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1.
Bifurcations observed in
the spectra of coupled electron-phonon modes in
multiferroic
PrFe3(BO3)4 subjected to a magnetic field / K. N. Boldyrev [et al.]. - Electronic text data> // ArXiv. - 2016. - Ст. 1609.02125. - Cited References: 19. - This research was supported by the Russian Scientific Foundation under Grant No 14-12-01033, the President of Russian Federation (MK-3521-2015.2, K.N.B.), and the U.S. Department of Energy under Grant No DE-FG02-07ER46382 (experiments at U4-IR beamline NSLS-BNL, T.N.S. and A.A.S.). The National Synchrotron Light Source is operated as a User Facility for he U.S. Department of Energy under Contract No. DE-AC02-98CH10886. Part of this work was supported by EMFL (contract No. 26211). M.N.P. thanks B.Z. Malkin helpful discussions.
Аннотация:
We report on bifurcations effect mediated by the electron-phonon coupling in a concentrated rare-earth-containing antiferromagnet, observed in the spectra of coupled 4f-electron-phonon modes under the influence of an external magnetic field. The effect was observed in the low-temperature far-infrared (terahertz) reflection spectra of a
multiferroic
easy-axis antiferromagnet PrFe3(BO3)4 in magnetic fields Bext||c. Both paramagnetic and magnetically ordered phases (including a spin-flop one) were studied in magnetic fields up to 30 T. We show that the field behavior of the coupled modes can be successfully explained and modeled on the base of the equation derived in the frame of the theory of coupled electron-phonon modes, with the same field-independent electron-phonon interaction constant |W|=14.8cm−1.
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Держатели документа:
Institute of Spectroscopy, Russian Academy of Sciences, 108840 Troitsk, Moscow, Russia
Department of Physics, New Jersey Institute of Technology, 07102 Newark, New Jersey, USA
High Field Magnet Laboratory (HFML-EMFL), Radboud University, 6525 ED Nijmegen, Netherlands
Kirenskiy Institute of Physics, Siberian Branch of RAS, 660036 Krasnoyarsk, Russia
Доп.точки доступа:
Boldyrev, K. N.; Stanislavchuk, T. N.; Sirenko, A. A.; Kamenskyi, D.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Popova, M. N.
}
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2.
Caloric Effects in
Multiferroic
Composites (x)La0.7Pb0.3MnO3 — (1-x)PbTiO3 / I. N. Flerov [et al.]> //
Joint 14th Rus./CIS/Baltic/Japan Symp. on Ferroelectricity (RCBJSF)/ Young sci. school on the spect. studies of critical dynamics at struct. phase trans. : Abstract book / org. comm. A. N. Vtyurin ; progr. comm. I. N. Flerov. - 2018. - P. 11. - Cited References: . - ISBN 978-5-9651-1144-2
Перевод заглавия:
Калорические эффекты в мультиферроидных композитах (x)La0.7Pb0.3MnO3 — (1-x)PbTiO3
Материалы конференции
Доп.точки доступа:
Vtyurin, A. N. \org. comm.\; Втюрин, Александр Николаевич; Flerov, I. N. \progr. comm.\; Флёров, Игорь Николаевич; Flerov, I. N.; Mikhaleva, E. A.; Михалева, Екатерина Андреевна; Kartashev, A. V.; Карташев, Андрей Васильевич; Gorev, M. V.; Горев, Михаил Васильевич; Joint Russia/CIS/Baltic/Japan Symposium on Ferroelectricity(14 ; May 14-18, 2018 ; St. Perersburg); Young scientists school on the spectroscopic(May 14-18, 2018 ; St. Perersburg); Физико-технический институт им. А.Ф. Иоффе РАН; Санкт-Петербургский политехнический университет им. Петра Великого
}
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3.
Change of the
local magnetic properties during f-f transitions in
multiferroic
Nd0.5Gd0.5Fe3(BO3)4 single crystal / A. V. Malakhovskii [et al.]> //
Ultrafast magnetism conf. (UMC 2015) : program. - Nijmegen, 2015
Материалы конференции
Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Gnatchenko, S. L.; Kachur, I. S.; Piryatinskaya, V. G.; Sukhachev, A. L.; Сухачев, Александр Леонидович; Temerov, V. L.; Темеров, Владислав Леонидович; Ultrafast Magnetism Conference(2015 ; okt. ; 19-23 ; Nijmengen, Netherlands)
}
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4.
