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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Nikolaev N. S., Isakova V. G., Vnukova N. G., Elesina V. I., Glushenko G. A., Tomashevich Y. V., Churilov G. N.
Заглавие : Synthesis of Ni nanoclusters supported on diamond by plasma technique and their electrochemical properties
Колич.характеристики :6 с
Место публикации : Diam. Relat. Mater. - 2024. - Vol. 142. - Ст.110844. - ISSN 09259635 (ISSN), DOI 10.1016/j.diamond.2024.110844. - ISSN 18790062 (eISSN)
Примечания : Cited References: 35
Аннотация: In this study, particles of synthetic undoped diamond (DN) obtained via the high pressure – high temperature method were coated with a nickel shell using metallic nickel plasma in a two-jet plasma generator with gas vortex and magnetic flux stabilization. Through the use of scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy, we observed the formation of a nickel diamond composite with a core-shell structure, where DN serves as the core and Ni nanoclusters form the shell (DN@Ni). The results of voltammetric analysis indicated that DN@Ni, when deposited on a graphite electrode, exhibited significant electrocatalytic activity in the oxidation of methanol and paracetamol in an alkaline electrolyte.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Afonnikova S. D., Bauman, Yury I., Stoyanovskii, Vladimir O., Volochaev M. N., Mishakov, Ilya V., Vedyagin, Aleksey A.
Заглавие : Effect of Cu on performance of self-dispersing Ni-catalyst in production of carbon nanofibers from ethylene
Колич.характеристики :17 с
Место публикации : C – J. Carbon Res. - 2023. - Vol. 9, Is. 3: Advanced Carbon Nanomaterials and Hybrids. - Ст.77. - ISSN 23115629 (eISSN), DOI 10.3390/c9030077
Примечания : Cited References: 72. - This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov Institute of Catalysis (project AAAA-A21-121011390054-1). The physicochemical characterization of samples was supported by the Russian Science Foundation (project No. 22-13-00406, https://rscf.ru/en/project/22-13-00406/BIC SB RAS (accessed on 30 March 2023))Analysis of the physicochemical properties of the samples was performed using the equipment of the ‘National Center for Catalyst Research’ (Novosibirsk, BIC SB RAS) and Krasnoyarsk regional Center of the Collective Use (KSS SB RAS). The authors are grateful to A.N. Serkova for the performed SEM studies, B.A. Kolesov for the Raman spectra data, to A.B. Ayupov for analyzing samples by low-temperature adsorption/desorption of nitrogen, to Y.V. Shubin for the XRD analysis and to E.I. Belyaeva for the particle distribution analysis
Аннотация: The development of effective catalysts for the pyrolysis of light hydrocarbons with the production of carbon nanomaterials represents a relevant direction. In the present work, the influence of copper addition on performance of a self-dispersed Ni-catalyst and structural features of the obtained carbon nanofibers (CNFs) was studied. The precursors of Ni and Ni-Cu catalysts were prepared by activation of metal powders in a planetary mill. During contact with the C2H4/H2 reaction mixture, a rapid disintegration of the catalysts with the formation of active particles catalyzing the growth of CNFs has occurred. The kinetics of CNF accumulation during ethylene decomposition on Ni- and Ni-Cu catalysts was studied. The effect of temperature on catalytic performance was explored and it was shown that introduction of copper promotes 1.5–2-fold increase in CNFs yield in the range of 525–600 °C; the maximum CNFs yield (100 g/gcat and above, for 30-min reaction) is reached on Ni-Cu-catalyst at 575–600 °C. A comparative analysis of the morphology and structure of CNF was carried out using electron microscopy methods. The growth mechanism of carbon filaments in the shape of “railway crossties” on large nickel crystals (d 250 nm) was proposed. It was found that the addition of copper leads to a decrease in the bulk density of the carbon product from 40–60 to 25–30 g/L (at T = 550–600 °C). According to the low-temperature nitrogen adsorption data, specific surface area (SSA) of CNF samples (at T ˂ 600 °C) lies in the range of 110–140 m2/g, regardless of the catalyst composition; at T = 600 °C the introduction of copper contributed to an increase in the specific surface of CNF by 100 m2/g.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Molchanova A. D., Moshkina E. M., Molokeev M. S., Tropina E. V., Bovina A. F., Boldyrev K. N.
