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1.


   
    Magnetic Resonance Imaging of Water Absorption by Highly Porous Ceramic Materials / E. V. Morozov [et al.] // Dokl. Chem. - 2019. - Vol. 484, Is. 2. - P. 44-47, DOI 10.1134/S0012500819020058. - Cited References: 9. - The studies were performed using equipment of KRTsKP FITs "KNTs SO RAN" in the framework of the program of basic research of the Russian Academy of Sciences (project no. V.44.1.7.) regarding the development of the MRI methodology for studying composite and porous materials, and also supported by the Russian Foundation for Basic Research (project no. 16-29-05334ofi_m "Scientific foundations for creating thin-film coatings with controlled wettability") regarding the development of water-repellent porous materials. . - ISSN 0012-5008
Кл.слова (ненормированные):
magnetic resonance imaging -- porosity -- ceramic materials -- hydrophobic coatings -- adsorption -- capillary phenomena
Аннотация: A nontrivial character of water absorption in highly porous ceramic materials has been demonstrated for the first time by magnetic resonance imaging: a phenomenon of hygroscopic memory has been detected consisting in the concentration of adsorbed water in certain areas inside the sample, repeated during subsequent wetting with water. It has been shown that hydrophobization of the material by applying fluoro paraffin coatings to oxide fibers using the method of dissolution of fluoropolymers in supercritical CO2 has a significant impact on the transport of water into products and can be considered an efficient means of protecting porous materials from moisture. The results demonstrate the capabilities of the MRI method in studying the water absorption and identifying water migration pathways in highly porous materials.

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Публикация на русском языке Магнитно-резонансная томография водопоглощения высокопористыми керамическими материалами [Текст] / Е. В. Морозов [и др.] // Докл. Акад. наук. - 2019. - Т. 484 № 5. - С. 563-567

Держатели документа:
Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Kirenskii Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
All-Russian Research Institute of Aviation Materials, Moscow, 105005, Russian Federation
Gubkin State University of Oil and Gas, Moscow, 119991, Russian Federation

Доп.точки доступа:
Morozov, E. V.; Морозов, Евгений Владимирович; Buznik, V. M.; Bespalov, A. S.; Grashchenkov, D. V.
}
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2.


   
    Magnetic circular dichroism and absorption spectra of 5I8 → 5F5 transition in HoAl3(BO3)4 and HoFe3(BO3)4 single crystals / A. V. Malakhovskii [et al.] // Phys. Lett. A. - 2019. - Vol. 383, Is. 16. - P. 1960-1966, DOI 10.1016/j.physleta.2019.03.016. - Cited References: 34. - The work was supported by the Russian Foundation for Basic Researches grant 19-02-00034. . - ISSN 0375-9601
Кл.слова (ненормированные):
Ho3+ ion -- f-f transitions -- Magnetic circular dichroism -- Electron structure
Аннотация: Comparative study of magnetic circular dichroism (MCD) and absorption spectra of HoAl3(BO3)4 and HoFe3(BO3)4 single crystals in the region of 5I8 → 5F5 transition of the Ho3+ ion was carried out. Absorption spectra were decomposed into the Lorentz shape components and intensities of transitions were obtained. Unusually strong vibronic transitions were observed in HoAl3(BO3)4, but were not observed in HoFe3(BO3)4 that testified to the strong non diagonal vibronic interaction in HoAl3(BO3)4. The MCD spectra were analyzed in approximation of the ∣J,± MJ≻ of the wave functions of the free atom and using concept of the crystal quantum number. Peculiarity of application of this concept to ions with integer moments was revealed and modification of the concept was suggested. With the help of the MCD spectra, the Zeeman splitting of some transitions was found. In particular, the Landé factor gC ≈2 of the ground state of the Ho3+ ion in HoAl3(BO3)4 in the trigonal axis direction was determined. It appeared to be five times less than that in HoFe3(BO3)4 also found with the help of the MCD.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sokolov, V. V.; Соколов, Валерий Владимирович; Gudim, I. A.; Гудим, Ирина Анатольевна; Rautskii, M. V.; Рауцкий, Михаил Владимирович
}
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3.


   
    Element selective magnetism in Ho0.5Nd0.5Fe3(BO3)4 single crystal probed with hard X-ray magnetic circular dichroism / M. Platunov [et al.] // J. Magn. Magn. Mater. - 2019. - Vol. 479. - P. 312-316, DOI 10.1016/j.jmmm.2019.02.040. - Cited References: 40. - The study was supported in part by the grants of the Russian Foundation for Basic Research (project Nos. 16-32-60049, 17-02-00826, 18-42-243007) and the Foundation for Assistance to Small Innovative Enterprises (FASIE, UMNIK program). The magnetic measurements were carried out in the Shared Facility Centre of P.N. Lebedev Physical Institute of RAS. We are grateful to Dr. Alexey Bosak for providing assistance of the structural experiments on the ID28 beamline. We are also grateful to Dr. Evgeniy Eremin from Kirensky Institute of Physics for providing the results of magnetic measurements and for useful discussions. The authors thank the ID12 beamline staffs for help during the XMCD experiment and also gratefully acknowledge the beamtime provision (proposal HC-1804) by the ESRF. . - ISSN 0304-8853. - ISSN 1873-4766
РУБ Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
MICROSTRUCTURE
   TRANSITIONS

   ND

Кл.слова (ненормированные):
X-ray magnetic circular dichroism -- X-ray absorption -- Magnetic properties
Аннотация: We present a study of a Ho0.5Nd0.5Fe3(BO3)4 single crystal aiming at understanding the roles of each magnetic sublattices in magnetic transitions at low temperatures. The crystal structure is determined to have the R32 symmetry in whole studied temperature range but the crystal appears to be racemic. Element selective magnetic properties studied with X-ray magnetic circular dichroism at the L2,3-edges of Ho and Nd, and at the Fe K-edge at T = 3 K under magnetic fields of ±17 T are compared with the results of macroscopic magnetization measurements in pure and substituted crystals. All three magnetic sublattices are shown to be strongly coupled and to undergo a spin-reorientation transition when magnetic field is applied along the trigonal c-axis. On the contrary, when magnetic field is applied in the ab-plane only the holmium atoms exhibit a sizeable magnetization jump. This result allows us to conclude that the spin-flop transitions observed in macroscopic magnetization curves and associated anomalies of electric polarization are due to the Ho3+ magnetic moment reorientation.

