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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Аверьянов, Евгений Михайлович
Заглавие : Оптическая анизотропия и ориентационный порядок одноосных пленок сопряженных полимеров
Место публикации : Жидк. кристаллы и их практич. использ. - 2020. - Т. 20, № 1. - С. 53-63. - ISSN 1991-3966, DOI 10.18083/LCAppl.2020.1.53; Liq. Cryst. Appl.
Примечания : Библиогр.: 14
Аннотация: Для одноосной пленки сопряженного полимера с макромолекулами в виде наборов субъединиц разной длины установлена связь компонент e(1,2)j(w) диэлектрической функции ej(w) = e1j(w) + ie2j(w) с параметром ориентационного порядка s дипольных моментов молекулярных переходов, отвечающих изолированной полосе поглощения света c поляризацией вдоль (j = || ) и нормально (j =. ) оптической оси пленки. Новые методы определения s реализованы для пленки полимера P3OT с плоскостной ориентацией субъединиц и известными зависимостями e(1,2)j(w) в областях прозрачности и низкочастотного электронного поглощения. Учтена анизотропия компонент fj(w) = 1 + Lj[ej(w) - 1] тензора локального поля. Экспериментальные значения компонент Lj тензора Лорентца для пленки P3OT определены с использованием зависимостей e1j(w) в видимой области прозрачности. Показано совместное влияние длины и ориентационного порядка субъединиц, а также динамических диполь-дипольных взаимодействий между субъединицами (эффектов локального поля) на положение максимумов полос e2j(w).The uniaxial film of conjugated polymer with macromolecules as a set of subunits of different lengths was studied. For this film, the connection between the components e(1,2)j(w) of the dielectric function ej(w) = e1j(w) + ie2j(w) and the orientation order parameter s was established. The orientation order parameter s of the dipole moments of molecular transitions corresponds to an isolated absorption band of light with polarization along (j = ||) and across (j =. the optical axis of the film. New methods have been implemented for determining s of the P3OT polymer film. The P3OT polymer film is characterized by a planar orientation of subunits and known dependences e(1,2)j(w) in the regions of transparency and low-frequency electron absorption. The anisotropy of the components fj(w) = 1 + Lj[ej(w) - 1] of the local-field tensor was taken into account. The experimental values of the components Lj of the Lorentz tensor for the P3OT film were determined using the dependences e1j(w) in the visible transparency region. The combined effect of the length and orientation order of the subunits, as well as dynamic dipole-dipole interactions between subunits (local-field effects) on the position of the maxima of the e2j(w) bands was shown.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Parshin A. M., Sutormin V. S., Zyryanov V. Ya., Shabanov V. F.
Заглавие : Polar anchoring energy and tilt angle measured by magneto-optical technique in nematic doped with ionic surfactant
Место публикации : Liq. Cryst. - 2020. - Vol. 47, Is. 12. - P.1825-1831. - ISSN 0267-8292, DOI 10.1080/02678292.2020.1733683. - ISSN 1366-5855(eISSN)
Примечания : Cited References: 32
Предметные рубрики: LIQUID-CRYSTAL
TEMPERATURE-DEPENDENCE
INTERFACE
ADSORPTION
Аннотация: The surface anchoring of a nematic doped with the ionic surfactant has been investigated and compared with the one in the undoped sample. The director tilt angle at the substrates coated with the orienting polymer film has been determined by the null method in a rotating magnetic field. The Frederiks transition in a magnetic field has been chosen as a convenient technique to measure the polar anchoring energy Wθ. The temperature dependences of anchoring energy have been obtained for the various nematic cells. The Wθ values for nematic doped with the ionic surfactant are less than for the undoped one. The factors affecting the measurement accuracy have been discussed. The accuracy is higher for the thinner nematic layers and weaker anchoring energy.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Loiko V. A., Konkolovich A. V., Miskevich A. A., Krakhalev M. N., Prishchepa O. O., Zyryanov V. Ya.
