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Selective adsorption capacity of Fe3O4@C nanoparticles with respect to organic cationic dyes / O. S. Ivanova, I. S. Edelman, A. Е. Sokolov [et al.] // The Sixth Asian school-conference on physics and technology of nanostructured materials : Proceedings. - VLadivostok, 2022. - Ст. IV.p.14. - P. 231-232. - Cited References: 3 . - ISBN 987-5-8044-1716-2
Рубрики:

Аннотация: The Fe3O4 and core-shell Fe3O4@C magnetic nanoparticles (NPs) with an average size of 15 ± 2 nm were synthesized and characterized. Comparative study of two types of NPs revealed their different sorption capacity of cationic and anionic dyes. The leading role of electrostaticinteractions in the dyes adsorption by Fe3O4@C NPs has been revealed.

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Держатели документа:
Kirensky Institute of Physics, FRC KSC SB RAS
Department of Applied Physics, National Pingtung University

Доп.точки доступа:
Ivanova, O. S.; Иванова, Оксана Станиславовна; Edelman, I. S.; Эдельман, Ирина Самсоновна; Sokolov, A. Е.; Соколов, Алексей Эдуардович; Svetlitsky, E. S.; Светлицкий, Евгений Сергеевич; Lin, C.-R.; Chun-Rong Lin; Chen, Y. -Z.; Ying-Zhen Chen; Tseng, Y.-T.; Yaw-Teng Tseng; Asian School-Conference on Physics and Technology of Nanostructured Materials(6 ; 2022 ; Apr. 25-29 ; Vladivostok); Азиатская школа-конференция по физике и технологии наноструктурированных материалов(6 ; 2022 ; 25-29 апр. ; Владивосток)
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Magnetic nanoparticles Fe3O4, Fe3O4@sIo2, Fe3O4@C, and Fe3O4@C@C for the organic dyes adsorption / O. S. Ivanova, I. S. Edelman, A. Е. Sokolov [et al.] // VIII Euro-Asian symposium "Trends in magnetism" (EASTMAG-2022) : Book of abstracts / program com. S. G. Ovchinnikov [et al.]. - 2022. - Vol. 2, Sect. M : Magnetism in biology and medicine. - Ст. M.O4. - P. 424-436. - Cited References: 1. - Support by Ministry of Science and Technology of Taiwan, Grants MOST № 108-2923-M-153-001-MY3 and № 109-2112-M-153-003- is acknowledged . - ISBN 978-5-94469-051-7

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia
National Pingtung University, Pingtung City, Taiwan

Доп.точки доступа:
Ivanova, O. S.; Иванова, Оксана Станиславовна; Edelman, I. S.; Эдельман, Ирина Самсоновна; Sokolov, A. Е.; Соколов, Алексей Эдуардович; Svetlitsky, E. S.; Chun-Rong Lin; Ying-Zhen Chen; Российская академия наук; Физико-технический институт им. Е.К. Завойского ФИЦ Казанского научного центра РАН; Казанский (Приволжский) федеральный университет; Euro-Asian Symposium "Trends in MAGnetism"(8 ; 2022 ; Aug. ; 22-26 ; Kazan); "Trends in MAGnetism", Euro-Asian Symposium(8 ; 2022 ; Aug. ; 22-26 ; Kazan)
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Quantum chemical study of the spectral characteristics of fluorescein dyes bound to chitosan / A. V. Rogova, M. A. Gerasimova, F. N. Tomilin, E. A. Slyusareva // Proc. SPIE : SPIE, 2021. - Vol. 12086: 15th International Conference on Pulsed Lasers and Laser Applications (12 - 17 September 2021, Tomsk, Russia) Conference code: 176103. - Ст. 120861V, DOI 10.1117/12.2613980. - Cited References: 17. - This study was supported by the Russian Foundation for Basic Research, project no. 19-02-00450-а and by the Ministry of Science and High Education of Russian Federation, project no. FSRZ-2020-0008
Кл.слова (ненормированные):
chitosan -- density functional theory -- eosin Y -- erythrosin B -- fluorescein -- polarizable continuum model -- time-dependent procedure
Аннотация: Recently, there has been an increased interest in natural polysaccharides, in particular, chitosan, which are widely used in medicine and industry. Chitosan labeled with fluorescein dyes acquires additional optical properties that can be used in sensing and delivery systems. Mechanism of binding of a polymer to a label largely determines the field of its possible applications. The quantum chemical calculation using the B3LYP/aug-cc-pVDZ theory level has been made in order to contribute to the understanding of intermolecular interactions. The geometry of fluorescein, eosin Y, and erythrosin B in the dianionic, monoanionic, and neutral quinoid forms interacting with chitosan has been optimized and the absorption spectra have been calculated using the time-dependent density functional theory taking into account the solvent. The comparison of the calculated absorption spectra with the experimental data has shown a major role of the electrostatic mechanism in binding of anionic dyes to the protonated chitosan groups.