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Держатели документа:
RAS, Fed Res Ctr KSC SB, Kirensky Inst Phys, Akademgorodok 50,Bld 38, Krasnoyarsk 660036, Russia.
European Synchrotron, ESRF, 71 Ave Martyrs CS40220, F-38043 Grenoble 9, France.
Swiss Norwegian Beamlines ESRF, 71 Ave Martyrs CS40220, F-38043 Grenoble 9, France.
RAS, PN Lebedev Phys Inst, Moscow 119991, Russia.

Доп.точки доступа:
Platunov, M. S.; Платунов, Михаил Сергеевич; Kazak, N. V.; Казак, Наталья Валерьевна; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна; Knyazev, Yu. V.; Князев, Юрий Владимирович; Gavrilkin, S. Yu.; Dyadkin, Vadim; Dovgaliuk, Iurii; Chernyshov, Dmitry; Hen, Amir; Wilhelm, Fabrice; Rogalev, Andrei; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Russian Foundation for Basic Research [16-32-60049, 17-02-00826, 18-42-243007]; Foundation for Assistance to Small Innovative Enterprises (FASIE, UMNIK program)
}
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4.


   
    Broadband Tamm plasmon polariton / A. M. Vyunishev [et al.] // J. Opt. Soc. Am. B. - 2019. - Vol. 36, Is. 8. - P. 2299-2305, DOI 10.1364/JOSAB.36.002299. - Cited References: 50. - Russian Foundation for Basic Research (RFBR) (18-32-00053); Grant of the President of the Russian Federation (MK-2761.2019.2). . - ISSN 0740-3224. - ISSN 1520-8540
   Перевод заглавия: Широкополосный таммовский плазмон-поляритон
РУБ Optics
Рубрики:
PHOTONIC CRYSTAL
   OPTICAL-CONSTANTS

   PERFECT ABSORBER

   ABSORPTION

Аннотация: A broadband Tamm plasmon polariton localized at the interface between the Bragg mirror and a thin metallic layer has been theoretically and experimentally investigated. The possibility of a localized state formation has been demonstrated and energy coefficients at the Tamm plasmon polariton wavelength have been predicted in the framework of the coupled mode theory. The metallic layer material and thickness corresponding to the maximum coupling between the incident radiation and the Tamm plasmon polariton has been determined. Experimental reflectance and transmittance spectra of the structure consisting of the Bragg mirror and chromium layers of different thicknesses have been measured. The analysis of the energy spectra shows the existence of the wavelength range with the near-unity absorption coefficient inside the Bragg mirror bandgap. The use of chromium as a metal results in the broadband Tamm plasmon polariton excitation. It is demonstrated that the experimental data is in a good agreement with the calculation.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Moscow MV Lomonosov State Univ, Dept Phys, Moscow 119991, Russia.
Skolkovo Inst Sci & Technol, Ctr Design Mfg & Mat, 3 Nobel St, Moscow 143026, Russia.

Доп.точки доступа:
Vyunishev, A. M.; Вьюнышев, Андрей Михайлович; Bikbaev, R. G.; Бикбаев, Рашид Гельмединович; Svyakhovskiy, Sergey E.; Timofeev, I. V.; Тимофеев, Иван Владимирович; Pankin, P. S.; Панкин, Павел Сергеевич; Evlashin, Stanislav A.; Vetrov, S. Ya.; Ветров, Степан Яковлевич; Myslivets, S. A.; Мысливец, Сергей Александрович; Arkhipkin, V. G.; Архипкин, Василий Григорьевич; Russian Foundation for Basic Research (RFBR) [18-32-00053]; Russian Federation [MK-2761.2019.2]
}
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5.


   
    IR-range photoinduced diode effect in the manganese-substituted bismuth ferrite films / S. S. Aplesnin [et al.] // Semicond. Sci. Technol. - 2019. - Vol. 34, Is. 9. - Ст. 095007, DOI 10.1088/1361-6641/ab3160. - Cited References: 45. - The reported study was funded by RFBR according to the research project No 18-52-00009 Bel_ a; No 18-32-00079 mol_ a and Belarusian Foundation project No F18R-084. The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science No 18-42-240001 r_ a, to the research project: "Inversion of the sign of the components of the magnetoelectric tensor on the temperature in films of bismuth garnet ferrite replaced by neodymium". This work is part of the research program the state order No 3.5743.2017/6.7. . - ISSN 0268-1242. - ISSN 1361-6641
РУБ Engineering, Electrical & Electronic + Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
POOLE-FRENKEL CONDUCTION
   BIFEO3 FILMS

   LIGHT

Кл.слова (ненормированные):
multiferroic -- films -- diode effect -- polarization -- I-V characteristics -- optical absorption
Аннотация: The photoinduced diode effect has been found in BiMnxFe1-xO3 (0 < X < 0.15) films in the near-infrared and violet spectral ranges in a wide temperature interval. The dependences of the diode effect on temperature, wavelength, and illumination power have been established. The mechanism of the ferroelectric diode has been determined using its I-V characteristics at different illumination powers, optical spectra, far-infrared absorption spectra, and electric polarization hysteresis. The interplay between the photodiode effect and conductivity mechanism has been elucidated. The model of strong Coulomb potential fluctuations and quantum well asymmetry caused by the electric polarization in the film and difference between the times of carrier thermalization and recombination of electrons and holes is proposed.
В пленках феррита висмута BiMnxFe1-xO3 (0< x < 0.15) обнаружен фотоиндуцированный диодный эффект в ближней инфракрасной и фиолетовой областях спектра в широкой области температур. Определена зависимость диодного эффекта от температуры, длины волны, мощности освещения. Механизм ферроэлектрического диода определяется из вольт-амперных характеристик при разных интенсивностях освещения, оптических спектров и спектров поглощения в дальней ИК области, гистерезиса электрической поляризации. Устанавливается связь фотодиодного эффекта с механизмом проводимости. Предложена модель сильных флуктуаций кулоновского потенциала, асимметрия квантовых ям в результате наличия электрической поляризации в пленке и отличие времен термолизации носителей тока и рекомбинации электронов и дырок.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk, Russia.
Reshetnev Siberian State Univ Sci & Technol, Krasnoyarsk, Russia.
Siberian Fed Univ, Krasnoyarsk, Russia.
Sci Pract Mat Res Ctr NAS Belarus, Minsk, BELARUS.