Заглавие : Synthesis and optical properties of nickel-doped copper metaborate crystals
Колич.характеристики :6 с
Место публикации : Opt. Spectrosc. - 2023. - Vol. 131, Is. 8. - P.717-722. - ISSN 0030400X (ISSN), DOI 10.1134/S0030400X23060127. - ISSN 15626911 (eISSN)
Примечания : Cited References: 18. - The study was performed with the support of Russian Science Foundation, RSF grant no. 19-12-00413
Аннотация: This work presents information on the growth and spectroscopic study of single crystals of copper metaborate doped with nickel Cu1–xNixB2O4 (x = 0.05, 0.1). In the absorption spectra of both crystals, satellites related to Cu centers distorted by impurity Ni atoms were observed near the lines of zero phonon transitions. Polarization studies in the isotropic ab-plane of the tetragonal crystal Cu1–xNixB2O4 show the presence of linear magnetic dichroism in the magnetically ordered state, which was previously observed both in manganese-doped and undoped copper metaborates CuB2O4. The temperature of magnetic phase transitions into the collinear antiferromagnetic and into helicoidal structures, TN = 19.1 K and T * = 8.6 K, respectively, were determined from the temperature dependence of the dichroic signal.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stolyar S. V., Li O. A., Nikolaeva E. D., Vorotynov A. M., Velikanov D. A., Knyazev Yu. V., Bayukov O. A., Iskhakov R. S., P’yankov V. F., Volochaev M. N.
Заглавие : An effective method of magnetic hyperthermia based on the ferromagnetic resonance phenomenon
Место публикации : Phys. Met. Metallogr. - 2023. - Vol. 124, Is. 2. - P.174-180. - ISSN 0031918X (ISSN), DOI 10.1134/S0031918X22601834. - ISSN 15556190 (eISSN)
Примечания : Cited References: 15. - This study was supported by grant no. 22-14-20020 from the Russian Science Foundation and the Krasnoyarsk Regional Fund for Support of Scientific and Technological Activities. The authors are grateful to the Krasnoyarsk Regional Center for Collective Use at Federal Research Center Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, for providing their research facilities
Аннотация: Nickel and cobalt ferrite nanoparticles have been synthesized using the chemical precipitation method; the nanoparticle sizes were found to be 63 ± 22 and 26 ± 4 nm, respectively. The static hysteresis loops and Mossbauer spectra have been measured. It is shown that cobalt ferrite powders are magnetically harder than nickel ferrite powders. Ferromagnetic resonance (FMR) curves have been studied. It is found that the FMR absorption for cobalt ferrite is observed at room temperature and above. The time dependences of the nanoparticle warm-up under FMR conditions have been measured. The maximum temperature changes for nickel ferrite and cobalt ferrite particles are 8 and 11 K, respectively. Using the example of cobalt ferrite powder, the possibility of effectively heating of particles in the FMR mode in their own field without using a DC magnetic field source is shown. The observed effect can be used in magnetic hyperthermia.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Solovev P. N., Afonin A. O., Belyaev B. A., Boev N. M., Govorun I. V., Izotov A. V., Ugrymov A. V., Leksikov An. A.