Colossal magnetodielectric effect
in SmFe3(BO3)(4)
multiferroic
/ A. A. Mukhin [et al.]> // JETP Letters. - 2011. -
Vol. 93
,
Is. 5
. - P. 275-281,
DOI
10.1134/S0021364011050079. - Cited References: 17. - We are grateful to A.K. Zvezdin and A.P. Pyatakov for the discussion of this work and valuable comments. This work was supported by the Russian Foundation for Basic Research, project nos. 10-02-00846 and 09-02-01355. . - ISSN 0021-3640
РУБ
Physics, Multidisciplinary
Рубрики:
FERROELECTRICITY
MAGNETOSTRICTION
GARNETS
Аннотация:
The colossal (more than threefold) decrease in the dielectric constant E in the easy-plane SmFe3(BO3)(4) ferroborate in a magnetic field of similar to 5 kOe applied in the basal ab plane of the crystal has been found. A close relation of this effect to anomalies in the field dependence of the electric polarization has been established. It has been shown that this magnetodielectric effect is due to the contribution to E from the electric susceptibility, which is related to the rotation of spins in the ab plane, arises in the region of the antiferromagnetic ordering T T (N) and electric polarization in the magnetic field has been proposed, taking into account the additional anisotropy in the basal plane induced by the magnetoelastic stresses.
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Держатели документа:
[Mukhin, A. A.
Ivanov, V. Yu.
Kuz'menko, A. M.] Russian Acad Sci, Prokhorov Gen Phys Inst, Moscow 119991, Russia
[Vorob'ev, G. P.
Kadomtseva, A. M.
Narizhnaya, A. S.
Popov, Yu. F.] Moscow MV Lomonosov State Univ, Moscow 119992, Russia
[Bezmaternykh, L. N.
Gudim, I. A.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 880036, Russia
ИФ СО РАН
Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow 119991, Russian Federation
Moscow State University, Moscow 119992, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk 880036, Russian Federation
Доп.точки доступа:
Mukhin, A. A.; Vorob'ev, G. P.; Ivanov, V. Y.; Kadomtseva, A. M.; Narizhnaya, A. S.; Kuz'menko, A. M.; Popov, Y. F.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна
}
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5.
Complex interplay between
3d and 4f magnetic systems in
multiferroic
DyMnO3 / A. N. Matveeva, I. A. Zobkalo, M. Meven [et al.]> // J. Magn. Magn. Mater. - 2023. -
Vol. 569
. - Ст. 170415,
DOI
10.1016/j.jmmm.2023.170415. - Cited References: 28. - The authors are grateful to S.V. Gavrilov for the technical assistance. This work was supported by the Russian Foundation for Basic Research grant # 19-52-12047, and DFG grant # SA 3688/1-1, also by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science to the research projects number 18-42-243024 and 20-42-243008. The neutron data were obtained at the instrument HEiDi operated jointly by RWTH Aachen University and Jülich Centre for Neutron Science within JARA cooperation . - ISSN 0304-8853
Кл.слова (ненормированные):
Neutron diffraction
--
Crystal structure
--
Multiferroics
--
Magnetic structure
--
Manganites
Аннотация:
Structural and magnetic properties of single crystals of DyMnO3 were investigated by neutron diffraction in order to study the peculiarities of 3d-4f interactions in this compound. Precise magnetic order and its detailed temperature evolution were determined using single crystal neutron diffraction. Elliptical cycloid on manganese subsystem below TCh = 19 K was confirmed, with temperature decrease the elipticity of the Mn magnetic structure reduces significantly, creating almost circular cycloid. Temperature evolution of the magnetic structure demonstrate specific hysteretic behavior. The results show a complex interplay between transition metal and rare earth magnetic sublattices leading to so-called “Mn- controlled” and “Dy- controlled” magnetic states. The strong and complicate 3d-4f interaction leads to the unusual very slow magnetic structure relaxation.
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Держатели документа:
Petersburg Nuclear Physics Institute by B.P. Konstantinov of NRC «Kurchatov Institute», Gatchina, 188300, Russian Federation
Institute of Crystallography, RWTH Aachen University and Julich Centre for Neutron Science at Heinz Maier- Leibnitz Zentrum, Garching, Germany
Kirensky Institute of Physics, Federal Research Center, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Доп.точки доступа:
Matveeva, A. N.; Zobkalo, I. A.; Meven, M.; Freidman, A. L.; Фрейдман, Александр Леонидович; Semenov, S. V.; Семёнов, Сергей Васильевич; Terentjev, K. Yu.; Терентьев, Константин Юрьевич; Pavlovskiy, N. S.; Павловский, Николай Сергеевич; Kolkov, M. I.; Колков, Максим Игоревич; Shaykhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Hutanu, V.
}
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6.
