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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Volova T. G., Shumilova A. A., Shidlovskiy I. P., Nikolaeva E. D., Sukovatiy A. G., Vasiliev A. D., Shishatskaya E. I.
Заглавие : Antibacterial properties of films of cellulose composites with silver nanoparticles and antibiotics
Место публикации : Polym Test. - 2018. - Vol. 65. - P.54-68. - ISSN 01429418 (ISSN), DOI 10.1016/j.polymertesting.2017.10.023
Примечания : Cited References: 61. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project № 16-43-242024 . The study was supported by the State budget allocated to the fundamental research at the Russian Academy of Sciences (project No AAAA-A17-117013050028-8 ).
Ключевые слова (''Своб.индексиров.''): bacterial cellulose--composites--silver nanoparticles--antibiotics--properties--antibacterial activity
Аннотация: The present study describes production of bacterial cellulose composites with silver nanoparticles and antibiotics and compares their properties. Bacterial cellulose (BC) composites synthesized in the culture of the strain of acetic acid bacterium Komagataeibacter xylinus VKPM B-12068 with silver nanoparticles, BC/AgNps, were produced hydrothermally, under different AgNO3 concentrations (0.0001, 0.001, and 0.01 M) in the reaction medium. The presence of silver in the BC/AgNp composites was confirmed by elemental analysis conducted using scanning electron microscopy with a system of X-ray spectral analysis. Analysis showed that the average atomic number of silver particles in composite samples depended on the concentration of AgNO3: as AgNO3 concentration in the reaction solution was increased, silver content in the composites increased from 0.044 to 0.37 mg/cm2. BC composites with amikacin and ceftriaxone were prepared by immersing dry BC films in solutions containing different concentrations of the antibiotics. The surface structure and properties and physicochemical and mechanical characteristics of composites were investigated using SEM, DSC, X-ray analysis, the system for measuring water contact angles, and electromechanical tensile testing machine. The disk-diffusion method and the shake-flask culture method used in this study showed that all experimental composites had pronounced antibacterial activity against E. coli, Ps. eruginosa, K. pneumoniae, and St. aureus, and the BC/antibiotic composites were more active than BC/AgNp ones; S. aureus was the most susceptible to the effect of BC composites. No potential cytotoxicity was detected in any of the BC/AgNp composites in the NIH 3T3 mouse fibroblast cell culture, in contrast to the BC/antibiotic composites. These results suggest that BC composites constructed in the present study hold promise as dressings for managing wounds, including contaminated ones.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Khaydarov R., Gapurova O., Abdukhakimov M., Sadikov I., Garipov I., Krishnamurthy P. T., Zharkov S. M., Zeer G. M., Abolentseva P. A., Prudnikova S. V., Evgrafova S. Y.
Заглавие : Antimicrobial properties of nanofiltration membranes modified with silver nanoparticles
Коллективы : SFU Joint Scientific Center; Ministry of Science and Higher Education of the Russian Federation [FSRZ-2020-0011]
Место публикации : Emerg. Mater. - 2022. - Vol. 5, Is. 5. - P.1477-1483. - ISSN 2522-5731, DOI 10.1007/s42247-021-00330-2. - ISSN 2522-574X(eISSN)
Примечания : Cited References: 31. - The SEM and TEM analysis was carried out in the SFU Joint Scientific Center under the support of the Ministry of Science and Higher Education of the Russian Federation (#FSRZ-2020-0011)
Аннотация: The growth of bacteria and fungi on a nanofiltration (NF) membrane is known to reduce its permeability and lifetime and increase overall energy use. Over the last decade, application of silver nanoparticles (AgNPs) has shown to present a strong potential in preventing biofouling of NF membrane processes. The paper deals with a novel facile method developed to in situ incorporate nanosilver stabilized with the polyhexamethylene biguanide hydrochloride (PHMB) onto the commercial NF membrane surface. The scanning electron microscopy (SEM) investigations confirmed a uniform distribution of AgNPs on the surface of NF membrane although AgNPs tend to agglomerate into nano-sized colloidal clusters. Our results showed that AgNPs had little impact on the performance of the NF membrane, including salt rejection and water permeation properties. To evaluate the antibacterial properties of nanocomposite membranes, a "time-kill" analysis, a microbiological technique for measuring the change in a population of microorganisms under the impact of a specific sample, has been used against representatives of Gram-positive and Gram-negative bacteria. Inductively coupled mass spectrometry (ICP-MS) was used to study kinetics of Ag release from modified NF membrane. Leaching rates of Ag were low that will possibly result in long-established antimicrobial and antifungal properties. The present research offers a potential for its further use as a new type of modified NF membrane mitigating biofouling.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Volova, Tatiana G., Prudnikova, Svetlana V., Kiselev, Evgeniy G., Nemtsev I. V., Vasiliev A. D., Kuzmin, Andrey P., Shishatskaya, Ekaterina I.