Заглавие : Second harmonic generation as a probe of parametric spin wave instability processes in thin magnetic films
Место публикации : Phys. Rev. B. - 2022. - Vol. 106, Is. 6. - Ст.064406. - ISSN 24699950 (ISSN), DOI 10.1103/PhysRevB.106.064406
Примечания : Cited References: 33. - This work was supported by the Russian Science Foundation under Grant No. 19-72-10047. The equipment of the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” was used during the measurements
Аннотация: We have explored the dynamic response of in-plane magnetized thin permalloy films excited by microwave fields of high amplitudes (up to 3 Oe) at 1 GHz. The response was detected using a microstrip line by measuring the second harmonic signal generated by the dynamic components of the uniform magnetization. The data measured at ferromagnetic resonance showed the threshold effect of the Suhl parametric instability process. With the increase of the microwave power above the threshold value, the dynamic response revealed an intricate nonlinear behavior, including the emergence of an additional threshold. This second threshold can be explained in terms of the "stage by stage"process of parametric spin wave excitation following the S theory of Zakharov, L'vov, and Starobinets.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Molchanova A. D., Moshkina E. M., Molokeev M. S., Tropina E. V., Bovina A. F., Boldyrev K. N.
Заглавие : Synthesis and optical properties of nickel-doped copper metaborate crystals
Место публикации : Opt. Spectrosc. - 2022. - Vol. 130, Is. 1. - P.105-109. - ISSN 0030400X (ISSN), DOI 10.21883/EOS.2022.01.52994.41-21. - ISSN 15626911 (eISSN)
Примечания : Cited References: 18. - The study was performed with the support of Russian Science Foundation, RSF grant № 19-12-00413
Аннотация: This work presents information on the growth and spectroscopic study of single crystals of copper metaborate doped with nickel Cu1–xNixB2O4 (x = 0.05, 0.1). In the absorption spectra of both crystals, satellites related to Cu centers distorted by impurity Ni atoms were observed near the lines of zero phonon transitions. Polarization studies in the isotropic ab-plane of the tetragonal crystal Cu1–xNixB2O4 show the presence of linear magnetic dichroism in the magnetically ordered state, which was previously observed both in manganese-doped and undoped copper metaborates CuB2O4. The temperature of magnetic phase transitions into the collinear antiferromagnetic and into helicoidal structures, TN = 19.1 K and T* = 8.6 K, respectively, were determined from the temperature dependence of the dichroic signal.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Padamata, Sai Krishna, Yasinskiy, Andrey, Shabanov A. V., Bermeshev, Timofey, Yang, You-jian, Wang, Zhao-wen, Cao, Dao, Polyakov, Peter
Заглавие : Improving corrosion resistance of Cu-Al-based anodes in KF-AlF3-Al2O3 melts
Коллективы : State Assignment for the Science of Siberian Federal University, Russia [FSRZ-2020-0013]
Место публикации : Trans. Nonferrous Met. Soc. China. - 2022. - Vol. 32, Is. 1. - P.354-363. - ISSN 1003-6326, DOI 10.1016/S1003-6326(22)65800-X. - ISSN 2210-3384(eISSN)
Примечания : Cited References: 24. - The work is performed as a part of the State Assignment for the Science of Siberian Federal University, Russia (No. FSRZ-2020-0013) . Use of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS" is acknowledged
Предметные рубрики: NI-FE
ALUMINUM ELECTROLYSIS
INERT ANODES
NICKEL FERRITE
BEHAVIOR
Аннотация: The anodic behaviour of pre-oxidised and non-oxidised Cu−Al-based anodes (Cu−10Al and Cu−9.8Al−2Mn) in KF−AlF3−Al2O3 melts was studied through galvanostatic and potentiodynamic polarization techniques. The alloy compositions were oxidised for a short-term (8 h) at 700 °C, followed by galvanostatic polarization for 1 h at 800 °C with an applied current density of 0.4 A/cm2. The potentiodynamic curves were recorded with a sweep rate of 0.01 V/s. XRD analysis was conducted on frozen melt samples collected on the surface of the anode, and SEM observation was performed on the anode after the experiment to study the phases of the scales formed on the alloys. All the anode materials had a steady potential between 2.30 and 2.50 V(vs Al/AlF3). The corrosion rates of the anodes were calculated from the data acquired through potentiodynamic polarization. It was seen that pre-oxidised anodes possess a low corrosion rate compared to those without pre-oxidation treatment.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Potylitsyna, Arina R., Mishakov, Ilya, V, Bauman, Yury, I, Kibis, Lidia S., Shubin, Yury, V, Volochaev M. N., Melgunov, Maxim S., Vedyagin, Aleksey A.
