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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrov K. S., Beznosikov B. V.
Заглавие : Crystal chemistry and prediction of compounds with a structure of skutterudite type
Место публикации : Crystallogr. Rep. - 2007. - Vol. 52, Is. 1. - P.28-36. - ISSN 1063-7745, DOI 10.1134/S106377450701004X
Примечания : Cited References: 47
Предметные рубрики: SUPERCONDUCTOR PROS4SB12
MAGNETIC-PROPERTIES
HIGH-PRESSURE
RARE-EARTH
TRANSITION
LAFE4P12
Аннотация: Crystallochemical analysis of skutterudite-type structures in the BX3, AB(4)X(12), and A B-3' B4O12 compositions (A and B are metals; X = P, As, Sb) has been performed. Probable regions of structure formation are determined, thereby indicating that more than 270 new compounds of the AB4X12 composition can be synthesized.(1)
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrov K. S., Bartolome J.
Заглавие : Structural distortions in families of perovskite-like crystals
Место публикации : Phase Transit.: TAYLOR & FRANCIS LTD, 2001. - Vol. 74, Is. 3. - P.255-335. - ISSN 0141-1594, DOI 10.1080/01411590108228754
Примечания : Cited References: 262
Предметные рубрики: LOW-TEMPERATURE PHASE
INELASTIC-NEUTRON-SCATTERING
POWDER PROFILE REFINEMENT
MII = CO
X-RAY
RAMAN-SCATTERING
ORDERED PEROVSKITE
RHOMBOHEDRAL PEROVSKITES
RB2KMIIIF6 ELPASOLITES
MAGNETIC-PROPERTIES
Ключевые слова (''Своб.индексиров.''): structural phase transitions--perovskites--perovskite-like crystals--group theoretical classification
Аннотация: The crystallographic and group theoretical analysis of the structural phase transitions in perovskite and perovskite-like crystals is reviewed. We include ABX(3) perovskites and their relative crystals of ReO3 type (G(0) = O-h(1)), elpasolites, cryolites and their relatives (G(0) = O-h(5)) layered crystals of TIAIF(4) series (G(0) = D-4h(1)), Aurivillius and Ruddlesden-Popper series (G(0) = D-4h(17)). The structures in their initial phase G(0) often contain n layers (n = 1, 2,3) of vertex linked octahedra. The distorted phases produced by one kind of tilt and by superposition of tilts in the slabs are enumerated. Most of the tilts correspond to symmetry changes, which can be associated to definite librational lattice modes irreducible representations of the G(0) group. The softening of modes associated to the PT has been found experimentally in many perovskites, elpasolites and layered crystals with n = 1. In contrast, no such soft modes have been found yet for even-layered (n = 2) crystals. Examples of successive phase transitions due to the superposition of tilts in these types of crystals have been collected.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ovchinnikov S. G., Burkova L. V., Seredkin V. A., Yakovchuk V. Y.
Заглавие : An analysis of the mechanism of Kerr effect enhancement in Mn/Dy/Bi
Место публикации : Phys. Solid State: AMER INST PHYSICS, 1999. - Vol. 41, Is. 1. - P80-86. - ISSN 1063-7834, DOI 10.1134/1.1130733
Примечания : Cited References: 35
Предметные рубрики: ELECTRONIC-STRUCTURE
THIN-FILMS
MAGNETIC-PROPERTIES
RARE-EARTH
MAGNETOOPTICAL PROPERTIES
MNBI FILMS
STABILITY
GD
Аннотация: A study is reported of the structural, magnetic, and magneto-optic properties of Mn/Dy/Bi films obtained by multilayer technology. The maximum Kerr rotation angle in such films is shown to be theta(k) = 2.25 degrees. Possible reasons for such a large Kerr effect enhancement are considered, namely, an increase in the 6p - 3d transition probability caused by symmetry distortion, polarization of the Bi6p band, and a change in the density of states near the Fermi level. The latter reason has been analyzed by simulating the electronic structure of Mn/Dy/Bi through superposition of Dy levels on the MnBi band structure. This approach has revealed possible additional transitions which may be induced by the presence of a Dy buffer and could contribute to the Kerr magneto-optic effect. (C) 1999 American Institute of Physics. [S1063=7834(99)02001-8].
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova N. B., Kazak N. V., Markov V. V., Ovchinnikov S. G., Rudenko V. V., Abd-Elmeguid M. M.
