. The authors thank JSCC RAS for providing computational resources
Аннотация:
Luminescent trans-[Pb(DMTU-S)4Cl2] (DMTU: N,N′-dimethylthiourea) was designed and prepared via either
mechanochemical
or solvothermal methods, and the structures of DMTU and trans-[Pb(DMTU-S)4Cl2] have been resolved using X-ray single-crystal diffraction. Upon excitation over broadband covering the range from 450 to 250 nm, trans-[Pb(DMTU-S)4Cl2] shows yellow-green emission peaking at 549 nm with a spectral width of 110 nm, which is assigned to the triplet–singlet transition of Pb2+ ions within distorted heterogeneous S4Cl2 octahedra. The broadband excitation comprised singlet–singlet transitions of Pb2+ ions and energy transfer from orbitals involving those of organic ligands. Simultaneous analysis of the luminescent bandwidth and Stokes shift gives for Pb2+ ions in S4Cl2 octahedra the value of the Huang–Rhys parameter S = 4.25 and the energy of phonon involved in the formation of the luminescence spectrum of the order of 90 meV. Quantum yield as high as 91% is detected for excitation at 365 nm. This high quantum yield indicates the absence of noticeable concentration quenching at an average distance of 9.4 Å between the Pb2+ ions within the structure of trans-[Pb(DMTU)4Cl2]. The weak spin–orbit intersystem crossing is deduced from a high photoluminescence quantum yield (PLQY) value. Time dependent-density functional theory (TD-DFT) calculations of the nanocluster indicate the red shift of absorption bands in Pb(DMTU)4Cl2 with respect to parent DMTU. The high-performance photoluminescence and stability demonstrated promising applications in photonics.
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10.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Orlov Yu. S., Vereshchagin S. N., Novikov, S., V, Burkov A. T., Borus A. A., Sitnikov, M., V, Solovyov L. A., Volochaev M. N., Dudnikov V. A.
Заглавие
: Effect of mechanical activation on the thermoelectric properties of Sr1-xSmxTiO3 ceramics
Коллективы
: Russian Science FoundationRussian Science Foundation (RSF) [19-72-00097]
Место публикации
: Ceram. Int. - 2021. - Vol. 47, Is. 20. - P.28992-28999. - ISSN 0272-8842,
DOI
10.1016/j.ceramint.2021.07.060. - ISSN 1873-3956(eISSN)
Примечания
: Cited References: 31. - This study was supported by the Russian Science Foundation, project no. 19-72-00097
Предметные рубрики:
SRTIO3
LA
MICROSTRUCTURE
CONDUCTIVITY
PERFORMANCE
FIGURE
MERIT
Аннотация:
The Sr1-xSmxTiO3 (х = 0.025, 0.05, 0.075, 0.1, 0.2) strontium titanate solid solutions were prepared from oxides and carbonates using a conventional ceramic technology based on the
mechanochemical
activation. The electrical conductivity and Seebeck coefficient of the synthesized compounds were measured in the temperature range from 300 to 800 K. We found that the properties of the samples significantly depend on the preliminary
mechanochemical
activation. The thermoelectric power factor attains maximum value in the hydrogen reduced samples with concentration of х = 0.05 and 0.075 obtained from nanoparticles: 5.5 μW/(cm · K2) for Sr0.95Sm0.05TiO3 (580 K) and 4.10 μW/(cm · K2) for Sr0.925Sm0.075TiO3 (650 K). An increase in the annealing temperature of mechanically activated samples leads to an even greater increase in electrical conductivity and power factor: 9.2 μW/(cm · K2) for Sr0.925Sm0.075TiO3 (650 K).
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11.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Orlov Yu. S., Vereshchagin S. N., Solovyov L. A., Borus A. A., Volochaev M. N., Nikitin A. V., Bushinsky M. V., Lanovsky R. A., Rymski G. S., Dudnikov V. A.
Заглавие
: Stability and thermoelectric properties of mechano-activated solid solutions of Sr1-xLnxTiO3-δ (Ln = Nd, Gd, Dy)
Место публикации
: J. Taiwan Inst. Chem. Eng. - 2022. - Vol. 138. - Ст.104449. - ISSN 18761070 (ISSN),
DOI
10.1016/j.jtice.2022.104449
Примечания
: Cited References: 39. - This study was supported by the Russian Foundation for Basic Research, project no. 20-52-04008 Bel_mol_a. Thermal analysis was performed within the scope of Budget Project No. 0287-2021-00-13 for the Institute of Chemistry and Chemical Technology SB RAS
Аннотация:
Background: The effect of
mechanochemical
activation on the microstructure, morphology, and thermoelectric parameters of the materials leading to an increase in the power factor (PF) is demonstrated by the example of the Sr1-xLnxTiO3-δ (Ln = Nd, Gd, Dy; x = 0.05, 0.075, 0.1) solid solutions. Methods: The strontium titanate solid solutions have been synthesized using a conventional ceramic technology from particles of different sizes obtained by mechanical activation of annealed ceramics. Findings: It is shown that different sizes of initial particles cause the morphological and microstructural differences and significantly affect the stability and thermoelectric properties of the synthesized samples. It has been established that a decrease in the initial particle size ensures the thermal stability of the samples and leads to an increase in their electrical conductivity and PF at the minor variation in the Seebeck coefficient. The PF of the Sr0.925Nd0.075TiO3 solid solution changes by a factor of 7. It has been found that the mechanically activated samples have the much lower porosity than the nonactivated ones, which noticeably reduces the effective area of their interaction with the environment (oxygen release and absorption); therefore, all the measurement data obtained on the mechanically activated samples upon their heating and cooling are reversible.
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12.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Iskhakov R.S., Kuzovnikova L.A., Denisova E.A., Komogortsev S.V., Bondarenko G.V.
Заглавие
: Structure and magnetic features of Co-Cu alloys synthesized by mechanical alloying from the powder precursors with excess enthalpy
Коллективы
: Fundamental Bases of
Mechanochemical
Technologies, International Conference
Место публикации
: III International conference "Fundamental Bases of
Mechanochemical
Technologies". FBMT-2009. - 2009. - P.135
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