Complex magnetic order
in the Nd(Tb)Fe3(BO3)4
multiferroic
revealed by single-crystal neutron diffraction / I. V. Golosovsky [et al.]> // Phys. Rev. B. - 2019. -
Vol. 99
,
Is. 13
. - Ст. 134439,
DOI
10.1103/PhysRevB.99.134439. - Cited References: 33. - This work was supported by the Russian Grant No. RFBR 16-02-00058. A.A.M. acknowledges the financial support from the Russian Science Foundation (16-12-10531). . - ISSN 2469-9950
Кл.слова (ненормированные):
Antiferromagnetism
--
Binary alloys
--
Crystal structure
--
Crystallography
--
Magnetic structure
--
Neodymium compounds
--
Neutron diffraction
--
Single crystals
--
Terbium compounds
Аннотация:
Magnetic structure of the substituted multiferroics-ferroborates Nd0.9Tb0.1Fe3(BO3)4 and Nd0.8Tb0.2Fe3(BO3)4 were determined in the framework of a self-consistent refinement of the single crystal neutron diffraction data. The small substitution of Nd for Tb leads to the reorientation of the main antiferromagnetic vector L from the basal plane towards the hexagonal axis. The reorientation takes place via an angular structure for which L does not coincide with the principal crystallographic directions and evolves with temperature due to competing magnetic anisotropies of Fe, Nd, and Tb subsystems. Our refinement at 2 K reveals the existence of distortions in the collinear antiferromagnetic Fe spin arrangement suggested before in other ferroborates. Therefore, besides the main antiferromagnetic vector L, the magnetic structure involves additional fine symmetrized combinations of spin components allowed by symmetry. They coexist with certain L components and could originate from the antisymmetric Dzyaloshinsky-Moriya Fe-Fe exchange interactions. At higher temperatures, the magnetic structure is described by the simple collinear model, where the L vector is deviated from the hexagonal plane. © 2019 American Physical Society.
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Держатели документа:
National Research Center, Kurchatov Institute, B.P. Konstantinov Petersburg Nuclear Physics Institute, Gatchina, 188300, Russian Federation
Prokhorov General Physics Institute, RAS, Moscow, 119991, Russian Federation
Universite Grenoble Alpes, CEA, INAC-MEM, Grenoble, 38000, France
Institucio Catalana de Recerca i Estudis Avancats, Barcelona, E-08010, Spain
Fisika Aplikatua II, Zientzia Eta Teknologia Fakultatea, Universidad Del Pais Vasco, UPV/EHU, Bilbao, 48940, Spain
Kirenskii Institute of Physics, Siberian Division of RAS, Krasnoyarsk, 660038, Russian Federation
Доп.точки доступа:
Golosovsky, I. V.; Vasilev, A. I.; Mukhin, A. A.; Ressouche, E.; Skumryev, V.; Urcelay-Olabarria, I.; Gudim, I. A.; Гудим, Ирина Анатольевна; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
}
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7.
Coupling between phonon
and crystal-field excitations in
multiferroic
PrFe3(BO3)4 / K. N. Boldyrev [et al.]> // Phys. Rev. B. - 2014. -
Vol. 90
,
Is. 12
. - Ст. 121101,
DOI
10.1103/PhysRevB.90.121101. - Cited References: 35. - This research was supported by the Russian Scientific Foundation under Grant No. 14-12-01033, the President of Russian Federation (MK-1700.2013.2; K.N.B.), and the U.S. Department of Energy under Grant No. DE-FG02-07ER46382 (experiments at U4-IR beamline NSLS-BNL; T.N.S. and A.A.S.). The National Synchrotron Light Source is operated as a User Facility for the U.S. Department of Energy under Contract No. DE-AC02-98CH10886. M.N.P. thanks B. Z. Malkin for drawing her attention to the work [33] and for helpful discussions. . - ISSN 1098-0121. - ISSN 1550-235X
Перевод заглавия:
Взаимодействие между фононами и возбуждениями кристаллического поля в мультиферроике PrFe3(BO3)4
РУБ
Physics, Condensed Matter
Рубрики:
MAGNETOELECTRIC PROPERTIES
GROUND-STATE
SM
Аннотация:
Far-infrared reflection and ellipsometry measurements on
multiferroic
PrFe3(BO3)4 and SmFe3(BO3)4 single crystals were used to investigate the interaction between lattice phonons and electronic excitations associated with 4f crystal-field transitions. A temperature-dependent interference between two types of excitations was observed in PrFe3(BO3)4 in which the frequency of 4f crystal-field electronic excitation of Pr3+ falls into the TO-LO frequency interval of the optical phonon mode near 50 cm−1 (1.5 THz). Experimental data were explained on the basis of a theoretical model of coupled electron-phonon modes. The fitting procedure revealed the value 14.8 cm−1 for the electron-phonon coupling constant. This rather large value points to an essential role played by the electron-phonon interaction in the physics of multiferroics.
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Держатели документа:
RAS, Inst Spect, Troitsk 142190, Russia
New Jersey Inst Technol, Dept Phys, Newark, NJ 07102 USA
RAS, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Доп.точки доступа:
Boldyrev, K. N.; Stanislavchuk, T. N.; Sirenko, A. A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Popova, M. N.; Russian Scientific Foundation [14-12-01033]; President of Russian Federation [MK-1700.2013.2]; U.S. Department of Energy [DE-FG02-07ER46382, DE-AC02-98CH10886]
}
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8.