Заглавие : Small-angle scattering and radiation polarization by a stretched polymer film with nematic liquid crystal droplets having a single-domain structure
Коллективы : Belarusian Republican Foundation for Fundamental Research [F18RA-003]; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of Krasnoyarsk krai; Krasnoyarsk Krai Foundation of Science [18-42-243006]
Место публикации : Opt. Spectrosc. - 2020. - Vol. 128, Is. 3. - P.331-338. - ISSN 0030-400X, DOI 10.1134/S0030400X20030121. - ISSN 1562-6911(eISSN)
Примечания : Cited References: 24. - This work was carried out within the framework of the agreement on interacademic collaboration between the National Academy of Sciences of Belarus and Siberian Branch of the Russian Academy of Sciences. It was supported by the Belarusian Republican Foundation for Fundamental Research (project no. F18RA-003). M.N. Krakhalev acknowledges the support of the Russian Foundation for Basic Research, the Government of Krasnoyarsk krai, and Krasnoyarsk Krai Foundation of Science (grant no. 18-42-243006).
Предметные рубрики: IONIC MODIFICATION
LIGHT
Аннотация: The coefficient of directed transmittance of a stretched polymer-dispersed liquid crystal film with a defect-free single-domain liquid crystal droplet structure formed by a stretched surfactant-doped film and the polarization degree of forward-transmitted light in the visible and near-infrared spectrum ranges are studied. Results are presented for the 5CB, E7, and E44 nematic liquid crystals. Dependences of the transmission coefficient and polarizing ability of the film on the photodetector field of view are studied. Relationships allowing one to determine film parameters at which the transmission coefficient and polarizing ability of the films simultaneously reach values close to limit ones (0.5 and ±1.0, respectively) are obtained in the Foldy–Twersky and anomalous diffraction approximations.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gunyakov V. A., Krakhalev M. N., Timofeev I. V., Zyryanov V. Ya., Shabanov V. F.
Заглавие : Optical modes of multilayered photonic structure containing nematic layer with abnormal electroconvective rolls
Место публикации : Opt. Mater. - 2020. - Vol. 100. - Ст.109630. - ISSN 09253467 (ISSN), DOI 10.1016/j.optmat.2019.109630
Примечания : Cited References: 30. - We are grateful to M.N. Volochaev for providing TEM micrograph of the mirror
Аннотация: Optical modes of a multilayered photonic structure with the twisted nematic liquid crystal as a defect layer have been investigated. The electroconvective flow in the nematic makes a spatially periodic structure in the form of abnormal rolls. Non-adiabatic propagation of polarized light in the defect layer causes unique features of the optical modes corresponding to the ordinary o-waves. The decay of these modes has been demonstrated with increasing voltage due to the effect of cross-polarization diffraction loss. The modes short-wave shift resulting from the contribution of the non-adiabatic geometric phase to the total phase delay of the wave during a round-trip propagation through the photonic structure has been found both experimentally and numerically.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Кузьменок Н. М., Михалёнок С. Г., Орёл А. С., Shevchuk M. O., Bezborodov V. S., Крахалев, Михаил Николаевич, Сутормин, Виталий Сергеевич, Прищепа, Оксана Олеговна, Жаркова Г. М., Zyryanov V. Ya.
Заглавие : Синтез органилтрифенилфосфоний галогенидов, четвертичных аммонийных солей и исследование их применения в качестве сурфактантов, растворимых в жидких кристаллах
Место публикации : Жидк. кристаллы и их практич. использ. - 2020. - Т. 20, № 1. - С. 6-18. - ISSN 1991-3966, DOI 10.18083/LCAppl.2020.1.6; Liq. Cryst. Appl.
Примечания : Библиогр.: 18. - Работа выполнена частично при финансировании по проекту междисциплинарных интеграционных исследований СО РАН.
