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1.


   
    A hybrid quantum–classical theory for predicting terahertz charge-transfer plasmons in metal nanoparticles on graphene / A. S. Fedorov, E. V. Eremkin, P. O. Krasnov [et al.] // J. Chem. Phys. - 2024. - Vol. 160, Is. 4. - Ст. 044117, DOI 10.1063/5.0178247. - Cited References: 61. - This study was funded by the Ministry of Science and High Education of Russian Federation, Project No. FSRZ-2023-0006. The calculations of CTPs in specific NP–graphene complexes were performed within the RSF Grant No. 23-12-20007 and the Krasnoyarsk Territorial Foundation for Support of Scientific and R & D Activities, Agreement No. 256. H. Ågren was supported by the Swedish Science Research Council on Contract No. 2022-03405 . - ISSN 0021-9606. - ISSN 1089-7690
Аннотация: Metal nanoparticle (NP) complexes lying on a single-layer graphene surface are studied with a developed original hybrid quantum–classical theory using the Finite Element Method (FEM) that is computationally cheap. Our theory is based on the motivated assumption that the carrier charge density in the doped graphene does not vary significantly during the plasmon oscillations. Charge transfer plasmon (CTP) frequencies, eigenvectors, quality factors, energy loss in the NPs and in graphene, and the absorption power are aspects that are theoretically studied and numerically calculated. It is shown the CTP frequencies reside in the terahertz range and can be represented as a product of two factors: the Fermi level of graphene and the geometry of the NP complex. The energy losses in the NPs are predicted to be inversely dependent on the radius R of the nanoparticle, while the loss in graphene is proportional to R and the interparticle distance. The CTP quality factors are predicted to be in the range ~ 10 – 100. The absorption power under CTP excitation is proportional to the scalar product of the CTP dipole moment and the external electromagnetic field. The developed theory makes it possible to simulate different properties of CTPs 3–4 orders of magnitude faster compared to the original FEM or the finite-difference time domain method, providing possibilities for predicting the plasmonic properties of very large systems for different applications.

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Держатели документа:
International Research Center of Spectroscopy and Quantum Chemistry, Siberian Federal University, 660041 Krasnoyarsk, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia
Institute of Computational Modeling SB RAS, 660036 Krasnoyarsk, Russia
Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala, Sweden

Доп.точки доступа:
Fedorov, A. S.; Федоров, Александр Семенович; Eremkin, E. V.; Krasnov, P. O.; Gerasimov, V. S.; Agren, H.; Polyutov, S. P.
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2.


    Bikbaev, R. G.
    Transparent conductive oxides for the epsilon-near-zero Tamm plasmon polaritons / R. G. Bikbaev, S. Ya Vetrov, I. V. Timofeev // J. Opt. Soc. Am. B. - 2019. - Vol. 36, Is. 10. - P. 2817-2823, DOI 10.1364/JOSAB.36.002817. - Cited References: 44. - The reported study was funded by RFBR according to the research project No 18-32-00053 and financial support RFBR and MOST according to the research project No 19-52-52006. . - ISSN 0740-3224
Кл.слова (ненормированные):
Aluminum oxide -- II-VI semiconductors -- Indium compounds -- Infrared devices -- Optical films -- Phonons -- Photons -- Plasmons -- Q factor measurement -- Tin oxides -- Transfer matrix method -- Transparent conducting oxides -- Zinc oxide
Аннотация: We demonstrate the possibility of using transparent conducting oxides [aluminum-doped zinc oxide (AZO), gallium-doped zinc oxide (GZO), indium tin oxide (ITO)] to form Tamm plasmon polaritons in the near-infrared spectral range where the permittivity of oxides is near zero. The spectral properties of the structures are investigated in the framework of the temporal coupled-mode theory and confirmed by the transfer matrix method. It is found that in the critical coupling conditions, the maximal Q-factor of a Tamm plasmon polariton is achieved when a photonic crystal is conjugated with the AZO film, while at the conjugation with the ITO films, the broadest spectral line is obtained. The sensitivity of the wavelength and spectral width of the Tamm plasmon polariton to changes in the oxide film thickness, bulk concentration of a dopant, and angle of incidence is demonstrated.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Vetrov, S. Ya.; Ветров, Степан Яковлевич; Timofeev, I. V.; Тимофеев, Иван Владимирович; Бикбаев, Рашид Гельмединович
}
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3.