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Держатели документа:
Siberian Federal University, Svobodny 79, Krasnoyarsk, 660041, Russian Federation
Kirensky Institute of Physics, KSC SB RAS, Akademgorodok 50/38, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Rogova, A. V.; Gerasimova, M. A.; Tomilin, F. N.; Томилин, Феликс Николаевич; Slyusareva, E. A.; International Conference on Pulsed Lasers and Laser Applications(15 ; 2021 ; Sept. ; Tomsk, Russia)
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Inverse mode of ion-surfactant method of director reorientation inside nematic droplets / M. N. Krakhalev, O. O. Prishchepa, V. Y. Zyryanov // Mol. Cryst. Liquid Cryst. - 2009. - Vol. 512, Is. 1. - P. 1998-2003, DOI 10.1080/15421400903050814. - Cited Reference Count: 8. - Гранты: This work was partially supported by the grants Nos. NSh-3818.2008.3; 02.740.11.0220, and No. 08-03-01007 of RFBR, and Nos. 27.1; 110; 144 of SB RAS. M. Krakhalev acknowledges the financial support from K. I. Zamaraev MBN Foundation. O. Prishchepa acknowledges the financial support from Russian Science Support Foundation. - Финансирующая организация: RFBR [NSh-3818.2008.3, 02.740.11.0220, 08-03-01007]; SB RAS [27.1; 110; 144]; Zamaraev MBN Foundation; Russian Science Support Foundation . - ISSN 1542-1406
Кл.слова (ненормированные):
electrically commanded surfaces -- ion surfactant -- nematic -- polymer dispersed liquid crystals -- surface anchoring -- Electrically commanded surfaces -- Ion surfactant -- Nematic -- Polymer dispersed liquid crystals -- Surface anchoring -- Applied voltages -- Crossed polarizers -- Director fields -- Director reorientation -- Droplet structure -- Electrically commanded surfaces -- High concentration -- Homeotropic -- Initial state -- Ionic modification -- Liquid-crystal droplets -- Nematic droplets -- Nematic polymer -- Surface-active cations -- Surface-anchoring -- Trimethyl -- Ammonium compounds -- Cationic surfactants -- Crystals -- Drop formation -- Dyes -- Ionization of liquids -- Ions -- Liquid crystal displays -- Liquid crystals -- Liquids -- Nematic liquid crystals
Аннотация: Inverse mode of a novel electrooptical effect caused by the ionic modification of boundary conditions has been studied for liquid crystal droplets. We have considered the droplets of nematic 5CB doped with cationic surfactant cetyl-trimethyl-ammonium-bromide and dispersed in polyvinyl alcohol. In the initial state the surface anchoring was normal on the whole interface due to the high concentration of homeotropic surfactant. Applied voltage results in the purification of a section of the interface from the surface-active cations thereby restoring here a tangential anchoring and stimulating the significant transformation of droplet structure. At that three different types of director field distribution can be realized within the same droplet. The proper textures of the droplet both in the crossed polarizers and without analyzer are considered.

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Держатели документа:
SB RAS, LV Kirensky Phys Inst, Krasnoyarsk Sci Ctr, Krasnoyarsk, Russia
Siberian Fed Univ, Krasnoyarsk, Russia

Доп.точки доступа:
Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич
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Dichroic dyes in oriented PDLC films / V. A. Gunyakov, V. A. Zhuikov, V. Ya. Zyryanov [et al.] // 4th International Meeting on Optics of Liquid Crystals : abstracts. - 1991. - P. 72