Аннотация: Синтезированы четвертичные аммонийные соли и органилтрифенилфосфоний галогениды, ионы которых могут оказывать ориентирующее воздействие на жидкие кристаллы. Исследована растворимость полученных соединений в нематическом жидком кристалле – 4-пентил-4'-цианобифениле (5ЦБ). Показано, что две аммонийные соли не только растворяются в нематике, но и диссоциируют на ионы. При этом анионы, перемещаясь в электрическом поле, способны модифицировать граничные условия, что открывает возможность использования данных соединений для ионно-сурфактантного метода управления жидкокристаллическими материалами.Quaternary ammonium salts and organotriphenylphosphonium halides have been synthesized. Their ions can have an orienting effect on liquid crystals. The solubility of the obtained compounds in the nematic liquid crystal - 4-cyano-4'-pentylbiphenyl (5CB) has been studied. It was shown that two ammonium salts both dissolve in the nematic and also dissociate into ions. At that, the anions moving in electric field can modify the boundary conditions. This fact allows using these compounds for the ion-surfactant method of controlling liquid crystal materials.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Аверьянов, Евгений Михайлович
Заглавие : Новые методы исследования ориентационного порядка одноосных молекулярных пленок на основе оптических данных
Место публикации : Жидк. кристаллы и их практич. использ. - 2020. - Т. 20, № 1. - С. 41-46. - ISSN 1991-3966, DOI 10.18083/LCAppl.2020.1.41; Liq. Cryst. Appl.
Примечания : Библиогр.: 7
Аннотация: Установлена связь компонент ε(1,2)j(ω) диэлектрической функции εj(ω) = ε1j(ω) + iε2j(ω) для одноосной молекулярной пленки в области изолированной полосы поглощения света, поляризованного вдоль (j = ||) и нормально (j = ⊥) оптической оси пленки, с параметром ориентационного порядка S дипольных моментов молекулярных переходов, отвечающих данной полосе поглощения. Развиты новые методы определения S, подтвержденные для пленки органического полупроводника PTCDA нанометровой толщины с известными зависимостями ε(1,2)j(ω) в областях прозрачности и низкочастотного электронного поглощения. Показано влияние ориентационного порядка и анизотропии динамических диполь-дипольных межмолекулярных взаимодействий (эффектов локального поля) на положение максимумов полос ε2j(ω).The components ε(1,2)j(ω) of the dielectric function εj(ω) = ε1j(ω) + iε2j(ω) for uniaxial molecular film in the region of an isolated absorption band of the light polarized along (j = ||) and across (j = ⊥) the film optical axis were considered. The connection of the components with the orientation order parameter S of the dipole moments of molecular transitions corresponding to a given absorption band was established. New methods for determining S are developed. They are confirmed for the organic semiconductor PTCDA film of nanoscale thickness with the known dependences ε(1,2)j(ω) in the transparency and low-frequency electron absorption regions. The effect of the orientation order and anisotropy of dynamic dipole-dipole intermolecular interactions (local-field effects) on the maxima position of the ε2j(ω) bands was shown.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Паршин, Александр Михайлович, Баранник, Алексей Владимирович
Заглавие : Оптическое пропускание доменной структуры нематика на поверхности полимера в магнитном поле
Место публикации : Жидк. кристаллы и их практич. использ. - 2020. - Т. 20, Вып. 2. - С. 62-68. - ISSN 1991-3966, DOI 10.18083/LCAppl.2020.2.62; Liq. Cryst. Appl.
Примечания : Библиогр.: 20
Предметные рубрики: LIGHT-SCATTERING
DEFECTS
Аннотация: Исследовано распространение лазерного луча через слой гибридно-упорядоченного нематика с поверхностной линией дисклинации, состоящий из доменов с радиальной конфигурацией нематического директора на пленке поликарбоната. Ориентационная структура в объеме домена трансформируется в планарную одноосную, задаваемую линией дисклинации, либо в гомеотропную под действием магнитного поля. Получена зависимость интенсивности света, прошедшего через слой, от магнитного поля, прикладываемого перпендикулярно поверхности полимера. Оптическое пропускание сопровождалось интерференционными минимумами и максимумами. Представлена модель интерференции света, основанная на двулучепреломлении, учитывающая рассеяние на ориентационно-структурных неоднородностях доменного ансамбля. Из рассмотрения свободной энергии жидкого кристалла и эффектов двулучепреломления выведено аналитическое выражение, устанавливающее зависимость между интенсивностью света и напряженностью магнитного поля, совпадающее с экспериментом.The propagation of a laser beam through a layer of a hybrid ordered nematic on a polycarbonate film is studied. The nematic has a surface disclination line consisting of domains with a radial configuration of the nematic director. The orientational structure in the domain volume can be transformed into a planar uniaxial structure defined by a disclination line or into a homeotropic one under the influence of a magnetic field. The dependence of the light intensity transmitted through the layer on the magnetic field applied perpendicular to the polymer surface is obtained. Optical transmission was accompanied by interference minima and maxima. Light interference model based on birefringence which takes into account scattering by the orientation-structural inhomogeneities of the domain ensemble is presented. Considering the analysis of the liquid crystal free energy and the birefringence effects, an analytical expression is derived. It establishes the relationship between the light intensity and the magnetic field strength, which coincides with the experiment.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Avdeeva A. Yu., Vetrov S. Ya., Bikbaev R. G., Pyatnov M. V., Rudakova N. V., Timofeev I. V.