Доп.точки доступа:
Aplesnin, S. S.; Аплеснин, Сергей Степанович; Kretinin, V. V.; Masyugin, A. N.; Romanova, O. B.; Романова, Оксана Борисовна; Sitnikov, M. N.; Begisheva, O. B.; Galyas, A., I; Demidenko, O. F.; Yanushkevich, K., I; RFBR [18-52-00009 Bel_ a, 18-32-00079 mol_ a]; Belarusian Foundation [F18R-084]; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science [18-42-240001 r_ a]; [3.5743.2017/6.7]
}
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6.


   
    Nuclear dynamics in resonant inelastic X-ray scattering and X-ray absorption of methanol / V. V. da Cruz [et al.] // J. Chem. Phys. - 2019. - Vol. 150, Is. 23. - Ст. 234301, DOI 10.1063/1.5092174. - Cited References: 80. - We acknowledge Emelie Ertan for sharing insights into performing the RASPT2 calculations. This work was supported by the Swedish Research Council (Nos. VR 2015-04510, 2015-03781, 2015-03956, and 2016-03619), the Knut and Alice Wallenberg Foundation (Grant No. KAW-2013.0020), Carl Tryggers Foundation, and within the State Contract of the Ministry of Education and Science of the Russian Federation for Siberian Federal University for Scientific Research in 2017-2019 (Project No. 3.2662.2017). V.V.C. and R.C.C. acknowledge the Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (No. CNPq 234625/2014-7). A.F. acknowledges support by the European Research Council Advanced Grants 2014 Advanced Investigator Grant No. 669531 EDAX under the Horizon 2020 European Union Framework Program for Research and Innovation. M.O. acknowledges support from the Helmholtz Virtual Institute VI419 "Dynamic Pathways in Multidimensional Landscapes." Numerical simulations were performed on the resources provided by the Swedish National Infrastructure for Computing (SNIC 2018/3-104, 023/07-18). The experimental RIXS data were obtained at the ADRESS beamline of the Swiss Light Source at the Paul Scherrer Institut. . - ISSN 0021-9606. - ISSN 1089-7690
РУБ Chemistry, Physical + Physics, Atomic, Molecular & Chemical
Рубрики:
MANY-BODY THEORY
   VIBRATIONAL STRUCTURE

   LIQUID METHANOL

Аннотация: We report on a combined theoretical and experimental study of core-excitation spectra of gas and liquid phase methanol as obtained with the use of X-ray absorption spectroscopy (XAS) and resonant inelastic X-ray scattering (RIXS). The electronic transitions are studied with computational methods that include strict and extended second-order algebraic diagrammatic construction [ADC(2) and ADC(2)-x], restricted active space second-order perturbation theory, and time-dependent density functional theory—providing a complete assignment of the near oxygen K-edge XAS. We show that multimode nuclear dynamics is of crucial importance for explaining the available experimental XAS and RIXS spectra. The multimode nuclear motion was considered in a recently developed “mixed representation” where dissociative states and highly excited vibrational modes are accurately treated with a time-dependent wave packet technique, while the remaining active vibrational modes are described using Franck–Condon amplitudes. Particular attention is paid to the polarization dependence of RIXS and the effects of the isotopic substitution on the RIXS profile in the case of dissociative core-excited states. Our approach predicts the splitting of the 2a″ RIXS peak to be due to an interplay between molecular and pseudo-atomic features arising in the course of transitions between dissociative core- and valence-excited states. The dynamical nature of the splitting of the 2a″ peak in RIXS of liquid methanol near pre-edge core excitation is shown. The theoretical results are in good agreement with our liquid phase measurements and gas phase experimental data available from the literature.

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Держатели документа:
KTH Royal Inst Technol, Dept Theoret Chem & Biol, S-10691 Stockholm, Sweden.
Univ Potsdam, Inst Phys & Astron, Karl Liebknecht Str 24-25, D-14476 Potsdam, Germany.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Uppsala Univ, Dept Phys & Astron, Box 516, SE-75120 Uppsala, Sweden.
Univ Turku, Dept Phys & Astron, FI-20014 Turun, Finland
Helmholtz Zentrum Berlin Mat & Energie, Inst Methods & Instrumentat Synchrotron Radiat Re, Albert Einstein Str 15, D-12489 Berlin, Germany.
Paul Scherrer Inst, Photon Sci Div, CH-5232 Villigen, Switzerland.
Stockholm Univ, AlbaNova Univ Ctr, Dept Phys, S-10691 Stockholm, Sweden.

Доп.точки доступа:
da Cruz, V. V.; Ignatova, N.; Игнатова Н. Ю.; Couto, R. C.; Fedotov, D. A.; Rehn, D. R.; Savchenko, V.; Савченко В.; Norman, P.; Agren, H.; Polyutov, S. P.; Полютов, Сергей Петрович; Niskanen, J.; Eckert, S.; Jay, R. M.; Fondell, M.; Schmitt, T.; Pietzsch, A.; Fohlisch, A.; Gel'mukhanov, F.; Гельмуханов, Фарис Хафизович; Odelius, M.; Kimberg, V.; Кимберг, Виктор Валерьевич; Swedish Research Council [VR 2015-04510, 2015-03781, 2015-03956, 2016-03619]; Knut and Alice Wallenberg Foundation [KAW-2013.0020]; Carl Tryggers Foundation; Conselho Nacional de Desenvolvimento Cientifico e Tecnologico [CNPq 234625/2014-7]; European Research Council under the European Union [669531 EDAX]; Helmholtz Virtual Institute "Dynamic Pathways in Multidimensional Landscapes" [VI419]; Swedish National Infrastructure for Computing [SNIC 2018/3-104, 023/07-18]; Ministry of Education and Science of the Russian Federation [3.2662.2017]
}
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7.