Заглавие : Analysis of the electrical and optical properties of VBO3 single crystals and Fe1-xVxBO3 solid solutions on the basis of a many-electron model of energy band structure
Место публикации : Phys. Solid State: AMER INST PHYSICS, 2004. - Vol. 46, Is. 8. - P1462-1468. - ISSN 1063-7834, DOI 10.1134/1.1788779
Примечания : Cited References: 32. - One of the authors (M.M.A.) would like to thank the Deutsche Forschungsgemeinschaft (SFB608) for financial support. This study was supported by the Russian Foundation for Basic Research (project no. 03-02-16286), the program "Integration" (project no. B0017), and the program of the Division of Physical Sciences of the Russian Academy of Sciences "Strongly Correlated Electrons"
Предметные рубрики: MAGNETIC-PROPERTIES
CALCITE STRUCTURE
PHASE-TRANSITION
FERRIC BORATE
HIGH-PRESSURE
FEBO3
FE1-XCRXBO3
FERROMAGNET
MOSSBAUER
SPECTRA
Аннотация: A many-electron model of the energy band structure of VBO3 and of Fe1 - xVxBO3 solid solutions is proposed with strong electron correlations taken into account. Experimental optical absorption spectra and data on the resistivity are discussed in the framework of the suggested model. Variation in the magnetic and electronic properties of VBO3 and Fe1 - xVxBO3 under high pressure is predicted. For VBO3, a Mott-Hubbard (insulator-metal) transition is expected in the high-pressure phase. In Fe1 - xVxBO3 solid solutions, a nontrivial variation in the properties is predicted, leading to the appearance of a different magnetic state. (C) 2004 MAIK "Nauka / Interperiodica".
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : APLESNIN S. S.
Заглавие : FORMATION OF FERROMAGNETIC ORDER IN ANISOTROPIC FRUSTRATED ANTIFERROMAGNETS
Место публикации : Fiz. Tverd. Tela: MEZHDUNARODNAYA KNIGA, 1992. - Vol. 34, Is. 2. - P554-560. - ISSN 0367-3294
Примечания : Cited References: 5
Предметные рубрики: COMPETING INTERACTIONS
MAGNETIC-PROPERTIES
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Romanova O. B., Янушкевич, Казимир Иосифович
Заглавие : Magnetoresistance effect in anion-substituted manganese chalcogenides
Место публикации : Phys. Status Solidi B. - 2015. - Vol. 252, Is. 8. - P.1792-1798. - ISSN 0370, DOI 10.1002/pssb.201451607. - ISSN 15213951 (eISSN)
Примечания : Cited References: 35. - This study was supported by the official assignment no. 114090470016.
Предметные рубрики: MAGNETIC-PROPERTIES
ELECTRONIC-STRUCTURE
SOLID-SOLUTIONS
MnTe
MnSe
CONDUCTIVITY
TRANSITION
Ключевые слова (''Своб.индексиров.''): electron tunneling--magnetic properties--magnetoresistance--semiconductors
Аннотация: The electric and magnetic properties of anion-substituted antiferromagnetic MnSe1-xTex (0.1≤x≤0.4) semiconductors in the 77-700K temperature range and magnetic fields under 1T are studied. In the MnSe1-xTex solid solutions, negative magnetoresistance in the vicinity of the Néel temperature for x=0.1 and for composition with x=0.2 in the paramagnetic range below 270K is revealed. A dependence of the magnetic susceptibility versus the prehistory of the samples is found. The model of localized spin-polarized electrons with the localization radius depending on the magnetic field is proposed for x=0.1. In the paramagnetic range, the negative magnetoresistance and the behavior of magnetic moment are a result of orbital glass formation.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S.