Заглавие : Chiral optical Tamm states at the interface between a Dye-doped cholesteric liquid crystal and an anisotropic mirror
Коллективы : Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund [19-42-240004]; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [19-52-52006]
Место публикации : Materials. - 2020. - Vol. 13, Is. 15. - Ст.3255. - ISSN 1996-1944(eISSN), DOI 10.3390/ma13153255
Примечания : Cited References: 44. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project No. 19-42-240004 and by Russian Foundation for Basic Research, project No. 19-52-52006
Предметные рубрики: PHASE
POLARIZATION
MODES
Аннотация: The resonant splitting of optical Tamm state numerically is demonstrated. The Tamm state is localized at the interface between a resonant chiral medium and a polarization-preserving anisotropic mirror. The chiral medium is considered as a cholesteric liquid crystal doped with resonant dye molecules. The article shows that the splitting occurs when dye resonance frequency coincides with the frequency of the Tamm state. In this case the reflectance, transmittance, and absorptance spectra show two distinct Tamm modes. For both modes, the field localization is at the interface between the media. The external field control of configurable optical and structural parameters paves the way for use in tunable chiral microlaser.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Parshin A. M., Barannik A. V., Zyryanov V. Ya., Shabanov V. F.
Заглавие : Light interference in a hybrid-aligned nematic layer with nonordered surface disclination lines
Место публикации : J. Opt. Soc. Am. B. - 2020. - Vol. 37, Is. 7. - P.2053-2057. - ISSN 0740-3224, DOI 10.1364/JOSAB.395976. - ISSN 1520-8540(eISSN)
Примечания : Cited References: 19
Предметные рубрики: LIQUID-CRYSTAL
SCATTERING
DEFECTS
DOMAINS
Аннотация: The propagation of a laser beam through a hybrid-aligned nematic layer with a surface disclination line has been investigated. A model of the light interference has been developed to consider the scattering by the structural inhomogeneities. The analytical expression that includes the factor characterizing an exponential decrease in the light scattering has been obtained. The dependence of the intensity of light transmitted through the layer on the magnetic field has been measured. The dependence has been accompanied by the interference oscillations. The theoretical expression is consistent with the experiment, which confirms the correctness of the model concepts.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Prishchepa O. O., Sutormin V. S., Bikbaev R. G., Timofeev I. V., Zyryanov V. Ya.
Заглавие : Electrically induced transformations of defects in cholesteric layer with tangential-conical boundary conditions
Место публикации : Sci. Rep. - 2020. - Vol. 10, Is. 1. - Ст.4907. - ISSN 20452322 (ISSN), DOI 10.1038/s41598-020-61713-9
Примечания : Cited References: 45. - The authors are grateful for the financial support by the Russian Science Foundation (Grant No. 18-72-10036)
Аннотация: Electric-field-induced changes of the orientational structures of cholesteric liquid crystal layer with the tangential-conical boundary conditions have been investigated. The samples with the ratio of the cholesteric layer thickness d to the helix pitch p equalled to 0.57 have been considered. The perpendicularly applied electric field causes a decrease of the azimuthal director angle at the substrate with the conical surface anchoring. In the cells with d = 22 μm, the defect loops having the under-twisted and over-twisted areas are formed. At the defect loop the pair of point peculiarities is observed where the 180° jump of azimuthal angle of the director occurs. Under the action of electric field the loops shrink and disappear. In the cells with d = 13 μm, the over-twisted and under-twisted defect lines are formed. Applied voltage results in the shortening of lines or/and their transformation into a defect of the third type. The director field distribution near defect lines of three types has been investigated by the polarising microscopy techniques. It has been revealed that the length ratio between the over-twisted and third-type defect lines can be controlled by the electric field.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gardymova, Anna P., Krakhalev M. N., Zyryanov V. Ya.