   
    Temperature-dependent absorption lines observation in Raman spectra of SmFe3 (BO3)4 ferroborate / E. Moshkina [et al.] // J. Raman Spectrosc. - 2018. - Vol. 49, Is. 10. - P. 1732-1735, DOI 10.1002/jrs.5430. - Cited References: 12. - RFBR, Grant/Award Numbers: 18-02-00696 and 18-02-00754 . - ISSN 0377-0486. - ISSN 1097-4555
   Перевод заглавия: Температурно зависимые линии поглощения в спектрах комбинационного рассеяния ферробората SmFe3(BO3)4
РУБ Spectroscopy
Рубрики:
SmFe3 (BO3)4
   Ho1-xNdxFe3(BO3)4

   CRYSTALS

Кл.слова (ненормированные):
absorption -- ferroborates -- huntite -- level splitting -- magnetic phase -- transitions
Аннотация: The paper demonstrates possibilities of observation and thermal dependency study of the absorption lines as a co‐product of Raman spectroscopy study in SmFe3 (BO3)4 ferroborate. Raman spectra of the ferroborate were studied in a wide temperature range (T = 10÷300 K). Temperature‐dependent absorption lines sensitive to the magnetic phase transition have been observed in Raman spectra at two spectral ranges.

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Держатели документа:
RAS, Fed Res Ctr KSC SB, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian State Univ Sci & Technol, Krasnoyarsk, Russia.

Доп.точки доступа:
Moshkina, E. M.; Мошкина, Евгения Михайловна; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович; Krylov, A. S.; Крылов, Александр Сергеевич; RFBR [18-02-00696, 18-02-00754]
}
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8.


   
    Спектр СВЧ резонансного поглощения в аморфных микропроволоках на основе кобальта / И. Г. Важенина [и др.] // Магнитные материалы. Новые технологии : тез. докл. VIII Байкал. междунар. конф. BICMM-2018 / чл. прогр. ком. R. S. Iskhakov [et al.]. - Иркутск, 2018. - С. 170-171. - Библиогр.: 3 . - ISBN 978-5-00133-051-6
   Перевод заглавия: Microwave frequency resonance absorption spectrum of amorphous Co-based microwire

РИНЦ,
Материалы конференции,
Материалы конференции,
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Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Iskhakov, R. S. \чл. прогр. ком.\; Исхаков, Рауф Садыкович; Ovchinnikov, S. G. \чл. прогр. ком.\; Овчинников, Сергей Геннадьевич; Aplesnin, S. S. \чл. прогр. ком.\; Аплеснин, Сергей Степанович; Balaev, D. A. \чл. прогр. ком.\; Балаев, Дмитрий Александрович; Важенина, Ирина Георгиевна; Vazhenina, I. G.; Комогорцев, Сергей Викторович; Komogortsev, S. V.; Iskhakov, R. S.; Рауцкий, Михаил Владимирович; Rautskii, M. V.; Незнахин, Д. С.; Гаврилюк, Алексей Александрович; Немцев, Иван Васильевич; Nemtsev, I. V.; Байкальская международная конференция "Магнитные материалы. Новые технологии"(8 ; 2018 ; авг. ; 24-28 ; Иркутск); "Магнитные материалы. Новые технологии", Байкальская международная конференция(8 ; 2018 ; авг. ; 24-28 ; Иркутск); "Magnetic materials. New tecnologies", Baikal International Conference(8 ; 2018 ; Aug. 24-28 ; Irkutsk); Иркутский государственный университет
}
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9.


    Arkhipkin, V. G.
    One- and two-dimensional Raman-induced diffraction gratings in atomic media / V. G. Arkhipkin, S. A. Myslivets // Phys. Rev. A. - 2018. - Vol. 98, Is. 1. - Ст. 013838, DOI 10.1103/PhysRevA.98.013838. - Cited References: 37 . - ISSN 2469-9926. - ISSN 2469-9934
РУБ Optics + Physics, Atomic, Molecular & Chemical
Рубрики:
ELECTROMAGNETICALLY INDUCED TRANSPARENCY
   COLD ATOMS

   ABSORPTION

Аннотация: We propose and analyze an efficient scheme for the one- and two-dimensional atomic gratings based on periodic spatial modulation of the Raman gain and dispersion, which we name the Raman-induced diffraction gratings (RIDGs). There are fundamentally different from those based on electromagnetically induced transparency. As the probe field propagates along the direction normal to the standing pump wave, it can be effectively diffracted into high-order directions. The grating is a hybrid grating, i.e. it represents a mixture of amplitude and phase gratings. We identify the conditions when all high-order diffractions are amplified. In addition, we also show that diffraction of a probe field could be dynamically controlled using an additional laser field. With its help, it is possible to suppress or amplify diffraction beams. The RIDGs can be considered as all-optical multibeam splitters with amplification.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Inst Engn Phys & Radioelect, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Myslivets, S. A.; Мысливец, Сергей Александрович; Архипкин, Василий Григорьевич
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10.


   
    Study of Peculiarities of the Microwave Absorption Spectrum of Nanocrystalline Thin Magnetic Films / B. A. Belyaev [et al.] // Russ. Phys. J. - 2019. - Vol. 61, Is. 10. - P. 1798-1805, DOI 10.1007/s11182-019-01603-4. - Cited References: 22. - This work was supported by the Ministry of Education and Science of the Russian Federation, project No. RFMEFI60417X0179. . - ISSN 1064-8887. - ISSN 1573-9228
Рубрики:
MICROMAGNETIC CALCULATION
   SIMULATIONS

   PARTICLES

   MODES

Кл.слова (ненормированные):
micromagnetic modeling -- nanocrystallites -- random magnetic anisotropy -- ferromagnetic resonance -- microwave
Аннотация: Based on the micromagnetic model which takes into account the random distribution of the uniaxial magnetic anisotropy directions in crystallites of a nanocrystalline film, an effective method has been implemented for calculation of the magnetization dynamics in microwave fields. For a certain range of crystallite sizes, when the energy of the random magnetic anisotropy is comparable to the exchange energy, a significant change of the ferromagnetic resonance field, broadening of the resonance line, and the appearance of an asymmetry in the shape of the resonance curve were found. With an increase of the crystallite sizes, the resonance field first grows, then, it quickly decreases to its minimum, and then, it grows again to reach saturation. In this case, the steepness of the left slope of the broadening resonance curve first decreases faster than that of the right slope, leading to the symmetry breaking of the resonance curve shape, then, the curve becomes symmetrical again, and then, the steepness of the left slope becomes greater than that of the right slope.