Заглавие : Metal dusting as a key route to produce functionalized carbon nanofibers
Коллективы : Ministry of Science and Higher Education of the Russian Federation [AAAA-A21-121011390054-1, 0239-2021-0010, 121031700315-2]
Место публикации : React. Kinet. Mech. Catal. - 2022. - Vol. 135, Is. 3. - P.1387-1404. - ISSN 1878-5190, DOI 10.1007/s11144-022-02169-y. - ISSN 1878-5204(eISSN)
Примечания : Cited References: 65. - This work was supported by the Ministry of Science and Higher Education of the Russian Federation (Project numbers AAAA-A21-121011390054-1 (ID: 0239-2021-0010) and 121031700315-2)
Предметные рубрики: CHLORINATED HYDROCARBONS
NI-CU
DECOMPOSITION
NANOTUBES
CATALYST
Аннотация: The present paper reports a new method of producing N-doped carbon nanofibers via metal dusting of a ternary NiMoW alloy in the atmosphere containing C2HCl3 and CH3CN vapors at 600 °C. The initial alloy was prepared by a co-precipitation technique. The carbon deposition was monitored gravimetrically. The early stages of the metal dusting process were studied in detail using scanning and transmission electron microscopies. It was established that the rapid disintegration of the microdispersed NiMoW alloy with the formation of nanosized particles catalyzing the growth of carbon filaments occurs within the first 5 min of the reaction. The presence of C2HCl3 vapors in the reaction medium was shown to be the urgent condition to provide efficient metal dusting. The effect of the CH3CN concentration in the trichloroethylene-containing reaction mixture on the carbon deposition is investigated. As observed, the CH3CN content noticeable affects the carbon yield (after 2 h of reaction). The dome-shaped dependence of carbon yield reaches its maximal value of ~ 200 g/g(cat) at a CH3CN concentration of 33 vol%. According to X-ray photoelectron spectroscopy, the obtained carbon filaments are functionalized with Cl (0.1–1.2 wt%), O (3–6 wt%), and N (0.5–1.3 wt%). The prepared carbon filaments possess a segmented secondary structure, which is typical for carbon nanomaterials derived via catalytic decomposition of chlorine-substituted hydrocarbons. Low-temperature nitrogen adsorption measurement revealed that the specific surface area of the N-containing samples varies in a range from 370 to 550 m2/g.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova E. A., Chekanova L. A., Komogortsev S. V., Rautsky M. V., Nemtsev I. V., Iskhakov R. S., Plotnikov V. S., Tkachev V. V., Li O. A., Dolgopolova M. V.
Заглавие : Core-shell and bi-segmented cobalt-nickel nanorods prepared by electroless deposition
Место публикации : IEEE Trans. Magn. - 2022. - Vol. 58, Is. 2. - Ст.2300805. - ISSN 00189464 (ISSN), DOI 10.1109/TMAG.2021.3098747
Примечания : Cited References: 27. - This work was funded by RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, project number 20-43-240003. The authors thank the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center“ Krasnoyarsk Science Center SB RAS” for the provided equipment
Аннотация: A porous polymer loaded with segmented nanorods of magnetic metal is very promising for the design of novel microwave devices. Arrays of bi-segmented Ni/Co and core-shell Ni@Co rods were prepared by electroless deposition into porous of polycarbonate track etched membrane. An intrinsic effective magnetic field of the magnetic composite nanorods aligned in the nonmagnetic template was studied by magnetization curves and ferromagnetic resonance. The effect of the interface boundaries for two types of bi-segmented rods with coaxial and along-axis Co/Ni segmentation to effective field was established.
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10.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Molchanova A. D., Boldyrev K. N., Moshkina E. M.