Заглавие : Two-particle spin-singlet excitations in coupled spin-1/2 antiferromagnetic alternating chains
Место публикации : J. Phys.: Condens. Matter: IOP PUBLISHING LTD, 2001. - Vol. 13, Is. 14. - P.3403-3410. - ISSN 0953-8984, DOI 10.1088/0953-8984/13/14/313
Примечания : Cited References: 14
Предметные рубрики: MAGNETIC-PROPERTIES
LIGHT-SCATTERING
CUGEO3
S=1/2
Ключевые слова (''Своб.индексиров.''): antiferromagnetic materials--approximation theory--chemical bonds--electron transport properties--monte carlo methods--particles (particulate matter)--quantum theory--thermal effects--antiferromagnetic alternating chains--excitation spectrum--interchain exchange--mean-field approximation--quantum monte carlo method--singlet gaps--spin-singlet excitations--energy gap
Аннотация: The spectrum of the two-particle spin-singlet (DeltaS(z) = 0, +/-1) excitations of a weakly coupled antiferromagnetic spin-1/2 alternating (J(1) +/- delta) chain is calculated using a mean-field approximation for the interchain exchange (J(2)) by the quantum Monte Carlo method. The bandwidth change of these excitations, the mass gaps in the singlet-singlet excitation spectrum, the top boundaries of the bands and the velocities of these excitations are estimated as functions of the alternating bond delta. The temperatures at which the singlet gaps close are determined.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Udod L. V., Sitnikov M. N., Shestakov N. P.
Заглавие : Bi2(Sn0.95Cr0.05)2O7: Structure, IR spectra, and dielectric properties
Место публикации : Ceram. Int.: Elsevier, 2016. - Vol. 42, Is. 4. - P.5177-5183. - ISSN 02728842 (ISSN), DOI 10.1016/j.ceramint.2015.12.040
Примечания : Cited References: 45. - This work was supported by the Russian Foundation for Basic Research Projects no. 15-42-04099 r_siberia_a, Siberian Branch of Science and NAS of Belarus “Electronic and magnetic phase transitions in materials with magnetoelectric affect” and government work no. 114090470016.
Предметные рубрики: BISMUTH PYROSTANNATE
PYROCHLORE STRUCTURE
MAGNETIC-PROPERTIES
PARTIAL OXIDATION
HIGH-TEMPERATURE
X-RAY
Bi2Sn2O7
SUBSTITUTION
CATALYSTS
DIFFRACTION
Ключевые слова (''Своб.индексиров.''): bismuth pyrostannate--infrared absorption spectra--structural transition--permittivity--debye model
Аннотация: Infrared absorption spectra of the bismuth pyrostannate Bi2(Sn0.95Cr0.05)2O7 were investigated in the frequency range 350-1100 cm-1 at temperatures of 110-525 K. Four frequency regions with split absorption lines are distinguished. Softening of frequencies at the structural transitions was observed. The maxima of permittivity measured in the frequency range 1-200 kHz at temperatures 100-400 K were determined. It was found that the magnetic susceptibility changes its sign in the low-temperature region. The correlation between anomalies in the magnetic susceptibility, permittivity, and absorption line intensity was established. Softening of frequencies is explained by the variation in the coefficient of thermal expansion of the lattice. The temperature behavior of permittivity is described using the Debye model. © 2015 Elsevier Ltd and Techna Group S.r.l.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Cazacu, Nicoleta, Chilom, Claudia G., Iftimie, Sorina, Balasoiu, Maria, Ladygina, Valentina P., Stolyar S. V., Orelovich, Oleg L., Kovalev, Yuriy S., Rogachev, Andrey V.
Заглавие : Biogenic ferrihydrite nanoparticles produced by Klebsiella oxytoca: Characterization, physicochemical properties and bovine serum albumin interactions
Место публикации : Nanomaterials. - 2022. - Vol. 12, Is. 2. - Ст.249. - ISSN 2079-4991(eISSN), DOI 10.3390/nano12020249
Примечания : Cited References: 59. - This research was funded by JINR Themes 02-1-1107-2011/2021, 04-5-1131-2017/2021 and 04-4-1133-2018/2023 and with the financial support of the RO-JINR Projects Nos. 366/11.05.2021 (items 7, 86, 97) and 365/11.05.2021 (items 8, 87 and 98). This work also benefited from the use of the SasView application, originally developed under NSF Award DMR-0520547. SasView also contains the code developed with funding from the EU Horizon 2020 program under the SINE2020 project Grant No 654000. The APC was funded by JINR Theme 02-1-1107-2011/2021, Project No. 366/11.05.2021, item 7. This study used the infrastructure of the Applied Genetics Resource Facility of MIPT (Suport Grant 075-15-2021-684)
Предметные рубрики: MAGNETIC-PROPERTIES
REDUCTION
MOSSBAUER
FERRITIN
DOCKING
BINDING
Аннотация: The synthesis of nanoparticles inside microorganisms is an economical alternative to chemical and physical methods of nanoparticle synthesis. In this study, ferrihydrite nanoparticles synthesized by Klebsiella oxytoca bacterium in special conditions were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDS), small-angle X-ray (SAXS), UV-Vis spectroscopy, fluorescence, fluorescence resonance energy transfer (FRET), and molecular docking. The morphology and the structure of the particles were characterized by means of SEM and SAXS. The elemental content was determined by means of the EDS method. The absorption properties of the ferrihydrite nanoparticles were investigated by UV-Vis spectroscopy. The binding mechanism of the biogenic ferrihydrite nanoparticles to Bovine Serum Albumin (BSA) protein, studied by fluorescence, showed a static and weak process, combined with FRET. Protein denaturation by temperature and urea in the presence of the ferrihydrite nanoparticles demonstrated their influence on the unfolding process. The AutoDock Vina and UCSF Chimera programs were used to predict the optimal binding site of the ferrihydrite to BSA and to find the location of the hydrophobic cavities in the sub-domain IIA of the BSA structure.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Anshits A. G., Bayukov O. A., Kondratenko E. V., Anshits N. N., Pletnev O. N., Rabchevskii E. V., Solovyov L. A.