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Публикация на русском языке Исследование особенностей спектра СВЧ-поглощения нанокристаллических тонких магнитных пленок [Текст] / Б. А. Беляев [и др.] // Изв. вузов. Физика. - 2018. - Т. 61 № 10. - С. 50-56

Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Fed Res Ctr KSC, Siberian Branch, Krasnoyarsk, Russia.
Siberian Fed Univ, Krasnoyarsk, Russia.

Доп.точки доступа:
Belyaev, B. A.; Беляев, Борис Афанасьевич; Boev, N. M.; Боев, Никита Михайлович; Izotov, A. V.; Изотов, Андрей Викторович; Solovev, P. N.; Соловьев, Платон Николаевич; Ministry of Education and Science of the Russian Federation [RFMEFI60417X0179]
}
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11.


    Bikbaev, R. G.
    Epsilon-Near-Zero Absorber by Tamm Plasmon Polariton / R. G. Bikbaev, S. Y. Vetrov, I. V. Timofeev // Photonics. - 2019. - Vol. 6, Is. 1. - Ст. 28, DOI 10.3390/photonics6010028. - Cited References: 45. - This research was funded by RFBR according to the research project No. 18-32-00053. I.V.T. and S.Y.V. acknowledge financial support from RFBR and MOST according to the research project No. 19-52-52006. . - ISSN 2304-6732
РУБ Optics
Рубрики:
PERFECT ABSORPTION
   PHOTONIC CRYSTAL

   PROPAGATION

   LIGHT

Кл.слова (ненормированные):
photonic crystal -- nanocomposite -- epsilon near-zero material -- Tamm plasmon polariton
Аннотация: Two schemes of excitation of a Tamm plasmon polariton localized at the interface between a photonic crystal and a nanocomposite with near-zero effective permittivity have been investigated in the framework of the temporal coupled-mode theory. The parameters of the structure have been determined, which correspond to the critical coupling of the incident field with a Tamm plasmon polariton and, consequently, ensure the total absorption of the incident radiation by the structure. It has been established that the spectral width of the absorption line depends on the scheme of Tamm plasmon polariton excitation and the parameters of a nanocomposite film. The features of field localization at the Tamm plasmon polariton frequency for different excitation schemes have been examined. It has been demonstrated that such media can be used as narrowband absorbers based on Tamm plasmon polaritons localized at the interface between a photonic crystal and a nanocomposite with near-zero effective permittivity.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Vetrov, S. Ya.; Ветров, Степан Яковлевич; Timofeev, I. V.; Тимофеев, Иван Владимирович; Бикбаев, Рашид Гельмединович; RFBR; MOST [19-52-52006]
}
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12.


   
    FTIR spectroscopy of early and latewood of Larix gmelinii growing along the polar treeline: the correlation between absorption bands and climatic factors / E. A. Tyutkova, S. R. Loskutov, N. P. Shestakov // Wood Mater. Sci. Eng. - 2020. - Vol. 15, Is. 4. - P. 205-212, DOI 10.1080/17480272.2018.1562495. - Cited References: 33 . - ISSN 1748-0272
Кл.слова (ненормированные):
Spectral analysis -- wood -- annual rings -- cellulose -- hemicellulose -- weather conditions
Аннотация: This paper presents the results of FTIR spectroscopy of the 1988–1998 annual ring early and latewood of Larix gmelinii (Rupr.) Rupr.) found along the polar treeline (Taimyr Peninsula, 70°52′53″ N, 102°58′26″ E). We analyzed samples of early and latewood to identify absorption bands of groups of wood components, as well as the bands that characterized the interactions among the components. We studied bound water spectral characteristics for wood formed in different years. An analysis of the correlation between the values of spectral absorption bands and mean monthly air temperature and precipitation showed that May-August weather had the greatest influence on the synthesis of the main polymeric components of early and latewood. Air temperature had a considerable effect on polymer composition of cell walls forming in early and latewood, whereas precipitation influenced only earlywood. FTIR spectroscopy is a promising tool to develop information on the biochemical composition of the walls of early and late tracheids of annual rings and on weather and climate influences on cell wall synthesis.

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Держатели документа:
V.N. Sukachev Institute of Forest, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Tyutkova, E. A.; Loskutov, S. R.; Shestakov, N. P.; Шестаков, Николай Петрович
}
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13.


   
    Renewable P-type zeolite for superior absorption of heavy metals: Isotherms, kinetics, and mechanism / M. Chen, S. Nong, Y. Zhao [et al.] // Sci. Total Environ. - 2020. - Vol. 726. - Ст. 138535, DOI 10.1016/j.scitotenv.2020.138535. - Cited References: 47. - This work was supported by the National Key Research and Development Program of China (Grant No. 2016YFB0901600 ); National Science Foundation of China (Grant No. 21871008 ); Science and Technology Commission of Shanghai Municipality (Grant No. 14520722000 ) and China Postdoctoral Science Foundation [Grant No. 8206300161 ]. Thank Shuying Nong for her experimental assistance . - ISSN 0048-9697
Кл.слова (ненормированные):
Uptake capacity -- High efficiency -- Drinkable level -- Regeneration
Аннотация: Zeolite is a characteristic material for removing heavy metals exhibiting by low tolerance quantities. It is particularly desirable although challenging to cultivate an unmodified and reusable zeolite for eradicating heavy metals with great capacity. Herein, we sought out and firstly synthesized the uniform octahedral zeolite Na6Al6Si10O32·12H2O for heavy metal ions trap, proven extraordinarily effective decontamination of M2+ (Pb2+, Cd2+, Cu2+, and Zn2+). The maximum capacities of Pb2+, Cd2+, Cu2+, and Zn2+ were 649, 210, 90 and 88 mg/g, and the distribution coefficients (Kd) was ~108 mL/g for Pb2+ which emphasized the superior effectiveness of Na6Al6Si10O32·12H2O contrasted with other zeolites. Rapid adsorption was observed that Pb2+ concentration (7.5 ppm) was reduced to 0.6 ppb in 2 min. The removal mechanism was ascribed to the ion exchange and hydroxyl groups thereby affording high adsorption capacity. We also investigated the heavy metal removal of zeolite 13X and 4A for comparison and concluded the determining factor affecting absorption capacity. The removal rate of Pb remained at 97% even after five regeneration recycles. The zeolite was therefore promising for practical water purification and industrialization.