Заглавие : Spectroscopic study and analysis of d-d transitions in Ni ions in nickel orthoborate (Cu, Ni)B2O4
Коллективы : International Baltic Conference on Magnetism: focus on nanobiomedicine and smart materials, Балтийский федеральный университет им. И. Канта
Место публикации : 4th International Baltic Conference on Magnetism (IBCM 2021): Book of abstracts. - 2021. - P.165
Примечания : Cited References: 7. - This work was supported by the Russian Science Foundation, grant № 19-12-00413
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Timofeeva E. E., Panchenko E. Y., Tagiltsev A. I., Larchenkova N. G., Tokhmetova A. B., Chumlyakov Y. I., Volochaev M. N.
Заглавие : Orientation dependence of superelasticity in quenched high-nickel Ti-51.8Ni single crystals
Место публикации : Mater. Lett. - 2021. - Vol. 282. - Ст.128677. - ISSN 0167577X (ISSN), DOI 10.1016/j.matlet.2020.128677
Примечания : Cited References: 12. - This work was supported by the Russian Science Foundation (grant No. 18–19–00298 ). The electron microscopy studies were carried out on the equipment of the Krasnoyarsk Regional Center for Collective Use SB RAS
Аннотация: The orientation dependence of the functional and mechanical properties of quenched Ti-51.8at.%Ni single crystals, undergoing a strain-glass transition upon cooling/heating was investigated. It was found that a compressive stress above 800 MPa leads to the B2-B19′ martensitic transformation (MT), regardless of orientation. In the high-strength [0 0 1]-orientation, superelasticity (SE) was observed at 203–248 K, with a reversible strain of 2.3%. Degradation of SE at deforming stresses σ 1000 MPa was associated with the formation of {1 1 3}B2 twins during the reverse MT. In the low-strength [1 1 1]-orientation, the formation of stress-induced B19′-martensite occurred simultaneously with the plastic deformation of the B2-phase (due to the formation of reorientation bands and dislocation slip) and a reversible strain was not observed.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Belyaev B. A., Boev N. M., Gorchakovsky A. A., Galeev R. G.
Заглавие : Inspection probes of a ferromagnetic resonance scanning spectrometer
Место публикации : Instrum. Exp. Tech. - 2021. - Vol. 64, Is. 2. - P.277-284. - ISSN 00204412 (ISSN), DOI 10.1134/S0020441221010218
Примечания : Cited References: 24. - This study was supported by the Ministry of Science and Higher Education of the Russian Federation as part of a complex project on the development of high-technology production facilities (agreement no. 075-11-2019-054, November 22, 2019)
Аннотация: The design of inspection probes for a scanning ferromagnetic resonance spectrometer, which are designed for recording the absorption spectra of electromagnetic energy by local areas of thin magnetic films, is described. The degree of locality is determined by the diameter of the measuring hole of the probe in the range of 0.1–1.0 mm. The sensitivity of the device is significantly increased due to the miniaturization of the heterogeneous measuring resonator and its comparatively high Q factor. A set of replaceable probes makes it possible to cover the frequency range of 0.1–6.0 GHz, the signal-to-noise ratio for a probe with a hole diameter of 0.8 mm, which was measured on a permalloy film with a thickness of 5 nm, is at least 20 dB.
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13.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Denisova E. A., Chekanova L. A., Komogortsev S. V., Rautskii M. V., Nemtsev I. V., Iskhakov R. S., Tkachev V. V., Plotnikov V. S., Dolgopolova M. V.