Заглавие : Optical textures and orientational structures in cholesteric droplets with conical boundary conditions
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [18-72-10036]
Место публикации : Molecules. - 2020. - Vol. 25, Is. 7. - Ст.1740. - ISSN 1420-3049(eISSN), DOI 10.3390/molecules25071740
Примечания : Cited References: 53. - The authors are grateful for the financial support by the Russian Science Foundation (grant No. 18-72-10036).
Предметные рубрики: DISPERSED LIQUID-CRYSTALS
CHIRAL NEMATIC DROPLETS
IONIC MODIFICATION
Аннотация: Cholesteric droplets dispersed in polymer with conical boundary conditions have been studied. The director configurations are identified by the polarising microscopy technique. The axisymmetric twisted axial-bipolar configuration with the surface circular defect at the droplet’s equator is formed at the relative chirality parameter N0≤2.9 . The intermediate director configuration with the deformed circular defect is realised at 2.9N03.95 , and the layer-like structure with the twisted surface defect loop is observed at N0≥3.95 . The cholesteric layers in the layer-like structure are slightly distorted although the cholesteric helix is untwisted.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vetrov S. Ya., Timofeev I. V., Shabanov V. F.
Заглавие : Localized modes in chiral photonic structures
Место публикации : Phys. Usp. - 2020. - Vol. 63, Is. 1. - P.33-56. - ISSN 1063-7869, DOI 10.3367/UFNe.2018.11.038490. - ISSN 1468-4780(eISSN)
Примечания : Cited References: 251
Предметные рубрики: CHOLESTERIC LIQUID-CRYSTAL
CONTROLLED LIGHT-SCATTERING
SCULPTURED THIN-FILMS
Аннотация: We discuss chiral structures in self-organizing, artificial, and biological materials. A review of experimental studies and recent advances in the localization of light in chiral structures is given. The behavior of polarized resonant modes in such structures is examined using the example of a one-dimensional photonic crystal containing liquid crystal materials. The anomalous spectral shifts of transmission peaks are interpreted as the contribution of the geometric phase caused by the twisting of the layers of the liquid crystal. The optical Tamm state localized at the boundary between chiral and nonchiral mirrors in the form of a cholesteric layer and a polarization-preserving anisotropic mirror is analytically and numerically described. Considerable attention is paid to the presentation of the properties of localized optical modes in the cholesteric with a resonant metal-dielectric nanocomposite. New possibilities for controlling the properties of the photonic structure are noted, due to the combination of the dispersion of the resonant medium and the intrinsic dispersion of the cholesteric. Attention is focused on controlled hybrid modes in the cholesteric structure formed by the coupling of localized modes. Possible applications and further ways of developing the concept of chiral photonic structures are deliberated.
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13.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Loiko V. A., Konkolovich A. V., Miskevich A. A., Prishchepa O. O., Shabanov A. V., Krakhalev M. N., Zyryanov V. Ya.
Заглавие : Polymer films with elongated droplets of nematic liquid crystal: light transmission, scattering, and polarization
Коллективы : European Conference on Liquid Crystals
Место публикации : 15th Eur. Conf. Liq. Cryst. (ECLC): conf. progr. - 2019. - Ст.H2-O-31
Примечания : Cited References: 3
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14.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Prishchepa O. O., Feyzer K. A., Krakhalev M. N., Sutormin V. S., Loiko V. A., Miskevich A. A., Zyryanov V. Ya.
Заглавие : Polymer dispersed liquid crystal films with conical boundary conditions for electrically controllable polarizers
Коллективы : European Conference on Liquid Crystals
Место публикации : 15th Eur. Conf. Liq. Cryst. (ECLC): conf. progr. - 2019. - Ст.H2-O-33
Примечания : Cited References: 2. - The study was funded by the Russian Foundation for Basic Research (grant No. 18-42-243006)
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15.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Rudyak V. Yu., Krakhalev M. N., Sutormin V. S., Prischepa O. O., Zyryanov V. Ya., Emelyanenko A. V.