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Держатели документа:
Beijing National Laboratory for Molecular Sciences and State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
CAS Key Laboratory of Materials for Energy Conversion and State Key Laboratory of High-Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China

Доп.точки доступа:
Chen, M.; Nong, S.; Zhao, Y.; Riaz, M. S.; Xiao, Y.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Huang, F.
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14.


   
    Electrophysical properties of composites based on polyethylene modified with multi-walled carbon nanotubes with high content of Fe-Co-catalyst / S. I. Moseenkov, V. L. Kuznetsov, A. V. Zavorin [et al.] // Russ. J. Appl. Chem. - 2020. - Vol. 93, Is. 4. - P. 586-594, DOI 10.1134/S107042722004014X. - Cited References: 30. - This work was financially supported by the Russian Science Foundation, project no. 17-73-20293. . - ISSN 1070-4272. - ISSN 1608-3296
РУБ Chemistry, Applied
Рубрики:
POLYMER COMPOSITES
   NANOPARTICLES

   ACTIVATION

   NANOCOMPOSITES

Кл.слова (ненормированные):
multi-walled carbon nanotubes -- ferromagnetic catalyst particles -- polymer composites -- mechanical mixing in the melt -- gigahertz range -- electromagnetic absorption
Аннотация: The effect of the residual catalyst for the synthesis of multi-walled carbon nanotubes (MWCNTs) on the electrophysical properties of MWCNT-polyethylene composites produced by melt mechanical mixing was studied. The residual catalyst content was varied by changing the MWCNTs synthesis time. The nanotubes used in the work were characterized using transmission and scanning electron microscopy, atomic emission analysis, X-ray phase analysis, and magnetic permeability measurements. The structure of the synthesized composites was studied using optical and scanning electron microscopy. The dependences of the specific magnetization on the applied magnetic field, bulk electrical conductivity on the volumetric content of the filler in the composite, and the frequency dependences of the reflection, transmission, and absorption of electromagnetic radiation in the range 0.01-18 GHz were obtained. It was established that the obtained composites are characterized by a uniform distribution of nanotubes in the polymer matrix, and the dependence of the bulk electrical conductivity on the content of MWCNTs in the composite has a percolation character. Variation in the synthesis time of nanotubes allows producing MWCNTs with a high content of ferromagnetic particles, which are an alloy close in stoichiometry to the composition of the active component of the catalyst. It was shown that the use of composites modified with MWCNTs with a high content of residual catalyst is more effective for absorbing electromagnetic radiation due to an increase in their magnetic losses.

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Публикация на русском языке Электрофизические свойства композитов на основе полиэтилена, модифицированного многослойными углеродными нанотрубками с высоким содержанием Fe-Co-катализатора [Текст] / С. И. Мосеенков, В. Л. Кузнецов, А. В. Заворин [и др.] // Журн. прикл. химии. - 2020. - Т. 93 № 4. - С. 581-590

Держатели документа:
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia.
Novosibirsk Natl Res State Univ, Novosibirsk 630090, Russia.
Natl Res Tomsk State Univ, Tomsk 634050, Russia.
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Moseenkov, S. I.; Kuznetsov, V. L.; Zavorin, A. V.; Golubtsov, G. V.; Korovin, E. Yu.; Suslyaev, V. I.; Ishchenko, A. V.; Serkova, A. N.; Sergeenko, D. I.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Russian Science FoundationRussian Science Foundation (RSF) [17-73-20293]
}
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15.


   
    Optical functional units in zero-dimensional metal halides as a paradigm of tunable photoluminescence and multicomponent chromophores / M. Z. Li, M. S. Molokeev, J. Zhao, Z. G. Xia // Adv. Opt. Mater. - 2020. - Vol. 8, Is. 8. - Ст. 1902114, DOI 10.1002/adom.201902114. - Cited References: 38. - This work was supported by the National Natural Science Foundation of China (Nos. 51961145101, 51722202, and 51972118), Fundamental Research Funds for the Central Universities (D2190980), the Guangdong Provincial Science & Technology Project (2018A050506004), and this work was also funded by RFBR according to the Research Project No. 19-52-80003 . - ISSN 2195-1071
   Перевод заглавия: Оптические функциональные элементы в 0D металлгалогенидах как парадигма перестраиваемой фотолюминесценции многокомпонентных хромофоров
РУБ Materials Science, Multidisciplinary + Optics
Рубрики:
PEROVSKITES
   LUMINESCENCE

   ABSORPTION

   EMISSION

Кл.слова (ненормированные):
hybrid metal halides -- optical functional applications -- structural design
Аннотация: Zero-dimensional (0D) organic–inorganic hybrid luminescent metal halides have many promising optoelectronic applications; however, the single building unit in the 0D framework restricts their multimode optical control and photoluminescence tuning. Thus, it remains urgent but challenging to rationally design distinct anionic polyhedral with different optical functions and further expand this family by an equivalent cation substitution and halogen replacement. Herein, (C9NH20)9[Pb3X11](MX4)2 (X = Br and Cl, M = Mn, Fe, Co, Ni, Cu, and Zn) is successfully synthesized verifying the rationality of the design philosophy, and the optical characterizations demonstrate the effects of X‐position anions and M‐position cations on luminescence process. Intriguingly, both [Pb3X11]5− and [MX4]2− perform as inorganic building units in this 0D system and optically active centers, in which the former leads to high‐efficiency broad‐band yellow/green emission originating from self‐trapped excitons and the as‐observed multicomponent chromophores are derived from the absorption of the latter in the visible light region. The present work highlights the importance of different optical functional units showing synergistic effects on the physical properties and inspires future studies to explore multifunctional application of 0D luminescent metal halides.

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Держатели документа:
Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing Municipal Key Lab New Energy Mat & Techno, Beijing 100083, Peoples R China.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
South China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510641, Peoples R China.
South China Univ Technol, Inst Opt Commun Mat, Guangzhou 510641, Peoples R China.

Доп.точки доступа:
Li, Mingze; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhao, Jing; Xia, Zhiguo
}
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16.