Заглавие : Bacterial cellulose (BC) and BC composites: Production and properties
Коллективы : Ministry of Science and Higher Education of the Russian Federation [FSRZ-2020-0006]
Место публикации : Nanomaterials. - 2022. - Vol. 12, Is. 2. - Ст.192. - ISSN 2079-4991(eISSN), DOI 10.3390/nano12020192
Примечания : Cited References: 113. - This research was financially supported by the State Assignment of the Ministry of Science and Higher Education of the Russian Federation No. FSRZ-2020-0006
Предметные рубрики: SILVER NANOPARTICLES
GLUCONACETOBACTER-HANSENII
MICROBIAL CELLULOSE
Аннотация: The synthesis of bacterial cellulose (BC) by Komagataeibacter xylinus strain B-12068 was investigated on various C-substrates, under submerged conditions with stirring and in static surface cultures. We implemented the synthesis of BC on glycerol, glucose, beet molasses, sprat oil, and a mixture of glucose with sunflower oil. The most productive process was obtained during the production of inoculum in submerged culture and subsequent growth of large BC films (up to 0.2 m2 and more) in a static surface culture. The highest productivity of the BC synthesis process was obtained with the growth of bacteria on molasses and glycerol, 1.20 and 1.45 g/L per day, respectively. We obtained BC composites with silver nanoparticles (BC/AgNPs) and antibacterial drugs (chlorhexidine, baneocin, cefotaxime, and doripenem), and investigated the structure, physicochemical, and mechanical properties of composites. The disc-diffusion method showed pronounced antibacterial activity of BC composites against E. coli ATCC 25922 and S. aureus ATCC 25923.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bikbaev R. G., Vetrov S. Ya., Timofeev I. V.
Заглавие : The optical Tamm states at the interface between a photonic crystal and nanoporous silver
Место публикации : J. Opt.: IOP, 2017. - Vol. 19, Is. 1. - Ст.015104. - ISSN 20408978 (ISSN), DOI 10.1088/2040-8986/19/1/015104
Примечания : Cited References: 38. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project № 16-42-243065, SB RAS No. II.2P (0358-2015-0010), the Ministry of Education and Science of the Russian Federation, projects no. 3.1276.2014/K and no. 3.1211.2017/PCH. I.V.T. acknowledges financial support from RFBR research project № 15-02-03838.
Ключевые слова (''Своб.индексиров.''): photonic crystal--nanoporous silver--optical tamm state--effective permittivity
Аннотация: The optical Tamm states (OTSs) localized at the edges of a photonic crystal bounded by a nanoporous silver (NPS) film are investigated. NPS involves spherical vacuum nanopores dispersed in the metal matrix and is characterized by the effective resonance permittivity. The transmission, reflection, and absorption spectra of the structures under study at the normal incidence of light are calculated. It is shown that each Tamm state has its own frequency range where the real part of effective permittivity is negative. The light field localization at the high- and low-frequency OTSs is investigated. The specific features of spectral manifestation of the OTSs are studied in dependence on the nanopore concentration in the metal matrix and on the NPS film thickness.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Baker, Syed, Prudnikova, Svetlana V., Shumilova, Anna A., Perianova, Olga V., Zharkov S. M., Kuzmin A.