Заглавие : Catalytic properties and nature of active centers of ferrospheres in oxidative coupling of methane
Коллективы : Russian Science Foundation [14-13-00289]
Место публикации : Appl. Catal. A-Gen.: Elsevier Science, 2016. - Vol. 524. - P.192-199. - ISSN 0926-860X, DOI 10.1016/j.apcata.2016.06.032. - ISSN 1873-3875(eISSN)
Примечания : Cited References:47. - This study was supported by the Russian Science Foundation (project no. 14-13-00289).
Предметные рубрики: GLASS CRYSTAL CATALYSTS
MAGNETIC-PROPERTIES
PROFILE REFINEMENT
FLY-ASH
MOSSBAUER
MICROSPHERES
PERFORMANCE
CONVERSION
ETHYLENE
OXIDE
Ключевые слова (''Своб.индексиров.''): methane coupling--active center--ferrospinel--mossbauer spectroscopy
Аннотация: Ferrospheres with the Fe2O3 content in the range from 76 to 97 wt% were applied as catalysts for the oxidative coupling of methane (OCM). To identify their phase composition and distribution of iron sites, the ferrospheres were characterized by X-ray powder diffraction and Mossbauer spectroscopy before and after the OCM reaction. Magnetite-based ferrite spinel, hematite and aluminosilicate glasses were established to be the main phases. The ferrospinel of all ferrospheres partially oxidized to hematite after the OCM reaction. It was established that the yield of C-2-hydrocarbons sharply increased at the ferrospheres with Fe2O3 content higher than 89 wt% The spinel phase of these ferrospheres includes Fevv3+(B) sites with a Ca2+ tetrahedral cation and an octahedral cation vacancy among the nearest neighbors. A linear correlation between the yield of C-2-hydrocarbons (ethane and ethylene) and the content of such sites was established, thus indicating that their electrophilic oxygen species participate in selective CH4 conversion to C2H6. (C) 2016 Elsevier B.V. All rights reserved.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Komogortsev S. V., Patrusheva T. N., Balaev D. A., Denisova E. A., Ponomarenko I. V.
Заглавие : Cobalt ferrite nanoparticles in a mesoporous silicon dioxide matrix
Коллективы : Development of the Scientific Potential of Higher Education [RNP. 2.1.1/2584]; Krasnoyarsk Regional Science Foundation; Russian Foundation for Basic Research [r-Enisei-a 03-07-96803, 09-02-98002-r_sibir'_a]
Место публикации : Tech. Phys. Lett. - 2009. - Vol. 35, Is. 10. - P.882-884. - ISSN 1063-7850, DOI 10.1134/S1063785009100022
Примечания : Cited References: 10. - This study was supported in part by the Federal Program "Development of the Scientific Potential of Higher Education" (project no. RNP. 2.1.1/2584) and jointly by the Krasnoyarsk Regional Science Foundation and the Russian Foundation for Basic Research (project nos. r-Enisei-a 03-07-96803 and 09-02-98002-r_sibir'_a).