   
    Broadband Tamm plasmons in chirped photonic crystals for light-induced water splitting / M. V. Pyatnov, R. G. Bikbaev, I. V. Timofeev [et al.] // Nanomaterials. - 2022. - Vol. 12, Is. 6. - Ст. 928, DOI 10.3390/nano12060928. - Cited References: 41 . - ISSN 2079-4991
Кл.слова (ненормированные):
water splitting -- plasmon catalysis -- solar-to-hydrogen efficiency -- photocurrent
Аннотация: An electrode of a light-induced cell for water splitting based on a broadband Tamm plasmon polariton localized at the interface between a thin TiN layer and a chirped photonic crystal has been developed. To facilitate the injection of hot electrons from the metal layer by decreasing the Schottky barrier, a thin n-Si film is embedded between the metal layer and multilayer mirror. The chipping of a multilayer mirror provides a large band gap and, as a result, leads to an increase in the integral absorption from 52 to 60 percent in the wavelength range from 700 to 1400 nm. It was shown that the photoresponsivity of the device is 32.1 mA/W, and solar to hydrogen efficiency is 3.95%.

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Держатели документа:
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Institute of Computer Modelling, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Pyatnov, M. V.; Пятнов, Максим Владимирович; Bikbaev, R. G.; Бикбаев, Рашид Гельмединович; Timofeev, I. V.; Тимофеев, Иван Владимирович; Ryzhkov, I. I.; Vetrov, S. Ya.; Ветров, Степан Яковлевич; Shabanov, V. F.; Шабанов, Василий Филиппович
}
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4.


   
    Charge transfer plasmons in the arrays of nanoparticles connected by conductive linkers / A. S. Fedorov, M. A. Visotin, V. S. Gerasimov [et al.] // J. Chem. Phys. - 2021. - Vol. 154, Is. 8. - Ст. 012009, DOI 10.1063/5.0040128. - Cited References: 41. - This study was supported by the Russian Science Foundation, Project No. 18-13-00363 . - ISSN 0021-9606
Кл.слова (ненормированные):
Analytical expressions -- Carrier scattering -- Charge displacement -- External electromagnetic field -- Finite difference time domain simulations -- Metallic nanoparticles -- Numerical solution -- Plasmon oscillations
Аннотация: Charge transfer plasmons (CTPs) that occur in different topology and dimensionality arrays of metallic nanoparticles (NPs) linked by narrow molecular bridges are studied. The occurrence of CTPs in such arrays is related to the ballistic motion of electrons in thin linkers with the conductivity that is purely imaginary, in contrast to the case of conventional CTPs, where metallic NPs are linked by thick bridges with the real optical conductivity caused by carrier scattering. An original hybrid model for describing the CTPs with such linkers has been further developed. For different NP arrays, either a general analytical expression or a numerical solution has been obtained for the CTP frequencies. It has been shown that the CTP frequencies lie in the IR spectral range and depend on both the linker conductivity and the system geometry. It is found that the electron currents of plasmon oscillations correspond to minor charge displacements of only few electrons. It has been established that the interaction of the CTPs with an external electromagnetic field strongly depends on the symmetry of the electron currents in the linkers, which, in turn, are fully governed by the symmetry of the investigated system. The extended model and the analytical expressions for the CTPs frequencies have been compared with the conventional finite difference time domain simulations. It is argued that applications of this novel type of plasmon may have wide ramifications in the area of chemical sensing.

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Держатели документа:
International Research Center of Spectroscopy and Quantum Chemistry - IRC SQC, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
National Research Tomsk State University, Tomsk, 634050, Russian Federation
Institute of Computational Modelling, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Federal Siberian Research Clinical Centre, FMBA of Russia, Krasnoyarsk, 660037, Russian Federation
Kyungpook National University, Daegu, 41566, South Korea

Доп.точки доступа:
Fedorov, A. S.; Федоров, Александр Семенович; Visotin, M. A.; Высотин, Максим Александрович; Gerasimov, V. S.; Polyutov, S. P.; Avramov, P. A.
}
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5.