Заглавие : Bio-functionalization of phytogenic Ag and ZnO nanobactericides onto cellulose films for bactericidal activity against multiple drug resistant pathogens
Место публикации : J. Microbiol. Methods. - 2019. - Vol. 159. - P.42-50. - ISSN 0167-7012, DOI 10.1016/j.mimet.2019.02.009. - ISSN 1872-8359(eISSN)
Примечания : Cited References: 59
Предметные рубрики: SILVER NANOPARTICLES
ANTIMICROBIAL ACTIVITY
SIZE
COMPOSITES
MEMBRANE
Аннотация: The present study describes the synthesis of silver and zinc oxide nanobactericides from the phytogenic source Bupleurum aureum The synthesized nanobactericides were characterized and evaluated for bio-functionalization onto bacterial cellulose membrane which was synthesized by Komagataeibactencylinus B-12068 culture strain. The synthesis of nanobacterides were initially confirmed using UV-Visible spectroscopy which indicated localized surface resonance (LSPR) peaks at 415 nm for silver nanobactericides and 280 nm for zinc nanobactericides. The nature of the capping agent for synthesized nanobactericides was predicted using FTIR which confirmed the presence of functional moieties. XRD analysis revealed their crystalline nature while morphological characteristics were studied using TEM which confirmed the polydispersity of nanobactericides with the average size in the range of 20-25 nm. The nanobactericides were tested for their antimicrobial activity against seven multi-drug resistant pathogens which were clinically isolated from patients suffering from a myriad of microbial infections. The tested pathogens had antimicrobial resistance to ten different antibiotics and have been reported to be the major cause of nosocomial infections. The nanobactericides displayed significant activity against the test pathogens. Silver nanobactericides showed the highest activity against Escherichia coli strain 55 with a 24 mm zone of inhibition while zinc oxide nanobactericides displayed the highest activity against methicillinresistant Staphylococcus aureus (MRSA) with a 20 mm inhibition zone. The bio- functionalized cellulose films (BCF) were characterized using SEM along with physicochemical analysis. The BCF's were evaluated for anti-bacterial activity against test pathogens which resulted in marked antimicrobial potential against multi-drug resistant bacteria and therefore has the potential to be utilized as an efficient alternative to counter drug resistant pathogens.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Baker, Syed, Volova, Tatiana, Prudnikova, Svetlana V., Shumilova, Anna A., Perianova, Olga, V, Zharkov S. M., Kuzmin A. R., Kondratenka, Olga, Kiryukhin, Bogdan, Shidlovskiy, Ivan P., Potkina, Zoya K., Khohlova, Olga Y., Lobova, Tatiana I.
Заглавие : Bio-hybridization of nanobactericides with cellulose films for effective treatment against members of ESKAPE multi-drug-resistant pathogens
Коллективы : Ministry of Education and Science of the Russian Federation under the scheme of 5-100: Russian Academic Excellence Project
Место публикации : Appl. Nanosci. - 2018. - Vol. 8, Is. 5. - P.1101-1110. - ISSN 2190-5509, DOI 10.1007/s13204-018-0717-9. - ISSN 2190-5517(eISSN)
Примечания : Cited References: 51. - Authors are thankful for Ministry of Education and Science of the Russian Federation for providing funding under the scheme of 5-100: Russian Academic Excellence Project. Authors are grateful for facilities provided by Siberian Federal University to carry out the present study.
Предметные рубрики: SILVER NANOPARTICLES
BACTERIAL CELLULOSE
ANTIBIOTIC-RESISTANCE
Ключевые слова (''Своб.индексиров.''): eskape--bio-hybridization--silver nanobactericides--phytogenic--bactericidal activity
Аннотация: The rapid expansion of drug-resistant pathogens has created huge global impact and development of novel antimicrobial leads is one of the top priority studies in the current scenario. The present study aims to develop bio-hybridized nanocellulose films which comprise of phytogenic silver nanobactericides. The nanobactericides were synthesized by treating 1 mM silver nitrate with aqueous extract of Chamerion angustifolium which reduced the metal salt to produce polydispersed nanobactericides which were tested against the members of ESKAPE drug-resistant communities. The synthesized silver nanobactericides were subjected to characterization with UV–visible spectra which displayed maximum absorbance at 408 nm. The bio-molecular interaction of phyto-constituents to mediate synthesis and stabilization