Предметные рубрики: MAGNETIC-PROPERTIES
NANOSIZED COFE2O4
ANISOTROPY
POWDERS
CURVES
Аннотация: We have studied magnetic nanoparticles of cobalt ferrite obtained by the extraction-pyrolysis method in a mesoporous silicon dioxide (MSM-41) molecular sieve matrix. The X-ray diffraction data show evidence for the formation of CoFe(2)O(4) particles with a coherent scattering domain size of similar to 40 nm. Measurements of the magnetization curves showed that powders consisting of these nanoparticles are magnetically hard materials with a coercive field of H (c)(4.2 K) = 9.0 kOe and H (c)(300 K) = 1.8 kOe and a reduced remanent magnetization of M (r)/M (s)(4.2 K) = 0.83 and M (r)/M (s)(300 K) = 0.49. The shape of the low-temperature (4.2 K) magnetization curves is adequately described in terms of the Stoner-Wohlfarth model for randomly oriented single-domain particles with a cubic magnetic anisotropy.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ruseikina A. V., Solovyov L. A., Molokeev M. S., Andreev O. V.
Заглавие : Crystal structures of EuLnCuS3 (Ln = Nd and Sm)
Место публикации : Russ. J. Inorg. Chem.: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 57, Is. 1. - P.79-83. - ISSN 0036-0236, DOI 10.1134/S0036023612010172
Примечания : This work was supported by the Federal Target Program "Scientific and Pedagogical Personnel of Innovative Russia" for 2009-2013 (grant nos. 6K/143-09 (P 646) and NK-409/5 (P2263)) and the President of the Russian Federation (Support Program for Leading Scientific Schools of the Russian Federation, grant NSh-4645.2010.2).The results of this study have been presented at the X International Scientific Conference “Solid-State Chemistry: Nanomaterials, Nanotechnologies” (Stavropol, October 17–22, 2010) and the All-Russia Scientific Conference “Challenges of Modern Chemistry. Theory and Practice” (Ufa, October 21–23, 2010).
Предметные рубрики: RARE-EARTH
MAGNETIC-PROPERTIES
COPPER SULFIDE
CHALCOGENIDES
EUROPIUM
EU2CUS3
Аннотация: The compound sulfides EuLnCuS3 (Ln = Nd and Sm) were obtained for the first time. Their crystal structures were determined from X-ray powder diffraction data. The crystals of both compounds are orthorhombic (space group Pnma). The compound EuNdCuS3 is isostructural with BaLaCuS3; the unit cell parameters are a = 11.0438(2) Å, b = 4.0660(1) Å, c = 11.4149(4) Å. The compound EuSmCuS3 is isostructural with Eu2CuS3; the unit cell parameters are a = 10.4202(2) Å, b = 3.9701(1) Å, c = 12.8022(2) Å.
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13.

Вид документа : Статья из журнала
Шифр издания : Physics, Applied/C94
Автор(ы) : Korshunov M. M., Ovchinnikov S. G., Shneyder E. I., Gavrichkov V. A., Orlov Yu.S., Nekrasov I. A., Pchelkina Z. V.
Заглавие : Cuprates, manganites and cobaltites: Multielectron approach to the band structure
Место публикации : Mod. Phys. Lett. B: WORLD SCIENTIFIC PUBL CO PTE LTD, 2012. - Vol. 26, Is. 24. - Ст.1230016. - ISSN 0217-9849, DOI 10.1142/S0217984912300165
Примечания : Cited References: 93. - We are thankful to O. K. Andersen, V. I. Anisimov, A. F. Barabanov, K. I. Kikoin, N. M. Plakida, S. Sakai, A.-M.S. Tremblay, V. V. Val'kov, and R. O. Zaitsev for useful discussions. This work was supported by the Presisium of RAS program Quantum physics of condensed matter N 20.7, Grant "Leading scientific schools of Russia" (NSh 1044-2012.2), RFBR (Grant No. 09-02-00127), Integration Grant of SBRAS-UrBRAS N 44, Grant of President of Russia MK-1683.2010.2, FCP Scientific and Research-and-Educational Personnel of Innovative Russia for 2009-2013 (GK 16.740.12.0731 and GK 16.740.11.0740), and Siberian Federal University (Theme N F-11). M.M.K. and E.I.S. acknowledges support from The Dynasty Foundation and ICFPM.