Доп.точки доступа:
Gunyakov, V. A.; Гуняков, Владимир Алексеевич; Zhuikov, V. A.; Жуйков, Владимир Александрович; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Smorgon, S. L.; Сморгон, Сергей Леонидович; Shabanov, V. F.; Шабанов, Василий Филиппович; International Meeting on Optics of Liquid Crystals(4 ; 1991 ; Florida, USA)
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Optical anisotropy of uniaxially oriented films of polymer-encapsulated liquid crystals / V. G. Nazarov [et al.] // J. Opt. Technol. - 2005. - Vol. 72, Is. 9. - P. 675-677, DOI 10.1364/JOT.72.000675. - Cited Reference Count: 13 . - SEP. - ISSN 1070-9762
Кл.слова (ненормированные):
Dichroic dyes -- Laser radiation -- Optical anisotropy -- Uniaxially oriented films -- Anisotropy -- Density (optical) -- Dyes -- Helium neon lasers -- Light polarization -- Light scattering -- Light transmission -- Liquid crystal polymers -- Optical films
Аннотация: Uniaxially oriented films of polymer-encapsulated liquid crystals (PELCs) possess strong light-scattering anisotropy. The macroscopic transmittance anisotropy in uniaxially oriented PELC films can be strengthened by adding dichroic dyes to the LC drops. The ratio T-perpendicular to/T-parallel to of the principal components of the optical transmittance polarized perpendicular and parallel to the orientation of the PELCs, respectively, has been measured for He-Ne laser radiation transmitted through uniaxially oriented samples. The experiments showed that the transmittance anisotropy T-perpendicular to/T-parallel to for samples doped with dye is greater than the anisotropy caused only by light scattering. (c) 2005 Optical Society of America.

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Держатели документа:
Krasnoyarsk State Technical University, Krasnoyarsk, Russian Federation
L V. Kirenskii Institute of Physics, Siberian Section, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Nazarov, V. G.; Gunyakov, V. A.; Гуняков, Владимир Алексеевич; Parshin, A. M.; Паршин, Александр Михайлович; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Shabanov, V. F.; Шабанов, Василий Филиппович; International Seminar on Display Optics(1 ; OCT 18-20, 2004 ; St Petersburg, RUSSIA)
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Core-shell magnetite nanoparticles: morphology, magnetic properties, organic dyes adsorption / O. S. Ivanova, I. S. Edelman, E. S. Svetlitsky [et al.] // International conference "Functional materials" : book of abstracts / ed. V. N. Berzhansky ; org. com. S. G. Ovchinnikov [et al.]. - Simferopol, 2023. - P. 114. - Cited References: 1. - РФН № 23-22-10025

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Держатели документа:
Kirensky Institute of Physics, FRC KSC SB RAS,
Siberian Federal University
National Pingtung University, 90003, Pingtung City, Taiwan