   
    Charge-transfer plasmons of complex nanoparticle arrays connected by conductive molecular bridges / A. S. Fedorov, M. A. Visotin, E. V. Eremkin [et al.] // Phys. Chem. Chem. Phys. - 2022. - Vol. 24, Is. 32. - P. 19531-19540, DOI 10.1039/d2cp01811j. - Cited References: 43. - The work is supported (ASF, EVE, POK, and SPP) by the Russian Science Foundation (project no. 18-13-00363) . - ISSN 1463-9076
Кл.слова (ненормированные):
Charged nanoparticles -- Complex nanoparticles -- Coulombs energy -- External electromagnetic field -- Molecular bridges -- Molecular dynamics algorithms -- Molecular linkers -- Nanoparticle array -- Plasmon frequency -- Statistic approaches
Аннотация: Charge-transfer plasmons (CTP) in complexes of metal nanoparticles bridged by conductive molecular linkers are theoretically analysed using a statistic approach. The applied model takes into account the kinetic energy of carriers inside the linkers including its dissipation and the Coulomb energy of the charged nanoparticles. The plasmons are statistically investigated for systems containing a large number of complexes of bridged nanoparticles of realistic sizes generated using a simplified molecular dynamics algorithm, where the geometries of the complexes are dependent on the rate of connection of the linkers with the nanoparticles. As illustrated, the distribution of CTP frequencies in the generated nanoparticle complexes is very inhomogeneous. It has a narrow peak, corresponding to CTP plasmons in dimers, and two broad peaks, corresponding mainly to low and high-frequency oscillations in chains of connected nanoparticles. It is found that in general the plasmon frequencies depend inversely on the value of the complex dipole moment of the plasmon oscillation, where the assumption follows that low-frequency plasmons will be more efficiently excited in an external electromagnetic field. To calculate the CTP energy absorption in this field two model modifications are proposed: a system-external electromagnetic field interaction model and a simplified broadening plasmon peak model where the plasmons are calculated at first without damping and where the delta-shaped oscillation peaks are broadened then due to the damping. It is demonstrated that both modifications lead to a wide and almost monotonic absorption in the IR region for all generated systems containing a large number of bridged nanoparticles due to the presence of a large number of CTPs in this region.

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Держатели документа:
International Research Center of Spectroscopy and Quantum Chemistry - IRC SQC, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Department of Physics and Astronomy, Uppsala University, Box 516, Uppsala, SE-751 20, Sweden
Federal Siberian Research Clinical Center under FMBA of Russia, Krasnoyarsk, 660037, Russian Federation

Доп.точки доступа:
Fedorov, A. S.; Федоров, Александр Семенович; Visotin, M. A.; Высотин, Максим Александрович; Eremkin, E. V.; Krasnov, P. O.; Agren, H.; Polyutov, S. P.
}
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6.


   
    Charge-transfer plasmons with narrow conductive molecular bridges: A quantum-classical theory / A. S. Fedorov, P. O. Krasnov, M. A. Visotin [et al.] // J. Chem. Phys. - 2019. - Vol. 150, Is. 24. - Ст. 244125, DOI 10.1063/1.5131734. - Cited References: 56. - This study was supported by the Russian Science Foundation, Project No. 18-13-00363. . - ISSN 0021-9606. - ISSN 1089-7690
   Перевод заглавия: Плазмоны с переносом заряда в системах с узкими проводящими молекулярными мостиками: квантово-классическая теория
Аннотация: We analyze a new type of plasmon system arising from small metal nanoparticles linked by narrow conductive molecular bridges. In contrast to the well-known charge-transfer plasmons, the bridge in these systems consists only of a narrow conductive molecule or polymer in which the electrons move in a ballistic mode, showing quantum effects. The plasmonic system is studied by an original hybrid quantum-classical model accounting for the quantum effects, with the main parameters obtained from first-principles density functional theory simulations. We have derived a general analytical expression for the modified frequency of the plasmons and have shown that its frequency lies in the near-infrared (IR) region and strongly depends on the conductivity of the molecule, on the nanoparticle–molecule interface, and on the size of the system. As illustrated, we explored the plasmons in a system consisting of two small gold nanoparticles linked by a conjugated polyacetylene molecule terminated by sulfur atoms. It is argued that applications of this novel type of plasmon may have wide ramifications in the areas of chemical sensing and IR deep tissue imaging.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia
Federal Siberian Research Clinical Center under FMBA of Russia, 660037 Krasnoyarsk, Russia
Siberian Federal University, 660041 Krasnoyarsk, Russia
Reshetnev Siberian State University of Science and Technology, 660037 Krasnoyarsk, Russia
Division of Theoretical Chemistry and Biology, Royal Institute of Technology, SE-100 44 Stockholm, Sweden

Доп.точки доступа:
Fedorov, A. S.; Федоров, Александр Семенович; Krasnov, P. O.; Visotin, M. A.; Высотин, Максим Александрович; Tomilin, F. N.; Томилин, Феликс Николаевич; Polyutov, S. P.; Полютов, Сергей Петрович; Ågren, H.
}
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7.