of nanobactericides was studied with Fourier-transform infrared spectroscopy (FTIR) which depicted functional groups associated with nanobactericides. The crystalline nature was studied with X-ray diffraction (XRD) which showed Bragg’s intensities at 2θ angle which denoted (111), (200), (220), and (311) planes. The morphological characteristics of silver nanobactericides were defined with transmission electron Microscopy (TEM) image which displayed polydispersity of silver nanobactericides with size ranging from 2 to 40 nm. The synthesized nanobactericides showed a significant activity against MRSA strain with 21 mm zone of inhibition. The minimal inhibitory concentration of silver nanobactericides to inhibit the growth of test pathogens was also determined which ranged between 0.625 and 1.25 μg/ml. The silver nanobactericides were bio-hybridized onto nanocellulose films produced by Komagataeibacter xylinus B-12068 culture strain. The films were dried to determine the mechanical properties which showed increased in Young’s modulus and tensile strength in comparison with control bacterial cellulose films. Overall, the results obtained in the present investigation are promising enough to report bactericidal activity of bio-hybridized nanobactericidal films against ESKAPE. These communities are reported to cause severe threats to all forms of lives irrespective to their habitats which can lead to huge economical crisis.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Внукова, Наталья Григорьевна, Лопатин, Владислав Александрович, Осипова, Ирина Владимировна, Чурилов, Григорий Николаевич
Заглавие : Comparative characteristics of alternating current light source with copper and silver electrodes under power samples analysis
Коллективы : "Современный атомно-эмиссионный анализ и науки о земле", семинар, Российская академия наук, Сибирское отделение РАН, Иркутский научынй центр СО РАН, Институт геохимии им. А. П. Виноградова СО РАН
Место публикации : Современный атомно-эмиссионный анализ и науки о земле: программа и тезисы докл. науч. семинара с междунар. участием, посвящ. 150-летию создания Кирхгофом и Бунзеном основ атом. спектроскопии, 30 июня - 4 июля 2009 г., г. Иркутск/ [отв. ред.: Е. В. Шабанова, О. В. Зарубина]. - 2009. - С. 17-18. - ISBN 978-5-94797-139-2
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisenko Y. G., Sedykh A. E., Molokeev M. S., Oreshonkov A. S., Aleksandrovsky A. S., Krylov A. S., Khritokhin N. A., Sal'nikova E. I., Andreev O. V., Muller-Buschbaum K.
Заглавие : Crystal and electronic structure, thermochemical and photophysical properties of europium-silver sulfate monohydrate AgEu(SO4)2·H2O
Место публикации : J. Solid State Chem. - 2021. - Vol. 294. - Ст.121898. - ISSN 00224596 (ISSN), DOI 10.1016/j.jssc.2020.121898
Примечания : Cited References: 54. - This work was partially supported by the Russian Foundation for Basic Research (Grant 19-33-90258∖19 ). Use of equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center « Krasnoyarsk Science Center SB RAS» is acknowledged
Аннотация: In order to synthesize single crystals of europium-silver double sulfate monohydrate, a hydrothermal reaction route was used. It was found that the crystallization cannot be performed under standard conditions. The compound AgEu(SO4)2·H2O crystallizes in the trigonal crystal system, space group P3221 (a = 6.917(1), c = 12.996(2) Å, V = 538.53(17) Å3). The structure consists of triple-capped trigonal prisms [EuO9], in which one oxygen atom belongs to crystalline water, silver octahedra [AgO6], and sulfate tetrahedra [SO4]. The hydrogen bonds in the system additionally stabilize the structure. The electronic band structure wasstudied by density functional theory calculations which show that AgEu(SO4)2·H2O is an indirect band gap dielectric. Temperature dependent photoluminescence spectroscopy shows emission bands of transitions from the 5D0 state to the spin-orbit components of the 7FJmultiplet (J = 0–6).The ultranarrow transition 5D0 - 7F0 shows a red shift with respect to other europium-containing water-free sulfates that is ascribed to the presence of OH group in the crystal structure in the close vicinity of the Eu3+ ion. An effect of abnormal sensitivity of the Ω4 intensity factor to minor distortions of the local environment is detected for the observed low local symmetry of C2.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Slabko V. V., Tsipotan A. S. , Aleksandrovsky A. S., Slyusareva E. A.