Crystal field and
exchange interactions in the SmFe3(BO3)4
multiferroic
/ M. N. Popova [et al.]> // J. Exp. Theor. Phys. - 2014. -
Vol. 118
,
Is. 1
. - P. 111-123,
DOI
10.1134/S1063776114010142. - Cited References: 22. - This work was supported by the Russian Foundation for Basic Research (project no. 13-02-00787) and the basic research program Quantum Mesoscopic and Disordered Structures of the Presidium of the Russian Academy of Sciences. . - ISSN 1063-7761. - ISSN 1090-6509
РУБ
Physics, Multidisciplinary
Аннотация:
The optical spectra of oriented SmFe3(BO3)4 single crystals are studied in the region of the f-f transitions in the Sm3+ ion by Fourier spectroscopy. The energies, the symmetry properties, and the exchange splittings of the Stark sublevels of the ground and 17 excited multiplets of the Sm3+ ion in a crystal field of symmetry D 3 are determined from the measured temperature dependences of polarized-radiation absorption spectra. The parameters of the crystal field acting on samarium ions and the parameters of the exchange interaction between Sm3+ and Fe3+ ions are found. The anisotropy of the effective exchange interaction is shown to be substantially stronger than the magnetic anisotropy, due to a strong crystal-field-induced mixing of the ground and excited multiplets.
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Публикация на русском языке
Исследование кристаллического поля и обменных взаимодействий в мультиферроике SmFe3( BO3)4 [Текст] / М. Н. Попова [и др.] // Журн. эксперим. и теор. физ. : Наука, 2014. - Т. 145 Вып. 1. - С. 128-142
Держатели документа:
Russian Acad Sci, Inst Spect, Moscow 142190, Russia
Kazan Privolzhsky Fed Univ, Kazan 420008, Russia
State Univ, Moscow Inst Phys & Technol, Dolgoprudnyi 141700, Moscow Oblast, Russia
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Доп.точки доступа:
Popova, M. N.; Chukalina, E. P.; Malkin, B. Z.; Erofeev, D. A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Russian Foundation for Basic Research [13-02-00787]; basic research program Quantum Mesoscopic and Disordered Structures of the Presidium of the Russian Academy of Sciences
}
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9.
Crystal structure of
bismuth-containing NdFe3(BO3)4 in the temperature range 20–500 K / E. S. Smirnova, O. A. Alekseeva, A. P. Dudka [et al.]> // Acta Crystallogr. B. - 2022. -
Vol. 78
,
Pt. 1
. - P. 1-13,
DOI
10.1107/S205252062101180X. - Cited References: 44. - This work was performed using the equipment of the Shared Research Center FSRC `Crystallography and Photonics' RAS supported by the Russian Ministry of Science and Higher Education. This work was supported by the Ministry of Science and Higher Education within the State assignment FSRC `Crystallography and Photonics' RAS . - ISSN 2052-5206
РУБ
Chemistry, Multidisciplinary + Crystallography
Рубрики:
MAGNETIC PHASE-TRANSITIONS
UNIT-CELL PARAMETERS
DIFFRACTION
Кл.слова (ненормированные):
neodymium iron borate
--
multiferroic
--
crystal structure
--
multi-temperature
--
single-crystal X-ray diffraction
--
Mossbauer spectroscopy
--
characteristic temperature
Аннотация:
Neodymium iron borate NdFe3(BO3)4 is an intensively studied
multiferroic
with high electric polarization values controlled by a magnetic field. It is characterized by a large quadratic magnetoelectric effect, rigidity in the base plane and a rather strong piezoelectric effect. In this work, the atomic structure of (Nd0.91Bi0.09)Fe3(BO3)4 was studied by single-crystal X-ray diffraction in the temperature range 20–500 K (space group R32, Z = 3). The Bi atoms found in the composition partially substitute the Nd atoms in the 3a position; they entered the structure due to the growth conditions in the presence of Bi2Mo3O12. It was shown that in the temperature range 20–500 K there is no structural phase transition R32→P3121, which occurs in rare-earth iron borates (RE = Eu–Er, Y) with an effective rare-earth cation radius smaller than that of Nd. The temperature dependence of the unit-cell c parameter reveals a slight increase on cooling below 90 K, which is similar to the results obtained previously for iron borates of Gd, Y and Ho. The atomic distances (Nd,Bi)—O, (Nd,Bi)—B, (Nd,Bi)—Fe, Fe—O, Fe—B and Fe—Fe in the iron chains and between chains decrease steadily with decreasing temperature from 500 to 90 K, whereas the B1(3b)—O distance does not change and the average B2(9e)—O distance increases slightly. There is a uniform decrease in the atomic displacement parameters with decreasing temperature, with a more pronounced decrease for the Nd(3a) and O2(9e) atoms. The O2(9e) atoms are characterized by the maximum atomic displacement parameters and the most elongated atomic displacement ellipsoids. The characteristic Debye and Einstein temperatures, and the static component in the atomic displacements were determined for cations using multi-temperature diffraction data. It was shown that the Nd cations have the weakest bonds with the surrounding atoms and the B cations have the strongest.