   
    Dissipative chaos in semiconductor superlattices / K. N. Alekseev [et al.] // Phys. Rev. B. - 1996. - Vol. 54, Is. 15. - P. 10625-10636, DOI 10.1103/PhysRevB.54.10625. - Cited References: 89 . - ISSN 0163-1829
РУБ Physics, Condensed Matter
Рубрики:
NEGATIVE DIFFERENTIAL CONDUCTIVITY
   INJECTED SIGNAL

   BLOCH OSCILLATIONS

   COLLECTIVE EXCITATIONS

   DETERMINISTIC CHAOS

   MINIBAND TRANSPORT

   SURFACE-PLASMONS

   TIME-SERIES

   LASER

   VELOCITY

Аннотация: We consider the motion of ballistic electrons in a miniband of a semiconductor superlattice (SSL) under the influence of an external, time-periodic electric field. We use a semiclassical, balance-equation approach, which incorporates elastic and inelastic scattering (as dissipation) and the self-consistent field generated by the electron motion. The coupling of electrons in the miniband to the self-consistent held produces a cooperative nonlinear oscillatory mode which, when interacting with the oscillatory external field and the intrinsic Bloch-type oscillatory mode, can lead to complicated dynamics, including dissipative chaos. For a range of values of the dissipation parameters we determine the regions in the amplitude-frequency plane of the external field in which chaos can occur. Our results suggest that for terahertz external fields of the amplitudes achieved by present-day free-electron lasers, chaos may be observable in SSL's. We clarify the nature of this interesting nonlinear dynamics in the superlattice-external-field system by exploring analogies to the Dicke model of an ensemble of two-level atoms coupled with a resonant cavity field, and to Josephson junctions.

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Держатели документа:
LOS ALAMOS NATL LAB,DIV THEORET,LOS ALAMOS,NM 87545
LV KIRENSKII INST PHYS,KRASNOYARSK 660036,RUSSIA
UNIV ILLINOIS,DEPT PHYS,URBANA,IL 61801
ИФ СО РАН

Доп.точки доступа:
Alekseev, K. N.; Berman, G. P.; Campbell, D. K.; Cannon, E. H.; Cargo, M. C.
}
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8.


   
    Intense charge transfer plasmons in golden nanoparticle dimers connected by conductive molecular linkers / A. S. Fedorov, M. A. Visotin, A. V. Lukyanenko [et al.] // J. Chem. Phys. - 2024. - Vol. 160, Is. 8. - Ст. 084110, DOI 10.1063/5.0183334. - Cited References: 52. - This study was supported by the Russian Science Foundation, Agreement No. 23-12-20007, and the Government of the Krasnoyarsk Territory and the Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, Agreement No. 256 . - ISSN 0021-9606. - ISSN 1089-7690
Аннотация: Golden nanoparticle dimers connected by conjugated molecular linkers 1,2-bis(2-pyridyl)ethylene are produced. The formation of stable dimers with 22 nm diameter nanoparticles is confirmed by transmission electron microphotography. The possibility of charge transfer through the linkers between the particles in the dimers is shown by the density functional theory calculations. In addition to localized plasmon resonance of solitary nanoparticles with a wavelength of 530 nm, the optical spectra exhibit a new intense absorption peak in the near-infrared range with a wavelength of ∼780 nm. The emergent absorption peak is attributed to the charge-transfer plasmon (CTP) mode; the spectra simulated within the CTP developed model agree with the experimental ones. This resonant absorption may be of interest to biomedical applications due to its position in the so-called transmission window of biological tissues. The in vitro heating of CTP dimer solution by a laser diode with a wavelength of 792 nm proved the efficiency of CTP dimers for achieving a temperature increase of ΔT = 6 °C, which is sufficient for hyperthermia treatment of malignant tumors. This indicates the possibility of using hyperthermia to treat malignant tumors using the material we synthesized.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia
International Research Center of Spectroscopy and Quantum Chemistry – IRC SQC, Siberian Federal University, 660041 Krasnoyarsk, Russia
Siberian Federal University, 660041 Krasnoyarsk, Russia
Institute of Computational Modeling, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia

Доп.точки доступа:
Fedorov, A. S.; Федоров, Александр Семенович; Visotin, M. A.; Высотин, Максим Александрович; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Gerasimov, V. S.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич
}
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9.