Заглавие : Orientation structures of nematic liquid crystal in ellipsoidal droplets
Коллективы : European Conference on Liquid Crystals
Место публикации : 15th Eur. Conf. Liq. Cryst. (ECLC): conf. progr. - 2019. - Ст.PB-17
Примечания : Cited References: 4
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Parshin A. M., Barannik A. V., Zyryanov V. Ya., Shabanov V. F.
Заглавие : Interference of nonpolarized light in liquid crystal domains on a polymer surface
Место публикации : J. Opt. Soc. Am. B. - 2019. - Vol. 36, Is. 7. - P.1845-1849. - ISSN 0740-3224, DOI 10.1364/JOSAB.36.001845. - ISSN 1520-8540(eISSN)
Примечания : Cited References: 23
Предметные рубрики: FRIEDERICKSZ THRESHOLD
FIELD
LAYER
FILM
Аннотация: The interference of nonpolarized light transmitted through an ensemble of nematic liquid crystal domains formed on a polycarbonate surface has been investigated. A model based on the superposition of the ordinary and extraordinary beams passing through domains with a radial structure has been developed. Expressions for the phase difference and intensity of the interfering beams have been derived that take into account the distribution of the liquid crystal director field. The dependences of the optical transmittance of a domain layer on the applied voltage have been calculated with regard to the material and optical constants of a liquid crystal and structural features and averaged morphological parameters of individual domains in the experimental sample. The results of the calculation are consistent with the experimental data, which confirms the validity of the proposed model. (C) 2019 Optical Society of America
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Rudyak, Vladimir Yu., Prishchepa O. O., Gardymova, Anna P., Emelyanenko, Alexander V., Liu, Jui-Hsiang, Zyryanov V. Ya.
Заглавие : Orientational structures in cholesteric droplets with homeotropic surface anchoring
Коллективы : Russian Foundation for Basic Research Project [19-53-52011 MNT_a, RFMEFI62117X0011]
Место публикации : Soft Matter. - 2019. - Vol. 15, Is. 28. - P.5554-5561. - ISSN 1744-683X, DOI 10.1039/c9sm00384c. - ISSN 1744-6848(eISSN)
Примечания : Cited References: 67. - This work was supported by the Russian Foundation for Basic Research Project No. 19-53-52011 MNT_a. The research is carried out using the equipment of the shared research facilities of HPC computing resources at Lomonosov Moscow State University supported by the project RFMEFI62117X0011.
Предметные рубрики: LIQUID-CRYSTAL DROPLETS
TOPOLOGICAL DEFECTS
NEMATIC DROPLETS
Аннотация: The dependency of orientational structures in cholesteric droplets with homeotropic surface anchoring on the helicity parameter has been studied by experiment and simulations. We have observed a sequence of structures, in which the director configurations and topological defects were identified by comparison of polarized microscopy pictures with simulated textures. A toron-like and low-symmetry intermediate layer-like structures have been revealed and studied in detail. The ranges of stability of the observed structures have been summarized in a general diagram and explained by the helicity parameter dependence of the free energy terms.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Liao H., Zhao M., Zhou Y., Molokeev M. S., Liu Q., Zhang Q., Xia Z.
Заглавие : Polyhedron Transformation toward Stable Narrow-Band Green Phosphors for Wide-Color-Gamut Liquid Crystal Display
Место публикации : Adv. Funct. Mater. - 2019. - Vol. 29, Is. 30. - Ст.1901988. - ISSN 1616301X (ISSN) , DOI 10.1002/adfm.201901988
Примечания : Cited References: 34. - The present work was supported by the National Natural Science Foundations of China (Grant Nos. 51722202, 91622125, and 51572023), Natural Science Foundations of Beijing (2172036), Fundamental Research Funds for the Central Universities (FRF‐TP‐18‐002C1), and the Guangdong Provincial Science & Technology Project (No. 2018A050506004).