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Держатели документа:
Russian Acad Sci, Fed Sci Res Ctr Crystallog & Photon, Shubnikov Inst Crystallog, Moscow 119333, Russia.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Доп.точки доступа:
Smirnova, E. S.; Alekseeva, O. A.; Dudka, A. P.; Verin, I. A.; Artemov, V. V.; Lyubutina, M. V.; Gudim, I. A.; Гудим, Ирина Анатольевна; Frolov, K. V.; Lyubutin, I. S.; Russian Ministry of Science and Higher Education; Ministry of Science and Higher Education within the State assignment FSRC 'Crystallography and Photonics' RAS
}
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10.
Dielectric and Raman
spectroscopy measurements across structural phase transition in
multiferroic
HoFe3(BO3)4 single crystal / A. Tripathy [et al.]> //
AIP Conf. Proc. - 2019. -
Vol. 2162
: International Conference on Advanced Materials, ICAM 2019. - Ст. 020062,
DOI
10.1063/1.5130272. - Cited References: 10. - DKS acknowledges support from the DST, New Delhi, India through the grant no INI/RUS/RFBR/P-269 (Indo Russian project). K.G. thanks, Council of Scientific and Industrial Research, New Delhi, India, for support in the form of SRF.
Аннотация:
We report on findings in the HoFe3(BO3)4 single crystal across structural phase transition by the dielectric and Raman spectroscopic measurements. In most of the compounds of RFe3(BO3)4 (R=La-Lu) family low temperature P3121 structure is introduced through structural phase transition (from space group R32). Temperature dependent dielectric measurements on the HoFe3(BO3)4 crystal depicts a step like feature at the structural phase transition at ?366 K. The Raman spectroscopy study also confirms the structural transition around this temperature. A clear signature of structural transition is reflected in the Raman spectra, mainly in the frequency range (200-400 cm-1). Appearance of new Raman modes below the transition temperature also indicates that the transition is from a high symmetry phase to a low symmetry phase.
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Держатели документа:
UGC-DAE Consortium for Scientific Research, Indore, 452001, India
Department of Physics, Aligarh Muslim University, Aligarh, 202002, India
L. V. Kirensky Institute of Physics, Siberian Branch of Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Доп.точки доступа:
Tripathy, A.; Gautam, K.; Dey, K.; Ahad, A.; Gudim, I. A.; Гудим, Ирина Анатольевна; Sathe, V. G.; Shukla, D. K.; International Conference on Advanced Materials(12-14 June 2019 ; Kannur, India)
}
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11.
Gavrichkov, V. A.
Effect of optical f - f excitations on the Nd-Fe exchange interaction in Nd ferroborate with
multiferroic
properties / V. A. Gavrichkov, A. V. Malakhovskii, S. G. Ovchinnikov> // Phys. Rev. B. - 2021. -
Vol. 104
,
Is. 6
. - Ст. 064445,
DOI
10.1103/PhysRevB.104.064445. - Cited References: 28. - The reported study was supported by the RFBR Grant 19-02-00034. V.A.G. is also grateful to the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, and Krasnoyarsk Regional Fund of Science according to the research project "Studies of superexchange and electron-phonon interactions in correlated systems as a basis for searching for promising functional materials" No. 20-42-240016 . - ISSN 2469-9950. - ISSN 2469-9969
РУБ
Materials Science, Multidisciplinary + Physics, Applied + Physics, Condensed Matter
Рубрики:
LOCAL MAGNETIC-PROPERTIES
SINGLE-CRYSTAL
EXCITED-STATES
Аннотация:
We considered the effect of optical pumping at the f−f transitions frequency on d−f superexchange in the rare-earth antiferromagnetic ferroborate Nd0.5Gd0.5Fe3(BO3)4 between Nd3+ ions in the excited states of the 4G5/2, 2G7/2, and Fe3+ in the ground state 6A1. In the ferroborate, d−f superexchange is directly related to the strong magnetoelectric coupling observed in the ground state of the material. We show that under optical pumping at the frequency of f−f transitions 4I9/2↔(4G5/2+2G7/2) in the Nd3+ ion, the nature of the d−f interaction changes to FM. The phenomena can be explained by the occupation of the excited Nd3+ “spin pure” states with spin 1/2, or their mixing to the optically excited states with spin 3/2 due to the spin-orbit interaction. Near optically excited ions Nd3+, magnetic frustrations change from FM ordering under the d−f AFM interaction to AFM ordering under the FM interaction in the basal hexagonal plane.
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Держатели документа:
Kirensky Inst Phys, Akademgorodok 50,Bld 38, Krasnoyarsk 660036, Russia.
Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Гавричков, Владимир Александрович; RFBRRussian Foundation for Basic Research (RFBR) [19-02-00034]; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Krasnoyarsk Regional Fund of Science [20-42-240016]; Government of Krasnoyarsk Territory
}
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12.