Доп.точки доступа:
Berzhansky, V. N. \ed.\; Бержанский, Владимир Наумович; Ovchinnikov, S. G. \org. com.\; Овчинников, Сергей Геннадьевич; Ivanova, O. S.; Иванова, Оксана Станиславовна; Edelman, I. S. (Edel'man, I. S.); Эдельман, Ирина Самсоновна; Svetlitsky, E. S.; Sokolov, A. Е.; Соколов, Алексей Эдуардович; Zharkov, S. M.; Жарков, Сергей Михайлович; Petrov, D. A.; Петров, Дмитрий Анатольевич; Sukhachev, A. L.; Сухачев, Александр Леонидович; Toropova, E. S.; Chun-Rong Lin; Ying-Zhen Chen; "Functional materials", International conference(2023 ; Oct. 2-6 ; Crimea, Foros); Крымский федеральный университет имени В.И. Вернадского
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Core–shell Fe3O4@C nanoparticles for the organic dye adsorption and targeted magneto-mechanical destruction of Ehrlich ascites carcinoma cells / O. S. Ivanova, I. S. Edelman, Ch.-R. Lin [et al.] // Materials. - 2023. - Vol. 16, Is. 1. - Ст. 23, DOI 10.3390/ma16010023. - Cited References: 65. - This research was funded partly by the Ministry of Science and Higher Education of the Russian Federation, project FWES-2021-0035. C.-R.L., Y.-Z.C. and A.A.S. thank the National Science and Technology Council of Taiwan for the financial support, Grants NSTC № 108-2923-M-153-001-MY3 and № 110-2112-M-153-005-. Magnetic investigations were carried out in the Center for Collective Use of the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” . - ISSN 1996-1944
Кл.слова (ненормированные):
magnetite nanoparticles -- adsorption -- organic dyes -- aptamers -- magnetically induced cell destruction
Аннотация: The morphology, structure, and magnetic properties of Fe3O4 and Fe3O4@C nanoparticles, as well their effectiveness for organic dye adsorption and targeted destruction of carcinoma cells, were studied. The nanoparticles exhibited a high magnetic saturation value (79.4 and 63.8 emu/g, correspondingly) to facilitate magnetic separation. It has been shown that surface properties play a key role in the adsorption process. Both types of organic dyes—cationic (Rhodomine C) and anionic (Congo Red and Eosine)—were well adsorbed by the Fe3O4 nanoparticles’ surface, and the adsorption process was described by the polymolecular adsorption model with a maximum adsorption capacity of 58, 22, and 14 mg/g for Congo Red, Eosine, and Rhodomine C, correspondingly. In this case, the kinetic data were described well by the pseudo-first-order model. Carbon-coated particles selectively adsorbed only cationic dyes, and the adsorption process for Methylene Blue was described by the Freundlich model, with a maximum adsorption capacity of 14 mg/g. For the case of Rhodomine C, the adsorption isotherm has a polymolecular character with a maximum adsorption capacity of 34 mg/g. To realize the targeted destruction of the carcinoma cells, the Fe3O4@C nanoparticles were functionalized with aptamers, and an experiment on the Ehrlich ascetic carcinoma cells’ destruction was carried out successively using a low-frequency alternating magnetic field. The number of cells destroyed as a result of their interaction with Fe3O4@C nanoparticles in an alternating magnetic field was 27%, compared with the number of naturally dead control cells of 6%.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC Siberian Branch, Russian Academy of Sciences, Krasnoyarsk 660036, Russia
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk 660041, Russia
Department of Applied Physics, National Pingtung University, Pingtung City 90003, Taiwan
Laboratory of Biomolecular and Medical Technologies, Krasnoyarsk State Medical University Named after Prof. V.F. Voino-Yasenetsky, Krasnoyarsk 660022, Russia
Laboratory for Digital Controlled Drugs and Theranostics, Federal Research Center KSC Siberian Branch, Russian Academy of Sciences, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Ivanova, O. S.; Иванова, Оксана Станиславовна; Edelman, I. S.; Эдельман, Ирина Самсоновна; Lin, Chun-Rong; Svetlitsky, E. S.; Светлицкий, Евгений Сергеевич; Sokolov, A. Е.; Соколов, Алексей Эдуардович; Lukyanenko, Kirill A.; Sukhachev, A. L.; Сухачев, Александр Леонидович; Shestakov, N. P.; Шестаков, Николай Петрович; Chen, Ying-Zhen; Spivakov, Aleksandr A.
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Adsorption of organic dyes by Fe3O4@C, Fe3O4@C@C, and Fe3O4@SiO2 magnetic nanoparticles / O. S. Ivanova, I. S. Edelman, A. E. Sokolov [et al.] // Bull. Russ. Acad. Sci. Phys. - 2023. - Vol. 87, Is. 3. - P. 338-342, DOI 10.3103/S1062873822701192. - Cited References: 17. - This research was funded partly by the Ministry of Science and Higher Education of the Russian Federation, project FWES-2021-0035. Ch. R. Lin and Yu. Zh. Chen thank the National Science and Technology Council of Taiwan for the financial support, MOST no. 110-2112-M-153-005- and no. 108-2923-M-153-001-MY3 . - ISSN 1062-8738. - ISSN 1934-9432
Аннотация: Fe3O4@C, Fe3O4@C@C, and Fe3O4@SiO2 core–shell nanoparticles are synthesized via thermal decomposition and coprecipitation. Samples are characterized via X-ray spectroscopy, transmission electron microscopy, and magnetometry. It is shown that the magnetic core of all nanoparticles is nanocrystalline and has crystal parameters corresponding to only one phase of Fe3O4, covered with a uniform shell of amorphous carbon or silicon oxide around 8 nm thick. Special attention is given to adsorption properties of the nanoparticles with respect to four dyes: Methylene blue, Congo Red, Eosin Y, and Rhodamine C. The high selectivity of Fe3O4@C nanoparticles to various dyes is revealed.

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Публикация на русском языке Адсорбция органических красителей магнитными наночастицами Fe3O4@C, Fe3O4@C@C, Fe3O4@SiO2 [Текст] / О. С. Иванова, И. С. Эдельман, А. Э. Соколов [и др.] // Изв. РАН. Сер. физич. - 2023. - Т. 87 № 3. - С. 390-395

Держатели документа:
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia
Siberian Federal University, 660041, Krasnoyarsk, Russia
National Pingtung University, 900392, Pingtung, Taiwan

Доп.точки доступа:
Ivanova, O. S.; Иванова, Оксана Станиславовна; Edelman, I. S.; Эдельман, Ирина Самсоновна; Sokolov, A. Е.; Соколов, Алексей Эдуардович; Svetlitsky, E. S.; Светлицкий, Евгений Сергеевич; Zharkov, S. M.; Жарков, Сергей Михайлович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Lin, Ch. R.; Chen, Yu. Zh.
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10.