Предметные рубрики: HIGH-TEMPERATURE SUPERCONDUCTORS
MEAN-FIELD THEORY
DENSITY-FUNCTIONAL FORMALISM
CORRELATED ELECTRON-SYSTEMS
TRANSITION-METAL COMPOUNDS
SPIN-STATE TRANSITION
T-J MODEL
MAGNETIC-PROPERTIES
COPPER OXIDES
LaCoO3
Ключевые слова (''Своб.индексиров.''): lda plus gtb method--strongly-correlated systems--band structure
Аннотация: High-T-c superconductors with CuO2 layers, manganites La1-xSrxMnO3 and cobaltites LaCoO3 present several mysteries in their physical properties. Most of them are believed to come from the strongly-correlated nature of these materials. From the theoretical viewpoint, there are many hidden rocks in making the consistent description of the band structure and low-energy physics starting from the Fermi-liquid approach. Here, we discuss the alternative method - multielectron approach to the electronic structure calculations for the Mott insulators - called LDA + GTB (local density approximation + generalized tight-binding) method. Its origin is a straightforward generalization of the Hubbard perturbation theory in the atomic limit and the multiband p - d Hamiltonian with the parameters calculated within LDA. We briefly discuss the method and focus on its applications to cuprates, manganites and cobaltites.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Poperechny I. S., Krasikov A. A., Semenov S. V., Popkov S. I., Knyazev Yu. V., Kirillov V. L., Yakushkin S. S., Martyanov O. N., Raikher Y. L.
Заглавие : Dynamic remagnetisation of CoFe2O4 nanoparticles: thermal fluctuational thawing of anisotropy
Коллективы : [AAAA-A17-117103050081-1]; [AAAAA20-120020690030-5]
Место публикации : J. Phys. D. - 2021. - Vol. 54, Is. 27. - Ст.275003. - ISSN 0022-3727, DOI 10.1088/1361-6463/abf371. - ISSN 1361-6463(eISSN)
Примечания : Cited References: 63. - Experimental measurements were supported by Project No. AAAA-A17-117103050081-1. I S P and Yu L R acknowledge the support of ICMM in the framework of topical task AAAAA20-120020690030-5. The numerical calculations were performed on the Uran supercomputer (Ural Branch, Russian Academy of Sciences, Ekaterinburg)
Предметные рубрики: COBALT-FERRITE NANOPARTICLES
MAGNETIC-PROPERTIES
SIZE
COERCIVITY
Аннотация: We report a study of the magnetodynamics of cobalt ferrite (CoFe2O4) nanoparticles with an average diameter of ~6 nm. Hysteresis loops were measured under quasi-static conditions and in pulse fields with amplitudes H0 of up to 130 kOe and for durations τP of 8 and 16 ms. The growth of coercivity Hc observed with an increase in the magnetic field variation rate dH/dt (determined by the values of H0 and τP) and the reduction of Hc with temperature is ascribed to the superparamagnetic effect. The proposed theoretical model explains the observed dependences fairly well. Notably, the effective magnetic anisotropy constant obtained exceeds the value for bulk crystals and might be indicative of the contribution of surface magnetic anisotropy.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Abramova G. M., Vorotynov A. M., Petrakovskii G. A., Kiselev N. I., Velikanov D. A., Bovina A. F., Al'mukhametov R. F., Yakshibaev R. A., Gabitov E. V.
Заглавие : Electron transition in intercalated disulfide CuCrS2
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2004. - Vol. 46, Is. 12. - P2225-2228. - ISSN 1063-7834, DOI 10.1134/1.1841385
Примечания : Cited References: 12
Предметные рубрики: METAL DICHALCOGENIDES
MAGNETIC-PROPERTIES
Аннотация: Electrical, resonant, and magnetic properties of intercalated copper chromium disulfide CuCrS2 are studied. It is established that CuCrS2 is an antiferromagnetic semiconductor with Neel temperature T-N = 40.7 K and an effective magnetic moment of 4.3mu(B). Anomalies in the electrical, magnetic, and resonant properties of CuCrS2 are found at T-c = 110 K, which suggest an electron transition accompanied by alteration of the valences of the 3d-metal ions. (C) 2004 MAIK "Nauka/Interperiodica".
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Atuchin V. V., Aleksandrovsky A. S., Chimitova O. D., Diao C. P., Gavrilova T. A., Kesler V. G., Molokeev M. S., Krylov A. S., Bazarov B. G., Bazarova J. G., Lin Z. S.