Заглавие : Core-shell and Bi-segmented cobalt-nickel nanorods prepared by electroless deposition
Коллективы : IEEE International Magnetics Conference
Место публикации : IEEE International Magnetics Virtual Conference (INTERMAG'21): Digest book. - 2021. - P.1342
Примечания : Cited References: 2. - This work was funded by the RFBR, the Government of the Krasnoyarsk Territory, the KRFS (project no. 20-43-240003)
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kveglis, Ludmila I., Noskov, Fedor M., Volochaev M. N., Nyavro, Alexander V., Filarowski, Aleksander
Заглавие : Magnetic properties of nickel-titanium alloy during martensitic transformations under plastic and elastic deformation
Место публикации : Symmetry. - 2021. - Vol. 13, Is. 4. - Ст.665. - ISSN 2073-8994(eISSN), DOI 10.3390/sym13040665
Примечания : Cited References: 61
Предметные рубрики: NITI SHAPE-MEMORY
CRYSTAL-STRUCTURE
WAVE MECHANICS
TRANSITIONS
Аннотация: This paper focuses on the processes of the occurrence of magnetization during structure formation in samples of Ni51Ti49 alloy under deformation conditions. The possibility of the existence of a phase with an FCC (face-centered cubic) lattice in titanium nickelide has been demonstrated by electron microscopy and electron diffraction. It has been discovered that the interplanar distances of BCC110 (body-centered cubic), FCC111, and HCP002 (hexagonal close packed) in the alloy under study have similar values, which indicates the possibility of their mutual polymorphic transformation. Based on the modular self-organization, a scheme of martensitic transformations in titanium nickelide from the B2 structure (BCC lattice) to the B19' structure (HCP lattice) through an intermediate phase with an FCC lattice is proposed. It is shown that lenticular crystals appear in the Ni51Ti49 alloy under tensile deformation until rupture, which is accompanied by the onset of ferromagnetism. The effect of magnetization in Ni51Ti49 samples when immersed in liquid nitrogen has been also discovered. In this case, the reason for the appearance and disappearance of magnetization can be associated with microdeformation processes caused by direct and reverse martensitic transitions that occur during cooling and heating of the samples.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Abylgazina L., Senkovska I., Ehrling S., Bon V., St. Petkov P., Evans J. D., Krylova S. N., Krylov A. S., Kaskel S.
Заглавие : Tailoring adsorption induced switchability of a pillared layer MOF by crystal size engineering
Место публикации : CrystEngComm. - 2021. - Vol. 23, Is. 3. - P.538-549. - ISSN 14668033 (ISSN), DOI 10.1039/d0ce01497d
Примечания : Cited References: 71. - The authors thank the DFG (FOR 2433 MOF Switches, Project No. 279409724) for financial support. P.P. and J. D. E. thank Center for Information Services and High Performance Computing (ZIH) at TU Dresden for providing high-performance computing facilities. Authors acknowledge Helmholtz-Zentrum Berlin für Materialien und Energie for allocated beamtime at KMC-2 and MX14.2 beamlines. J. D. E. acknowledges the support of the Alexander von Humboldt foundation and HPC platforms provided by a GENCI grant (A0070807069)
Аннотация: The pillared layer framework DUT-8(Zn) (Zn2(2,6-ndc)2(dabco), 2,6-ndc = 2,6-naphthalenedicarboxylate, dabco = 1,4-diazabicyclo-[2.2.2]-octane, DUT = Dresden University of Technology) is a prototypical switchable MOF, showing characteristic adsorption and desorption induced open phase (op) to closed phase (cp) transformation associated with huge changes in cell volume. We demonstrate switchability strongly depends on a framework-specific critical particle size (dcrit). Superposed, the solvent removal process (pore desolvation stress contracting the framework) significantly controls the cp/op ratio after desolvation and, subsequently, the adsorption induced switchability characteristics of the system. After desolvation, the dense cp phase of DUT-8(Zn) shows no adsorption-induced reopening and therefore is non-porous for N2 at 77 K and CO2 at 195 K. However, polar molecules with a higher adsorption enthalpy, such as chloromethane at 249 K and dichloromethane (DCM) at 298 K can reopen the macro-sized crystals upon adsorption. For macro-sized particles, the outer surface energy is negligible and only the type of metal (Zn, Co, Ni) controls the DCM-induced gate opening pressure. The node hinge stiffness increases from Zn to Ni as confirmed by DFT calculations, X-ray crystal structural analysis, and low frequency Raman spectroscopy. This softer Zn-based node hinges and overall increased stabilization of cp vs. op phase shift the critical particle size at which switchability starts to become suppressed to even lower values (dcrit ‹ 200 nm) as compared to the Ni-based system (dcrit ≈ 500 nm). Hence, the three factors affecting switchability (energetics of the empty host, (Eop–Ecp) (I), particle size (II), and desolvation stress (III)) appear to be of the same order of magnitude and should be considered collectively, not individually.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Pile S., Feggeler T., Schaffers T., Meckenstock R., Buchner M., Spoddig D., Zingsem B., Ney V., Farle M., Wende H., Ohldag H., Ney A., Ollefs K.