Effect of Sequential
Heat Impacts on the Formation of a Stable State of the xLPM-(1-x)PT
Multiferroic
Composites / E. A. Mikhaleva [et al.]> // Phys. Solid State. - 2018. -
Vol. 60
,
Is. 12
. - P. 2524-2531,
DOI
10.1134/S1063783419010189. - Cited References: 15. - This study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory, and the Krasnoyarsk Territorial Foundation for Support of the Scientific and R&D Activity, project no. 17-42-240076 "Complex Approach to Searching and Development of Promising Solid-State Ferroic Cooling Agents Based on the Single- and Multicaloric Effects." . - ISSN 1063-7834. - ISSN 1090-6460
РУБ
Physics, Condensed Matter
Рубрики:
PbTiO3
Аннотация:
The effect of thermal cycling and sintering temperature on the chemical and thermodynamic stability of the bulk
multiferroic
xLa0.7Pb0.3MnO3–(1 – x)PbTiO3 quasi-ceramic and ceramic composites has been experimentally investigated. It is shown that the limiting temperature of the long-term sample firing should not exceed 1070 K. It has been found that sintering at this temperature and/or short-term exposure of the samples at higher temperatures (up to 1220 K) significantly increase the sample compactness, stabilize the thermal expansion, and enhance the quality of the composites. It has been established that the component grain integrity is violated by shrinkage of the samples and a sharp change in their volume during the phase transition of a ferroelectric component.
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Публикация на русском языке
Влияние последовательных термических воздействий на формирование стабильного состояния мультиферроидных композитов xLPM-(1-x)PT [Текст] / Е. А. Михалева [и др.] // Физ. тверд. тела. - 2019. - Т. 61 Вып. 1. - С. 87-94
Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660041, Russia.
Доп.точки доступа:
Mikhaleva, E. A.; Михалева, Екатерина Андреевна; Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Shabanov, A. V.; Шабанов, Александр Васильевич; Russian Foundation for Basic Research [17-42-240076]; Government of the Krasnoyarsk Territory [17-42-240076]; Krasnoyarsk Territorial Foundation [17-42-240076]
}
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13.
Effect of uncontrolled
impurities on magnetic and structural transitions of the GdFe3(BO3)4
multiferroic
/ I. A. Gudim, E. V. Eremin, A. S. Krylov, V. R. Titova> //
V International Baltic Conference on Magnetism. IBCM : Book of abstracts. - 2023. - P. 128. - Cited References: 3. - Support by RSF and KRFS № 22-12-20019 are acknowledged
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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS
Доп.точки доступа:
Gudim, I. A.; Гудим, Ирина Анатольевна; Eremin, E. V.; Еремин, Евгений Владимирович; Krylov, A. S.; Крылов, Александр Сергеевич; Titova, V. R.; International Baltic Conference on Magnetism(5 ; 2023 ; Aug. 20-24 ; Svetlogorsk, Russia); Балтийский федеральный университет им. И. Канта
}
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14.
Shinkorenko, A. S.
Electronic structure, magnetic, optical and polarization properties of the
multiferroic
CaMnTi2O6 by first principles / A. S. Shinkorenko, V. I. Zinenko, M. S. Pavlovski> //
Joint 14th Rus./CIS/Baltic/Japan Symp. on Ferroelectricity (RCBJSF)/ Young sci. school on the spect. studies of critical dynamics at struct. phase trans. : Abstract book / org. comm. A. N. Vtyurin ; progr. comm. I. N. Flerov. - 2018. - P. 148. - Cited References: . - ISBN 978-5-9651-1144-2
Материалы конференции
Доп.точки доступа:
Vtyurin, A. N. \org. comm.\; Втюрин, Александр Николаевич; Flerov, I. N. \progr. comm.\; Флёров, Игорь Николаевич; Zinenko, V. I.; Зиненко, Виктор Иванович; Pavlovskii, M. S.; Павловский, Максим Сергеевич; Шинкоренко, Алексей Сергеевич; Joint Russia/CIS/Baltic/Japan Symposium on Ferroelectricity(14 ; May 14-18, 2018 ; St. Perersburg); Young scientists school on the spectroscopic(May 14-18, 2018 ; St. Perersburg); Физико-технический институт им. А.Ф. Иоффе РАН; Санкт-Петербургский политехнический университет им. Петра Великого
}
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15.