Заглавие : Dynamics of self-organized aggregation of resonant nanoparticles in a laser field
Коллективы : Grant of the Ministry of Education and Science of the Russian Federation for Siberian Federal University; SB RAS Grant [24.31]; RFBR [14-02-00219 A]
Место публикации : Appl. Phys. B: Springer, 2014. - Vol. 117, Is. 1. - P.271-278. - ISSN 0946-2171, DOI 10.1007/s00340-014-5831-0. - ISSN 1432-0649
Примечания : Cited References: 30. - This research is partially supported by Grant of the Ministry of Education and Science of the Russian Federation for Siberian Federal University, by SB RAS Grant 24.31, and by RFBR Research Project No. 14-02-00219 A.
Предметные рубрики: PHOTOSTIMULATED AGGREGATION
SILVER
PRINCIPLES
PARTICLES
SPECTRA
SOLS
Аннотация: Self-organized aggregation of nanoparticles in external resonant laser field is considered using Brownian dynamics model. Formation probabilities are calculated for the pair of particles in dependence on laser wavelength and mutual orientation of particles. Times required for aggregation are calculated. Possibility of efficient aggregation using pulsed laser is deduced.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Markel V. A., Pustovit V. N., Karpov S. V., Obuschenko A. V., Gerasimov V. S., Isaev I. L.
Заглавие : Electromagnetic density of states and absorption of radiation by aggregates of nanospheres with multipole interactions
Место публикации : Phys. Rev. B: AMER PHYSICAL SOC, 2004. - Vol. 70, Is. 5. - Ст.54202. - ISSN 1098-0121, DOI 10.1103/PhysRevB.70.054202
Примечания : Cited References: 81
Предметные рубрики: DISCRETE-DIPOLE APPROXIMATION
ENHANCED RAMAN-SCATTERING
METAL FRACTAL CLUSTERS
OPTICAL-PROPERTIES
SELECTIVE PHOTOMODIFICATION
DISORDERED CLUSTERS
NUMERICAL-SIMULATION
SPECTRAL DEPENDENCE
PARTICULATE MATTER
LIGHT-SCATTERING
Ключевые слова (''Своб.индексиров.''): carbon--iron--palladium--silver--article--dipole--electromagnetic field--geometry--mathematical analysis--molecular interaction--nanoparticle--radiation absorption
Аннотация: We calculate the quasistatic electromagnetic density of states for aggregates of touching spheres, in particular, linear chains and computer-generated random fractal aggregates. Multipole moments with orders of up to L=64 are taken into account for random aggregates with the number of particles of up to N=100 and up to L=8000 for linear chains. Extensive comparisons with the dipole approximation and geometrical cluster renormalization method are performed. Extinction spectra are calculated for several metals and black carbon. Long wavelength electromagnetic properties of fractal aggregates are considered in details.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zakomirnyi V. I., Rinkevicius Z., Baryshnikov G. V., Sorensen L. K., Agren H.
Заглавие : Extended Discrete Interaction Model: Plasmonic Excitations of Silver Nanoparticles
Место публикации : J. Phys. Chem. C. - 2019. - Vol. 123, Is. 47. - P.28867-28880. - ISSN 19327447 (ISSN), DOI 10.1021/acs.jpcc.9b07410
Примечания : Cited References: 64. - H.Å. and V.I.Z. acknowledge the support of the Russian Science Foundation (project no. 18-13-00363). L.K.S. acknowledges the support of Carl Tryggers Stifetelse, project no. CTS 18-441.
Аннотация: We present a new atomistic model for plasmonic excitations and optical properties of metallic nanoparticles, which collectively describes their complete response in terms of fluctuating dipoles and charges that depend on the local environment and on the morphology of the composite nanoparticles. Being atomically dependent, the total optical properties, the complex polarizability, and the plasmonic excitation of a cluster refer to the detailed composition and geometric characteristics of the cluster, making it possible to explore the role of the material, alloy mixing, size, form shape, aspect ratios, and other geometric factors down to the atomic level and making it useful for the design of plasmonic particles with particular strength and field distribution. The model is parameterized from experimental data and, at present, practically implementable for particles up to more than 10 nm (for nanorods even more), thus covering a significant part of the gap between the scales where pure quantum calculations are possible and where pure classical models based on the bulk dielectric constant apply. We utilized the method to both spherical and cubical clusters along with nanorods where we demonstrate both the size, shape, and ratio dependence of plasmonic excitations and connect this to the geometry of the nanoparticles using the plasmon length.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vorobyev S. A., Likhatski M. N., Romanchenko A. S., Fetisova O. Y., Kazachenko A. S., Volochaev M. N., Mikhlin Y. L.