    Karpov, S. V.
    Simulation of conditions for fabrication of optical nanowaveguides in the form of chains of spherical metal nanoparticles by electrostatic functionalization of the process substrate / S. V. Karpov, I. L. Rasskazov // Colloid J. - 2013. - Vol. 75, Is. 3. - P. 279-288, DOI 10.1134/S1061933X13030083 . - ISSN 1061-933X
Кл.слова (ненормированные):
Deposition of metals -- Electrical parameter -- Experimental conditions -- Nonuniform electric field -- Ordered structures -- Selective deposition -- Single-domain structure -- Transmission property -- Deposition -- Electric fields -- Mathematical models -- Metal nanoparticles -- Photoexcitation -- Plasmons -- Sols -- Substrates
Аннотация: A method is proposed for electrostatic functionalization of substrates used to prepare ordered structures composed of closely spaced plasmon-resonant nanoparticles. The method ensures selective deposition of nanoparticles from the bulk of a colloidal system onto the substrates. This method is based on placing a metal nanotemplate of a required configuration at the opposite side of a substrate, with an electric potential being applied to the template. A mathematical model is developed to ensure that the system parameters responsible for the deposition of metal nanoparticles into ordered single-domain structures on the substrate from a bulk sol in a nonuniform electric field generated by the nanotemplate correspond to the real experimental conditions. Since the degree of imperfection of the synthesized chains governs the applicability of these structures to transmission of the optical excitation at the frequency of the surface plasmon of the particles, the dependence of the degree of imperfection on the physicochemical and electrical parameters of the system is studied using the Brownian-dynamics model. The calculations of the spectral and transmission properties of nanowaveguides of this type are exemplified. В© 2013 Pleiades Publishing, Ltd.

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Публикация на русском языке Моделирование условий синтеза оптических нановолноводов из цепочек сферических металлических наночастиц методом электростатической функционализации технологической подложки. - [S. l. : s. n.]

Держатели документа:
Russian Acad Sci, Siberian Branch, Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660028, Russia;

Доп.точки доступа:
Рассказов, Илья Леонидович; Rasskazov, I. L.; Карпов, Сергей Васильевич
}
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10.


    Mankov, Yu. I.
    Bulk plasma waves in a randomly inhomogeneous conductor / Yu. I. Mankov // Phys. Solid State. - 2012. - Vol. 54, Is. 7. - P. 1323-1331, DOI 10.1134/S1063783412070268. - Cited References: 27 . - ISSN 1063-7834
РУБ Physics, Condensed Matter
Рубрики:
VOLUME PLASMONS
   DISPERSION

   PLASMAVERLUSTES

   SURFACE

Аннотация: The modification of the spectrum and damping of bulk plasma waves due to three-dimensional random inhomogeneities of the density of a degenerate electron gas in a conductor have been investigated using the averaged Green’s function method. The dependences of the frequency and damping of the averaged plasma waves, as well as the position ν m and width Δν of the peak of the imaginary part of the Fourier trans-form of the averaged Green’s function, on the wave vector k have been determined in the self-consistent approximation, which makes it possible to take into account multiple scattering of plasma waves by inhomogeneities. It has been found that, in the long-wavelength region of the spectrum, the decrease revealed in the frequency of the plasma waves is caused by the inhomogeneities, which agrees qualitatively with the behavior of the position of the peak ν m . In the range of large values of the correlation length of inhomogeneities and small values of k, the damping of the plasma waves tends to zero, whereas the width of the peak Δν remains finite, which is due to the nonuniform broadening. A comparison with the data of numerical calculations has been performed.

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Публикация на русском языке Маньков, Юрий Иннокентьевич. Объемные плазменные волны в случайно-неоднородном проводнике [Текст] / Ю. И. Маньков // Физ. тверд. тела : Физико-технический институт им. А.Ф.Иоффе РАН, 2012. - Т. 54 Вып. 7. - С. 1249-1255


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Маньков, Юрий Иннокентьевич
}
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