Evidence for a
collinear easy-plane magnetic structure of
multiferroic
EuFe3(BO3)4: Spectroscopic and theoretical studies / M. N. Popova [et al.]> // Phys. Rev. B. - 2016. -
Vol. 94
,
Is. 18
. - Ст. 184418,
DOI
10.1103/PhysRevB.94.184418. - Cited References: 49. - This work was supported by the Russian Science Foundation under Grant No. 14-12-01033. I.A.G. and V.L.T. are grateful to L. N. Bezmaternykh for useful comments concerning the crystal growth, to M. S. Molokeev for the XRD characterization of the samples, and to the Russian Foundation for Basic Research for a financial support (Grants No. 13-02-12442 and No. 14-02-00307a). . - ISSN 1098-0121
Перевод заглавия:
Фактические данные по коллинеарности легкоплоскостной магнитной структуры мультиферроика EuFe3 (BO3) 4: спектроскопические и теоретические исследования
Аннотация:
We performed high-resolution polarized optical transmission spectroscopy and theoretical studies of
multiferroic
EuFe3(BO3)4 single crystals in the three phases: paramagnetic R32(T˃Ts=84K) and P3121(Ts˃T˃TN=34K), and antiferromagnetic (T˂TN) ones. The analysis of the spectra reveals interesting details of the magnetic structure, namely, a collinear arrangement of the iron magnetic moments along the C2 symmetry axis in the ab crystallographic plane of EuFe3(BO3)4 below TN. Spectral signatures of the phase transitions and the spin-phonon interaction are observed and discussed. Reliable crystal-field and exchange-interaction parameters are obtained and used to model the magnetic susceptibility of the compound. The results of detailed calculations of the electric polarization of EuFe3(BO3)4 in the R32 phase are presented, and mechanisms of the magnetoelectric response are discussed. We detect a strong effect of impurities (that enter the crystal from a flux in the course of the crystal growth) on the structural phase-transition temperature and demonstrate a coexistence of both R32 and P3121 phases down to the lowest temperatures in a EuFe3(BO3)4 crystal grown with the Bi2Mo3O12 based flux, due to inhomogeneous distribution of impurity Bi3+ ions. Our study can be considered as a demonstration of the abilities of optical spectroscopy in delivering new information on a magnetic compound, even in the case when other methods fail. © 2016 American Physical Society.
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Держатели документа:
Institute for Spectroscopy, Russian Academy of Sciences, Troitsk, Moscow, Russian Federation
Kazan Federal University, Kazan, Russian Federation
Department of Physics, New Jersey Institute of Technology, Newark, NJ, United States
Moscow Institute of Physics and Technology, State University, Dolgoprydny, Moscow region, Russian Federation
L. V. Kirensky Institute of Physics, Siberian Branch of RAS, Krasnoyarsk, Russian Federation
Доп.точки доступа:
Popova, M. N.; Malkin, B. Z.; Boldyrev, K. N.; Stanislavchuk, T. N.; Erofeev, D. A.; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна
}
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16.
Giant gigahertz optical
activity in
multiferroic
ferroborate / A. M. Kuzmenko [et al.]> // Phys. Rev. B. - 2014. -
Vol. 89
,
Is. 17
. - Ст. 174407,
DOI
10.1103/PhysRevB.89.174407. - Cited References: 35. - This work was supported by the Russian Foundation for Basic Researches (Grants No. 12-02-01261 and No. 12-02-31461 mol) and by the Austrian Science Funds (Grants No. I815-N16 and No. W1243). . - ISSN 1098-0121. - ISSN 1550-235X
Рубрики:
RFE3(BO3)4
Аннотация:
In contrast to the well-studied
multiferroic
manganites with a spiral structure, the electric polarization in
multiferroic
borates is induced within a collinear antiferromagnetic structure and can easily be switched by small static fields. Because of specific symmetry conditions, the static and dynamic properties in borates are directly connected, which leads to giant magnetoelectric and magnetodielectric effects. Here we prove experimentally that the giant magnetodielectric effect in samarium ferroborate, SmFe3(BO3)4, is of intrinsic origin and is caused by an unusually large electromagnon situated in the microwave range. This electromagnon reveals a strong optical activity exceeding 120 degrees of polarization rotation in a millimeter thick sample.
В отличие от хорошо изученных мультиферроиков манганитов со спиральной структуры, электрическая поляризация в мультиферроиков боратов индуцируется в коллинеарной антиферромагнитной структуре и может легко переключаться небольшими статическими полями. Из-за специфических условий симметрии, статические и динамические свойства боратов непосредственно связаны, что приводит к гигантским магнитоэлектрическому и магнитодиэлектрическому эффектам. Здесь мы экспериментально доказываем, что гигантский магнитодиэлектрический эффект в самариевом ферробората, SmFe3 (BO3) 4, имеет самостоятельное происхождение и вызван необычно большим электромагноном, расположеным в микроволновом диапазоне. Это электромагнон показывает сильную оптическую активность, более 120 градусов вращения поляризации в миллиметровом образце.
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Держатели документа:
Russian Acad Sci, Prokhorov Gen Phys Inst, Moscow 119991, Russia
Vienna Univ Technol, Inst Solid State Phys, A-1040 Vienna, Austria
RAS, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Доп.точки доступа:
Kuzmenko, A. M.; Кузьменко А. М.; Shuvaev, A.; Dziom, V.; Pimenov, A.; Schiebl, M.; Mukhin, A. A.; Ivanov, V. Yu.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Russian Foundation for Basic Researches [12-02-01261, 12-02-31461 mol]; Austrian Science Funds [I815-N16, W1243]
}
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17.