Заглавие : Electronic structure of β-RbSm(MoO4)2 and chemical bonding in molybdates
Коллективы : Ministry of Education and Science of the Russian Federation; National Natural Science Foundation of China [11174297, 11474292]; National Basic Research Project of China [2011CB922204]; Foundation of the Director of Technical Institute of Physics and Chemistry, CAS; RAS [24-29]; RFBR [13-02-00825]
Разночтения заглавия :. в WoS: Electronic structure of beta-RbSm(MoO4)2 and chemical bonding in molybdates
Место публикации : Dalton Trans.: Royal Society of Chemistry, 2015. - Vol. 44, Is. 4. - P.1805-1815. - ISSN 1477-9226, DOI 10.1039/c4dt03203a. - ISSN 1477-9234
Примечания : Cited References: 121. - VVA and ASA gratefully acknowledge the Ministry of Education and Science of the Russian Federation for financial support. ZL acknowledges the support by National Natural Science Foundation of China (11174297 and 11474292), the National Basic Research Project of China (2011CB922204), and Foundation of the Director of Technical Institute of Physics and Chemistry, CAS. The work was partially supported by RAS Project 24-29 and RFBR Grant 13-02-00825.
Предметные рубрики: RAY PHOTOELECTRON-SPECTROSCOPY
CRYSTAL-STRUCTURE
X-RAY
NEUTRON-DIFFRACTION
MAGNETIC-PROPERTIES
PHASE-FORMATION
CORE LEVELS
2ND-HARMONIC GENERATION
LUMINESCENCE PROPERTIES
VIBRATIONAL PROPERTIES
Аннотация: Microcrystals of orthorhombic rubidium samarium molybdate, beta-RbSm(MoO4)(2), have been fabricated by solid state synthesis at T = 450 degrees C, 70 h, and at T = 600 degrees C, 150 h. The crystal structure has been refined by the Rietveld method in space group Pbcn with cell parameters a = 5.0984(2), b = 18.9742(6) and c = 8.0449(3) angstrom (R-B = 1.72%). Thermal properties of beta-RbSm(MoO4)(2) were traced by DSC over the temperature range of T = 20-965 degrees C, and the earlier reported β ↔ α phase transition at T similar to 860-910 degrees C was not verified. The electronic structure of beta-RbSm(MoO4) 2 was studied by employing theoretical calculations and X-ray photoelectron spectroscopy. It has been established that the O 2p-like states contribute mainly to the upper part of the valence band and occupy the valence band maximum, whereas the Mo 4d-like states contribute mainly to the lower part of the valence band. Chemical bonding effects have been analysed from the element core level binding energy data. In addition, it was found that the luminescence spectrum of beta-RbSm(MoO4)(2) is rather peculiar among the Sm3+ containing materials. The optical refractive index dispersion in beta-RbSm(MoO4)(2) was also predicted by the first-principles calculations.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vorotynov A. M., Petrakovskii G. A., Sablina K. A., Bovina A. F., Vasil'ev A. D.
Заглавие : EPR study of the Jahn-Teller effect of Cu2+ ions in ZnGa2O4
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2010. - Vol. 52, Is. 11. - P2415-2418. - ISSN 1063-7834, DOI 10.1134/S1063783410110314
Примечания : Cited References: 12
Предметные рубрики: MAGNETIC-PROPERTIES
PARTICLES
CUFE2O4
Аннотация: The Jahn-Teller effect in the ZnGa2O4 spinel single crystal has been investigated using electron paramagnetic resonance of Cu2+ ions in the temperature range 110-560 K. It has been shown that copper ions occupy octahedral sites 16d in the ZnGa2O4 crystal with cubic symmetry O (h) (7) (Fd-3m). At T 560 K, the octahedra undergo tetragonal distortions (predominantly tension) and rotation around the fourfold axes by the angle theta a parts per thousand 2.6A degrees. The parameters of the spin Hamiltonian, which characterize the prolate (g (aEuro-)
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Melchakova I., Kovaleva E. A., Mikhaleva, Natalia S., Tomilin F. N., Ovchinnikov S. G., Kuzubov A. A., Avramov P. V.