Заглавие : Non-standing spin-waves in confined micrometer-sized ferromagnetic structures under uniform excitation
Место публикации : Appl. Phys. Lett. - 2020. - Vol. 116, Is. 7. - Ст.072401. - ISSN 00036951 (ISSN), DOI 10.1063/1.5139881
Примечания : Cited References: 37. - The use of the Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Contract No. DE-AC02-76SF00515. The authors would like to thank the Austrian Science Foundation (FWF), Project No. I-3050 as well as the German Research Foundation (DFG), Project No. OL513/1-1 for financial support. K.O., H.W., B.Z and M.F. acknowledge additional funding from Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) – Project-ID 405553726 – TRR 270 and B.Z and M.F. acknowledge additional funding from Research Grant No. 075-15-2019-1886 from the Government of the Russian Federation
Аннотация: A non-standing characteristic of directly imaged spin-waves in confined micrometer-sized ultrathin Permalloy (Ni80Fe20) structures is reported along with evidence of the possibility to alter the observed state by modifications to the sample geometry. Using micromagnetic simulations, the presence of the spin-wave modes excited in the Permalloy stripes along with the quasi-uniform modes was observed. The predicted spin-waves were imaged in direct space using time resolved scanning transmission X-ray microscopy, combined with a ferromagnetic resonance excitation scheme (STXM-FMR). STXM-FMR measurements revealed a non-standing characteristic of the spin-waves. Also, it was shown by micromagnetic simulations and confirmed using STXM-FMR results that the observed characteristic of the spin-waves can be influenced by the local magnetic fields in different sample geometries.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ushakov A. V., Karpov I. V., Fedorov L. Y., Demin V. G., Goncharova E. A., Shaihadinov A. A., Zeer G. M., Zharkov S. M.
Заглавие : The effect of microstructural features on the ferromagnetism of nickel oxide nanoparticles synthesized in a low-pressure arc plasma
Место публикации : Physica E. - 2020. - Vol. 124. - Ст.114352. - ISSN 13869477 (ISSN), DOI 10.1016/j.physe.2020.114352
Примечания : Cited References: 31. - The work was performed with a support of the grant of the Russian Science Foundation (Project No. 16-19-10054 ). The electron microscopy investigations were conducted in the SFU Joint Scientific Center supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation
Аннотация: Nickel oxide nanoparticles were first synthesized by sputtering high-purity nickel in an oxygen plasma of a low-pressure arc discharge. The structure, morphology, and optical and magnetic properties of NiO nanoparticles were studied by XRD, TEM, FTIR, UV-VIS, and VSM. TEM images showed that the obtained NiO nanoparticles have a narrow particle size distribution and an average particle size of 12 nm. The XRD results and the processing of diffractograms by the Rietveld method showed that the obtained nanoparticles have a face-centered cubic lattice with an average particle size of 13 nm. With decreasing temperature, residual stresses increase and peaks corresponding to the superstructure appear. The band gap of NiO was determined from the optical absorption spectrum and amounted to 3.21 eV. Magnetic measurements showed that, at temperatures of 200 and 300 K, NiO nanoparticles, unlike bulk particles, exhibit ferromagnetic behavior, and at 5 K a magnetic hysteresis loop appears. Based on the studies, a dendritic model of the nanoparticle microstructure is proposed.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Belousov A. L., Patrusheva T. N., Karacharov A. A., Ivanenko A. A., Kirik S. D., Khol'kin A. I.