Аннотация: A robust and stable narrow-band green emitter is recognized as a key enabler for wide-color-gamut liquid crystal display (LCD) backlights. Herein, an emerging rare earth silicate phosphor, RbNa(Li3SiO4)2:Eu2+ (RN:Eu2+) with exceptional optical properties and excellent thermal stability, is reported. The resulting RN:Eu2+ phosphor presents a narrow green emission band centered at 523 nm with a full width at half maximum of 41 nm and excellent thermal stability (102%@425 K of the integrated emission intensity at 300 K). RN:Eu2+ also shows a high quantum efficiency, an improved chemical stability, and a reduced Stokes shift owing to the modified local environment, in which [NaO8] cubes replace [LiO4] squares in RbLi(Li3SiO4)2:Eu2+ via polyhedron transformation. White light-emitting diode (wLED) devices with a wide color gamut (113% National Television System Committee (NTSC)) and high luminous efficacy (111.08 lm W−1) are obtained by combining RN:Eu2+ as the green emitter, K2SiF6:Mn4+ as the red emitter, and blue-emitting InGaN chips. Using these wLEDs as backlights, a prototype 20.5 in. LCD screen is fabricated, demonstrating the bright future of stable RN:Eu2+ for wide-color-gamut LCD backlight application.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Rudakova N. V., Timofeev I. V., Bikbaev R. G., Pyatnov M. V., Vetrov S. Ya., Lee W.
Заглавие : Chiral optical Tamm states at the interface between an all-dielectric polarization-preserving anisotropic mirror and a cholesteric liquid crystal
Место публикации : Crystals. - 2019. - Vol. 9, Is. 10. - Ст.502. - ISSN 20734352 (ISSN), DOI 10.3390/cryst9100502
Примечания : Cited References: 48. - Russian Foundation for Basic Research (RFBR), Russia, grant No. 19-52-52006; Ministry of Science and Technology, Taiwan (MOST), grant No. 106-2923-M-009-002-MY3; M.V.P. thanks RFBR and KRSTSF for the research Project No. 18-42-243025.
Аннотация: As a new localized state of light, the chiral optical Tamm state exists at the interface between a polarization-retaining anisotropic mirror and a substance with optical activity. Considering a hybrid structure comprising a metal-free polarization-preserving mirror and a cholesteric liquid crystal, we highlight the high Q factor arising from the all-dielectric framework. The intensity of localized light decreases exponentially with increasing distance from the interface. The penetration of the field into the cholesteric liquid crystal is essentially prohibited for wavelengths lying in the photonic bandgap and close to the cholesteric pitch length. The dielectric mirror has its own photonic bandgap. The energy transfer along the interface can be effectively switched off by setting the tangential wave vector to zero. The spectral behavior of the chiral optical Tamm state is observed both as reflection and transmission resonance. This Fano resonance is analogous to the Kopp-Genack effect. Our analytics are well in line with precise calculations, which may pave a new route for the future development of intelligent design for laser and sensing applications.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Parshin A. M.
Заглавие : Structural stability of nematic liquid crystal droplets in the light of the catastrophe theory
Место публикации : Mod. Phys. Lett. B. - 2019. - Vol. 33, Is. 34. - Ст.1950434. - ISSN 0217-9849, DOI 10.1142/S0217984919504347. - ISSN 1793-6640 (eISSN)
Примечания : Cited References: 25. - The work was supported in part by the Siberian Branch of the Russian Academy of Sciences, integration Project No. 356-2018-0058.
Аннотация: Dynamical systems and defects in liquid crystals (LCs) are described using topological methods. Meanwhile, the director field distribution in LC droplets is affected by many bulk and surface factors that are difficult to take into account in the topological analysis. Therefore, the structural instability of a LC droplet formed in a magnetic field has been investigated by us in the framework of the catastrophe theory. The effect of temperature on the control parameters of the cusp catastrophe, which leads to the transition from a bipolar structure with extended poles to the homogeneous or radial configuration, has been estimated. It has been established from the potential curves that the transition is induced by the variation in the LC director orientation between the potential minima related to the LC polymer anchoring energy and magnetic field. The interplay of the cusp catastrophe control parameters and anchoring parameters has been elucidated.
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