Заглавие : Fabrication of Extremely Concentrated Silver Hydrosols without Additional Stabilizers
Место публикации : ACS Sustain. Chem. Eng. - 2020. - Vol. 8, Is. 46. - P.17225-17233. - ISSN 21680485 (ISSN), DOI 10.1021/acssuschemeng.0c06006
Примечания : Cited References: 64. - This research was supported by the Russian Science Foundation, grant 18-73-00142 (S.A.V.). We acknowledge that facilities of the Krasnoyarsk Regional Research Equipment Centre of SB RAS were employed in the work
Аннотация: Applications of silver nanoparticles (Ag NPs) in modern technologies require environmentally friendly methods of large-scale production of the nanoparticles with controlled morphology and surface state in the form of high-concentration metal sols with minimal quantities of organic stabilizers. Herein, we report a procedure based on reduction of aqueous silver nitrate with ferrous sulfate in the presence of citrate ions. We studied the effect of various factors on the chemical reaction by applying transmission electron microscopy, ultraviolet-visible absorption spectroscopy, and dynamic light scattering (DLS) and proposed protocols with reduced quantities of the reagents allowing preparation of uniform spherical Ag NPs of 5 to 15 nm in diameter. A DLS study of sols after dilution was employed to estimate the tendency of colloidal particles to interact in order to optimize post-synthetic purification and concentration procedures. Particularly, filtration instead of centrifugation and electrolytic coagulation with trisodium citrate in place of sodium nitrate were utilized to produce extremely concentrated, more than 1000 g/L Ag, and stable silver hydrosols with no additional stabilizers. The chemical, X-ray photoelectron spectroscopy, and thermogravimetric analyses demonstrated that the Ag NPs contained citrate-derived capping ligands, and low amounts of Fe are appropriated for chemical and low-temperature sintering, surface functionalization, nanofluidics, and other applications.
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13.

Вид документа : Статья из журнала
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Автор(ы) : Golovnev N. N., Molokeev M. S., Lutoshkin M. A.
Заглавие : Crystal structure of catena-(μ4-1,3-diethyl-2-thiobarbiturato-O,O’,S,S)silver(I)
Место публикации : Russ. J. Inorg. Chem.: MAIK Nauka-Interperiodica / Springer, 2015. - Vol. 60, Is. 5. - P.572-576. - ISSN 0036, DOI 10.1134/S0036023615050071. - ISSN 15318613(eISSN)
Примечания : Cited References:25
Предметные рубрики: 1,3-DIETHYL-2-THIOBARBITURIC ACID
HYDROGEN-BOND
COMPLEXES
Аннотация: The crystal structure of catena-(μ4-1,3-diethyl-2-thiobarbiturato-O,O’,S,S)silver(I) [Ag(μ4-DETBA-O,O’,S,S] (1), where HDETBA is 1,3-diethyl-2-thiobarbituric acid C8H12N2O2S, has been solved by X-ray powder diffraction. Crystals of complex 1 are monoclinic, a = 7.8339(2) Å, b = 15.4970(4) Å, c = 8.7502(2) Å, β = 111.916(2)°, V = 985.53(5) Å3, space group P21/c, Z = 4. The Ag+ ion is coordinated by two oxygen atoms and two sulfur atoms to form a distorted tetrahedron. Tetrahedra share sulfur atom vertices to form infinite chains linked via bridging DETBA− ions into a three-dimensional framework. No hydrogen bonds have been found in the structure, but π-π interaction is observed between DETBA− ions.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kononova O. N., Duba E. V., Efimova A. S., Ivanov A. I., Krylov A. S.
Заглавие : Ion exchange recovery of platinum(IV) from hydrochloric acid solutions in the presence of silver(I)
Место публикации : Russ. J. Phys. Chem. A. - 2020. - Vol. 94, Is. 4. - P.828-834. - ISSN 0036-0244, DOI 10.1134/S003602442004007X. - ISSN 1531-863X(eISSN)
Примечания : Cited References: 35
Предметные рубрики: GROUP METALS
SORPTION
PALLADIUM
RESINS
Аннотация: The ion exchange sorption of the platinum(IV) chloride complexes in the presence of silver(I) chloro complexes from 2 and 4 M aqueous solutions of hydrochloric acid is studied on Purolite anion exchangers with different functional groups. The high selectivity of the investigated sorbents with respect to platinum during its recovery from individual hydrochloric acid solutions and in the presence of silver chloride complexes is determined. Since the latter are in this case virtually not sorbed in the presence of platinum(IV), they can be separated at the stage of sorption. The excellent kinetic properties of the investigated anion exchangers are revealed, allowing platinum to be eluted after its separation from silver chloro complexes in a dynamic mode.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kononova O. N., Duba E. V., Medovikov D. V., Krylov A. S.