Giant optical activity
near electromagnons in
multiferroic
ferroborites: SmFe3(BO3)4 [Текст] / A. A. Mukhin [et al.]> //
Moscow int. Symp. on Magnet. (MISM-2014) : Book of abstracts. - 2014. - Ст. 1RP-O-3. - P. 394 . - ISBN 978-5-91978-025-0
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Доп.точки доступа:
Mukhin, A. A.; Kuzmenko, A. M.; Кузьменко А.М.; Ivanov, V.Yu.; Shuvaev, A.; Dziom, V.; Pimenov, A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Moscow International Symposium on Magnetism(6 ; 2014 ; 29 June-3 July ; Moscow); Московский государственный университет им. М.В. Ломоносова
}
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18.
Hard X-ray dichroisms
studies of
multiferroic
Ga- Fe03 crystal / A. Rogalev, F. Wilhelm, A. Bosak [et al.]> //
Moscow Int. Symp. on Magnet. (MISM-2011) : Book of abstracts. - 2011. - Ст. 24TL-H-5. - P. 607-608
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Доп.точки доступа:
Rogalev, A.; Wilhelm, F.; Bosak, A.; Goulon, J.; Smekhova, A.; Gan’shina, E. A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Kazak, N. V.; Казак, Наталья Валерьевна; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Moscow International Symposium on Magnetism(5 ; 2011 ; Aug. ; 21-25 ; Moscow)
}
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19.
Heat capacity and
thermodynamic properties of GaFeO3 in the range 330-900 K / V. M. Denisov [et al.]> // Inorg. Mater. - 2013. -
Vol. 49
,
Is. 12
. - P. 1227-1228,
DOI
10.1134/S0020168513120042. - Cited References: 10 . - ISSN 0020-1685
РУБ
Materials Science, Multidisciplinary
Рубрики:
MULTIFERROIC
GAFEO3
SINGLE-CRYSTALS
TEMPERATURE
BIFEO3
Аннотация:
The heat capacity of
multiferroic
GaFeO3 has been measured in a wide temperature range and the results have been used to evaluate its thermodynamic functions (enthalpy increment and entropy change).
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Публикация на русском языке
Теплоемкость и термодинамические свойства GaFeO3 в области 330–900 К. - [S. l. : s. n.]
Держатели документа:
Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Krasnoyarsk 660041, Russia
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660074, Russia
Доп.точки доступа:
Denisov, V. M.; Irtyugo, L. A.; Denisova, L. T.; Patrin, G. S.; Патрин, Геннадий Семёнович; Volkov, N. V.; Волков, Никита Валентинович
}
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20.
High-resolution optical spectroscopy
and modeling of spectral and magnetic properties of
multiferroic
ErFe3(BO3)4 / M. N. Popova, E. P. Chukalina, D. S. Erofeev [et al.]> // Phys. Rev. B. - 2020. -
Vol. 101
,
Is. 20
. - Ст. 205108,
DOI
10.1103/PhysRevB.101.205108. - Cited References: 38. - Financial support of the Russian Science Foundation under Grant No. 19-12-00413 is acknowledged. . - ISSN 2469-9950. - ISSN 2469-9969
РУБ
Materials Science, Multidisciplinary + Physics, Applied + Physics, Condensed Matter
Рубрики:
F-F TRANSITIONS
ENERGY-LEVELS
ER3+ IONS
GROWTH
Аннотация:
We carried out the high-resolution broadband temperature-dependent polarized optical spectroscopy and theoretical studies of ErFe3(BO3)4 single crystals in the paramagnetic and antiferromagnetic (T˂TN=39K) phases. On the basis of the experimentally determined 45 crystal-field (CF) levels of Er3+ ions at sites with the C2 point symmetry, CF calculations were performed, a set of physically grounded CF parameters was obtained and used to model the temperature dependences of the Er magnetic moments measured in neutron-scattering experiments, as well as the magnetic susceptibility and magnetization of the compound; the contributions of the quasi-one-dimensional iron magnetic subsystem were calculated in the frame of the previously developed self-consistent four-particle cluster model. The modeling strongly supports an easy-plane collinear structure of iron magnetic moments and excludes earlier proposed additional magnetic phase.
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Держатели документа:
Russian Acad Sci, Inst Spect, Moscow 108840, Russia.
Natl Res Univ, Moscow Inst Phys & Technol, Dolgoprudnyi 141701, Moscow Region, Russia.
LV Kirenskii Inst Phys, Siberian Branch RAS, Krasnoyarsk 660036, Russia.
Kazan Fed Univ, Kazan 420008, Russia.
Доп.точки доступа:
Popova, M. N.; Chukalina, E. P.; Erofeev, D. S.; Jablunovskis, A.; Gudim, I. A.; Гудим, Ирина Анатольевна; Malkin, B. Z.; Russian Science FoundationRussian Science Foundation (RSF) [19-12-00413]
}
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