    Malakhovskii, A. V.
    Magnetic circular dichroism and absorption spectra of f–f transitions 5I8 → 5F2 and 5F3 in the HoFe3(BO3)4 single crystal / A. V. Malakhovskii, V. V. Sokolov, I. A. Gudim // Low Temp. Phys. - 2020. - Vol. 46, Is. 7. - P. 734-739, DOI 10.1063/10.0001371. - Cited References: 16. - The study was supported by the Russian Foundation for Basic Research, grant No. 19-02-00034, and also by the Krasnoyarsk Krai Russian Foundation for Basic Research and the Krasnoyarsk Krai Regional Fund of Science as part of project No. 19-42-240003 on "The influence of the local environment on the magneto-optical properties of f-f transitions in rare-earth aluminoborates and ferroborates" . - ISSN 1063-777X. - ISSN 1090-6517
РУБ Physics, Applied
Рубрики:
MAGNETOOPTICAL ACTIVITY
   ELECTRON-STRUCTURE

   ERFE3(BO3)4

Кл.слова (ненормированные):
magnetic circular dichroism -- f-ftransitions -- rare earth ferroborates
Аннотация: Magnetic circular dichroism (MCD) and absorption spectra of multiferroic HoFe3(BO3)4 of 5I8 → 5F2 and 5F3 f–f transitions are measured at T = 90 K. The absorption spectra are expanded into Lorentzian components, and the transition intensities are obtained. The Zeeman splitting of some transitions is determined using the MCD and absorption spectra. The MCD spectra and Zeeman splitting are theoretically analyzed in the free-atom |J, ±MJ〉wave function approximation by using the concept of a crystalline quantum number. An inconsistency is revealed when this concept is applied to ions with an integer moment, and a modification of the concept is proposed. Anomalously intense vibronic repetitions of electronic transitions from excited sublevels of the ground multiplet are found.

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Публикация на русском языке Малаховский, Александр Валентинович. Магнитный круговой дихроизм и поглощение кристалла HoFe3(BO3)4 в области f–f переходов 5I8 → 5F2 и 5F3 [Текст] / А. В. Малаховский, В. В. Соколов, И. А. Гудим // Физ. низких температур. - 2020. - Т. 46 № 7. - С. 869-876

Держатели документа:
Russian Acad Sci, Siberian Branch, Fed Res Ctr Krasnoyarsk Sci Ctr, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Sokolov, V. V.; Соколов, Валерий Владимирович; Gudim, I. A.; Гудим, Ирина Анатольевна; Малаховский, Александр Валентинович; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [19-02-00034]; Krasnoyarsk Krai Russian Foundation for Basic Research; Krasnoyarsk Krai Regional Fund of Science [19-42-240003]
}
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17.


   
    Formation, evolution and characteristics of copper sulfide nanoparticles in the reactions of aqueous cupric and sulfide ions / Y. Mikhlin, V. Nasluzov, A. Ivaneeva [et al.] // Mater. Chem. Phys. - 2020. - Vol. 255. - Ст. 123600, DOI 10.1016/j.matchemphys.2020.123600. - Cited References: 74. - This research was supported by the Russian Foundation for Basic Research , project 18-03-00526a . We thank the ESRF for allocating beamtime, and the BM23 staff for their help during the experiments. Facilities of the Krasnoyarsk Regional Research Equipment Centre of SB RAS were employed in the work . - ISSN 0254-0584
   Перевод заглавия: Формирование, эволюция и свойства наночастиц сульфида меди, сформировавшихся в результате реакции между ионами меди и серы в водном растворе
Кл.слова (ненормированные):
Copper sulfide nanoparticles -- Polysulfide -- X-ray photoelectron spectroscopy -- X-ray absorption spectroscopy -- DFT+U
Аннотация: Colloidal copper sulfides produced in reactions of aqueous copper and sulfide ions are important for many materials applications, environment and mineral processing. Here, CuxS nanoparticles formed and aged at varying copper sulfate to sodium sulfide ratios were studied using in situ UV–vis–NIR spectroscopy, dynamic light scattering, X-ray absorption spectroscopy, ex situ TEM, X-ray photoelectron spectroscopy and Raman scattering, and DFT + U calculations. It was established that the ratio of aqueous Cu2+ to S2− ions of 1:2 is critical for the reaction, which yields disordered covellite-like 4–6 nm Cu0.7S nanoparticles comprised polysulfide species at this and higher sulfide concentrations; upon aging, the particles release sulfur and transform to chalcocite-like structure (Cu2-xS, x < 1). Conversely, at the “excess” of copper ions, Cu2-xS-type particles grew into 12–14 nm “covellitic” nanoparticles. The optical absorbance at 1100–1200 nm commonly attributed to localized surface plasmon resonance increased with time and was lowest for Cu2+/S2−= 1:2. DFT + U calculations found that polysulfide stabilizes copper-deficit covellite, while Cu vacancies in chalcocite are more favorable and destabilized by S–S bonding; the Fermi level energy increases and the hole density decreases with polysulfide formation. We believe that CuS2 clusters form initially, and following conversion of disulfide to polysulfide and then monosulfide ions rather than release of Cu determines the character of CuxS nanoparticles.

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Держатели документа:
Institute of Chemistry and Chemical Technology, Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences, Akademgorodok, 50/24, Krasnoyarsk, 660036, Russian Federation
Kirensky Institute of Physics, Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50/38, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Svobodny Pr. 79, Krasnoyarsk, 660041, Russian Federation
European Synchrotron Radiation Facility, 6 Rue Jules Horowitz, Grenoble, F-38042, France

Доп.точки доступа:
Mikhlin, Y. L.; Nasluzov, V.; Ivaneeva, A.; Vorobyev, S.; Likhatski, M.; Romanchenko, A.; Krylov, A. S.; Крылов, Александр Сергеевич; Zharkov, S. M.; Жарков, Сергей Михайлович; Meira, D. M.
}
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18.