Заглавие : Amorphous and Crystalline Nickel Oxide Films Obtained by the Extraction-Pyrolysis Method for Electrochromic Cells
Коллективы : program "Research and Development for the Priority Areas of the Russian Science-and-Technology Sector for 2014-2020" [075-15-2019-1843]; [RFMEFI60719X0307]
Место публикации : Theor. Found. Chem. Eng. - 2020. - Vol. 54, Is. 4. - P.699-705. - ISSN 0040-5795, DOI 10.1134/S0040579520040041. - ISSN 1608-3431(eISSN)
Примечания : Cited References: 8. - This work was performed as part of the program "Research and Development for the Priority Areas of the Russian Science-and-Technology Sector for 2014-2020"; Grant Agreement no. 075-15-2019-1843; the Project Unique Identifier RFMEFI60719X0307
Предметные рубрики: NIO THIN-FILMS
Аннотация: This paper reports studies of thin films of nickel oxide obtained by the extraction–pyrolysis method on glass and quartz substrates at temperatures of 380–600°C. The films have been characterized by atomic force microscopy and X-ray diffraction. It is shown that amorphous and crystalline nickel oxide films are formed on the glass. The grain size depends on the annealing temperature, while increased annealing temperatures lead to recrystallization and a decrease in the grain size in NiO films from 130 to 35 nm.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Saykova, Diana, Saikova, Svetlana, Mikhlin, Yuri, Panteleeva, Marina, Ivantsov R. D., Belova E.
Заглавие : Synthesis and characterization of core-shell magnetic nanoparticles NiFe2O4@Au
Место публикации : Metals. - 2020. - Vol. 10, Is. 8. - Ст.1075. - ISSN 2075-4701(eISSN), DOI 10.3390/met10081075
Примечания : Cited References: 45
Предметные рубрики: NICKEL FERRITE NANOPARTICLES
GOLD NANOPARTICLES
OXIDATION
REDUCTION
Аннотация: In this study, NiFe2O4@Au core–shell nanoparticles were prepared by the direct reduction of gold on the magnetic surface using amino acid methionine as a reducer and a stabilizing agent simultaneously. The obtained nanoparticles after three steps of gold deposition had an average size of about 120 nm. The analysis of particles was performed by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and UV-Vis spectroscopy techniques. The results indicate successful synthesis of core–shell particles with the magnetic core, which consists of a few agglomerated nickel ferrite crystals with an average size 25.2 ± 2.0 nm, and the thick gold shell consists of fused Au0 nanoparticles (NPs). Magnetic properties of the obtained nanoparticles were examined with magnetic circular dichroism. It was shown that the magnetic behavior of NiFe2O4@Au NPs is typical for superparamagnetic NPs and corresponds to that for NiFe2O4 NPs without a gold shell. The results indicate the successful synthesis of core–shell particles with the magnetic nickel ferrite core and thick gold shell, and open the potential for the application of the investigated hybrid nanoparticles in hyperthermia, targeted drug delivery, magnetic resonance imaging, or cell separation. The developed synthesis strategy can be extended to other metal ferrites and iron oxides.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zamkova N. G., Gavrichkov V. A., Sandalov I. S., Ovchinnikov S. G.
Заглавие : Proximity of Ferromagnetic Nickel to Paramagnetic Instability
Коллективы : Russian Foundation for Basic Research [16-02-00273]
Место публикации : JETP Letters. - 2019. - Vol. 109, Is. 4. - P.276-279. - ISSN 0021-3640, DOI 10.1134/S0021364019040131. - ISSN 1090-6487(eISSN)
Примечания : Cited References: 21. - This work was supported by the Russian Foundation for Basic Research (project no. 16-02-00273).
Предметные рубрики: TOTAL-ENERGY CALCULATIONS
WAVE
Аннотация: The phase diagram of Ni in the space of the parameters has been studied within the Kanamori model with the parameters determined from comparison with ab initio calculations for ferromagnetic Ni. The proximity of Ni to the boundary of the transition to a paramagnetic state has been found.
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