Заглавие : Ion-exchange sorption of palladium(II) from hydrochloric acid solutions in the presence of silver(I)
Место публикации : Russ. J. Phys. Chem. A. - 2018. - Vol. 92, Is. 10. - P.2053-2059. - ISSN 0036-0244, DOI 10.1134/S0036024418100138. - ISSN 1531-863X(eISSN)
Примечания : Cited References: 36
Предметные рубрики: PLATINUM-GROUP METALS
RECOVERY
COMPLEXES
CHLORIDE
PD(II)
Ключевые слова (''Своб.индексиров.''): palladium--silver--hydrochloric acid solutions--sorption--sorptive extraction
Аннотация: The sorptive extraction of palladium(II) chloride complexes in the presence of silver(I) chloride complexes from 2 and 4 M aqueous solutions of HCl with a series of Purolite anionites with different functional groups is studied. An anion exchange mechanism of sorption is identified from Raman spectroscopy data. Kinetic properties that are inherent to the investigated ionites and allow the elution of palladium(II) and silver(I) after their extraction in a dynamic mode are revealed.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kononova O. N., Duba E. V., Medovikov D. V., Efimova A. S., Ivanov A. I., Krylov A. S.
Заглавие : Ion-exchange sorption of silver(I) chloride complexes from aqueous HCl solutions
Место публикации : Russ. J. Phys. Chem. A. - 2017. - Vol. 91, Is. 12. - P.2383-2388. - ISSN 00360244 (ISSN), DOI 10.1134/S0036024417120135
Примечания : Cited References: 31
Ключевые слова (''Своб.индексиров.''): silver--anionites--hydrochloric acid solutions--sorption
Аннотация: The ion-exchange sorption of silver(I) chloride complexes from 1–4 M aqueous solutions of HCl on a series of Purolite anionites with various functional groups was studied. The ion-exchange equilibria in the systems were found to be anomalous according to Raman spectroscopy, which does not significantly affect the sorption properties of the ionites.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Karpov S. V., Popov A. K., Slabko V. V.
Заглавие : Photochromic reactions in silver nanocomposites with a fractal structure and their comparative characteristics
Место публикации : Tech. Phys.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2003. - Vol. 48, Is. 6. - P749-756. - ISSN 1063-7842, DOI 10.1134/1.1583830
Примечания : Cited References: 24
Предметные рубрики: SMALL-PARTICLE COMPOSITES
OPTICAL-PROPERTIES
COLLOIDAL SILVER
SELECTIVE PHOTOMODIFICATION
CLUSTERS
LIGHT
Аннотация: Conditions for a change in the polarization selectivity of dips in the plasmon absorption spectra of fractal silver nanocomposites irradiated by pulsed laser radiation are studied. The energy thresholds of the polarization selectivity are evaluated, and the polarization and spectral threshold characteristics are compared. Mechanisms behind the correlation between the fractal structure of the nanocomposites, on the one hand, and their optical and photochromic properties, on the other hand, are discussed. (C) 2003 MAIK "Nauka / Interperiodica".
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Isaenko L., Dong L., Kurus A., Lin Z., Yelisseyev A., Lobanov S., Molokeev M. S., Korzhneva K., Goloshumova A.