    Carbon double coated Fe3O4@C@C nanoparticles: Morphology features, magnetic properties, dye adsorption / C. R. Lin, O. S. Ivanova, I. S. Edelman [et al.] // Nanomaterials. - 2022. - Vol. 12, Is. 3. - Ст. 376, DOI 10.3390/nano12030376. - Cited References: 44. - The work was supported financially by the Russian Foundation for Basic Research, Grant No. 19-52-52002 and Ministry of Science and Technology of Taiwan, Grants MOST No. 108-2923-M-153-001-MY3 and No. 109-2112-M-153-003-. The support was obtained also from the Joint Scientific Center of the Siberian Federal University supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation, where the Transmission Electron Microscopy studies were carried out . - ISSN 2079-4991
   Перевод заглавия: Наночастицы Fe3O4@C@C с двойным углеродным покрытием: Морфологические особенности, магнитные свойства, адсорбция красителей

РУБ Chemistry, Multidisciplinary + Nanoscience & Nanotechnology + Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
SOLID-PHASE EXTRACTION
FE3O4 NANOPARTICLES
PROFILE REFINEMENT
Кл.слова (ненормированные):
core-shell Fe3O4@C nanoparticles -- core-shell Fe3O4@C@C nanoparticles -- magnetic properties -- dyes adsorption
Аннотация: This work is devoted to the study of magnetic Fe3O4 nanoparticles doubly coated with carbon. First, Fe3O4@C nanoparticles were synthesized by thermal decomposition. Then these synthesized nanoparticles, 20–30 nm in size were processed in a solution of glucose at 200 °C during 12 h, which led to an unexpected phenomenon – the nanoparticles self-assembled into large conglomerates of a regular shape of about 300 nm in size. The morphology and features of the magnetic properties of the obtained hybrid nanoparticles were characterized by transmission electron microscopy, differential thermo-gravimetric analysis, vibrating sample magnetometer, magnetic circular dichroism and Mössbauer spectroscopy. It was shown that the magnetic core of Fe3O4@C nanoparticles was nano-crystalline, corresponding to the Fe3O4 phase. The Fe3O4@C@C nanoparticles presumably contain Fe3O4 phase (80%) with admixture of maghemite (20%), the thickness of the carbon shell in the first case was of about 2–4 nm. The formation of very large nanoparticle conglomerates with a linear size up to 300 nm and of the same regular shape is a remarkable peculiarity of the Fe3O4@C@C nanoparticles. Adsorption of organic dyes from water by the studied nanoparticles was also studied. The best candidates for the removal of dyes were Fe3O4@C@C nanoparticles. The kinetic data showed that the adsorption processes were associated with the pseudo-second order mechanism for cationic dye methylene blue (MB) and anionic dye Congo red (CR). The equilibrium data were more consistent with the Langmuir isotherm and were perfectly described by the Langmuir–Freundlich model.

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Держатели документа:
Natl Pingtung Univ, Dept Appl Phys, Pingtung City 90003, Taiwan.
RAS, FRC KSC SB, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Inst Engn Phys & Radioelect, Krasnoyarsk 660041, Russia.
RAS, FRC KSC SB, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Lin, Chun-Rong; Ivanova, O. S.; Иванова, Оксана Станиславовна; Edelman, I. S.; Эдельман, Ирина Самсоновна; Knyazev, Yu. V.; Князев, Юрий Владимирович; Zharkov, S. M.; Жарков, Сергей Михайлович; Petrov, D. A.; Петров, Дмитрий Анатольевич; Sokolov, A. Е.; Соколов, Алексей Эдуардович; Svetlitsky, E. S.; Светлицкий, Евгений Сергеевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Solovyov, Leonid A.; Chen, Ying-Zhen; Tseng, Yaw-Teng; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [19-52-52002]; Ministry of Science and Technology of TaiwanMinistry of Science and Technology, Taiwan [108-2923-M-153-001-MY3, 109-2112-M-153-003]; Joint Scientific Center of the Siberian Federal University [FSRZ-2020-0011]; Ministry of Science and Higher Education of the Russian Federation
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