   
    Optical properties of the HoGa3(BO3)4 crystal: experiment and ab initio calculation / S. N. Krylova, A. S. Aleksandrovsky, E. M. Roginskii [et al.] // Ferroelectrics. - 2020. - Vol. 559, Is. 1. - P. 135-140, DOI 10.1080/00150193.2020.1722015. - Cited References: 22. - This work was supported by the Russian Foundation for Basic Research (grant No 18-02-00754) . - ISSN 0015-0193
Кл.слова (ненормированные):
HoGa3(BO3)4 -- ab initio calculation -- absorption spectrum -- band structure
Аннотация: Single crystal of HoGa3(BO3)4 has been grown using solution-melt synthesis. The optical band gap determined from the measured absorption spectrum is due to direct allowed transition and equals to 4.14 eV. The optical properties of this crystal are calculated by the plane-wave pseudo-potential method based on density functional theory. The structure of the crystal has been optimized. The electronic structure of HoGa3(BO3)4 is calculated. The experimental and theoretical fundamental absorption spectra are compared. The calculated bandgap is in good agreement with the experimental data.

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Держатели документа:
Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Ioffe Institute, St. Petersburg, Russian Federation
St. Petersburg State University, St. Petersburg, Russian Federation
Moscow Institute of Physics and Technology, Dolgoprudny, Russian Federation

Доп.точки доступа:
Krylova, S. N.; Крылова, Светлана Николаевна; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Roginskii, E. M.; Krylov, A. A.; Gudim, I. A.; Гудим, Ирина Анатольевна; Vtyurin, A. N.; Втюрин, Александр Николаевич
}
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19.


   
    Non-chemical fluorination of hexagonal boron nitride by high-energy ion irradiation / S. Entani [et al.] // Nanotechnology. - 2020. - Vol. 31, Is. 12. - Ст. 125705, DOI 10.1088/1361-6528/ab5bcc. - Cited References: 53 . - ISSN 0957-4484. - ISSN 1361-6528
Кл.слова (ненормированные):
Hexagonal boron nitride -- heteroatom doping -- high-energy ion irradiation -- near edge X-ray absorption fine structure -- ab initio calculation
Аннотация: Two-dimensional materials such as hexagonal boron nitride (h-BN) and graphene have attracted wide attention in nanoelectronics and spintronics. Since their electronic characteristics are strongly affected by the local atomic structure, the heteroatom doping could allows us to tailor the electronic and physical properties of two-dimensional materials. In this study, a non-chemical method of heteroatom doping into h-BN under high-energy ion irradiation was demonstrated for the LiF/h-BN/Cu heterostructure. Spectroscopic analysis of chemical states on the relevant atoms revealed that 6 ± 2% fluorinated h-BN are obtained by the irradiation of 2.4 MeV Cu2+ ions with the fluence up to 1014 ions/cm2. It was shown that the high-energy ion irradiation leads to a single-sided fluorination of h-BN by the formation of the fluorinated sp 3-hybridized BN.

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Держатели документа:
National Institutes for Quantum and Radiological Science and Technology Takasaki Advanced Radiation Research Institute, Takasaki, 370-1292, JAPAN
National University of Science and Technology MISiS, Moscow, RUSSIAN FEDERATION
Kirensky Institute of Physics, Krasnoyarsk, RUSSIAN FEDERATION
Ritsumeikan University College of Science and Engineering Graduate School of Science and Engineering, Kusatsu, Shiga, JAPAN
Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Sendai, JAPAN
Research Institute for Applied Mechanics, Kyushu University, Kasuga, JAPAN
National Institutes for Quantum and Radiological Science and Technology Takasaki Advanced Radiation Research Institute, Takasaki, JAPAN
Inorganic Nanomaterials lab, Nacional'nyj issledovatel'skij tehnologiceskij universitet MISiS, Moscow, Moscow, RUSSIAN FEDERATION

Доп.точки доступа:
Entani, Shiro; Larionov, K. V.; Ларионов, Константин В.; Popov, Z. I.; Попов, Захар Иванович; Takizawa, Masaru; Mizuguchi, Masaki; Watanabe, Hideo; Li, Songtian; Naramoto, Hiroshi; Sorokin, Pavel B.; Sakai, Seiji
}
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20.


   
    Magnetic circular dichroism in the canted antiferromagnet α-Fe2O3: bulk single crystal and nanocrystals / R. Ivantsov [et al.] // J. Magn. Magn. Mater. - 2020. - Vol. 498. - Ст. 166208, DOI 10.1016/j.jmmm.2019.166208. - Cited References: 60. - The authors thank S.L. Sukhachev for help in conducting absorption experiments and S.G. Ovchinnikov for fruitful discussions. The work is supported by Russian Academy of Sciences in the frame of the Project № 0356-2017-0030. . - ISSN 0304-8853. - ISSN 1873-4766
   Перевод заглавия: Круговой магнитный дихроизм в антиферромагнетике α-Fe2O3: объемный монокристалл и нанокристаллы
Кл.слова (ненормированные):
Hematite -- α-Fe2O3 -- optical absorption -- magnetic circular dichroism -- ellipsometric parameters -- Raman scattering -- one-ion d-d transitions -- pare exciton-magnon transitions
Аннотация: Hematite, α-Fe2O3, is a canted antiferromagnet with the Neel temperature of 960 K. The Morin transition, which occurs when the temperature is lowered to ∼260 K, when the magnetic moments of the sublattices become strictly antiparallel to each other and the resulting magnetic moment disappears, is a characteristic feature of this compound. Detailed investigations are presented here of the magneto-optical effects in the α-Fe2O3 nanoparticles in the transmitted light and in the α-Fe2O3 single crystal in the reflected light. Two types of magneto-optic features were revealed in the magnetic circular dichroism (MCD) spectrum. Some of them described by the Gauss line shape were associated with one-ion d-d transitions. Others were described by the S-shaped line with the inflection points corresponding to the absorption maxima. Last features were assigned to the pair exciton-magnon transitions. An exceptionally strong S-shaped line at 2.0-2.5 eV appeared to be a unique feature of α-Fe2O3 distinguishing it from other iron oxide compounds. The origin of the high effectiveness of the pair exciton-magnon interaction giving rise to this strong S-shaped feature in the MCD spectrum of α-Fe2O3 is discussed.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk,660036, Russia
Siberian Federal University, Krasnoyarsk, 660041, Russia

Доп.точки доступа:
Ivantsov, R. D.; Иванцов, Руслан Дмитриевич; Ivanova, O. S.; Иванова, Оксана Станиславовна; Zharkov, S. M.; Жарков, Сергей Михайлович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Krylov, A. S.; Крылов, Александр Сергеевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Edelman, I. S.; Эдельман, Ирина Самсоновна
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