Заглавие : External electric field effect on electronic properties and charge transfer in CoI2/NiI2 spinterface
Коллективы : Ministry of Education and Science of the Russian FederationMinistry of Education and Science, Russian Federation [16.1455.2017/PCh]; National Research Foundation of KoreaNational Research Foundation of Korea [NRF-2017R1A2B4004440]; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science [18-43-243011]
Место публикации : Int. J. Quantum Chem. - 2020. - Vol. 120, Is. 3. - Ст.e26092. - ISSN 0020-7608, DOI 10.1002/qua.26092. - ISSN 1097-461X(eISSN)
Примечания : Cited References: 27. - Ministry of Education and Science of the Russian Federation, Grant/Award Number: 16.1455.2017/PCh; National Research Foundation of Korea, Grant/Award Number: NRF-2017R1A2B4004440; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, Grant/Award Number: 18-43-243011
Предметные рубрики: MAGNETIC-PROPERTIES
METAL
EDGE
Аннотация: Electronic structure and spin-related properties of CoI2/NiI2 heterostructure were studied by means of density functional theory. It was shown that the electronic structure at the Fermi level can be characterized by a band gap. The effect of the external electric field on charge transfer and electronic properties of the CoI2/NiI2 interface was investigated, and it was found that band gap width depends on the strength of the applied electric field, switching its nature from semiconducting to a half-metallic one. An easy control of the electronic properties and promising spin-polarized nature of the CoI2/NiI2 spinterface allows the heterostructure to be used in spin-related applications.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Iskhakov R. S., Komogortsev S. V., Balaev A. D., Okotrub A. V., Kudashov A. G., Kuznetsov V. L., Butenko Y. V.
Заглавие : Fe nanowires in carbon nanotubes as an example of a one-dimensional system of exchange-coupled ferromagnetic nanoparticles
Место публикации : JETP Letters. - 2003. - Vol. 78, Is. 4. - P.236-240. - ISSN 0021-3640, DOI 10.1134/1.1622038
Примечания : Cited References: 38
Предметные рубрики: MAGNETIC-PROPERTIES
RANDOM ANISOTROPY
ELECTRODEPOSITED NANOWIRES
NI NANOWIRES
ARRAYS
NANOCRYSTALLINE
ALUMINA
NICKEL
PORES
STATE
Аннотация: The cooperative phenomena revealed in the field and temperature dependences of the magnetization in a system of iron nanoparticles in carbon nanotubes were studied experimentally. The character of the temperature dependences of the magnetization indicates that the ferromagnetic Fe particles in carbon nanotubes are exchange-coupled. In the region where the magnetization approaches saturation, the magnetization curves reveal the power dependence DeltaM similar to H-3/2 typical for a one-dimensional system of exchange-coupled ferromagnetic nanoparticles. (C) 2003 MAIK "Nauka / Interperiodica".
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stolyar S. V., Balaev D. A., Ladygina V. P., Pankrats A. I., Yaroslavtsev R. N., Velikanov D. A., Iskhakov R. S.
Заглавие : Ferromagnetic resonance study of biogenic ferrihydrite nanoparticles: spin-glass state of surface spins
Место публикации : JETP Letters. - 2020. - Vol. 111, Is. 3. - P.183-187. - ISSN 0021-3640, DOI 10.1134/S0021364020030145. - ISSN 1090-6487(eISSN)
Примечания : Cited References: 41. - This work was supported by the Russian Foundation for Basic Research, project no. 18-02-40137.This work was supported by the Russian Foundation for Basic Research, by the Government of Krasnoyarsk krai, by the Krasnoyarsk Regional Fund for the Support of Scientific and Technical Activities (project no. 19-42-240012 r_a “Magnetic Resonance in Ferrihydrite Nanoparticles: Effects Associated with the Core-Shell Structure”), and by the Council of the President of the Russian Federation for State Support of Young Scientists and Leading Scientific Schools (project no. MK-1263.2020.3).
Предметные рубрики: MAGNETIC-PROPERTIES
NIO NANOPARTICLES
TRANSITION
ANISOTROPY
Аннотация: Ferrihydrite nanoparticles (2–3 nm in size), which are products of the vital activity of microorganisms, are studied by the ferromagnetic resonance method. The “core” of ferrihydrite particles is ordered antiferromagnetically, and the presence of defects leads to the appearance of an uncompensated magnetic moment in nanoparticles and the characteristic superparamagnetic behavior. It is established from the ferromagnetic resonance data that the field dependence of the frequency is described by the expression 2πν/γ = HR + H A(T=0) (1 − T/T*), where γ is the gyromagnetic ratio, HR is the resonance field, HA ≈ 7 kOe, and T* ≈ 50 K. The induced anisotropy HA is due to the spin-glass state of the near-surface regions.
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