Заглавие : LixAg1–xGaSe2: interplay between lithium and silver in mid-infrared nonlinear optical chalcogenides
Место публикации : Adv. Opt. Mater. - 2022. - Vol. 10, Is. 24. - Ст.2201727. - ISSN 21951071 (ISSN), DOI 10.1002/adom.202201727
Примечания : Cited References: 37. - This work was supported by the National Natural Science Foundation of China (Grant No. 22133004), Russian Science Foundation, grant # 19‐12‐00085‐P (crystal growth, crystal structure analysis, band gap measurement) and partly done on state assignment of IGM SB RAS (composition chemical analysis)
Аннотация: AgGaSe2 and LiGaSe2 are two famous mid-infrared nonlinear optical (NLO) materials with similar chemical formula but different structural symmetry. The former material has relatively larger NLO effect and birefringence but rather small energy band gap, while the latter is the opposite. Aiming at achieving a good balance of NLO properties, here the substitution between silver and lithium ions on the evolution of structural and optical properties in a new series of LixAg1–xGaSe2 crystals is systematically investigated. It reveals that, with the increase of Li content, LixAg1–xGaSe2 almost keeps the same tetragonal symmetry with AgGaSe2 until x ≈ 0.9. The NLO effects and birefringence values vary with respect to x with the largest variation at x = 0.8–0.9. The optimal combination of birefringence (0.03–0.025) and nonlinear parameters (26–30 pm V−1) is achieved at x = 0.4–0.5. As the energy band gap increases with the increase of x, the maximal value of 2.2 eV for chalcopyrite structure suggests that the laser-induced damage threshold of LixAg1–xGaSe2 would be as large as five-fold of AgGaSe2. This study provides a good example to show that the rational substitution between Li and Ag can significantly improve the balance of NLO properties in chalcogenides.
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19.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Sokolov A. E., Zabluda V. N., Ovchinnikov S. G., Knyazev B. A., Gerasimov V. V., Michlin J. L., Veshnyakova E.A., Zubavichus Y. V., Kalsin A. M.
Заглавие : Magnetooptics in gold and silver nanosizes low-dimensional objects
Коллективы : "Nanomaterials: Application and Properties", International Conference (3; 16–21 Sept., 2013; Alushta, Ukraine)
Место публикации : Proc. Int. Conf. Nanomaterials: Application and Properties. - 2013. - Vol. 2, № 1. - Ст.01NFPMM06
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Popkov S. I., Semenov S. V., Bykov A. A., Shaykhutdinov K. A., Gokhfeld D. M., Petrov M. I.
Заглавие : Magnetoresistance hysteresis of bulk textured Bi1.8Pb0.3Sr1.9Ca2Cu3Ox + Ag ceramics and its anisotropy
Коллективы :
Место публикации : Physica C. - 2010. - Vol. 470, Is. 1. - P.61-67. - ISSN 0921-4534, DOI 10.1016/j.physc.2009.10.007
Примечания : Cited References: 24. - Authors thanks to I.L. Belozerova for help in preparation of textured ceramics. This work was supported by program N5 of RAS, project N7, and in part in frames of young scientist projects of Siberian Federal University, project N6.
Предметные рубрики: CRITICAL-CURRENT ANISOTROPY
HIGH-TEMPERATURE SUPERCONDUCTOR
CRITICAL-CURRENT DENSITY
MAGNETIC HYSTERESIS
TAPES
FLUX
YBA2CU3O7-DELTA
FIELD
Ключевые слова (''Своб.индексиров.''): magnetoresistance--anisotropy--scaling--magnetization--bi2223--bscco--anisotropy--bi2223--bscco--magnetization--magnetoresistance--scaling--bi-2223--bscco--external fields--granular superconductors--magnetic induction--parameters characterizing--anisotropy--calcium--ceramic materials--crystallites--electric resistance--hysteresis--lead--magnetic moments--magnetoelectronics--magnetoresistance--nanocrystalline alloys--silver--superconducting materials--superconductivity--magnetic field effects
Аннотация: Magnetoresistance of bulk textured Bi1.8Pb0.3Sr1.9Ca2Cu3Ox + Ag ceramics has been studied in the magnetic fields applied parallel and perpendicular to a-b planes of Bi2223 crystallites. Besides well known anisotropy of magnetoresistance of textured superconductors (R-H parallel to c RH parallel to a-b), anisotropic hysteresis of R(H) dependences was investigated. Parameters characterizing hysteretic R(H) curves differ for the cases H parallel to c and H parallel to a-b. This behavior is explained within the model of a granular superconductor where the total magnetic induction in the intercrystallite boundaries is superposition of the external field and the magnetic field induced by dipole magnetic moments of neighbor crystallites. (C) 2009 Elsevier B.V. All rights reserved.
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